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Isothermal compression of an eclogite from the Western Gneiss Region (Norway) 挪威西片麻岩区榴辉岩的等温压缩
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-09-15 DOI: 10.1111/jmg.12692
Martin Simon, Pavel Pitra, Philippe Yamato, Marc Poujol

In the Western Gneiss Region in Norway, mafic eclogites form lenses within granitoid orthogneiss and contain the best record of the pressure and temperature evolution of this ultrahigh-pressure (UHP) terrane. Their exhumation from the UHP conditions has been extensively studied, but their prograde evolution has been rarely quantified although it represents a key constraint for the tectonic history of this area. This study focused on a well-preserved phengite-bearing eclogite sample from the Nordfjord region. The sample was investigated using phase-equilibrium modelling, trace-element analyses of garnet, trace- and major-element thermobarometry and quartz-in-garnet barometry by Raman spectroscopy. Inclusions in garnet core point to crystallization conditions in the amphibolite facies at 510–600°C and 11–16 kbar, whereas chemical zoning in garnet suggests growth during isothermal compression up to the peak pressure of 28 kbar at 600°C, followed by near-isobaric heating to 660–680°C. Near-isothermal decompression to 10–14 kbar is recorded in fine-grained clinopyroxene–amphibole–plagioclase symplectites. The absence of a temperature increase during compression seems incompatible with the classic view of crystallization along a geothermal gradient in a subduction zone and may question the tectonic significance of eclogite facies metamorphism. Two end-member tectonic scenarios are proposed to explain such an isothermal compression: Either (1) the mafic rocks were originally at depth within the lower crust and were consecutively buried along the isothermal portion of the subducting slab or (2) the mafic rocks recorded up to 14 kbar of tectonic overpressure at constant depth and temperature during the collisional stage of the orogeny.

在挪威西部片麻岩区,镁铁质榴辉岩在花岗质正片麻岩中形成透镜体,并包含了该超高压(UHP)地体压力和温度演化的最佳记录。它们在超高压条件下的剥露已经得到了广泛的研究,但它们的前进演化很少被量化,尽管这是该地区构造史的一个关键制约因素。本研究的重点是来自Nordfjord地区的一个保存完好的含多硅榴辉岩样品。使用相平衡模型、石榴石微量元素分析、微量元素和主元素热压测量法以及拉曼光谱的石英石榴石内压测量法对样品进行了研究。石榴石岩芯中的包裹体表明在510–600°C和11–16°C的角闪岩相中存在结晶条件 kbar,而石榴石中的化学分区表明在等温压缩至28的峰值压力期间生长 kbar,600°C,然后近等压加热至660–680°C。近等温减压至10-14 kbar记录在细粒单斜辉石-角闪石-斜长石的杂合岩中。压缩过程中没有温度升高,这似乎与俯冲带中沿地热梯度结晶的经典观点不一致,并可能质疑榴辉岩相变质作用的构造意义。提出了两种端元构造场景来解释这种等温压缩:(1)镁铁质岩石最初位于下地壳深处,并沿着俯冲板的等温部分连续埋藏;或(2)记录的镁铁质岩石多达14 造山运动碰撞阶段恒定深度和温度下构造超压的kbar。
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引用次数: 5
Thermal pulse induced by emplacement of Ramba leucogranites in southern Tibet 藏南兰巴浅花岗岩体侵位引起的热脉冲
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-09-01 DOI: 10.1111/jmg.12690
Xu Chu, Ozan Akça, Fred Gaidies, Ivano Gennaro, Weiqiang Ji

The thermal histories of Himalayan leucogranites provide critical information for unravelling the post-collisional geodynamics of the Himalayas. The Ramba Dome is located at the intersection of the Tethyan Himalayan leucogranite belt with the Yadong–Gulu Rift and hosts several generations of granitic intrusions. Of these intrusions, the 8-Ma two-mica granites and garnet leucogranite dykes are the youngest of Himalayan leucogranites. In this study, we focus on the carbonaceous staurolite schist located ~1.3 km from the intrusion to constrain the thermal history of the aureole that marked the cessation of leucogranite magmatism. The schist contains euhedral garnet and staurolite porphyroblasts in a foliated matrix of muscovite + biotite + chlorite + plagioclase + quartz + graphite. The staurolite shows minor compositional variations from the inclusion-free core to the inclusion-rich rim. By contrast, the garnet features a distinctive bell-shaped Mn profile and increasing Mg# from the garnet core to rims. In a graphite-bearing equilibrium phase diagram for a modified bulk composition with garnet cores removed, the garnet rim composition suggests a peak temperature of ~550°C, consistent with an independent thermometer based on the Raman spectra of carbonaceous materials (RSCM; 548 ± 9°C). The P–T condition lies within the narrow low-variance field bracketed by the staurolite-in and chlorite-out boundaries, indicating minimal overstepping of staurolite nucleation and growth. On the other hand, the garnet core composition indicates 520°C at 2.5 kbar, about 40°C higher than the predicted garnet-in boundary (~480°C). This apparent temperature overstep corresponds to a small chemical affinity (<5 kJ/mol 12 O) for garnet nucleation, comparable to previous estimates. The sharp boundaries of the high-Ca sector zoning in the core indicate limited diffusion modification (~1.5 Ma if at the peak temperature). The short thermal pulse involves advective heat transfer by leucogranite emplacement, followed by rapid cooling toward the end of Himalayan magmatism and rapid exhumation likely facilitated by the Yadong–Gulu Rift.

喜马拉雅隐色花岗岩的热历史为揭示喜马拉雅碰撞后的地球动力学提供了关键信息。Ramba穹隆位于特提斯-喜马拉雅淡色花岗岩带与亚东-咕噜裂谷的交汇处,并存在几代花岗岩侵入体。在这些侵入体中,8‐Ma双云母花岗岩和石榴石浅色花岗岩脉是喜马拉雅浅色花岗岩中最年轻的。在这项研究中,我们重点研究了距离侵入体约1.3公里的碳质十字石片岩,以限制标志着浅色花岗岩岩浆作用停止的Aurele的热历史。片岩在白云母的叶理基质中含有自形石榴石和十字石斑晶 + 黑云母 + 绿泥石 + 斜长石 + 石英 + 石墨从无夹杂物的核心到富含夹杂物的边缘,十字石显示出微小的成分变化。相比之下,石榴石具有独特的钟形Mn剖面,从石榴石核心到边缘的Mg#不断增加。在去除石榴石核的改性体成分的含石墨平衡相图中,石榴石边缘成分表明峰值温度约为550°C,与基于碳质材料拉曼光谱的独立温度计一致(RSCM;548 ± 9°C)。P–T条件位于由十字石入界和绿泥石出界包围的狭窄低方差场内,表明十字石成核和生长的越界程度最小。另一方面,石榴石核心成分表明在2.5 kbar时为520°C,比预测的石榴石边界(~480°C)高出约40°C。这种表观温度超越对应于石榴石成核的小化学亲和力(<5 kJ/mol 12 O),与之前的估计相当。堆芯中高Ca扇形区带的尖锐边界表明扩散改性有限(如果在峰值温度下,约1.5 Ma)。短的热脉冲涉及浅色花岗岩侵位的平流热传递,随后喜马拉雅岩浆作用结束时的快速冷却和亚东-古陆裂谷可能促进的快速剥露。
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引用次数: 1
Significance of selective crystal entrainment and differential crystal-melt separation in petrogenesis of granites from the Tongbai orogen 选择性晶体夹带和差异晶体熔体分离在桐柏造山带花岗岩成因中的意义
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-09-01 DOI: 10.1111/jmg.12691
Qiang-Qiang Zhang, Xiao-Ying Gao, Yong-Fei Zheng
<p>Partial melting has been shown to be an important mechanism for intracrustal differentiation and granite petrogenesis. However, a series of compositional differences between granitic melt from experiments and natural granites indicate that the processes of crustal differentiation are complex. To shed light on factors that control the processes of crustal differentiation, and then the compositions of granitic magma, a combined study of petrology and geochemistry was carried out for granites (in the forms of granitic veins and parautochthonous granite) from a granulite terrane in the Tongbai orogen, China. These granites are characterized by high SiO<sub>2</sub> (>72 wt%) and low FeO and MgO (<4 wt%) with low Na<sub>2</sub>O/K<sub>2</sub>O ratios (<0.7). Minerals in these granites show variable microstructures and compositions. Phase equilibrium modelling using P–T pseudosections shows that neither anatectic melts nor fractionated melts match the compositions of the target granites, challenging the conventional paradigm that granites are the crystallized product of pure granitic melts. Based on the microstructural features of minerals in the granites, and a comparison of their compositions with crystallized minerals from anatectic melts and minerals in granulites, the minerals in these granitoids are considered to have three origins. The first is entrained garnets, which show comparable compositions with those in host granulites. The second is early crystallized mineral from melts, which include large plagioclase and K-feldspar (with high Ca contents) crystals as well as a part of biotite whose compositions can be reproduced by crystallization of the anatectic melts. The compositions of other minerals such as small grained plagioclase, K-feldspar and anorthoclase in the granites with low Ca contents are not well reconstructed, so they are considered as the third origin of crystallized products of fractionated melts. The results of mass balance calculation show that the compositions of these granites can be produced by mixing between different proportions of crystallized minerals and fractionated melts with variable amounts of entrained minerals. However, the calculated modal proportions of different crystallized minerals (plagioclase, K-feldspar, biotite and quartz) in the granites are significantly different from those predicted by melt crystallization modelling. Specifically, some rocks have lower modes of biotite and plagioclase, whereas others show lower K-feldspar modes than those produced by melt crystallization. This indicates that the crystallized minerals would be differentially separated from the primary magmas to form the evolved magmas that produce these granites. Therefore, the crystal entrainment and differential melt-crystal separation make important contributions to the composition of the target granites. Compared with leucogranites worldwide, the target granites show comparable compositions. As such, the leucogranites m
部分熔融已被证明是地壳内分异和花岗岩成因的重要机制。然而,实验花岗岩熔体与天然花岗岩的一系列成分差异表明,地壳分异过程是复杂的。为了揭示控制地壳分异过程的因素,进而揭示花岗质岩浆的组成,对桐柏造山带某花岗质地体中的花岗质花岗岩(花岗脉和副原生花岗质)进行了岩石学和地球化学联合研究。这些花岗岩具有高SiO2(约72 wt%)、低FeO和MgO (<4 wt%)、低Na2O/K2O比值(<0.7)的特点。这些花岗岩中的矿物表现出不同的微观结构和组成。使用P-T伪剖面的相平衡模型显示,无熔熔体和分馏熔体都与目标花岗岩的成分不匹配,挑战了花岗岩是纯花岗岩熔体结晶产物的传统范式。根据花岗岩中矿物的显微结构特征,并与无水熔体的结晶矿物和麻粒岩中的矿物组成进行比较,认为这些花岗岩中的矿物有三个成因。第一种是夹带石榴石,其组成与寄主麻粒岩相当。第二种是熔体中的早期结晶矿物,包括大斜长石和钾长石(钙含量高)晶体,以及部分黑云母,其成分可以通过熔净熔体的结晶重现。低钙花岗岩中小粒斜长石、钾长石、斜长石等矿物组成重构不佳,可认为是分选熔体结晶产物的第三来源。质量平衡计算结果表明,这些花岗岩的组成可以由不同比例的结晶矿物和分选熔体混合产生,并带有不同数量的夹带矿物。然而,花岗岩中不同结晶矿物(斜长石、钾长石、黑云母和石英)的模态比例计算结果与熔融结晶模型预测结果存在显著差异。具体来说,一些岩石具有较低的黑云母和斜长石模式,而另一些岩石则具有较低的钾长石模式。这表明结晶矿物将不同地从原始岩浆中分离出来,形成产生这些花岗岩的演化岩浆。因此,晶体夹带作用和熔融-晶体分异作用对目标花岗岩的组成有重要贡献。与世界范围内的浅花岗岩相比,目标花岗岩的成分具有可比性。因此,除了不同程度的部分熔融作用外,浅花岗岩体可能是由原生花岗岩浆在不同程度上的结晶分馏形成的。
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引用次数: 0
Low temperature eclogite facies rocks discovered in the Eastern Himalayan Syntaxis: Poly-cyclic metamorphic evolution and implications 喜马拉雅造山带东部发现的低温榴辉岩相岩石:多旋回变质演化及其意义
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-08-19 DOI: 10.1111/jmg.12689
Wangchao Li, Changqing Yin, Zeming Zhang, Peter A. Cawood, Shun Li, Jian Zhang, Huixia Ding, Jiahui Qian, Yanling Zhang

We report the first occurrence of poly-cyclic high-pressure low-temperature (HP-LT) rocks from the easternmost Indus-Yarlung suture zone, formed during subduction of Neo-Tethyan oceanic lithosphere. Petrology, mineral composition and P–T pseudosection modelling reveal two low-temperature eclogite facies metamorphic events with an initial high-pressure P–T condition of 16.4–18.7 kbar and 510–520°C, exhumation to 10.5–12.0 kbar and 580–590°C and a subsequent second high-pressure P–T condition of ~16 kbar and ~560°C and exhumation to ≤9 kbar and ≤600°C. This history implies a complex ‘yo-yo type’ P–T path. In situ monazite dating and textural relationships show that late-stage exhumation, cooling and garnet breakdown occurred at c. ~25–22 Ma. We interpret the first burial event to represent subduction of the Neo-Tethys Ocean at the eastern Indus-Yarlung suture zone. Initial exhumation, reburial and final exhumation represent material transport in a large-scale convective circulation system in the subduction channel. Convective overturn in the subduction channel evidently serves both as a mechanism to produce poly-cyclic metamorphism and to exhume LT eclogite facies rocks.

我们报告了印度河-雅鲁藏河最东部缝合带首次出现的多旋回高压低温(HP‐LT)岩石,形成于新特提斯洋岩石圈的俯冲过程中。岩石学、矿物成分和P–T假剖面建模揭示了两个低温榴辉岩相变质事件,初始高压P–T条件为16.4–18.7 kbar和510–520°C,挖掘至10.5–12.0 kbar和580–590°C以及随后约16的第二个高压P–T条件 kbar和~560°C,挖掘至≤9 kbar且≤600°C。这段历史意味着一条复杂的“溜溜球型”P–T路径。原位独居石测年和结构关系表明,晚期剥露、冷却和石榴石破碎发生在约25–22年 马。我们将第一次埋藏事件解释为新特提斯洋在印度河-雅鲁藏河缝合带东部的俯冲。最初的挖掘、重新埋葬和最终的挖掘代表了俯冲通道中大规模对流环流系统中的物质运输。俯冲通道中的对流翻转显然既是产生多旋回变质作用的机制,也是剥露LT榴辉岩相岩石的机制。
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引用次数: 1
P–T–t–D records of Early Palaeozoic Andean-type shortening of a hot active margin: The Dunhuang block in NW China 早古生代热活动边缘安第斯型缩短的P-T-t-D记录:中国西北敦煌地块
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-08-11 DOI: 10.1111/jmg.12688
Jérémie Soldner, Pavla Štípská, Karel Schulmann, Chao Yuan, Robert Anczkiewicz, Yingde Jiang, Marta Koziarska, Le Zhang, Yunying Zhang, Xinyu Wang
<p>High-pressure (H<i>P</i>) granulites form either in the domain of the subducted plate during continental collision or in supra-subduction systems where the thermally softened upper plate is shortened and thickened. Such a discrepancy in tectonic setting can be evaluated by metamorphic pressure–temperature–time-deformation (<i>P–T–t–D</i>) paths. In the current study, <i>P–T–t–D</i> paths of Early Palaeozoic H<i>P</i> granulite facies rocks, in the form of metabasic lenses enclosed in migmatitic metapelite, from the Dunhuang block, NW China, are investigated in order to constrain the nature of the H<i>P</i> rocks and shed light on the geodynamic evolution of a modern hot orogenic system in an active margin setting. The rocks show a polyphase evolution characterized by (1) relics of horizontal or gently dipping fabric (S1) preserved in cores of granulite lenses and in garnet porphyroblasts, (2) a N-S trending sub-vertical fabric (S2) preserved in low-strain domains and (3) upright folds (F3) associated with a ubiquitous steep E-W striking axial planar foliation (S3). Garnet in the granulites preserves relics of a prograde mineral assemblage M1a equilibrated at ~11.5 kbar and ~770–780°C, whereas the matrix granulite assemblage (M1b) from the S1 fabric attained peak pressure at ~13.5 kbar and ~850°C. The granulites were overprinted at ~8–11 kbar and ~850–900°C during crustal melting (M2) followed by partial re-equilibration (M3) at ~8 kbar and ~625°C. A garnet Lu–Hf age of 421.6 ± 1.2 Ma dates metamorphism M1, while a garnet Sm–Nd age of 385.3 ± 4.0 Ma reflects M3 cooling of the granulites. The mineral assemblage, M1, of the host migmatitic metapelite formed at ~9–12.5 kbar and ~760–810°C, partial melting and migmatization (M2) occurred at ~7 kbar and ~760°C and re-equilibration (M3) at ~5–6 kbar and ~675°C. A garnet Lu–Hf age of 409.7 ± 2.3 Ma dates thermal climax (M2) and a garnet Sm–Nd age of 356 ± 11 Ma constrains M3 for the migmatitic metapelites. The timing of this late phase is also bracketed by an emplacement age of syntectonic granite dated at c. 360 Ma. Decoupling of M1 and M2 <i>P–T</i> evolutions between the mafic granulites and migmatitic metapelites indicates their different positions in the crustal column, while the shared pressure–temperature (<i>P–T</i>) evolution M3 suggests formation of a mélange-like association during the late stages of orogeny. The high-pressure event D1-M1 is interpreted as a result of Late Silurian–Early Devonian moderate crustal thickening of a thermally softened and thinned pre-orogenic crust. The high-temperature (H<i>T</i>) re-equilibration D2-M2 is interpreted as a result of Mid-Devonian shortening of the previously thickened crust, possibly due to ‘Andean-type’ underthrusting. The D3-M3 event reflects Late Devonian supra-subduction shortening and continuous erosion of the sub-crustal lithosphere. This tectono-metamorphic sequence of events is explained by polyphased Andean-type deformation of a ‘Casca
高压麻粒岩要么形成于大陆碰撞时的俯冲板块区域,要么形成于热软化的上板块被缩短和加厚的上俯冲系统。构造环境的这种差异可以通过变质压力-温度-时间-变形(P-T-t-D)路径来评价。本文对敦煌地块早古生代高压麻粒岩相岩的P-T-t-D路径进行了研究,以期约束高压岩石的性质,揭示现代热造山系统在活动边缘环境下的地球动力学演化。岩石呈现多相演化特征,包括:(1)麻粒岩透镜体岩心和石榴石斑母岩心中保存的水平或缓浸织物(S1),(2)低应变域中保存的N - S向亚垂直织物(S2),以及(3)与普遍存在的陡E - W向轴向平面片理(S3)相关的直立褶皱(F3)。麻粒岩中的石榴石保留了在~11.5 kbar和~770 ~ 780℃下平衡的渐变矿物组合M1a的遗迹,而S1织物中的基质麻粒岩组合(M1b)在~13.5 kbar和~850℃时达到峰值压力。在地壳熔融(M2)过程中,麻粒岩在~8 - 11 kbar和~ 850-900°C的温度下叠印,然后在~8 kbar和~625°C的温度下进行部分再平衡(M3)。石榴石的Lu-Hf年龄为421.6±1.2 Ma,表明变质作用为M1;石榴石的Sm-Nd年龄为385.3±4.0 Ma,表明麻粒岩的M3冷却作用。主岩混染变长岩的矿物组合M1形成于~9 ~ 12.5 kbar和~760 ~ 810℃,部分熔融和混染(M2)发生于~7 kbar和~760℃,再平衡(M3)发生于~5 ~6 kbar和~675℃。石榴石的Lu-Hf年龄为409.7±2.3 Ma,确定了热顶极(M2),石榴石的Sm-Nd年龄为356±11 Ma,限制了混染变质长岩的M3。这一晚期阶段的时间也与约360 Ma的同构造花岗岩就位年龄相吻合。基性麻粒岩和混染变质岩的M1和M2 P-T演化解耦表明它们在地壳柱中的位置不同,而共同的压力-温度(P-T)演化M3表明在造山后期形成了一个类似于msamuange的组合。高压事件D1 - M1被解释为晚志留世-早泥盆世地壳热软化变薄的中度增厚的结果。高温(HT)再平衡D2 - M2被解释为中泥盆世之前变厚的地壳缩短的结果,可能是由于“安第斯型”逆冲作用。D3 - M3事件反映了晚泥盆世上俯冲缩短和地壳下岩石圈的持续侵蚀。这种构造变质序列可以用“卡斯卡迪亚型”活动边缘的多阶段安第斯型变形来解释,这对应于一个上俯冲构造转换范式。
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引用次数: 1
Social Satisfaction and Living Alone: Predictors of Self-Perception of Mental Health Improvement After Psychosis. 社交满意度和独居:社会满意度和独居:精神病后自我感觉心理健康改善的预测因素。
2区 地球科学 Q1 GEOLOGY Pub Date : 2022-08-06 eCollection Date: 2022-01-01 DOI: 10.1093/schizbullopen/sgac052
Patricia R Turner, Emily R Saeteurn

Background: Psychosis recovery can accompany social and self-stigma for the survivor, which can interfere with the person reaching their personal recovery goals. We hypothesized that there would be a strong association between social satisfaction and self-perceived mental health improvement, and that living alone would be a risk factor to self-perceived improvement.

Study design: Our strengths-based quantitative study aims to identify the most important factors to psychosis survivors for their mental health recovery. Survey responses from wave 5 of the Population Assessment of Tobacco and Health (PATH) study were used, specifically from those who self-identified as psychosis survivors (n = 710), analyzing the association between self-reported mental health symptoms, social satisfaction changes in the last year, living alone, and demographic variables, with self-reported mental health recovery in the last year.

Study results: Ordinary least squares regression analysis revealed three predictors of self-reported mental health improvement for psychosis survivors: social satisfaction, living alone, and lower anxiety. As hypothesized, social satisfaction was the largest determinant in self-perceived mental health improvement, but contrary to our hypothesis, living alone was a protective factor.

Conclusion: Prioritizing social satisfaction over group living environments for people recovering after psychosis.

背景:精神病康复可能会给幸存者带来社会和自我污名,从而影响他们实现个人康复目标。我们假设,社会满意度与自我感觉的心理健康改善之间存在密切联系,而独居将是影响自我感觉改善的一个风险因素:我们基于优势的定量研究旨在找出对精神病幸存者的心理健康康复最重要的因素。研究使用了烟草与健康人群评估(PATH)研究第五波的调查问卷,特别是那些自我认定为精神病幸存者的调查问卷(n = 710),分析了自我报告的精神健康症状、过去一年的社会满意度变化、独居、人口统计学变量与自我报告的过去一年精神健康恢复之间的关联:研究结果:普通最小二乘法回归分析显示,社会满意度、独居和较低的焦虑是预测精神病幸存者自述心理健康改善的三个因素。正如假设的那样,社交满意度是自我感觉心理健康改善的最大决定因素,但与我们的假设相反,独居是一个保护因素:结论:对于精神病康复者来说,社会满意度优先于集体生活环境。
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引用次数: 0
HTLP metamorphism and fluid-fluxed melting during multistage anatexis of continental crust (N Sardinia, Italy) 大陆地壳多级锐钛矿作用期间的HTLP变质作用和流体熔融作用(意大利撒丁岛北部)
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-07-29 DOI: 10.1111/jmg.12687
Leonardo Casini, Matteo Maino, Antonio Langone, Giacomo Oggiano, Stefania Corvò, Joan Reche Estrada, Montserrat Liesa

The Variscan high-grade metamorphic basement of northern Sardinia and southern Corsica record lower Carboniferous anatexis related to post-collisional decompression of the orogen. Migmatites exposed in the Punta Bianca locality (Italy) consist of quartz + biotite + plagioclase + K-feldspar orthogneisses, garnet and cordierite-bearing diatexite and metatexites, derived from metasediments. Field evidence, petrographic observations, ELA-ICP-MS zircon and monazite dating and pseudosection modelling suggest that anatexis was apparently episodic involving two main stages of partial melting. Using pseudosection modelling, we infer that the first stage of partial melting is in the upper amphibolite facies (~0.45 GPa at ~740°C). Cordierite overgrowths replacing sillimanite, combined with the composition of plagioclase and K-feldspar, suggest decompression followed cooling below the solidus at low pressures of ~0.3 GPa. The age of the first anatectic event is not precisely constrained because of extensive resetting of the isotopic systems during the second melting stage, yet few zircons preserve a lower Carboniferous age which is consistent with the regional dataset. This lower Carboniferous migmatitic fabric is offset by a network of pseudotachylyte-bearing faults suggestive of cooling to greenschist facies conditions. Garnet/cordierite-bearing diatexites incorporate fragments of pseudotachylite-bearing orthogneiss and metatexites. Pseudosection modelling indicates nearly isobaric re-heating up to ~750°C, followed by further cooling below the solidus. The inferred P–T path is consistent with decompression and cooling of the Variscan crust through post-collisional extension and collapse of the thickened orogenic crust, followed by nearly isobaric re-heating at low pressures (~0.3 GPa) yielding to a second melting stage under LP-HT conditions. U/Th-Pb monazite ages for diatexite migmatites indicate an upper bound of 310–316 Ma for the second melting stage, suggesting that the second melting stage is coincident with the regional phase of crustal shearing. The cause of the high geothermal gradient required for re-heating during the second melting stage is unknown but likely requires some heat source that was probably related to dissipation of mechanical work within crustal-scale shear zones. According to this interpretation, some upper Carboniferous peraluminous granite precursors of the Corsica–Sardinia Batholith could be the outcome rather than the cause of the late-Variscan high-T metamorphism.

撒丁岛北部和科西嘉岛南部的Variscan高变质基底记录了与碰撞后造山带减压有关的下石炭世深熔作用。在Punta Bianca地区(意大利)暴露的混长岩由石英+黑云母+斜长石+钾长石正长石,含石榴石和堇青石的闪长岩和偏长岩组成,来源于变质沉积物。现场证据、岩石学观察、ELA - ICP - MS锆石和独居石定年和伪剖面模拟表明,深熔作用明显是断断续续的,涉及两个主要的部分熔融阶段。利用伪剖面模拟,我们推断第一阶段部分熔融发生在上角闪岩相(~0.45 GPa, ~740℃)。堇青石过度生长取代硅线石,结合斜长石和钾长石的组成,表明在~0.3 GPa的低压下冷却至固相以下后减压。由于在第二次熔融阶段对同位素系统进行了广泛的重置,因此第一次熔蚀事件的年龄并没有得到精确的限制,但很少有锆石保留了较低石炭世的年龄,这与区域数据一致。下石炭世的混染岩构造被一组含假硅酸盐的断裂网络所抵消,这表明它们的相条件已冷却至绿片岩。含石榴石/堇青石的双辉长岩结合了含伪水晶石的正长岩和偏辉长岩的碎片。伪截面模型表明,接近等压再加热至~750°C,然后进一步冷却至固相以下。推断的P-T路径与Variscan地壳通过碰撞后的伸展和增厚的造山带地壳的坍塌而进行的减压和冷却相一致,然后在低压(~0.3 GPa)下进行近等压再加热,从而在LP - HT条件下产生第二次熔融阶段。闪长杂岩的U/Th‐Pb独居石年龄在310 ~ 316 Ma之间,表明第二次熔融期与区域地壳剪切期重合。在第二次融化阶段重新加热所需的高地温梯度的原因尚不清楚,但可能需要一些热源,这可能与地壳尺度剪切带内机械功的耗散有关。根据这一解释,科西嘉-撒丁岛基的一些上石炭世过铝质花岗岩前体可能是晚Variscan高T变质作用的结果而不是原因。
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引用次数: 4
Trace-element heterogeneity in rutile linked to dislocation structures: Implications for Zr-in-rutile geothermometry 金红石中与位错结构相关的微量元素非均质性:对Zr - in -金红石地温测量的影响
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-07-22 DOI: 10.1111/jmg.12686
Rick Verberne, Hugo W. van Schrojenstein Lantman, Steven M. Reddy, Matteo Alvaro, David Wallis, Denis Fougerouse, Antonio Langone, David W. Saxey, William D. A. Rickard

The trace-element composition of rutile is commonly used to constrain PTt conditions for a wide range of metamorphic systems. However, recent studies have demonstrated the redistribution of trace elements in rutile via high-diffusivity pathways and dislocation-impurity associations related to the formation and evolution of microstructures. Here, we investigate trace-element migration in low-angle boundaries formed by dislocation creep in rutile within an omphacite vein of the Lago di Cignana unit (Western Alps, Italy). Zr-in-rutile thermometry and inclusions of quartz in rutile and of coesite in omphacite constrain the conditions of rutile deformation to around the prograde boundary from high pressure to ultra-high pressure (~2.7 GPa) at temperatures of 500–565°C. Crystal-plastic deformation of a large rutile grain results in low-angle boundaries that generate a total misorientation of ~25°. Dislocations constituting one of these low-angle boundaries are enriched in common and uncommon trace elements, including Fe and Ca, providing evidence for the diffusion and trapping of trace elements along the dislocation cores. The role of dislocation microstructures as fast-diffusion pathways must be evaluated when applying high-resolution analytical procedures as compositional disturbances might lead to erroneous interpretations for Ca and Fe. In contrast, our results indicate a trapping mechanism for Zr.

金红石的微量元素组成通常用于限制各种变质系统的P–T–T条件。然而,最近的研究表明,金红石中微量元素通过高扩散率途径和位错-杂质缔合物的重新分布与微观结构的形成和演化有关。在这里,我们研究了微量元素在低角度边界中的迁移,该边界是由Lago di Cignana单元(意大利西阿尔卑斯)的绿辉石脉内金红石的位错蠕变形成的。Zr在金红石中的测温以及金红石中石英和绿辉石中柯石英的包裹体将金红石变形的条件限制在500–565°C温度下从高压到超高压(~2.7GPa)的前进边界附近。大金红石晶粒的晶体塑性变形导致低角度边界,产生约25°的总取向差。构成这些低角度边界之一的位错富含常见和不常见的微量元素,包括Fe和Ca,为微量元素沿位错核的扩散和捕获提供了证据。在应用高分辨率分析程序时,必须评估位错微观结构作为快速扩散途径的作用,因为成分扰动可能导致对Ca和Fe的错误解释。相反,我们的结果表明了Zr的俘获机制。
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引用次数: 2
Multi-episodic formation of baddeleyite and zircon in polymetamorphic anorthosite and rutile-bearing ilmenitite from the Chiapas Massif Complex, Mexico 墨西哥恰帕斯地块杂岩多变质斜长岩和含金红石钛铁矿中坏辉石和锆石的多期形成
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-06-28 DOI: 10.1111/jmg.12683
Alejandro Cisneros de León, Axel K. Schmitt, Bodo Weber
<p>Massif-type anorthosite and comagmatic associations of rutile-bearing ilmenitite (RBI) and oxide-apatite-rich amphibolite (OARA) from the Chiapas Massif Complex (CMC) in southeastern Mexico display a protracted billion-year accessory mineral record encompassing magmatic crystallization at c. 1.0 Ga to recent ductile shear deformation at c. 3.0 Ma. Multiple discrete zircon populations between these age end-members resulted from neoformation/recrystallization during local to regional metamorphism that affected the southeastern portion of the CMC. The ubiquitous presence of relict baddeleyite (ZrO<sub>2</sub>), along with various zircon generations spatially associated with pristine to partly retrogressed Zr-bearing igneous and metamorphic minerals (e.g., ilmenite, rutile, högbomite and garnet), suggests significant Zr diffusive re-equilibration (exsolution) during slow cooling and mineral breakdown followed by crystallization of baddeleyite. The subsequent transformation of baddeleyite into zircon was likely driven by reaction with Si-bearing fluids in several geochronologically identified metamorphic stages. Strikingly contrasting compositional signatures in coeval zircon from anorthosite (silicate-dominated) and comagmatic RBI (Ti-Fe-oxide-dominated) indicate a major role of fluids locally equilibrating with the rock matrix, as indicated by distinct zircon trace element and oxygen isotopic compositions. A high-grade metamorphic event at c. 950 Ma is likely responsible for the formation of coarse-grained rutile (~0.1–10 mm in diameter), srilankite, zircon and garnet with rutile inclusions as well as metamorphic högbomite surrounding Fe-Mg spinel. Zr-in-rutile minimum temperatures suggest >730°C for this event, which may correlate to rutile-forming granulite facies metamorphism in other Grenvillian-aged basement rocks in Mexico and northern South America. A younger generation of baddeleyite exsolution occurred during post-peak cooling of coarse-grained rutile, reflected in rimward Zr depletion and formation of discontinuous baddeleyite coronas. Baddeleyite around rutile was then transformed into zircon possibly during subsequent metamorphism at c. 920 or 620 Ma, resulting from syn-kinematic and contact metamorphism, respectively. Regional metamorphism at c. 450 and 250 Ma extensively overprinted the existing zircon population, especially during the Triassic event, as suggested by a significant presence of zircon with this age. Nearly pristine baddeleyite occurring interstitial to ilmenite yielded an isochron age of c. 232 Ma according to in situ U–Pb secondary ion mass spectrometry (SIMS), suggesting either formation during metamorphic peak conditions or post-peak cooling. Zircon with ages of c. 80–100 Ma in anorthosite is identified for the first time within the CMC and coincides with cooling ages of c. 100 Ma for coarse-grained rutile. This age is similar to those of rocks occurring ~200 km further to the east in Guatemala, which are also b
墨西哥东南部恰帕斯地块杂岩(CMC)中含金红石的钛铁矿(RBI)和富含氧化磷灰石的角闪岩(OARA)的地块型斜长岩和岩浆组合显示了一段长达10亿年的辅助矿物记录,包括1.0 Ga的岩浆结晶和3.0 Ma的近期韧性剪切变形。在这些年龄端元之间的多个离散锆石种群是由局部到区域变质作用期间的新形成/再结晶造成的,这些变质作用影响了CMC的东南部。残余坏辉石(ZrO2)的普遍存在,以及与原始到部分退变含锆火成岩和变质矿物(如钛铁矿、金红石、högbomite和石榴石)相关的各种锆石代,表明在缓慢冷却和矿物分解过程中,锆的扩散再平衡(析出)显著,然后是坏辉石的结晶。在地质年代学上确定的几个变质期中,变质岩与含硅流体的反应可能导致了变质岩向锆石的转化。从锆石微量元素和氧同位素组成可以看出,同时期的斜长岩(硅酸盐为主)和岩浆型RBI(钛铁氧化物为主)锆石的组成特征明显不同,表明流体在与岩石基质的局部平衡中起主要作用。c. 950 Ma的高变质事件可能形成了粗粒金红石(直径~0.1 ~ 10mm)、含金红石包裹体的硅蓝石、锆石和石榴石,以及围绕铁镁尖晶石的变质岩högbomite。金红石中锆的最低温度为>730°C,这可能与墨西哥和南美洲北部其他格伦维里亚时代基底岩石中的金红石形成麻粒岩相变质有关。粗粒金红石峰后冷却过程中出现了较年轻一代的坏辉石析出,表现为Zr向内耗竭和不连续坏辉石日冕的形成。金红石周围的坏辉石可能在随后的约920或620 Ma变质作用中转化为锆石,分别是同步变质作用和接触变质作用的结果。c. 450和250 Ma的区域变质作用广泛地覆盖了现有的锆石种群,特别是在三叠纪事件期间,这表明这个时代的锆石大量存在。根据原位U-Pb二次离子质谱分析(SIMS),在钛铁矿与钛铁矿之间出现的近乎原始的坏辉石的等时线年龄为c. 232 Ma,表明它可能是在变质峰条件下形成的,也可能是峰后冷却形成的。斜长岩的锆石年龄在80 ~ 100 Ma之间,与粗晶金红石的冷却年龄在100 Ma之间一致。这一年龄与危地马拉东部约200公里的岩石年龄相似,这些岩石也被波洛奇断裂系统所束缚,但被榴辉岩相变质作用所覆盖。然而,在200ma之后在中压中心南部发生的高压事件目前还没有得到支持。尽管与普通火成岩相比,CMC斜长岩组合中金红石和钛铁矿的丰度异常高,但这里记录的反应仍然强调了这些相在广泛的变质条件下产生含锌副矿物的重要性。
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引用次数: 1
Tectonic erosion and deep subduction in Central Tibet: Evidence from the discovery of retrograde eclogites in the Amdo microcontinent 西藏中部构造侵蚀与深俯冲:来自安多微大陆逆行榴辉岩发现的证据
IF 3.4 2区 地球科学 Q1 GEOLOGY Pub Date : 2022-06-28 DOI: 10.1111/jmg.12685
Yinbiao Peng, Shengyao Yu, Sanzhong Li, Yongjiang Liu, M. Santosh, Pei Lv, Yunshuai Li, Chuanzhi Li, Yiming Liu

The Amdo microcontinent which separates the Qiangtang terrane to the north and the Lhasa terrane to the south is a key terrane for reconstructing the tectonic evolution of Central Tibet. We report the new finding of retrograde eclogites within the Amdo microcontinent in this study. The eclogites are characterized by peak metamorphic mineral assemblages of garnet, omphacite, rutile and quartz and underwent a four-stage metamorphic evolution, including a peak eclogite facies stage (M1) at ~20–24 kbar and 580–620°C, followed by an HP granulite facies decompression stage (M2) at ~13–15 kbar and 750–780°C, a subsequent MP-UHT granulite facies heating stage (M3) at 8–10 kbar and >840°C and a final amphibolite facies retrogression (M4) at 5.3–6.0 kbar and 560–580°C. The eclogites exhibit rare earth element distribution patterns and trace element abundances similar to those of N-MORB and arc-related volcanics, with depleted whole-rock εNd(t) values of 3.4 to 4.2, and are inferred to have formed in a back-arc basin tectonic setting. Zircon and rutile U–Pb dating yields a protolith age of 226 ± 5 Ma, a peak eclogite facies metamorphic age of 190 ± 1 Ma, an HP granulite facies metamorphic age of 179 ± 1 Ma and an amphibolite facies retrograde age of 172 ± 1 Ma. The clockwise P–T–t paths and the oceanic protolith signature of retrograde eclogites suggest that part of the back arc basin was subducted to depths of ~80 km. Tectonic erosion associated with the subduction of the Amdo microcontinent beneath the Tethys Ocean accounts for the deep subduction of the back-arc basin and the absence of arc magmatic rocks in the northern Amdo microcontinent.

安多微大陆北隔羌塘地体,南隔拉萨地体,是重建西藏中部构造演化的关键地体。本文报道了在安多微大陆内发现的逆行榴辉岩的新发现。榴辉岩以石榴石、辉长石、金红石和石英的变质峰矿物组合为特征,经历了4期变质演化,包括~20 ~ 24 kbar和580 ~ 620℃的榴辉岩相峰阶段(M1)、~13 ~ 15 kbar和750 ~ 780℃的高压麻粒岩相减压阶段(M2)、8 ~ 10 kbar和>840℃的MP-UHT麻粒岩相加热阶段(M3)和5.3 ~ 6.0 kbar和560 ~ 580℃的角闪岩相退变阶段(M4)。榴辉岩稀土元素分布模式和微量元素丰度与N-MORB和弧缘火山岩相似,全岩亏缺εNd(t)值为3.4 ~ 4.2,形成于弧后盆地构造环境。锆石和金红石U-Pb定年结果表明,原岩年龄为226±5 Ma,榴辉岩相峰变质年龄为190±1 Ma,高压麻粒岩相变质年龄为179±1 Ma,角闪岩相逆变质年龄为172±1 Ma。顺时针P-T-t路径和逆行榴辉岩的海洋原岩特征表明,部分弧后盆地俯冲至~80 km深度。与特提斯洋下安多微大陆俯冲有关的构造侵蚀作用,是导致安多微大陆北部弧后盆地深俯冲和弧后岩浆岩缺失的主要原因。
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引用次数: 3
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Journal of Metamorphic Geology
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