Journal of Fluorescence最新文献

In this study, Hummer's method was modified to synthesize graphene oxide (GO). GO-based nanocomposites GO/ZnO, GO/MoO₃, and GO/ZnO/MoO₃ were synthesized using co-precipitation and solid-state reaction methods. The prepared GO and nanocomposites were characterized using UV-Visible spectroscopy, scanning electron microscopy (SEM), Raman spectroscopy, and X-ray diffraction (XRD). SEM images showed distinct morphological differences among GO, GO/ZnO, and GO/MoO₃, while UV-Visible and Raman spectroscopy demonstrated the influence of ZnO and MoO₃ on the optical properties and interactions of GO. Using visible light irradiation, photocatalytic degradation studies showed improved results for the GO/MoO₃ nanocomposites. The 93% degradation of methylene blue (MB) achieved by GO/MoO₃ after 280 minutes was greater than that of GO/ZnO/MoO₃ (92% degradation at 360 minutes) and GO/ZnO (93% degradation at 340 minutes) within the same period. High efficiency photodegradation of methylene blue (MB) under visible light irradiation of GO/MoO₃ nanocomposites were shown by these findings, demonstrating their strong potential for environmental remediation applications.

The present study proposes a new approach for detecting trace amounts of creatinine (Cre) through the utilization of a fluorescence sensor system consisting of nitrogen doped carbon dots (NCDs) and gold ions (Au³⁺). Yellow fluorescent carbon dots were prepared using a one-step hydrothermal method with o-phenylenediamine and isopropanol as raw materials. First, gold ions are reduced to gold nanoparticles (Au NPs), which bind to NCDs, resulting in electron transfer and fluorescence quenching of NCDs. After adding creatinine, Cre and Au NPs were preferentially combined to form non-fluorescent complexes, and the NCDs fluorescence was restored. The study achieved a detection limit of 1.06 × 10^-7 M for Au³⁺ and 9.29 × 10^-9 M for creatinine, indicating a high level of sensitivity. The sensing system has also been successfully utilized for detecting Au³⁺ in lake water and Cre in human urine, indicating its promising potential and practical applications in the areas of environmental monitoring and biosensing.

Materials with long afterglow (LAG) became very renowned in the field of luminescence due to their high ability to store energy. However, the development of LAG phosphors is mostly dependent on rare-earth activators, which are commercially expensive due to their limited availability across the world. On the other hand, LAG phosphors that are not based on rare-earth and are developed as an alternative cannot compete with existing rare-earth LAG phosphors. Copper-doped zinc sulfide (ZnS:Cu) phosphor developed long ago has considerable afterglow, but its development has been too tedious, and expensive, and contains usage of toxic gasses such as H₂S, CS₂, etc. and most of the literature refers to the cubic phase of ZnS. To overcome these issues and simplify the process, we have developed a cost-effective approach to synthesize the hexagonal phase of ZnS, without the involvement of hazardous gases. This is one of the very few reports that highlights the appearance of LAG phenomenon from the hexagonal ZnS:Cu phosphor system. Structural, morphological, and optical studies of the developed ZnS:Cu LAG phosphor have been carried out. The phosphor showed a strong green photoluminescence at 515 nm and an afterglow duration of ~ 1 h useful for specific applications of visual markings in dark conditions. The thermoluminescence spectrum shows a broad and intense glow peak at 377.15 K that indicates the electron trap depth to be at 0.75 eV, supporting our afterglow results.

Synthesis-oriented design led us to the construction of a propeller-like dye, containing the triangle terthiophene and triphenylamine units. It reveals typical photochromic properties with alternated UV (390 nm) and visible light (˃ 440 nm) irradiation and the dye solution (in THF) color was also toggled between yellow-green and colorless. A new absorption band was observed in visible region (415-600 nm). Additionally, the photochromic dye was highly emissive with the absolute quantum yield being 0.27. After UV light irradiation, the emission was quenched significantly (Φ = 0.08) at photo-stationary state, and thus establishing a switchable emission "on-off" system by alternated UV/visible light irradiation cycle. Detailed structural analysis was carried out based on the optimized dye structure. Both the antiparallel conformation and the distance of reactive carbon atoms (< 4.2 Å) led to the smoothly photochromic behavior.

The traditional methods for identifying water sources in coal mines lack the ability to quickly detect water sources and are prone to causing secondary pollution of samples. In contrast, laser induced fluorescence (LIF) technology has been introduced for the identification of coal mine water sources due to its high sensitivity and real-time performance. However, extreme learning machine (ELM) have shortcomings in randomly selecting weights and biases. The Beluga Whale Optimization (BWO) algorithm has efficient optimization capability, global search capability, adaptability and parallelism, and can find the optimal weights and biases in a short time. The combination of LIF technology and BWO-ELM model can be applied to quickly identify the welling water source in coal mine. Select sandstone water and old goaf water from the Huainan mining area as experimental samples, and mix them in different proportions to prepare 7 mixed water samples for testing. Utilize LIF technology to obtain spectral curve images, preprocess them with polynomial smoothing algorithm (SG) and spectral multiple scattering correction (MSC), and perform dimensionality reduction using factor analysis (FA) and linear discriminant analysis (LDA) methods. Finally, construct ELM models, Long Short Term Memory (LSTM) models, BWO-ELM models, and Particle Swarm Optimization Extreme Learning Machine(PSO-ELM) models for the dimensionality reduced data. In order to improve the reliability and accuracy of the results, the experimental results were kept to 5 decimal places. From the experimental results, it can be seen that SG-LDA-BWO-ELM has the best fitting effect, with a fitting coefficient of 0.99990, a root mean square error of 0.00041, a mean square error approaching 0, and an average absolute error of 0.00021. It has the best convergence and the smallest absolute error among all models, making it the most suitable for identifying mine water inrush. It is of great significance for preventing and controlling mine water disasters and ensuring coal mine production safety.

A fluorescent turn-on chemosensor (BA) was constructed by attaching bis(pyridin-2-ylmethyl)-amine (DPA) unit to the BODIPY scaffold. It can give a prominent green/yellow fluorescent response selectivity with each of Zn²⁺/Hg²⁺/Cd²⁺/Ca²⁺/Mn²⁺/Pb²⁺/Al³⁺. The 1:1 stoichiometry of BA and metal ions was drawn from the analysis of Job's plot. The limit detection of BA in recognition of Zn²⁺/Hg²⁺/Cd²⁺/Ca²⁺/Mn²⁺/Pb²⁺/Al³⁺ is ranged in 50.8-146.6 nM. There exists a linear relationship between the fluorescence intensity and concentration of metal ions (Zn²⁺: 4-15 µM). The mechanism of fluorescence signal "turn-on" is based on the photo induced transfer (PET) in the excited state of BA. The coordinated metal ions significantly weakened the electron-donating ability nitrogen atom in DPA, thus recovering the emission character of BODIPY. The substituted group at the phenyl ring in meso-position of BODIPY scaffold determines the recognizable list of metal ions.

In this context, we used the multicomponent Chichibabin pyridine synthesis reaction to synthesize a novel di(thiophen-2-yl) substituted and pyrene-pyridine fluorescent molecular hybrid. The computational (DFT and TD-DFT) and experimental investigations were performed to understand the photophysical properties of the synthesized new structural scaffold. The synthesized ligand displays highly selective fluorescent sensing properties towards Fe³⁺ ions when compared to other competitive metal ions (Al³⁺, Ba²⁺, Ca²⁺, Cd²⁺, Co²⁺, Cr³⁺, Cu²⁺, Fe²⁺, Hg²⁺, Na⁺, Ni²⁺, Pb²⁺, Sr²⁺, Sn²⁺ and Zn²⁺). The photophysical properties studies reveal that the synthesized hybrid molecule has a binding constant of 2.30 × 10³ M^-1 with limit of detection (LOD) of 4.56 × 10^-5 M (absorbance mode) and 5.84 × 10^-5 M (emission mode) for Fe³⁺ ions. We believe that the synthesized pyrene-conjugated hybrid ligand can serve as a potential fluorescent chemosensor for the selective and specific detection of Fe³⁺ ions.

In this study, a novel double-emission fluorescence probe at 340 and 400 nm was synthesized by one-pot method using phenylalanine (Phe) and ascorbic acid (AA) as stabilizing and reducing agents. It was found that the fluorescence intensity of the probe at 400 nm could be controlled by controlling the temperature within a certain range, and the ratio of double-emission fluorescence probe could be further regulated. Under the optimal conditions, the fluorescence intensity at 340 nm decreased significantly, while it only showed a slight decrease at 400 nm, which constituted the ratio fluorescence probe. The synthesized fluorescence probe showed good linearity in the range of 0.2-32 μM, and its detection limit was 63.4 nM. Moreover, the method was successfully employed to determine VA in vanilla drink and perfumes, and corresponding results were consistent with those of HPLC.

The novel TURN-OFF fluorescent sensors 4-(Benzo[1,3]dioxol-5-yloxymethyl)-7-hydroxy-chromen-2-one (4BHC) and 4-(6-Bromo-benzo[1,3]dioxol-5-yloxymethyl)-7-hydroxy-chromen-2-one (4BBHC) are designed and synthesized for the spectrofluorometric detection of the biologically important Fe³⁺ ions, which has sensitive and selective fluorescence quenching over other competitive metal ions. The effectiveness of the sensors and rapid response are validated through UV-Visible, and fluorescence spectral changes. These spectral changes could be due to the formation of coordination bond between ligand and metal ion. The binding stoichiometry of both sensors with Fe³⁺ ions is studied with the help of Job's plot, which gives a 1:2 coordination ratio; this is further confirmed through DFT, IR and NMR studies. The association constants of 4BHC and 4BBHC are calculated through Benesie-Hildebrand plots, and they are found to be 6 × 10⁴ M^-1 and 11.2 × 10⁴ M^-1 respectively. Following, LOD is calculated to define the range of sensitivity of the proposed sensors and is found to be 3.43 μM and 2.14 μM respectively. The chemical hardness parameter suggested that both sensors are soft molecules. In addition, low cytotoxicity levels of 4BHC and 4BBHC led to the demonstration of their efficacy in In-Vitro imaging of Fe³⁺ ions inside living cells, which ensures that these sensors are promising candidates for bioimaging.

Diabetic mellitus management extends beyond blood glucose monitoring to the essential task of mitigating the overexpression of reactive oxygen species (ROS), particularly vital for cellular repair, especially within the nervous system. Herein, antioxidant carbon dots (Arg-CDs) were designed and prepared using anhydrous citric acid, L-arginine, and ethylenediamine as sources through a hydrothermal method. Arg-CDs exhibited excellent scavenging ability to 2,2-Diphenyl-1-picrylhydrazyl (DPPH∙), and fluorescence response to hydroxyl radicals (∙OH), a characteristic representative of reactive oxygen species (ROS). Assisted by glucose oxidase and Fe²⁺, Arg-CDs showed a sensitive and selective response to glucose. The quenching mechanism of Arg-CDs by formed ∙OH was based on the static quenching effect (SQE). The analytical performance of this method for glucose detection encompassed a wide linear range (0.3-15 μM), a low practical limit of detection (0.1 μM) and practical applicability for blood glucose monitoring. In an in vitro model employing glial cells (BV2 cells), it was observed that high glucose medium led to notable cellular damage ascribed to the excessive ROS production from hyperglycemia. The diminished and apoptotic glial cells were gradually recovered by adding increased contents of Arg-CDs. This work illustrates a promising area that designs effective carbon dots with antioxidant capacity for the dual applications of detection and cell repairing based on the utilization of antioxidant activity.