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Heat transfer effect on the performance of three-heat-reservoir thermal Brownian refrigerator 传热对三热源布朗制冷机性能的影响
3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-10-09 DOI: 10.1515/jnet-2023-0050
Congzheng Qi, Lingen Chen, Yanlin Ge, Huijun Feng
Abstract A finite-time thermodynamic (FTT) model of three-heat-reservoir thermal Brownian refrigerator is established in this paper. This model can be equivalent to the coupling of a thermal Brownian engine and a thermal Brownian refrigerator with heat transfer effects. Expressions for cooling load and coefficient of performance (COP) are derived by combining FTT and non-equilibrium thermodynamics (NET). The system performance is studied and compared with those of previous models. For fixed internal parameters, the thermal conductance distributions among three heat exchangers are optimized for maximal cooling load. For fixed inventory allocations, the internal parameters are also optimized for maximal cooling load. Finally, the double-maximum cooling load is obtained by optimizing internal parameters and external thermal conductance distributions simultaneously, and the optimal operating temperatures are also derived. Results show that half of total thermal conductance should be placed in condenser to reject heat to ambient under maximal cooling load regime. The heat transfer determines system performance by controlling the working temperatures and the coupling of two external loads. The system works in reversible state when COP reaches its maximum value. The new performance limits can predict that of three-heat-reservoir thermal Brownian refrigerator more accurately, and also include those of NET model.
摘要建立了三热源布朗制冷机的有限时间热力学模型。该模型可以等效为热布朗机和热布朗制冷机的耦合,具有传热效应。结合FTT和非平衡热力学推导了冷负荷和性能系数(COP)的表达式。对系统性能进行了研究,并与已有模型进行了比较。在内部参数固定的情况下,以最大冷负荷为目标,优化三台换热器之间的导热系数分布。对于固定库存分配,内部参数也优化为最大冷却负荷。最后,通过同时优化内部参数和外部热导分布,获得双最大冷负荷,并推导出最佳工作温度。结果表明,在最大冷负荷工况下,冷凝器中应放置总热导的一半,以将热量排出环境。传热通过控制工作温度和两个外部负载的耦合来决定系统的性能。当COP达到最大值时,系统工作在可逆状态。新的性能极限可以更准确地预测三热源热布朗制冷机的性能极限,也包括NET模型的性能极限。
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引用次数: 2
Frontmatter 头版头条
3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-10-01 DOI: 10.1515/jnet-2023-frontmatter4
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引用次数: 0
Improved modeling of Janus membrane considering the influence of hydrophilic layer characteristics 考虑亲水层特性影响的Janus膜的改进建模
3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-09-18 DOI: 10.1515/jnet-2023-0037
Noha M. Sayed, Hussien Noby, Kyaw Thu, Ahmed H. El-Shazly
Abstract Some of the previous investigations neglect the mass transfer contribution of the hydrophilic layer for modeling the Janus membrane that is used for direct contact membrane distillation (DCMD). This work studies the impact of adding such resistance on the performance of the DCMD, especially on the temperature polarization coefficient (TPC), thermal efficiency, and permeate flux. The commercial software Ansys 2020 was used to describe the transport behavior through the Janus membrane. The bulk-flow model was employed to evaluate the permeate flow through the hydrophilic layer for the first time. Simulation results were compared with the experimental results from the literature for validating the model, and a satisfactory agreement was found. Results demonstrated that the permeate flux increased by about 61.3 % with changing the porosity of the hydrophilic layer from 0.5 to 0.9 for the membrane with the lowest hydrophilic layer thickness. Moreover, the thermal conductivities of both layers contribute significantly to the DCMD’s overall performance enhancement. Vapour flux might be enhanced by increasing the hydrophilic layer’s thermal conductivity while decreasing the hydrophobic layer’s thermal conductivity. Finally, the DCMD thermal efficiency was investigated, for the first time, in terms of both layer characteristics.
在直接接触膜蒸馏(DCMD)过程中,一些研究忽略了亲水性层的传质作用。本文研究了加入该电阻对DCMD性能的影响,特别是对温度极化系数(TPC)、热效率和渗透通量的影响。利用商业软件Ansys 2020描述了通过Janus膜的输运行为。首次采用体积流模型对亲水性层的渗透流动进行了评价。将仿真结果与文献中的实验结果进行了比较,验证了模型的正确性。结果表明,亲水性层厚度最低的膜,当亲水性层孔隙度由0.5增加到0.9时,膜的渗透通量增加约61.3%。此外,两层的热导率对DCMD的整体性能增强有重要贡献。提高亲水层的热导率,降低疏水层的热导率,可以增强蒸汽通量。最后,首次从两层特性的角度研究了DCMD的热效率。
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引用次数: 0
Effect of non-ideal gas working fluid on power and efficiency performances of an irreversible Otto cycle 非理想气体工质对不可逆奥托循环功率和效率的影响
IF 6.6 3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-09-07 DOI: 10.1515/jnet-2023-0036
Di Wu, Y. Ge, Lingen Chen, Lei Tian
Abstract Based on the irreversible Otto cycle model, applying finite-time-thermodynamic theory, this paper takes power and efficiency as the objective functions, further studies the cycle performance under the condition of non-ideal gas working fluid, analyzes the effects of different loss items and freedom degree (d) of monatomic gas on the cycle performance, and compares performance differences of ideal gas and non-ideal gas under different specific heat models. The results demonstrate that, with the increase of d, the maximum-power-output (Pmax), the maximum-thermal-efficiency (ηmax), the corresponding optimal compression-ratio ( ( γ opt ) p ${({gamma }_{text{opt}})}_{p}$ ) and efficiency (η P ) at the Pmax point, and the corresponding optimal compression ratio ( ( γ opt ) η ${({gamma }_{text{opt}})}_{eta }$ ) and power (P η ) at the ηmax point will all increase; the Pmax, ( γ opt ) p ${({gamma }_{text{opt}})}_{p}$ , ηmax, ( γ opt ) η ${({gamma }_{text{opt}})}_{eta }$ , η p and P η will decrease with the increases of three irreversible losses; the specific heat model has only quantitative effect on cycle performance but no qualitative effect; under condition of non-ideal gas specific heat model, the power and efficiency are the smallest.
摘要基于不可逆奥托循环模型,应用有限时间热力学理论,以功率和效率为目标函数,进一步研究了非理想气体工作流体条件下的循环性能,分析了单原子气体的不同损失项和自由度(d)对循环性能的影响,并比较了理想气体和非理想气体在不同比热模型下的性能差异。结果表明,随着d的增加,最大功率输出(Pmax)、最大热效率(ηmax)、相应的最佳压缩比(γopt)p${({gamma}_{text{opt})}_(p}$)和Pmax点的效率(ηp),相应的最优压缩比(γopt)η${({gamma}_{text{opt})}_;Pmax、(γopt)p${({gamma}_{text{opt})}_;比热模型对循环性能只有定量影响,没有定性影响;在非理想气体比热模型条件下,功率和效率最小。
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引用次数: 3
Computational radiative transport in complex geometries using orthogonal coordinates 利用正交坐标计算复杂几何中的辐射输运
IF 6.6 3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-09-05 DOI: 10.1515/jnet-2023-0009
Md. Ershadul Haque, S. Mansoor, B. Yilbas
Abstract Radiative heat transport involving complex geometries is an important area of investigation. The formulation of the transport phenomenon is more involved and consideration of the proper treatment of the irregular geometry becomes necessary for accurate estimation of heat transfer rates. Therefore, the present study focuses on the modeling and the solution of the radiative transfer equation (RTE) in an absorbing, emitting, and isotropically scattering, participating media for complex geometries using the body-fitted coordinates. The RTE in an orthogonal coordinate system is formulated and is then numerically solved in conjunction with a numerically generated, body-fitted, curvilinear coordinate system. The geometries are considered to be opaque and, in the analysis, both the radiative as well as the non-radiative equilibrium cases are considered. The formulation is validated through the previously published results. Notable agreement is observed between the results and those reported earlier for different complex geometries and various properties of the participating media.
摘要复杂几何形状的辐射热传输是一个重要的研究领域。传输现象的公式化更为复杂,为了准确估计传热率,有必要考虑对不规则几何形状的适当处理。因此,本研究的重点是使用贴体坐标对复杂几何形状的吸收、发射和各向同性散射参与介质中的辐射传输方程(RTE)进行建模和求解。正交坐标系中的RTE是公式化的,然后与数值生成的贴体曲线坐标系一起进行数值求解。几何结构被认为是不透明的,在分析中,既考虑了辐射平衡情况,也考虑了非辐射平衡情况。该配方通过先前公布的结果进行了验证。对于不同的复杂几何形状和参与介质的各种性质,在结果与先前报道的结果之间观察到显著的一致性。
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引用次数: 0
Investigation of non-equilibrium separation time on the partitioning of cephalexin in an aqueous two-phase system composed of glucose and acetonitrile 非平衡分离时间对头孢氨苄在葡萄糖-乙腈双水相体系中分配的影响
IF 6.6 3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-07-17 DOI: 10.1515/jnet-2023-0028
Parsa Movahedi, Ali Jalali Qush Qayeh, Javad Rahbar Shahrouzi
Abstract In order to commercialize aqueous two-phase systems (ATPSs), not only the equilibrium data is essential, but also the knowledge of separation mechanisms, kinetics, settling time, and operational conditions are needed. Mixing duration and settling time are the most critical factors affecting separation and biomolecule partitioning in terms of economic aspects. This research aimed to find the desired conditions for separating cephalexin in an ATPS consisting of acetonitrile, glucose, and water. Firstly, the evolution of the interphase region was observed. Hereafter, to examine the effect of time on the experimental tie-lines and partition coefficient in non-equilibrium states, the settling time was varied from 2 min to 24 h. In addition, centrifugation was applied to help the separation at different time intervals and rotational speeds. The results of tie-lines slope and partitioning coefficients showed that the system approaches equilibrium after 5 h. However, using the centrifuge separation at 4000 rpm improved the separation time to 45 min, reaching 80 % of the actual partition coefficient. It can be concluded that with an acceptable tolerance in the partition coefficient, a remarkably diminished settling time is available for economic productivity in industrial units.
摘要为了使双水相系统(ATPSs)商业化,不仅平衡数据是必不可少的,而且还需要分离机理、动力学、沉降时间和操作条件的知识。从经济角度来看,混合持续时间和沉降时间是影响分离和生物分子分配的最关键因素。本研究旨在寻找在由乙腈、葡萄糖和水组成的ATPS中分离头孢氨苄的理想条件。首先,观察了界面区的演化。此后,为了检验时间对非平衡状态下实验联络线和分配系数的影响,沉降时间从2 最小 至24 h.此外,在不同的时间间隔和转速下应用离心来帮助分离。联络线斜率和分配系数的结果表明,系统在5 h.然而,使用4000的离心机分离 rpm将分离时间提高到45 分钟,达到80 % 实际分配系数。可以得出结论,在分配系数具有可接受的公差的情况下,工业单元的经济生产力可以显著缩短沉降时间。
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引用次数: 0
Uncovering enzymatic structural adaptations from energy dissipation 从能量耗散中揭示酶的结构适应性
IF 6.6 3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-07-07 DOI: 10.1515/jnet-2023-0044
A. Arango-Restrepo, D. Barragán, J. Rubí
Abstract While genetic mutations, natural selection and environmental pressures are well-known drivers of enzyme evolution, we show that their structural adaptations are significantly influenced by energy dissipation. Enzymes use chemical energy to do work, which results in a loss of free energy due to the irreversible nature of the process. By assuming that the catalytic process occurs along a potential barrier, we describe the kinetics of the conversion of enzyme-substrate complexes to enzyme-product complexes and calculate the energy dissipation. We show that the behaviour of the dissipated energy is a non-monotonic function of the energy of the intermediate state. This finding supports our main result that enzyme configurations evolve to minimise energy dissipation and simultaneously improve kinetic and thermodynamic efficiencies. Our study provides a novel insight into the complex process of enzyme evolution and highlights the crucial role of energy dissipation in shaping structural adaptations.
摘要虽然基因突变、自然选择和环境压力是酶进化的众所周知的驱动因素,但我们发现它们的结构适应受到能量耗散的显著影响。酶利用化学能做功,由于过程的不可逆性,这会导致自由能的损失。通过假设催化过程沿着势垒发生,我们描述了酶-底物复合物转化为酶-产物复合物的动力学,并计算了能量耗散。我们证明了耗散能量的行为是中间态能量的非单调函数。这一发现支持了我们的主要结果,即酶构型的进化可以最大限度地减少能量耗散,同时提高动力学和热力学效率。我们的研究为酶进化的复杂过程提供了新的见解,并强调了能量耗散在形成结构适应中的关键作用。
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引用次数: 0
Frontmatter 头版头条
3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-06-13 DOI: 10.1515/jnet-2023-frontmatter3
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引用次数: 0
Relations between timescales of stochastic thermodynamic observables 随机热力学可观测度的时间尺度关系
IF 6.6 3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-05-16 DOI: 10.1515/jnet-2022-0104
Erez Aghion, Jason R. Green
Abstract Any real physical process that produces entropy, dissipates energy as heat, or generates mechanical work must do so on a finite timescale. Recently derived thermodynamic speed limits place bounds on these observables using intrinsic timescales of the process. Here, we derive relationships for the thermodynamic speeds for any composite stochastic observable in terms of the timescales of its individual components. From these speed limits, we find bounds on thermal efficiency of stochastic processes exchanging energy as heat and work and bound the rate of entropy change in a system with entropy production and flow. Using the time set by an external clock, we find bounds on the first time to reach any value for the entropy production. As an illustration, we compute these bounds for Brownian particles diffusing in space subject to a constant-temperature heat bath and a time-dependent external force.
摘要任何产生熵、以热的形式耗散能量或产生机械功的真实物理过程都必须在有限的时间尺度上进行。最近导出的热力学速度限制使用过程的内在时间尺度对这些可观测值进行了限制。在这里,我们导出了任何复合随机可观测的热力学速度在其单个分量的时间尺度方面的关系。从这些速度极限中,我们找到了以热和功交换能量的随机过程的热效率的边界,并约束了具有熵产生和熵流动的系统中的熵变化率。使用外部时钟设置的时间,我们找到第一次达到熵产生任何值的时间的界限。举例来说,我们计算了布朗粒子在恒温水浴和时间相关外力作用下在空间中扩散的这些边界。
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引用次数: 0
Concepts of phenomenological irreversible quantum thermodynamics II: time dependent statistical ensembles of bipartite systems 唯象不可逆量子热力学的概念Ⅱ:二分系统的时间相关统计系综
IF 6.6 3区 工程技术 Q1 Physics and Astronomy Pub Date : 2023-04-27 DOI: 10.1515/jnet-2023-0023
W. Muschik
Abstract The wide-spread opinion is that original quantum mechanics is a reversible theory, but this statement is only true for undecomposed systems that are those systems for which sub-systems are out of consideration. Taking sub-systems into account, as it is by definition necessary for decomposed systems, the interaction Hamiltonians –which are absent in undecomposed systems– can be a source of irreversibility in decomposed systems. Thus, the following two-stage task arises: How to modify von Neumann’s equation of undecomposed systems so that irreversibility appears, and how this modification affects decomposed systems? The first step was already done in Muschik (“Concepts of phenomenological irreversible quantum thermodynamics: closed undecomposed Schottky systems in semi-classical description,” J. Non-Equilibrium Thermodyn., vol. 44, pp. 1–13, 2019) and is repeated below, whereas the second step to formulate a quantum thermodynamics of decomposed systems is performed here by modifying the von Neumann equations of the sub-systems by a procedure wich is similar to that of Lindblad’s equation (G. Lindblad, “On the generators of quantum dynamical semigroups,” Commun. Math. Phys., vol. 48, p. 119130, 1976), but different because the sub-systems interact with one another through partitions.
摘要广泛的观点是,原始量子力学是一种可逆理论,但这一说法只适用于未分解的系统,即不考虑子系统的系统。考虑到子系统,正如分解系统所必需的那样,相互作用哈密顿量——在未分解系统中不存在——可能是分解系统不可逆性的来源。因此,出现了以下两个阶段的任务:如何修改冯·诺依曼的未分解系统方程,使其出现不可逆性,以及这种修改如何影响分解系统?第一步已经在Muschik中完成(“现象学不可逆量子热力学的概念:半经典描述中的封闭未分解肖特基系统”,J.Non Balancement Thermodyn.,第44卷,第1-132019页),并在下面重复,而公式化分解系统的量子热力学的第二步在这里通过用类似于Lindblad方程的程序修改子系统的von Neumann方程来执行(G.Lindblad,“关于量子动力学半群的生成子”,Commun.Math.Phys.,vol.48,p.1191301976),但是不同之处在于子系统通过分区相互作用。
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引用次数: 0
期刊
Journal of Non-Equilibrium Thermodynamics
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