Pub Date : 2004-03-01DOI: 10.5650/OLEOSCIENCE.4.97
H. Ishii
Amino acid based esters, which have amino acid residue as hydrophilic moiety, are reviewed with respect to their properties and cosmetic applications. Due to their chemical structures, they could be described as polar materials which have properties of oils and surfactants. In this paper, two types of amino acid based esters are introduced. N-lauroyl sarcosine isopropyl ester (SLIP) can dissolve low-solubility materials such as organic UV-A absorbing agents, and improve the dispersion of Titanium dioxide pigments in oil. SLIP allows low-solubility materials to be easily incorporated into cosmetic formulation. On the other hand, N-lauroyl glutamic acid sterol esters (AGCEs) are cosmetically very suitable for skin-care and hair-care products. AGCEs show similarities to intercellular lipids of epidermis and hair.
{"title":"Characteristic Properties and Application of Amino Acid Based Esters","authors":"H. Ishii","doi":"10.5650/OLEOSCIENCE.4.97","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.4.97","url":null,"abstract":"Amino acid based esters, which have amino acid residue as hydrophilic moiety, are reviewed with respect to their properties and cosmetic applications. Due to their chemical structures, they could be described as polar materials which have properties of oils and surfactants. In this paper, two types of amino acid based esters are introduced. N-lauroyl sarcosine isopropyl ester (SLIP) can dissolve low-solubility materials such as organic UV-A absorbing agents, and improve the dispersion of Titanium dioxide pigments in oil. SLIP allows low-solubility materials to be easily incorporated into cosmetic formulation. On the other hand, N-lauroyl glutamic acid sterol esters (AGCEs) are cosmetically very suitable for skin-care and hair-care products. AGCEs show similarities to intercellular lipids of epidermis and hair.","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2004-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79771910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2003-02-01DOI: 10.5650/OLEOSCIENCE.3.77
弘幸 古田, 大光 前田
{"title":"N-混乱ポルフィリン-新規ポルフィリン異性体-の化学","authors":"弘幸 古田, 大光 前田","doi":"10.5650/OLEOSCIENCE.3.77","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.3.77","url":null,"abstract":"","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2003-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81369691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2003-01-01DOI: 10.5650/OLEOSCIENCE.3.19
利彦 長村
{"title":"膜による光エネルギーの化学・電気・光変換","authors":"利彦 長村","doi":"10.5650/OLEOSCIENCE.3.19","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.3.19","url":null,"abstract":"","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2003-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81905563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2003-01-01DOI: 10.5650/OLEOSCIENCE.3.29
篤治 池田
{"title":"ホスト-ゲスト包接錯体を利用する [60] フラーレンの水溶化とその応用研究","authors":"篤治 池田","doi":"10.5650/OLEOSCIENCE.3.29","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.3.29","url":null,"abstract":"","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2003-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83085860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2002-12-01DOI: 10.5650/OLEOSCIENCE.2.739
博信 國枝
{"title":"界面活性剤自己組織体溶液の相挙動, 構造, 機能に関する研究","authors":"博信 國枝","doi":"10.5650/OLEOSCIENCE.2.739","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.2.739","url":null,"abstract":"","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2002-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85388290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2002-10-01DOI: 10.5650/OLEOSCIENCE.2.637
興一 浦田
{"title":"グリセリルエーテル関連化合物開発と“Green Chemistry”","authors":"興一 浦田","doi":"10.5650/OLEOSCIENCE.2.637","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.2.637","url":null,"abstract":"","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2002-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74901066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2002-08-01DOI: 10.5650/OLEOSCIENCE.2.451
M. Shionoya, Kentaro Tanaka
A number of strategies have been so far employed for modifying the periphery of DNA with metal complexes. However, little has been done to explore the DNA core . Recently, we envisioned the use of charged or uncharged metal complexes as replacement building blocks in the interior of the DNA helix. Replacement of the hydrogen-bonded base pairing of natural DNA by alternative base pairing modes is expected to lead not only to expansion of the genetic alphabet but also to novel DNA structures and functions based on the controlled and periodic spacing of the building blocks along the helix axis. This paper provides a summary of our recent progress devoted to the introduction of metal-assisted base pairs directed towards what we term the nano-assembly of metals into the DNA core . Specifically, we detail here syntheses of artificial /3-C-nucleosides bearing a chelator nucleobase (o-phenylenediamine, catechol, 2-aminophenol, pyridine, or hydroxypyridone , and so on), their metal coordination properties with metal ions, and the incorporation of these building blocks into DNA oligomers . The present results raise the appealing possibility that this approach could lead eventually to a novel molecular architecture-type approach to the nano-assembly of multi-metal arrays .
{"title":"Construction of Artificial DNAs Containing a Metal Complex-Type Base Pair","authors":"M. Shionoya, Kentaro Tanaka","doi":"10.5650/OLEOSCIENCE.2.451","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.2.451","url":null,"abstract":"A number of strategies have been so far employed for modifying the periphery of DNA with metal complexes. However, little has been done to explore the DNA core . Recently, we envisioned the use of charged or uncharged metal complexes as replacement building blocks in the interior of the DNA helix. Replacement of the hydrogen-bonded base pairing of natural DNA by alternative base pairing modes is expected to lead not only to expansion of the genetic alphabet but also to novel DNA structures and functions based on the controlled and periodic spacing of the building blocks along the helix axis. This paper provides a summary of our recent progress devoted to the introduction of metal-assisted base pairs directed towards what we term the nano-assembly of metals into the DNA core . Specifically, we detail here syntheses of artificial /3-C-nucleosides bearing a chelator nucleobase (o-phenylenediamine, catechol, 2-aminophenol, pyridine, or hydroxypyridone , and so on), their metal coordination properties with metal ions, and the incorporation of these building blocks into DNA oligomers . The present results raise the appealing possibility that this approach could lead eventually to a novel molecular architecture-type approach to the nano-assembly of multi-metal arrays .","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2002-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88419504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2002-07-01DOI: 10.5650/OLEOSCIENCE.2.411
Wakida Shin-ichi
Trends in high throughput analytical methods weredescribed including our studies, chemical sensors based on potentiometry, capillary electrophoresis (CE), CE with mass spectrometry and microchip for surfactants and their degradation products in waters.
{"title":"High Throughput Analysis for Surfactants and Their Degradation Products in Waters","authors":"Wakida Shin-ichi","doi":"10.5650/OLEOSCIENCE.2.411","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.2.411","url":null,"abstract":"Trends in high throughput analytical methods weredescribed including our studies, chemical sensors based on potentiometry, capillary electrophoresis (CE), CE with mass spectrometry and microchip for surfactants and their degradation products in waters.","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2002-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87321227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2002-06-01DOI: 10.5650/OLEOSCIENCE.2.333
和夫 宮下
{"title":"共役型リノレン酸 (CLN) によるガン予防","authors":"和夫 宮下","doi":"10.5650/OLEOSCIENCE.2.333","DOIUrl":"https://doi.org/10.5650/OLEOSCIENCE.2.333","url":null,"abstract":"","PeriodicalId":16191,"journal":{"name":"Journal of Japan Oil Chemists Society","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2002-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89477883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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