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Quantifying Vein Network Permeability in Dehydrated Serpentinites Using Thermodynamics and Generative AI 利用热力学和生成式人工智能量化脱水蛇纹岩脉网渗透率
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-11 DOI: 10.1029/2025JB032776
Austin Arias, Lisa Eberhard, Andreas Beinlich, Timm John, Alissa Kotowski, Oliver Plümper

Fluids released from subducting hydrated rocks influence volcanism, tectonics, and geochemical cycling, but the mechanisms of fluid escape in subduction zones remain poorly understood. We address this issue by investigating the Erro-Tobbio meta-serpentinites (ET-MS), Italy, exhumed serpentinite rocks that preserve extensive dehydration vein networks formed by the porosity-generating breakdown of antigorite and brucite. We characterized the structure and morphology of these self-organized vein networks and evaluated their hydrodynamic properties using a novel approach. Specifically, we combined X-ray tomography and drone imagery with generative machine learning, electron microscopy, and equilibrium thermodynamics to model and analyze fluid pathways in the ET-MS. In both natural and simulated samples, these dehydration vein networks act as efficient drainage systems, enabling rapid fluid percolation even at porosities below 1%. The maximum network permeability is 1015m2 ${approx} 1{0}^{-15}{,mathrm{m}}^{2}$, several orders of magnitude higher than that of intact serpentinite. Fe-rich olivine and monticellite occur alongside relict brucite and magnetite in these veins. This assemblage indicates that the high permeability arises from porosity localized along brucite- and magnetite-rich veins, where infiltration of reducing fluids enhanced dehydration reactions. These findings demonstrate that serpentinite dehydration in subduction zones can produce flow-optimized vein structures that efficiently channel fluids at low porosity, potentially influencing fluid migration on local to regional scales before widespread dehydration occurs.

从俯冲含水岩石中释放的流体影响火山作用、构造和地球化学循环,但对俯冲带中流体逸出的机制仍知之甚少。我们通过研究意大利的Erro-Tobbio变质蛇纹岩(ET-MS)来解决这个问题,挖掘出的蛇纹岩岩石保存了由反长花岗岩和水辉石的孔隙生成分解形成的广泛脱水脉网。我们描述了这些自组织静脉网络的结构和形态,并使用一种新的方法评估了它们的水动力特性。具体来说,我们将x射线断层扫描和无人机图像与生成式机器学习、电子显微镜和平衡热力学相结合,对ET-MS中的流体路径进行建模和分析。在自然和模拟样品中,这些脱水静脉网络作为有效的排水系统,即使在孔隙度低于1%的情况下,也能实现流体的快速渗透。最大网络渗透率为≈1¹0−15¹m2${approx} 1{0}^{-15}{,mathrm{m}}^{2}$,比完整蛇纹岩高几个数量级。富铁橄榄石和蒙长石与残留的水辉石和磁铁矿共存。这一组合表明,高渗透率来源于富水镁石和磁铁矿脉体沿线的孔隙,其中还原性流体的渗透增强了脱水反应。这些发现表明,俯冲带的蛇纹岩脱水可以产生流动优化的脉状结构,有效地引导低孔隙度的流体,在广泛脱水发生之前,可能会影响局部到区域尺度的流体运移。
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引用次数: 0
2D Broadband Magnetotelluric Study of the Axial Fault Region of the New Madrid Seismic Zone 新马德里地震带轴向断裂带二维宽带大地电磁研究
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-09 DOI: 10.1029/2024JB030583
Kaushik Sarker, Chris Cramer

This study investigates whether seismicity in the New Madrid Seismic Zone (NMSZ), specifically the Axial Fault, is predominantly influenced by fluids or fault locking. Previous resistivity studies in the region were restricted by their focus, MT station spacing, and equipment bandwidth, which limited the resolution of resistivity structures near fault zones. We conducted a comprehensive investigation using broadband magnetotelluric (MT) soundings from December 2021 to March 2023. Data were collected along five profiles spanning frequencies from 0.00005 to 10,000 Hz. Four shallow-focus profiles were located near Steele and Caruthersville in the Missouri Bootheel region, while a deeper cross-section extended from Obion, TN to Wardell, MO, reaching a depth of 80 km and crossing the Reelfoot Rift's Axial Fault. Our findings indicate that earthquakes cluster within a highly resistive zone (1,000–10,000 Ω-m), suggesting a fault-locking mechanism in the brittle zone because they coincide with low velocity anomalies from previous studies. The profiles usually have a conductive anomaly on the SE side of the fault at a depth of 2–30 km. That conductive anomaly may be interpreted as a weaker, more ductile zone adjacent to the stronger brittle zone associated with the fault. These results suggest that both fault locking and fluid presence significantly influence NMSZ seismicity, with their effects varying by depth and location.

本研究探讨了新马德里地震带(NMSZ)的地震活动性,特别是轴向断层,是否主要受到流体或断层锁定的影响。以往在该地区开展的电阻率研究受限于研究重点、台站间距和设备带宽等因素,限制了断裂带附近电阻率结构的分辨率。从2021年12月至2023年3月,我们利用宽带大地电磁(MT)测深进行了全面调查。数据沿着五个剖面收集,频率从0.00005到10,000 Hz。四个浅焦点剖面位于密苏里州Bootheel地区的Steele和Caruthersville附近,而更深的剖面从田纳西州的Obion延伸到密苏里州的Wardell,达到80公里的深度,并穿过Reelfoot裂谷的轴向断层。我们的研究结果表明,地震集中在一个高阻带内(1000 - 10000 Ω-m),这表明脆性带存在断层锁定机制,因为它们与先前研究中的低速异常相吻合。这些剖面通常在断层东南侧2 ~ 30 km深度处有导电异常。该导电异常可以解释为与断层相关的较强脆性带相邻的较弱、较韧性带。这些结果表明,断层锁定和流体存在对NMSZ地震活动都有显著影响,其影响随深度和位置的不同而不同。
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引用次数: 0
Crustal Structure of Laurentia and Peri-Gondwanan Terranes Beneath Ireland and Britain and Comparison With Eastern North America 爱尔兰和不列颠之下劳伦西亚和近冈瓦南地体的地壳结构及其与北美东部的比较
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-09 DOI: 10.1029/2025JB031184
Roberto Masis, Paul Karabinos, Maureen D. Long, John W. F. Waldron, James Bourke

The Appalachian-Caledonian orogen was built during the Paleozoic by accretion of peri-Gondwanan terranes onto Laurentia, culminating in the formation of Pangea. During the Mesozoic, Pangea broke apart, displacing one section of the belt to eastern North America and another to northwestern Europe. These areas share aspects of their tectonic history but have been shaped differently by later Paleozoic orogenesis and Mesozoic rifting; therefore, comparisons between these regions offer an opportunity to understand which processes have been responsible for shaping their present-day crustal structure. This study compares the crustal structure across the Laurentian and peri-Gondwanan sutures in these regions and explores how it has been shaped by their tectonic histories. We use receiver functions with harmonic decomposition to analyze the geometry of Laurentia, Ganderian and Avalonian crust beneath Ireland and Britain and compare them with New England, northeastern USA. The Laurentian crustal thickness beneath Ireland and Britain ranges from ∼26 to 32 km, whereas that of the peri-Gondwanan terranes varies from ∼32 to 38 km. Our analysis also provides insight into dipping interfaces and anisotropy near the Moho, which vary considerably across the study area. In contrast to our findings in Ireland and Britain, beneath New England Laurentian crust is significantly thicker (∼44 km) than accreted terrane crust (∼32 km). We hypothesize that Mesozoic rifting led to significant thinning of Laurentian crust beneath Ireland and Britain, and that regionally specific orogenic processes during the middle and late Paleozoic controlled the evolution of accreted terrane crust differently in these areas.

阿巴拉契亚-加里东造山带是在古生代由冈瓦南附近的地体向劳伦西亚的增生而形成的,最终形成了泛大陆。在中生代,盘古大陆分裂了,把带的一部分移到了北美东部,另一部分移到了欧洲西北部。这些地区具有相同的构造历史,但受到晚古生代造山作用和中生代裂陷作用的不同影响;因此,对这些区域的比较提供了一个机会,让我们了解是哪些过程形成了它们今天的地壳结构。这项研究比较了这些地区的劳伦森缝合线和冈瓦南缝合线的地壳结构,并探讨了它们的构造历史是如何塑造它的。我们用接收函数和谐波分解分析了爱尔兰和英国地下的Laurentia、Ganderian和Avalonian地壳的几何形状,并与美国东北部的新英格兰地区进行了比较。爱尔兰和不列颠之下的劳伦特地壳厚度介于~ 26至32公里之间,而冈瓦南附近的地壳厚度介于~ 32至38公里之间。我们的分析还提供了对莫霍附近倾斜界面和各向异性的深入了解,这些界面和各向异性在研究区域内变化很大。与我们在爱尔兰和英国的发现相反,在新英格兰之下,劳伦地壳(~ 44公里)明显比增生的地壳(~ 32公里)厚。我们认为,中生代裂谷作用导致了爱尔兰和不列颠地区劳伦地壳的显著减薄,而中晚古生代的区域造山作用对这些地区的增生地壳的演化具有不同的控制作用。
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引用次数: 0
Thermal and Compositional Characterization of the Greater Alpine Crust Using Seismic Observables 利用地震观测资料研究大阿尔卑斯地壳的热成分特征
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-09 DOI: 10.1029/2025JB033617
Henrique Berger Roisenberg, Lapo Boschi, Fabio Cammarano

The Greater Alpine crust provides a natural laboratory for investigating tectonic and geodynamic processes owing to its strong structural and lithological heterogeneity. A key challenge is constraining its thermal and compositional properties, given the limited direct observations and the uncertainties of existing models. We analyze two years of seismic ambient noise recorded at about 700 broadband seismic stations, and eight years of teleseismic earthquakes recorded at approximately 400 broadband stations. Using ambient noise tomography and receiver functions, we derive the Vs of the crust, the average Vp/Vs ratio, and a new Moho depth map for the Greater Alpine region. Moho depths range from 15 to 55 km, and Vp/Vs ratios vary from <1.65 in the Variscan domain to >1.8 in the Apennines, Dinarides and sedimentary basins. Thermodynamic modeling translates these seismic results into quantitative estimates of silica content and linear thermal gradients. We find that the Variscan crust is relatively cold (<20°C/km) and silica-rich (>62 wt% SiO2 $Si{O}_{2}$), in contrast with Alpine–Apenninic domains that show elevated thermal gradients (>25°C/km) and more mafic compositions (<60 wt% SiO2 $Si{O}_{2}$). However, elastic velocities predicted by mineral physics systematically exceed observed seismic velocities, reflecting effects of sediments, porosity, anelastic relaxation, and non-equilibrium processes not captured in thermodynamic equilibrium models. We apply empirical corrections to address these discrepancies, emphasizing caution when interpreting seismic velocities from mineral physics models. These quantitative constraints refine the thermal and chemical distinction between stable Paleozoic lithosphere and actively deforming orogens in the Greater Alpine crust.

由于其强烈的构造和岩性非均质性,大阿尔卑斯地壳为研究构造和地球动力学过程提供了一个天然的实验室。考虑到有限的直接观测和现有模型的不确定性,一个关键的挑战是限制其热性质和组成性质。我们分析了大约700个宽带地震台站记录的两年的地震环境噪声,以及大约400个宽带台站记录的8年的远震地震。利用环境噪声层析成像和接收函数,我们得到了地壳的v值,平均Vp/Vs比,以及大阿尔卑斯地区新的莫霍深度图。莫霍盆地深度为15 ~ 55 km, Vp/Vs比值从Variscan域的1.65到亚平宁、Dinarides和沉积盆地的1.8不等。热力学建模将这些地震结果转化为硅含量和线性热梯度的定量估计。我们发现Variscan地壳相对寒冷(<20°C/km),并且硅含量丰富(>62 wt% S²i²O2$Si{O}_{2}$),而阿尔卑斯-亚宁地区则表现出较高的热梯度(>25°C/km)和更多的基性成分(<60 wt% S²i²O2$Si{O}_{2}$)。然而,矿物物理学预测的弹性速度系统地超过了观测到的地震速度,反映了沉积物、孔隙度、非弹性松弛和热力学平衡模型中未捕获的非平衡过程的影响。我们应用经验修正来解决这些差异,强调在解释矿物物理模型的地震速度时要谨慎。这些定量限制细化了大阿尔卑斯地壳中稳定的古生代岩石圈和活跃变形造山带之间的热化学区别。
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引用次数: 0
Testing Volcano Deformation Models Against 3D Seismic Reflection Imagery of Ancient Intrusions 基于古侵入体三维地震反射图像的火山变形模型测试
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-05 DOI: 10.1029/2025JB032007
C. Magee, S. K. Ebmeier, J. Hickey

Magma intrusion often drives uplift of the overburden and free surface. Analytical modeling of such surface uplift at active volcanoes allows us to estimate intrusion geometries and positions, as well as volume and pressure changes; these insights have proven critical to forecasting volcanic unrest and eruptions. However, it is rarely possible to compare geodetic source parameters retrieved from analytical models to known intrusion geometries. Seismic reflection data offer an opportunity to image and quantify ancient, buried intrusion geometries and their overburden deformation (i.e., a forced fold). Here, we use 3D seismic reflection data offshore NW Australia to investigate an Early Cretaceous forced fold developed above a laccolith emplaced at ∼0.6–1 km depth. We remove the effects of post-emplacement, burial-related compaction and estimate surface displacement patterns for the forced fold. Analytical modeling of these surface displacements, using both thin plate bending and elastic half-space solutions, suggest source (intrusion) estimates of position and lateral dimensions are similar to those of the actual laccolith. There are some differences between measurements of the laccolith and modeled source estimates, which we attribute to syn-intrusion space-making mechanisms (e.g., compaction). We particularly find penny shaped crack and rectangular dislocation elastic half-space solutions underestimate source emplacement depth by ∼0.2–0.9 km, probably reflecting a lack of heterogeneity (layering) in our models. Our novel approach highlights seismic reflection data is a powerful tool for understanding and testing how magma emplacement translates into surface deformation at active volcanoes.

岩浆侵入常引起上覆岩和自由地表的隆升。对活火山地表隆起的分析建模使我们能够估计侵入的几何形状和位置,以及体积和压力的变化;事实证明,这些洞见对于预测火山动荡和喷发至关重要。然而,很少有可能将从分析模型中检索到的大地测量源参数与已知的入侵几何形状进行比较。地震反射数据提供了成像和量化古老的、埋藏的侵入体几何形状及其上覆层变形(即强迫褶皱)的机会。在这里,我们使用澳大利亚西北部近海的三维地震反射数据来研究早白垩世在0.6-1 km深的湖纹岩上发育的强迫褶皱。我们消除了安置后的影响,埋葬相关的压实和估计地表位移模式的强迫褶皱。使用薄板弯曲和弹性半空间解对这些表面位移进行分析建模,表明源(侵入)的位置和横向尺寸估计与实际的缓蚀石相似。缓蚀石的测量值与模型源估计值之间存在一些差异,我们将其归因于同步入侵空间形成机制(例如压实)。我们特别发现便士形裂缝和矩形位错弹性半空间解低估了震源就位深度约0.2-0.9 km,这可能反映了我们模型中缺乏非均质性(分层)。我们的新方法强调地震反射数据是理解和测试岩浆侵位如何转化为活火山表面变形的有力工具。
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引用次数: 0
Sound Velocities and Structural Transitions of Endmember and Fe, Al, Mg, Ti-Bearing CaSiO3 Glasses Up to 23 GPa 高达23 GPa的端元和含Fe, Al, Mg, ti的CaSiO3玻璃的声速和结构转变
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-05 DOI: 10.1029/2025JB032766
Wenhao Su, Wen-Yi Zhou, Jiasen Hu, Ming Hao, Anne Pommier, Jin S. Zhang

The study of silicate glasses is important to understand the physical and chemical properties of silicate melts under high-pressure conditions relevant to planetary interiors. We conducted in situ Brillouin spectroscopy measurements on two endmember, low-impurity CaSiO3 glasses and one Fe, Al, Mg, Ti-bearing CaSiO3 glass up to 23 GPa. We obtained pressure-dependent acoustic velocities and derived elastic moduli that exhibit discontinuities indicative of structural transitions in all compositions. The endmember CaSiO3 glasses exhibit velocity softening below 2.6 GPa, consistent with earlier findings in other silicate glasses, while the Fe, Al, Mg, Ti-bearing CaSiO3 glass displays a delayed onset of softening and densification. This softening is attributed to intermediate-range structural rearrangements. Above ∼8 GPa, both glasses show rapid increases in velocities and elastic moduli, reflecting densification associated with structural transitions. Comparison with other silicate glasses demonstrates that Ca acts as a strong network modifier, significantly reducing the stiffness of the glasses, while the addition of Fe, Al, Mg, and Ti collectively has a mixed effect on elasticity. CaSiO3 glass crosses over in density with its counterpart crystal, wollastonite, at only ∼3 GPa—a pressure lower than any other crossover pressure observed in silicate glasses—suggesting that Ca-rich melts may become gravitationally stable at much shallower depths in planetary interiors than other silicate melts. These results provide new constraints on the structural evolution and elasticity of Ca-rich silicate glasses under compression and have implications for modeling the mobility of silicate melts in deep planetary environments.

硅酸盐玻璃的研究对于了解与行星内部有关的高压条件下硅酸盐熔体的物理和化学性质具有重要意义。我们对两个端元低杂质CaSiO3玻璃和一个含Fe, Al, Mg, ti的CaSiO3玻璃进行了高达23 GPa的原位布里渊光谱测量。我们获得了与压力相关的声速,并推导出弹性模量,这些模量在所有成分中都表现出指示结构转变的不连续。端元CaSiO3玻璃表现出低于2.6 GPa的速度软化,与之前在其他硅酸盐玻璃中的发现一致,而含Fe, Al, Mg, ti的CaSiO3玻璃表现出延迟的软化和致密化。这种软化归因于中期的结构重排。在~ 8gpa以上,两种玻璃都表现出速度和弹性模量的快速增加,反映了与结构转变相关的致密化。与其他硅酸盐玻璃的对比表明,Ca作为一种强网络改性剂,显著降低了玻璃的刚度,而Fe、Al、Mg和Ti的共同加入对玻璃的弹性有混合作用。CaSiO3玻璃在密度上与它的对偶晶体硅灰石交叉,只有~ 3gpa——比在硅酸盐玻璃中观察到的任何其他交叉压力都要低——这表明富钙熔体在行星内部较浅的深度可能比其他硅酸盐熔体变得重力稳定。这些结果为富钙硅酸盐玻璃在压缩条件下的结构演化和弹性提供了新的约束条件,并对模拟行星深部环境中硅酸盐熔体的迁移性具有重要意义。
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引用次数: 0
Impact of Fluid-Induced Pore Geometry Alteration on Acoustic Velocity in Carbonate Rocks 流体诱导的孔隙几何变化对碳酸盐岩声速的影响
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-05 DOI: 10.1029/2025JB031854
Ralf J. Weger, Peter K. Swart, Gregor P. Eberli

We performed laboratory experiments to study the effects of fluid-induced precipitation and dissolution on pore space geometry and corresponding acoustic velocity in carbonate rocks. This approach separates the impact of pore structure changes from other factors like compaction and tracks only variations in acoustic velocity alongside changes in porosity resulting from calcium carbonate cementation and dissolution. In the precipitation experiments, the degree of velocity variation is strongly influenced by the specific location of cementation. Grain-contact cementation strengthens the rock framework, which results in a marked increase in acoustic velocity, while the growth of intrapore aragonite crystals usually produce more intricate, softer frameworks that have a minimal effect on velocity yet generally cause a slight reduction. Dissolution predominantly eliminates non-load-bearing small particles, which leads to increased porosity yet results in only a marginal decrease in acoustic velocity. The dissolution creates bigger void spaces in the rock without increasing its structural complexity while maintaining its inherent strength. Using the parameters of internal pore geometry, including dominant pore size and perimeter-over-area ratio, we demonstrate that pore geometry has a greater influence on elastic properties and acoustic velocity than porosity by itself. These results question standard porosity-velocity models while demonstrating the need for quantitative pore geometry parameters in rock physics models that analyze seismic reflection data. Without integrating pore geometry parameters, seismic data analysis risks underestimating porosity in dissolution areas or incorrectly classifying grain-contact cementation as lithological changes.

通过室内实验研究了流体诱导沉淀和溶蚀对碳酸盐岩孔隙空间几何形状和相应声速的影响。这种方法将孔隙结构变化的影响与压实等其他因素分离开来,只跟踪声速变化以及碳酸钙胶结和溶解导致的孔隙度变化。在降水实验中,胶结的具体位置对速度变化的程度有很大影响。颗粒接触胶结强化了岩石骨架,这导致声速显著增加,而孔内文石晶体的生长通常会产生更复杂、更柔软的骨架,这对声速的影响很小,但通常会引起轻微的降低。溶解主要消除了非承重小颗粒,导致孔隙度增加,但声波速度仅略有下降。溶解在岩石中产生更大的空隙,而不会增加其结构复杂性,同时保持其固有强度。利用孔隙内部几何参数,包括优势孔径和周长面积比,我们证明了孔隙几何对弹性性能和声速的影响大于孔隙率本身。这些结果对标准孔隙-速度模型提出了质疑,同时证明了在分析地震反射数据的岩石物理模型中需要定量孔隙几何参数。如果不整合孔隙几何参数,地震数据分析可能会低估溶蚀区的孔隙度,或者错误地将颗粒接触胶结作用归类为岩性变化。
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引用次数: 0
Stress Barriers and Their Impact on Rupture Propagation 应力障碍及其对破裂扩展的影响
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-05 DOI: 10.1029/2025JB032879
F. Paglialunga, J. P. Ampuero, F. Passelègue

Earthquake ruptures often exhibit complex behaviors, including abrupt arrest followed by delayed re-nucleation. While on-fault stress heterogeneity is a recognized contributing factor, as it can arrest or slow down rupture propagation, its interaction with propagating ruptures remains complex and not fully understood. Here, we study frictional ruptures under controlled laboratory conditions by imposing a heterogeneous stress field along an artificial fault. This setup consistently led to the spontaneous emergence of a well-defined stress barrier. Our results show that the presence and strength of the stress barrier systematically influence rupture propagation, sometimes in non-trivial ways. As expected, strong barriers tend to arrest ruptures, while weaker ones reduce their velocity, inducing a time delay in the rupture propagation. However, we also observe several less-intuitive outcomes, including static triggering, barrier-induced supershear transition, and dynamic triggering. We elucidate the physics behind each interaction mechanism through Linear Elastic Fracture Mechanics (for the arrest and deceleration mechanisms) and the Rate-and-State framework (for the static triggering). Interestingly, static triggering and barrier-induced supershear transitions can enable rupture propagation beyond barriers that are expected to arrest ruptures. Similarly, dynamic triggering can accelerate the onset of rupture beyond barriers that decelerate ruptures. Moreover, our experiments show that the barrier efficiency evolves over successive earthquake cycles, weakening with repeated partial ruptures and becoming permanent once complete ruptures break through the fault. This experimental study underscores the critical role of stress heterogeneity in controlling the dynamics of frictional ruptures and offers new insights into the physics of delayed rupture triggering.

地震破裂通常表现出复杂的行为,包括突然停止,随后延迟再成核。虽然断层应力非均质性是公认的促成因素,因为它可以阻止或减缓破裂的传播,但它与传播破裂的相互作用仍然很复杂,尚未完全了解。在这里,我们通过沿人工断层施加非均匀应力场,在受控的实验室条件下研究摩擦破裂。这种设置总是导致一个明确的压力屏障的自发出现。我们的研究结果表明,应力屏障的存在和强度系统地影响破裂的传播,有时以非平凡的方式。正如预期的那样,强大的屏障往往会阻止破裂,而较弱的屏障会降低破裂的速度,从而导致破裂传播的时间延迟。然而,我们也观察到一些不太直观的结果,包括静态触发、屏障诱导的超剪切转变和动态触发。我们通过线性弹性断裂力学(用于停止和减速机制)和速率-状态框架(用于静态触发)阐明了每种相互作用机制背后的物理原理。有趣的是,静态触发和屏障诱导的超剪切转变可以使破裂扩展超出预期的阻止破裂的屏障。同样,动态触发可以加速破裂的发生,超越减速破裂的屏障。此外,我们的实验表明,屏障效率在连续的地震周期中不断演变,随着重复的部分破裂而减弱,一旦完全破裂突破断层,屏障效率就会变得永久。该实验研究强调了应力非均匀性在控制摩擦破裂动力学中的关键作用,并为延迟破裂触发的物理学提供了新的见解。
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引用次数: 0
Reconstructing Late Pleistocene to Prehistorical Holocene Geomagnetic Field Variations From La Palma Lava Flows (Canary Islands, Spain): Unraveling Viscous Components 从西班牙加那利群岛拉帕尔马熔岩流重建晚更新世至史前全新世地磁场变化:解开粘性成分
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-05 DOI: 10.1029/2025JB032659
Eva Vernet, Manuel Calvo-Rathert, Ángel Carrancho, Yuhji Yamamoto, Lidia Rodríguez-Méndez, Josep M. Parés, Vicente Soler

We present new vector paleomagnetic data from 13 radiometrically dated lava-flows in southern La Palma (Canary Islands) spanning from 1 to 56 ka, which covers most of the Late Pleistocene to prehistoric Holocene volcanic record in the island. Using a paleointensity multimethod approach including Thellier-type and Shaw-type techniques, and combining detailed rock magnetic and mineralogical analyses, we assess the reliability and possible biases in paleointensity estimations in volcanic rocks affected by low-temperature oxidation and coarse ferromagnetic grains. Results indicate a strong viscous component linked to maghemitization, which compromises paleointensity reliability and accuracy. Low temperature demagnetization pretreatments significantly mitigated the viscosity contribution, improving success rates by highlighting the original thermoremanent magnetization (TRM) and revealing possible overestimations in standard Thellier-type treated samples affected by maghemitization. The full vector results, compared with several paleosecular variation curves, exhibited both low and high field intensity periods, including a relative paleointensity minimum at ∼27 ka (VADM ∼26 ZAm2) and the record of the Levant intensity high (VADM ∼108 ZAm2). This study contributes with valuable constraints for improving geomagnetic models, especially for low-latitude regions, and underscores the importance of integrating magnetic mineralogy with paleointensity protocols to mitigate bias in geomagnetic reconstructions.

本文报道了加那利群岛拉帕尔马南部13个熔岩流的新向量古地磁数据,时间跨度为1 ~ 56 ka,涵盖了该岛晚更新世至史前全新世的大部分火山记录。采用包括thellier型和shaw型技术在内的古强度多方法方法,结合详细的岩石磁学和矿物学分析,评估了低温氧化和粗铁磁颗粒影响下火山岩古强度估计的可靠性和可能存在的偏差。结果表明,与岩浆作用有关的强粘性成分影响了古强度的可靠性和准确性。低温退磁预处理显著降低了粘度的贡献,通过突出原始热磁化(TRM)和揭示受磁化影响的标准thlier型处理样品可能的高估,提高了成功率。与多个古长期变化曲线相比,全矢量结果显示出低场强周期和高场强周期,包括相对古强度最小值(VADM ~ 26 ZAm2)在~ 27 ka和高场强记录(VADM ~ 108 ZAm2)。该研究为改进地磁模型,特别是低纬度地区的地磁模型提供了有价值的约束,并强调了将磁矿物学与古强度协议结合起来以减轻地磁重建中的偏差的重要性。
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引用次数: 0
Quantifying Regime Transition of Mineral Precipitation in a Microfluidic Fracture 微流控裂隙中矿物沉淀的状态转换量化
IF 4.1 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-02-05 DOI: 10.1029/2025JB031915
Xu-Sheng Chen, Ran Hu, Chen-Xing Zhou, Qiu-Rong Jiang, Zhibing Yang, Yi-Feng Chen

Mineral precipitation is ubiquitous in subsurface environments, influencing processes such as karst evolution and carbon mineralization. While precipitation dynamics have been extensively studied in porous media, the pattern formation and transitions in fractured media remain underexplored. In this study, we develop a novel experimental system to investigate precipitation dynamics in microfluidic fractures by integrating charge-coupled device camera, micro-PIV, and confocal microscopy. Flow-through experiments on CaCO3 precipitation are performed by co-injecting Na2CO3 and CaCl2 under controlled flow rates Pe and saturation indices SI. Real-time imaging of precipitation dynamics and velocity fields revealed two distinct patterns. At low Pe and low SI, mineral precipitation exhibits precipitation band acting as a barrier that inhibits mixing of the reactants and results in minimal permeability reduction. In contrast, at high Pe and high SI, the system transitions to precipitation clusters, characterized by widespread particle distribution that significantly reduces permeability. We demonstrate that this pattern shift is governed by the balance between fluid shear forces and repulsive forces between CaCO3 particles. When repulsive forces dominate, particles cannot aggregate, leading to band formation, whereas shear-induced aggregation promotes cluster growth. Theoretical analysis is developed to interpret the regime transition, and a phase diagram mapping precipitation regime as a function of Pe and SI shows well agreement with experimental results. These findings provide critical insights into fracture mineral precipitation, which are crucial for predicting injectivity and permeability in CO2 mineralization processes.

矿物降水在地下环境中普遍存在,影响岩溶演化和碳矿化等过程。虽然多孔介质中的降水动力学已经得到了广泛的研究,但裂缝介质中模式的形成和转变仍未得到充分的探索。在这项研究中,我们开发了一种新的实验系统,通过集成电荷耦合器件相机,微型piv和共聚焦显微镜来研究微流体裂缝中的沉淀动力学。在控制流速Pe和饱和指数SI的条件下,通过共注入Na2CO3和CaCl2进行CaCO3沉淀的流动实验。降水动力学和速度场的实时成像显示了两种不同的模式。在低Pe和低SI条件下,矿物沉淀表现为沉淀带,作为抑制反应物混合的屏障,导致最小的渗透率降低。相反,在高Pe和高SI下,体系转变为降水团簇,其特征是颗粒分布广泛,显著降低了渗透率。我们证明了这种模式的转变是由CaCO3颗粒之间的流体剪切力和排斥力之间的平衡所控制的。当斥力占主导地位时,粒子不能聚集,导致带状形成,而剪切诱导的聚集促进簇生长。建立了理论分析来解释体系转变,并绘制了Pe和SI随沉淀体系变化的相图,与实验结果吻合较好。这些发现为裂缝矿物沉淀提供了重要的见解,这对于预测CO2矿化过程的注入性和渗透率至关重要。
{"title":"Quantifying Regime Transition of Mineral Precipitation in a Microfluidic Fracture","authors":"Xu-Sheng Chen,&nbsp;Ran Hu,&nbsp;Chen-Xing Zhou,&nbsp;Qiu-Rong Jiang,&nbsp;Zhibing Yang,&nbsp;Yi-Feng Chen","doi":"10.1029/2025JB031915","DOIUrl":"10.1029/2025JB031915","url":null,"abstract":"<p>Mineral precipitation is ubiquitous in subsurface environments, influencing processes such as karst evolution and carbon mineralization. While precipitation dynamics have been extensively studied in porous media, the pattern formation and transitions in fractured media remain underexplored. In this study, we develop a novel experimental system to investigate precipitation dynamics in microfluidic fractures by integrating charge-coupled device camera, micro-PIV, and confocal microscopy. Flow-through experiments on CaCO<sub>3</sub> precipitation are performed by co-injecting Na<sub>2</sub>CO<sub>3</sub> and CaCl<sub>2</sub> under controlled flow rates <i>Pe</i> and saturation indices SI. Real-time imaging of precipitation dynamics and velocity fields revealed two distinct patterns. At low <i>Pe</i> and low SI, mineral precipitation exhibits precipitation band acting as a barrier that inhibits mixing of the reactants and results in minimal permeability reduction. In contrast, at high <i>Pe</i> and high SI, the system transitions to precipitation clusters, characterized by widespread particle distribution that significantly reduces permeability. We demonstrate that this pattern shift is governed by the balance between fluid shear forces and repulsive forces between CaCO<sub>3</sub> particles. When repulsive forces dominate, particles cannot aggregate, leading to band formation, whereas shear-induced aggregation promotes cluster growth. Theoretical analysis is developed to interpret the regime transition, and a phase diagram mapping precipitation regime as a function of <i>Pe</i> and SI shows well agreement with experimental results. These findings provide critical insights into fracture mineral precipitation, which are crucial for predicting injectivity and permeability in CO<sub>2</sub> mineralization processes.</p>","PeriodicalId":15864,"journal":{"name":"Journal of Geophysical Research: Solid Earth","volume":"131 2","pages":""},"PeriodicalIF":4.1,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146129275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Geophysical Research: Solid Earth
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