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Journal of Japan Oil Chemists Society最新文献

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Atherosclerosis and Oxysterols 动脉粥样硬化和氧化固醇
Pub Date : 2002-05-01 DOI: 10.5650/oleoscience.2.267
Rvouta Maeba
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引用次数: 0
2-ドコサヘキサエノイル-sn-グリセロ-3-ホスホコリンの半合成 2-氨基乙酸乙酯酰-sn-甘油-3-磷酸胆碱的半合成
Pub Date : 2002-02-01 DOI: 10.5650/OLEOSCIENCE.2.75
英彦 日比野
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引用次数: 0
油脂栄養及び生体内酸化 (特に老化色素) に関する研究 油脂营养和生物内氧化(特别是老化色素)的研究
Pub Date : 2001-12-01 DOI: 10.5650/OLEOSCIENCE.1.1121
弘幸 島崎
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引用次数: 0
現在のキャノーラ (Brassica napus L.) 育種の最先端 目前最先进的canola (Brassica napus L.)育种
Pub Date : 2001-08-01 DOI: 10.5650/OLEOSCIENCE.1.835
T. Kubik, Chibwe Chungu, S. Freeman, Bruce G. Murray, Pat Corbett, S. Thompson, 淳一 生稲
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引用次数: 0
221st ACS National Meetingに参加して 参加了221st ACS National Meeting
Pub Date : 2001-07-01 DOI: 10.1021/cen-09408-meetings1
土屋 好司
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引用次数: 3
マイクロエマルション-ベース-オルガノゲル 微塑-基-奥尔加诺凝胶
Pub Date : 2001-07-01 DOI: 10.5650/OLEOSCIENCE.1.743
勇 宮田, 政勝 米勢
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引用次数: 0
マンガン(III)に基づく酸化反応を利用した有機合成への新展開 利用基于锰(III)的氧化反应的有机合成的新发展
Pub Date : 2001-05-01 DOI: 10.5650/OLEOSCIENCE.1.491
宏 西野
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引用次数: 4
Microencapsulation Using Supercritical Carbon Dioxide 使用超临界二氧化碳进行微胶囊化
Pub Date : 2001-04-01 DOI: 10.5650/OLEOSCIENCE.1.373
K. Mishima, K. Matsuyama
A new method for rapid expansion from supercritical solution with a nonsolvent (RESS-N) to obtain polymer microparticles containing proteins, medicine and inorganic microparticles is presented in the following. On this method, a suspension of microparticles such as protein in carbon dioxide(CO2) containing a cosolvent and dissolved polymer is sprayed through a nozzle into atmosphere. Polymer solubility, such as that of poly(ethylene glycol) and poly(methyl methacrylate), in CO2 was found to increase significantly through use of low molecular weight alcohols as cosolvents. Subsequent to expansion, the particles do not agglomerate, since pure cosolvent functions as nonsolvent for the polymer. Polymer coating thickness on about core materials, mean particle diameter and particle size distribution can be controlled according to polymer feed composition.
本文介绍了一种用非溶剂(RESS-N)从超临界溶液中快速膨胀得到含有蛋白质、药物和无机微粒的聚合物微粒的新方法。在这种方法中,含有助溶剂和溶解聚合物的二氧化碳(CO2)中的蛋白质等微粒悬浮液通过喷嘴喷射到大气中。聚合物的溶解度,如聚(乙二醇)和聚(甲基丙烯酸甲酯),在二氧化碳中发现,通过使用低分子量的醇作为共溶剂显著增加。在膨胀之后,颗粒不会聚集,因为纯共溶剂对聚合物起非溶剂的作用。聚合物涂层厚度、平均粒径和粒径分布可根据聚合物进料组成进行控制。
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引用次数: 0
Microscopic Solvent Properties of Supercritical Methanol and Its Application to Methylation 超临界甲醇的微观溶剂性质及其在甲基化中的应用
Pub Date : 2001-04-01 DOI: 10.5650/OLEOSCIENCE.1.381
T. Sako
Supercritical methanol, which has 512.6 K of critical temperature and 8.09 MPa of critical pressure, is a promising solvent for advanced chemical reaction processes. As this solvent can change the solvent properties much more widely and successively than liquids solvents and control the solvation structure easily by manipulating the temperature and pressure, we can realize the high reaction rate and the selective conversion to a desirable product atthe same time. In this review, we show the dependence of the microscopic solvent properties of suband supercritical methanol on temperature and pressure and explain the relationship between the properties and reactivity. Then we describe the highly selective and non-catalytic methylation of aromatic ring , Nmethylation, 0-methylation and production of acetal from ketone using supercritical methanol.
超临界甲醇具有512.6 K的临界温度和8.09 MPa的临界压力,是一种很有前途的高级化学反应溶剂。由于该溶剂可以比液体溶剂更广泛、更连续地改变溶剂性质,并且可以通过调节温度和压力轻松地控制溶剂化结构,因此可以同时实现高反应速率和选择性转化为所需产物。本文介绍了亚超临界和超临界甲醇的微观溶剂性质对温度和压力的依赖性,并解释了性质与反应性之间的关系。然后介绍了芳烃环的高选择性非催化甲基化、甲基化、0-甲基化以及用超临界甲醇从酮制缩醛。
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引用次数: 0
Molecular conversion synchronized by 4-electron reduction of oxygen 由氧的4电子还原同步的分子转化
Pub Date : 2001-02-01 DOI: 10.5650/OLEOSCIENCE.1.147
K. Yamamoto
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引用次数: 0
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Journal of Japan Oil Chemists Society
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