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Late Carboniferous Geomagnetic Field Events Recorded in Post-Collisional Altenberg–Teplice Caldera, Variscan Belt 瓦里斯坎带碰撞后Altenberg-Teplice火山口晚石炭世地磁场事件记录
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-13 DOI: 10.1029/2025jb031983
P. Vitouš, M. S. Petronis, M. S. Foucher, F. Tomek
Characteristic remanent magnetizations isolated from the late Variscan Altenberg–Teplice Caldera exhibit paleomagnetic directions, ranging from those consistent with the expected primary Late Carboniferous geomagnetic field to intermediate directions that significantly diverge from the dipole states. Most of the examined samples of the syn-caldera rhyolite dike swarm, portions of the intra-caldera ignimbrite fill, the outflow ignimbrite, and the syn- to post-caldera ring dike system appear to retain a primary thermoremanent magnetization, as supported by rock-magnetic data. Certain parts of the intra-caldera ignimbrites and younger syn- to post-collapse ring dikes record intermediate directions, which we interpret as unrecognized field behavior intervals during the Late Carboniferous, within the Kiaman Reversed Polarity Superchron. Based on our new paleomagnetic results supported by cross-cutting relationships, we propose the identification of previously unrecognized excursions within the Kiaman Superchron. These events are constrained by geochronology and occurred between approximately 314.7 and 312.6 million years ago during Chron PE5r. This study provides new paleomagnetic evidence that challenges the long-standing assumption of generally reversed polarity over the ∼55-million-year duration of the Kiaman Superchron and offers new insights into the variability of geomagnetic behavior during this interval in Earth's history.
从Variscan晚期Altenberg-Teplice火山口分离出的特征剩磁显示出古地磁方向,从与预期的晚石炭世原始地磁场一致的方向到与偶极子状态显著偏离的中间方向。根据岩石磁性数据,大多数同破火山口流纹岩岩脉群、部分破火山口内的火成岩充填物、流出的火成岩以及同破火山口后的环形岩脉系统的检测样本似乎都保留了初级的热磁化。火山口内火成岩的某些部分和较年轻的同-后崩塌环岩脉记录了中间方向,我们将其解释为在晚石炭世,在Kiaman反极性超时期内未被识别的场行为间隔。基于交叉关系支持的古地磁结果,我们提出了在Kiaman超时线中识别以前未被识别的偏移。这些事件受到地质年代学的限制,发生在大约3.147亿至3.126亿年前的纪年PE5r期间。这项研究提供了新的古地磁证据,挑战了长期以来的假设,即在大约5500万年的基亚曼超时期内,地球的极性普遍逆转,并为地球历史上这段时间内地磁行为的可变性提供了新的见解。
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引用次数: 0
Large-Scale Deformation, Strain Characteristics, and Locking Distribution of the Qilian-Haiyuan Fault System 祁连-海原断裂系统大尺度变形、应变特征及锁紧分布
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-13 DOI: 10.1029/2024jb030647
Donglin Wu, Chunyan Qu, Dezheng Zhao, Han Chen, Yilin Rong, Xiaoyi Wang, Xinjian Shan
The Qilian-Haiyuan fault system is the main tectonic boundary of the northeastern Tibetan Plateau, controlling the regional tectonic deformation and seismic activity. Extensive Sentinel-1 SAR data (2014–2021) are used to map the regional tectonic deformation, strain distribution, and locking along primary and secondary faults. We firstly use SAR images on five ascending and six descending tracks to obtain the large-scale displacement rate fields by InSAR time series analysis. We calculate high-resolution east-west, vertical velocity fields, and horizontal strain rate fields by combining GNSS horizontal velocities. Additionally, we invert kinematic parameters of fault locking based on 2D elastic dislocation models, and explore the spatiotemporal evolution of creep rates on the Laohushan segment and its relationship with nearby earthquakes. We show that there are two spatially separated high-strain zones, one along the Tianzhu Gap and the 1920 Haiyuan earthquake rupture zone, and the other along the North Qilian fault. Creep rate of the eastern Laohushan segment has been decreasing over the past three decades, from ∼10 mm/yr to ≤2 mm/yr. We argue that the creep may be modulated by co- and post-seismic stress perturbations imparted by two ∼ M6 earthquakes in Jingtai in 1990 and 2000.
祁连-海源断裂系是青藏高原东北部的主要构造边界,控制着区域构造变形和地震活动。利用大量Sentinel-1 SAR数据(2014-2021年)绘制了区域构造变形、应变分布和主、次断层锁定图。首先利用5个上升轨道和6个下降轨道的SAR图像,通过InSAR时间序列分析得到大尺度位移率场。结合GNSS水平速度计算高分辨率东西速度场、垂直速度场和水平应变率场。此外,基于二维弹性位错模型反演断层锁定的运动学参数,探讨老虎山段蠕变速率的时空演化及其与附近地震的关系。结果表明,沿天柱断裂带和1920年海原地震断裂带和北祁连断裂带存在两个空间上分离的高应变带。在过去的30年里,老虎山东部的蠕变速率一直在下降,从~ 10 mm/yr下降到≤2 mm/yr。我们认为蠕变可能受到1990年和2000年两次~ M6地震所带来的共震和震后应力扰动的调节。
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引用次数: 0
Archeointensity Database and Geomagnetic Field Reference Curves for South America Over the Past 5 Millennia 过去5000年来南美洲的考古强度数据库和地磁场参考曲线
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-12 DOI: 10.1029/2025jb032478
Victor J. O. Marum, Filipe Terra-Nova, Gelvam A. Hartmann, Erwan Thébault, Plinio Jaqueto, Wilbor Poletti, Ricardo I. F. Trindade
The study of variations in geomagnetic field intensity over time and space is crucial to understand the evolution of the geodynamo and its interactions with the Earth's surface. In this work, we introduce the SAGEOMAG (South America GEOMAGnetic) database, a comprehensive and updated repository of geomagnetic field intensity records derived from archeological artifacts and volcanic materials over the past 5 millennia and adherent to the FAIR (Findable, Accessible, Interoperable and Reusable) principles. A key advantage of the SAGEOMAG database is the inclusion of statistical parameters at the specimen level for data quality control, as well as the data categorization according to the hierarchical level of record (site, fragment or specimen). Additionally, we propose new intensity references curves for South America (SARIC), modeled with a bootstrap algorithm that minimizes the influence of outliers and estimates the probability density function without needing explicit prior shape considerations. For records without intensity errors and age uncertainty details in the original studies, standard errors and uncertainties were assigned based on log-normal distributions. Our findings demonstrate that the modeling of master curves is highly sensitive to the quality filters applied to the data and the hierarchical level of the records. This study aims to improve the organization of geomagnetic data for South America and contribute to regional and global archeomagnetic field modeling, thereby enhancing our understanding of the geomagnetic field evolution and especially the South Atlantic Anomaly (SAA).
研究地磁场强度随时间和空间的变化对于了解地球发电机的演变及其与地球表面的相互作用至关重要。在这项工作中,我们介绍了SAGEOMAG(南美地磁)数据库,这是一个综合的、更新的地磁强度记录库,这些记录来自于过去5000年的考古文物和火山物质,并遵循FAIR(可查找、可访问、可互操作和可重复使用)原则。SAGEOMAG数据库的一个关键优势是包含标本级别的统计参数,用于数据质量控制,以及根据记录的层次级别(地点、片段或标本)对数据进行分类。此外,我们为南美洲(SARIC)提出了新的强度参考曲线,该曲线采用自举算法建模,该算法可以最小化异常值的影响,并在不需要明确的先验形状考虑的情况下估计概率密度函数。对于原始研究中没有强度误差和年龄不确定性细节的记录,根据对数正态分布分配标准误差和不确定性。我们的研究结果表明,主曲线的建模对应用于数据的质量滤波器和记录的层次水平高度敏感。本研究旨在改善南美洲地磁资料的整理,为区域和全球的古磁场模拟做出贡献,从而加深对地磁场演化,特别是南大西洋异常(SAA)的认识。
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引用次数: 0
Seismicity and Detailed Fault Zone Structure Beneath Haicheng Seismic Zone, NE China: Implications for the Fluid-Induced Fault Reactivation 中国海城地震带地震活动性和详细断裂带结构:对流体诱导断层再活化的启示
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-11 DOI: 10.1029/2025jb032942
Dong Yan, You Tian, Cai Liu, Xiaodong Song
The 1975 Ms 7.3 Haicheng earthquake occurred in northwestern Liaodong Peninsula, which was successfully forecasted and marked a landmark achievement in seismology. However, the seismogenic mechanism of this earthquake remains poorly known. In this study, we obtain high-precision earthquake catalog and 3-D models of crustal P- and S-wave velocities (Vp, Vs) and their ratio (Vp/Vs) in the Haicheng seismic zone (HSZ) from an unprecedentedly dense seismic array that we recently deployed. Our results show the seismicity pattern in the HSZ is predominantly controlled by an interconnected conjugate fault system, comprising the WNW-striking Haichenghe fault and its NE-striking concealed secondary fault. Furthermore, a prominent fluid-rich zone characterized by low Vp, low Vs and high Vp/Vs ratio is clearly revealed in the middle crust at ∼15 km depth, directly beneath the hypocentral region of the 1975 Haicheng earthquake. A distinct seismic cluster is also observed adjacent to the main shock hypocenter, exhibiting spatial correlation with the underlying crustal fluid reservoir. This geometric correspondence indicates a fluid-driven triggering mechanism that contributes to the localized seismicity. We deem that the reactivation of preexisting seismogenic faults induced by crustal fluid migration could be a possible mechanism for the nucleation of such a large intraplate earthquake.
1975年辽东半岛西北部发生的海城7.3级地震预报成功,是地震学上具有里程碑意义的重大成就。然而,这次地震的发震机制仍然知之甚少。本文在海城地震带(HSZ)进行了高精度地震目录和地壳纵、横波速度(Vp, Vs)及其比值(Vp/Vs)的三维模型。结果表明,高新区地震活动模式主要受一个相互连接的共轭断裂系统控制,该系统由西北西向的海城河断裂及其北东向的隐伏次级断裂组成。此外,在1975年海城地震震源正下方~ 15 km深度的中地壳中,清晰地显示出一条以低Vp、低Vs和高Vp/Vs为特征的富流体带。在主震源附近还观察到一个明显的地震群,显示出与下伏地壳流体储层的空间相关性。这种几何对应表明流体驱动的触发机制有助于局部地震活动性。我们认为,由地壳流体迁移引起的原有发震断裂的重新激活可能是这种大板内地震成核的可能机制。
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引用次数: 0
The Significance of Magnetic Fabrics Preserved in Hydrothermally Altered Rocks 热液蚀变岩中磁组构保存的意义
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-10 DOI: 10.1029/2025jb033102
Ben Latimer, William McCarthy, Tobias Mattsson, John Reavy
Anisotropy of Magnetic Susceptibility (AMS) and Anisotropy of Magnetic Remanence (AMR) are critical petrofabric tools for investigating the evolution of volcano-magmatic, tectonic, and surface process systems. These highly sensitive techniques can distinguish multiple magnetic fabrics within individual samples, crucial in assessing archives of emplacement and deformation in granitic intrusions where magmatic and tectonic processes occur concurrently or successively. However, mineral phases that dominate AMS and AMR signals are highly susceptible to hydrothermal alteration that may overprint pre-existing petrofabrics. Despite this, the mechanisms and extent to which hydrothermal alteration modifies magnetic fabrics remain poorly understood, raising concerns about the reliability of interpretations in studies involving hydrothermally altered rocks. This study assesses the significance of magnetic fabrics preserved in a hydrothermally altered fault zone that crosscuts a granitic pluton. Data are collected from unaltered granodiorite peripheral to the fault, the fault damage zone and the fault core to assess the impact of hydrothermal alteration on magnetic fabrics associated with magmatic and tectonic processes. Our integrated magnetic and hyperspectral approach to characterizing alteration type and intensity, combined with measurement of AMS and AMR fabrics, reveal a distinctive magnetic fabric associated with hydrothermal alteration that overprints earlier magmatic and tectonic fabrics. While composite magnetic fabrics are well documented in igneous systems, fabrics that directly record hydrothermal alteration imparting a systematic, measured fabric is incredibly rare and this paves the way for further work on the tracing of fluid flow in fault zones using rock magnetic fabrics as a paleoflow indicator.
磁化率各向异性(AMS)和剩磁各向异性(AMR)是研究火山-岩浆、构造和地表过程系统演化的重要岩石组构工具。这些高度敏感的技术可以区分单个样品中的多种磁性结构,对于评估岩浆和构造过程同时或先后发生的花岗岩侵入体的侵位和变形档案至关重要。然而,主导AMS和AMR信号的矿物相非常容易受到热液蚀变的影响,这些蚀变可能会覆盖先前存在的岩石组构。尽管如此,热液蚀变改变磁性结构的机制和程度仍然知之甚少,这引起了人们对热液蚀变岩石研究中解释的可靠性的担忧。本研究评估了在横切花岗岩岩体的热液蚀变断裂带中保存的磁性织物的意义。通过对断裂外围未蚀变的花岗闪长岩、断裂损伤带和断裂核的数据采集,评价了热液蚀变对岩浆和构造过程相关磁组构的影响。综合磁谱和高光谱方法表征蚀变类型和强度,结合AMS和AMR组构的测量,揭示了与热液蚀变相关的独特磁组构,覆盖了早期的岩浆和构造组构。虽然复合磁组构在火成岩系统中有很好的记录,但直接记录热液蚀变的组构却非常罕见,这为进一步利用岩石磁组构作为古流动指示物来追踪断裂带流体流动铺平了道路。
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引用次数: 0
Climate-Induced Length of Day Variations Since the Late Pliocene 晚上新世以来气候引起的日长变化
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-10 DOI: 10.1029/2025jb032161
Mostafa Kiani Shahvandi, Benedikt Soja
Understanding the history of Earth rotation variations and its connection to mantle dynamics is one of the most important problems is global geophysics. However, our knowledge of these variations—in particular those induced by climate on geological timescales—is limited due to both modeling deficiencies and the scarcity of paleoclimate data. In order to advance our understanding of this problem, here we first develop a new probabilistic deep learning methodology called Physics-Informed Diffusion Model (PIDM). We then use PIDM in conjunction with the recently available paleoclimate data—specifically, sea level variations since the Late Pliocene—to precisely reconstruct the history of climate-induced changes in the Earth's rotation rate (i.e., Length of Day variations: <span data-altimg="/cms/asset/e74e8899-d1be-4d45-893f-a3b47d40740b/jgrb70212-math-0001.png"></span><mjx-container ctxtmenu_counter="10" ctxtmenu_oldtabindex="1" jax="CHTML" role="application" sre-explorer- style="font-size: 103%; position: relative;" tabindex="0"><mjx-math aria-hidden="true" location="graphic/jgrb70212-math-0001.png"><mjx-semantics><mjx-mrow><mjx-mi data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic- data-semantic-role="greekletter" data-semantic-speech="normal upper Delta" data-semantic-type="identifier"><mjx-c></mjx-c></mjx-mi></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display="inline" unselectable="on"><math altimg="urn:x-wiley:21699313:media:jgrb70212:jgrb70212-math-0001" display="inline" location="graphic/jgrb70212-math-0001.png" xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi data-semantic-="" data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic-role="greekletter" data-semantic-speech="normal upper Delta" data-semantic-type="identifier" mathvariant="normal">Δ</mi></mrow>${Delta }$</annotation></semantics></math></mjx-assistive-mml></mjx-container>LOD). We reconcile <span data-altimg="/cms/asset/39c68a83-966a-4bc0-b38b-cf199fe860d6/jgrb70212-math-0002.png"></span><mjx-container ctxtmenu_counter="11" ctxtmenu_oldtabindex="1" jax="CHTML" role="application" sre-explorer- style="font-size: 103%; position: relative;" tabindex="0"><mjx-math aria-hidden="true" location="graphic/jgrb70212-math-0002.png"><mjx-semantics><mjx-mrow><mjx-mi data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic- data-semantic-role="greekletter" data-semantic-speech="normal upper Delta" data-semantic-type="identifier"><mjx-c></mjx-c></mjx-mi></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display="inline" unselectable="on"><math altimg="urn:x-wiley:21699313:media:jgrb70212:jgrb70212-math-0002" display="inline" location="graphic/jgrb70212-math-0002.png" xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mi data-semantic-="" data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic-role="greekletter" data-semantic-spe
了解地球自转变化的历史及其与地幔动力学的联系是全球地球物理学最重要的问题之一。然而,由于建模的缺陷和古气候数据的缺乏,我们对这些变化的认识——特别是那些由地质时间尺度上的气候引起的变化——是有限的。为了促进我们对这个问题的理解,我们首先开发了一种新的概率深度学习方法,称为物理信息扩散模型(PIDM)。然后,我们将PIDM与最近可获得的古气候数据(特别是自晚上新世以来的海平面变化)结合起来,精确地重建气候引起的地球自转速率变化的历史(即,日长变化:Δ${Delta}$LOD)。我们调和了Δ${Delta}$LOD从各种气候模式和古气候代用物(即地质记录,如底栖有孔虫化石和珊瑚礁)推断出来的。基于我们对Δ${Delta}$LOD的重建,我们揭示了(a)第四纪冰期造成的大幅度波动,其幅度超过了目前已知的过程,包括大气、陆地水文和地核的过程;(b)北半球冰盖开始引起的地球扁圆度变化导致的以前未被认识到的长期趋势;(c) 21世纪气候变化造成的几乎前所未有的白昼长度增加速度。
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引用次数: 0
Blueschist Dislocation Creep and Glide in Subduction Systems: Constraints From Glaucophane Experiments 俯冲系统中的蓝片岩位错蠕变和滑动:来自蓝片实验的约束
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-09 DOI: 10.1029/2025jb033622
Lonnie J. Hufford, Leif Tokle, Whitney M. Behr, Luiz F. G. Morales, Claudio Madonna
Blueschists are a defining component of subducting oceanic crust and influence slab and interface rheology across thermal regimes. Glaucophane, the dominant sodic amphibole in blueschist, is a key rheology-controlling phase, yet its dislocation-based strength is poorly constrained. We conducted load-stepping experiments in a Griggs apparatus at 600–700<span data-altimg="/cms/asset/29c4d2e5-c12b-49d0-be57-f8cb73f05b6b/jgrb70249-math-0001.png"></span><mjx-container ctxtmenu_counter="65" ctxtmenu_oldtabindex="1" jax="CHTML" role="application" sre-explorer- style="font-size: 103%; position: relative;" tabindex="0"><mjx-math aria-hidden="true" location="graphic/jgrb70249-math-0001.png"><mjx-semantics><mjx-mrow><mjx-mo data-semantic- data-semantic-role="degree" data-semantic-speech="degree" data-semantic-type="punctuation"><mjx-c></mjx-c></mjx-mo></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display="inline" unselectable="on"><math altimg="urn:x-wiley:21699313:media:jgrb70249:jgrb70249-math-0001" display="inline" location="graphic/jgrb70249-math-0001.png" xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><mo data-mjx-pseudoscript="true" data-semantic-="" data-semantic-role="degree" data-semantic-speech="degree" data-semantic-type="punctuation">°</mo></mrow>${}^{circ}$</annotation></semantics></math></mjx-assistive-mml></mjx-container>C and 1.0 GPa over shear strain rates from ∼<span data-altimg="/cms/asset/f064364c-9ce5-4da4-a9a5-b433251dd2a6/jgrb70249-math-0002.png"></span><mjx-container ctxtmenu_counter="66" ctxtmenu_oldtabindex="1" jax="CHTML" role="application" sre-explorer- style="font-size: 103%; position: relative;" tabindex="0"><mjx-math aria-hidden="true" location="graphic/jgrb70249-math-0002.png"><mjx-semantics><mjx-mrow data-semantic-children="0,16" data-semantic-content="1" data-semantic- data-semantic-role="unknown" data-semantic-speech="1.2 times 1 0 Superscript negative 8 Baseline normal s Superscript negative 1" data-semantic-type="infixop"><mjx-mn data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic- data-semantic-parent="17" data-semantic-role="float" data-semantic-type="number"><mjx-c></mjx-c><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mn><mjx-mo data-semantic- data-semantic-operator="infixop,×" data-semantic-parent="17" data-semantic-role="unknown" data-semantic-type="operator" rspace="4" space="4"><mjx-c></mjx-c></mjx-mo><mjx-mrow data-semantic-annotation="clearspeak:unit" data-semantic-children="2,7,13" data-semantic-content="14,15" data-semantic- data-semantic-parent="17" data-semantic-role="implicit" data-semantic-type="infixop"><mjx-mn data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic- data-semantic-parent="16" data-semantic-role="integer" data-semantic-type="number"><mjx-c></mjx-c></mjx-mn><mjx-mo data-semantic-added="true" data-semantic- data-semantic-operator="infixop,⁢" data-semantic-parent="16" data-semantic-role="multiplication" data-seman
蓝片岩是俯冲洋壳的重要组成部分,影响着板块和界面的热流变。蓝片岩中占主导地位的钠质角闪孔蓝片岩是一个关键的流变控制相,但其位错强度约束较差。我们在格里格斯设备上进行了负载步进实验,温度为600-700°${}^{circ}$C和1.0 GPa,剪切应变率从~ 1.2×1¹¹¹¹¹¹¹¹¹¹¹¹³³³³,{mathrm{s}}³³³,{mathrm{s}}³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³³。力学数据显示,应力指数从2.8到3.2在相对较低的应力(位错蠕变)到13-19在高应力(位错滑动)。不溶溶消光、亚晶发育和再结晶晶粒证实了位错活动。我们推导流法为位错蠕变n = 3, Q = 450±下午15美元焦每摩尔,一个= 2.32×1010 $ {10}^ {10}$ MPa−n ${文本{MPa}} ^ {n} $ s−1 $ { mathrm{年代}}^{1}= 1⁢和位错滑移美元038.02美元1{0}^{38.02}$,σp ${σ}_ {p} $ = 22 GPa, H = 800焦每摩尔,p = 1, Q = 2。对地质条件的外推表明,位错滑动在稳态俯冲界面条件下不会发生,而可能只与瞬态高应力扰动有关。在450°C以上的温度下,位错蠕变占主导地位,晶粒尺寸为~ 1mm或更大。与已发表的石英/沉积和榴辉岩流动规律的比较表明,蓝片岩强度介于这些端元之间,这意味着蓝片岩强度对镁质主导(无沉积物)边缘的长期界面强度有重要贡献。综上所述,这些结果完善了蓝片岩受控的流变学及其对俯冲带力学的影响。
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引用次数: 0
Effect of Dislocations on Polycrystal Anelasticity Inferred From In Situ Forced Oscillation Test 从原位强迫振荡试验推断位错对多晶非弹性的影响
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-09 DOI: 10.1029/2025jb032220
Kosuke Yabe, Yasuko Takei, Riku Sugimoto
To understand the effect of dislocations on the velocity and attenuation of seismic waves, the anelasticity of polycrystalline samples was measured in situ during dislocation creep. We used polycrystalline borneol as a rock analog. Because the effects of grain boundary mechanism on the anelastic properties of this material are well known, dislocation effect can be detected as a deviation from them. We developed a new experimental apparatus and conducted the forced oscillation tests continuously on the sample deforming under various creep stresses ranging from diffusion to dislocation creep regimes. The testing frequency was mostly fixed at 5 Hz, but was sometimes scanned from 16 to 0.5 Hz. When the creep stress was higher than 2 MPa, the dominant deformation mechanism changed from grain boundary diffusion creep to dislocation creep. However, modulus reduction was not observed, indicating that dislocations significantly affected creep, but did not affect anelasticity. The different effects of dislocations on creep and anelasticity were explained in terms of the viscous resistance to dislocation motion.
为了了解位错对地震波速度和衰减的影响,在原位测量了多晶样品在位错蠕变过程中的非弹性。我们用多晶冰片作为岩石模拟物。由于晶界机制对材料非弹性性能的影响是众所周知的,位错效应可以被检测为偏离它们。研制了一种新的实验装置,对试样在扩散蠕变和位错蠕变等不同应力状态下的变形进行了连续的强迫振荡试验。测试频率大多固定在5hz,但有时扫描范围为16 ~ 0.5 Hz。当蠕变应力大于2 MPa时,主要变形机制由晶界扩散蠕变转变为位错蠕变。然而,没有观察到模量降低,这表明位错显著影响蠕变,但不影响非弹性。从位错运动的粘性阻力角度解释了位错对蠕变和非弹性的不同影响。
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引用次数: 0
Influence of polyvinyl chloride contaminant on chemical recycling of polyethylene via thermal and catalytic pyrolysis 聚氯乙烯污染物对热裂解和催化热解聚乙烯化学回收的影响
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-07 DOI: 10.1002/aic.70332
Chaoran Zhang, Zhixiang Li, Yan Cheng, Wenjie Wang, Zhongyao Zhang, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
Polyethylene (PE) is the most abundant component of plastic waste. Its chemical recycling primarily relies on pyrolysis, which produces pyrolysis oils that can be catalytically upgraded into light olefins. In practice, PE is often recycled alongside polyvinyl chloride (PVC) contaminants, which are difficult to completely separate given their use in multilayer materials. Upon heating, PVC readily releases acidic hydrogen chloride, which can negatively impact chemical recycling. However, most studies have focused on the chemical recycling of pure PE, with limited attention to the effects of PVC contamination. Here, by employing a pyrolyzer–gas chromatography–mass spectrometry/ flame ionization detector/thermal conductivity detector system, we reveal that PVC contamination significantly increases char formation at the expense of pyrolysis oils—the precursors for monomer recovery. Furthermore, rapid deactivation of the ZSM-5 catalyst is observed, attributed to acidity loss caused by framework aluminum leaching. These deleterious effects are effectively mitigated through an ionic liquid–based dehydrochlorination pretreatment of feedstock, the kinetic model of which is developed.
聚乙烯(PE)是塑料垃圾中含量最多的成分。它的化学回收主要依赖于热解,热解产生的油可以催化升级为轻质烯烃。在实践中,PE通常与聚氯乙烯(PVC)污染物一起回收,由于它们在多层材料中的使用,很难完全分离。加热后,PVC容易释放出酸性氯化氢,这会对化学回收产生负面影响。然而,大多数研究都集中在纯PE的化学回收上,对PVC污染的影响关注有限。在这里,通过使用热解-气相色谱-质谱/火焰电离检测器/导热检测器系统,我们发现PVC污染显著增加了炭的形成,以牺牲热解油(单体回收的前体)为代价。此外,观察到ZSM-5催化剂的快速失活,归因于框架铝浸出引起的酸度损失。通过离子液体对原料进行脱氢氯化预处理,有效地减轻了这些有害影响,并建立了其动力学模型。
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引用次数: 0
Observations of Tidal Induced Responses in Self-Potential Data in a UK Beach Sand Aquifer: Implications for Monitoring Seawater Intrusion 英国海滩砂含水层自电位资料中潮汐诱导响应的观测:监测海水入侵的意义
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-07 DOI: 10.1029/2025jb033414
T. S. L. Rowan, A. P. Butler, M. C. McDonnell, J. F. Águila, R. Flynn, G. A. Hamill, S. Donohue, M. D. Jackson
Affordable and effective early warning of saline intrusion into aquifers is a key challenge affecting coastal water supplies. This paper reports on self-potential (SP) monitoring close to a mobile saline-fresh water interface over a 3-month period. SP, groundwater level, temperature and fluid electrical conductivity (FEC) were monitored in 12 boreholes, distributed over a variety of depths and distances to the high-water mark (HWM). Power Spectral Density (PSD) analysis of SP data showed a clear semi-diurnal (principal-lunar, M2) tidal component, with an amplitude of around 1 mV. The M2 magnitude linearly decreased with depth and distance from the shore. Whilst PSD analysis showed M2 components in borehole water levels, none were detected in groundwater temperature and FEC. The results suggest that SP M2 components were generated remote from the boreholes by the movement of a saline interface, most likely associated with the upper saline plume. Superimposed on these tidal signals were periodic rises and falls in mean SP of around 5–10 mV. These responses appear linked to storm surge events, during which seawater advanced beyond the monitoring boreholes, although data interpretation is complex due to salinity changes at the reference electrode. The results provide further support for the use of SP as a precursor to saline intrusion. Critically, they provide the first quantitative spatial characterization of tidal SP responses, demonstrating that the M2 signal magnitude can be predicted from electrode depth and shoreline distance (R2 = 0.96) and suggest the possibility of using multi-point SP monitoring to remotely track saline plume movement.
对咸水侵入含水层进行经济有效的早期预警是影响沿海供水的一项关键挑战。本文报道了近3个月的盐-淡水流动界面自电位监测。在12个井眼中监测SP、地下水位、温度和流体电导率(FEC),这些井眼分布在不同深度和距离的高水位标志(HWM)处。SP数据的功率谱密度(PSD)分析显示有明显的半日(主月,M2)潮汐分量,振幅约为1 mV。M2震级随深度和离岸距离线性减小。虽然PSD分析显示了钻孔水位中的M2成分,但地下水温度和FEC中没有检测到M2成分。结果表明,SP M2组分是在远离井眼的地方由盐水界面的运动产生的,很可能与上部盐水羽流有关。叠加在这些潮汐信号上的是平均SP的周期性上升和下降,大约在5-10毫伏之间。这些反应似乎与风暴潮事件有关,在此期间,海水超出了监测钻孔,尽管由于参考电极的盐度变化,数据解释很复杂。该结果进一步支持了SP作为盐水侵入的前驱体的使用。重要的是,他们首次提供了潮汐SP响应的定量空间表征,表明M2信号量级可以通过电极深度和海岸线距离预测(R2 = 0.96),并提出了使用多点SP监测远程跟踪盐羽运动的可能性。
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引用次数: 0
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Journal of Geophysical Research: Solid Earth
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