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A general relativistic kinetic theory approach to linear transport in generic hydrodynamic frame 一般流体动力系中线性输运的广义相对论动力学方法
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-04-09 DOI: 10.1515/jnet-2024-0024
Long Cui, Xin Hao, Liu Zhao
In this study, we investigate the linear transport of neutral system within the framework of relativistic kinetic theory. Under the relaxation time approximation, we obtain an iterative solution to the relativistic Boltzmann equation in generic stationary spacetime. This solution provides a scheme to study non-equilibrium system order by order. Our calculations are performed in generic hydrodynamic frame, and the results can be reduced to a specific hydrodynamic frame by imposing constraints. As a specific example, we analytically calculated the covariant expressions of the particle flow and the energy momentum tensor up to the first order in relaxation time. Finally and most importantly, we present all 14 kinetic coefficients for a neutral system, which are verified to satisfy the Onsager reciprocal relation in a generic hydrodynamic frame and guarantee a non-negative entropy production in the frame where the first order conservation laws are restored.
在本研究中,我们在相对论运动理论的框架下研究了中性系的线性输运。在松弛时间近似下,我们得到了广义静止时空中相对论玻尔兹曼方程的迭代解。该解提供了一种逐级研究非平衡系统的方案。我们的计算是在一般的水动力框架下进行的,通过施加约束,结果可以简化为特定的水动力框架。作为一个具体的例子,我们解析地计算了粒子流和能量动量张量在松弛时间上的一阶协变表达式。最后,最重要的是,我们给出了一个中性系统的所有14个动力学系数,并证明了它们在一般流体动力系中满足Onsager互反关系,并保证了在恢复一阶守恒律的系中产生非负熵。
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引用次数: 0
Optimization of injection parameters, and ethanol shares for cottonseed biodiesel fuel in diesel engine utilizing artificial neural network (ANN) and taguchi grey relation analysis (GRA) 基于人工神经网络(ANN)和田口灰关联分析(GRA)的棉籽生物柴油柴油喷射参数及乙醇份额优化
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-03-13 DOI: 10.1515/jnet-2024-0095
G. Praveen Kumar Yadav, Pullarao Muvvala, R. Meenakshi Reddy
The increase of fossil fuel powered industrial processes and vehicles has resulted in the exhaustion of petroleum reserves and pollution of the environment. Because of its clean-burning, renewable, and biodegradable qualities, biodiesel is becoming more and more recognized as a potential diesel fuel alternative. The present study investigates engine performance and emission characteristics of cottonseed oil (CSBD20) and diesel blends tested on single-cylinder compression ignition engine by several injection timings, injection pressures, and ethanol shares. Performance parameters such as brake thermal efficiency (BTE), brake-specific fuel consumption (BSFC), exhaust emissions such as hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NO x ), carbon dioxide (CO2), and smoke were considered as output factors, considering injection timing (IT), ethanol share (ES), injection pressure (IP) as input factors utilizing artificial neural network (ANN) and taguchi grey relation analysis (GRA). The ANN model accurately predicts the input-output relationships of ethanol and cottonseed biodiesel blends, as validated by experimental comparisons. The predicted values for BTE, BSFC, HC, CO, NO x , and smoke show close alignment with experimental results, with marginal errors of 6.2 %, 2.8 %, 7.1 %, 4.7 %, 6.8 %, and 5.6 %, respectively, confirming its reliability. In addition, this study utilized Taguchi grey relational analysis (GRA) to find optimum engine operating conditions. The analysis revealed that the optimal engine operating conditions were IT at 27° CA bTDC, ES at 15 %, and IP at 200 bar. Furthermore, confirmation tests are also conducted at optimum operating conditions, and the revealed values are closer to taguchi GRA experiments and ANN predicted values.
化石燃料驱动的工业过程和车辆的增加导致了石油储量的枯竭和环境的污染。由于其清洁燃烧、可再生和可生物降解的特性,生物柴油越来越被认为是一种潜在的柴油替代品。在单缸压缩点火发动机上,通过不同的喷射时间、喷射压力和乙醇份额,研究了棉籽油(CSBD20)和柴油混合物的发动机性能和排放特性。利用人工神经网络(ANN)和田口灰色关联分析(GRA),将制动热效率(BTE)、制动油耗(BSFC)、废气排放(碳氢化合物(HC)、一氧化碳(CO)、氮氧化物(NO x)、二氧化碳(CO2)和烟雾等性能参数作为输出因素,将喷射定时(IT)、乙醇份额(ES)、喷射压力(IP)作为输入因素。人工神经网络模型准确地预测了乙醇和棉籽生物柴油混合物的投入产出关系,并通过实验比较得到了验证。BTE、BSFC、HC、CO、NO x和smoke的预测值与实验结果吻合较好,边际误差分别为6.2%、2.8%、7.1%、4.7%、6.8%和5.6%,证明了该方法的可靠性。此外,本研究利用田口灰色关联分析(GRA)来寻找发动机的最佳工况。分析表明,发动机的最佳工作条件是27°CA bTDC, 15% ES和200 bar的IP。并在最优工况下进行了验证试验,所得结果与田口GRA实验和人工神经网络预测值更为接近。
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引用次数: 0
Effect of depositional nanoparticles on heat transfer at the solid–liquid interface using molecular dynamics simulations 应用分子动力学模拟沉积纳米颗粒对固液界面传热的影响
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-03-12 DOI: 10.1515/jnet-2024-0080
Xunyan Yin, Congzheng Li, Zhihai Kou, Ran Zhang, Hailun Zhou
Here, we investigate the effect of depositional nanoparticles (DNPs) on boiling heat transfer using molecular dynamics simulations. We discuss the type and density of DNPs and reveal their physical mechanism on boiling heat transfer. In the case of nanoparticle material changes, the onset time of explosive boiling, the heat flux, and the enhancement factor of the DNPs are calculated, and the results show that the heat transfer at the solid–liquid interface is enhanced due to the DNPs. The enhancement of Cu-DNP is the largest, followed by Ag- and Au-DNP. Compared with a smooth surface, the interfacial interaction of the DNP surface is increased, resulting in the improvement of the surface wettability, which is beneficial to heat transfer. Furthermore, the interfacial thermal resistance affects the heat transfer when the DNP material changes. The DNPs enhance the vibrational thermal matching of atoms at the solid–liquid interface, leading to heat traveling more easily across the interface, and thus the heat transfer between surface and fluid is enhanced. In the case of nanoparticle density changes, the results demonstrate that the boiling heat transfer is enhanced by an increase in DNP density, which confirms that the interfacial interaction and the thermal resistance have significant effects on the heat transfer at the solid–liquid interface.
本文采用分子动力学模拟方法研究了沉积纳米颗粒(DNPs)对沸水传热的影响。讨论了DNPs的类型和密度,并揭示了它们对沸腾传热的物理机理。在纳米颗粒材料变化的情况下,计算了爆炸沸腾的起始时间、热流密度和DNPs的增强因子,结果表明DNPs的存在增强了固液界面处的换热。Cu-DNP的增强作用最大,其次是Ag-和Au-DNP。与光滑表面相比,DNP表面的界面相互作用增加,导致表面润湿性改善,有利于传热。此外,当DNP材料发生变化时,界面热阻影响传热。DNPs增强了固液界面处原子的振动热匹配,使热更容易通过界面传播,从而增强了表面与流体之间的传热。在纳米颗粒密度变化的情况下,纳米颗粒的沸腾传热随着DNP密度的增加而增强,这证实了界面相互作用和热阻对固液界面处的传热有显著影响。
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引用次数: 0
Exergy-based efficient ecological-function optimization for endoreversible Carnot refrigerators 内可逆卡诺冰箱基于火用的高效生态功能优化
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-03-12 DOI: 10.1515/jnet-2024-0099
Yanju He, Yanlin Ge, Lingen Chen, Huijun Feng
Based on the definition of exergy-based efficient ecological-function (EEF) proposed in the existing literature, which is the product of energy conversion coefficient-of-performance (ɛ) and exergy-based ecological-function (E), this paper will introduce the exergy-based EEF into performance optimization for Carnot refrigerator cycle. Via endoreversible Carnot refrigerator model established in previous literature, expression of the exergy-based EEF of refrigerator is derived based on finite-time thermodynamic theory, relationships of dimensionless exergy-based EEF versus ɛ and cooling load (R) are studied, and performance differences of refrigerator cycles at the maximum exergy-based EEF, at the maximum E, and at the maximum efficient cooling-load conditions are compared. The results demonstrate that relationships of dimensionless exergy-based EEF versus R and ɛ are parabolic-like ones; in actual design, the refrigerator should be designed at the larger R and ɛ points. When exergy-based EEF is taken as optimization-objective, although R decreases slightly, ɛ is increased, and entropy-generation-rate (σ) is greatly decreased, so exergy-based EEF does not only reflect the compromise between the R and σ, but also reflect the compromise between the R and ɛ.
基于现有文献提出的高效生态功能(EEF)的定义,即能量转换系数与高效生态功能(E)的乘积,本文将高效生态功能引入卡诺制冷机循环的性能优化中。利用文献中建立的内可逆卡诺制冷机模型,基于有限时间热力学理论推导了制冷机火用EEF的表达式,研究了无因次火用EEF与冷负荷(R)的关系,比较了最大火用EEF、最大E和最大有效冷负荷工况下制冷机循环的性能差异。结果表明:基于无因次能的EEF与R和i呈抛物线型关系;在实际设计中,制冷机应在较大的R点和R点进行设计。以火用EEF为优化目标时,R虽略有减小,但η增大,熵生成率σ大大减小,因此火用EEF不仅反映了R与σ的折衷,也反映了R与η的折衷。
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引用次数: 0
Energetic analysis of a non-isothermal linear energy converter operated in reverse mode (I-LEC): heat pump 反向模式下非等温线性能量转换器(I-LEC)的能量分析:热泵
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-03-06 DOI: 10.1515/jnet-2024-0065
Saul Gonzalez-Hernandez
In this paper, we perform an energetic analysis of a non-isothermal linear energy converter operated in inverse mode (refrigerator and heat pump). This is done within the framework of linear irreversible thermodynamics (LIT), starting from the model of an inverse linear energy converter (I-LEC) proposed by S. Gonzalez et al. (S. Gonzalez-Hernandez and L.-A. Arias-Hernandez, “Thermoelectric thomson relations revisited for a linear energy converter,” J. Non-Equilibrium Thermodyn., vol. 44, no. 3, pp. 315–332, 2019). We extend this model to the case of heat pumps, considering different objective functions and performing their respective analyses. We particularly focus on the coefficient of performance (COP) of heating, ϵ H . Additionally, we propose other energetic functions that may be of interest in the analysis of heat pumps, drawing analogies with the well-known functions for refrigerators and heat engines. Finally, we present a brief description of thermoelectric phenomena, focusing primarily on the Peltier effect. A brief analysis of the results obtained in the context of thermoelectric cooling and heating is presented for a non-isothermal LEC.
在本文中,我们进行了一个非等温线性能量转换器在逆模式(冰箱和热泵)运行的能量分析。这是在线性不可逆热力学(LIT)的框架内完成的,从S. Gonzalez等人(S. Gonzalez- hernandez和l. a . a .)提出的逆线性能量转换器(I-LEC)模型开始。Arias-Hernandez,“对线性能量转换器的热电汤姆逊关系的重新审视”,J.非平衡热力学。,第44卷,no。3, pp. 315-332, 2019)。我们将此模型扩展到热泵的情况下,考虑不同的目标函数并执行各自的分析。我们特别关注供暖的性能系数(COP), ε H。此外,我们提出了其他可能对热泵分析感兴趣的能量函数,与众所周知的冰箱和热机的功能进行类比。最后,我们简要描述了热电现象,主要集中在珀尔帖效应上。简要分析了非等温LEC在热电冷却和加热的情况下获得的结果。
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引用次数: 0
Heat transfer at nano-scale and boundary conditions: a comparison between the Guyer-Krumhansl model and the Thermomass theory 纳米尺度和边界条件下的传热:Guyer-Krumhansl模型与热质理论的比较
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-03-06 DOI: 10.1515/jnet-2024-0098
Carmelo F. Munafó, Patrizia Rogolino, Antonio Sellitto
In this paper we deepen into the influence of the boundary conditions on the heat-flux behavior in the case of thin nanowires. We compare the evolution of an initially inhomogeneous heat flux between two systems at the same (constant) temperature according to two theoretical models, one only emphasizing the role played by the non-local effects, and the other only accounting for the influence of the non-linear effects. It is found that non-local effects yield a monotonic trend toward the equilibrium, whereas non-linear effects yield an oscillating trend. The behavior of the entropy in both cases is analyzed as well.
本文深入研究了边界条件对细纳米线热流特性的影响。我们比较了两个系统在相同(恒定)温度下的初始不均匀热通量的演变,根据两个理论模型,一个只强调非局部效应的作用,另一个只考虑非线性效应的影响。研究发现,非局部效应产生单调的平衡趋势,而非线性效应产生振荡趋势。对这两种情况下的熵的行为进行了分析。
{"title":"Heat transfer at nano-scale and boundary conditions: a comparison between the Guyer-Krumhansl model and the Thermomass theory","authors":"Carmelo F. Munafó, Patrizia Rogolino, Antonio Sellitto","doi":"10.1515/jnet-2024-0098","DOIUrl":"https://doi.org/10.1515/jnet-2024-0098","url":null,"abstract":"In this paper we deepen into the influence of the boundary conditions on the heat-flux behavior in the case of thin nanowires. We compare the evolution of an initially inhomogeneous heat flux between two systems at the same (constant) temperature according to two theoretical models, one only emphasizing the role played by the non-local effects, and the other only accounting for the influence of the non-linear effects. It is found that non-local effects yield a monotonic trend toward the equilibrium, whereas non-linear effects yield an oscillating trend. The behavior of the entropy in both cases is analyzed as well.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"33 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic characterization of transient valve temperatures in diesel engines using probabilistic methods 用概率方法对柴油机瞬态气门温度进行热力学表征
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-02-27 DOI: 10.1515/jnet-2024-0052
Pardeep Kumar, Anikate Gupta, Dinesh Kumar, Vipin Kumar Sharma, Santosh Kumar Rai
This investigation aimed to predict the temperature distribution in the inlet and exhaust valve and isotherms to the cooling media at a given load of a diesel engine. For the analysis that has been done a Tata- Mercedes diesel engine with 90 mm bore diameter and Stroke length of 120 mm was analysed using FEM through Ansys workbench 15.0. Steady as well as transient cases were considered in combination. The temperature distribution and isotherms are computed and plotted using Ansys. The results obtained by Ansys workbench 15.0 were satisfactory and were in line when compared with finite differential analysis. There is a large temperature variation along the length of the valve. It may vary from 560 °C to 110 °C from tip to valve head in the exhaust valve while this variation is less in the case of inlet valve from 540 °C to 100 °C from the face to the tip. The linear temperature difference between the nodes at the base of the stem to the node at the center of the face increases with time and acquires the maximum value of about 120 °C at about 10 s then it decreases till the valve attains a steady state value. Thus, was observed from analysis that during this time there is a maximum probability of failure of valves due to linear differences in temperature.
本研究旨在预测柴油机在给定负荷下进排气气阀内的温度分布以及冷却介质的等温线。本文采用Ansys workbench 15.0对一台直径为90mm、行程长度为120mm的塔塔-奔驰柴油机进行了有限元分析。同时考虑了稳态和瞬态两种情况。利用Ansys计算并绘制了温度分布和等温线。在Ansys workbench 15.0中得到的结果与有限差分分析结果一致,令人满意。沿着阀门的长度有很大的温度变化。在排气阀中,从阀顶到阀头的温度变化范围从560°C到110°C,而在进口阀中,从表面到阀顶的温度变化范围从540°C到100°C,这种变化较小。阀杆基部节点与端面中心节点之间的线性温差随时间增大,在10 s左右达到最大值120℃左右,然后逐渐减小,直至阀达到稳态值。因此,从分析中可以看出,在此期间,由于温度的线性差异,阀门失效的概率最大。
{"title":"Thermodynamic characterization of transient valve temperatures in diesel engines using probabilistic methods","authors":"Pardeep Kumar, Anikate Gupta, Dinesh Kumar, Vipin Kumar Sharma, Santosh Kumar Rai","doi":"10.1515/jnet-2024-0052","DOIUrl":"https://doi.org/10.1515/jnet-2024-0052","url":null,"abstract":"This investigation aimed to predict the temperature distribution in the inlet and exhaust valve and isotherms to the cooling media at a given load of a diesel engine. For the analysis that has been done a Tata- Mercedes diesel engine with 90 mm bore diameter and Stroke length of 120 mm was analysed using FEM through Ansys workbench 15.0. Steady as well as transient cases were considered in combination. The temperature distribution and isotherms are computed and plotted using Ansys. The results obtained by Ansys workbench 15.0 were satisfactory and were in line when compared with finite differential analysis. There is a large temperature variation along the length of the valve. It may vary from 560 °C to 110 °C from tip to valve head in the exhaust valve while this variation is less in the case of inlet valve from 540 °C to 100 °C from the face to the tip. The linear temperature difference between the nodes at the base of the stem to the node at the center of the face increases with time and acquires the maximum value of about 120 °C at about 10 s then it decreases till the valve attains a steady state value. Thus, was observed from analysis that during this time there is a maximum probability of failure of valves due to linear differences in temperature.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"85 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143517942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance comparison of water towers and combined pumped hydro and compressed gas system and proposing a novel hybrid system to energy storage with a case study of a 50 MW wind farm 水塔与抽水蓄能和压缩气体联合系统的性能比较,并以50mw风电场为例,提出一种新型的混合系统用于储能
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-02-27 DOI: 10.1515/jnet-2024-0102
Amin Hadidi
In general, the most important method of energy storage at the power plant scale is the pumped hydro method, which has been developed in two main models to improve its performance, which is pumped hydro combined with compressed gas (PHCCG) and pumped hydro in closed towers (PHWT). In this research, to answer which of these methods is more suitable, in the form of a case study, both systems were designed to store the generated energy in the Aghkand wind farm with a nominal power of 50 (MW), and the performance of both was completely compared with each other. The findings indicated that the efficiency of the PHWT method was higher, but on the other hand, the water requirement of the PHCCG method was much lower than the PHWT method. Also, in an innovative way, the PHWT system was presented with a combination of towers of different classes and the performance of each was investigated. Finally, by combining both PHWT and PHCCG systems, a new hybrid system (HPHWTCG) was proposed. By using this hybrid system, the advantages of both methods can be used at the same time and the disadvantages of each method can be eliminated to a great extent. The efficiency of PHWT and PHCCG is 65 % and 45 % respectively. The efficiency of HPHWTCG is between these two values based on its structure.
一般来说,电站规模的蓄能方式中最重要的是抽水蓄能方式,为了提高其性能,抽水蓄能已经发展为两种主要模式,即压缩气体抽水蓄能(PHCCG)和闭式塔抽水蓄能(PHWT)。在本研究中,为了回答哪一种方法更合适,以案例研究的形式,两种系统都被设计为将产生的能量存储在Aghkand风电场中,标称功率为50 (MW),并且两者的性能完全相互比较。结果表明,PHWT法的效率更高,但PHCCG法的需水量远低于PHWT法。此外,以一种创新的方式,提出了PHWT系统与不同类型的塔的组合,并对每个塔的性能进行了研究。最后,将PHWT系统与PHCCG系统相结合,提出了一种新的混合系统(HPHWTCG)。通过使用这种混合系统,可以同时利用两种方法的优点,并在很大程度上消除每种方法的缺点。PHWT和PHCCG的效率分别为65%和45%。从结构上看,HPHWTCG的效率介于这两个值之间。
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引用次数: 0
Existence of the Chapman–Enskog solution and its relation with first-order dissipative fluid theories Chapman-Enskog解的存在性及其与一阶耗散流体理论的关系
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-02-27 DOI: 10.1515/jnet-2024-0086
Ana Laura García-Perciante, Alma Rosa Méndez, Olivier Sarbach
The conditions for the existence of the Chapman–Enskog first-order solution to the Boltzmann equation for a dilute gas are examined from two points of view. The traditional procedure is contrasted with a somehow more formal approach based on the properties of the linearized collision operator. It is shown that both methods lead to the same integral equation in the non-relativistic scenario. Meanwhile, for relativistic systems, the source term in the integral equation adopts two different forms. However, as we explain, this does not lead to an inconsistency. In fact, the constitutive equations that are obtained from both methods are shown to be equivalent within relativistic first-order theories. The importance of stating invariant definitions for the transport coefficients in this context is emphasized.
本文从两个角度研究了稀薄气体波尔兹曼方程的查普曼-恩斯科格一阶解的存在条件。传统方法与基于线性化碰撞算子特性的更为正式的方法进行了对比。结果表明,在非相对论情况下,两种方法都能得出相同的积分方程。同时,对于相对论系统,积分方程中的源项采用了两种不同的形式。不过,正如我们所解释的,这并不会导致不一致。事实上,在相对论一阶理论中,两种方法得到的构成方程是等价的。我们强调了在这种情况下说明输运系数不变定义的重要性。
{"title":"Existence of the Chapman–Enskog solution and its relation with first-order dissipative fluid theories","authors":"Ana Laura García-Perciante, Alma Rosa Méndez, Olivier Sarbach","doi":"10.1515/jnet-2024-0086","DOIUrl":"https://doi.org/10.1515/jnet-2024-0086","url":null,"abstract":"The conditions for the existence of the Chapman–Enskog first-order solution to the Boltzmann equation for a dilute gas are examined from two points of view. The traditional procedure is contrasted with a somehow more formal approach based on the properties of the linearized collision operator. It is shown that both methods lead to the same integral equation in the non-relativistic scenario. Meanwhile, for relativistic systems, the source term in the integral equation adopts two different forms. However, as we explain, this does not lead to an inconsistency. In fact, the constitutive equations that are obtained from both methods are shown to be equivalent within relativistic first-order theories. The importance of stating invariant definitions for the transport coefficients in this context is emphasized.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"34 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143517941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Is there a need for an extended phase definition for systems far from equilibrium? 对于远离平衡的系统是否需要一个扩展的相定义?
IF 6.6 3区 工程技术 Q1 MECHANICS Pub Date : 2025-02-13 DOI: 10.1515/jnet-2024-0063
Fernando Bautista, Juan Paulo García-Sandoval, Octavio Manero
Phase diagrams out of equilibrium have been the subject of intense research. An essential concept in these diagrams is the phase definition. Currently, that definition is well established for systems at classic thermodynamic equilibrium conditions. However, such phase definition is inadequate for systems that are not at equilibrium in the classic thermodynamic sense, like fluid systems under flowing conditions. Complex fluids may exhibit instabilities like shear-banding flow and a non-equilibrium critical point where banding flow ends. At this point, the fluid undergoes a phase transition from heterogeneous to homogeneous states. An extended thermodynamic space of variables is considered to adequately address this situation, which includes non-conservative variables such as stress and shear rate. Hence, the current phase definition based on conservative variables does not apply to non-equilibrium phase diagrams. On this basis, a broader definition of phase is required. We propose that this broader definition considers the thermodynamic variables space of Extended Irreversible Thermodynamics and the mathematical conditions that ensure compatibility between equilibrium and non-equilibrium conditions for systems where phases are well described by thermodynamic potentials even out of equilibrium.
非平衡相图一直是研究的热点。这些图中的一个基本概念是阶段定义。目前,对于处于经典热力学平衡条件下的系统,这一定义已经得到了很好的确立。然而,这样的相定义对于经典热力学意义上的非平衡系统,如流动条件下的流体系统,是不充分的。复杂流体可能表现出不稳定性,如剪切带状流动和带状流动结束的非平衡临界点。此时,流体经历了从非均相到均相的相变。一个扩展的热力学变量空间被认为足以解决这种情况,其中包括非保守变量,如应力和剪切速率。因此,目前基于保守变量的相定义不适用于非平衡相图。在此基础上,需要对相位进行更广泛的定义。我们提出这个更广泛的定义考虑了扩展不可逆热力学的热力学变量空间和确保平衡和非平衡条件之间相容的数学条件,其中相可以很好地用热力学势描述,即使在非平衡状态下。
{"title":"Is there a need for an extended phase definition for systems far from equilibrium?","authors":"Fernando Bautista, Juan Paulo García-Sandoval, Octavio Manero","doi":"10.1515/jnet-2024-0063","DOIUrl":"https://doi.org/10.1515/jnet-2024-0063","url":null,"abstract":"Phase diagrams out of equilibrium have been the subject of intense research. An essential concept in these diagrams is the phase definition. Currently, that definition is well established for systems at classic thermodynamic equilibrium conditions. However, such phase definition is inadequate for systems that are not at equilibrium in the classic thermodynamic sense, like fluid systems under flowing conditions. Complex fluids may exhibit instabilities like shear-banding flow and a non-equilibrium critical point where banding flow ends. At this point, the fluid undergoes a phase transition from heterogeneous to homogeneous states. An extended thermodynamic space of variables is considered to adequately address this situation, which includes non-conservative variables such as stress and shear rate. Hence, the current phase definition based on conservative variables does not apply to non-equilibrium phase diagrams. On this basis, a broader definition of phase is required. We propose that this broader definition considers the thermodynamic variables space of Extended Irreversible Thermodynamics and the mathematical conditions that ensure compatibility between equilibrium and non-equilibrium conditions for systems where phases are well described by thermodynamic potentials even out of equilibrium.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"67 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143417792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Non-Equilibrium Thermodynamics
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