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The Piedmont Zone From the Western Alps (Italy): New Insights From High-Pressure Ophiolitic Metasediments in the Soana Valley 西阿尔卑斯山(意大利)的山前带:来自索亚纳山谷高压蛇绿质变质沉积物的新见解
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-10-22 DOI: 10.1111/jmg.70013
Alessia Modesti, Francesco Gosio, Paolo Nimis, Paola Tartarotti, Omar Bartoli, Silvana Martin

Metaophiolites and metasediments of the Piedmont Zone are exposed in the Soana Valley, a poorly studied area of the Western Alps, located between the Europe-related Gran Paradiso massif and the Adria-related Sesia–Lanzo zone. Previous investigations reported the occurrence of only greenschist-facies metamorphic assemblages in the metasediments. We present new petrographic analyses and phase equilibria modelling of garnet-chloritoid- and garnet-lawsonite-choritoid-bearing mica schists from the Soana Valley. These mica schists preserve relicts of Alpine high-pressure mineral assemblages, testifying both a prograde and a decompressional evolution. Four main metamorphic stages are recognized from compositional zoning of garnet in a garnet-lawsonite-chloritoid-bearing mica schist: a subduction-related prograde stage at 17.0–18.5 kbar and 420°C–440°C (high-pressure blueschist-facies), a pressure peak at 19.0–21.5 kbar and 440°C–460°C (blueschist–eclogite-facies transition) and two decompressional stages at 17.5–18.5 kbar and 470°C–490°C (high-pressure blueschist-facies) and 14–15 kbar and 490°C–510°C (peak temperature). The peak pressure conditions of the Soana Valley metasediments are comparable (∆P ≤ 2–3 kbar) to those reported for some units of the external Western Alps located at structurally lower levels. Our results lead us to interpret the Piedmont Zone as a stack of tectonic slices, each one with its own metamorphic history, accreted together during subduction, rather than an assemblage of two juxtaposed belts characterized by distinct metamorphic histories, as traditionally reported.

皮埃蒙特带的变质绿岩和变质沉积岩暴露在西阿尔卑斯山的Soana山谷,该地区位于与欧洲有关的大天堂地块和与亚德里亚有关的Sesia-Lanzo带之间,研究较少。以往的研究只发现了绿片岩相变质组合。我们提出了来自Soana山谷的含石榴石-绿泥石和石榴石-钙泥石-脉络膜云母片岩的新的岩石学分析和相平衡模型。这些云母片岩保存了阿尔卑斯高压矿物组合的遗迹,证明了一个渐进和减压的演化过程。从含石榴石-白榴石-绿泥石云母片岩中石榴石的成分分带可识别出4个主要变质阶段:与俯冲有关的17.0 ~ 18.5 kbar、420℃~ 440℃(高压蓝片岩相)的递进阶段,19.0 ~ 21.5 kbar、440℃~ 460℃(蓝片岩-榴辉岩相过渡)的压力峰值阶段,17.5 ~ 18.5 kbar、470℃~ 490℃(高压蓝片岩相)和14 ~ 15 kbar、490℃~ 510℃(峰值温度)的减压阶段。Soana Valley沉积物的峰值压力条件与位于结构较低水平的西阿尔卑斯山外部某些单元的峰值压力条件相当(∆P≤2-3 kbar)。我们的研究结果使我们将山前带解释为一堆构造片,每个构造片都有自己的变质历史,在俯冲过程中聚集在一起,而不是像传统报道的那样,是两个并列带的组合,其特征是不同的变质历史。
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引用次数: 0
Can Multiphase Inclusions in Garnet From Eclogite Facies Rocks Be a Product of Melt or Supercritical Fluid Entrapment During Subduction? 榴辉岩相岩石榴石中的多相包裹体是熔融产物还是俯冲过程中超临界流体夹带的产物?
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-09-12 DOI: 10.1111/jmg.70009
Shah Wali Faryad

Dehydration of rocks and minerals during high-pressure metamorphism is controlled by the thermal structure of the subduction zone and can be traced by the stability fields of hydrous phases. Consistent with the results of experimental works, the content of silicate components in fluids is assumed to increase from the fields of subcritical to supercritical fluid at higher pressure and to hydrous melt at higher temperature. As there is no direct information about the composition of these fluids along the subduction zone, the multiphase (polyphase) inclusions in anhydrous minerals in eclogite facies rocks are frequently interpreted as products of such fluids or melt, which became entrapped and subsequently crystallised. Although some of these multiphase inclusions are formed by quartz and feldspars and have a composition of granitic melt, most of them contain phases that do not support their formation from granitic or other types of melt. The assumption of their formation from supercritical fluids or melt has stimulated laboratory research to reproduce the original fluids or melts from which these multiphase inclusions could have originated. Therefore, petrological data useful to verify or falsify this assumption is essential for further direction in multidisciplinary research on fluid and melt generation in the subduction zone. This paper presents textural and compositional relations among multiphase inclusions in garnet from various lithologies subjected to high- to ultrahigh-pressure metamorphism. The aim is to substantiate the in situ formation of multiphase inclusions through recrystallisation of pre-existing (hydrous) solid phases enclosed within host minerals. In addition to the presence of original hydrous solid phases, evidence is provided for their transformation into high-pressure phases during prograde metamorphism as well as their subsequent modification and decomposition during retrogression or heating associated with decompression. Furthermore, it is discussed whether the crystallisation of garnet with inclusions is in agreement with bulk-rock fractionation and thermodynamic modelling and whether the compositions of multiphase inclusions correspond to the pressure–temperature fields of hydrous melts or supercritical fluids from experimental data. The results of the study on the textural and compositional relationships of the multiphase inclusions, along with the pressure stability fields of the host minerals, support the interpretation that these inclusions formed by recrystallisation of originally enclosed aqueous and anhydrous phases, rather than by entrapment from a melt.

高压变质作用过程中岩石和矿物的脱水受俯冲带热构造控制,并可通过水相稳定场进行追踪。与实验结果一致,假定流体中硅酸盐组分的含量在高压下从亚临界流体到超临界流体,在高温下从含水熔体增加。由于没有关于沿俯冲带这些流体组成的直接信息,榴辉岩相岩石中无水矿物中的多相包裹体经常被解释为这些流体或熔体的产物,这些流体或熔体被包裹并随后结晶。虽然这些多相包裹体中的一些是由石英和长石形成的,并且具有花岗岩熔体的成分,但它们中的大多数包含的相并不支持它们由花岗岩或其他类型的熔体形成。多相包裹体由超临界流体或熔体形成的假设刺激了实验室研究,以重现这些多相包裹体可能起源于的原始流体或熔体。因此,有助于验证或证伪这一假设的岩石学数据对于进一步指导俯冲带流体和熔体生成的多学科研究至关重要。本文介绍了高-超高压变质作用下不同岩性石榴石中多相包裹体的结构和组成关系。目的是通过包裹在宿主矿物内的预先存在的(含水)固相的再结晶来证实多相包裹体的原位形成。除了原始的含水固相存在外,还提供了它们在前向变质作用过程中转变为高压相的证据,以及它们在退变或与减压相关的加热过程中随后的变质分解的证据。此外,从实验数据中讨论了石榴石与包裹体的结晶是否符合块岩分馏和热力学模型,多相包裹体的组成是否符合含水熔体或超临界流体的压力-温度场。对多相包裹体的结构和组成关系的研究结果,以及宿主矿物的压力稳定场,支持了这些包裹体是由原来封闭的水相和无水相再结晶形成的解释,而不是由熔体包裹形成的。
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引用次数: 0
Featured Cover 了封面
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-09-10 DOI: 10.1111/jmg.70010
Zhen M. G. Li, Fred Gaidies, Yi-Chao Chen, Jia-Shun Hu, Chun-Ming Wu

The cover image is based on the Original Article Thermodynamic and Kinetic Controls on the Growth of Metapelitic Garnet in the Danba Dome (SW China): Insights From Microstructure, Element Mapping and Thermodynamic Modelling by Zhen M. G. Li et al., https://doi.org/10.1111/jmg.70005.

封面图片基于原文章《丹巴巨圆顶变长石石榴石生长的热力学和动力学控制:来自微观结构、元素映射和热力学建模的见解》,作者:Zhen M. G. Li等,https://doi.org/10.1111/jmg.70005。
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引用次数: 0
Confronting Episodic vs. Continuous Heat Sources in Long-Lived Hot Orogens: Insights From Petrochronological Studies in the Nova Venecia Complex, Araçuaí Orogen (SE Brazil) 面对长寿命热造山带的间歇热源与连续热源:来自巴西东南部Araçuaí造山带Nova veneecia杂岩年代学研究的见解
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-09-09 DOI: 10.1111/jmg.70007
Lucas R. Schiavetti, Vinicius T. Meira, Sean Mulcahy, Jeffrey D. Vervoort, Peter L. Baker, George L. Luvizotto, Ricardo I. F. Trindade

Orogenic belts that sustain elevated temperatures at intermediate crustal depths for tens of millions of years are known as hot orogens. The evolution of these hot orogens is largely influenced by thermal maturation, primarily driven by the distribution of heat-producing elements (HPEs), such as K, Th and U in the overthickened crust. This process involves widespread anatexis, granulite facies metamorphism, extensive transfer of fluids and magma and large-scale crustal flow. Although most of the thermal evolution of hot orogens is controlled by HPEs, episodic heat transfer may also contribute to their geodynamic development. The Araçuaí orogen, located in southeastern Brazil, represents a Neoproterozoic hot orogen that exposes in its internal domain deeper levels of an overthickened crust, resembling the Tibetan plateau. Its evolution involves more than 120 million years of magmatism and metamorphism, including ultra-high-temperature metamorphism. Different geodynamic models have been suggested to explain the thermal evolution of this orogen, ranging from episodic heat sources within subduction-collisional orogeny to continuous long-lived heat sources in collisional or intracontinental settings. In this paper, we integrate detailed thermodynamic modelling, Lu–Hf and Sm–Nd garnet dating, and U–Pb and REE zircon data from an outcrop that includes granulite facies metasedimentary rocks (Nova Venecia complex) and an intrusive gabbroic stock (São Gabriel pluton). This key outcrop allows us to investigate the history of high-grade regional metamorphism within the internal domain of the Araçuaí orogen, as well as the thermal impact of the late-stage high-temperature magmatism on the later evolution of this hot orogen. Our data indicate that the studied rocks reached near-peak conditions (6.5–10 kbar and ~800°C) at 535–530 Ma and followed a near-isothermal decompression path to 5–6 kbar at ~530–520 Ma. Only local effects of contact metamorphism (~5 kbar and 900°C–1000°C) were observed along the contact between the gabbroic stock and its host rock. Based on this newly integrated dataset and the compilation of existing information, we argue that the Araçuaí orogen evolved from a single, continuous, long-lived heat source controlled by radiogenic decay from HPEs, rather than episodic advective heating from subduction/collision-related processes.

在中间地壳深处维持高温数千万年的造山带被称为热造山带。这些热造山带的演化在很大程度上受热成熟的影响,热成熟主要是由过热地壳中K、Th和U等产热元素的分布所驱动的。这一过程包括广泛的深熔作用、麻粒岩相变质作用、流体和岩浆的广泛转移以及大规模的地壳流动。虽然热造山带的热演化主要受hpe控制,但间歇性的热传递也可能对热造山带的地球动力学发展起作用。它的演化经历了超过1.2亿年的岩浆作用和变质作用,包括超高温变质作用。人们提出了不同的地球动力学模型来解释该造山带的热演化,从俯冲碰撞造山带中的偶发热源到碰撞或陆内环境中的连续长寿命热源。在本文中,我们整合了详细的热力学模拟、Lu-Hf和Sm-Nd石榴石定年、U-Pb和REE锆石数据,这些数据来自一个露头,包括麻粒岩相变质沉积岩(Nova Venecia杂岩)和侵入辉长岩(s o Gabriel岩体)。这一关键的露头使我们能够研究Araçuaí造山带内部域的高级别区域变质史,以及晚期高温岩浆活动对该热造山带后期演化的热影响。研究结果表明,岩石在535 ~530 Ma时达到近峰值状态(6.5 ~ 10 kbar和~800℃),在~530 ~ 520 Ma时达到近等温减压至5 ~ 6 kbar。接触变质作用(~ 5kbar, 900°C ~ 1000°C)仅在辉长岩与寄主岩石接触处发生。基于这一新整合的数据集和现有信息的汇编,我们认为Araçuaí造山带是从一个单一的、连续的、长寿命的热源演化而来的,该热源受HPEs放射性成因衰变的控制,而不是由俯冲/碰撞相关过程产生的偶发性平流加热。
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引用次数: 0
Tectonothermal Evolution of the NW Wyoming Province: Insights From Coupled Garnet Lu-Hf and Sm-Nd Geochronology 怀俄明州西北部构造热演化:来自石榴石Lu-Hf和Sm-Nd地质年代学的启示
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-08-17 DOI: 10.1111/jmg.70006
Tsai-Wei Chen, Jeff Vervoort, Julia Baldwin, Peter Baker

Understanding how Paleoproterozoic orogenic processes shaped the assembly of Laurentia remains a critical puzzle in deciphering Earth's ancient tectonic history. To address this challenge, the Montana metasedimentary terrane in the northwest Wyoming Province, which preserves a complex record of multiple metamorphic episodes, provides a unique opportunity. In this study, we integrate garnet composition with coupled Lu-Hf and Sm-Nd geochronology to unravel the polymetamorphic history of this terrane and constrain the timing and mechanisms of orogenic processes. Our new garnet Lu-Hf and Sm-Nd ages reveal three distinct age groups: 2.42, 2.19–2.06 and 1.83–1.70 Ga. Most analysed garnet samples demonstrate typical prograde zoning patterns with enriched Mn and Lu contents in their core, suggesting that the Lu-Hf ages from these samples reflect the timing of prograde metamorphism. The ~30 Myr younger Sm-Nd ages for most samples document the cooling process that followed peak metamorphic conditions during the orogenic cycle. One amphibolite sample shows reverse Lu zoning that likely resulted from mineral breakdown reactions, suggesting complex trace-element incorporation during high-grade metamorphic processes. By integrating our age data with the estimated peak metamorphic conditions reported by previous studies, we identify a spatial and temporal trend of decreasing metamorphic grade that progressed southeastward from the northwestern boundary of the terrane between 1.8 and 1.7 Ga. This pattern reveals a propagation of orogenic activity during the Big Sky orogeny, providing insights into the thermal evolution and incorporation of terranes during Laurentia assembly.

了解古元古代造山过程如何塑造劳伦西亚的组合,仍然是破译地球古代构造历史的一个关键难题。为了应对这一挑战,怀俄明州西北部的蒙大拿元沉积岩提供了一个独特的机会,它保存了多个变质期的复杂记录。在本研究中,我们将石榴石组成与耦合的Lu-Hf和Sm-Nd地质年代学结合起来,揭示了该地块的多变质历史,并限制了造山过程的时间和机制。我们的新石榴石Lu-Hf和Sm-Nd年龄显示了三个不同的年龄组:2.42、2.19-2.06和1.83-1.70 Ga。多数分析的石榴石样品显示出典型的前进变质带模式,其核心中Mn和Lu含量富集,表明这些样品的Lu- hf年龄反映了前进变质作用的时间。大多数样品的~30 Myr年轻Sm-Nd年龄记录了造山旋回期间峰值变质条件后的冷却过程。其中一个角闪岩样品显示出可能由矿物分解反应导致的反向Lu分带,表明在高变质过程中存在复杂的微量元素掺入。通过将年龄数据与前人报道的估计变质峰条件相结合,我们确定了在1.8 ~ 1.7 Ga之间,变质等级从地体西北边界向东南方向递减的时空趋势。该模式揭示了大天空造山运动期间造山活动的传播,为劳伦西亚组合期间地体的热演化和合并提供了见解。
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引用次数: 0
Fluid or Melt? Distinguishing Syn-Deformational Interaction Pathways 流动还是融化?区分同步变形相互作用途径
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-08-14 DOI: 10.1111/jmg.70008
Hindol Ghatak, Nathan R. Daczko, Sandra Piazolo, Tom Raimondo

Understanding whether deformation occurred in the presence of aqueous fluid or silicate melt is crucial for interpreting ductile shear zones, impacting their thermal and geochemical evolution, and having rheological consequences. To identify the syn-deformational fluid type, we investigate contrasting shear zones active during the Alice Springs Orogeny in central Australia, focusing on their effects on dry granulite facies gneisses transformed into greenschist–amphibolite facies schists. Shear zones in the north-western part of the orogen (Reynolds–Anmatjira Ranges) exhibit greenschist–lower amphibolite facies muscovite–chlorite assemblages, quartz veins and microstructures indicative of solid-state deformation. These features collectively suggest deformation in the presence of aqueous fluid. In contrast, shear zones in the south-eastern part (Strangways Range) display upper amphibolite facies garnet–biotite–sillimanite assemblages, along with granitic dykes and lenses retaining igneous textures. Microstructures, such as ‘string of bead’ textures and felsic minerals forming films along grain boundaries or exhibiting low apparent dihedral angles, indicate the former presence of melt in high strain rocks. This suggests that hydration in the south-eastern shear zones was driven by externally sourced silicate melt and melt–rock reactions. Differentiating between the two types of shear zones using whole rock major and trace element data is challenging. However, rare earth element (REE) analyses show potential. Limited REE metasomatism is observed where aqueous fluids are inferred, with three samples in a transect displaying consistent patterns. In contrast, where silicate melt is interpreted as the metasomatic agent, REE metasomatism is more variable, exhibiting atypical REE patterns relative to common rock types and considerable variability between samples in a transect. This contrast is attributed to greater mobility of REEs in silicate melt compared to aqueous fluid.

了解变形是否发生在含水流体或硅酸盐熔体存在的情况下,对于解释韧性剪切带、影响其热学和地球化学演化以及流变学后果至关重要。为了识别同变形流体类型,我们研究了澳大利亚中部爱丽斯泉造山运动期间活动的剪切带对比,重点研究了它们对干麻粒岩相片麻岩向绿片岩-角闪岩相片岩转变的影响。造山带西北部(Reynolds-Anmatjira Ranges)剪切带呈现绿片岩-下角闪岩相白云母-绿泥石组合、石英脉和显示固态变形的显微构造。这些特征共同表明在含水流体存在时发生了变形。东南部(Strangways Range)剪切带显示上部角闪岩相石榴石-黑云母-硅线岩组合,花岗岩岩脉和透镜体保留火成岩结构。微观结构,如“串珠”结构和长英质矿物沿晶界形成薄膜或表现出低表观二面角,表明在高应变岩石中以前存在熔体。这表明东南剪切带的水化作用是由外源硅酸盐熔体和熔融岩反应驱动的。利用全岩主量元素和微量元素数据来区分两种类型的剪切带是具有挑战性的。然而,稀土元素(REE)分析显示出潜力。在推断含水流体的地方观察到有限的稀土交代作用,在一个样带中有三个样品显示一致的模式。相比之下,当硅酸盐熔体被解释为交代介质时,稀土交代作用更加多变,相对于普通岩石类型表现出非典型的稀土模式,并且在样带中样品之间具有相当大的可变性。这种对比归因于硅酸盐熔体中稀土元素的流动性比含水流体大。
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引用次数: 0
Thermodynamic and Kinetic Controls on the Growth of Metapelitic Garnet in the Danba Dome (SW China): Insights From Microstructure, Element Mapping and Thermodynamic Modelling 丹巴巨丘变长石石榴石生长的热力学和动力学控制:来自微观结构、元素映射和热力学模型的见解
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-08-06 DOI: 10.1111/jmg.70005
Zhen M. G. Li, Fred Gaidies, Yi-Chao Chen, Jia-Shun Hu, Chun-Ming Wu

Understanding the growth history of metamorphic garnet is crucial for revealing metamorphic evolution and distinguishing thermodynamic and kinetic contributions during metamorphism. Garnet crystals in metapelites from a Barrovian-type metamorphic sequence in the Danba dome (SW China) record microstructural and compositional patterns that provide insights into the petrogenetic evolution of the samples during metamorphism. While sector-zoned garnet in graphite-rich layers and garnet crystals with trace element and microstructural evidence of biotite overgrowth are common in the lower grade garnet–staurolite–kyanite zones, these features are absent in the higher grade sillimanite zone. Reactions associated with accessory phases during garnet growth may explain the yttrium (Y) and heavy rare earth element (HREE) annuli observed in garnet of rocks from the garnet and staurolite zones. The absence of these Y and HREE annuli in garnet of rocks from the sillimanite zone is explained by variations in the bulk-rock composition of the samples, which resulted in different pressure–temperature (P–T) conditions of garnet-forming and accessory phase breakdown reactions (e.g., monazite–allanite transition). Whereas isopleth thermobarometry applied to the cores of the largest garnet crystals demonstrates initial garnet growth close to equilibrium in a rock that was collected very close to the garnet isograd, different degrees of driving force (~1.22.3 kJ per mole 12-oxygen garnet) were required for garnet nucleation in other rocks, pointing to varying reaction affinities for initial garnet growth. Garnet crystallization modelling for a rock from the garnet zone also predicts the observed mineral assemblages and garnet growth zoning exceptionally well and yields peak P–T conditions that are identical to the results obtained by conventional thermobarometry. Taken together, these results imply that the growth of metapelitic garnet in the Danba dome was controlled by both thermodynamic (e.g., P–T composition (X) relations) and kinetic (e.g., elemental mobility, protolith heterogeneity, reaction history, and chemical driving force for garnet nucleation) factors. This study underscores the specific impacts of these factors on the growth characteristics of metapelitic garnet in a regional metamorphic context.

了解变质石榴石的生长历史,对于揭示变质演化、区分变质过程中的热力学和动力学贡献具有重要意义。丹巴丘巴罗维亚型变质层序变质岩中的石榴石晶体记录了变质过程中样品的微观结构和组成模式,为研究变质过程中样品的成岩演化提供了依据。在低品位石榴石—星绿岩—蓝晶石带中,富石墨层中的石榴石呈扇形分布,石榴石晶体具有微量元素和黑云母过度生长的显微结构证据,而在高品位硅线石岩带中则不存在这些特征。石榴石生长过程中与副相相关的反应可以解释石榴石和星橄榄岩带岩石中石榴石中观察到的钇(Y)和重稀土元素(HREE)环空。硅线石岩带的石榴石中不存在这些Y和HREE环空,这可以解释为样品的体岩组成的变化,这导致了石榴石形成和副相分解反应(如独居石- allanite转变)的不同压力-温度(P-T)条件。虽然应用于最大石榴石晶体岩心的等径热压测量显示,在非常接近石榴石等径的岩石中,石榴石的初始生长接近平衡,但在其他岩石中,石榴石成核需要不同程度的驱动力(~ 1.2-2.3 kJ / mol 12氧石榴石),这表明初始石榴石生长的反应亲和力不同。对石榴石带岩石的石榴石结晶模型也能很好地预测观察到的矿物组合和石榴石生长分区,并产生与常规热气压计相同的峰值P-T条件。综上所述,丹巴圆丘中变长石石榴石的生长受热力学(如P-T组成(X)关系)和动力学(如元素迁移率、原岩非均质性、反应历史和石榴石成核的化学驱动力)因素的双重控制。本研究强调了这些因素对区域变质背景下变长岩石榴石生长特征的具体影响。
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引用次数: 0
Calibration, Validation and Evaluation of Machine Learning Thermobarometers in Metamorphic Petrology: An Application to Biotite and Outlook for Future Strategy 变质岩石学中机器学习温度计的校准、验证和评估:在黑云母上的应用及未来策略展望
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-07-31 DOI: 10.1111/jmg.70004
Philip Hartmeier, Jacob B. Forshaw, Pierre Lanari

Geothermobarometry provides crucial constraints on the physical conditions of metamorphism, offering insights into petrogenetic processes and providing key information on thermal regimes and metamorphic depths to other geological disciplines. However, calibrating a thermobarometer from the natural record is challenging because independent pressure (P) and temperature (T) estimates are required, and the compositional variation of minerals—governed by multiple metamorphic reactions—must be captured in a complex function. This work calibrates a machine learning thermobarometer for biotite using relative PT estimates based on mineral assemblage sequences. A neural network is used as a flexible model to fit a high-dimensional thermobarometric regression curve. To address the challenge of sparse training data, a transfer learning strategy is employed, where the model is primarily trained on a large dataset generated with phase equilibrium modelling before refinement with natural data. A general framework for calibrating machine learning thermobarometers is outlined using a neural network thermobarometer for biotite as an example. Selection of the best-performing model is guided by k-fold cross-validation alongside complementary accuracy checks using metamorphic sequences and precision assessments via Monte Carlo error propagation. Evaluation on an independent test dataset, compiled from the literature, indicates that the model is a potential biotite single-crystal thermometer with a root mean square error of ± 45°C, consistent with the estimated uncertainty of Ti-in-Bt thermometry applied to the same data. A potential barometer is affected by systematic underestimation of pressures above 0.6 GPa due to regression to the mean of the natural database, which is biased towards low-pressure metamorphism. This limits its applicability in higher-pressure regimes. This study highlights the potential of using neural networks with transfer learning in petrological applications since they are often constrained by limited natural data.

地温测压法对变质作用的物理条件提供了关键的约束,为岩石形成过程提供了见解,并为其他地质学科提供了热状态和变质深度的关键信息。然而,从自然记录中校准温度计是具有挑战性的,因为需要独立的压力(P)和温度(T)估计,并且矿物的成分变化(由多重变质反应控制)必须在一个复杂的函数中捕获。这项工作使用基于矿物组合序列的相对P-T估计校准黑云母的机器学习温度计。采用神经网络作为柔性模型拟合高维热气压回归曲线。为了解决稀疏训练数据的挑战,采用了一种迁移学习策略,在使用自然数据进行细化之前,模型首先在由相平衡建模生成的大型数据集上进行训练。以黑云母神经网络温度计为例,概述了校准机器学习温度计的一般框架。最佳表现模型的选择由k-fold交叉验证指导,同时使用变质序列进行互补精度检查,并通过蒙特卡罗误差传播进行精度评估。根据文献编制的独立测试数据集进行的评估表明,该模型是一个潜在的黑云母单晶温度计,其均方根误差为±45°C,与应用于相同数据的Ti-in-Bt测温法的估计不确定度一致。由于回归到自然数据库的平均值,系统地低估了0.6 GPa以上的压力,这对潜在的气压表有影响,这偏向于低压变质作用。这限制了它在高压环境中的适用性。这项研究强调了在岩石学应用中使用神经网络和迁移学习的潜力,因为它们通常受到有限的自然数据的限制。
{"title":"Calibration, Validation and Evaluation of Machine Learning Thermobarometers in Metamorphic Petrology: An Application to Biotite and Outlook for Future Strategy","authors":"Philip Hartmeier,&nbsp;Jacob B. Forshaw,&nbsp;Pierre Lanari","doi":"10.1111/jmg.70004","DOIUrl":"https://doi.org/10.1111/jmg.70004","url":null,"abstract":"<p>Geothermobarometry provides crucial constraints on the physical conditions of metamorphism, offering insights into petrogenetic processes and providing key information on thermal regimes and metamorphic depths to other geological disciplines. However, calibrating a thermobarometer from the natural record is challenging because independent pressure (<i>P</i>) and temperature (<i>T</i>) estimates are required, and the compositional variation of minerals—governed by multiple metamorphic reactions—must be captured in a complex function. This work calibrates a machine learning thermobarometer for biotite using relative <i>P</i>–<i>T</i> estimates based on mineral assemblage sequences. A neural network is used as a flexible model to fit a high-dimensional thermobarometric regression curve. To address the challenge of sparse training data, a transfer learning strategy is employed, where the model is primarily trained on a large dataset generated with phase equilibrium modelling before refinement with natural data. A general framework for calibrating machine learning thermobarometers is outlined using a neural network thermobarometer for biotite as an example. Selection of the best-performing model is guided by <i>k</i>-fold cross-validation alongside complementary accuracy checks using metamorphic sequences and precision assessments via Monte Carlo error propagation. Evaluation on an independent test dataset, compiled from the literature, indicates that the model is a potential biotite single-crystal thermometer with a root mean square error of ± 45°C, consistent with the estimated uncertainty of Ti-in-Bt thermometry applied to the same data. A potential barometer is affected by systematic underestimation of pressures above 0.6 GPa due to regression to the mean of the natural database, which is biased towards low-pressure metamorphism. This limits its applicability in higher-pressure regimes. This study highlights the potential of using neural networks with transfer learning in petrological applications since they are often constrained by limited natural data.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 8","pages":"755-780"},"PeriodicalIF":3.4,"publicationDate":"2025-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.70004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145022369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Applications of Quartz-in-Garnet Elastic Geobarometry to Mid-Crustal Barrovian Metamorphic Rocks Demonstrated Using Tensionally Stressed Inclusions From the Grand Canyon 用大峡谷拉应力包裹体证明石榴石中石英弹性地压测量在中地壳巴罗威变质岩中的应用
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-07-01 DOI: 10.1111/jmg.70002
Suzanne Autrey, Chloe Bonamici, Michael L. Williams

Quartz-in-garnet elastic geobarometry (QuiG) pressures were obtained for inclusions exhumed from low-to-moderate pressure and moderate-to-high temperature Barrovian metamorphic conditions. Exhumation from these conditions causes quartz inclusions to expand less than their garnet hosts and experience tensional stresses. Most of the inclusions analysed in this study had near zero strains and stresses, which can preclude the ability to identify entrapped inclusions. New methods for identifying inclusion strains related to entrapment when the results cluster near zero were applied, revealing a population of tensile inclusions related to entrapment during metamorphism. Three hundred twenty-three inclusions were analysed from rock samples from the Upper Granite Gorge of the Grand Canyon. Inclusion remnant pressures were calculated using (1) shifted Raman modes assuming hydrostatic stress and (2) strains and the phonon-mode Grüneisen tensor of quartz. A range of entrapment pressures was determined for each garnet, but careful inspection of the inclusions and statistical analysis of the data sets successfully identified and removed inclusions that returned spurious results. QuiG yielded robust entrapment pressure estimates using the two different elastic geobarometry approaches. In this study, the refined QuiG technique yielded entrapment pressures that are consistent with the known geology of upper greenschist facies and upper amphibolite facies schists from the base of the Grand Canyon. Results from a zoned garnet grain show that multiple pressure populations can be preserved in a single garnet. The new QuiG results have implications for the robustness of QuiG in Barrovian rocks, where strains in inclusions can be near zero, and the ability of inclusions to retain early pressure information after being subjected to subsequent high-grade metamorphism.

对低至中压和中至高温巴罗威变质条件下出土的包裹体进行了石英-石榴石弹性地压测量(QuiG)。在这些条件下的挖掘导致石英包裹体的膨胀小于其石榴石宿主,并经历张应力。在本研究中分析的大多数包裹体具有接近零的应变和应力,这可以排除识别包裹体的能力。当结果聚类接近零时,应用新方法识别与夹带有关的包裹体应变,揭示了变质作用期间与夹带有关的拉伸包裹体种群。从大峡谷上花岗岩峡谷的岩石样本中分析了323个内含物。采用(1)假设静水应力和(2)应变的位移拉曼模和石英的声子模grisen张量计算包体残余压力。确定了每种石榴石的夹带压力范围,但对包裹体的仔细检查和对数据集的统计分析成功地识别并去除了返回虚假结果的包裹体。QuiG使用两种不同的弹性地球气压测量方法得出了可靠的圈闭压力估计。在这项研究中,改进的QuiG技术获得的圈闭压力与大峡谷底部上部绿片岩相和上部角闪岩相片岩的已知地质一致。从一个带状石榴石晶粒的结果表明,在一个石榴石中可以保存多个压力种群。新的QuiG结果对巴罗维岩中QuiG的稳健性(包裹体中的应变可能接近于零)以及包裹体在遭受随后的高变质作用后保留早期压力信息的能力具有重要意义。
{"title":"Applications of Quartz-in-Garnet Elastic Geobarometry to Mid-Crustal Barrovian Metamorphic Rocks Demonstrated Using Tensionally Stressed Inclusions From the Grand Canyon","authors":"Suzanne Autrey,&nbsp;Chloe Bonamici,&nbsp;Michael L. Williams","doi":"10.1111/jmg.70002","DOIUrl":"https://doi.org/10.1111/jmg.70002","url":null,"abstract":"<div>\u0000 \u0000 <p>Quartz-in-garnet elastic geobarometry (QuiG) pressures were obtained for inclusions exhumed from low-to-moderate pressure and moderate-to-high temperature Barrovian metamorphic conditions. Exhumation from these conditions causes quartz inclusions to expand less than their garnet hosts and experience tensional stresses. Most of the inclusions analysed in this study had near zero strains and stresses, which can preclude the ability to identify entrapped inclusions. New methods for identifying inclusion strains related to entrapment when the results cluster near zero were applied, revealing a population of tensile inclusions related to entrapment during metamorphism. Three hundred twenty-three inclusions were analysed from rock samples from the Upper Granite Gorge of the Grand Canyon. Inclusion remnant pressures were calculated using (1) shifted Raman modes assuming hydrostatic stress and (2) strains and the phonon-mode Grüneisen tensor of quartz. A range of entrapment pressures was determined for each garnet, but careful inspection of the inclusions and statistical analysis of the data sets successfully identified and removed inclusions that returned spurious results. QuiG yielded robust entrapment pressure estimates using the two different elastic geobarometry approaches. In this study, the refined QuiG technique yielded entrapment pressures that are consistent with the known geology of upper greenschist facies and upper amphibolite facies schists from the base of the Grand Canyon. Results from a zoned garnet grain show that multiple pressure populations can be preserved in a single garnet. The new QuiG results have implications for the robustness of QuiG in Barrovian rocks, where strains in inclusions can be near zero, and the ability of inclusions to retain early pressure information after being subjected to subsequent high-grade metamorphism.</p>\u0000 </div>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 7","pages":"734-753"},"PeriodicalIF":3.4,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144767665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of Water Contents Between Ultrahigh-Pressure Oceanic and Continental Eclogites From the North Qaidam Orogen 柴达木北造山带超高压洋陆榴辉岩水分含量比较
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-26 DOI: 10.1111/jmg.70003
Ren-Xu Chen, Zhi-Min Wang, Bing Gong, Xiang-Ping Zha, Yuan Gao

Water storage and transport in eclogite are critical for the water cycle in subduction zones. A combined study of the petrology and water contents of nominally anhydrous minerals (NAMs) was carried out on oceanic and continental eclogites from the North Qaidam orogen. The results are used to compare the presence, abundance and behaviour of free fluids of subducting mafic crust at subarc depths between oceanic and continental subduction zones and to further investigate the water storage and transport in subducting mafic crust with respect to the geothermal gradients of subduction zones. Both oceanic and continental eclogites experienced Alpine-type ultrahigh-pressure (UHP) metamorphism with similar P–T paths. The hydrogen incorporation of OH modes at 3450–3470 and 3600–3630 cm−1 in omphacite is controlled by the classical mechanism (H++Al3+ → Si4+). The OH mode at 3510–3540 cm−1 in omphacite is mainly controlled by the Ca and Na contents at the M2 site. The primary structural water content of garnet is positively correlated with temperature, indicating that temperature plays an important role in hydrogen incorporation into garnet during the high-pressure (HP) to UHP metamorphic transition. In contrast, the water content of omphacite does not differ between HP and UHP eclogite-facies conditions. This observation suggests different hydrogen incorporation between garnet and omphacite in response to P–T changes. Garnet and omphacite in oceanic and continental eclogites exhibit similar primary structural water contents under UHP conditions, indicating that the subducting mafic crust in the oceanic and continental subduction zones experienced similar water storage and transport during the HP-to-UHP metamorphic transition despite their different protolith natures. The eclogites that experienced different P–T paths exhibited different water contents under HP and UHP conditions, indicating that water storage and transport in the subducting mafic crust are controlled by the geothermal gradients of subduction zones rather than by the protoliths. An elevated thermal gradient enhances the decomposition of hydrous minerals and the incorporation of hydrogen into NAMs. A large amount of water is released from the subducting mafic crust during prograde Alpine-type HP eclogite-facies metamorphism, resulting in less water left to be released during further Alpine-type HP-to-UHP eclogite-facies transitions.

榴辉岩中的储水和输水对俯冲带的水循环至关重要。对柴达木北造山带洋、陆榴辉岩进行了名义无水矿物(NAMs)的岩石学和水组分的综合研究。利用这些结果比较了大洋和大陆俯冲带之间亚弧深度俯冲基性地壳自由流体的存在、丰度和行为,并从俯冲带地温梯度的角度进一步研究了俯冲基性地壳的储水和输运。海相榴辉岩和陆相榴辉岩均经历了阿尔卑斯型超高压变质作用,P-T路径相似。在3450 ~ 3470和3600 ~ 3630 cm−1处,辉石中OH−模式的氢掺入受经典机制(H++Al3+→Si4+)控制。红辉石在3510 ~ 3540 cm−1处的OH−模式主要受M2位点Ca和Na含量的控制。石榴石初级结构含水量与温度呈正相关,表明在高压变质向超高压变质转变过程中,温度对石榴石含氢起重要作用。相比之下,高压和超高压榴辉岩相条件下辉辉岩的含水量没有差异。这一观察结果表明,石榴石和辉石之间的氢结合不同,以响应P-T的变化。海陆榴辉岩中的石榴石和辉长石在超高压条件下表现出相似的初级构造水含量,表明海陆俯冲带的俯冲基性地壳虽然原岩性质不同,但在高压-超高压变质转变过程中经历了相似的储水输运过程。经历不同P-T路径的榴辉岩在高压和超高压条件下表现出不同的含水量,表明俯冲基性地壳中的水分储存和输送受俯冲带地温梯度控制,而不是受原岩控制。升高的热梯度促进了含水矿物的分解和氢与纳米颗粒的结合。在高寒型高压榴辉岩相递进变质过程中,俯冲基性地壳释放出大量的水,导致高寒型高压榴辉岩相进一步向超高压榴辉岩相转变时,释放出的水较少。
{"title":"Comparison of Water Contents Between Ultrahigh-Pressure Oceanic and Continental Eclogites From the North Qaidam Orogen","authors":"Ren-Xu Chen,&nbsp;Zhi-Min Wang,&nbsp;Bing Gong,&nbsp;Xiang-Ping Zha,&nbsp;Yuan Gao","doi":"10.1111/jmg.70003","DOIUrl":"https://doi.org/10.1111/jmg.70003","url":null,"abstract":"<div>\u0000 \u0000 <p>Water storage and transport in eclogite are critical for the water cycle in subduction zones. A combined study of the petrology and water contents of nominally anhydrous minerals (NAMs) was carried out on oceanic and continental eclogites from the North Qaidam orogen. The results are used to compare the presence, abundance and behaviour of free fluids of subducting mafic crust at subarc depths between oceanic and continental subduction zones and to further investigate the water storage and transport in subducting mafic crust with respect to the geothermal gradients of subduction zones. Both oceanic and continental eclogites experienced Alpine-type ultrahigh-pressure (UHP) metamorphism with similar P–T paths. The hydrogen incorporation of OH<sup>−</sup> modes at 3450–3470 and 3600–3630 cm<sup>−1</sup> in omphacite is controlled by the classical mechanism (H<sup>+</sup>+Al<sup>3+</sup> → Si<sup>4+</sup>). The OH<sup>−</sup> mode at 3510–3540 cm<sup>−1</sup> in omphacite is mainly controlled by the Ca and Na contents at the M2 site. The primary structural water content of garnet is positively correlated with temperature, indicating that temperature plays an important role in hydrogen incorporation into garnet during the high-pressure (HP) to UHP metamorphic transition. In contrast, the water content of omphacite does not differ between HP and UHP eclogite-facies conditions. This observation suggests different hydrogen incorporation between garnet and omphacite in response to P–T changes. Garnet and omphacite in oceanic and continental eclogites exhibit similar primary structural water contents under UHP conditions, indicating that the subducting mafic crust in the oceanic and continental subduction zones experienced similar water storage and transport during the HP-to-UHP metamorphic transition despite their different protolith natures. The eclogites that experienced different P–T paths exhibited different water contents under HP and UHP conditions, indicating that water storage and transport in the subducting mafic crust are controlled by the geothermal gradients of subduction zones rather than by the protoliths. An elevated thermal gradient enhances the decomposition of hydrous minerals and the incorporation of hydrogen into NAMs. A large amount of water is released from the subducting mafic crust during prograde Alpine-type HP eclogite-facies metamorphism, resulting in less water left to be released during further Alpine-type HP-to-UHP eclogite-facies transitions.</p>\u0000 </div>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"43 7","pages":"706-733"},"PeriodicalIF":3.4,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144768052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Metamorphic Geology
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