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Photochemical Water Oxidation Using {PMo12O40@Mo72Fe30}n Based Soft Oxometalate 基于{PMo12O40@Mo72Fe30}n的软金属氧酸盐光化学水氧化
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317500010
Santu Das, Soumyajit Roy
Finding an alternative energy resource which can produce clean energy at a low cost is one of the major concerns of our times. The conversion of light energy into chemical energy is one key step forward in the direction. With that end in view photochemical water oxidation to produce oxygen plays a crucial role. In the present paper we have synthesized a soft oxometalate {PMo12O40@Mo72Fe30}n(1) from its well-known precursor polyoxometalate constituent [Muller et al., Chem. Commun. 1, 657 (2001)]. It is known that in the matter of catalysis, high surface area, possibility of heterogenization, recoverability makes soft oxometalates (SOMs) attractive as catalytic materials. Here we exploit such advantages of SOMs. The SOM based material acts as an active catalyst for photochemical water oxidation reaction with a maximum turnover number of 20256 and turnover frequency of 24.11min−1. The catalyst material is stable under photochemical reaction conditions and therefore can be reused for multiple photo catalytic water oxidation reaction cycles.
寻找一种能够以低成本生产清洁能源的替代能源是我们时代的主要关切之一。将光能转化为化学能是朝着这个方向迈出的关键一步。有鉴于此,光化学水氧化产生氧气起着至关重要的作用。在本文中,我们合成了一种软的含氧金属盐{PMo12O40@Mo72Fe30}n(1) 由其众所周知的前体多金属氧酸盐组分[Muller等人,Chem.Commun.1657(2001)]制备。众所周知,在催化方面,高表面积、多相化的可能性、可回收性使软金属氧化合物(SOMs)作为催化材料具有吸引力。在这里,我们利用SOM的这些优势。SOM基材料作为光化学水氧化反应的活性催化剂,最大周转数为20256,周转频率为24.11min−1。催化剂材料在光化学反应条件下是稳定的,因此可以重复用于多个光催化水氧化反应循环。
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引用次数: 4
Antibacterial Drug Releasing Materials by Post-Polymerization Surface Modification 聚合后表面改性的抗菌药物释放材料
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317400056
Shuyun Chng, M. Moloney, L. Wu
Functional materials are available by the post-polymerization surface modification of diverse polymers in a three-step process mediated, firstly, by carbene insertion chemistry, secondly, by diazonium coupling, and thirdly by modification with a remotely tethered spiropyran unit, and these materials may be used for the reversible binding and release of Penicillin V. Surface loading densities of up to 0.19mmol/g polymer are achievable, leading to materials with higher loading densities and release behavior relative to unmodified controls, and observable antibacterial biocidal activity.
功能材料可通过三步过程对不同聚合物进行聚合后表面改性获得,首先通过卡宾插入化学,其次通过重氮偶联,第三通过用远程连接的螺吡喃单元进行改性,这些材料可用于青霉素V的可逆结合和释放。可实现高达0.19mmol/g聚合物的表面负载密度,从而使材料相对于未改性的对照具有更高的负载密度和释放行为,并具有可观察到的抗菌杀生物活性。
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引用次数: 2
Effect of Ambient Temperature on Hydrophobic Recovery Behavior of Silicone Rubber Composites 环境温度对硅橡胶复合材料疏水恢复性能的影响
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317500034
Xiangyang Peng, Li Zijian, Feng Zheng, Ni Zhang, Zhen Huang, P. Fang
A series of silicone rubber samples with different cyclosiloxanes contents have been successfully prepared, and their hydrophobic recovery behaviors and mechanism were investigated in detail. The gas chromatography-mass spectroscopy technique after Soxhlet extraction was utilized to examine the low molecular weight siloxanes in the sample, SEM was used to observe the surface morphology of the silicone rubber influenced by plasma treatment, and contact angle measurement was applied to probe the hydrophobic recovery of the sample surface after plasma treatment at different storage temperatures. The storage time-dependent contact angle of water can be well fitted by the diffusion model calculated from Fick’s second law. The results imply that the hydrophobic recovery of silicone rubber is related to the diffusion of low molecular weight siloxanes, while larger content or higher temperature can induce faster hydrophobic recovery.
成功制备了一系列不同环硅氧烷含量的硅橡胶样品,并对其疏水回收行为和机理进行了详细的研究。利用索氏提取后的气相色谱-质谱技术检测样品中的低分子量硅氧烷,并应用接触角测量来探测在不同储存温度下等离子体处理后样品表面的疏水性恢复。根据Fick第二定律计算的扩散模型可以很好地拟合水的储存时变接触角。结果表明,硅橡胶的疏水性恢复与低分子量硅氧烷的扩散有关,而含量越大或温度越高,疏水性恢复越快。
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引用次数: 2
Eigenvalue Approach in a Generalized Thermal Shock Problem for a Transversely Isotropic Half-Space 横观各向同性半空间广义热冲击问题的特征值法
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317500022
I. Abbas, A. Hobiny
In the present work, the investigating of the disturbances in a homogeneous, transversely isotropic elastic medium with generalized thermoelastic theory has been concerned. The formulation is applied to generalized thermoelasticity based on three different theories. Laplace and Fourier transforms are used to solve the problem analytically. The essential equations have been written as a vector-matrix differential equation in the Laplace transform domain, then solved by an eigenvalue approach. The inverses of Fourier transforms are obtained analytically. The result is used to solve a specific two-dimensional problem. The technique is illustrated by means of several numerical experiments performed. The results were verified numerically and are plotted.
在本工作中,用广义热弹性理论研究了均匀、横向各向同性弹性介质中的扰动。基于三种不同的理论,将该公式应用于广义热弹性力学。拉普拉斯变换和傅立叶变换被用来解析地解决这个问题。基本方程被写成拉普拉斯变换域中的向量矩阵微分方程,然后用特征值法求解。解析地得到了傅立叶变换的逆。该结果用于解决特定的二维问题。通过几个数值实验对该技术进行了说明。对结果进行了数值验证并绘制了图表。
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引用次数: 1
Cyclodextrins: A Weapon in the Fight Against Antimicrobial Resistance 环糊精:对抗抗菌素耐药性的武器
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317400068
C. Wong, A. Dolzhenko, Sui-Mae Lee, D. Young
Antimicrobial resistance poses one of the most serious global challenges of our age. Cyclodextrins (CDs) are widely utilized excipients in formulations because of their solubilizing properties, low toxicity, and low inflammatory response. This review summarizes recent investigations of antimicrobial agents involving CDs and CD-based antimicrobial materials. CDs have been employed for antimicrobial applications either through formation of inclusion complexes or by chemical modification of their hydroxyl groups to tailor pharmaceutically active compounds. Applications of these CD inclusion complexes include drug delivery, antimicrobial coatings on materials (e.g., biomedical devices and implants) and antimicrobial dressings that help to prevent wound infections. There are relatively limited studies of chemically modified CDs with antimicrobial activity. The mechanism of action of antimicrobial CD inclusion complexes and derivatives needs further elucidation, but activity of CDs and their derivatives is often associated with their interaction with bacterial cell membranes.
抗菌素耐药性是我们这个时代最严重的全球性挑战之一。环糊精(CDs)因其增溶性、低毒性和低炎症反应而被广泛应用于配方辅料中。本文综述了近年来涉及cd和基于cd的抗菌材料的抗菌剂的研究进展。通过形成包合物或通过对其羟基进行化学修饰以定制具有药物活性的化合物,CDs已被用于抗菌应用。这些CD包合物的应用包括药物递送、材料上的抗菌涂层(例如,生物医学设备和植入物)和有助于预防伤口感染的抗菌敷料。对具有抗菌活性的化学修饰CDs的研究相对有限。抗菌CD包合物及其衍生物的作用机制有待进一步阐明,但CD及其衍生物的活性通常与它们与细菌细胞膜的相互作用有关。
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引用次数: 5
Effect of Ruthenium Concentration on Structural and I-V Characteristics of ZnO Thin Films by Sol–Gel Method 钌浓度对溶胶-凝胶法制备ZnO薄膜结构和I-V特性的影响
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317500046
R. Vettumperumal, S. Kalyanaraman, R. Thangavel
Nanocrystalline ruthenium (Ru)-doped ZnO thin films on sapphire substrate was prepared using sol–gel method by spin coating technique. The structural and I-V characteristics of Ru doped ZnO thin films were studied from the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) analysis and Raman spectroscopy. X-ray diffraction (XRD) results revealed that the deposited films belonged to hexagonal wurtzite structure with c-axis orientation. It is also confirmed from the Raman spectra. Enhancement of longitudinal optical (LO) phonon is observed by the strong electron–phonon interaction. An observed increment in sheet resistance with increase in dopant percentage of Ru (1–2mol%) in ZnO films was found and better I-V characteristic behavior was observed at 1mol% of Ru-doped ZnO thin films. Trap limited current flow inside the material was calculated from the log I versus log V plot in the higher voltage region.
采用溶胶-凝胶法,采用旋涂技术在蓝宝石衬底上制备了纳米钌掺杂ZnO薄膜。通过X射线衍射(XRD)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)和拉曼光谱研究了Ru掺杂ZnO薄膜的结构和I-V特性。X射线衍射(XRD)结果表明,沉积的薄膜属于c轴取向的六方纤锌矿结构。拉曼光谱也证实了这一点。通过强电子-声子相互作用观察到纵向光学(LO)声子的增强。发现随着Ru在ZnO薄膜中的掺杂百分比(1–2mol%)的增加,观察到薄层电阻的增加,并且在1mol%的Ru掺杂ZnO薄膜中观察到更好的I-V特性。根据较高电压区域中log I与log V的关系图计算材料内部的陷阱限制电流。
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引用次数: 2
Latest Advances in Antibacterial Materials 抗菌材料的最新进展
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-07-27 DOI: 10.1142/S2251237317400019
X. Loh
This paper will update readers on the latest work in the area of antibacterial polymeric systems. There is extensive literature on existing systems. This complexity confines us to the latest antibacterial materials which possess (1) responsive antibacterial activity on their own; (2) anti-biofilm formation and (3) formation of antibacterial polymeric films. The objective of this review is to provide an overview of the antibacterial synthetic polymer field. In this paper, I will analyze the early promise of this technology as well as highlight potential challenges that adopters could face. The primary focus will be the application of materials to the medical industry and to show how these materials can be tailored to create responsive, customized bactericidal materials.
本文将向读者介绍抗菌聚合物系统领域的最新工作。有大量关于现有系统的文献。这种复杂性将我们局限于最新的抗菌材料,这些材料本身具有(1)响应性抗菌活性;(2) 抗生物膜形成和(3)抗菌聚合物膜的形成。本综述的目的是对抗菌合成聚合物领域进行综述。在本文中,我将分析这项技术的早期前景,并强调采用者可能面临的潜在挑战。主要重点将是材料在医疗行业的应用,并展示如何对这些材料进行定制,以创造出响应灵敏、定制的杀菌材料。
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引用次数: 20
Four-Dimensional (4D) Printing: Applying Soft Adaptive Materials to Additive Manufacturing 四维(4D)打印:将软适应性材料应用于增材制造
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-03-16 DOI: 10.1142/S2251237317400032
Zibiao Li, X. Loh
Four-dimensional (4D) printing is an up-and-coming technology for the creation of dynamic devices which have shape changing capabilities or on-demand capabilities over time. Through the printing of adaptive 3D structures, the concept of 4D printing can be realized. Modern manufacturing primarily utilizes direct assembly techniques, limiting the possibility of error correction or instant modification of a structure. Self-building, programmable physical materials are interesting for the automatic and remote construction of structures. Adaptive materials are programmable physical or biological materials which possess shape changing properties or can be made to have simple logic responses. There is immense potential in having disorganized fragments form an ordered construct through physical interactions. However, these are currently limited to only self-assembly at the smallest scale, typically at the nanoscale. The answer to customizable macro-structures is in additive manufacturing, or 3D printing. 3D printing is a 30 years old technology which is beginning to be widely used by consumers. However, the main gripes about this technology are that it is too inefficient, inaccessible, and slow. Cost is also a significant factor in the adoption of this technology. 3D printing has the potential to transform and disrupt the manufacturing landscape as well as our lives. 4D printing seeks to use multi-functional materials in 3D printing so that the printed structure has multiple response capabilities and able to self-assemble on the macroscale. In this paper, we will analyze the early promise of this technology as well as to highlight potential challenges that adopters could face. The primary focus will be to have a look at the application of materials to 3D printing and to show how these materials can be tailored to create responsive customized 4D structures.
四维(4D)打印是一种新兴技术,用于创建具有随时间变化的形状或按需功能的动态设备。通过自适应3D结构的打印,可以实现4D打印的概念。现代制造主要利用直接组装技术,限制了结构纠错或即时修改的可能性。自行构建、可编程的物理材料对结构的自动化和远程施工很有兴趣。自适应材料是可编程的物理或生物材料,具有改变形状的特性或可以使其具有简单的逻辑响应。无组织的碎片通过物理相互作用形成有序结构具有巨大的潜力。然而,这些目前仅限于最小规模的自组装,通常是在纳米级。可定制宏结构的答案是在增材制造或3D打印中。3D打印是一项已有30年历史的技术,正开始被消费者广泛使用。然而,对这项技术的主要抱怨是它效率太低、无法访问和速度太慢。成本也是采用这项技术的一个重要因素。3D打印有可能改变和颠覆制造业和我们的生活。4D打印寻求在3D打印中使用多功能材料,使得打印的结构具有多种响应能力并且能够在宏观尺度上自组装。在本文中,我们将分析这项技术的早期前景,并强调采用者可能面临的潜在挑战。主要重点将是了解材料在3D打印中的应用,并展示如何对这些材料进行定制,以创建响应性定制的4D结构。
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引用次数: 10
Liquid Resins-Based Additive Manufacturing 液体树脂增材制造
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-03-07 DOI: 10.1142/S2251237317400044
Fei Wang, Fuke Wang
In this review, additive manufacturing technologies using liquid resins as materials are reviewed from the perspective of printing technologies and materials. Most importantly, recent progress of new printing technologies and printers as well as novel printing materials and their applications are summarized, based on which potential future research directions are discussed at the end of this review.
本文从印刷技术和材料的角度综述了以液体树脂为材料的增材制造技术。最重要的是,综述了新印刷技术和打印机的最新进展,以及新型印刷材料及其应用,并在此基础上讨论了未来潜在的研究方向。
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引用次数: 14
3D Printing of Biosamples: A Concise Review 生物样品的3D打印:简明综述
IF 1.5 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2017-01-22 DOI: 10.1142/S2251237317400020
Victoria X. Zhao, T. I. Wong, Xiaodong Zhou
This paper reviews the recent development of 3D printing of biosamples, in terms of the 3D structure design, suitable printing technology, and available materials. Successfully printed 3D biosamples should possess the properties of high cell viability, vascularization and good biocompatibility. These goals are attained by printing the materials of hydrogels, polymers and cells, with a carefully selected 3D printer from the categories of inkjet printing, extrusion printing and laser printing, based on the uniqueness, advantages and disadvantages of these technologies. For recent developments, we introduce the 3D applications of creating scaffolds, printing cells for self-assembly and testing platforms. We foresee more bio-applications of 3D printing will be developed, with the advancements on materials and 3D printing machines.
本文从生物样品的三维结构设计、合适的打印技术和可用的材料等方面综述了生物样品三维打印的最新进展。成功打印的3D生物样品应具有高细胞活力、血管化和良好的生物相容性。这些目标是通过使用从喷墨打印、挤出打印和激光打印类别中精心选择的3D打印机打印水凝胶、聚合物和细胞的材料来实现的,基于这些技术的独特性、优点和缺点。关于最近的发展,我们介绍了创建支架、打印自组装细胞和测试平台的3D应用。我们预计,随着材料和3D打印机器的进步,3D打印的更多生物应用将得到发展。
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引用次数: 1
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Journal of Molecular and Engineering Materials
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