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Investigation of Graphene Reinforcement Effect on Young's Modulus of Cross-Linked Epoxy Nanocomposites by a New Heuristic Protocol 石墨烯增强对交联环氧纳米复合材料杨氏模量影响的新启发式研究
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-15ha92
Muhammet Erdöl, A. E. S. Konukman, Ahmet Sinan Öktem
Using a new heuristic procedure, the influence of graphene reinforcement on Young's modulus of crosslinked epoxy was analyzed. Graphene reinforcement was investigated for 1%, 2%, 3%, and 4% weight ratios. Graphene sheet edges were functionalized with hydrogen atoms and were placed middle of simulation cells. Simulation cell sizes were determined such that the graphene sheets were non-periodic. Thus, the edge effects of graphene sheets could be observed in dynamic simulations. The heuristic protocol is used for the crosslinking process of epoxy. It is less sophisticated than the multi-step iterative approach and is utilized for various components. It also updates higher-order covalent bond and partial charge terms in real-time to prevent inaccurate chemical couplings caused by ignoring angle-based covalent terms. Crosslinked epoxy structures were created by 80% with this new heuristic protocol as a matrix structure. To analyze the multiple variations with the same amount of molecules in each weight ratio, each simulation cell was built as three individual samples, and the standard deviation values were calculated. Young's modulus of the nanocomposite system was then calculated using a constant-strain energy minimization approach. The inter-atomic and intra-atomic interactions were described using the Molecular Potentials for Atomistic Simulation Studies (COMPASS) force field. As expected, the Young Modulus of epoxy resin increased with the addition of graphene reinforcement. This increase in Young's modulus was calculated by 6% for 1% graphene reinforcement, 10% for 2% graphene reinforcement, 14% for 3% graphene reinforcement, and 16% for 4% graphene reinforcement. As the graphene reinforcement ratio increases, the increase in Young's modulus tends to diminish. It's also worth noting that the MD simulation results in this work were in close agreement with the experimental results published in the literature. Both qualitative and quantitative numerical results show the effect of the abovementioned parameters. They will provide gain energy and time for prior synthesizing the new materials and serve as benchmark solutions for future comparisons of numerical and experimental results.
采用一种新的启发式方法,分析了石墨烯增强剂对交联环氧树脂杨氏模量的影响。研究了1%、2%、3%和4%重量比的石墨烯增强材料。石墨烯薄片的边缘被氢原子功能化,并被放置在模拟细胞的中间。模拟电池尺寸的确定使得石墨烯片是非周期性的。因此,在动态模拟中可以观察到石墨烯片的边缘效应。将启发式协议应用于环氧树脂的交联过程。它不如多步骤迭代方法复杂,可用于各种组件。它还可以实时更新高阶共价键和部分电荷项,以防止由于忽略基于角度的共价键项而导致的不准确的化学偶联。用这种新的启发式协议作为矩阵结构,交联环氧树脂结构的生成率为80%。为了分析各重量比中相同分子数量下的多重变化,将每个模拟细胞构建为3个单独的样本,并计算标准差值。然后使用恒应变能量最小化方法计算纳米复合材料体系的杨氏模量。利用分子势原子模拟研究(COMPASS)力场描述了原子间和原子内相互作用。正如预期的那样,环氧树脂的杨氏模量随着石墨烯增强剂的加入而增加。杨氏模量的增加分别为1%石墨烯增强剂6%,2%石墨烯增强剂10%,3%石墨烯增强剂14%,4%石墨烯增强剂16%。随着石墨烯增强率的增加,杨氏模量的增加趋于减小。同样值得注意的是,本工作的MD模拟结果与文献中发表的实验结果非常吻合。定性和定量数值结果均表明了上述参数的影响。它们将为预先合成新材料提供能量和时间,并作为未来数值和实验结果比较的基准解决方案。
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引用次数: 1
Study of Substrate Temperatures Effects on the Properties of Ultrasonically Sprayed SnS2 Thin Films 衬底温度对超声喷涂SnS2薄膜性能影响的研究
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-2rx1mg
Z. Hadef, K. Kamli, B. Zaidi, S. Boulkhessaim, B. Chouial
Tin disulfide (SnS2) thin films have drawn worldwide attention because of their outstanding performance and earth-abundant constituents. However, problems such as coexistence of complex secondary phases (SnS, Sn2S3), the band tailing issue, and bulk defects need to be addressed for further efficiency improvement. In this regard, the present work is intended for the treatment of one of these problems. Herein, a single phase SnS2 has been obtained using an ultrasonic spray pyrolysis method. which is confirmed by X-ray diffraction (XRD) and energy dispersive X-rays (EDXs) characterization techniques. The substrate temperatures (Ts) were increased from 250 °C to 450 °C, and this significantly improved the film's characteristics, which varied from an amorphous phase and a mixture of crystalline phases, SnS2 and SnS (for the films obtained at Ts = 250 and 300 °C) to a SnS2 pure phase with a hexagonal structure (for Ts ≥ 350 °C). The morphological, optical, and electrical properties of SnS2 films are greatly improved by temperature increases too, especially for the film obtained at 450 °C. This suggests that there are opportunities for further efficiency by using the as-deposited SnS2 thin film at 450 °C.
二硫化锡(SnS2)薄膜因其优异的性能和丰富的化学成分而受到世界的广泛关注。但是,为了进一步提高效率,还需要解决复杂二次相(SnS、Sn2S3)共存、带尾问题、体缺陷等问题。在这方面,本工作旨在处理其中一个问题。本文采用超声喷雾热解法制备了单相SnS2。x射线衍射(XRD)和能量色散x射线(EDXs)表征技术证实了这一点。衬底温度(Ts)从250°C提高到450°C,这显著改善了薄膜的特性,从非晶相和结晶相,SnS2和SnS的混合物(对于Ts = 250°C和300°C获得的薄膜)转变为具有六边形结构的SnS2纯相(对于Ts≥350°C)。随着温度的升高,SnS2薄膜的形貌、光学和电学性能也得到了很大的改善,尤其是在450°C时得到的薄膜。这表明在450°C下使用沉积的SnS2薄膜有可能进一步提高效率。
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引用次数: 0
Magnetic Hyperthermia of Polyvinylpyrrolidone Coated La0.6Sr0.4MnO3 Nanoparticles Synthesized by Sol-Gel Auto Combust Method 溶胶-凝胶自燃烧法制备聚乙烯吡咯烷酮包被La0.6Sr0.4MnO3纳米颗粒的磁热疗研究
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-c1h50r
Yashpreet, B. Chudasama
Lanthanum strontium manganite (La0.6Sr0.4MnO3) nanoparticles have been synthesized by sol-gel auto combustion method. Four sets of LSMO nanoparticles have been synthesized by varying the reaction pH from 10 to 13. LSMO nanoparticles were further functionalized with Polyvinylpyrrolidone (PVP). Structural properties of LSMO nanoparticles were determined by powder X-ray diffraction. Rietveld refinement of diffractograms revealed that irrespective of synthesis conditions, LSMO nanoparticles were synthesized with rhombohedral and orthorhombic crystal phases. Magnetic properties (saturation magnetization, domain magnetization and Curie temperature) of LSMO nanoparticles have been determined by vibration sample magnetometer. Synthesized LSMO nanoparticles are soft ferromagnetic and possesses Curie temperature in between 360 – 370 K. Their saturation magnetization increases with increases in reaction pH, which is in good agreement with the corresponding increase in their rhombohedral phase fraction. PVP coated LSMO nanoparticles when exposed to AC magnetic field produces magnetic hyperthermia temperature (45 °C) within 10 minutes of exposure. Hyperthermia efficiency of LSMO nanoparticles measured in terms of specific loss power (SLP) increases with magnetic field frequency and field strength and it decreases with nanoparticle concentration. LSMO nanoparticles synthesized at pH 10, 11 and 12 are suitable for the magnetic hyperthermia therapy of cancer while the one synthesized at pH 13 is not suitable for magnetic hyperthermia as it could not produce the requisite temperature of 45 °C needed to induce cell apoptosis in in-vivo experiments. Highest hyperthermia efficiency (15.69 W/g) was observed for PVP coated LSMO nanoparticles (concentration: 12.5 mg/mL) synthesized at pH 10 when exposed to an AC magnetic field of strength 10 mT and field frequency of 935.6 KHz.
采用溶胶-凝胶自燃烧法制备了镧锶锰酸盐(La0.6Sr0.4MnO3)纳米颗粒。通过改变反应pH值在10 ~ 13之间的变化,合成了四组LSMO纳米颗粒。聚乙烯吡咯烷酮(PVP)进一步功能化了LSMO纳米颗粒。采用粉末x射线衍射法测定了LSMO纳米颗粒的结构性质。衍射图的Rietveld细化表明,无论合成条件如何,合成的LSMO纳米颗粒都具有菱形和正交晶相。用振动样品磁强计测定了LSMO纳米颗粒的磁性能(饱和磁化强度、畴磁化强度和居里温度)。合成的LSMO纳米粒子具有软铁磁性,居里温度在360 ~ 370k之间。它们的饱和磁化强度随反应pH的增加而增加,这与它们的菱面体相分数的相应增加是一致的。PVP涂层的LSMO纳米颗粒暴露于交流磁场时,在暴露10分钟内产生磁热疗温度(45°C)。以比损耗功率(SLP)衡量的LSMO纳米颗粒热疗效率随磁场频率和磁场强度的增加而增加,随纳米颗粒浓度的增加而降低。在pH值为10、11和12的条件下合成的LSMO纳米颗粒适合于磁热疗癌症,而在pH值为13的条件下合成的LSMO纳米颗粒不适合磁热疗,因为在体内实验中无法产生诱导细胞凋亡所需的45℃温度。在pH值为10的交流磁场强度为10 mT,场频为935.6 KHz时,合成的PVP包被LSMO纳米颗粒(浓度为12.5 mg/mL)的热疗效率最高(15.69 W/g)。
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引用次数: 0
Structural, Optical and Ionic Properties of PVA Capped CuS Quantum Dots PVA包覆cu量子点的结构、光学和离子性质
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-i9y6sp
S. Nath, P. Kalita
Copper sulphide quantum dots were synthesized by a simple chemical route using ammonia (aq.) as a complexing agent in PVA matrix. Copper acetate monohydrate and thiourea were used as precursors. The particle sizes as obtained from XRD results were found to be in good agreement with those of HRTEM. The UV-Vis. absorption and PL emission spectra exhibited a systematic blue shift of absorption and emission respectively confirming quantum confinement effect in the synthesized quantum dots. The band gap as estimated from Tauc-plot increased from 3.26eV to 3.92eV with change of concentration of complexing agent. The FTIR spectra exhibited Cu-S stretching peaks characteristic of CuS. Ionic contributions of the electrolytic ionic CuS solution as measured by a standard conductivity cell clearly showed the semiconducting behavior of the product material. The synthesized material may be exploited in fabrication of an optoelectronic device in UV-blue region.
以氨水为络合剂,在聚乙烯醇(PVA)基质中采用简单的化学方法合成了硫化铜量子点。以一水乙酸铜和硫脲为前驱体。XRD结果与HRTEM结果吻合较好。紫外可见。吸收光谱和PL发射光谱分别表现出系统的吸收和发射蓝移,证实了合成量子点的量子约束效应。随着络合剂浓度的变化,tauc图估计的带隙由3.26eV增大到3.92eV。FTIR光谱显示出Cu-S拉伸峰特征。通过标准电导率电池测量的电解离子cu溶液的离子贡献清楚地显示了产品材料的半导体行为。该合成材料可用于制造紫外-蓝区域的光电器件。
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引用次数: 0
Magnetic Behavior of Ising Nanowire with Mixed Integer Spins: A Monte Carlo Study 混合整数自旋的Ising纳米线的磁性行为:蒙特卡罗研究
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-m5cw02
A. Lafhal, E. M. Jalal, A. Hasnaoui, H. Saadi, N. Hachem, M. Madani, M. El Bouziani
The magnetic and thermal properties of a ferrimagnetic mixed spin-1 and spin-2 cubic Ising nanowire are studied by using the Monte Carlo simulation. The influences of the nearest (JAB) and next-nearest neighbor (JA and JB) exchange interactions and the single-ion anisotropies (DA and DB) on the critical and compensation temperatures are illustrated. Moreover, the phase diagrams on the (temperature, anisotropy) plane are plotted for several values of JA/|JAB|. The system shows very rich and interesting behaviors, namely first and second order phase transitions, tricritical points and compensation phenomenon. Finally, the dependence of hysteresis loops on the anisotropies, the exchange interactions and the temperature is also investigated.
采用蒙特卡罗模拟方法研究了自旋为1和自旋为2的亚铁磁性混合立方Ising纳米线的磁性和热学性质。说明了最近离子(JAB)和次近邻离子(JA和JB)交换相互作用以及单离子各向异性(DA和DB)对临界温度和补偿温度的影响。此外,还绘制了不同JA/|JAB|值在(温度、各向异性)平面上的相图。系统表现出非常丰富而有趣的行为,即一阶和二阶相变、三临界点和补偿现象。最后,研究了磁滞回线与各向异性、交换相互作用和温度的关系。
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引用次数: 1
Removal of Congo Red from Wastewater Using ZnO/MgO Nanocomposites as Adsorbents: Equilibrium Isotherm Analyses, Kinetics and Thermodynamic Studies ZnO/MgO纳米复合吸附剂去除废水中的刚果红:平衡等温线分析、动力学和热力学研究
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-aijz91
Shifa Wang, S. Tang, Huajing Gao, Chuan Yu, Han Yang, Xianlun Yu, Xi Ping Chen, Leiming Fang, Dengfeng Li
One step polyacrylamide gel method was used to synthesize the ZnO/MgO adsorbents and the adsorption behavior with Congo red (CR) from wastewater was extensively investigated. Various advanced techniques were applied to confirm the ZnO/MgO adsorbents consist of Zn, C, Mg and O elements and do not contain any other impurity elements. With the increase of MgO content, the morphology of ZnO/MgO adsorbent changes from the agglomeration of large particles to evenly dispersed fine particles and then to icicle structure. Results demonstrated that the adsorption process of ZnO/MgO adsorbents was significantly affected by the change in initial dye solution pH, initial adsorbent dosage, contact time and reaction temperature. The optimum pH, adsorbent dosage, contact time and reaction temperature is 9.81, 2 g /L, 65 min and 293 K, respectively. The maximum adsorption capacity of ZnO/MgO (nZnO:nMgO = 8:2) adsorbents (295.138 mg/g) for the adsorption of CR dye was approximately double that of previous reports (125 mg/g). The adsorption equilibrium data are well fitted by the Freundlich and Langmuir isotherm models. Thermodynamic studies indicate that the adsorption process of ZnO/MgO adsorbents is an exothermic process. Based on the experimental and theoretical analysis, the adsorption mechanism for the ZnO/MgO adsorbents consisted of hydrogen bonding, n-π interaction and electrostatic interaction. The present work pioneers the potential application of ZnO/MgO adsorbents for the adsorption of CR dye and further provides experimental evidence for the synthesis of other adsorbents.
采用一步聚丙烯酰胺凝胶法制备了氧化锌/氧化镁吸附剂,并对其对刚果红(CR)的吸附性能进行了研究。采用各种先进技术,证实ZnO/MgO吸附剂由Zn、C、Mg和O元素组成,不含任何其他杂质元素。随着MgO含量的增加,ZnO/MgO吸附剂的形貌由大颗粒团聚到均匀分散的细颗粒再到冰柱结构。结果表明,初始染料溶液pH、初始吸附剂投加量、接触时间和反应温度对ZnO/MgO吸附剂的吸附过程有显著影响。最佳pH值为9.81,吸附剂用量为2 g /L,接触时间为65 min,反应温度为293 K。ZnO/MgO (nZnO:nMgO = 8:2)吸附剂对CR染料的最大吸附量(295.138 mg/g)约为以往报道(125 mg/g)的两倍。吸附平衡数据用Freundlich和Langmuir等温模型拟合得很好。热力学研究表明,ZnO/MgO吸附剂的吸附过程是一个放热过程。通过实验和理论分析,ZnO/MgO吸附剂的吸附机理主要是氢键、n-π相互作用和静电相互作用。本研究为ZnO/MgO吸附剂在CR染料上的潜在应用开辟了道路,并为其他吸附剂的合成提供了实验依据。
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引用次数: 6
Effect of ZnO Nanoparticles Salt Precursors on Structural, Morphological, Optical and MB Photocatalytic Properties Using Hydrothermal Synthesis 水热合成ZnO纳米盐前驱体对结构、形态、光学和MB光催化性能的影响
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-03-30 DOI: 10.4028/p-82qxbi
Hicham Bahtoun, L. Hadjeris, S. Iaiche, Tarek Diab Ounis
ZnO nanoparticles were successfully produced via a simple low cost hydrothermal method using different metal precursors. Zn (CH3COO)2), (Zn (NO3)2) and (ZnCl2) were the source materials. The obtained nanoparticles were investigated by means XRD, SEM and DRS. The XRD exhibited the high crystallinity of the pure ZnO phase with hexagonal wurtzite crystalline structure for all simples excepted for ZnO synthetized from ZnCl2 precursor. The crystallite sizes was estimated in the range of 20-37 nm. The precursor type do not affect the Eg of the nanoparticles. The bandgaps energies were between 3.21-3.22 eV. The type of precursor affect the particles morphology. SEM images revealed different morphologies. The photocatalytic activity of the synthetized ZnO NPs in comparison with that of commercial powder for the methylene blue (MB) degradation under UV irradiation, showed the appropriate activity of nanostructures obtained by Zn (NO3)2 and Zn (CH3COO)2 precursors. The first-order kinetic constant over ZnO from Zn (NO3)2 was 1.9, 3.7 and 1.5 times of ZnO commercial powder, ZnO from ZnCl2 and Zn (CH3COO)2, respectively. The ZnO NPs from Zn (NO3)2 and Zn (CH3COO)2 precursors have the best photocatalytic degradation performance with a degradation rate of 99.3% and 96.4%, respectively. The higher photocatalytic performance was probably due to the larger crystallinity, purity phase and specific morphologies than smaller particle size effect. Thus, the synthetized ZnO nanoparticles by the soft hydrothermal process are a promising candidate for the photocatalytic purposes of dyes from waters.
采用不同的金属前驱体,通过简单、低成本的水热法制备了氧化锌纳米颗粒。Zn (CH3COO)2)、Zn (NO3)2和ZnCl2为源物质。采用XRD、SEM和DRS对所制得的纳米颗粒进行了表征。XRD结果表明,除由ZnCl2前驱物合成的ZnO外,其余样品均为高结晶度的纯ZnO,具有六方纤锌矿结构。晶体尺寸在20 ~ 37 nm之间。前驱体类型不影响纳米颗粒的Eg。带隙能量在3.21 ~ 3.22 eV之间。前驱体的类型影响颗粒形态。扫描电镜图像显示不同的形态。合成的ZnO纳米粒子在紫外光下降解亚甲基蓝(MB)的光催化活性与商业粉末的光催化活性比较,表明以Zn (NO3)2和Zn (CH3COO)2为前驱物制备的纳米结构具有适当的光催化活性。Zn (NO3)2制得的氧化锌的一级动力学常数分别是工业氧化锌粉、ZnCl2制得的氧化锌和Zn (CH3COO)2制得的氧化锌的1.9倍、3.7倍和1.5倍。由Zn (NO3)2和Zn (CH3COO)2前驱体制备的ZnO NPs光催化降解性能最好,降解率分别为99.3%和96.4%。较高的光催化性能可能是由于更大的结晶度、纯度相和特定的形貌而不是较小的粒径效应。因此,软水热法制备的ZnO纳米颗粒是光催化水中染料的理想材料。
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引用次数: 1
Growth of Ni-Co-S Nanoflakes on Ni Bowl-Like Micro/Nano Array as a Non-Enzymatic Electrode for Detection of Glucose Ni- co - s纳米片在Ni碗状微/纳米阵列上生长作为葡萄糖检测的非酶电极
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2022-11-21 DOI: 10.4028/p-3103ee
Xiaolan Tang, J. Zhao, L. Qin, Ying-Ying Xu
A new synthetic procedure to Metal/metal sulfide hierarchical pore array composites was described. That is, a layer of Ni-Co-S nanoflakes was in situ constructed on the Ni ordered bowl-like micro/nanoarrays through a two-step electrodeposition method with the assistance of a colloidal sphere template. Such as-grown hierarchical composites could increase the specific surface areas and provide more active sites for electrocatalytic reactions. It exhibited a high catalytic activity to glucose, with a high sensitivity of 1210.1 μM‧mM-1cm-2 and a wide linear range from 0.5 μM to 2.0 mM. This work provides another candidate material for the development of planar non-enzymatic glucose sensors.
介绍了一种合成金属/金属硫化物层次化孔阵列复合材料的新工艺。也就是说,在胶体球模板的辅助下,通过两步电沉积法在Ni有序碗状微纳米阵列上原位构建了一层Ni- co -s纳米片。这种生长的分层复合材料可以增加比表面积,并为电催化反应提供更多的活性位点。该材料对葡萄糖具有较高的催化活性,灵敏度为1210.1 μM·mM-1cm-2,线性范围为0.5 μM ~ 2.0 mM。该研究为平面非酶促葡萄糖传感器的开发提供了另一种候选材料。
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引用次数: 0
Antibacterial Polysulfone Nanofiber Functionalized with Green Silver Nanoparticles by a Facile Wetting Method for Microbial Corrosion Protection 绿色纳米银功能化抗菌聚砜纳米纤维的易湿法微生物腐蚀防护
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2022-11-21 DOI: 10.4028/p-4z44c3
Nalan Oya San Keskin, Furkan Deniz, H. Nazır
The introduction of antimicrobial nanoparticles into nanofiber coatings is significant for enhancing microbial corrosion protection. Here, electrospun polysulfone nanofiber (PSU-Nf) and PSU-Nf functionalized with biogenic silver nanoparticles (AgNPs) coatings (PSU-Nf-AgNPs) used for Cobalt (Co) corrosion resistance in a marine environment containing Aeromonas eucrenophila (A. eucrenophila). We utilized the barrier function of the PSU-Nf and the bacterial inhibition property of the AgNPs that are synthesized using bacteria. The thickness of nanofiber coatings was 233.11 ± 33.64 µm analyzed by optical microscope and beadless morphology of nanofibers was observed using scanning electron microscope (SEM). The corrosion behavior of Co coated with PSU-Nf and PSU-Nf-AgNPs in abiotic and in the presence of the bacterium environment was investigated via polarization techniques and electrochemical impedance spectroscopy (EIS). Corrosion analysis reveals that the charge transfer resistance (Rct) increased because of the addition of the nanostructure resulting in a reduction in corrosion rate. SEM micrographs show Co surface was severely damaged by a microbial corrosive attack with severe crevices. However, the PSU-Nf and especially PSU-Nf-AgNPs coated Co surface was still covered by nanofiber coatings as the bacteria colony was not noticed. In addition, the results of the performing bacterial disk diffusion method indicated that electrospun PSU-Nf-AgNPs have good antibacterial activity against Gram-positive, Gram-negative, and model biofilm bacterium. It was found that the uncoated Co surface had severe crevices and offered poor corrosion resistance under mineral salt medium with A. eucrenophila strain. Therefore, PSU-Nf-AgNPs coated Co exhibited better corrosion resistance in mineral salt medium containing bacteria.
在纳米纤维涂层中引入抗微生物纳米颗粒对提高涂层的微生物防腐性能具有重要意义。在这里,静电纺聚砜纳米纤维(PSU-Nf)和PSU-Nf功能化的生物纳米银(AgNPs)涂层(PSU-Nf-AgNPs)用于在含有嗜嗜嗜气单胞菌(a .嗜嗜嗜嗜气单胞菌)的海洋环境中抗钴(Co)腐蚀。我们利用PSU-Nf的屏障功能和细菌合成的AgNPs的细菌抑制特性。光学显微镜观察纳米纤维涂层的厚度为233.11±33.64µm,扫描电镜观察纳米纤维的无头形貌。利用极化技术和电化学阻抗谱(EIS)研究了PSU-Nf和PSU-Nf- agnps涂层Co在非生物和细菌环境中的腐蚀行为。腐蚀分析表明,纳米结构的加入增加了电荷传递电阻(Rct),从而降低了腐蚀速率。SEM显微图显示,Co表面受到微生物腐蚀的严重破坏,出现了严重的裂缝。然而,PSU-Nf,特别是PSU-Nf- agnps涂层的Co表面仍然被纳米纤维涂层覆盖,因为细菌菌落没有被发现。此外,执行细菌圆盘扩散法的结果表明,静电纺丝PSU-Nf-AgNPs对革兰氏阳性、革兰氏阴性和模式生物膜细菌具有良好的抗菌活性。结果表明,在无机盐介质中,未涂覆的Co表面存在严重的裂纹,耐蚀性较差。因此,包覆Co的PSU-Nf-AgNPs在含细菌的无机盐介质中具有更好的耐腐蚀性。
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引用次数: 0
Silicon-Doped Nanostructured Fe80Ni20 Alloys: The Role of Si on the Microstructure, Morphology and Magnetic Properties 掺硅纳米Fe80Ni20合金:Si对其组织、形貌和磁性能的影响
IF 1.7 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2022-11-21 DOI: 10.4028/p-6nyf2h
Hafida Ourihane, A. Guittoum, M. Hemmous, D. Martínez-Blanco, J. Blanco, P. Gorria, N. Boukherroub
Fe(Ni, Si) solid solutions were elaborated by high energy mechanical alloying from elemental Fe, Ni and Si powdersfor a milling time of 72 h. From X-ray diffraction (XRD) analysis, it has been shown that the Fe(Ni, Si) samples present a single phase in the whole range of Si content and exhibit a solid solution of disordered bcc α-Fe. The lattice parameter a (Å) of the new structures and the mean crystallitessize (nm) were found to decrease with increasing Si contents. In contrast, the microstrain behaviour presents two different stages as the Si contents are increased. Scanning Electron Microscopy (SEM) images confirmed the behaviour of the mean crystallites size, where it can be seen that the addition of Si promotes the reduction of the size of powder particles. The saturation magnetization Ms was found to decrease by a factor of almost 1.4 and the coercively was found to increase by a factor of almost 2.4, when the Si content was increased from x= 0 % to x= 20 %. The Mössbauer spectroscopy confirmed the local in site crystal locations of Si and Ni as they diffuse into the matrix of the bcc α-Fe structure to form a solid solution.
将单质Fe、Ni和Si粉末经72 h的高能机械合金化制备出Fe(Ni, Si)固溶体。x射线衍射(XRD)分析表明,Fe(Ni, Si)样品在整个Si含量范围内均为单相,表现为无序的bcc α-Fe固溶体。新结构的晶格参数a (Å)和平均晶粒尺寸(nm)随Si含量的增加而减小。随着硅含量的增加,微应变行为呈现出两个不同的阶段。扫描电镜(SEM)图像证实了平均晶粒尺寸的行为,其中可以看到Si的加入促进了粉末颗粒尺寸的减小。当Si含量从x= 0%增加到x= 20%时,饱和磁化强度Ms降低了近1.4倍,矫顽力Ms增加了近2.4倍。Mössbauer光谱证实了Si和Ni扩散到bcc α-Fe结构基体中形成固溶体时的局部原位晶体位置。
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引用次数: 0
期刊
Journal of Nano Research
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