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Gold-rare metal and associated mineralization in the western part of Bolshevik Island, Severnaya Zemlya archipelago 地岛群岛布尔什维克岛西部金稀有金属及伴生矿化
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2023-02-27 DOI: 10.31897/pmi.2022.94
A. Evdokimov, V. Fokin, Nikolai Shanurenko
The presented studies are aimed to determine the formation patterns of the gold-rare metal mineralization within one of the most inaccessible Arctic islands of the Russian Federation, Bolshevik Island of the Severnaya Zemlya archipela-go. The relevance of the work is determined by the high probability of discovering a significant in terms of metal reserves deposit, which is proved by many researchers on the example of known large deposits to be a typical feature of sites with gold-rare metal formation. Obviously, only the possibility of discovering and subsequent development of a deposit of a highly liquid type of mineral, gold, can ensure the profitability of mining production on Severnaya Zemlya. It is established that the main geological, mineralogical, and geochemical features of the gold-rare metal mineralization in the Kropotkinsko-Nikitinskaya metallogenic zone of Bolshevik Island correspond to that of similar ore sites in Russia and the world. The occurrences of other formation types revealed in this metallogenic zone suggest a certain zoning in their distribution: mineralization is located in the apical parts of granitoids and in the nearest halo of hornfelses. At a distance, with an exit from the hornfelsed zone, there are occurrences of a cassiterite-sulphide formation with elevated gold and silver content at the top of the ore column, together with an increased amount of polymetallic ores. Occurrences of gold-quartz and gold-sulphide-quartz formations are localized in fault zones, as a rule, farther from granitoids. The total vertical range of gold mineralization exceeds 300 m. The assignment of all types of mineralization in the Kropotkinsko-Nikitinskaya metallogenic zone of Bolshevik Island to a single hydrothermal process is emphasized by the similar isotope composition of lead galena from heterogeneous occurrences, which determines the age of all mineralization at 200-300 Ma.
所提出的研究的目的是确定在俄罗斯联邦最难以到达的北极岛屿之一,塞维尔亚地群岛的布尔什维克岛内金稀有金属矿化的形成模式。这项工作的相关性是由发现一个重要的金属储量矿床的高概率决定的,许多研究人员以已知的大型矿床为例证明,这是具有金-稀有金属形成的地点的典型特征。显然,只有有可能发现并随后开发高流动性矿物——黄金——的矿床,才能确保塞维纳亚地岛采矿生产的盈利能力。确定了布尔什维克岛克鲁泡特金斯科-尼基金斯卡亚成矿带金稀有金属成矿的主要地质、矿物学和地球化学特征与俄罗斯和世界上类似矿点的地质、矿物学和地球化学特征一致。该成矿带其他构造类型的产状显示出一定的分带性:成矿作用位于花岗岩类的顶端和最近的角兽晕。在离角化带较远的地方,有一个出口,矿柱顶部有一个锡石-硫化物地层,金和银含量升高,同时多金属矿数量增加。金-石英和金-硫化物-石英的产状一般分布在离花岗岩较远的断裂带中。金矿化总垂向范围超过300 m。布尔什维克岛Kropotkinsko-Nikitinskaya成矿带所有类型的成矿作用都属于单一的热液作用,来自非均质矿点的铅方铅矿的同位素组成相似,确定了所有成矿作用的年龄在200-300 Ma之间。
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引用次数: 0
Assessment of the possibility of using leucoxene-quartz concentrate as raw material for production of aluminium and magnesium titanates 以亮色英-石英精矿为原料生产钛酸铝、钛酸镁的可能性评价
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2023-02-22 DOI: 10.31897/pmi.2023.15
E. Kuzin, I. Mokrushin, N. Kruchinina
Leucoxene-quartz concentrate is a large-tonnage by-product of development of the Timan oil-titanium field (oil-saturated sandstones) which is not commercially used at present. High content of titanium compounds (to 50 % by weight) and lack of industrial, cost-effective, and safe technologies for its processing determine a high relevance of the work. Conventional processing technologies allow increasing the concentration of TiO2, but they are only a preparation for complex and hazardous selective chlorination. The process of pyrometallurgical conversion of leucoxene-quartz concentrate into aluminium and magnesium titanates was investigated. It was ascertained that the temperature of solid-phase reaction in Al2O3-TiO2-SiO2 system necessary for the synthesis of aluminium titanate (Al2TiO5) is 1,558 °С, and for MgO-TiO2-SiO2 system – 1,372 °С. Scaling up the process made it possible to synthesize a significant number of samples of titanate-containing products, the phase composition of which was studied by X-ray phase analysis. Two main phases were identified in the products: 30 % aluminium/magnesium titanate and 40 % silicon dioxide. In products of pyrometallurgical processing in the presence of aluminium, phases of pseudobrookite (3.5 %) and titanite (0.5 %) were also found. It was ascertained that in magnesium-containing system the formation of three magnesium titanates is possible: MgTiO3 – 25, Mg2TiO4 – 35, MgTi2O5 – 40 %. Experiments on sulphuric acid leaching of samples demonstrated a higher degree of titanium compounds extraction during sulphuric acid processing. An integrated conceptual scheme for processing leucoxene-quartz concentrate to produce a wide range of potential products (coagulants, catalysts, materials for ceramic industry) was proposed.
亮绿英-石英精矿是提曼油-钛油田(含油砂岩)开发的大吨位副产物,目前尚未商品化。钛化合物的高含量(占重量的50%)和缺乏工业、成本效益和安全的加工技术决定了这项工作的高度相关性。传统的处理技术可以增加TiO2的浓度,但它们只是为复杂和危险的选择性氯化做准备。研究了辉绿石英精矿火法转化钛酸铝、钛酸镁的工艺。确定了合成钛酸铝(Al2TiO5)所需的固相反应温度为1558°С,合成MgO-TiO2-SiO2体系所需的固相反应温度为1372°С。扩大工艺规模可以合成大量的含钛酸盐产品样品,并通过x射线相分析研究了其相组成。在产品中确定了两种主要相:30%钛酸铝/镁和40%二氧化硅。在有铝存在的火法冶炼产品中,还发现了假绿铜矿(3.5%)和钛矿(0.5%)相。确定了在含镁体系中可以形成三种钛酸镁:MgTiO3 - 25、Mg2TiO4 - 35、MgTi2O5 - 40%。对样品的硫酸浸出实验表明,在硫酸处理过程中,钛化合物的提取率较高。提出了一种综合处理二苯二烯-石英精矿的概念方案,以生产广泛的潜在产品(混凝剂、催化剂、陶瓷工业材料)。
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引用次数: 0
Microbiological remediation of oil-contaminated soils 石油污染土壤的微生物修复
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2023-02-16 DOI: 10.31897/pmi.2023.8
I. Sozina, A. Danilov
Microbiological remediation is a promising technology for the elimination of environmental contamination by oil and petroleum products, based on the use of the metabolic potential of microorganisms. The issue of environmental contamination by crude oil and its refined products is relevant in the Russian Federation since the oil industry is one of the leading sectors of the country. Mechanical and physico-chemical methods of treatment are widely used to clean oil-contaminated soils. However, the methods belonging to these groups have a number of significant drawbacks, which actualizes the development of new methods (mainly biological), since they are more environmentally friendly, cost-effective, less labor-intensive, and do not require the use of technical capacities. Various bio-based products based on strains and consortia of microorganisms have been developed that have proven effectiveness. They include certain genera of bacteria, microscopic fungi, and microalgae, substances or materials acting as sorbents of biological agents and designed to retain them in the soil and increase the efficiency of bioremediation, as well as some nutrients. Statistical data, the most effective methods, and technologies, as well as cases of using microorganisms to restore oil-contaminated soils in various climatic conditions are presented.
微生物修复是一种很有前途的技术,用于消除石油和石油产品对环境的污染,基于微生物的代谢潜力的利用。原油及其精炼产品污染环境的问题与俄罗斯联邦有关,因为石油工业是该国的主要部门之一。机械和物理化学处理方法被广泛应用于石油污染土壤的清洁。然而,属于这些群体的方法有一些明显的缺点,这使新方法(主要是生物方法)的发展成为现实,因为它们对环境更友好、成本效益高、劳动密集程度低,并且不需要使用技术能力。基于菌株和微生物联合体的各种生物基产品已被开发出来,并已证明有效。它们包括某些属的细菌、微真菌和微藻、作为生物制剂吸附剂的物质或材料,旨在将它们保留在土壤中并提高生物修复的效率,以及一些营养物质。介绍了统计数据,最有效的方法和技术,以及在各种气候条件下利用微生物恢复石油污染土壤的案例。
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引用次数: 2
Composite model of seismic monitoring data analysis during mining operations on the example of the Kukisvumchorrskoye deposit of AO Apatit 以AO Apatit Kukisvumchorrskoye矿床为例,采矿过程中地震监测数据分析的复合模型
Q1 Earth and Planetary Sciences Pub Date : 2023-02-16 DOI: 10.31897/pmi.2023.9
Alexander Gospodarikov, Ilia Revin, Konstantin Morozov
Geomechanical monitoring of the rock mass state is an actively developing branch of geomechanics, in which it is impossible to distinguish a single methodology and approaches for solving problems, collecting and analyzing data when developing seismic monitoring systems. During mining operations, all natural factors are subject to changes. During the mining of a rock mass, changes in the state of structural inhomogeneities are most clearly manifested: the existing natural structural inhomogeneities are revealed; there are movements in discontinuous disturbances (faults); new man-made disturbances (cracks) are formed, which are accompanied by changes in the natural stress state of various blocks of the rock mass. The developed method for evaluating the results of monitoring geomechanical processes in the rock mass on the example of the United Kirovsk mine of the CF AO Apatit allowed to solve one of the main tasks of the geomonitoring system – to predict the location of zones of possible occurrence of dangerous manifestations of rock pressure.
岩体状态的地质力学监测是地质力学的一个积极发展的分支,在开发地震监测系统时,不可能区分单一的方法和方法来解决问题,收集和分析数据。在采矿作业中,所有的自然因素都会发生变化。在岩体开采过程中,结构不均匀性状态的变化最为明显:现有的天然结构不均匀性被揭示出来;在不连续的扰动(断层)中有运动;新的人为扰动(裂缝)形成,伴随着岩体各块体自然应力状态的变化。以CF AO Apatit的联合基洛夫斯克矿为例,所开发的评估岩体地质力学过程监测结果的方法解决了地质监测系统的主要任务之一-预测可能发生岩石压力危险表现的区域的位置。
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引用次数: 0
Uranium in man-made carbonates on the territory of Ufa 乌法境内人造碳酸盐中的铀
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2023-01-26 DOI: 10.31897/pmi.2023.4
I. Farkhutdinov, R. Khayrullin, B. Soktoev, A. Zlobina, E. Chesalova, A. Farkhutdinov, A. Tkachev
The paper presents the results of analyzing uranium content in man-made carbonates (scale crusts) on the territory of Ufa based on examination of 42 samples. The median uranium content in the investigated samples stands at 1.44 mg/kg, which is significantly lower than the background values (scales from the Lake Baikal water, a clarke of sedimentary carbonate rocks) and data on other settlements of the Republic of Bashkortostan. Low values of uranium content are probably associated with the effects of the three leading factors, i.e. specific subsurface geology of the territory (gypsum, limestone); types of water supply; water treatment processes for the centralized type of water supply. Spatial distribution of uranium in man-made carbonates is characterized with uniformity, which is disturbed in two cases, i.e. a change of the water supply type (from centralized to individual); and material of the vessels used for boiling the water. No significant differences were detected when comparing samples of man-made carbonates associated with different sources of water supply (the bucket and infiltration types of water intake) and the types of household filters.
本文介绍了对乌法境内42个人工碳酸盐(结垢)样品的铀含量分析结果。所调查样品中铀含量的中位数为1.44毫克/公斤,大大低于背景值(贝加尔湖水的尺度,沉积碳酸盐岩的clarke)和巴什科尔托斯坦共和国其他定居点的数据。铀含量的低值可能与三个主要因素的影响有关,即领土的特定地下地质(石膏、石灰石);供水类型;水处理工艺为集中式供水。人工碳酸盐中铀的空间分布具有均匀性,但在两种情况下受到干扰,即供水类型的变化(从集中到个别);以及用来烧开水的容器的材料。在比较与不同供水来源(桶式和渗透式取水方式)和家用过滤器类型相关的人造碳酸盐样本时,未发现显著差异。
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引用次数: 1
Production of biodiesel fuel from vegetable raw materials 以植物为原料生产生物柴油
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2023-01-23 DOI: 10.31897/pmi.2022.15
N. Kondrasheva, A. Eremeeva
One way to reduce the amount of harmful emissions from diesel fuel could be the replacement of part of the fuel with biofuel. Research is related to the production of biodiesel fuel in three ways: transesterification of vegetable oils; esterification of fat acids extracted from vegetable oil; and hydroprocessing of vegetable oils using catalysts in the diesel hydrotreatment process. Food and non-food oils, monatomic and diatomic alcohols were used to produce biodiesel fuel. Optimal parameters of vegetable oil transesterification have been determined: temperature; raw material ratio (oil/alcohol); mixing speed; time; type of process catalyst. The characteristics of the obtained biodiesel fuel samples were studied and compared with each other as well as with the requirements of EN 14214 “Automotive fuels. Fat acid methyl ethers for diesel engines. General technical requirements” and EN 590:2009 “EURO diesel fuel. Technical specifications”. With regard to the physical and chemical characteristics of biodiesel fuel, the best way to produce it is by transesterification of vegetable oils. However, all fuels can be used as components of a blended environmentally friendly diesel fuel.
减少柴油有害排放物的一种方法是用生物燃料替代部分燃料。与生物柴油燃料生产有关的研究有三种途径:植物油酯交换法;植物油中脂肪酸的酯化反应研究并在柴油加氢处理过程中使用催化剂对植物油进行加氢处理。食用油和非食用油、单原子醇和双原子醇被用于生产生物柴油燃料。确定了植物油酯交换反应的最佳工艺参数:温度;原料比(油/醇);搅拌速度;时间;工艺催化剂类型。研究了所得生物柴油燃料样品的特性,并与EN 14214“汽车燃料”的要求进行了比较。柴油发动机用脂肪酸甲基醚。通用技术要求”和EN 590:2009“欧洲柴油燃料”。技术规格”。考虑到生物柴油燃料的物理化学特性,最好的生产方法是植物油酯交换反应。然而,所有的燃料都可以作为混合环保柴油燃料的组成部分。
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引用次数: 11
Parameter determination of the method of directional unloading of the reservoir based on physical modelling on a true triaxial loading setup 基于真三轴加载物理模拟的储层定向卸载方法参数确定
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2022-12-30 DOI: 10.31897/pmi.2022.95
V. Karev, Yuri Kovalenko, V. Khimulia, N. Shevtsov
The article presents a theoretical and experimental substantiation of the method of directional unloading of the reservoir in fields with low-permeability reservoirs. The relevance of the article is due to the reduction of hydrocarbon resources in modern conditions and the need to create new efficient environmentally friendly technologies to develop hydrocarbon deposits with hard-to-recover reserves, primarily with low-permeability reservoirs. The results of a theoretical study of the stress-strain state in the vicinity of a well, both cased and open, are presented. They are necessary to develop programs for laboratory testing of core specimens from the studied fields. A technique for physical modelling of deformation processes in the bottomhole zone with a decrease in pressure at the well bottom in a true triaxial loading unit is described in order to determine the parameters of the process impact on the formation reservoir, leading to an increase in well productivity. The method was applied to the conditions of the low-permeability reservoir at the Verkhneviluchanskoye oil and gas condensate field in the southwest of the Republic of Sakha (Yakutia). Expe-rimental studies were carried out on a unique scientific unit for true triaxial loading, created at the IPMech RAS, the Triaxial Independent Loading Test System. The directional unloading method was adapted for the studied field, the process parameters of successful application of the method were determined: the bottomhole design, the drawdown values necessary to increase the permeability of the bottomhole formation zone.
本文对低渗透油藏定向卸荷方法进行了理论和实验验证。这篇文章的相关性是由于现代条件下碳氢化合物资源的减少,需要创造新的高效环保技术来开发储量难以开采的碳氢化合物矿床,主要是低渗透油藏。本文介绍了套管和裸眼井附近应力-应变状态的理论研究结果。它们对于制定研究地区岩心标本的实验室测试程序是必要的。描述了一种在真三轴加载装置中井底压力降低时,对井底区域的变形过程进行物理建模的技术,以确定该过程对地层储层的影响参数,从而提高油井产能。将该方法应用于萨哈共和国(雅库特)西南部Verkhneviluchanskoye凝析油气田的低渗透储层条件。实验研究是在IPMech RAS(三轴独立加载测试系统)创建的真正三轴加载的独特科学单元上进行的。针对所研究的油田,采用定向卸载方法,确定了该方法成功应用的工艺参数:井底设计、提高井底储层渗透率所需的压降值。
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引用次数: 0
Determination of suitable distance between methane drainage stations in Tabas mechanized coal mine (Iran) based on theoretical calculations and field investigation 基于理论计算和实地考察的伊朗Tabas机械化煤矿甲烷排气站间适宜距离的确定
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2022-12-30 DOI: 10.31897/pmi.2022.106
A. Hosseini, Mehdi Najafi, A. Morshedy
A large amount of gas is emitted during underground mining processes, so mining productivity decreases and safety risks increase. Efficient methane drainage from the coal seam and surrounding rocks in underground mines not only improves safety but also leads to higher productivity. Methane drainage must be performed when the ventilation air cannot dilute the methane emissions in the mine to a level below the allowed limits. The cross-measure borehole method is one of the methane drainage methods that involves drilling boreholes from the tailgate roadway to an un-stressed zone in the roof or floor stratum of a mined seam. This is the main method used in Tabas coal mine N 1. One of the effective parameters in this method is the distance between methane drainage stations, which has a direct effect on the length of boreholes required for drainage. This study was based on the measurement of ventilation air methane by methane sensors and anemometers placed at the longwall panel as well as measuring the amount of methane drainage. Moreover, in this study, the obtained and analyzed data were used to determine the suitable distance between methane drainage stations based on the cross-measure borehole method. In a field test, three borehole arrangements with different station distances in Panel E4 of Tabas coal mine N 1 were investigated. Then, the amounts of gas drained from these arrangements were compared with each other. The highest methane drainage efficiency was achieved for distances in the range of 9-12 m between methane drainage stations.
地下开采过程中产生大量瓦斯,降低了开采生产率,增加了安全隐患。有效地从地下矿井的煤层和围岩中抽放瓦斯,不仅提高了安全生产,而且提高了生产效率。当通风空气不能将矿井的甲烷排放稀释到允许限度以下时,必须进行甲烷排放。交叉钻孔法是一种瓦斯抽放方法,它从尾板巷道向煤层顶板或底板地层的无应力区钻孔。这是塔巴斯1号煤矿采用的主要方法。该方法的有效参数之一是甲烷排气站之间的距离,它直接影响排气站所需钻孔的长度。本研究通过放置在长壁板上的甲烷传感器和风速计测量通风空气中的甲烷,并测量甲烷排放量。此外,本研究还利用获取和分析的数据,基于交叉测量钻孔法确定甲烷排气站之间的合适距离。在现场试验中,对塔巴斯1矿E4盘3个不同站位距离的钻孔布置进行了研究。然后,从这些布置中排出的气体量相互比较。甲烷排水站之间距离为9 ~ 12 m时,甲烷排采效率最高。
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引用次数: 2
Autoclave modeling of corrosion processes occurring in a gas pipeline during transportation of an unprepared multiphase medium containing CO2 高压灭菌器模拟含CO2的未准备多相介质在输气管道中发生的腐蚀过程
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2022-12-30 DOI: 10.31897/pmi.2022.92
N. Shaposhnikov, I. Golubev, S. Khorobrov, Alexander Kolotiy, A. Ioffe, V. Revyakin
The problem of selecting a method for ensuring the reliability of the unprepared fluid transport facilities of an unprepared fluid in the presence of carbon dioxide is considered. Carbon dioxide corrosion is one of the dangerous types of damage to field and main pipelines. It has been shown that dynamic autoclave tests should be carried out during staged laboratory tests in order to determine the intensity of carbon dioxide corrosion and to select the optimal method of protection. A hypothesis about the imperfection of the existing generally accepted approaches to dynamic corrosion testing has been put forward and confirmed. A test procedure based on the use of an autoclave with an overhead stirrer, developed using elements of mathematical modeling, is proposed. The flows created in the autoclave provide corrosive wear of the sample surface similar to the internal surfaces elements wear of the pipelines piping of gas condensate wells. The autoclave makes it possible to simulate the effect of the organic phase on the flow rate and the nature of corrosion damage to the metal surface, as well as the effect of the stirrer rotation speed and, accordingly, the shear stress of the cross section on the corrosion rate in the presence/absence of a corrosion inhibitor. The given results of staged tests make it possible to judge the high efficiency of the developed test procedure.
考虑了在存在二氧化碳的情况下,选择一种方法来保证未准备流体的未准备流体输送设施的可靠性的问题。二氧化碳腐蚀是油田和主要管道的危险破坏类型之一。为了确定二氧化碳腐蚀的强度和选择最佳的保护方法,应在分阶段的实验室试验中进行动态高压灭菌器试验。提出并证实了现有普遍接受的动态腐蚀试验方法的不完全性。提出了一种基于使用带有顶置搅拌器的高压灭菌器的测试程序,并利用数学建模的元素进行了开发。在高压灭菌器中产生的流动对样品表面造成腐蚀性磨损,类似于凝析气井管道的内部表面元件磨损。高压灭菌器可以模拟有机相对流速的影响和金属表面腐蚀损伤的性质,以及搅拌器转速的影响,相应地,在存在/不存在缓蚀剂的情况下,截面的剪切应力对腐蚀速率的影响。阶段测试的给定结果可以判断所开发的测试程序的高效率。
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引用次数: 0
Estimation of the influence of fracture parameters uncertainty on the dynamics of technological development indicators of the Tournaisian-Famennian oil reservoir in Sukharev oil field 苏哈列夫油田图尔纳—法门尼期油藏裂缝参数不确定性对技术开发指标动态影响的估算
IF 2 Q1 Earth and Planetary Sciences Pub Date : 2022-12-30 DOI: 10.31897/pmi.2022.102
Aleksanr Kochnev, N. Kozyrev, S. Krivoshchekov
Issues related to the influence of reservoir properties uncertainty on oil field development modelling are considered. To increase the reliability of geological-hydrodynamic mathematical model in the course of multivariate matching, the influence of reservoir properties uncertainty on the design technological parameters of development was estimated, and their mutual influence was determined. The optimal conditions for the development of the deposit were determined, and multivariate forecasts were made. The described approach of history matching and calculation of the forecast of technological development indicators allows to obtain a more reliable and a less subjective history match as well as to increase the reliability of long-term and short-term forecasts.
考虑了油藏性质不确定性对油田开发建模的影响。为提高多元拟合过程中地质-水动力数学模型的可靠性,评估了储层物性不确定性对开发设计工艺参数的影响,确定了它们之间的相互影响。确定了矿床发育的最佳条件,并进行了多元预测。所描述的历史匹配和技术发展指标预测的计算方法可以获得更可靠和较少主观的历史匹配,并提高长期和短期预测的可靠性。
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引用次数: 1
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Journal of Mining Institute
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