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Synergistic effect of nano silicon and piperazine pyrophosphate/melamine polyphosphate on flame retardancy of polypropylene 纳米硅与焦磷酸哌嗪/聚磷酸三聚氰胺对聚丙烯阻燃性能的协同效应
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-06-20 DOI: 10.1177/07349041231175344
Chenran Fan, Lijuan Wei, Shicheng Zhao
To improve the flame retardant efficiency of intumescent flame retardants, some nano-scale additives as synergists were always added. In this work, nano silicon and piperazine pyrophosphate/melamine polyphosphate into polypropylene was investigated, which was obviously efficient to improve thermal stability and flame retardancy. The optimal synergistic ratio corresponded to 1 wt% SiO2, 10 wt% piperazine pyrophosphate, and 5 wt% melamine polyphosphate. The system passed the UL-94 V-1 classification and had a limiting oxygen index value of 34.5%. It exhibited a decrease on peak heat release rate and peak smoke production rate by 81% and 80%, respectively. Based on characterizations of scanning electron microscope, Fourier-transform infrared spectroscopy, and X-ray photoelectron spectroscopy, the synergistic mechanism was investigated. A reactive cross-linking network between SiO2 and piperazine pyrophosphate/melamine polyphosphate during burning was formed to enhance the structure of carbon protective layer. Nano silicon acted as a foaming nucleating agent to promote the formation of porous dense carbon layer in intumescent flame retardants during burning. The synergistic strategy of SiO2 and piperazine pyrophosphate/melamine polyphosphate provided new compounded system for the design of polymeric materials with excellent flame retardancy, great thermal stability, and low release of heat and smoke.
为了提高膨胀型阻燃剂的阻燃效率,通常需要添加纳米级助剂作为增效剂。本文研究了纳米硅与焦磷酸哌嗪/聚磷酸三聚氰胺合成聚丙烯的方法,该方法对提高聚丙烯的热稳定性和阻燃性有明显的效果。最佳增效比例为1 wt% SiO2, 10 wt%焦磷酸哌嗪,5 wt%聚磷酸三聚氰胺。该系统通过UL-94 V-1分级,极限氧指数为34.5%。峰值放热率和峰值产烟率分别降低了81%和80%。基于扫描电镜、傅里叶变换红外光谱和x射线光电子能谱的表征,对协同作用机理进行了研究。燃烧过程中SiO2与焦磷酸哌嗪/聚磷酸三聚氰胺形成反应交联网络,增强了碳保护层的结构。在膨胀型阻燃剂中,纳米硅作为发泡成核剂,在燃烧过程中促进多孔致密碳层的形成。SiO2与焦磷酸哌嗪/三聚氰胺的协同策略为设计阻燃性好、热稳定性好、放热低、发烟少的高分子材料提供了新的复合体系。
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引用次数: 0
Modelling of the swelling behaviour of a fire retarded material under a cone calorimeter 锥形量热计下阻燃材料膨胀行为的建模
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-06-06 DOI: 10.1177/07349041231177183
Manon Fleurotte, G. Debenest, O. Authier, G. Fontaine, S. Bourbigot, A. Amokrane
Modelling the swelling behaviour of intumescent materials is an important and challenging issue because this phenomenon influences their pyrolysis process. It must be therefore considered to improve the predictability of pyrolysis models. The objective of this work was to implement a swelling model in the pyrolysis code Gpyro in order to predict the behaviour of a sample of ethylene vinyl acetate containing aluminium trihydroxide (EVA/ATH) polymer studied by cone calorimetry. This polymer is used for making the external sheath of electrical cables. Unlike existing works in the literature, the model implemented here, and adapted to EVA/ATH, does not require information on the densities of the initial and final materials, which makes it more predictive. To characterize the swelling, experiments were carried out to measure the evolution of the sample thickness as a function of time. The mass loss and the back surface temperature of the sample were also measured. This was done under different operating conditions. These measurements are compared with the swelling predicted by the model and the results were found to be in good agreement. The model can be extended easily to other materials.
对膨胀材料的膨胀行为进行建模是一个重要且具有挑战性的问题,因为这种现象会影响其热解过程。因此,必须考虑提高热解模型的可预测性。这项工作的目的是在热解代码Gpyro中实现溶胀模型,以预测通过锥形量热法研究的含乙烯-乙酸乙烯酯-氢氧化铝(EVA/ATH)聚合物样品的行为。这种聚合物用于制造电缆的外护套。与文献中现有的工作不同,这里实施的模型适用于EVA/ATH,不需要关于初始和最终材料密度的信息,这使其更具预测性。为了表征溶胀,进行了实验以测量样品厚度随时间的变化。还测量了样品的质量损失和背面温度。这是在不同的操作条件下完成的。将这些测量结果与模型预测的溶胀进行比较,发现结果非常一致。该模型可以很容易地扩展到其他材料。
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引用次数: 1
A review on volatilization of flame retarding compounds from polymeric textile materials used in firefighter protective garment 消防员防护服用高分子纺织材料中阻燃剂的挥发研究进展
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-05-06 DOI: 10.1177/07349041231171349
Vincent N Mokoana, J. Asante, O. J. Okonkwo
Polymeric textile materials, now, find extensive application in modern society than previously imagined, particularly in protective clothing. The application of these polymeric materials has been restricted by their flammability and contribution to fire risk. Flame retarding compounds and inherent flame-retardant materials have been introduced to reduce and even halt the flammability of polymers. However, over time, flame retardants tend to leach out of materials. The exposure of polymer textile to varying heat intensities may trigger polymer and flame retardant’s volatilization and thermal degradation. Firefighters may be exposed to toxic chemicals through the volatilization of flame-retardant compounds from the bunker gear. Flame retardant’s volatilization is associated with thermal degradation of the flame-retardant chemical compounds in the textile material. This review focuses on volatilization of flame retardants from protective textile materials resulting from exposure to heat and seeks to provide the necessary understanding about the release of flame retardants from flame-retardant textiles, particularly firefighting garments.
聚合物纺织材料现在在现代社会中的应用比以前想象的要广泛,尤其是在防护服中。这些聚合物材料的应用受到其易燃性和火灾风险的限制。阻燃化合物和固有的阻燃材料已经被引入以减少甚至阻止聚合物的可燃性。然而,随着时间的推移,阻燃剂往往会从材料中浸出。聚合物纺织品暴露在不同的热强度下可能会引发聚合物和阻燃剂的挥发和热降解。消防队员可能会因掩体设备中的阻燃化合物挥发而暴露在有毒化学物质中。阻燃剂的挥发与纺织材料中阻燃化学化合物的热降解有关。这篇综述的重点是阻燃剂因暴露在高温下而从防护纺织品中挥发,并试图对阻燃纺织品,特别是消防服装中阻燃剂的释放提供必要的了解。
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引用次数: 1
Performance improvement of the dry chemical-based fire extinguishers using nanocalcium silicate synthesised from biowaste 利用生物废弃物合成纳米硅酸钙提高干粉灭火器性能
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-04-24 DOI: 10.1177/07349041231168553
Nuttabodee Viriyawattana, Surachat Sinworn
Herein, we investigated nanocalcium silicate (nCa2SiO4) prepared from clam shells and rice husks for its utilisation as a chemical agent in a fire-extinguishing mixture comprising ABC dry powder. The fire-extinguishing performance was evaluated with Class A and B fires. The prepared mixture was compared with commercial mono-ammonium phosphate powder based on different parameters, namely extinguishing time, amount of extinguishing agent used, fire temperature reduction rate, powder coating on the fuel and a reburn incident. It was found that the mixture of nCa2SiO4 and ABC dry powder could extinguish Class A and B fires within 10.67 and 9 s, respectively, while commercial mono-ammonium phosphate powder required 11 and 11.33 s to extinguish Class A and B fires, respectively. Thus, the mixture of nCa2SiO4 and ABC dry powder was more effective and less consumed as compared to commercial mono-ammonium phosphate powder (Class B only). This study demonstrates the efficacy of nCa2SiO4 to improve the performance of dry chemical-based fire extinguishers.
在此,我们研究了由蛤壳和稻壳制备的纳米硅酸钙(nCa2SiO4),将其用作包括ABC干粉的灭火混合物中的化学剂。对A类和B类火灾的灭火性能进行了评估。基于不同的参数,即灭火时间、灭火剂用量、火灾温度降低率、燃料上的粉末涂层和再燃事件,将制备的混合物与商业磷酸一铵粉末进行了比较。研究发现,nCa2SiO4和ABC干粉的混合物分别能在10.67和9s内扑灭A类和B类火灾,而商业磷酸一铵粉末分别需要11s和11.33s才能扑灭A类和B类火灾。因此,与商业磷酸一铵粉末(仅B类)相比,nCa2SiO4和ABC干粉的混合物更有效,消耗更少。本研究证明了nCa2SiO4在提高干粉灭火器性能方面的功效。
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引用次数: 0
Flammability and explosion characteristics of hardwood dust 硬木粉尘的燃烧和爆炸特性
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-04-19 DOI: 10.1177/07349041231168554
J. Przybysz, M. Celiński, P. Kozikowski, K. Mizera, M. Borucka, Agnieszka Gajek
Wood dust consists of the fine particles of wood that are produced when wood is processed. It is considered explosive, especially if it produces a dust cloud. Initiating the combustion process inside the dust–air cloud spreads this process throughout the entire volume. In this article, experiment was carried out to study the influence of type of hardwood on combustion parameters. An experimental investigation was carried out to determine the evolution of the ignition sensitivity, fire behaviour and explosion characteristics of three types of hardwood dust. To determine dust behaviour under fire conditions, a cone calorimeter was used. Explosion characteristics were tested with the use of a 20 L spherical vessel and minimum ignition energy tested on MINOR II Apparatus, which is a modified Hartmann’s Tube. Studies have shown a large effect of particle size on explosion parameters, while for flammability parameters the effect is not so noticeable.
木尘由木材加工过程中产生的木材细颗粒组成。它被认为是爆炸性的,尤其是当它产生尘埃云时。在尘埃-空气云中启动燃烧过程会将这一过程传播到整个体积。本文通过实验研究了硬木的种类对燃烧参数的影响。进行了一项实验研究,以确定三种类型的硬木粉尘的着火敏感性、着火行为和爆炸特性的演变。为了确定火灾条件下的灰尘行为,使用了锥形量热计。使用20 L球形容器,并在改进的哈特曼管MINOR II装置上测试了最小点火能量。研究表明,颗粒大小对爆炸参数有很大影响,而对于可燃性参数,这种影响并不那么明显。
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引用次数: 0
Automatic early detection of wildfire smoke with visible-light cameras and EfficientDet 使用可见光相机和EfficientDet自动早期检测野火烟雾
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-04-18 DOI: 10.1177/07349041231163451
A. Fernandes, Andrei Borissovitch Utkin, Paulo Chaves
The ability of EfficientDet, a framework developed in 2019 for object detection, to automatically detect smoke plumes at a distance of several kilometers is demonstrated. Recent articles have raised concerns about the effectiveness of EfficientDet in fire detection applications, with over 40% of false positives reported. The proposed EfficientDet model achieved a true detection rate of 80.4% and a false-positive rate of 1.13% on a testing set. The data set used in this study, which includes 14,125 smoke and 21,203 non-smoke images, is one of the largest, or even the largest, of its kind reported in the literature for images containing smoke plumes. Our results surpass those of a previous study that used the same data set and are more reliable and realistic than those reported by others, which may seem better, but were calculated using smaller and less representative data sets.
EfficientDet是一个于2019年开发的用于物体检测的框架,它能够自动检测几公里外的烟羽。最近的文章对EfficientDet在火灾探测应用中的有效性提出了担忧,报告的假阳性率超过40%。所提出的EfficientDet模型在测试集上实现了80.4%的真检测率和1.13%的假阳性率。这项研究中使用的数据集包括14125张烟雾图像和21203张非烟雾图像,是文献中报道的含有烟羽的图像中最大甚至最大的数据集之一。我们的结果超过了之前使用相同数据集的研究,比其他人报告的结果更可靠、更现实,这些结果可能看起来更好,但使用的是更小、更不具代表性的数据集。
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引用次数: 1
Toxicity of organophosphorus flame retardants 有机磷阻燃剂的毒性
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-03-23 DOI: 10.1177/07349041231161493
B. Howell
As the development and use of organophosphorus flame retardants have become more prevalent, concerns about potential toxicity are being raised. To date, most studies on potential toxicity have focused on simple phosphate esters and often include both alkyl and aryl esters or, in some cases, even halogenated phosphate esters (which should more properly be included among organohalogen flame retardants). The inclusion of several kinds of esters into a single study leads to muddled conclusions. Each class of phosphate esters should be subjected to toxicity assessment separately. Furthermore, the potential toxicity of the more effective (lower level of oxygenation at phosphorus: phosphonates, phosphinates, phosphine oxides) organophosphorus flame retardants has been little explored. The few results available suggest that these compounds exhibit no or minimal toxicity (lower than that of phosphates?). This represents an area that should be the focus of careful detailed studies to establish any potential toxicity.
随着有机磷阻燃剂的开发和使用越来越普遍,人们对其潜在毒性的担忧也越来越多。迄今为止,大多数关于潜在毒性的研究都集中在简单的磷酸酯上,通常包括烷基酯和芳基酯,或者在某些情况下,甚至包括卤化磷酸酯(更应该将其列入有机卤素阻燃剂中)。将几种酯类纳入一项研究导致结论混乱。每一类磷酸酯应分别进行毒性评估。此外,对更有效的有机磷阻燃剂(对磷的氧化水平较低:膦酸盐、膦酸盐、磷氧化物)的潜在毒性研究甚少。现有的少数结果表明,这些化合物没有毒性或毒性很小(低于磷酸盐)。这一领域应该成为仔细详细研究的重点,以确定任何潜在的毒性。
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引用次数: 0
Impact of additive manufacturing on reaction to fire 增材制造对火灾反应的影响
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-03-07 DOI: 10.1177/07349041231158990
T. Nazé, F. Poutch, F. Bonnet, M. Jimenez, S. Bourbigot
Additive manufacturing, including fused deposition modelling, is a growing technology opening up wide perspectives in material sciences. However, the ability to produce suitable fire-retarded materials via this process has never been studied extensively. This work focuses on understanding the relation between reaction to fire and numerous additive manufacturing parameters. The goal was to determine the impact of those parameters on standard fire tests such as flame propagation test (UL94V) and cone calorimetry. The results were compared with material samples formulated via usual processes. On one hand, flame propagation results are impacted by many additive manufacturing parameters, such as the design of the part and the material flow. On the other hand, cone calorimeter results are only influenced by parameters having an impact on the sample mass.
增材制造,包括熔融沉积建模,是一项不断发展的技术,在材料科学中开辟了广阔的前景。然而,通过该工艺生产合适的阻燃材料的能力从未得到广泛研究。这项工作的重点是了解对火的反应和许多增材制造参数之间的关系。目的是确定这些参数对标准火灾测试的影响,如火焰传播测试(UL94V)和锥形量热法。将结果与通过常规工艺配制的材料样品进行比较。一方面,火焰传播结果受到许多增材制造参数的影响,如零件的设计和材料流。另一方面,锥形量热计的结果只受对样品质量有影响的参数的影响。
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引用次数: 0
Upward flame spread over discrete thin solids separated by heat-absorbing inert materials 向上的火焰蔓延在由吸热惰性材料隔开的离散的薄固体上
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-02-10 DOI: 10.1177/07349041231153145
Wohan Cui, Ankit Sharma, Ya-Ting T. Liao
Flame spread over discrete solid fuels has been of key research interest in the past few decades. Most studies considered an array of discrete fuels separated by air gaps or heat-insulating inert materials. The effects of heat loss due to the discrete configuration are not well understood. The present study aims to bridge this knowledge gap. A series of experiments are performed using a vertical array of thin discrete fuels separated by heat-absorbing inert materials of different thicknesses. For comparisons, experiments are also performed using discrete fuels separated by air gaps and using continuous fuel. The flame base spread rate is found to be generally higher in discrete fuel than in continuous fuel configurations, due to a reduced fuel load per unit length. It is also found that the air and inert gaps have opposite effects on the solid burning rates. The air gaps break the no-slip boundary, allowing the laterally entrained buoyancy flow (normal to the sample surface) to push the flame closer to the samples. This leads to an enhanced heat flux on the sample surface and an increased solid burning rate. On the other hand, the inert materials retain the flow boundary profile and act as a heat sink during flame spread, thereby reducing the solid burning rate. As the inert thickness increases, flame spread rate and solid burning rate decrease. Based on these observations, an existing model for flame spread rate is updated by incorporating the heat-absorbing effects of the gaps. The correlation is validated using the experimental data.
在过去的几十年里,离散固体燃料上的火焰传播一直是关键的研究兴趣。大多数研究都考虑了一系列由气隙或隔热惰性材料分离的离散燃料。离散配置引起的热损失的影响尚不清楚。本研究旨在弥合这一知识差距。使用由不同厚度的吸热惰性材料分离的薄离散燃料的垂直阵列进行了一系列实验。为了进行比较,还使用由气隙分离的离散燃料和使用连续燃料进行了实验。由于每单位长度的燃料负载减少,发现离散燃料中的火焰基本传播率通常高于连续燃料配置中的火焰基础传播率。还发现,空气间隙和惰性间隙对固体燃烧速率有相反的影响。气隙打破了无滑动边界,允许横向携带的浮力流(垂直于样品表面)将火焰推向样品。这导致样品表面上的热通量增加,固体燃烧速率增加。另一方面,惰性材料保持流动边界轮廓,并在火焰蔓延期间充当散热器,从而降低固体燃烧速率。随着惰性层厚度的增加,火焰蔓延速率和固体燃烧速率降低。基于这些观察结果,通过结合间隙的吸热效应,对现有的火焰传播率模型进行了更新。使用实验数据验证了相关性。
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引用次数: 1
Old age and fire injury 老年与火伤
IF 1.9 4区 工程技术 Q2 Engineering Pub Date : 2023-02-01 DOI: 10.1177/07349041231153040
M. Taylor, H. Francis, J. Fielding
Previous studies indicated that the elderly are vulnerable to fire injury. In this article, the nature of such vulnerability in terms of fire injury risk factors including age band, gender, occupancy level, deprivation, mobility, alcohol consumption and attempting to fight the fire is examined in a UK Fire and Rescue Service between April 2011 and April 2022. Fire injury risk was more common the greater the age of the elderly individual, more likely for males up to 74, but more likely for females above that age, possibly due to the greater proportion of females to males above age 74 in the area and time period studied. Elderly fire injuries mainly occurred in single occupancy housing and in more deprived areas. Cooking-related fire injuries accounted for 60.2% of elderly fire injuries, followed by smoking-related fire injuries (14.3%) and heating-related fire injuries (7.2%). Fire fatalities were not included in the analysis.
先前的研究表明,老年人容易受到火灾伤害。在这篇文章中,2011年4月至2022年4月期间,英国消防救援局对这种脆弱性在火灾伤害风险因素方面的性质进行了研究,这些因素包括年龄段、性别、入住水平、剥夺、行动能力、饮酒和试图灭火。老年人的年龄越大,火灾伤害风险越普遍,74岁以下的男性更有可能,但该年龄以上的女性更有可能,这可能是因为在所研究的地区和时间段内,74岁以上的女性与男性的比例更大。老年人的火灾伤害主要发生在单人房和贫困地区。与烹饪相关的火灾伤害占老年人火灾伤害的60.2%,其次是与吸烟相关的火灾受伤(14.3%)和与供暖相关的火灾损伤(7.2%)。火灾死亡人数未纳入分析。
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引用次数: 1
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Journal of Fire Sciences
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