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Geochemical, mineralogical and petrographical characteristics of the domanik formation from north samara region in the volga-ural basin, Russia: Implication for unconventional tight oil reservoir potential 俄罗斯伏尔加盆地北萨马拉地区domanik组的地球化学、矿物学和岩石学特征:对非常规致密油藏潜力的启示
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111240
Shadi A. Saeed , Mohammed Hail Hakimi , Ameen A. Al-Muntaser , Aliia N. Khamieva , Mikhail A. Varfolomeev , Vladimir P. Morozov , Aref Lashin , Mohamed A. Abdelaal , Muneer A. Suwaid , Khairul Azlan Mustapha , Richard Djimasbe , Rail I. Kadyrov , Bulat I. Gareev , Michael Kwofie

This paper comprehensively analyzes the geochemical, mineralogical and petrographical properties combined with bulk kinetics modeling of the Domanik organic-rich carbonate from various depth intervals in Kuzminovsky oilfield (well № 26 R), Volga-Ural Basin, Russia. The results show that, the Domanik carbonate-rich samples are characterized by high content of the total organic matter (TOC) up to 13.31 wt %, and contain mainly Type II kerogen with a slight II/III kerogen type, reaching very good to excellent oil generation potential. Moreover, the studied samples contain hydrogen-rich kerogen, which expected to generate paraffin, naphthene and aromatic (P–N-A) oil with low wax content as demonstrated by the Py-GC Pyrolysis combined with the abundance of fluorescent alginite, amorphous organic matter, and bituminite as established from investigations via microscope. The maturity indicators demonstrated that, most of the examined Domanik carbonate-rich samples, with a burial depth between 1726.5 m and 1784.9 m, have generally reached low thermal maturity stages; thus, defining an immature to moderate-mature of oil generation window. The results of the kinetic models suggested that, Domanik carbonate-rich rocks with vitrinite reflectance (VRo) values in the range of 0.60–0.71%, have reached relatively low kerogen transformation ratio in the range of 10–20%, indicating low probability oil generation. These finding are confirmed by the presence of low oil saturation index of less than 100 mg HC/g rock (19.64–69.97). In addition, the results of thin section, scanning electron microscopy (SEM) and micro-computed tomography (micro-CT) showed that the studied samples are characterized by low porosity (up to 3.29%) with a wide pores size range, including interparticle, cavities, cracks and organic matter pores. The development of these pore types and their quality in the studied samples is mainly controlled by high mineralogical brittleness (i.e., carbonate and quartz) together with the high organic matter inputs. Therefore, according to the obtained results, characteristics and observations, the Domanik Formation has a high potential for commercial oil production, which typically requires hydraulic fracturing followed by an in-situ retort, mainly by thermal methods such as steam injection and in situ combustion process.

结合整体动力学模型,综合分析了俄罗斯伏尔加-乌拉尔盆地库兹米诺夫斯基油田(26 R井)不同深度层段Domanik富有机质碳酸盐岩的地球化学、矿物学和岩石学性质。结果表明,Domanik富碳酸盐样品总有机质(TOC)含量较高,达13.31 wt %,以II型干酪根为主,II/III型干酪根略占一部分,具有极好的生油潜力。此外,研究样品中含有富氢干酪根,通过Py-GC热解,结合显微镜观察发现荧光藻酸盐、无定形有机物和烟煤的丰度,可以得到蜡含量较低的石蜡、环烷和芳香(P-N-A)油。成熟度指标表明,所检测的Domanik富碳酸盐样品大多处于低热成熟阶段,埋深在1726.5 ~ 1784.9 m之间;从而定义了一个不成熟到中成熟的生油窗口。动力学模型结果表明,镜质组反射率(VRo)值在0.60 ~ 0.71%之间的Domanik富碳酸盐岩,其干酪根转化率较低,在10 ~ 20%之间,表明其生油概率较低。低含油饱和度指数< 100 mg HC/g岩石(19.64 ~ 69.97)证实了这一发现。薄片、扫描电镜(SEM)和显微ct (micro- computer tomography, micro-CT)分析结果表明,样品孔隙率低(3.29%),孔隙尺寸范围广,包括颗粒间、空洞、裂缝和有机质孔隙。研究样品中这些孔隙类型的发育及其质量主要受高矿物脆性(即碳酸盐和石英)和高有机质输入的控制。因此,根据所获得的结果、特征和观察结果,Domanik组具有很高的商业采油潜力,通常需要水力压裂,然后进行原位蒸馏法,主要是通过蒸汽注入和原位燃烧等热方法。
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引用次数: 6
Bridging the integration gap—simultaneous optimization of well placement, well trajectory, and facility layout 同时优化井位、井眼轨迹和设施布局
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111222
Kassem Ghorayeb , Hussein Hayek , Ahmad Harb , Haytham M. Dbouk , Tarek Naous , Anthony Ayoub , Richard Torrens , Owen Wells

We present an integrated field development planning framework that bridges the integration gap through concurrently optimizing well placement, well trajectory, and facility layout. The novel algorithms implemented in the proposed framework break organizational silos between the reservoir, wells, and facility domains and provide reservoir engineers, drilling engineers, facility engineers, and economists with a shared planning platform. The presented solution is modular, flexible, and allows for multiple layers of granularity and, hence, a spectrum of solutions with different trade-offs between accuracy and efficiency needed as the field development plan is refined through its history. Multiple scenarios and example cases are presented illustrating the features of the integrated optimization framework and their applicability in different potential onshore and offshore oil and gas field development projects.

A novel machine learning based optimization algorithm for well trajectory design is presented and achieves significant improvements in computational time compared to traditional optimization approaches. Using a machine learning model to design a well trajectory was three orders of magnitude faster than the differential evolution algorithm which, in turn, was the fastest among the different optimization algorithms that we have tested. The proposed machine learning model drastically reduced the CPU requirements of the integrated solution and enabled the modeling of complex cases of hundreds of wells and associated facility building blocks.

我们提出了一个综合油田开发规划框架,该框架通过同时优化井位、井轨迹和设施布局来弥合一体化差距。在所提出的框架中实现的新算法打破了储层、井和设施领域之间的组织筒仓,并为储层工程师、钻井工程师、设施工程师和经济学家提供了一个共享的规划平台。所提出的解决方案是模块化的、灵活的,并允许多层粒度,因此,随着油田开发计划的历史不断完善,需要在准确性和效率之间进行不同权衡的一系列解决方案。介绍了多个场景和实例,说明了集成优化框架的特点及其在不同潜在陆上和海上油气田开发项目中的适用性。提出了一种新的基于机器学习的井眼轨迹优化算法,与传统的优化方法相比,该算法在计算时间上有了显著的改进。使用机器学习模型设计井轨迹比微分进化算法快三个数量级,而微分进化算法又是我们测试过的不同优化算法中速度最快的。所提出的机器学习模型大大降低了集成解决方案的CPU需求,并能够对数百口井和相关设施构建块的复杂情况进行建模。
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引用次数: 2
Effect of clay type and content on the mechanical properties of clayey silt hydrate sediments 粘土类型和含量对粘质粉土水合物沉积物力学性能的影响
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111203
Qiongqiong Tang , Yuanbo Chen , Rui Jia , Wei Guo , Weiqiang Chen , Xiaoshuang Li , Huicai Gao , Yu Zhou

Knowledge of the mechanical properties of natural gas hydrate reservoirs is fundamental to the safe and commercial extraction of natural gas hydrate. In our work, according to the characteristics of marine sediments in the South China Sea, gas hydrate samples with matrices containing 0%, 10%, 20%, and 30% montmorillonite or illite were prepared based on the saturated gas method. Under effective confining pressures of 2, 3 and 4 MPa, drained compression tests were performed on the samples. The results show that the clay type and clay content affect the failure strength and deformation of clayey silt hydrate sediments. The presence of clay causes the clayey silt hydrate samples to exhibit strain hardening behavior accompanied by shear shrinkage, and the failure strength and stiffness decrease with increasing clay content, as does the internal friction angle. The strength, stiffness, and Poisson's ratio of samples containing illite are generally greater than those containing montmorillonite. In addition, due to the strong bound water between particles, the cohesion of hydrate samples containing montmorillonite with similar hydrate saturations is higher than that of samples containing illite, while the internal friction angle is lower. These results are valuable for production well siting assessment in clayey silt hydrate reservoir and provide requisite theoretical basis for wellbore safety design.

了解天然气水合物储层的力学性质是安全和商业化开采天然气水合物的基础。本文根据南海海相沉积物的特点,采用饱和气法制备了基质含0%、10%、20%和30%蒙脱土或伊利石的天然气水合物样品。在有效围压为2、3、4 MPa的条件下,对试样进行了排水压缩试验。结果表明,粘土类型和含量对粘土粉砂水化沉积物的破坏强度和变形有影响。粘土的存在使粘土粉土水化试样表现出应变硬化和剪切收缩的特征,破坏强度和刚度随粘土含量的增加而减小,内摩擦角也随粘土含量的增加而减小。含伊利石样品的强度、刚度和泊松比一般大于含蒙脱石样品。此外,由于颗粒间存在较强的结合水,含水饱和度相近的蒙脱土水合物样品的黏聚力高于含水饱和度相近的伊利石水合物样品,而内摩擦角较低。研究结果对泥质淤泥质水合物油藏生产井选址评价具有一定的参考价值,为井筒安全设计提供了必要的理论依据。
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引用次数: 11
Field performance and numerical simulation study on the toe to heel air injection (THAI) process in a heavy oil reservoir with bottom water 有底水稠油油藏足跟注气过程的现场性能及数值模拟研究
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111202
Hossein Anbari , John P. Robinson , Malcolm Greaves , Sean P. Rigby

Extra-heavy oil and bitumen (EHOB) comprise 30 percent of the remaining recoverable fossil fuel resources on Earth. This means EHOB could play an important role in a secure transition towards net zero emissions (NZE) by 2050. Technological developments, such as toe to heel air injection (THAI), have been shown to efficiently recover heavy oil with reduced environmental footprint. The Kerrobert project was the first to utilise the THAI technology in presence of bottom water (BW) in the reservoir. The project demonstrated a good performance (with average oil rate of 10 m3/day per well) compared to the conventional ISC operations in a BW situation. Lessons taken from the Kerrobert operational experience can assist the forthcoming THAI operations explicitly in the presence of BW. Dynamic field data for one of the best performing THAI pilot well pairs (K2), were analysed in this work. It was found that the K2 pilot must have experienced interference from K5, which is the closest neighbouring THAI well pair to the K2. Previously developed THAI models have not been validated against actual field data. A new field-scale THAI model in the presence of BW was constructed and, for the first time, validated against the field data from the Kerrobert project in this work. In addition, the quasi-staggered line drive well arrangement, as used for the K2 pilot, was studied. The daily and cumulative oil production rates were predicted well (the final agreement with field data was within 3 percent). The history matched model was then used to investigate the effect of the variation in air injection rates on THAI performance in presence of BW. Major developed zones during the propagation of the combustion front were numerically examined. It was demonstrated that extra air ingress from the neighbouring THAI well pair has caused a reduction in oxygen utilisation throughout the process. As a result, the simulated temperature profile declined with the increasing combustion time. The oxygen profile around the horizontal producer (HP) well was studied via the new history-matched model. An inversely proportional relationship was detected between the coke concentration and the oxygen profile around the HP well. It was found that the size of the steam zone, ahead of the combustion front, differs with variation in air injection rates. It was observed that some of the mobilised oil sank into the BW, leaving a significant amount of oil trapped in the reservoir. To prevent such an event, the location of the HP well was altered as a potential strategy to optimise the THAI efficiency. Consequently, the oxygen utilisation was improved by 13%, resulting in 73% higher cumulative oil production in comparison with the history-matched model.

超稠油和沥青(EHOB)占地球上剩余可开采化石燃料资源的30%。这意味着到2050年,EHOB可以在向净零排放(NZE)的安全过渡中发挥重要作用。技术发展,如足跟空气喷射(THAI),已被证明可以有效地回收重油,并减少环境足迹。Kerrobert项目是第一个在水库存在底层水(BW)的情况下使用THAI技术的项目。与BW情况下的传统ISC操作相比,该项目表现出良好的性能(平均每口井的石油流量为10 m3/天)。从Kerrobert操作经验中吸取的经验教训可以明确地帮助即将在BW存在的情况下进行的THAI操作。本工作分析了性能最好的THAI先导井对之一(K2)的动态现场数据。已经发现K2导频一定经历了来自K5的干扰,K5是与K2最近的相邻THAI井对。先前开发的THAI模型尚未根据实际现场数据进行验证。在BW存在的情况下,构建了一个新的现场规模THAI模型,并首次根据Kerrobert项目的现场数据进行了验证。此外,还研究了用于K2先导的准交错线驱动井布置。对日产油率和累计产油率进行了很好的预测(与现场数据的最终一致性在3%以内)。然后使用历史匹配模型研究了在BW存在的情况下,空气喷射速率的变化对THAI性能的影响。对燃烧前沿传播过程中的主要发展区进行了数值研究。研究表明,从相邻THAI井对进入的额外空气导致整个过程中氧气利用率降低。结果,模拟温度曲线随着燃烧时间的增加而下降。采用新的历史拟合模型对水平生产井周围的氧气剖面进行了研究。在焦炭浓度和HP井周围的氧气分布之间检测到反比关系。研究发现,燃烧前沿之前的蒸汽区的大小随着空气喷射率的变化而不同。据观察,一些调动的石油沉入BW,留下大量石油滞留在储层中。为了防止此类事件发生,HP井的位置被更改为优化THAI效率的潜在策略。因此,氧气利用率提高了13%,与历史匹配模型相比,累计石油产量提高了73%。
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引用次数: 4
Modeling of solids particle diversion to promote uniform growth of multiple hydraulic fractures 固体颗粒导流促进多道水力裂缝均匀生长的模拟
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111159
Bo Luo , George K. Wong , Jianchun Guo , Wei Fu , Guanyi Lu , Andrew P. Bunger

Solid particulate additives are sometimes used to promote the uniform growth of multiple hydraulic fractures in horizontal oil and gas wells. The principle is that solid particulates block, accumulate, and form larger porous plugging zones preferentially at entrances of fracture taking in the most fluid volume. These porous zones create fluid flow resistance or additional pressure loss; thereby, inhibiting the growth of these dominant fractures and diverting fluid to suppressed fractures. While this technology is promising, governing design parameters and ramifications of placing solids diverters inside the fracture remain unclear. This paper models the propagation of multi-fractures with diverter pressure losses induced by the porous plugging zones. The resulting non-linear hydraulic fracturing problem is solved numerically with an Implicit Level Set Algorithm (ILSA) for each time step and the mechanisms of diversion are illustrated by comparing and contrasting cases with and without particle diverter. In both cases, during the fluid ramp-up period (pumping rate gradually increases from 0 to fracturing rate (QT)), the injection can be equally distributed among fractures before the stress interference affects the fluid allocation (Phase I). Then, stress interference starts to partition more fluid into outer fractures and suppress the growth of the middle fracture (Phase II). Once the perforation friction loss is sufficient to counteract the stress interaction, injection begins to shift to the middle fracture, but still gives a significantly non-uniform fracture growth (Phase III). At this point, solid diverter particles are introduced, leading to three additional phases of growth. Phase IV introduces solid diverters to the treatment at a reduced pumping rate. Particles bridge, accumulate and create porous plugging zones at the flow entrance. A higher pressure drop in outer fractures diverts injection fluids to the middle fracture. Phase V resumes the treatment rate to QT without diverter. The increased pump rate in turn increases the pressure drop in outer fractures and diverts more fluids to the middle fracture. This results in a rapid extension velocity for the middle fracture, enabling it to have the chance to catch up with the longer outer fractures (in Phase VI). This process is controlled by the interplay among stress interference, perforation friction loss, and diverting pressure drop. These simulations demonstrate that a model-based optimization could improve the effectiveness of the diverter technology and promote a uniform multi-fracture growth.

固体颗粒添加剂有时用于促进水平油气井中多条水力裂缝的均匀生长。其原理是固体颗粒在裂缝入口优先堵塞、积聚,形成较大的孔隙堵塞区,吸收的流体体积最大。这些多孔区域会产生流体流动阻力或额外的压力损失;因此,抑制这些优势裂缝的生长,并将流体转向抑制裂缝。虽然这项技术很有前景,但在裂缝内放置固体暂堵剂的控制设计参数和影响仍不清楚。本文模拟了多孔封堵带引起的分流压力损失对多裂缝扩展的影响。采用隐式水平集算法(ILSA)对每个时间步进行数值求解,并通过对有和无颗粒导流剂的情况进行对比,说明了导流机理。在这两种情况下,在流体加速阶段(泵注速率从0逐渐增加到压裂速率(QT)),在应力干扰影响流体分配之前,注入可以均匀分布在裂缝之间(阶段1),然后,应力干扰开始将更多的流体分配到外部裂缝中,抑制中间裂缝的生长(阶段2)。注入流体开始向裂缝中部转移,但仍会产生明显不均匀的裂缝扩展(第三阶段)。此时,引入固体暂堵剂颗粒,导致另外三个阶段的扩展。第四阶段以较低的泵送速率引入固体暂堵剂。颗粒在流动入口桥接、积聚并形成多孔堵塞区。外部裂缝中较大的压降使注入流体转向中间裂缝。第五阶段在没有分流剂的情况下将治疗速率恢复到QT。泵速的增加反过来增加了外部裂缝的压降,并将更多的流体转向中间裂缝。这导致了中间裂缝的快速延伸速度,使其有机会赶上较长的外部裂缝(在第六阶段)。这一过程由应力干扰、射孔摩擦损失和转向压降之间的相互作用控制。这些模拟结果表明,基于模型的优化可以提高暂堵剂技术的有效性,促进多裂缝均匀生长。
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引用次数: 3
Anisotropic total variation pre-stack multitrace inversion based on Lp norm constraint 基于Lp范数约束的各向异性全变分叠前多道反演
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111212
Lian Zhao , Kai Lin , Xiaotao Wen , Yuqiang Zhang

Due to the instability of extracting elastic parameters from conventional elastic impedance variation with incident angle (EVA) pre-stack inversion and the fact that single-trace inversion does not consider the correlation between seismic traces and the lateral continuity of inversion results. An anisotropic total variation multitrace inversion method based on the LP norm constraint is proposed on the basis of EVA inversion. In this paper, the LP norm is used as the regularization constraint, the longitudinal and transverse difference operators are introduced, and the alternating direction multiplier algorithm and the 2D Sylvester equation solver algorithm are used as inversion algorithms to achieve a multitrace inversion of the elastic parameters. The feasibility of the method proposed in this paper is verified by making full use of the advantages of both methods and conducting trial calculations on some blocks of the Marmousi2 model. The method was further validated by applying it to actual data from marine shales of the Longmaxi-Wufeng Formation in the southern Sichuan Basin. The inversion results were validated using a combination of brittleness indices and microseismic monitoring to confirm the feasibility of the method in this paper.

由于从传统的弹性阻抗随入射角变化(EVA)叠前反演中提取弹性参数的不稳定性,以及单道反演没有考虑地震道之间的相关性和反演结果的横向连续性。在EVA反演的基础上,提出了一种基于LP范数约束的各向异性全变分多道反演方法。本文采用LP范数作为正则化约束,引入纵向和横向差分算子,采用交替方向乘法器算法和二维Sylvester方程求解器算法作为反演算法,实现了弹性参数的多轨迹反演。通过充分利用这两种方法的优点,并对Marmousi2模型的一些块进行试算,验证了本文提出的方法的可行性。将该方法应用于川南龙马溪五峰组海相页岩的实际资料,进一步验证了该方法的有效性。将脆性指数与微震监测相结合,对反演结果进行了验证,验证了本文方法的可行性。
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引用次数: 1
Manifestations of surfactant-polymer flooding for successful field applications in carbonates under harsh conditions: A comprehensive review 表面活性剂聚合物驱在恶劣条件下成功应用于碳酸盐岩的表现:综述
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111243
Anas M. Hassan , Emad W. Al-Shalabi , Waleed Alameri , Muhammad Shahzad Kamal , Shirish Patil , Syed Muhammad Shakil Hussain

Most oil fields today are mature, and the majority of the reservoirs in the Middle East are carbonate rocks characterized by high temperature high salinity (HTHS), heterogeneous mineral composition, and natural fractures. Enhanced oil recovery (EOR) methods are used for boosting oil recovery from the aged reservoirs beyond primary and secondary recovery stages. Nevertheless, it can be a challenging task to employ EOR techniques in these aged carbonate reservoirs. This is because carbonate reservoirs have mixed-to-oil-wet wettability with temperatures exceeding 85 °C and salinity of over 100,000 ppm, which renders secondary EOR-methods such as waterflooding ineffective. Therefore, even though carbonate reservoirs contain 60–65% of world's remaining oil, with immense intrinsic economic prospects, the oil recovery process from carbonate reservoirs remains a considerable challenge. Chemical-EOR (cEOR) techniques, like SP based cEOR, have shown marked promise in improved oil recovery, mainly from clastic reservoirs with medium temperature and salinity, unlike carbonate reservoirs. During SP-floodings, the surfactants get adsorbed due to the mineral composition of the carbonate rocks, and polymer degradation occurs due to HTHS conditions. Consequently, new surfactants and polymers have been structurally conformed and tested to improve their robustness and related recovery efficacy. For instance, Guerbet alkoxy-carboxylate surfactants demonstrated good stability at temperatures over 100 °C and salinities up-to 275,000 ppm, yielding tertiary recovery of 94.5% and low adsorption of 0.086 mg/g of rock. The cationic Gemini surfactants, zwitterionic or amphoteric class of surfactants are also suitable for HTHS carbonates. Besides, effective biosurfactants sourced from plant such as, soy, corn, etc., are non-toxic and readily biodegradable. The hydrophobically associating polyacrylamide (HAPAM) and its modified nanocomposite derivative can act as replacement surfactants, due to their wettability altering and robust characteristics. Novel polymers viz., NVP-based, novel smart thermoviscosifying polymers (TVP), soft microgel, and sulfonated polymers, are also relevant to HTHS carbonate applications. Xanthan gum, scleroglucan, and schizophyllan biopolymers have been noted to resist HTHS and low permeability conditions, requiring lower concentration and having low adsorption. Recent surfactant-polymer (SP) formulations also can be applicable for HTHS carbonates with excellent ternary recoveries (93.6%) and minimal retention (0.083 μg/g of rock). Such low retention values suggest low surfactants cost with minimal environmental impact. Moreover, several successful field applications in carbonates were conducted in preceding years; however, the performance of some novel surfactants under HTHS carbonates is yet to be fully understood. Hence, this comprehensive revie

今天的大多数油田都已成熟,中东的大多数储层都是碳酸盐岩,其特征是高温高盐度(HTHS)、不均匀矿物成分和天然裂缝。提高石油采收率(EOR)方法用于提高老化储层的石油采收率,使其超过初级和次级采收阶段。然而,在这些老化的碳酸盐岩储层中采用EOR技术可能是一项具有挑战性的任务。这是因为碳酸盐岩储层在温度超过85°C和盐度超过100000 ppm的情况下混合到了油湿润湿性,这使得二次提高采收率方法(如注水)无效。因此,尽管碳酸盐岩油藏含有世界剩余石油的60-65%,具有巨大的内在经济前景,但碳酸盐岩油藏的采油过程仍然是一个相当大的挑战。化学EOR(cEOR)技术,如基于SP的cEOR,在提高石油采收率方面显示出显著的前景,主要来自中等温度和盐度的碎屑岩储层,而不是碳酸盐岩储层。在SP驱油过程中,表面活性剂由于碳酸盐岩的矿物成分而被吸附,聚合物由于HTHS条件而发生降解。因此,新的表面活性剂和聚合物已经在结构上进行了鉴定和测试,以提高它们的稳健性和相关的回收效率。例如,Guerbet烷氧基羧酸盐表面活性剂在超过100°C的温度和高达275000 ppm的盐度下表现出良好的稳定性,产生94.5%的三次回收率和0.086 mg/g岩石的低吸附率。阳离子Gemini表面活性剂、两性或两性表面活性剂也适用于HTHS碳酸盐。此外,有效的生物表面活性剂来源于植物,如大豆、玉米等,无毒且易于生物降解。疏水缔合聚丙烯酰胺(HAPAM)及其改性的纳米复合衍生物由于其润湿性的改变和坚固的特性,可以作为替代表面活性剂。新型聚合物,即基于NVP的新型智能热增粘聚合物(TVP)、软微凝胶和磺化聚合物,也与HTHS碳酸盐应用有关。黄原胶、硬葡聚糖和裂叶兰生物聚合物已被注意到能够抵抗HTHS和低渗透性条件,需要较低的浓度和较低的吸附性。最近的表面活性剂聚合物(SP)配方也适用于HTHS碳酸盐,具有优异的三元回收率(93.6%)和最小的保留率(0.083μg/g岩石)。这种低保留值表明表面活性剂成本低,对环境的影响最小。此外,在过去几年中,在碳酸盐岩中进行了几次成功的现场应用;然而,一些新型表面活性剂在HTHS碳酸盐下的性能尚待充分了解。因此,这篇全面的综述旨在为表面活性剂和聚合物优化在HTHS碳酸盐领域的应用提供新的视角。建议清单作为高效SP注水设计的指南。这一关键文献评估为高温高压碳酸盐岩SP驱的成功现场应用提供了一系列潜在的表现形式,具有经济和环境可行性。
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引用次数: 14
Sealing capacity evolution of gypsum salt caprocks under multi-cycle alternating stress during operations of underground gas storage 地下储气库运行中多循环交变应力作用下石膏盐盖层封闭性演化
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111244
Xueying Lyu , Liang Yun , Jiangen Xu , Han Liu , Xinan Yu , Ping Peng , Mukun Ouyang , Yu Luo

Caprock sealing ability is one of the key geological factors to ensure the stable and safe operation of the underground gas storage (UGS). Gypsum salt rock is the high-quality caprock for oil and gas reservoirs, however, the effect of cyclic stress on its sealing capacity is still unclear, which restricts the construction progress of this kind of UGS. Therefore, taking the H UGS in the Sichuan Basin in China as an example, this paper analyzes the initial sealing capacity of gypsum salt caprock using cast thin section, conventional physical property test, nuclear magnetic resonance and breakthrough pressure tests. On this basis, study the variation characteristics of physical and mechanical parameters of gypsum salt caprock under cyclic stress using cyclic stress loading and unloading experiment, and then analyze the evolution law of its sealing capacity. The results show that gypsum salt caprocks of H UGS can be used as a good tight caprock with the porosity less than 1.0%, permeability less than 0.005 mD, breakthrough pressure greater than 6.0 MPa and triaxial compressive strength greater than 210 MPa. In addition, the physical properties of gypsum salt caprock become worse and the sealing capacity increases under cyclic stress, and physical and mechanical changes of gypsum salt caprock mainly occur in the first 30 cycles accounting for about 75%. Moreover, with the increase of cycles, the Poisson's ratio increases by 88% while the change range of elastic modulus is only 6.4%, indicating that gypsum salt caprocks mainly expands laterally and still maintain good elasticity. However, when the cycle times reach a certain threshold of 1002, the cumulative plastic strain of gypsum salt rock will become larger and larger until fracture. And the gypsum salt caprocks can be effective cover in the 184 cycles of loading and unloading with the maximum pressure threshold of 18 MPa and minimum pressure threshold of 1 MPa. This research results can provide theoretical guidance for cap rock stability analysis and operation parameter design of gas reservoir.

盖层封闭能力是保证地下储气库稳定安全运行的关键地质因素之一。膏盐岩是油气藏的优质盖层,但循环应力对其封闭能力的影响尚不清楚,制约了这种UGS的建设进度。因此,本文以中国四川盆地的H UGS为例,采用铸薄片、常规物性测试、核磁共振和突破压力测试等方法,对膏盐盖层的初始封闭能力进行了分析。在此基础上,利用循环应力加载和卸载实验,研究了膏盐盖层在循环应力作用下物理力学参数的变化特征,分析了其封闭能力的演化规律。结果表明,高UGS膏盐盖层孔隙度小于1.0%,渗透率小于0.005mD,穿透压力大于6.0MPa,三轴抗压强度大于210MPa,是一种良好的致密盖层。此外,在循环应力作用下,膏盐盖层的物理性质变差,封闭能力增强,膏盐盖层的物理力学变化主要发生在前30个循环,约占75%。此外,随着循环次数的增加,泊松比增加了88%,而弹性模量的变化范围仅为6.4%,表明膏盐盖层主要横向扩展,仍保持良好的弹性。然而,当循环次数达到1002的某一阈值时,膏盐岩的累积塑性应变会越来越大,直到破裂。膏盐盖层在最大压力阈值为18MPa、最小压力阈值为1MPa的184次加载和卸载循环中都能起到有效覆盖作用。该研究成果可为气藏盖层稳定性分析和运行参数设计提供理论指导。
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引用次数: 0
Integrated geochemical and statistical evaluation of the source rock potential in the deep-water, Western Basin of Ghana 加纳西部盆地深水烃源岩潜力综合地球化学与统计评价
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111164
Rabiatu Abubakar , Kofi Adomako-Ansah , Solomon Adjei Marfo , Clifford Fenyi , Judith Ampomah Owusu

Ghana is recognised as one of the recent oil and gas producing countries in the Gulf of Guinea, West Africa. However, despite the significant hydrocarbon accumulation in the Western Basin of Ghana, not much is known about the current potential of source rocks in this Basin. To broaden the scope of current knowledge on the Western Basin of Ghana, this paper identifies the current formation potential, organic matter origin, thermal maturity, and possible ages within the Cretaceous Period for hydrocarbon generation in the basin, using geochemical techniques and statistical analyses of 1530 cuttings and core samples. The geochemical parameters include pyrolysis data such as free hydrocarbon (S1), hydrocarbon generated (S2), carbon dioxide released (S3), hydrogen index (HI), production index (PI), maximum temperature (Tmax), oxygen index (OI) and total organic carbon (TOC). The formations encountered in the Western Basin, which have various ages within the Cretaceous Period , show a good to very good possibility of producing hydrocarbon with mainly kerogen type II/III and some amount of type I in certain formations. The majority of the Cretaceous ages fall in the early mature to peak maturity zone, with Campanian and Santonian considered as additional hydrocarbon sources to the Albian, Cenomanian, and Turonian. Pearson coefficient showed that TOC has a strong positive correlation with S2, positive correlation with S1 and HI, and negative correlation with Tmax. Two-Step and K-means clustering on the studied samples show that TOC, S2, and S3 are the major parameters for source rock potential prediction. Factor analysis gave three factors affecting source rock evaluation. Factor 1 highlights TOC, S1, and S2 as the parameters for identifying the quantity and quality of organic matter. This is confirmed by factor 2, which identifies HI and OI as the determining variables. Factor 3 identifies PI and Tmax as indicators of the thermal maturity of the source rock.

加纳被认为是西非几内亚湾最近的石油和天然气生产国之一。然而,尽管加纳西部盆地具有重要的油气聚集,但人们对该盆地目前的烃源岩潜力知之甚少。为了扩大目前对加纳西部盆地的认识范围,本文利用地球化学技术和1530个岩屑和岩心样本的统计分析,确定了该盆地目前的地层潜力、有机质来源、热成熟度和白垩纪可能的生烃年龄。地球化学参数包括热解数据,如游离烃(S1)、生烃(S2)、二氧化碳释放(S3)、氢指数(HI)、生产指数(PI)、最高温度(Tmax)、氧指数(OI)和总有机碳(TOC)。盆地西部地层在白垩纪范围内具有不同的年龄,具有较好的到极好的产烃可能性,以干酪根ⅱ/ⅲ型为主,个别地层有少量干酪根ⅰ型。白垩纪的大部分年龄落在早成熟至峰值成熟带,坎帕期和圣东期被认为是除阿尔比系、塞诺曼期和Turonian期外的额外烃源。Pearson系数显示TOC与S2呈正相关,与S1、HI呈正相关,与Tmax呈负相关。两步聚类和K-means聚类结果表明,TOC、S2和S3是烃源岩潜力预测的主要参数。因子分析给出了影响烃源岩评价的三个因素。因子1强调TOC、S1和S2作为识别有机质数量和质量的参数。因子2证实了这一点,它将HI和OI确定为决定变量。因子3认为PI和Tmax是烃源岩热成熟度的指标。
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引用次数: 4
Evaluation of L-ascorbic acid as a green low dosage hydrate inhibitor in water-based drilling fluid for the drilling of gas hydrate reservoirs l -抗坏血酸在水基钻井液中作为绿色低剂量水合物抑制剂的评价
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111156
Soubir Das , Vikas Mahto , G. Udayabhanu , M.V. Lall , Karan Singh , Mohinish Deepak

Hydrate plug formation in the drilling fluid flow line is a significant issue in the oil and gas industry. Green hydrate inhibitors have recently gained much interest in flow assurance problems as they are being used as alternatives for existing hydrate inhibitors. The present study described that L-ascorbic acid (LA), a natural organic compound, has been identified as a Low Dosage Hydrate Inhibitor and has exhibited better results than Polyvinylcaprolactum (PVCap) and Polyvinylpyrrolidone (PVP). The temperature-augmented visual method and a self-fabricated set-up have been used to determine the first hydrate crystal formation in the tetrahydrofuran (THF)-water hydrate system. LA has shown a better inhibition effect in terms of induction time (i.e., >1440 min) than PVCap (119.67–180.67 min) and PVP (85.33–240.67 min). Carboxymethyl cellulose (CMC), polyanionic cellulose (PAC), xanthan gum (XG), and potassium chloride (KCl) are mixed with water to make the water-based drilling fluids used in this study. The R2 values showed a good agreement with the Herschel-Bulkley Model (R2 ranges from 0.993 to 0.999 for 0.5 w/v% PVCap and 0.1 w/v% PVP-containing fluids) than Bingham Plastic Model (R2 ranges from 0.836 to 0.952 for 0.1 w/v% PVP and base fluids). The MPE values are less for Herschel-Bulkley Model (From 1.418 to 6.015 for 0.5 w/v% PVCap and 0.1 w/v% PVP) than for Bingham Plastic (From 9.985 to 29.718 for 1.0 w/v% PVP and 0.1 w/v% PVP). Cross Model is also used to determine the zero and infinite shear viscosities for the formulated fluid system, which showed the viscosities are in the permissible range. These observations suggest that L-ascorbic acid (LA) may be an effective hydrate inhibitor in drilling fluids.

钻井液流动管线中水合物塞的形成是石油和天然气行业中的一个重要问题。绿色水合物抑制剂最近对流量保证问题产生了很大的兴趣,因为它们被用作现有水合物抑制剂的替代品。本研究描述了L-抗坏血酸(LA),一种天然有机化合物,已被鉴定为低剂量水合物抑制剂,并表现出比聚乙烯己乳(PVCap)和聚乙烯吡咯烷酮(PVP)更好的效果。采用增温可视化方法和自制装置测定了四氢呋喃-水水合物体系中第一水合物晶体的形成。LA在诱导时间(即>;1440 min)方面表现出比PVCap(119.67–180.67 min)和PVP(85.33–240.67 min。R2值与Herschel-Bulkley模型(含0.5w/v%PVCap和0.1w/v%PVP的流体的R2范围为0.993至0.999)比Bingham塑料模型(含0.1w/v%PVP和基础流体的R2为0.836至0.952)显示出良好的一致性。Herschel-Bulkley模型的MPE值(对于0.5w/v%PVCap和0.1w/v%PVP,从1.418到6.015)小于宾汉塑料(对于1.0w/v%PPV和0.1w/v/v%PVP从9.985到29.718)。交叉模型还用于确定配方流体系统的零剪切粘度和无限剪切粘度,表明粘度在允许范围内。这些观察结果表明,L-抗坏血酸(LA)可能是钻井液中一种有效的水合物抑制剂。
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引用次数: 3
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Journal of Petroleum Science and Engineering
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