Pub Date : 2021-11-30DOI: 10.1177/07349041211056343
Manuel J. Barros-Daza, K. Luxbacher, B. Lattimer, J. Hodges
This article presents a conveyor belt fire classification model that allows for the determination of the most effective firefighting strategy. In addition, the effect of belt design parameters on the fire classification was determined. A methodology that involves the use of numerical simulations and artificial neural networks was implemented. An approach previously proposed for modeling fires over conveyor belts was used. With the objective of obtaining some required modeling input parameter and verifying the capacity of this approach to get realistic results, computational fluid dynamics model calibration and validation were carried out using experimental test results available in the literature. Results indicated that scenarios with belt positions closer to the mine roof and greater tunnel heights require a higher longitudinal air velocity to be attacked directly. Furthermore, the belt fire classification model provided by the artificial neural network had an accuracy around 95% when test scenarios were classified.
{"title":"Mine conveyor belt fire classification","authors":"Manuel J. Barros-Daza, K. Luxbacher, B. Lattimer, J. Hodges","doi":"10.1177/07349041211056343","DOIUrl":"https://doi.org/10.1177/07349041211056343","url":null,"abstract":"This article presents a conveyor belt fire classification model that allows for the determination of the most effective firefighting strategy. In addition, the effect of belt design parameters on the fire classification was determined. A methodology that involves the use of numerical simulations and artificial neural networks was implemented. An approach previously proposed for modeling fires over conveyor belts was used. With the objective of obtaining some required modeling input parameter and verifying the capacity of this approach to get realistic results, computational fluid dynamics model calibration and validation were carried out using experimental test results available in the literature. Results indicated that scenarios with belt positions closer to the mine roof and greater tunnel heights require a higher longitudinal air velocity to be attacked directly. Furthermore, the belt fire classification model provided by the artificial neural network had an accuracy around 95% when test scenarios were classified.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"40 1","pages":"44 - 69"},"PeriodicalIF":1.9,"publicationDate":"2021-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42689327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-11-01DOI: 10.1177/07349041211037192
J. Sarazin, Elsa Franchini, V. Dréan, Roman Chiva, S. Bourbigot
This article addresses the development of a bench-scale test (jetfire lab) mimicking the fire exposure of the large-scale jetfire facility. An experimental approach was addressed to develop direct correlation and to validate the similitude between bench-scale test and large-scale jetfire. Comparisons were made by testing Zaltex passive fire protection material in the form of panels. Novel setups were designed to make the jetfire lab able to measure time/temperature curves similar to those obtained at a large scale. The assembly of the tested samples was also investigated. An experimental protocol was elaborated to consider the junction between parts of the sample at the reduced scale. Direct correlation was found between the large and the bench scale and it was evidenced that jetfire lab can be used for preliminary study and development of new thermal barriers for fire protection.
{"title":"Jetfire lab: Jetfire at reduced scale","authors":"J. Sarazin, Elsa Franchini, V. Dréan, Roman Chiva, S. Bourbigot","doi":"10.1177/07349041211037192","DOIUrl":"https://doi.org/10.1177/07349041211037192","url":null,"abstract":"This article addresses the development of a bench-scale test (jetfire lab) mimicking the fire exposure of the large-scale jetfire facility. An experimental approach was addressed to develop direct correlation and to validate the similitude between bench-scale test and large-scale jetfire. Comparisons were made by testing Zaltex passive fire protection material in the form of panels. Novel setups were designed to make the jetfire lab able to measure time/temperature curves similar to those obtained at a large scale. The assembly of the tested samples was also investigated. An experimental protocol was elaborated to consider the junction between parts of the sample at the reduced scale. Direct correlation was found between the large and the bench scale and it was evidenced that jetfire lab can be used for preliminary study and development of new thermal barriers for fire protection.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"455 - 476"},"PeriodicalIF":1.9,"publicationDate":"2021-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48464133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-11-01DOI: 10.1177/07349041211043201
Ping-Jung Li, Chao-Shi Chen, Cheng-Yu Weng, Hsin-Hsiu Ho
This article discusses the overpressure of a gas explosion and the performance of applying water mist for explosion suppression. According to the experimental results, the larger the opening area, the more difficult it is for pressure to accumulate, resulting in lower overpressure of a gas explosion. When the opening was opened under a high air speed environment, the amount of entrained air was greater. Consequently, the occurrence time of the explosion was shorter than at a low air speed. Despite the water mist nozzle being installed outside the enclosure, a propane gas explosion still occurred regardless of the amount of water mist used, failing to suppress the explosion. However, the water mist nozzle installed inside the enclosure supplied an adequate amount of water mist that could wash a part of the propane, resulting in the fuel concentration dropping below the lower explosion limit, hindering the occurrence of an explosion.
{"title":"Evaluation of propane explosion with applied water mist","authors":"Ping-Jung Li, Chao-Shi Chen, Cheng-Yu Weng, Hsin-Hsiu Ho","doi":"10.1177/07349041211043201","DOIUrl":"https://doi.org/10.1177/07349041211043201","url":null,"abstract":"This article discusses the overpressure of a gas explosion and the performance of applying water mist for explosion suppression. According to the experimental results, the larger the opening area, the more difficult it is for pressure to accumulate, resulting in lower overpressure of a gas explosion. When the opening was opened under a high air speed environment, the amount of entrained air was greater. Consequently, the occurrence time of the explosion was shorter than at a low air speed. Despite the water mist nozzle being installed outside the enclosure, a propane gas explosion still occurred regardless of the amount of water mist used, failing to suppress the explosion. However, the water mist nozzle installed inside the enclosure supplied an adequate amount of water mist that could wash a part of the propane, resulting in the fuel concentration dropping below the lower explosion limit, hindering the occurrence of an explosion.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"443 - 454"},"PeriodicalIF":1.9,"publicationDate":"2021-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49570703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-11-01DOI: 10.1177/07349041211036651
Junhui Gong, Hongen Zhou, Hong Zhu, Conor G. McCoy, S. Stoliarov
Oriented strand board is a widely used construction material responsible for a substantial portion of the fire load of many buildings. To accurately model oriented strand board fire response, kinetics and thermodynamics of its thermal decomposition and combustion were carefully characterized using milligram-scale testing in part I of this study. In the current work, Controlled Atmosphere Pyrolysis Apparatus II tests were performed on representative gram-sized oriented strand board samples at a range of radiant heat fluxes. An automated inverse analysis of the sample temperature data obtained in these tests was employed to determine the thermal conductivities of the undecomposed oriented strand board and condensed-phase products of its decomposition. A complete pyrolysis model was formulated for this material and used to predict the mass loss rates measured in the Controlled Atmosphere Pyrolysis Apparatus II experiments. These mass loss rate profiles were predicted well with the exception of the second mass loss rate peak observed at 65 kW m−2 of radiant heat flux, which was underpredicted. To further validate the model, cone calorimeter tests were performed on oriented strand board at 25 and 50 kW m−2 of radiant heat flux. The results of these tests, including both mass loss rate and heat release rate profiles, were predicted reasonably well by the model.
定向刨花板是一种广泛使用的建筑材料，承担了许多建筑物的很大一部分火灾负荷。为了准确地模拟面向刨花板的火灾反应，本研究的第一部分使用毫克级测试仔细表征了其热分解和燃烧的动力学和热力学。在当前的工作中，受控气氛热解装置II在一定范围的辐射热通量下对具有代表性的克级定向板样品进行了测试。对这些测试中获得的样品温度数据进行自动反分析，以确定未分解的定向刨花板及其分解后的冷凝相产物的导热系数。建立了该材料的完整热解模型，并用于预测可控气氛热解装置II实验中测量的质量损失率。除了在辐射热流密度为65 kW m−2时观测到的第二个质量损失率峰值被低估外，这些质量损失率曲线都得到了很好的预测。为了进一步验证该模型，在定向刨花板上进行了辐射热通量为25和50 kW m - 2的锥形量热仪测试。这些试验的结果，包括质量损失率和放热率分布，都可以通过模型很好地预测。
{"title":"Development of a pyrolysis model for oriented strand board: Part II—Thermal transport parameterization and bench-scale validation","authors":"Junhui Gong, Hongen Zhou, Hong Zhu, Conor G. McCoy, S. Stoliarov","doi":"10.1177/07349041211036651","DOIUrl":"https://doi.org/10.1177/07349041211036651","url":null,"abstract":"Oriented strand board is a widely used construction material responsible for a substantial portion of the fire load of many buildings. To accurately model oriented strand board fire response, kinetics and thermodynamics of its thermal decomposition and combustion were carefully characterized using milligram-scale testing in part I of this study. In the current work, Controlled Atmosphere Pyrolysis Apparatus II tests were performed on representative gram-sized oriented strand board samples at a range of radiant heat fluxes. An automated inverse analysis of the sample temperature data obtained in these tests was employed to determine the thermal conductivities of the undecomposed oriented strand board and condensed-phase products of its decomposition. A complete pyrolysis model was formulated for this material and used to predict the mass loss rates measured in the Controlled Atmosphere Pyrolysis Apparatus II experiments. These mass loss rate profiles were predicted well with the exception of the second mass loss rate peak observed at 65 kW m−2 of radiant heat flux, which was underpredicted. To further validate the model, cone calorimeter tests were performed on oriented strand board at 25 and 50 kW m−2 of radiant heat flux. The results of these tests, including both mass loss rate and heat release rate profiles, were predicted reasonably well by the model.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"477 - 494"},"PeriodicalIF":1.9,"publicationDate":"2021-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48864535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-10-08DOI: 10.1177/07349041211039752
J. Marti, B. Schartel, E. Oñate
The behavior of the cable jacket in fire characterized by the tendency to melt and drip constitutes a major source of fire hazard. The reason is that the melted material may convey the flame from one point to another, expanding fire and contributing to the fire load. In this article, the capability of a new computational strategy based on the particle finite element method for simulating a bench-scale cables burning test is analyzed. The use bench-scale test has been previously used to simulate the full-scale test described in EN 50399. As the air effect is neglected, a simple combustion model is included. The samples selected are two cables consisting of a copper core and differently flame retarded thermoplastic polyurethane sheets. The key modeling parameters were determined from different literature sources as well as experimentally. During the experiment, the specimen was burned under the test set-up condition recording the process and measuring the temperature evolution by means of three thermocouples. Next, the test was reproduced numerically and compared with a real fire test. The numerical results show that the particle finite element method can accurately predict the evolution of the temperature and the melting of the jacket.
{"title":"Simulation of the burning and dripping cables in fire using the particle finite element method","authors":"J. Marti, B. Schartel, E. Oñate","doi":"10.1177/07349041211039752","DOIUrl":"https://doi.org/10.1177/07349041211039752","url":null,"abstract":"The behavior of the cable jacket in fire characterized by the tendency to melt and drip constitutes a major source of fire hazard. The reason is that the melted material may convey the flame from one point to another, expanding fire and contributing to the fire load. In this article, the capability of a new computational strategy based on the particle finite element method for simulating a bench-scale cables burning test is analyzed. The use bench-scale test has been previously used to simulate the full-scale test described in EN 50399. As the air effect is neglected, a simple combustion model is included. The samples selected are two cables consisting of a copper core and differently flame retarded thermoplastic polyurethane sheets. The key modeling parameters were determined from different literature sources as well as experimentally. During the experiment, the specimen was burned under the test set-up condition recording the process and measuring the temperature evolution by means of three thermocouples. Next, the test was reproduced numerically and compared with a real fire test. The numerical results show that the particle finite element method can accurately predict the evolution of the temperature and the melting of the jacket.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"40 1","pages":"3 - 25"},"PeriodicalIF":1.9,"publicationDate":"2021-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48939769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-10-07DOI: 10.1177/07349041211050328
K. Brent, J. T’ien
In using thin fire blankets to protect structures in wildfires, heat rejections by radiation (reflection and emission) are essential for good performance. By varying the radiative properties of the front and back surfaces of the blankets, this article offers an optimization study of several scenarios of incident heat flux including pure convection, pure radiation, and combinations of the two. Two types of blanket heat-blocking efficiencies are studied in the optimization scheme. An overall efficiency is defined as the amount of incident heat blocked to the total amount of incident heat in specified wildfire scenarios. An instantaneous heat-blocking efficiency is defined as the instantaneous heat flux blocked to the instantaneous incident total heat flux which provides good understanding of the physics of heat-blocking mechanisms of fire blanket under quasi-steady conditions. In addition to maximizing these heat-blocking efficiencies, there are other optimization objectives, including the minimization of the blanket backside temperature. A genetic algorithm is used for the multi-objective optimization schemes. For the transient heat incidence, the optimization for the entire time sequence is performed with the possibility of a change of blanket radiative properties during the fire sequence, accounting for changes to the fire-facing surface caused by the incident heat.
{"title":"Performance optimization of thin fire blankets by varying their radiative properties","authors":"K. Brent, J. T’ien","doi":"10.1177/07349041211050328","DOIUrl":"https://doi.org/10.1177/07349041211050328","url":null,"abstract":"In using thin fire blankets to protect structures in wildfires, heat rejections by radiation (reflection and emission) are essential for good performance. By varying the radiative properties of the front and back surfaces of the blankets, this article offers an optimization study of several scenarios of incident heat flux including pure convection, pure radiation, and combinations of the two. Two types of blanket heat-blocking efficiencies are studied in the optimization scheme. An overall efficiency is defined as the amount of incident heat blocked to the total amount of incident heat in specified wildfire scenarios. An instantaneous heat-blocking efficiency is defined as the instantaneous heat flux blocked to the instantaneous incident total heat flux which provides good understanding of the physics of heat-blocking mechanisms of fire blanket under quasi-steady conditions. In addition to maximizing these heat-blocking efficiencies, there are other optimization objectives, including the minimization of the blanket backside temperature. A genetic algorithm is used for the multi-objective optimization schemes. For the transient heat incidence, the optimization for the entire time sequence is performed with the possibility of a change of blanket radiative properties during the fire sequence, accounting for changes to the fire-facing surface caused by the incident heat.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"40 1","pages":"26 - 43"},"PeriodicalIF":1.9,"publicationDate":"2021-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45664907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-20DOI: 10.1177/07349041211043238
Zhouquan Cai, Xiao Chen, Jiaqing Zhang, Shouxiang Lu
The effect of different cable layouts on the fire behavior of electric cable arrays was experimentally studied. The influence of external heat flux on cable fire characteristics was investigated. Several parameters for electrical cables such as the post-burning morphology, ignition time, heat release rate, peak heat release rate and total heat release were obtained. The results show that cable layouts could affect cable charring degrees according to the post-burning morphology. A linear relationship was found in the transformed form of time to ignition and radiant heat flux, and the critical radiant heat flux value for the single cable array appeared smaller than that for the other two layouts. The peak heat release rate for Cables A–D with the single array presents the increasing trend with an increase in radiant heat flux, while the two parallel and intersectional cable arrays present the different trends. Moreover, the total heat release values of Cables A–D in the different cable layouts were analyzed. This work provides the basic data and preliminary investigation to fire engineering of cable arrays with the different layouts.
{"title":"Bench-scale experimental study on the fire behavior of electric cable arrays by considering different layouts","authors":"Zhouquan Cai, Xiao Chen, Jiaqing Zhang, Shouxiang Lu","doi":"10.1177/07349041211043238","DOIUrl":"https://doi.org/10.1177/07349041211043238","url":null,"abstract":"The effect of different cable layouts on the fire behavior of electric cable arrays was experimentally studied. The influence of external heat flux on cable fire characteristics was investigated. Several parameters for electrical cables such as the post-burning morphology, ignition time, heat release rate, peak heat release rate and total heat release were obtained. The results show that cable layouts could affect cable charring degrees according to the post-burning morphology. A linear relationship was found in the transformed form of time to ignition and radiant heat flux, and the critical radiant heat flux value for the single cable array appeared smaller than that for the other two layouts. The peak heat release rate for Cables A–D with the single array presents the increasing trend with an increase in radiant heat flux, while the two parallel and intersectional cable arrays present the different trends. Moreover, the total heat release values of Cables A–D in the different cable layouts were analyzed. This work provides the basic data and preliminary investigation to fire engineering of cable arrays with the different layouts.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"427 - 442"},"PeriodicalIF":1.9,"publicationDate":"2021-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42841444","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-01DOI: 10.1177/07349041211034460
G. Ronquillo, D. Hopkin, M. Spearpoint
Concerns about the environmental impact of building construction is leading to timber being more commonly used. However, it often faces scepticism regarding its safety in the event of fire. This article provides a point of reference on the fire performance of cross-laminated timber through a review of large-scale tests. Although adequately protecting CLT can make its contribution to fire insignificant, some of the internal surface of an enclosure can be exposed whilst still achieving adequate fire performance. Natural fire tests show that the charring rate and zero-strength layer thickness are higher than commonly used in guidance documents. The type of adhesive used to bond lamellae influences performance where delamination can lead to secondary flashovers, particularly in smaller enclosures. Structural elements can potentially collapse without self-extinction and/or suppression intervention. Tests to date have focussed on a residential context and knowledge gaps remain regarding larger enclosures, such as office-type buildings.
{"title":"Review of large-scale fire tests on cross-laminated timber","authors":"G. Ronquillo, D. Hopkin, M. Spearpoint","doi":"10.1177/07349041211034460","DOIUrl":"https://doi.org/10.1177/07349041211034460","url":null,"abstract":"Concerns about the environmental impact of building construction is leading to timber being more commonly used. However, it often faces scepticism regarding its safety in the event of fire. This article provides a point of reference on the fire performance of cross-laminated timber through a review of large-scale tests. Although adequately protecting CLT can make its contribution to fire insignificant, some of the internal surface of an enclosure can be exposed whilst still achieving adequate fire performance. Natural fire tests show that the charring rate and zero-strength layer thickness are higher than commonly used in guidance documents. The type of adhesive used to bond lamellae influences performance where delamination can lead to secondary flashovers, particularly in smaller enclosures. Structural elements can potentially collapse without self-extinction and/or suppression intervention. Tests to date have focussed on a residential context and knowledge gaps remain regarding larger enclosures, such as office-type buildings.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"327 - 369"},"PeriodicalIF":1.9,"publicationDate":"2021-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42600650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-01DOI: 10.1177/07349041211030188
Yawei Wang, G. Zou, C. Liu, Y. Gao
The Halon 1301 fixed gas fire extinguishing system used in ship engine rooms has been banned from production all over the world, because halon destroys the ozone layer. Therefore, it is necessary to find an environmentally friendly, compatible and efficient alternative firefighting system. In this study, we performed fire extinguishing tests in an ISO9705 standard room for four alternative fire extinguishing agents, as well as Halon 1301. The fire extinguishing efficiency of each agent was determined based on its cooling effect, dilution effect of oxygen concentration, the extinguishing time of the oil pool fire and the re-ignition probability of the wood stack. The test results provide data support for the selection of alternatives of Halon 1301 from the aspect of fire extinguishing efficiency. Among these results, Novec 1230 had the best ability to put out the oil pool fire, and HFC-227ea suppressed the wood stack fire the best. The difference between the cooling ability of each fire extinguishing agent was small, and the inert gas (IG-541) displayed the best ability to dilute oxygen. Hot aerosol required the longest time to extinguish fire. Consequently, under the existing design standards, HFC-227ea had the better firefighting efficiency, more suitable to replace Halon 1301.
{"title":"Comparison of fire extinguishing performance of four halon substitutes and Halon 1301","authors":"Yawei Wang, G. Zou, C. Liu, Y. Gao","doi":"10.1177/07349041211030188","DOIUrl":"https://doi.org/10.1177/07349041211030188","url":null,"abstract":"The Halon 1301 fixed gas fire extinguishing system used in ship engine rooms has been banned from production all over the world, because halon destroys the ozone layer. Therefore, it is necessary to find an environmentally friendly, compatible and efficient alternative firefighting system. In this study, we performed fire extinguishing tests in an ISO9705 standard room for four alternative fire extinguishing agents, as well as Halon 1301. The fire extinguishing efficiency of each agent was determined based on its cooling effect, dilution effect of oxygen concentration, the extinguishing time of the oil pool fire and the re-ignition probability of the wood stack. The test results provide data support for the selection of alternatives of Halon 1301 from the aspect of fire extinguishing efficiency. Among these results, Novec 1230 had the best ability to put out the oil pool fire, and HFC-227ea suppressed the wood stack fire the best. The difference between the cooling ability of each fire extinguishing agent was small, and the inert gas (IG-541) displayed the best ability to dilute oxygen. Hot aerosol required the longest time to extinguish fire. Consequently, under the existing design standards, HFC-227ea had the better firefighting efficiency, more suitable to replace Halon 1301.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"370 - 399"},"PeriodicalIF":1.9,"publicationDate":"2021-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/07349041211030188","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44371488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-13DOI: 10.1177/07349041211025456
Yinglin Liu, Yina Liu, Rongjie Yang
It is reported a convenient method to obtain flame-retardant polylactic acid composite by adding low amount of crystal form II ammonium polyphosphate (APP-II) or nano-compound of crystal form II ammonium polyphosphate with calcium-based montmorillonite. The structures and thermal properties of the crystal form II ammonium polyphosphate and crystal form II ammonium polyphosphate with calcium-based montmorillonite were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, and thermogravimetric analysis. Crystallography and morphologies of the polylactic acid and its composites with the crystal form II ammonium polyphosphate and crystal form II ammonium polyphosphate with calcium-based montmorillonite were measured through differential scanning calorimeter and scanning electron microscopy. In flame retardancy of the polylactic acid composites, the 5 wt% crystal form II ammonium polyphosphate could make the polylactic acid achieve the UL-94 vertical burning V-0 rating and limited oxygen index 27.3%. When using crystal form II ammonium polyphosphate with calcium-based montmorillonite in flame-retarding polylactic acid, only 3 wt% nano-compound can result in the same V-0 rating level and the limited oxygen index of 28.0%. Meanwhile, polylactic acid with crystal form II ammonium polyphosphate or crystal form II ammonium polyphosphate with calcium-based montmorillonite still keeps the good mechanical properties. The developed systems are environmentally friendly and highly effective flame retarding, which show a promising future in practical large-scale polylactic acid application.
{"title":"Polylactic acid flame-retarded by nano-compound of form II ammonium polyphosphate with montmorillonite","authors":"Yinglin Liu, Yina Liu, Rongjie Yang","doi":"10.1177/07349041211025456","DOIUrl":"https://doi.org/10.1177/07349041211025456","url":null,"abstract":"It is reported a convenient method to obtain flame-retardant polylactic acid composite by adding low amount of crystal form II ammonium polyphosphate (APP-II) or nano-compound of crystal form II ammonium polyphosphate with calcium-based montmorillonite. The structures and thermal properties of the crystal form II ammonium polyphosphate and crystal form II ammonium polyphosphate with calcium-based montmorillonite were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, and thermogravimetric analysis. Crystallography and morphologies of the polylactic acid and its composites with the crystal form II ammonium polyphosphate and crystal form II ammonium polyphosphate with calcium-based montmorillonite were measured through differential scanning calorimeter and scanning electron microscopy. In flame retardancy of the polylactic acid composites, the 5 wt% crystal form II ammonium polyphosphate could make the polylactic acid achieve the UL-94 vertical burning V-0 rating and limited oxygen index 27.3%. When using crystal form II ammonium polyphosphate with calcium-based montmorillonite in flame-retarding polylactic acid, only 3 wt% nano-compound can result in the same V-0 rating level and the limited oxygen index of 28.0%. Meanwhile, polylactic acid with crystal form II ammonium polyphosphate or crystal form II ammonium polyphosphate with calcium-based montmorillonite still keeps the good mechanical properties. The developed systems are environmentally friendly and highly effective flame retarding, which show a promising future in practical large-scale polylactic acid application.","PeriodicalId":15772,"journal":{"name":"Journal of Fire Sciences","volume":"39 1","pages":"495 - 511"},"PeriodicalIF":1.9,"publicationDate":"2021-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44307938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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