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Columnar-to-Equiaxed Transition in Metal-Matrix Composites Reinforced with Silicon Carbide Particles 碳化硅增强金属基复合材料的柱状向等轴转变
Pub Date : 2013-12-30 DOI: 10.1155/2013/628495
A. Ares, C. Schvezov
The present work is focused on the study of the effect of directional heat extraction on the silicon-carbide (SiC) distribution in zinc-aluminum matrix composites (MMCs) and on the columnar-to-equiaxed (CET) position in directionally solidified samples. To this end, a ZA-27 alloy matrix was reinforced with ceramic particles of SiC and vertically directionally solidified. The cooling rates, temperature gradients, and interphase velocities were then measured, and their influence on the solidification microstructure of the MMCs was analyzed. The recalescence detected and measured during the equiaxed transition was of the order of 3.5°C to 1.1°C. The values of the temperature gradients reached a minimum during the CET and were even negative in most cases (between −3.89 K and 0.06 K). The interphase velocities varied between 0.07 mm/s and 0.44 mm/s at the transition. Also, the presence of ceramic particles in ZA-27 alloys affected the thermodynamic local conditions and the kinetics of nucleation, producing a finer microstructure.
本文主要研究了定向热萃取对锌铝基复合材料(MMCs)中碳化硅(SiC)分布和定向凝固样品中柱-等轴(CET)位置的影响。为此,在ZA-27合金基体中加入SiC陶瓷颗粒并进行纵向固化。然后测量了冷却速率、温度梯度和界面速度,并分析了它们对mmc凝固组织的影响。在等轴转变过程中检测和测量到的复光在3.5°C到1.1°C之间。温度梯度值在CET期间达到最小值,在大多数情况下甚至为负(在- 3.89 K和0.06 K之间)。相变时相间速度在0.07 ~ 0.44 mm/s之间变化。此外,陶瓷颗粒的存在影响了ZA-27合金的局部热力学条件和成核动力学,产生了更精细的微观组织。
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引用次数: 5
Factorial Analysis of Welding Current Influence on Heat Affected Zone Hardness of Cast Iron, Aluminium, and Mild Steel Weldments Cooled in Palm Oil 焊接电流对棕榈油冷却铸铁、铝和低碳钢焊接件热影响区硬度影响的析因分析
Pub Date : 2013-11-20 DOI: 10.1155/2013/245312
C. Nwoye, J. Odō, E. Ameh, S. Nwakpa
Factorial analysis of heat affected zone hardness of some metals was evaluated. Three models were derived and used as tools for evaluating the welding current influence on the predictability of HAZ hardness in aluminium, cast iron, and mild steel weldments similarly cooled in palm oil. It was discovered that on welding these materials, and similarly cooling their respective weldments in palm oil, the model predicts aluminium weldment HAZ hardness by multiplying the determined general current product rule (GCPR) with the ratio: HAZ hardness product of cast iron and mild steel/HAZ hardness sum of cast iron and mild steel . Computational analysis of experimental and model-predicted results indicates that aluminium, cast iron, and mild steel weldment HAZ hardness per unit welding current as evaluated from experiment and derived model are 3.3917, 4.8333, and 2.7944 and 3.3915, 4.8335, and 2.7946 (VHN) A−1, respectively. Deviational analysis shows that the maximum deviation of model-predicted HAZ hardness from the experimental results is less than 0.007%. This invariably implies over 99.99 % confidence level for the derived models.
对几种金属的热影响区硬度进行了析因分析。导出了三个模型,并用作评估焊接电流对铝、铸铁和低碳钢焊接件HAZ硬度可预测性的影响的工具,这些焊接件同样在棕榈油中冷却。结果发现,在焊接这些材料时,同样在棕榈油中冷却各自的焊接件,该模型通过将确定的一般电流积规则(GCPR)与比值:铸铁和低碳钢的HAZ硬度积/铸铁和低钢的HAZ硬度之和相乘来预测铝焊接件的HAZ硬度。对实验和模型预测结果的计算分析表明,铝、铸铁和低碳钢焊件单位焊接电流的HAZ硬度分别为3.3917、4.8333和2.7944,分别为3.3915、4.8335和2.7946 (VHN) A−1。偏差分析表明,模型预测的HAZ硬度与实验结果的最大偏差小于0.007%。这必然意味着衍生模型的置信水平超过99.99%。
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引用次数: 2
Preparation of Niobium Metal Powder by Two-Stage Magnesium Vapor Reduction of Niobium Pentoxide 五氧化二铌两段镁气还原法制备金属铌粉
Pub Date : 2013-08-19 DOI: 10.1155/2013/629341
T. Kumar, S. R. Kumar, M. L. Rao, T. Prakash
Magnesium vapor reduction of niobium pentoxide was studied using a laboratory system. Niobium powder was prepared by the magnesium vapor reduction at 1123 K for 5 hours and it contained about 8 mass % oxygen. However, the oxygen concentration could be decreased to 0.65% when it was prepared by double-step reduction by magnesium vapor and a chemical treatment. Controlled and diluted supply of magnesium vapor to the reaction front has averted excess heat generation at the reaction front and thereby fine particles were produced. Effects of various factors on the vapor reduction process were studied and discussed.
采用实验室系统研究了五氧化二铌的镁气还原反应。在1123 K条件下,用镁蒸气还原法制备铌粉,其含氧量约为8%。而采用镁蒸汽两步还原法和化学处理法制备后,氧浓度可降至0.65%。控制和稀释镁蒸汽供应到反应前沿,避免了反应前沿产生多余的热量,从而产生了细颗粒。研究和讨论了各种因素对蒸汽还原过程的影响。
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引用次数: 8
Inhibition Effect of Substituted Thiadiazoles on Corrosion Activity of N80 Steel in HCl Solution 取代噻二唑对N80钢在HCl溶液中腐蚀活性的缓蚀作用
Pub Date : 2013-04-18 DOI: 10.1155/2013/256403
M. Yadav, Sumit Kumar, D. Behera
The inhibition effect of some prepared compounds, namely, thiadiazole derivatives, on N80 steel corrosion in 15% HCl solutions has been studied by using the weight loss, electrochemical polarization, and electrochemical impedance spectroscopy techniques. It was found that the inhibition efficiency of the thiadiazole derivatives, namely, 2-amino-5-(4-methoxyphenyl)-1,3,4-thiazole (AMPT), 2-amino-5-phenyl-1,3,4-thiazole (APT), and 2-amino-5-(4-chlorophenyl)-1,3,4-thiazole (ACPT), increases with the increase in concentration. Inhibition efficiency follows the order AMPT > APT > ACPT. The effect of temperature on the corrosion was investigated by the weight loss method, and some thermodynamic parameters were calculated. The inhibitive action may be attributed to the adsorption of inhibitor molecules on the active sites of the metal surface following Langmuir adsorption isotherm. Polarization measurements indicated that thiadiazole derivatives act as mixed-type corrosion inhibitor. The adsorption of thiadiazole derivatives on N80 surface exposed to inhibitor-containing solutions was confirmed using SEM and FT-IR spectra.
采用失重、电化学极化和电化学阻抗谱技术研究了所制备化合物噻二唑衍生物在15% HCl溶液中对N80钢的缓蚀作用。结果表明,噻唑类衍生物2-氨基-5-(4-甲氧基苯基)-1,3,4-噻唑(AMPT)、2-氨基-5-苯基-1,3,4-噻唑(APT)和2-氨基-5-(4-氯苯基)-1,3,4-噻唑(ACPT)的抑制效率随浓度的增加而增加。抑菌效果为AMPT > APT > ACPT。采用失重法研究了温度对腐蚀的影响,并计算了一些热力学参数。这种抑制作用可能是由于抑制剂分子按照Langmuir等温线吸附在金属表面的活性位点上。极化测量表明噻二唑衍生物为混合型缓蚀剂。利用扫描电镜(SEM)和红外光谱(FT-IR)研究了噻唑衍生物在N80表面的吸附作用。
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引用次数: 12
Mathematical Models for the Novel Cathode Convexes in a Reduction Cell 还原电池中新型阴极凸的数学模型
Pub Date : 2013-03-31 DOI: 10.1155/2013/196891
Z. He, T. Xia, W. Xiong, Q. Shen, B. Li
A less magnitude of liquid aluminum deformation is required to shorten the anode-cathode distance so as to lower the electric energy consumption of the aluminum reduction cell. A mathematical model aimed to describe the electrolyte/aluminum two-phase flow in reduction cells, based on the computational fluid dynamics method, was developed to study the impacts of the cathode convexes on the electrolyte/aluminum interface deformation. The results showed that the magnitude of the two-phase interface deformation was reduced for about 17.2% with the novel cathode convexes; while at the same time, the washout of the melt on the ledge was also enhanced.
为了缩短铝电解槽的阳极-阴极距离,降低电解槽的电能消耗,需要减小铝液的变形幅度。基于计算流体力学方法,建立了还原电池中电解液/铝两相流动的数学模型,研究了阴极凸性对电解液/铝界面变形的影响。结果表明:新型阴极凸面使两相界面变形幅度减小了约17.2%;与此同时,岩架上熔体的冲刷也增强了。
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引用次数: 1
XRD and DTA Analysis of Developed Agglomerated Fluxes for Submerged Arc Welding 埋弧焊烧结焊剂的XRD和DTA分析
Pub Date : 2013-03-11 DOI: 10.1155/2013/827491
Ajay Kumar, H. Singh, S. Maheshwari
A unique study of structural and chemical analysis of crystalline phases in developed agglomerated fluxes was carried out. Thirty-two fluxes were developed by using a mixture of oxides, halides, carbonates, silicates, and ferroalloys for submerged arc welding. The present paper focuses on only ten (out of thirty-two) fluxes which were analyzed by X-ray diffraction (XRD) to know the different types of oxides formed and changed in oxidation number of metallic centers after sintering process at around 850∘C. To know the effect of temperature over phase transformation and melting of different compounds, differential thermal analysis (DTA) was carried out from 1000 to 1400∘C. This study aims to know the quantity of ions present (percentage) and melting behavior of developed agglomerated fluxes for submerged arc welding process.
对发达的结块助熔剂中结晶相的结构和化学分析进行了独特的研究。将氧化物、卤化物、碳酸盐、硅酸盐和铁合金的混合物用于埋弧焊,研制了32种助焊剂。本文只关注了32种助焊剂中的10种,用x射线衍射(XRD)对它们进行了分析,以了解在850°C左右烧结过程中形成的不同类型的氧化物和金属中心氧化数的变化。为了了解温度对不同化合物相变和熔化的影响,从1000°C到1400°C进行了差热分析(DTA)。本研究的目的是了解埋弧焊过程中已开发的凝聚剂的离子含量(百分比)和熔化行为。
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引用次数: 4
Fabrication of Single-Phase NiTi by Combustion Synthesis of Mechanically Activated Powders 燃烧合成机械活化粉末制备单相NiTi
Pub Date : 2012-12-30 DOI: 10.1155/2012/153841
S. M. Nasab, M. Aboutalebi, S. H. Seyedein, A. M. Kakhki, J. V. Khaki
Single-phase NiTi was fabricated through the thermal explosion mode of combustion synthesis of mechanically activated powders. Combustion and ignition temperatures of combustion synthesis were investigated in different milling times. In this process, equiatomic powder mixtures of nickel and titanium were activated by planetary ball mill and pressed into disk-shaped pellets then heated in a tube furnace, while temperature-time profile was recorded. X-ray diffraction analysis (XRD) was performed on milled powders as well as synthesized samples. Scanning electron microscopy (SEM) was also used to study the microstructural evolution during milling. The results showed that there was a threshold milling time to obtain single-phase NiTi. It was also seen that the ignition temperature and combustion temperature were reduced significantly by increasing milling time.
采用燃烧合成机械活化粉末的热爆炸方式制备了单相镍钛。研究了不同磨粉时间下燃烧合成的燃烧温度和着火温度。在此过程中,镍和钛的等原子粉末混合物由行星球磨机活化,压制成圆盘状颗粒,然后在管式炉中加热,同时记录温度-时间曲线。对粉碎后的粉末和合成样品进行了x射线衍射分析(XRD)。利用扫描电子显微镜(SEM)研究了铣削过程中微观组织的演变。结果表明,制备单相NiTi存在一定的阈值时间。延长磨矿时间可以显著降低着火温度和燃烧温度。
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引用次数: 1
Effect of Diacetyl Monoxime Thiosemicarbazone on the Corrosion of Aged 18 Ni 250 Grade Maraging Steel in Sulphuric Acid Solution 二乙酰单胺硫代氨基脲对时效18ni250级马氏体时效钢在硫酸溶液中的腐蚀影响
Pub Date : 2012-12-17 DOI: 10.1155/2012/723687
T. Poornima, J. Nayak, A. Shetty
The corrosion inhibition of the aged 18 Ni 250 grade maraging steel in 0.5 M sulphuric acid by diacetyl monoxime thiosemicarbazone (DAMTSC) at 303–323 K has been investigated by potentiodynamic polarization, EIS, and SEM techniques. Good inhibition efficiency of DAMTSC was revealed even at low concentrations, which increased with the increase in DAMTSC concentration and decreased with the increase in temperature. The activation energies, , as well as other thermodynamic parameters (; ; ), were evaluated and discussed. The adsorption of DAMTSC on the aged maraging steel surface was found to obey the Langmuir adsorption isotherm model and shows mixed type inhibition behavior.
采用动电位极化、EIS和SEM技术研究了DAMTSC对时效18 Ni 250级马氏体时效钢在0.5 M硫酸中303 ~ 323 K的缓蚀作用。在低浓度条件下,DAMTSC也表现出良好的抑菌效果,抑菌效果随DAMTSC浓度的升高而升高,随温度的升高而降低。活化能、、以及其他热力学参数(;,),进行了评估和讨论。结果表明,DAMTSC在时效马氏体时效钢表面的吸附符合Langmuir吸附等温线模型,表现为混合型缓蚀行为。
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引用次数: 12
Mechanical Response of Al-1.09Mg2Si Alloy under Varying Mould and Thermal Ageing Conditions Al-1.09Mg2Si合金在不同模具和热时效条件下的力学响应
Pub Date : 2012-12-11 DOI: 10.1155/2012/921235
O. Sekunowo, G. Lawal, S. Adeosun
Samples of the 6063 (Al-1.09Mg2Si) alloy ingot were melted in a crucible furnace and cast in metal and sand moulds, respectively. Standard tensile, hardness, and microstructural test specimens were prepared from cast samples, solution treated at 520∘C, soaked for 6 hrs, and immediately quenched at ambient temperature in a trough containing water to assume a supersaturated structure. The quenched specimens were then thermally aged at 175∘C for 3–7 hrs. Results show that at different ageing time, varied fractions of precipitates and intermetallics evolved in the specimens’ matrices which affect the resulting mechanical properties. The metal mould specimens aged for four hours (MTA-4) exhibited superior ultimate tensile strength of 247.8 MPa; microhardness, 68.5 HV; elongation, 28.2% . It is concluded that the extent of improvement in mechanical properties depends on the fractions, coherence, and distribution of precipitates along with the type of intermetallics developed in the alloy during ageing process.
将6063 (Al-1.09Mg2Si)合金锭样分别在坩埚炉中熔化,在金属模和砂型中铸造。标准的拉伸、硬度和显微组织试样是由铸态试样制成的,在520°C下进行溶液处理,浸泡6小时,然后立即在常温下在装有水的槽中淬火,使其呈过饱和结构。然后将淬火后的样品在175°C下热时效3-7小时。结果表明,在不同时效时间下,试样基体中析出的析出相和金属间化合物含量不同,影响了试样的力学性能。时效4 h的金属模具试样(MTA-4)的极限抗拉强度为247.8 MPa;显微硬度:68.5 HV;伸长率:28.2%。结果表明,合金力学性能的改善程度取决于时效过程中析出相的分数、相干性和分布以及合金中形成的金属间化合物的类型。
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引用次数: 0
Precipitation of Phase Using General Diffusion Equation with Comparison to Vitek Diffusion Model in Dissimilar Stainless Steels 用一般扩散方程分析相的析出,并与Vitek扩散模型比较
Pub Date : 2012-11-22 DOI: 10.1155/2012/154617
Chih-Chun Hsieh, Weite Wu
This study performs a precipitation examination of the phase using the general diffusion equation with comparison to the Vitek model in dissimilar stainless steels during multipass welding. Experimental results demonstrate that the diffusivities (, , and ) of Cr, Ni, and Si are higher in -ferrite than (, , and ) in the phase, and that they facilitate the precipitation of the σ phase in the third pass fusion zone. The Vitek diffusion equation can be modified as follows: .
本研究使用一般扩散方程对不同不锈钢在多道焊接过程中的相进行了沉淀检验,并与Vitek模型进行了比较。实验结果表明,Cr、Ni和Si在-铁氧体中的扩散系数(、、和)高于相中的扩散系数(、、和),它们有利于第三道熔合区σ相的析出。Vitek扩散方程可以修改为:。
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引用次数: 7
期刊
Journal of Metallurgy
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