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Development and Characterization of Carbon Nanotube Reinforced Aluminium-6061 Metal Matrix Composites 碳纳米管增强铝-6061金属基复合材料的研制与表征
Pub Date : 2021-05-12 DOI: 10.4236/JMMCE.2021.93020
K. Preethi, Raju T.N, Shivappa H.A
An emerging class of new materials is being developed with carbon nanotubes as reinforcements for Al6061 matrix material resulting in CNT-MMC composite materials. To maximize tensile strength and electrical conductivity properties of CNT materials and for the MMCs to possess optimal properties, some synthetic techniques are developed. Care is taken to ensure that these techniques are economical in production, provide uniform reinforcement dispersion in the matrix and also realize strong coherence adhesion of the CNT reinforcements and Al-6061 matrix material. Aluminum reinforced with CNT via powder metallurgy (PM) technique can provide a very distinct advantage. The primary drive and distinct advantage in adopting aluminum is lightweight in comparison to metal and wood composites. Besides weight savings, non-corrosive, flexible, resistance to dent, low on maintenance cost and design flexibility are the highlights of aluminum. Aluminum has wide range of application in industries because of their low density, good workability and relatively low yield strength; whereas reinforcement adds rigidity and impedes crack propagation to a great extent. Thin fibers are used as reinforcement since they possess very high strength with improved overall properties, whereas CNT has a number of invaluable and unique properties in comparison to other fibers used as reinforcement. Due to the reinforcement of CNT in aluminum, the resultant composite possesses high strength to weight ratio. In this work, the CNTs used as reinforcement with varying weight % of 1, 1.5, 2 and Al6061 alloy as a matrix material. The composites were fabricated through powder metallurgy route. Ball milling was done to get homogeneous dispersion of CNT’s. Samples were prepared as per ASTM standards for various compositions and investigated for microstructure using scanning Electron microscopy (SEM). The mechanical properties like hardness were evaluated by Micro Vickers hardness tester and compression strength by Universal Testing Machine. The expected improvements in micro hardness and compressive strength of the MMC s were achieved.
碳纳米管作为Al6061基体材料的增强材料,形成了碳纳米管- mmc复合材料。为了最大限度地提高碳纳米管材料的抗拉强度和导电性,并使碳纳米管材料具有最佳的性能,人们开发了一些合成技术。注意确保这些技术在生产中是经济的,在基体中提供均匀的增强分散,并实现CNT增强和Al-6061基体材料的强相干附着力。通过粉末冶金(PM)技术用碳纳米管增强铝具有非常明显的优势。与金属和木材复合材料相比,采用铝的主要动力和明显优势是重量轻。除了重量轻,无腐蚀性,灵活,抗凹痕,低维护成本和设计灵活性是铝的亮点。铝因其密度低、和易性好、屈服强度较低而在工业上有广泛的应用;而钢筋则在很大程度上增加了刚度并阻碍了裂纹的扩展。薄纤维被用作增强材料,因为它们具有非常高的强度和改进的整体性能,而碳纳米管与用作增强材料的其他纤维相比具有许多宝贵和独特的性能。由于碳纳米管在铝中的增强,所得复合材料具有高强度重量比。在本研究中,采用了不同重量% 1、1.5、2的CNTs作为增强材料和Al6061合金作为基体材料。采用粉末冶金工艺制备复合材料。采用球磨法制备碳纳米管均匀分散。按照ASTM标准制备各种成分的样品,并使用扫描电子显微镜(SEM)研究其微观结构。采用显微维氏硬度计和万能试验机分别对材料的硬度、抗压强度等力学性能进行了测试。在显微硬度和抗压强度方面取得了预期的改善。
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引用次数: 1
Flotation-Calcination-Magnetic Separation Hybrid Process for Concentration of Rare Earth Minerals Contained in a Carbonatite Ore 某碳酸盐矿石中稀土矿物浮选—焙烧—磁选混选工艺研究
Pub Date : 2021-05-12 DOI: 10.4236/JMMCE.2021.93019
T. Negeri
A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. The deposit is known to contain at least 15 different rare earth minerals identified as silicocarbonatite, magnesiocarbonatite, ferrocarbonatites, calciocarbonatite, REE/Nb ferrocarbonatite, phosphates and niobates. Although no collector exists to float all the different rare earth minerals, the hydroxamic acid-based collectors have shown adequate efficiency in floating most of these minerals. 92% recovery of total rare earth oxide (TREO) and niobium in 45% mass was possible at d80 of <65 microns grind size. It was also possible to reduce the mass pull to 28%, but TREO and Nb’s recovery dropped to 85%. Calcination of the concentrate followed by quenching and fine grinding to <25 μm allowed upgrading the flotation concentrate by magnetic separation. It was demonstrated that at least 87% TREO and 85% Nb could be recovered in 16% of the feed mass. The paper discusses the overall concept of the flowsheet and the experimental strategies that led to this process.
采用浮选与磁选相结合的混合工艺,对含有大量铌的碳酸盐矿进行了多相稀土精矿的选矿。该矿床已知含有至少15种不同的稀土矿物,包括硅碳酸盐、镁碳酸盐、碳铁碳酸盐、钙碳酸盐、REE/Nb碳铁碳酸盐、磷酸盐和铌酸盐。虽然目前还没有捕收剂可以浮选所有不同的稀土矿物,但羟肟酸基捕收剂在浮选大多数这些矿物方面显示出足够的效率。当磨矿粒度<65 μ m时,总稀土氧化物(TREO)和总铌的回收率为45%,回收率可达92%。也有可能将质量拉力降低到28%,但TREO和Nb的回收率降至85%。精矿煅烧后淬火,细磨至<25 μm,实现了磁选浮选精矿的升级。结果表明,在16%的饲料质量中,至少可以回收87%的TREO和85%的Nb。本文讨论了流程的总体概念和导致这一过程的实验策略。
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引用次数: 0
Dynamic Fracture of a Semi-Crystalline Bio-Based Polymer Pipe: Effect of Temperature 温度对半结晶生物基聚合物管材动态断裂的影响
Pub Date : 2021-05-12 DOI: 10.4236/JMMCE.2021.93016
J. Kopp, J. Girardot
The influence of temperature on the resistance to rapid crack propagation of a semi-crystalline bio-based polymer was studied. The experimental results described in this study allow to initiate a first discussion on the role of viscosity and its link with the fracture behaviour and a heterogeneous microstructure such as the semi-crysalline polymer. Dynamic fracture tests on pipes were carried out. It would appear that a temperature decrease of approximately 40℃ relative to ambient has no significant influence on the average crack propagation velocity (≈0.6cR), fracture energy and surface roughness. On the contrary, crack propagation paths seem to vary with temperature. The difference in fracture behaviour between the amorphous and crystalline phase varies significantly as a function of temperature. The difference between the initiation resistance and the rapid propagation also varies. This difference seems to be significantly reduced by lowering the temperature. The mechanisms of cavitation damage and plastic flow are increasingly limited by the decrease in temperature (and therefore in macromolecular mobility). Crack propagation in the pipe is more extensive and therefore more critical. This is emphasised in particular by the probability of the material to be macro-branched as the temperature decreases.
研究了温度对半结晶生物基聚合物抗快速裂纹扩展性能的影响。本研究中描述的实验结果允许首次讨论粘度的作用及其与断裂行为和非均质微观结构(如半结晶聚合物)的联系。对管道进行了动态断裂试验。结果表明,相对于环境温度降低约40℃对平均裂纹扩展速度(≈0.6cR)、断裂能和表面粗糙度没有显著影响。相反,裂纹扩展路径似乎随温度的变化而变化。非晶相和结晶相的断裂行为差异随温度的变化而显著不同。起爆阻力与快速繁殖之间的差异也有所不同。这种差异似乎通过降低温度而显著减小。空化损伤和塑性流动的机制越来越受到温度降低的限制(因此也受到大分子迁移率的限制)。裂纹在管道中的扩展更广泛,因此更关键。当温度降低时,材料发生宏观分支的概率特别强调了这一点。
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引用次数: 0
Implementation and Evaluation of Certain Properties of a Polymer Matrix Composite Material Reinforced by Fibrous Residues of Saccharum officinarum in View of an Applicability Orientation 糖精纤维残基增强聚合物基复合材料的研制及性能评价
Pub Date : 2021-03-26 DOI: 10.4236/JMMCE.2021.92015
Marie Josette Ndengue, Merlin Zacharie Ayissi, Pierre Marcel Anicet Noah, F. B. Ebanda, A. Ateba
This study examines the implementation and characterization of a polymer matrix composite material reinforced by sugarcane residues. The aim of the study is to enhance the abundantly produced sugarcane bagasse in the form of residues in the processing plants of said sugar cane. The composite material developed takes into account the size parameters and mass load rate of the reinforcement, the variations of which are between 2.5 mm and 4 mm respectively for the first parameter and 10% to 25% for the second. The load on the test tube during the test has a random orientation. The composite is polyester matrix. The cold compression moulding technique was used in the production of the various samples. Physical properties such as the rate of water absorption and the density of the composite are assessed. The three-point bending tests are carried out with the aim of inducing Young’s modulus from the elaborate samples. Analysis of physical properties shows that water absorption increases with the rate of residue load. The average water absorption rate of bagasse fibres is estimated at 8% for the 2.5 mm fiber size and 12% for the 4 mm fiber size for all composites. Mechanical characterization by bending tests reveals a fragile behavior of the samples tested. Young’s modulus decreases when the load rate of fibrous residues increases regardless of the size of the fibers.
本研究探讨了甘蔗残基增强聚合物基复合材料的实现和表征。本研究的目的是在甘蔗加工厂中以残留物的形式提高大量生产的甘蔗渣的利用率。所研制的复合材料考虑了配筋的尺寸参数和质量载荷率,第一个参数的变化幅度在2.5 ~ 4mm之间,第二个参数的变化幅度在10% ~ 25%之间。在测试过程中,试管上的载荷具有随机方向。该复合材料为聚酯基。在各种样品的生产中采用了冷压缩成型技术。物理性质,如吸水率和复合材料的密度进行评估。三点弯曲试验的目的是诱导杨氏模量从精心制作的样品。物性分析表明,吸水率随负荷量的增加而增加。在所有复合材料中,2.5毫米纤维尺寸的甘蔗渣纤维的平均吸水率估计为8%,4毫米纤维尺寸的平均吸水率为12%。弯曲试验的力学特性揭示了被测样品的脆性行为。杨氏模量随纤维残余载荷率的增加而减小,与纤维的尺寸无关。
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引用次数: 6
Determination of Airways Resistance, Volumetric Efficiency and Development of Ventilation Model of Rosh Pinah Zinc Mine Namibia 纳米比亚Rosh Pinah锌矿气道阻力、通气量的测定及通风模型的建立
Pub Date : 2021-03-25 DOI: 10.4236/JMMCE.2021.92014
Jeremia Kalenga, J. M. Akande
A quantitative technique was conducted at Rosh Pinah Zinc mine, Namibia with its main purpose to determine airways resistance which is a function of the parameters; roughness of the airways and the friction factor. The 32 branch points (i.e. a-ag) that stand for ventilation circuit have been selected. Data collected includes, length and width of airways, air velocity; air density, and roughness of the airways which were used to determine coefficient of frictions, friction factors and airway resistances. A ventilation model was developed. In order to improve the current ventilation model, airways resistance of the mine was determined and simulated in a modified model using VentSimTM software. An average total airways resistance of 0.32027 Ns2/m8 has been achieved for Rosh Pinah mine. It should be pointed out that, as the mine advances its production faces deeper, this value would increases suddenly. Simulation revealed that as much as 34.4 m3/s of air can be received at the production faces, compared to the measured received amount of 19.3 m3/s. Therefore, volumetric efficiency of the mine was improved from 29.3% to 68.3%. It was also noticed that after importing the resistance values into the model together with other parameters, the model was greatly improved and no cause for concern.
在纳米比亚Rosh Pinah锌矿进行了定量技术,其主要目的是确定气道阻力,这是参数的函数;气道的粗糙度和摩擦系数。选取32个分支点(即a-ag)代表通风回路。收集的数据包括:气道的长度和宽度、气流速度;空气密度和气道的粗糙度用于确定摩擦系数,摩擦系数和气道阻力。开发了通风模型。为了改进现有的通风模型,利用VentSimTM软件对改进后的模型进行了气道阻力的测定和模拟。Rosh Pinah矿平均总气道阻力为0.32027 Ns2/m8。应该指出的是,随着矿山的推进,其生产面越深,这个值会突然增加。模拟结果表明,与测量的19.3 m3/s的空气接收量相比,生产面可接收多达34.4 m3/s的空气。因此,该矿的体积效率由29.3%提高到68.3%。我们还注意到,将电阻值与其他参数一起导入模型后,模型得到了很大的改进,无需担心。
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引用次数: 0
Investigation of Pegmatite Mineral Applicability from the Terek Ceramic Deposit in Kyrgyzstan for Production of Porcelain and Earthenware 吉尔吉斯斯坦Terek陶瓷矿床伟晶岩矿物在瓷器和陶器生产中的适用性研究
Pub Date : 2021-02-10 DOI: 10.4236/JMMCE.2021.92012
M. Abdullaeva, B. Murzubraimov, D. Altybaeva, Zh.D. Abdullaeva, G. Kalykova, Aishakan Suiunbekova, A. Osmonova
This article is investigating analysis and chemical composition of ceramic pegmatite minerals obtained from the Terek deposit in Toktogul district of Kyrgyzstan. Several methods such as mineralogical studies, magnetic and gravitational enrichments, silicate and chemical analyses of ceramic pegmatite minerals, quartz-feldspathic concentrate and sludge removal have been performed for determination of pegmatite mineral applicability for production of porcelain and earthenware.
本文研究了吉尔吉斯斯坦托克托古尔地区Terek矿床陶瓷伟晶岩矿物的分析和化学成分。为了确定伟晶岩矿物是否适用于生产瓷器和陶器,已经采用了矿物学研究、磁性和重力富集、硅酸盐和陶瓷伟晶岩矿物化学分析、石英长石精矿和污泥去除等几种方法。
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引用次数: 0
Affordable Water Filtration Technology for Disinfection By-Product Control for Small Rural Communities by Using Carbon Extracted from Local Fly Ash 利用从当地粉煤灰中提取的碳控制小型农村社区消毒副产物的经济实惠的水过滤技术
Pub Date : 2021-02-10 DOI: 10.4236/JMMCE.2021.92011
He-fei Zhang, T. Husain
The fly ash generated from local pulp and paper industries was transformed into activated carbon (AC) through physical activation process in a high temperature tube furnace in this study. Effects of two factors including activation temperature and activation time were investigated. Iodine number (IN), methylene blue value (MBV), and surface microstructure were all analyzed to assess the adsorption capacity of different carbon samples. The surface area of the carbon sample increased significantly from 486.44 m2/g to 847.26 m2/g before and after activation. The jar tests revealed that the use of 0.5 g (AC)/L (water) has the highest adsorption effectiveness. Meanwhile, the column filtration experiment indicated more than 60% of the organic matter can be removed by the carbon barrier within 2 hours filtration. The follow-up chlorination experiment illustrated that the formation of trihalomethanes (THMs) and haloacetic acids (HAAs) could be considerably prevented after filtration. Above all, the cost-effective carbon filtration technology developed in this study can potentially be applied as a pre-treatment technology for intake source waters for local communities.
本研究以当地制浆造纸工业产生的粉煤灰为原料,在高温管式炉中通过物理活化工艺转化为活性炭(AC)。考察了活化温度和活化时间两个因素的影响。通过分析碘值(IN)、亚甲基蓝值(MBV)和表面微观结构来评价不同碳样品的吸附能力。活化前后碳样的表面积由486.44 m2/g显著增加到847.26 m2/g。罐子试验表明,使用0.5 g (AC)/L(水)的吸附效果最高。同时,柱过滤实验表明,在2小时的过滤时间内,碳屏障的有机物去除率可达60%以上。后续的氯化实验表明,过滤后可有效防止三卤甲烷(THMs)和卤乙酸(HAAs)的生成。最重要的是,本研究开发的具有成本效益的碳过滤技术可以作为当地社区取水水源的预处理技术。
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引用次数: 0
Applications of Compliance to Cost Ratio (C-CR) Analysis in the Determination of Optimum Mix of Insulating Bricks in Masonry 成本比符合性分析在确定砌体保温砖最佳配合比中的应用
Pub Date : 2021-02-10 DOI: 10.4236/JMMCE.2021.92010
D. O. Folorunso, A. Akinwande
The scarcity of housing increases as population continues to rise all over the world. Despite government efforts at providing houses, yearly demand keeps on exceeding available houses and hence the hike in rent, the cost of erecting houses and the cost of building materials. This ultimately calls for a decisive solution. This study therefore applied compliance to cost ratio (C-CR) analysis in evaluating the optimum properties of fired ceramic bricks. The optimum mix proportions of waste glass (WG) and wood saw dust (WSD) in fired bricks, that will be suitable for housing constructions were hence determined. Fired clay brick samples which contained varied proportions of WG and WSD were examined for physical, mechanical and thermal properties in line with standard procedures. The results were compared with existing standards and property evaluation index, compliance level and C-CR were applied in analyzing the results obtained. It was observed that with increasing WG content, compliance level increased. Also, cost ratio and experimental cost of each brick sample trended upward. Sample with mix proportion; 20 wt% WG, 5 wt% WSD and 75 wt% clay had compliance level of 94% and C-CR index of 7.81, hence chosen as optimum mix proportion for masonry bricks.
随着世界各地人口的持续增长,住房的稀缺性也在增加。尽管政府努力提供住房,但每年的需求仍然超过可用的住房,因此租金、建造房屋的成本和建筑材料的成本都在上涨。这最终需要一个果断的解决办法。因此,本研究将遵从成本比(C-CR)分析用于评价烧结陶瓷砖的最佳性能。由此确定了适用于住宅建筑的烧结砖中废玻璃和木锯末的最佳混合比例。烧制粘土砖样品含有不同比例的WG和WSD,并按照标准程序测试其物理、机械和热性能。将所得结果与现有标准进行比较,并应用性能评价指标、符合性等级和C-CR对所得结果进行分析。观察到,随着WG含量的增加,依从性水平增加。每块砖样的成本比和实验成本呈上升趋势。混合比例试样;选用20 wt% WG、5 wt% WSD和75 wt%粘土作为砌体砖的最佳配合比,符合度为94%,C-CR指数为7.81。
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引用次数: 5
Alkaline Pre-Treatment of Coal Fly Ash as Bio-Silica Fertilizer 粉煤灰作为生物硅肥的碱性预处理研究
Pub Date : 2021-02-10 DOI: 10.4236/JMMCE.2021.92013
L. Santi, D. H. Goenadi, D. N. Kalbuadi, I. P. Sari, nbsp, Sulastri
This study deals with the pre-treatment of coal fly ash (CFA) by using alkaline substance to improve water solubility of Si which in turn readily available to the plants. Selected weight ratios of CFA/NaOH (s:s) were tested and the highest H4SiO4 yield ratio was selected for further study. X-ray diffraction and scanning electron microscopy analyses were performed to confirm the evidence of structural changes of the CFA upon alkaline treatment. To improve SiO2 dissolution, seven Si-solubilizing fungi, i.e., Aspergillus niger BCC194, A. niger K0909, A. niger A1601, Trichoderma polysporum, T. viride, T. pseudokoningii, and Trichoderma spp, were each inoculated onto pre-treated ash. The results indicated that the relationships between ratio of CFA/NaOH and total and soluble Si were linier (R2 = 0.97** and 0.96**, respectively). Total SiO2 values range from 10.43% to 13.02%, whereas soluble Si contents were 2.30% - 2.64% improved about 300 times compared to un-treated CFA. Both XRD and SEM analyses indicated that alkaline treatment to CFA caused particle damages resulting in increasing soluble Si. Inoculation of pre-treated CFA by T. polysporum up to twelve days of incubation yielded the highest soluble Si. Each fungal species grown on Bunt & Rovira solid media enriched with CFA as Si-source expressed significantly different ability in solubilizing Si from CFA. Citric acid was shown to be stronger compared to acetic and oxalic acids in solubilizing Si from CFA.
本文研究了用碱性物质对粉煤灰进行预处理,以提高硅的水溶性,从而使植物易于获得硅。测试了选定的CFA/NaOH的重量比(s:s),并选择了最高的H4SiO4收率进行进一步研究。x射线衍射和扫描电镜分析证实了碱性处理后CFA结构变化的证据。为了提高SiO2的溶解性,将黑曲霉BCC194、黑曲霉K0909、黑曲霉A1601、多孢木霉、绿霉、假孔木霉和木霉分别接种到预处理灰上。结果表明,CFA/NaOH与总硅和可溶性硅的比值呈线性关系(R2分别为0.97**和0.96**)。总SiO2值为10.43% ~ 13.02%,可溶性Si含量为2.30% ~ 2.64%,比未处理的CFA提高了约300倍。XRD和SEM分析表明,碱法处理对CFA造成颗粒损伤,导致可溶性Si增加。用多孢霉接种预处理过的CFA至12天,可获得最高的可溶性Si。在富含CFA作为硅源的Bunt & Rovira固体培养基上生长的不同真菌对CFA中硅的溶解能力有显著差异。柠檬酸比乙酸和草酸更能溶解CFA中的硅。
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引用次数: 1
Characterization and Valuation of a Clay Soil Sampled in Londéla-Kayes in the Republic of Congo 在刚果共和国的lond<s:1> - la- kayes取样的黏土特征和评价
Pub Date : 2021-02-10 DOI: 10.4236/JMMCE.2021.92009
Roger Makosso Voula, Flora Zita Mpissi Diamouangana, J. Moutou, Vivien Igore Banzouzi Samba, Mozalin Paul Foutou, Julien Placide Ngoma
In order to characterize and enhance clay collected in Londela-kayes in the Republic of Congo, in this work, it was a question of proceeding to the mineralogical, physico-chemical, thermal and geotechnical characterization of this clay. Next, determine the technological properties of fired bricks. For this, various methods were used in particular: X-ray diffraction, infrared spectroscopy, gravimetric thermal analysis and differential thermal analysis, dilatometric analysis, scanning electron microscopy, specific surface and analysis chemical. It appears that, for the mineralogical characterization, kaolinite is the most abundant mineral of this clay. The results of dilatometric analysis have shown that this clay can be fired at low temperatures. The geotechnical characterization showed that it is plastic clay thus exhibiting a high shrinkage. The results of the technological properties of LON1 bricks have shown that this clay cannot be used in the manufacture of fired bricks. The geotechnical properties must be improved by adding additives in order to improve the technological properties of the fired bricks.
为了鉴定和加强在刚果共和国Londela-kayes收集的粘土,在这项工作中,需要对这种粘土进行矿物学、物理化学、热学和岩土学表征。接下来,确定烧结砖的工艺性能。为此,特别使用了各种方法:x射线衍射、红外光谱、重量热分析和差热分析、膨胀分析、扫描电子显微镜、比表面和化学分析。从矿物学特征来看,高岭石是该粘土中含量最丰富的矿物。膨胀分析的结果表明,这种粘土可以在低温下烧制。岩土力学特性分析表明其为塑性粘土,具有较高的收缩率。对LON1砖的工艺性能进行了测试,结果表明这种粘土不能用于烧结砖的生产。为了提高烧结砖的工艺性能,必须通过添加添加剂来改善其土工性能。
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引用次数: 3
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Journal of Minerals and Materials Characterization and Engineering
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