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Дослідження та аналіз способів ремонту насосних штанг
Pub Date : 2021-05-18 DOI: 10.31471/1993-9973-2021-1(78)-43-50
Б. В. Копей, О. І. Стефанишин, О. Р. Мартинець, А. Б. Стефанишин
На даний час питання підвищення надійності та довговічності нафтогазового обладнання набули особливої актуальності. Колона насосних штанг (КНШ) є однією із найслабших ланок штангових свердловинних насосних установок (ШСНУ). Саме насосні штанги різко обмежують їх надійність і довговічність. Це пов’язано із надзвичайно важкими умовами роботи насосних штанг. Змінні навантаження розтягу та згину, вплив корозійно-активного середовища, тертя до колони насосно-компресорних труб (особливо в похилоспрямованих свердловинах), відкладення асфальто-смоляно-парафінових речовин та інші експлуатаційні фактори призводять до появи та інтенсивного розвитку корозійно-втомних тріщин і, як наслідок, до руйнування колони штанг. Такі аварії пов’язані з великими матеріальними затратами на ремонт і відновлення експлуатації свердловин. Близько 70% нафтових свердловин в Україні експлуатується штанговими свердловинними насосними установками (ШСНУ). Однією з основних проблем, пов'язаних з експлуатацією обладнаних ШСНУ свердловин, є частий вихід з ладу насосних штанг (НШ). Проведений аналіз  існуючих способів ремонту насосних штанг дасть можливість визначити ефективний метод їх ремонту. Запропоновано комбінований метод ремонту штанг обробкою металевими щітками та нанесенням модифікованого поліуретанового покриття. Проведені експерименти відрізків натурних штанг показують, що металеві щітки є ефективним засобом очищення і зміцнення штанг, особливо тих, які вже були в експлуатації. Встановлено, що метод комбінованого зміцнення обробкою щітками та нанесенням поліуретанового покриття додатково підвищує величину G-критерію на 20%. Модифіковане поліуретанове покриття дасть змогу підвищити стійкість штанги до стирання при терті до колони насосно-компресорних труб, з однієї сторони, та попередити відкладання асфальто-смоляно-парафінових речовин на тілі штанг, з іншої.
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引用次数: 0
Increasing the degree of hydrocarbon recovery factor from the water-flooded Hadiach oil and gas condensate field by injection of carbon dioxide 通过注入二氧化碳提高水淹Hadiach凝析油气田的油气采收率
Pub Date : 2021-03-29 DOI: 10.31471/1993-9973-2021-1(78)-17-24
S. Matkivskyi, O. Kondrat, O. Burachok, L. I. Haidarova
To investigate the effectiveness of technologies for the secondary production of hydrocarbons by injecting non-hydrocarbon gases into productive reservoirs, a study has been carried out using the Schlumberger’s prime hydrodynamic simulation tools –Eclipse and Petrel. On the basis of a live geological and technological model of the Hadiach oil and gas condensate field, an investigation has been made of the process of injecting carbon dioxide into the reservoir of the V-16 horizon in order to slow down the flow of formation water into gas-saturated intervals and displace residual natural gas reserves. Based on the results of modeling the development of the V-16 horizon of the Hadiach oil and gas condensate field, a high technological efficiency of carbon dioxide injection at the gas-water contact boundary has been established. When injecting carbon dioxide, the formation pressure in the reservoir is maintained at a higher level compared to depletion development, which leads to an increase in condensate production. The high solubility of carbon dioxide in formation fluids increases the mobility of condensate that has already fallen out in the formation, and at the same time reduces the mobility of formation water. Due to the high displacing properties of carbon dioxide, a high efficiency of its use as an injection agent is manifested in order to control the flow of formation water into productive reservoirs and increase the final hydrocarbon recovery factor. The expected gas recovery factor at the time of the breakthrough of carbon dioxide into the last of the producing wells increases by 3,22 % in terms of residual gas reserves, while the condensate recovery factor increases by 1,29 %. The practical implementation of systems for optimizing the development of hydrocarbon fields under such conditions will increase their production capabilities and, accordingly, increase the final coefficients of hydrocarbon recovery factor.
为了研究将非碳氢气体注入生产油藏的二次开采技术的有效性,使用斯伦贝谢的主要流体动力学模拟工具eclipse和Petrel进行了一项研究。在Hadiach凝析油气田现场地质技术模型的基础上,研究了V-16层向储层注入二氧化碳以减缓地层水向含气层段流动、驱替剩余天然气储量的过程。通过对Hadiach凝析油田V-16层发育过程的模拟,建立了气水接触界面注二氧化碳的高技术效率。当注入二氧化碳时,与衰竭开发相比,储层中的地层压力保持在较高水平,从而导致凝析油产量增加。二氧化碳在地层流体中的高溶解度增加了地层中已经析出的凝析油的流动性,同时降低了地层水的流动性。由于二氧化碳的高驱油特性,其作为注入剂的使用效率很高,可以控制地层水流入生产油藏,提高最终的油气采收率。当二氧化碳进入最后一口生产井时,剩余气储量的预期采收率增加了3.22%,而凝析油采收率增加了1.29%。在这种条件下,油田优化开发系统的实际实施将提高油田的生产能力,从而提高最终的油气采收率系数。
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引用次数: 0
Polymer dispersed system for in-situ fluid diversion 聚合物分散体系用于原位流体分流
Pub Date : 2021-03-29 DOI: 10.31471/1993-9973-2021-1(78)-61-72
Elchin F. Veliyev
High initial heterogeneity coefficient of reservoir coupled by a long period of exploitation, leads to a decrease in the effectiveness of most  EOR methods based on the displacing agents injection and  significantly increase economic costs. So, for example, in fields where the main oil recovery mechanism is waterflooding appearance of high-permeability channels is inevitable. Therefore this phenomenon negatively affects oil recovery factor, the displacement front uniformity and the injectivity profile. One of the most successful technologies to overcome these complications is the in-situ fluid diversion techniques based on creation of gel banks deep in the formation. The article presents a polymer-dispersed system (PDS) for deep flow diversion using on modified bentonite particles. Initially, bentonite particles were intercalated with precursor molecules, then copolymers of N-isopropylacrylamide (NIPAM) and acrylic acid (AA) were grafted onto the hydrophilic surface of bentonite particles by a graft polymerization reaction. The paper presents the study results of the physicochemical properties, rheology and colloid stability. The residual resistance factor has also been studied on sandpacks and core samples from the Azeri-Chirag-Guneshli field. The results of experiments shows increased hydraulic resistance while injection of PDS due to a sharp decrease in permeability. Core studies confirmed obtained results, showing a 61% decrease in permeability accompanied by an 11% increase in oil recovery. It was concluded that proposed composition is effective as deedp divertion agent and can increase oil recovery.
由于储层初始非均质系数高,再加上开发周期长,导致大多数注驱替剂提高采收率方法的有效性降低,经济成本显著增加。因此,以水驱为主要采油机制的油田为例,高渗透通道的出现是不可避免的。因此,这种现象对采收率、驱替前缘均匀性和注入剖面都有负面影响。克服这些复杂问题最成功的技术之一是基于在地层深处形成凝胶库的原位流体导流技术。本文介绍了一种改性膨润土颗粒聚合物分散体系(PDS)。首先在膨润土颗粒上嵌入前驱体分子,然后通过接枝聚合反应将n -异丙基丙烯酰胺(NIPAM)和丙烯酸(AA)的共聚物接枝到膨润土颗粒的亲水性表面。介绍了其理化性质、流变性和胶体稳定性的研究结果。对Azeri-Chirag-Guneshli油田砂包和岩心样品的残余电阻系数进行了研究。实验结果表明,注入PDS后,由于渗透率急剧下降,水力阻力增大。岩心研究证实了上述结果,渗透率降低了61%,但采收率提高了11%。结果表明,该组合物作为深层导流剂是有效的,可以提高采收率。
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引用次数: 0
Applying spectral decomposition for identifying lithological objects within Northern edge of Dnieper-Donets Depression 应用光谱分解识别第聂伯-顿涅茨凹陷北缘岩性目标
Pub Date : 2021-03-29 DOI: 10.31471/1993-9973-2021-1(78)-35-42
І. L. Mykhalevych
The article dwells upon the effective method of seismic data analysis called spectral decomposition. This method has been used worldwide for identifying additional geological features, as a tool for seismic geomorphology in the conditions of complicated geological structures during identification of paleochannels, lenses, and thin formations. It should be noted that spectral decomposition is not a direct tool for identifying the hydrocarbon saturation. It allows to represent the seismic data in the RGB format (red, green, blue) by way of decomposing seismic data into frequency elements. Authors demonstrate results of applying the seismic data spectral decomposition method within the terrigenous deposits on the example of gas fields in the Carbon age within the northern edge of Dnieper-Donets Depression.  Based on the results of the available seismic material analysis, it has been shown that within thick and porous sand bodies, spectral decomposition demonstrates reasonable results, and the most informative frequencies are 25, 28, 31, 37, 39, 47, 56 Hz. By confirming the really existing deposits in the Moskovian and Bashkirian ages, spectral decomposition gives grounds for considering this method an effective tool to be used within the northern edge of the DDD, because the latter usually clearly responds to lithology, and sometimes even to saturation. The 8 most representative horizons have been analyzed: М-2а, М-3а, М-4, М-6, М-7, B-6 (at different stratigraphic levels), B-7 and S-6. The most definite results have been received within the following horizons: M-2a (the deposit has been confirmed by drilling), M-3a (the deposit and paleochannel have been confirmed by drilling), M-4 (paleochannel). Having regarded the spectral decomposition in complex with the results of other geophysical methods, some perspective objects have been identified. The bodies have been confirmed by the results of AVO and Vp/Vs analyses. Both objects served the targets for two prospecting wells located in the most optimal conditions. It has been brightly illustrated that the spectral decompositions as a tool for geological prospecting  should be specifically used when some individual lenses and channel bodies are being prospected, with structural factor being present.
论述了一种有效的地震资料分析方法——谱分解。该方法已在世界范围内用于识别额外的地质特征,作为在复杂地质构造条件下识别古河道、透镜体和薄地层的地震地貌学工具。应该指出的是,光谱分解并不是识别烃饱和度的直接工具。通过将地震数据分解为频率元素,它允许以RGB格式(红、绿、蓝)表示地震数据。以第聂伯-顿涅茨凹陷北缘碳时代气田为例,介绍了地震资料谱分解方法在陆源沉积中的应用结果。根据已有的地震资料分析结果表明,在厚、多孔砂体中,谱分解结果合理,信息量最大的频率为25、28、31、37、39、47、56 Hz。通过确认莫斯科和巴什基里安时代真正存在的矿床,光谱分解使我们有理由认为这种方法是在DDD北部边缘使用的有效工具,因为后者通常对岩性有明显的反应,有时甚至对饱和度有反应。分析了8个最具代表性的层位:М-2а、М-3а、М-4、М-6、М-7、B-6(不同地层)、B-7和S-6。在M-2a层(矿床已通过钻井确认)、M-3a层(矿床和古河道已通过钻井确认)、M-4层(古河道)得到了最明确的结果。将光谱分解与其他地球物理方法的结果相结合,识别出一些透视目标。AVO和Vp/Vs分析结果证实了这些体的存在。两个目标均为位于最优条件下的两口探井服务。说明在有构造因素的个别透镜体和水道体找矿时,应特别采用光谱分解作为地质找矿工具。
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引用次数: 0
The research of the gas wells bottomhole formation zone treatment efficiency 气井井底地层层处理效率研究
Pub Date : 2021-03-29 DOI: 10.31471/1993-9973-2021-1(78)-51-60
N. Hedzyk, L. I. Haidarova
The final stage of development of natural gas fields is characterized by depletion of reservoir energy, deterioration of the bottomhole formation zone, which leads to low gas and condensate flow rates. Development of new and improvement of existing technologies for stimulation of oil and gas production for the conditions of Ukrainian fields should be carried out taking into account the fact that most fields are in the final stage of development; production wells are mainly marginal, water-flooded and are characterized by a significant decrease in the natural filtration properties of the bottomhole formation zone due to its colmatage with filtrates and dispersed particles used in drilling, well operation or workover, deposits of resins, asphaltens, paraffins, forming of high viscosity emulsions, swelling of the clay particles of the formation present in the reservoir, and the presence of other clogging agents. The well, its bottomhole zone and the formation part between the wells are interconnected and interacting elements of a single system. Failure to take into account the features and degree of impact of the bottomhole formation zone as one of the system’s elements leads to a general decrease in the development efficacy of the field as a whole. Therefore, the choice of technologies for the impact on the bottomhole formation zone requires a very careful assessment, taking into account the technological efficiency and payout time. The aim of the research is to determine the influence of the bottomhole formation treatment parameters on the well productivity. The tasks have been performed by analyzing the literature and conducting analytical calculations of the impact of various parameters of the treatment zone on the flow rate of the well. The described methods and results of calculations can be implemented in production when planning the action on the bottomhole formation zone by selecting the optimal treatment parameters at different stages of field development.
气田开发后期以储层能量枯竭、井底地层带恶化为特征,导致气、凝析油流速降低。在为乌克兰油田的情况开发新的和改进现有的提高石油和天然气产量的技术时,应考虑到大多数油田已处于开发的最后阶段;生产井主要是边缘井,水淹井,其特点是井底地层的自然过滤性能显著下降,这是由于钻井、井作业或修井过程中使用的滤液和分散颗粒的混合,树脂、沥青、石蜡的沉积,高粘度乳剂的形成,储层中地层粘土颗粒的膨胀以及其他堵塞剂的存在。井、井底区和井之间的地层部分是一个相互联系和相互作用的系统。由于未能将井底地层带的特征和影响程度作为系统要素之一加以考虑,导致整个油田的开发效率普遍下降。因此,在选择对井底地层产生影响的技术时,需要非常仔细地评估,同时考虑到技术效率和支出时间。研究的目的是确定井底地层处理参数对油井产能的影响。通过分析文献,并对处理区各参数对井流量的影响进行分析计算,完成了任务。通过在油田开发的不同阶段选择最优的处理参数,可以将上述方法和计算结果应用于生产中。
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引用次数: 0
Improving the efficiency of additional development of depleted gas reservoirs by displacing the residual gas with nitrogen 用氮气置换残余气,提高衰竭气藏追加开发效率
Pub Date : 2021-03-29 DOI: 10.31471/1993-9973-2021-1(78)-25-34
R. Kondrat, L. I. Haidarova
Based on the analysis of publications in domestic and foreign scientific and technical publications, the directions of increasing gas recovery from depleted gas reservoirs, which include the displacement of residual gas from the porous medium with nitrogen, are substantiated. Nitrogen can be obtained from the air in any oil and gas producing area using membrane, adsorption or cryogenic types of plants produced by the industry. The final gas recovery factor can be adjusted by choosing certain values ​​of technological parameters that characterize the process of reservoir development. Using hypothetical digital models, the influence on the total final gas recovery factor and the residual gas recovery factor of the pressure of the beginning of nitrogen injection into the reservoir, the rate, duration and cyclicity of its injection, the system for locating production and injection wells on the gas-bearing area and the technological modes of their operation was investigated. The results of the studies are shown in the form of graphical dependencies of the final gas recovery factor and the gas recovery factor for residual gas on the investigated determining parameters. Using the research results, the optimal values ​​of the parameters of the nitrogen injection process into a depleted gas reservoir of square and round shapes and the corresponding values ​​of the gas recovery coefficient have been established. The results of the studies performed indicate a significant technological efficiency of the displacement of residual gas by nitrogen from depleted gas reservoirs. Depending on the system of placement of production and injection wells in the gas-bearing area and the technological parameters of the nitrogen injection process into the reservoir, the gas recovery factor for the residual gas varies on average within the range of 53,97 – 61,82 %.
通过对国内外科技文献的分析,确定了衰竭气藏提高采收率的方向,包括利用氮气驱替多孔介质中的残余气。氮气可以从任何石油和天然气产区的空气中获得,使用膜,吸附或工业生产的低温类型的植物。最终的采收率可以通过选择一定的表征储层开发过程的技术参数值来调整。利用假设数字模型,研究了注氮起始压力、注氮速率、注氮持续时间、注氮循环度、产注井定位系统对含气区最终总采收率和剩余气采收率的影响及其操作技术模式。研究结果以图形形式显示了最终气采系数和残余气采系数与所研究的决定参数的依赖关系。利用研究结果,建立了方形和圆形枯竭气藏注氮工艺参数的最优值及相应的采收率系数值。研究结果表明,利用氮气驱替枯竭气藏残余气具有显著的技术效率。根据产注气井在含气区的布置方式和注氮工艺参数的不同,剩余气的采收率平均在53.97 ~ 61.82 %之间变化。
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引用次数: 0
Forecasting parameters of hydrocarbon systems for gas deposits of the Outer zone of Precarpathian Foredeep 不稳定巴阡前深外带气藏烃类系统预测参数
Pub Date : 2021-03-29 DOI: 10.31471/1993-9973-2021-1(78)-7-16
S. Kurovets, Е. О. Chornyi
Здійснено регіональне прогнозування пластових вуглеводневих систем для газових родовищ Зовнішньої зони Передкарпатського прогину. Установлено залежності поширення різних типів вуглеводневих систем, що уможливлює їх прогнозування на великих глибинах в області високих температур і тисків на початкових стадіях пошукових робіт. За результатами проведених аналізів існує значна розбіжність у складі вільних газів, що робить малоефективним застосування класичної статистичної обробки наявних матеріалів. Проте, за домінуючим масивом точок вдається визначити тенденції до зміни вмісту в газі окремих компонентів, які в сумі характеризують повний (100 % об’ємних) склад флюїду на різних рівнях глибин залягання покладів для двох частин Зовнішньої зони – північно-західної та південно-східної. Побудовано графіки та виведено відносно глибин залягання покладів рівняння регресії прогнозних параметрів, які входять у формулу підрахунку запасів вуглеводнів об’ємним методом. Виведені рівняння регресії для прогнозування в поєднані з лабораторними дослідженнями термобаричних умов (тиску і температури) з глибиною, оскільки відомості про них потрібні для обчислення окремих параметрів вуглеводневих систем.
对前喀尔巴阡地槽外区气田的储层碳氢系统进行了区域预测。确定了不同类型碳氢化合物系统分布的依存关系,从而有可能在勘探初期对高温高压地区的深层碳氢化合物系统进行预测。根据分析结果,游离气体的成分存在很大差异,这使得使用现有材料的经典统计处理方法无效。尽管如此,主要的点阵使我们能够确定气体中单个成分的含量趋势,这些成分共同描述了外区两个部分--西北部和东南部--不同矿床深度的流体全成分(体积百分比)。用体积法估算碳氢化合物储量的公式中包含的预测参数的回归方程是根据矿床深度绘制和推导的。预测的回归方程是结合热压条件(压力和温度)随深度变化的实验室研究得出的,因为计算碳氢化合物系统的某些参数需要这些信息。
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引用次数: 0
Investigation of the influence of gravel stuffing in an open drill on the productive characteristics of the well 裸眼钻井中砾石充填对油井生产特性影响的研究
Pub Date : 2020-12-28 DOI: 10.31471/1993-9973-2020-4(77)-16-22
R. Kondrat, N. Dremliukh, L. I. Haidarova
The negative consequences of sand production from the formation into the wellbore during the operation of wells with unstable rocks are characterized. A highly effective method of preventing sand from entering the well from the formation is the use of gravel packs, which are used in Ukraine and abroad. The types of gravel packs, the conditions for their application, the choice of the diameter of gravel grains for creating gravel pack are given. The types of gravel pack installation are considered depending on the geological and technical conditions of the reservoir. Calculations have been performed using Schlumberger's PipeSim software to assess the effect of gravel pack size and permeability on the performance specification of a gas well. Based on the research results, graphical de-pendences of gas flow rates in the presence of gravel pack on the permeability of the gravel pack at its various thicknesses have been constructed and analyzed. It has been found that the gas flow rate increases with an increase in the thickness of the gravel pack in the considered interval of its variation up to 0.9 m. The effect of the thickness of the gravel pack on the gas flow rate increases with an increase in its permeability. Based on the results of statistical processing of the calculated data using the least-squares method, the optimal values of the gravel pack permeability for various values of its thickness have been determined. The optimal values of the thickness and permeability of the gravel pack have been determined, beyond which the value of the gas flow rate practically does not change. The calculation of the pressure distribution along the bore of a gas well in the presence of gravel pack with certain optimal values of its permeability and thickness is performed. Using the PipeSim software, the influence of the de-gree of relative formation penetration on the productivity of a gas well in the presence of gravel packing has been investigated for determining certain optimal values of permeability and thickness of gravel packing.
在具有不稳定岩石的井中,从地层到井筒的出砂的负面影响是典型的。防止砂粒从地层进入井内的一种高效方法是使用砾石充填,这种方法在乌克兰和国外都有使用。介绍了砾石充填的类型、使用条件和砾石充填粒径的选择。砾石充填装置的类型取决于储层的地质和技术条件。使用斯伦贝谢的PipeSim软件进行了计算,以评估砾石充填尺寸和渗透率对气井性能指标的影响。基于研究结果,构建并分析了砾石充填时不同厚度砾石充填渗透率与气体流速的图形关系。研究发现,在砾石充填层厚度变化范围内,气体流速随砾石充填层厚度的增加而增加,其变化幅度可达0.9 m。砾石充填层厚度对气体流速的影响随其渗透率的增加而增大。利用最小二乘法对计算数据进行统计处理,确定了不同厚度下砾石充填层渗透率的最优值。砾石充填层厚度和渗透率的最佳值已经确定,超过此值,气体流速实际上不会发生变化。在给定最佳渗透率和厚度的条件下,计算了含砾石充填气井井筒内的压力分布。利用PipeSim软件,研究了存在砾石充填时地层相对侵深程度对气井产能的影响,以确定砾石充填渗透率和厚度的最佳值。
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引用次数: 0
Investigation of the flow twist influence on the well jet pumps characteristic 流动扭转对井喷泵特性影响的研究
Pub Date : 2020-12-28 DOI: 10.31471/1993-9973-2020-4(77)-31-40
D. Panevnyk
The scope of downhole ejection systems is limited by the low value of the efficiency of the jet pump, the value of which usually does not exceed 35 %. Significant energy losses when mixing flows are the reason for the low efficiency of the jet pump. The energy performance of the downhole ejection system can be increased by creating swirling vortex circulating currents in the flow part of the jet pump. This optimizes the nature of the flow mixing and increases the energy performance of the jet pump. In the process of studying the structures, features of the working process and usage experience of ejection systems designed for drilling, operation and repair of oil and gas wells, it is established that the twisting of the working medium in downhole jet pumps can be carried out using guide elements placed at a certain angle in the oncoming flow and rotation of individual parts of the ejection system by means of an external drive and hydraulic turbines. The use of guide elements and hydraulic turbines necessitates the use of part of the energy of the working flow, which drives the downhole jet pump, to spin the working medium. In oil and gas ejection systems, the twisting of working, injected and mixed streams can be realized, as well as the combined simultaneous twisting of several streams. In the process of analyzing the experience of using vortex jet devices, it has been found that the flow twist allows to increase the injection coefficient of the jet pump by 38.1 %, efficiency – up to 70 %, vacuum in the receiving ch amber – up to 40 %. The increase in the basic geometric pa-rameter of the jet pump reduces the effect of flow twist on the characteristics of the ejection system. Flow twisting in downhole jet pumps can be recommended in the implementation of long-term processes, for example, in the ex-traction of formation fluid, when the value of the efficiency of the ejection system significantly affects the cost of oil production.
喷射泵的效率通常不超过35%,这限制了井下喷射系统的应用范围。射流泵在混流过程中能量损失大是其效率低的原因。通过在喷射泵的流动部分产生旋涡循环电流,可以提高井下弹射系统的能量性能。这优化了流动混合的性质,提高了喷射泵的能量性能。通过对油气井钻井、作业和修井用喷射系统的结构、工作过程特点和使用经验的研究,确定了利用外部驱动和水轮机,在喷射系统各部件的迎面流和旋转中,以一定角度放置导向元件,实现井下喷射泵内工作介质的扭转。导流元件和水轮机的使用,需要利用工作流的一部分能量来驱动井下喷射泵旋转工作介质。在油气喷射系统中,可以实现工作流、注入流和混合流的旋扭,也可以实现多流的联合同步旋扭。在分析涡旋喷射装置使用经验的过程中,发现气流扭转可使喷射泵的喷射系数提高38.1%,效率可达70%,接收腔的真空度可达40%。射流泵基本几何参数的增大减小了流动扭转对喷射系统特性的影响。在长期作业过程中,例如在地层流体的抽提过程中,当喷射系统的效率值显著影响石油生产成本时,可以推荐使用井下喷射泵的流动扭曲。
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引用次数: 0
Technology of conversion of materials of power and oil refining objects 电力和炼油原料转化技术
Pub Date : 2020-12-28 DOI: 10.31471/1993-9973-2020-4(77)-7-15
L. Chelyadyn, V. Ribun, V. V. Vizinovych, І. V. Tarasiuk
Quantitative and qualitative characteristics of multi-ton materials in Ukraine and in Ivano-Frankivsk region, which Quantitative and qualitative characteristics of multi-ton materials in Ukraine and in Ivano-Frankivsk region, which contain energy components, are given. It is proposed to process water treatment sludges containing petro-leum products by preparing a raw material mixture from the following man-made substances: oil sludge, ash, zeo-lite screenings, calcium-containing compounds and viscous materials. The optimal composition of the raw material mixture is as follows: as a filler for construction products (concrete): ash – 60-65 %, liquid glass s olution – 5-7 %, limestone dust – 3-5 %, organic additives – 7-10 %, soda ash – 10-12 %, which is granulated and heat t reated at 120-140 °C. The research results and technical char acteristics of the obtained granular materials, which are formed from a mixture containing a significant amount of hydrocarbon sludge, have lower strength, but greater porosity and lower thermal conductivity. Granules from a mixture № 4-7 are characterized by higher strength, and due to their properties they belong to the structural and thermal insulation materials. The technology of obtaining a raw material mixture for soda production is based on the LeBlanc process – the interaction in the seco nd stage of sodium sulfate, carbon and calcium carbonate with the formation of calcium sulfide, sodium carbonate and carbon (IV) oxide. It is proposed to prepare a raw mixture for the production of sodium carbonate from sodium sulfate con-taining petroleum product, which is formed by the technology of obtaining oxygen-containing additives, and sludge containing petroleum products, which will provide a high temperature during the soda production process. The processing of sludge from oil refining and energy facilities into granular materials shows that they can be used in the construction industry and soda production, which reduces the energy consumption of the processes of obtaining such materials.
给出了乌克兰和伊万诺-弗兰科夫斯克地区含有能源成分的多吨材料的定量和定性特征。提出以油泥、灰分、零沸石筛分、含钙化合物和黏性物质为原料,制备含石油产品水处理污泥的混合原料。原料混合物的最佳组成如下:作为建筑产品(混凝土)的填料:灰分- 60- 65%,液态玻璃溶液-5 - 7%,石灰石粉尘- 3- 5%,有机添加剂-7 - 10%,纯碱-10 - 12%,将其制成颗粒,在120-140℃下加热。研究结果和所获得的颗粒材料的技术特征是,由含有大量碳氢污泥的混合物形成的颗粒材料强度较低,但孔隙率较大,导热系数较低。混合物№4-7的颗粒具有较高的强度,由于它们的性质,它们属于结构和保温材料。制碱原料混合物的获取技术是基于勒布朗过程——硫酸钠、碳和碳酸钙在第二阶段的相互作用,形成硫化钙、碳酸钠和氧化碳。提出以含石油产品的硫酸钠为原料,通过获得含氧添加剂的技术与含石油产品的污泥相结合,制备一种生产碳酸钠的原料混合物,该原料混合物将在苏打生产过程中提供高温。炼油和能源设施的污泥加工成颗粒状材料表明,它们可以用于建筑工业和苏打生产,从而降低了获取此类材料的过程的能耗。
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引用次数: 1
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Prospecting and Development of Oil and Gas Fields
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