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Reaction to fire of polymethylmethacrylate and polyvinylchloride under reduced oxygen concentrations in a controlled-atmospherecone calorimeter 在可控气氛锥量热计中,在降低氧浓度下,聚甲基丙烯酸甲酯和聚氯乙烯与火的反应
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-04-29 DOI: 10.1177/07349041221092968
S. Chatenet, O. Authier, S. Bourbigot, G. Fontaine
Electrical cable sheaths are the most abundant fire load in nuclear power plants, mainly in rooms that are kept in under slight pressure. This configuration leads fires to grow in under-ventilated and vitiated conditions. Assessing fire threat involves characterizing the heat released, responsible for fire growth, and the smoke evolved, which may interact with sensitive components in the area. For that purpose, a revisited controlled-atmosphere cone calorimeter has been designed, set up, and coupled to a Fourier transformed infrared spectrometer and an electrical low-pressure impactor to measure simultaneously the evolved gases and aerosols, respectively. This bench-scale apparatus has been first qualified with polymethylmethacrylate. It has second been used to characterize polyvinylchloride cable sheath representative material reaction to fire in under-ventilated and vitiated conditions. It appeared that vitiation in under-ventilated fires lowers the heat release rate and the fuel mass loss rate.
电缆护套是核电站中最丰富的火灾负荷,主要发生在承受轻微压力的房间中。这种配置会导致火灾在通风和污浊的条件下蔓延。评估火灾威胁包括表征释放的热量,这些热量是火灾发展的原因,以及产生的烟雾,这些烟雾可能与该地区的敏感成分相互作用。为此,设计、设置了一个重新访问的受控大气锥形量热计,并将其连接到傅立叶变换红外光谱仪和电低压冲击器,以分别同时测量释放的气体和气溶胶。这种台式仪器首次通过了聚甲基丙烯酸甲酯的鉴定。它已被第二次用于表征聚氯乙烯电缆护套在通风和污浊条件下对火灾的代表性材料反应。通风不足的火灾中的腐败现象似乎降低了热量释放率和燃料质量损失率。
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引用次数: 2
Experimental study of spruce wood reaction to fire in single burning item test 云杉木材在单燃项试验中对火反应的实验研究
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-04-08 DOI: 10.1177/07349041221089829
L. Terrei, D. Zeinali, Z. Acem, V. Marchetti, Paul Lardet, P. Boulet, G. Parent
The aim of this work is to study and characterize the fire behavior of vertically oriented spruce wood panels using experiments conducted at the scales of cone calorimeter and single burning item tests. For this purpose, first incombustible panels were exposed to burner powers of 15, 20, 30, and 50 kW in the single burning item tests to obtain a mapping of the total heat fluxes received by the panel. Subsequently, wood panels were exposed to the same burner powers for exposure times of 15, 20, and 30 min. Very thin thermocouples were embedded inside the wood panel to measure accurately the in-depth temperatures while the lateral position of the char front on the exposed surface and the depth of the char layer were also measured for each test. The latter measurement permitted to establish a char depth map according to the burner power and exposure time. Correspondingly, it was observed that for a fixed exposure time, the degraded area on the surface grows linearly with the burner power. Moreover, the in-depth char front position deduced from the 300 °C isotherm was found to comply very well with that obtained from direct measurements. Finally, a comparison is made between the char front depths measured with the single burning item and those measured with the cone calorimeter for similar heat fluxes, showing that the corresponding charring rates from these two tests deviate from one another only at low heat fluxes.
本工作的目的是研究和表征垂直定向云杉木板的燃烧行为,采用锥形量热计和单一燃烧项目测试的尺度进行实验。为此目的,首先将不燃面板暴露在燃烧器功率为15、20、30和50千瓦的单燃烧项目测试中,以获得面板接收的总热流的映射。随后,木板暴露在相同的燃烧器功率下,暴露时间分别为15、20和30分钟。在木板内嵌入极薄的热电偶以精确测量深度温度,同时在每次测试中还测量了炭面在暴露表面上的横向位置和炭层的深度。后一种测量允许根据燃烧器功率和曝光时间建立焦炭深度图。相应的,在固定的曝光时间内,表面的退化面积随着燃烧器功率的增加呈线性增长。此外,根据300℃等温线推算出的深部煤焦锋面位置与直接测量结果吻合较好。最后,比较了在相似热流下,单燃烧项与锥量热计测得的炭化锋深度,结果表明,只有在低热流下,两种试验的相应炭化率才会出现偏差。
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引用次数: 0
Material-scale flammability characteristics of epoxy-based coating systems 环氧树脂涂层体系的材料尺度燃烧特性
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-03-28 DOI: 10.1177/07349041221085898
Jonathan Siow, A. Dasari
Flammability of intumescent coatings at the materials-scale is “expected” to have an impact on their fire resistance offered to the steel member. However, to what extent and at what stage during the exposure to an imposed fire curve in a furnace are not thoroughly established. The role of different functionality of the flame-retardant additives in this process is also not clear despite a thorough understanding of their thermal decomposition mechanisms. In an effort to better understand some of these aspects, in this work, model systems based on different flame-retardant additives in epoxy are chosen to cover various strategies (like intumescent, radical quenching, and endothermic behavior) that are typically employed to reduce the flammability of a coating system. The flame-retardant additives chosen are ammonium polyphosphate, tetrabromobisphenol-A, 9,10-dihydro-9-oxa-10-phosphaphenanthrene oxide, and aluminum trihydroxide. The effects of flame-retardant additives on the curing, thermal decomposition, and flammability of epoxy resin are investigated. Reactive flame-retardant additives, in particular, are found to reduce the enthalpy associated with curing of epoxy by more than 45%. However, as the amount of hardener incorporated in these formulations is not controlled despite the presence of reactive flame-retardant additives, this had a negative effect on the thermal decomposition behavior of the epoxy/flame-retardant formulations, and consequently on the calculated decomposition activation energies. Heating rate seems to be a dominating parameter influencing the flammability of the formulations. Peak heat release rate values, irrespective of the formulation, increased by more than 1382%–1970% by changing the heating rate in a pyrolysis flow combustion calorimeter from 6°C/min to 100°C/min. As the flammable volatiles released per unit time are higher at high heating rates, ignition and subsequent flaming of the coating occurred in the furnace tests, where a cellulosic fire curve was simulated. This has significantly influenced the fire resistance times.
膨胀型涂料在材料范围内的易燃性“预计”会对其提供给钢构件的耐火性产生影响。然而,在暴露于熔炉中施加的火曲线的过程中,在多大程度上以及在什么阶段还没有完全确定。阻燃添加剂的不同功能在该过程中的作用也不清楚,尽管对其热分解机制有着深入的了解。为了更好地理解其中的一些方面,在这项工作中,选择了基于环氧树脂中不同阻燃添加剂的模型系统,以涵盖通常用于降低涂层系统可燃性的各种策略(如膨胀、自由基猝灭和吸热行为)。选择的阻燃添加剂是聚磷酸铵、四溴双酚A、9,10-二氢-9-氧杂-10-磷对映菲氧化物和氢氧化铝。研究了阻燃添加剂对环氧树脂固化、热分解和燃烧性能的影响。特别是,发现反应性阻燃添加剂可将与环氧树脂固化相关的焓降低45%以上。然而,尽管存在反应性阻燃添加剂,但由于这些配方中加入的硬化剂的量没有得到控制,这对环氧树脂/阻燃配方的热分解行为产生了负面影响,从而对计算的分解活化能产生了负面影响。加热速率似乎是影响配方可燃性的主要参数。通过将热解流动燃烧量热计中的加热速率从6°C/min更改为100°C/min,无论配方如何,峰值热释放速率值都增加了1382%-1970%以上。由于在高加热速率下每单位时间释放的易燃挥发物较高,因此在模拟纤维素燃烧曲线的熔炉测试中发生了涂层的点火和随后的燃烧。这对耐火时间产生了重大影响。
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引用次数: 0
Effects of spacing on flaming and smoldering firebrands in wildland–urban interface fires 林地-城市界面火灾中间距对燃烧和阴燃火焰的影响
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-03-24 DOI: 10.1177/07349041221081998
Byoungchul Kwon, Ya-Ting T. Liao
Firebrand (ember) attack has been shown to be one of the key mechanisms of wildfire spread into wildland–urban interface communities. After the firebrands land on a substrate material, the ignition propensity of the material depends on not only the attributes (e.g. shape, size, and numbers) but also the distribution of the firebrands. To help characterize this process, this study aims to investigate the effects of gap spacing on the burning behaviors of a group of wooden samples. Experiments are conducted using nine wooden cubes, 19 mm on each side. These samples are arranged in a 3 × 3 square pattern on suspension wires and are ignited by hot coils from the bottom surface. The gap spacing (s) between the samples varies in each test (ranging from 0 to 30 mm). After ignition, the samples are left to burn to completion. The burning process is recorded using video cameras. Sample mass loss and temperatures are monitored during the flaming and smoldering processes. The results show that the flame height and the sample mass loss rate have non-monotonic dependencies on the gap spacing. When the gap spacing reduces, the flame height and the mass loss rate first increase due to enhanced heat input from the adjacent flames to each sample. When s ≤ 10 mm, flames from individual samples are observed to merge into a single large fire. As s further decreases, the air entrainment at the flame bottom decreases and the flame lift-off distance at the flame center increases, resulting in an increased flame height, decreased flame heat feedback to the solid samples, and a decreased mass loss rate. The decreased mass loss rate eventually leads to a decrease in the flame height as well. The gaseous flame height is correlated to the solid burning rate. The correlation generally follows previous empirical equations for continuous fire sources. For the smoldering combustion, compared to a single burning sample, the smoldering temperature and duration significantly increase due to the thermal interactions between adjacent burning samples. To help interpret the results of the burning experiments, thermogravimetric analysis is also performed in air and nitrogen, resulting in heating rates ranging from 10 to 100 K/min.
火牌(余烬)袭击已被证明是野火蔓延到荒地-城市界面社区的关键机制之一。在火球落在基底材料上后,材料的点火倾向不仅取决于属性(例如形状、大小和数量),还取决于火球的分布。为了帮助描述这一过程,本研究旨在研究间隙间距对一组木质样品燃烧行为的影响。实验使用九个木制立方体进行,每侧19毫米。这些样品以3×3正方形的图案排列在吊线上,并由热线圈从底面点燃。样品之间的间隙在每次测试中都有所不同(范围从0到30mm)。点火后,让样品燃烧至完全。燃烧过程用摄像机记录下来。在燃烧和阴燃过程中监测样品的质量损失和温度。结果表明,火焰高度和样品质量损失率与间隙间距具有非单调依赖关系。当间隙间距减小时,火焰高度和质量损失率首先增加,这是由于从相邻火焰向每个样品输入的热量增加。当s≤10 mm时,观察到单个样本的火焰合并为一个大火。随着s的进一步降低,火焰底部的空气夹带减少,火焰中心的火焰提升距离增加,导致火焰高度增加,对固体样品的火焰热反馈减少,质量损失率降低。质量损失率的降低最终也导致火焰高度的降低。气体火焰高度与固体燃烧速率相关。相关性通常遵循先前连续火源的经验方程。对于阴燃燃烧,与单个燃烧样品相比,由于相邻燃烧样品之间的热相互作用,阴燃温度和持续时间显著增加。为了帮助解释燃烧实验的结果,还在空气和氮气中进行热重分析,导致加热速率在10至100K/min范围内。
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引用次数: 2
Flammability and thermal stability of thermoplastic-based composites filled with natural carbon 天然碳填充的热塑性基复合材料的可燃性和热稳定性
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-03-11 DOI: 10.1177/07349041221082928
Y. Al-Majali, J. Trembly
This investigation characterized flammability and thermal stability for a novel sustainable composite engineered for use in building applications. Flammability and thermal stability of coal plastic composites composed of coal (40–60 wt.%) and high-density polyethylene were compared to commercial wood–plastic composites. Pyrolysis thermogravimetric analysis results indicated that coal plastic composites possessed a single-step decomposition and higher char residue, while wood–plastic composites had two-step decomposition, with the first peak occurring at much lower temperatures. Thermogravimetric analyses in air suggest coal plastic composites, compared to wood–plastic composites and neat high-density polyethylene, were more thermally stable. Flash ignition temperatures for coal plastic composites were higher than high-density polyethylene and wood–plastic composites, while self-ignition temperatures were in the same range as wood–plastic composites. Rate of burning data indicated coal plastic composites were slower burning than wood–plastic composites, with increasing coal content slowing burning rate by 19.9%–27.6%. Cone calorimeter testing showed 27% and 59% reduction in total heat release and total smoke release as coal content increased while coal plastic composite with 60 wt.% coal possessed lower overall flammability in comparison with predominant commercially available wood–plastic composite products. Coal improved composite overall thermal stability and flammability by acting as char former and foaming agent.
这项研究的特点是可燃性和热稳定性的新型可持续复合材料工程用于建筑应用。对煤(40 - 60% wt.%)和高密度聚乙烯组成的煤塑复合材料的可燃性和热稳定性与市售木塑复合材料进行了比较。热解热重分析结果表明,煤塑复合材料具有单步分解和较高的焦渣,而木塑复合材料具有两步分解,且第一峰发生在较低的温度下。空气中的热重分析表明,与木塑复合材料和整齐的高密度聚乙烯相比,煤塑复合材料的热稳定性更高。煤塑复合材料的闪燃温度高于高密度聚乙烯和木塑复合材料,自燃温度与木塑复合材料相同。燃烧速率数据表明,煤塑复合材料的燃烧速度比木塑复合材料慢,煤含量的增加使燃烧速率降低了19.9%-27.6%。锥形量热计测试表明,随着煤含量的增加,总放热量和总放烟量分别减少27%和59%。与主要的市售木塑复合产品相比,煤具有较低的总体可燃性。煤作为成焦剂和发泡剂,提高了复合材料的整体热稳定性和可燃性。
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引用次数: 6
Challenges and limitation of wearable sensors used in firefighters’ protective clothing 用于消防员防护服的可穿戴传感器的挑战和局限性
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-03-01 DOI: 10.1177/07349041221079004
F. Shakeriaski, M. Ghodrat
This review aims to present recent improvements and existing challenges in the design of wearable sensors used in the firefighters’ protective clothing. Wearable sensors are generally used directly on the body or placed on wearable items to monitor data for the safety of firefighters. Recently, wearable sensors have attracted much attention from researchers and experts. Most investigations have addressed novel designs for wearable sensors to enhance firefighters’ safety measures and reduce the risk of exposure to fires. This article is an attempt to review design limitations of wearable sensors for future developments and improve existing shortcomings. The growing body of knowledge focused on the application of wearable technology to monitor firefighters’ activity, health, and body temperature. In the following, we have discussed the trials of the design of the existing sensors. Finally, moisture and radiation as common exterior parameters in fire events are discussed which received less attention and have major impact on the performance of firefighters’ wearable sensors.
本文综述了消防员防护服中使用的可穿戴传感器的最新改进和存在的挑战。可穿戴式传感器一般直接使用在身体上或放置在可穿戴物品上,以监测消防员的安全数据。近年来,可穿戴传感器受到了研究人员和专家的广泛关注。大多数调查都涉及可穿戴传感器的新设计,以增强消防员的安全措施并降低暴露于火灾中的风险。本文试图回顾可穿戴传感器的设计局限性,以促进未来的发展,并改进现有的缺点。越来越多的知识集中在可穿戴技术的应用上,以监测消防员的活动、健康和体温。在下面,我们讨论了现有传感器设计的试验。最后,讨论了火灾事件中常见的外部参数湿度和辐射,这两个参数受到的关注较少,但对消防员可穿戴传感器的性能影响较大。
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引用次数: 6
Experimental research on temperature distribution and charring rate of typical components of wood structure building 木结构建筑典型构件温度分布及炭化率的试验研究
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-01-21 DOI: 10.1177/07349041211073303
S. Wei, Huan Yang, Butong Gao, Haitao Cheng, Rongxiu Lu, Lihui Dong
This study presents the fire performance of typical components of wood structure buildings. The wooden beams and floor slabs, quite common in wood structure buildings, were burned with different fire exposure times by a pool fire source. Then, the surface temperature evolution and the charring rate were recorded and analyzed. The results show that the flashover and re-ignition phenomenon occurred in all wood materials under the burning pool fires. The glulam beam cross-section was U-shaped, and the maximum charring rates of glulam beam, cross-laminated timber floor, and cross-laminated timber partition board were 0.833 mm/min, 1.538 mm/min, and 0.435 mm/min, respectively. It can be seen that the combustion behavior time of specimens with different cross-section thicknesses is different. If the thickness of the specimens is appropriately increased, their combustion behavior time can be significantly improved.
本研究介绍了木结构建筑典型构件的防火性能。木梁和楼板在木结构建筑中很常见,它们被水池火源以不同的火灾暴露时间燃烧。然后,记录并分析了表面温度的变化和炭化速率。结果表明,在池火条件下,所有木材材料都出现了闪络和自燃现象。胶合木梁截面呈U形,胶合木梁、木地板和木隔板的最大炭化率分别为0.833 mm/min、1.538 mm/min和0.435 mm/min。可以看出,不同截面厚度的试样的燃烧行为时间不同。如果适当增加试样的厚度,则可以显著改善其燃烧行为时间。
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引用次数: 2
On the application of non-uniform water cooling for the fire safety of fuel storage tank farms 非均匀水冷在油库消防安全中的应用
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2022-01-17 DOI: 10.1177/07349041211072534
A. Saber, M. Abo El-Nasr, A. Elbanhawy
Compromising between application rate and spacing between tanks is one of the vague points regarding fire mitigation in hydrocarbon storage tanks. Codes and standards recommendations are not comprehensive and sometimes contradicting. The traditional, uniform, coolant application technique requires high storage capacities and over-consumes the coolant. This study investigates a non-traditional technique using non-uniform coolant distribution and illustrates the effect of this technique on coolant and land savings. A model is created to simulate fire propagation and mitigation through cooling water application under steady state conditions for surface pool fires in cylindrical hydrocarbon storage tanks. The model considers the types of fuel, the wind speed and direction, the smoke effect and the nozzles distribution, and the number of segments on the target tank surface. The model is applied on a real-life case study. The suggested technique achieved up to 30% reduction in cooling water consumption or 5.6% reduction in land area.
在碳氢化合物储罐中,应用速率和储罐间距之间的折衷是关于火灾缓解的模糊点之一。准则和标准的建议并不全面,有时甚至自相矛盾。传统的、均匀的冷却剂应用技术需要高存储容量,并且会过度消耗冷却剂。本研究调查了一种使用非均匀冷却剂分布的非传统技术,并说明了该技术对冷却剂和土地节约的影响。建立了一个模型来模拟圆柱形碳氢化合物储罐中表面池火灾在稳态条件下通过冷却水应用的火灾传播和缓解。该模型考虑了燃料类型、风速和风向、烟雾效应和喷嘴分布,以及目标油箱表面的节段数量。该模型应用于现实生活中的案例研究。所建议的技术实现了高达30%的冷却水消耗减少或5.6%的土地面积减少。
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引用次数: 1
Design of a radiant panel test at reduced scale for the high throughput development of artificial turf structures 高通量人造草坪结构开发的缩小尺寸辐射板试验设计
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2021-12-15 DOI: 10.1177/07349041211062046
Angeline Paturel, M. Casetta, Stijn Rambour, L. Janus, S. Duquesne
Artificial turf structures are increasingly used in closed areas and have to comply with the European fire standard for building products (EN ISO 13501-1). The main test to evaluate the fire performance of flooring products is the EN ISO 9239-1 radiant panel test. The test principle is to determine the critical heat flux of floorings exposed to a forced ignition and a specific heat flux profile. As large amounts of material are needed to perform the test, the development of a radiant panel test at reduced scale was considered. The experimental design methodology was implemented to mimic the heat flux profile. The fire performance of artificial turf structures was evaluated at both scales and the results were compared. The burnt lengths of the specimens and thus the critical heat flux are similar for both scales. Thus, the downscaled device could advantageously be used for high throughput development of artificial turf structures.
人造草坪结构越来越多地用于封闭区域,并且必须符合欧洲建筑产品防火标准(EN ISO 13501-1)。评估地板产品防火性能的主要测试是EN ISO 9239-1辐射板测试。测试原理是确定暴露在强制点火下的地板的临界热流密度和特定热流密度分布图。由于需要大量的材料来进行测试,因此考虑了小型化辐射板测试的发展。采用实验设计方法模拟热流场分布。在两个尺度上对人造草坪结构的防火性能进行了评价,并对结果进行了比较。试样的燃烧长度和临界热流密度在两种尺度上是相似的。因此,该装置可用于人造草坪结构的高通量开发。
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引用次数: 0
In-depth temperature and smoke production of charring wood under a constant external heat flux 恒定外部热通量下炭化木材的深度温度和产烟
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2021-12-02 DOI: 10.1177/07349041211057893
Yumi Matsuyama, F. Takahashi
The combustion characteristics of charring wood have been studied experimentally in a well-ventilated environment of a smoke chamber. A numerical simulation has also been performed for a limited case, with the Fire Dynamics Simulator, to estimate the burning environment. A horizontally placed specimen (ponderosa pine) with a moisture content of 0% or 20% is exposed to a radiant flux (25 kW/m2), with or without flaming ignition. Simultaneous measurements of the specimen’s in-depth temperature and the mass loss determine the charring front (rate) at 300 °C and the gasification rate, respectively. These condensed-phase conditions relate directly to real-time variations of gas-phase quantities: the specific optical density of smoke and the concentrations of toxic gases measured by a Fourier transform infrared gas analyzer. In-depth temperature trends are similar whether the flame exists, whereas the smoke and toxicants’ concentrations are substantially different. After the charring front moves through the specimen, the oxidative pyrolysis continues under the irradiation at high temperatures (up to ∼550 °C). Carbon monoxide and acrolein are produced continuously throughout the test, and the results indicate strong correlations. Although char formation of wood is favorable for fire safety, consequent incomplete combustion produces smoke and toxicants.
在通风良好的烟室环境中,对炭化木材的燃烧特性进行了实验研究。还使用火灾动力学模拟器对有限情况进行了数值模拟,以估计燃烧环境。将水分含量为0%或20%的水平放置的样品(黄松)暴露于辐射通量(25 kW/m2),具有或不具有火焰点火。样品深度温度和质量损失的同时测量确定了300时的炭化前沿(速率) °C和气化速率。这些凝聚相条件与气相量的实时变化直接相关:通过傅立叶变换红外气体分析仪测量的烟雾的比光密度和有毒气体的浓度。无论火焰是否存在,深度温度趋势都是相似的,而烟雾和有毒物质的浓度则大不相同。炭化前沿穿过试样后,在高温(高达~550 °C)。一氧化碳和丙烯醛在整个测试过程中不断产生,结果表明它们之间存在很强的相关性。尽管木材形成焦炭有利于消防安全,但随之而来的不完全燃烧会产生烟雾和有毒物质。
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引用次数: 0
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Journal of Fire Sciences
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