Significantly different peak pressure–temperature (P–T) conditions (18–26 kbar and 630–760°C versus 29–37 kbar and 750–940°C) have previously been published for eclogite and related metabasites from the south-eastern flank of the Pohorje Mountains in Slovenia. These rocks can show a bimodal distribution of chromium in the rock-forming minerals, particularly garnet, the role of which in their metamorphic evolution is unclear. Therefore, we studied an eclogite and a related rock with clinopyroxene containing only 17 mol% jadeite + acmite (sample 18Ca35a). KαCr intensity maps of garnet particularly in sample 18Ca35a show a sharp irregular boundary between the core (Gt1) and the mantle (Gt2). Gt1 of millimetre-sized garnet in this rock is nearly Cr-free and unzoned, whereas Gt2 is of different composition (0.22 wt.% Cr2O3) and slightly zoned. Nearly Cr-free amphibole, (clino)zoisite, kyanite and staurolite inclusions are present in Gt1. The matrix consists of garnet and Cr-bearing clinopyroxene, (clino)zoisite and amphibole. Thermodynamic modelling suggests peak P–T conditions of 22.5 ± 2 kbar at 710 ± 25°C (Gt1) and 23 ± 2 kbar at 700 ± 25°C (Gt2) in both samples. We interpret these findings to suggest that olivine- and hornblende-bearing gabbros with some chromite experienced early metamorphism in the eclogite facies, when Gt1 formed. The rock was subsequently exhumed and cooled leading to significant garnet corrosion. A second stage of metamorphism, recognized by mappable Cr contents in garnet, led to the growth of Gt2 and other Cr-bearing minerals at the expense of chromite relics, which survived stage I. The peak P–T conditions of stage II are compatible with those previously derived by same authors and support the view that probably no ultrahigh-pressure eclogite exists in the Pohorje Mountains. We relate the two metamorphic events to the Cretaceous and Palaeogene high-pressure events recently reported from micaschists of the Pohorje Mountains.
{"title":"Chromium in minerals as tracer of the polycyclic evolution of eclogite and related metabasite from the Pohorje Mountains, Slovenian Eastern Alps","authors":"Botao Li, Hans-Joachim Massonne","doi":"10.1111/jmg.12746","DOIUrl":"10.1111/jmg.12746","url":null,"abstract":"<p>Significantly different peak pressure–temperature (P–T) conditions (18–26 kbar and 630–760°C versus 29–37 kbar and 750–940°C) have previously been published for eclogite and related metabasites from the south-eastern flank of the Pohorje Mountains in Slovenia. These rocks can show a bimodal distribution of chromium in the rock-forming minerals, particularly garnet, the role of which in their metamorphic evolution is unclear. Therefore, we studied an eclogite and a related rock with clinopyroxene containing only 17 mol% jadeite + acmite (sample 18Ca35a). KαCr intensity maps of garnet particularly in sample 18Ca35a show a sharp irregular boundary between the core (Gt1) and the mantle (Gt2). Gt1 of millimetre-sized garnet in this rock is nearly Cr-free and unzoned, whereas Gt2 is of different composition (0.22 wt.% Cr<sub>2</sub>O<sub>3</sub>) and slightly zoned. Nearly Cr-free amphibole, (clino)zoisite, kyanite and staurolite inclusions are present in Gt1. The matrix consists of garnet and Cr-bearing clinopyroxene, (clino)zoisite and amphibole. Thermodynamic modelling suggests peak P–T conditions of 22.5 ± 2 kbar at 710 ± 25°C (Gt1) and 23 ± 2 kbar at 700 ± 25°C (Gt2) in both samples. We interpret these findings to suggest that olivine- and hornblende-bearing gabbros with some chromite experienced early metamorphism in the eclogite facies, when Gt1 formed. The rock was subsequently exhumed and cooled leading to significant garnet corrosion. A second stage of metamorphism, recognized by mappable Cr contents in garnet, led to the growth of Gt2 and other Cr-bearing minerals at the expense of chromite relics, which survived stage I. The peak P–T conditions of stage II are compatible with those previously derived by same authors and support the view that probably no ultrahigh-pressure eclogite exists in the Pohorje Mountains. We relate the two metamorphic events to the Cretaceous and Palaeogene high-pressure events recently reported from micaschists of the Pohorje Mountains.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"42 1","pages":"63-88"},"PeriodicalIF":3.4,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.12746","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136212314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F. Gaidies, T. Mccarron, A. D. Simpson, R. M. Easton, S. Glorie, B. Putlitz, K. Trebus
<p>The Flinton Group is a metasedimentary succession of the Grenville Province in SE Ontario, potentially allowing insight into the tectono-thermal evolution of continental crust during the Mesoproterozoic. At its Green Bay locality, Flinton Group metapelites of the staurolite zone contain abundant, post-kinematic garnet porphyroblasts. Whereas the larger garnet crystals are typically impinged, smaller crystals are isolated from each other, occasionally exhibiting elongated shapes with apparently trigonal morphology. Central sections of the garnet population of a representative sample reveal that garnet is composed of different compositional and microstructural domains. In the largest crystals of the population, garnet contains rectangular to rhombic domains, marked by sharp increases in the concentrations of Nb, V, Ti, and Cr. These domains are associated with irregularly shaped patches, characterized by spatially heterogenous enrichments of Ca and LREE, and depletions in the contents of P, Y, MREE, and HREE, accompanied by increased densities of comparatively coarse-grained quartz inclusions hosting apatite. Microstructural relationships indicate that these domains correspond to portions of garnet that pseudomorphed biotite, with the enrichments of Nb, V, Ti, and Cr outlining the original biotite shapes. The compositional patterns formed by Ca, P, Y, and REE indicate that apatite participated in the grain-fluid interactions that operated during the metasomatic replacement of biotite by garnet. The statistical analyses of the garnet number and size distributions confirm that garnet initially nucleated on biotite, controlled by the kinetics of attachment and detachment processes at the garnet/biotite interface, resulting in the typical impingement habit. In situ Lu–Hf garnet geochronology applied to garnet that did not pseudomorph biotite, and hence is enriched in HREE, points to a first metamorphic event at c. 1080 <math>