Pub Date : 2024-09-16DOI: 10.1088/1361-6463/ad76bc
Subrata Ghosh, Giacomo Pagani, Massimilano Righi, Chengxi Hou, Valeria Russo and Carlo S Casari
Advanced material composite of nanocarbons and metal-based materials provides a synergistic effect to obtain excellent electrochemical charge-storage performance and other properties. Herein, 3D porous carbon-metal oxynitride nanocomposites with tunable carbon/metal and oxygen/nitrogen ratio are synthesized uniquely by simultaneous ablation from two different targets by single-step pulsed laser deposition at room temperature. Co-ablation of titanium and vanadium nitride targets together with graphite allowed us to synthesize carbon-metal oxynitride porous nanocomposite and exploit them as a binder-free thin film supercapacitor electrode in aqueous electrolyte. We show that the elemental composition ratio and hence the structural properties can be tuned by selecting target configuration and by manipulating the ablation position. We investigate how this tuning capability impacts their charge-storage performances. We anticipate the utilization of as-synthesized various composites in a single PLD production run as next-generation active materials for flexible energy storage and optoelectronic applications.
{"title":"One-step pulsed laser deposition of carbon/metal oxynitride composites for supercapacitor application","authors":"Subrata Ghosh, Giacomo Pagani, Massimilano Righi, Chengxi Hou, Valeria Russo and Carlo S Casari","doi":"10.1088/1361-6463/ad76bc","DOIUrl":"https://doi.org/10.1088/1361-6463/ad76bc","url":null,"abstract":"Advanced material composite of nanocarbons and metal-based materials provides a synergistic effect to obtain excellent electrochemical charge-storage performance and other properties. Herein, 3D porous carbon-metal oxynitride nanocomposites with tunable carbon/metal and oxygen/nitrogen ratio are synthesized uniquely by simultaneous ablation from two different targets by single-step pulsed laser deposition at room temperature. Co-ablation of titanium and vanadium nitride targets together with graphite allowed us to synthesize carbon-metal oxynitride porous nanocomposite and exploit them as a binder-free thin film supercapacitor electrode in aqueous electrolyte. We show that the elemental composition ratio and hence the structural properties can be tuned by selecting target configuration and by manipulating the ablation position. We investigate how this tuning capability impacts their charge-storage performances. We anticipate the utilization of as-synthesized various composites in a single PLD production run as next-generation active materials for flexible energy storage and optoelectronic applications.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"92 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142263076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-16DOI: 10.1088/1361-6463/ad77de
N N Misra, Tejas Naladala and Khalid J Alzahrani
This review explores the engineering and design aspects of plasma activated water (PAW) systems, focusing on their application in food safety and agriculture. This review aims to bridge the gap between research and practical application, paving the way for the development of robust and efficient PAW systems for enhancing food safety and agricultural productivity. By examining a variety of activation methods, including direct gas ionization, underwater discharges, and dynamic interactions of ionized gases with liquids, this work discusses the mechanical designs that facilitate these processes, highlighting their scalability and efficiency. The discussion is grounded in a comprehensive relevant scientific and patent literature, offering a critical overview of the systems’ design parameters that influence the generation of reactive oxygen and nitrogen species (RONS). The designs reported in literature have employed three major approaches, viz. direct underwater discharges, gas ionization followed by introduction of plasma into the liquid, creation of gas liquid mixtures and subsequent ionization. The laboratory systems have relied on natural convective diffusion of the RONS into water, while most of the patents advocate use of forced convective diffusion of RONS to increase transfer rates. Despite widespread laboratory-scale research in PAW, the transition to industrial-scale systems remains underexplored.
{"title":"Design of systems for plasma activated water (PAW) for agri-food applications","authors":"N N Misra, Tejas Naladala and Khalid J Alzahrani","doi":"10.1088/1361-6463/ad77de","DOIUrl":"https://doi.org/10.1088/1361-6463/ad77de","url":null,"abstract":"This review explores the engineering and design aspects of plasma activated water (PAW) systems, focusing on their application in food safety and agriculture. This review aims to bridge the gap between research and practical application, paving the way for the development of robust and efficient PAW systems for enhancing food safety and agricultural productivity. By examining a variety of activation methods, including direct gas ionization, underwater discharges, and dynamic interactions of ionized gases with liquids, this work discusses the mechanical designs that facilitate these processes, highlighting their scalability and efficiency. The discussion is grounded in a comprehensive relevant scientific and patent literature, offering a critical overview of the systems’ design parameters that influence the generation of reactive oxygen and nitrogen species (RONS). The designs reported in literature have employed three major approaches, viz. direct underwater discharges, gas ionization followed by introduction of plasma into the liquid, creation of gas liquid mixtures and subsequent ionization. The laboratory systems have relied on natural convective diffusion of the RONS into water, while most of the patents advocate use of forced convective diffusion of RONS to increase transfer rates. Despite widespread laboratory-scale research in PAW, the transition to industrial-scale systems remains underexplored.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"30 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142263077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-16DOI: 10.1088/1361-6463/ad7510
Zhihao Mao, Da Li and Er-Ping Li
Metasurfaces have attracted widespread attention in recent years due to their powerful electromagnetic wave manipulation capabilities. This paper proposes and validates a single-polarized, angle-adjustable reflective digital coding metasurface. Each unit cell achieves independent reflection phase control by loading a PIN diode for on-off switching. The unit’s design and coding scheme are carefully optimized to ensure the performance of the proposed reconfigurable metasurface. As a validation, a prototype consisting of 16×16 elements is fabricated and measured, with a control signal provided by a field-programmable gate array controller. Experimental results demonstrate angle control of up to ±60° in the frequency range of 3.4 GHz–3.6 GHz, a peak gain of 24.9 dBi in a single channel, and gain exceeding 10 dBi across a 200 MHz operational bandwidth. Furthermore, the performance is validated in a communication system, yielding positive results. The proposed reflective digital coding metasurface contributes to the advancement of reconfigurable intelligent surfaces and holds promise for widespread adoption in various communication scenarios.
{"title":"Wide-angle reflection control with a reflective digital coding metasurface for 5G communication systems","authors":"Zhihao Mao, Da Li and Er-Ping Li","doi":"10.1088/1361-6463/ad7510","DOIUrl":"https://doi.org/10.1088/1361-6463/ad7510","url":null,"abstract":"Metasurfaces have attracted widespread attention in recent years due to their powerful electromagnetic wave manipulation capabilities. This paper proposes and validates a single-polarized, angle-adjustable reflective digital coding metasurface. Each unit cell achieves independent reflection phase control by loading a PIN diode for on-off switching. The unit’s design and coding scheme are carefully optimized to ensure the performance of the proposed reconfigurable metasurface. As a validation, a prototype consisting of 16×16 elements is fabricated and measured, with a control signal provided by a field-programmable gate array controller. Experimental results demonstrate angle control of up to ±60° in the frequency range of 3.4 GHz–3.6 GHz, a peak gain of 24.9 dBi in a single channel, and gain exceeding 10 dBi across a 200 MHz operational bandwidth. Furthermore, the performance is validated in a communication system, yielding positive results. The proposed reflective digital coding metasurface contributes to the advancement of reconfigurable intelligent surfaces and holds promise for widespread adoption in various communication scenarios.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"118 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142263072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-15DOI: 10.1088/1361-6463/ad76ba
Mingyun Yuan, Duc V Dinh, Soumen Mandal, Oliver A Williams, Zhuohui Chen, Oliver Brandt and Paulo V Santos
Telecommunication of the next generation demands filters that can operate in the 10 GHz range with sufficient bandwidths. For surface-acoustic-wave (SAW) devices this prerequisite translates into high sound velocities and high piezoelectric couplings. Wurtzite AlN on diamond, which exploits the strong piezoelectricity of AlN with the very high SAW velocity of diamond, has been considered a promising platform. A significant boost (up to a factor of 4) of the piezoelectric response can be obtained by alloying AlN with Sc. Here, the main challenge lies in the synthesis of highly-oriented thin (Sc,Al)N films on diamond. In this work, we aim at establishing a platform for SAW devices using plasma-assisted molecular beam epitaxy for the deposition of Sc0.2Al0.8N on diamond. We investigate the structural properties related to SAW generation gearing towards applications at high frequencies. To this end, we prepare (Sc,Al)N thin films on polished polycrystalline diamond wafers and demonstrate the efficient generation of SAW modes with frequencies up to 8 GHz. Systematic studies of the dependence of the SAW velocity and electromechanical coupling coefficient on the Sc0.2Al0.8N film thickness is presented for various SAW modes. Our result demonstrates the potential of this material combination for future application that requires large bandwidth in the ultra-high frequency range.
{"title":"Generation of GHz surface acoustic waves in (Sc,Al)N thin films grown on free-standing polycrystalline diamond wafers by plasma-assisted molecular beam epitaxy","authors":"Mingyun Yuan, Duc V Dinh, Soumen Mandal, Oliver A Williams, Zhuohui Chen, Oliver Brandt and Paulo V Santos","doi":"10.1088/1361-6463/ad76ba","DOIUrl":"https://doi.org/10.1088/1361-6463/ad76ba","url":null,"abstract":"Telecommunication of the next generation demands filters that can operate in the 10 GHz range with sufficient bandwidths. For surface-acoustic-wave (SAW) devices this prerequisite translates into high sound velocities and high piezoelectric couplings. Wurtzite AlN on diamond, which exploits the strong piezoelectricity of AlN with the very high SAW velocity of diamond, has been considered a promising platform. A significant boost (up to a factor of 4) of the piezoelectric response can be obtained by alloying AlN with Sc. Here, the main challenge lies in the synthesis of highly-oriented thin (Sc,Al)N films on diamond. In this work, we aim at establishing a platform for SAW devices using plasma-assisted molecular beam epitaxy for the deposition of Sc0.2Al0.8N on diamond. We investigate the structural properties related to SAW generation gearing towards applications at high frequencies. To this end, we prepare (Sc,Al)N thin films on polished polycrystalline diamond wafers and demonstrate the efficient generation of SAW modes with frequencies up to 8 GHz. Systematic studies of the dependence of the SAW velocity and electromechanical coupling coefficient on the Sc0.2Al0.8N film thickness is presented for various SAW modes. Our result demonstrates the potential of this material combination for future application that requires large bandwidth in the ultra-high frequency range.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"48 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142263080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-15DOI: 10.1088/1361-6463/ad77df
Yadong Qiao, Fadi Wang, Wei Guo, Yuhang Wang and Fengping Wang
The utilization of two-dimensional van der waals heterostructures in optoelectronic synapses allows for the integration of information processing and memory, thereby providing novel operating platforms for simulating the perceptual visual systems and developing the neuromorphic computing systems due to its contactless, highly efficient and parallel computing. Herein, we have constructed a straightforward MoS2/WS2 heterostructure optoelectronic synapse and examined its capacity to imitate synaptic behaviors under optical stimulus. The MoS2/WS2 device demonstrated several synaptic functions, such as the excitatory postsynaptic current, short-term plasticity, long-term plasticity, pairs-pulse facilitation and ‘learning-experience’ behavior. Moreover, the MoS2/WS2 synaptic device can achieve a wide range of photo response wavelengths, spanning from UV to visible light, as well as the conversion from short-term plasticity to long-term plasticity. Furthermore, light-induced charge transfer due to adsorption and desorption of oxygen molecules in MoS2/WS2 heterostructure can be used to explain its working mechanism. Additionally, the synaptic plasticity of MoS2/WS2 device can be controlled by adjusting the duration, power and number of the optical pulses, which renders the MoS2/WS2-based optoelectronic synaptic device extremely favorable for implementation in the perceptual visual system.
{"title":"Multi-wavelength optoelectronic synapse based on MoS2/WS2 van der waals heterostructures","authors":"Yadong Qiao, Fadi Wang, Wei Guo, Yuhang Wang and Fengping Wang","doi":"10.1088/1361-6463/ad77df","DOIUrl":"https://doi.org/10.1088/1361-6463/ad77df","url":null,"abstract":"The utilization of two-dimensional van der waals heterostructures in optoelectronic synapses allows for the integration of information processing and memory, thereby providing novel operating platforms for simulating the perceptual visual systems and developing the neuromorphic computing systems due to its contactless, highly efficient and parallel computing. Herein, we have constructed a straightforward MoS2/WS2 heterostructure optoelectronic synapse and examined its capacity to imitate synaptic behaviors under optical stimulus. The MoS2/WS2 device demonstrated several synaptic functions, such as the excitatory postsynaptic current, short-term plasticity, long-term plasticity, pairs-pulse facilitation and ‘learning-experience’ behavior. Moreover, the MoS2/WS2 synaptic device can achieve a wide range of photo response wavelengths, spanning from UV to visible light, as well as the conversion from short-term plasticity to long-term plasticity. Furthermore, light-induced charge transfer due to adsorption and desorption of oxygen molecules in MoS2/WS2 heterostructure can be used to explain its working mechanism. Additionally, the synaptic plasticity of MoS2/WS2 device can be controlled by adjusting the duration, power and number of the optical pulses, which renders the MoS2/WS2-based optoelectronic synaptic device extremely favorable for implementation in the perceptual visual system.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"54 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142263078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-12DOI: 10.1088/1361-6463/ad7154
Sourav Mandal and Tapan Kumar Nath
Most of the ferromagnetic shape memory (FSM) Heusler alloys, which are primarily studied in bulk form in the literature, exhibit p-d type hybridization. This study conducts a thorough multidirectional investigation of a strongly d-d hybridized quinary melt-spun annealed ribbon having the composition Ni35Mn34.5Co14Fe1Ti15.5 (NMCFT-1). This off-stoichiometric, polycrystalline FSM, fabricated using the melt-spin technique, exhibits a highly textured microstructure, double magnetic transitions and super-mechanical features mitigating brittleness. It crystallizes in a perfectly B2-type disorder austenite (Pm-3m, space group number 221) phase at room temperature. It has been hypothesized that geometric frustration is the causative factor for this disorder. Curie temperature of austenite phase ( ) between paramagnetic → ferromagnetic state is found to be ∼364.57 K, whereas martensite transformation temperature from weak magnetic martensite state to ferromagnetic austenite state is ∼174.74 K. Calculated moments (effective moment, = 5.12 ; low-temperature saturation moment, (or ) = 5.08 ) yield a Rhodes–Wohlfarth ratio of ∼1, indicating the existence of the non-itinerant nature of 3d electrons, whereas the ferromagnetism and the linear or non-linear dependency of ) on T2 around indicates the presence of long-range Rudermann–Kittel–Kasuya–Yosida-type interaction. More importantly, the maximum magnetic entropy change ( ) obtained across the first-order magneto-structural transition and second-order magnetic transition are +18.2 J·kg−1K−1 at 6 T and −8.8 J·kg−1K−1 at 2 T, respectively, while a very high working temperature span (ΔTFWHM) of 28.561 K and 6.922 K are found for the same condition. The sample exhibits a significant relative cooling power of 402.98 J·kg−1 at a magnetic field of 6 T across the FOMT and 60.19 J·kg−1 at a 2 T field across the SOMT, respectively, along with excellent mechanical features such as a Vickers hardness (HV) of 411.80 HV (∼4.04 GPa). Meanwhile, Chen’s super hard model fails to predict the ribbon’s HV value, but Miao’s hard model does, indicating that the ribbon is hard but not super hard. It also paves the way for additional investigation into innovative FSMs like this.
{"title":"Non-itinerant-type ferromagnetism and the magnetocaloric response of quinary all-d-metal ribbon: Ni35Mn34.5Co14Fe1Ti15.5","authors":"Sourav Mandal and Tapan Kumar Nath","doi":"10.1088/1361-6463/ad7154","DOIUrl":"https://doi.org/10.1088/1361-6463/ad7154","url":null,"abstract":"Most of the ferromagnetic shape memory (FSM) Heusler alloys, which are primarily studied in bulk form in the literature, exhibit p-d type hybridization. This study conducts a thorough multidirectional investigation of a strongly d-d hybridized quinary melt-spun annealed ribbon having the composition Ni35Mn34.5Co14Fe1Ti15.5 (NMCFT-1). This off-stoichiometric, polycrystalline FSM, fabricated using the melt-spin technique, exhibits a highly textured microstructure, double magnetic transitions and super-mechanical features mitigating brittleness. It crystallizes in a perfectly B2-type disorder austenite (Pm-3m, space group number 221) phase at room temperature. It has been hypothesized that geometric frustration is the causative factor for this disorder. Curie temperature of austenite phase ( ) between paramagnetic → ferromagnetic state is found to be ∼364.57 K, whereas martensite transformation temperature from weak magnetic martensite state to ferromagnetic austenite state is ∼174.74 K. Calculated moments (effective moment, = 5.12 ; low-temperature saturation moment, (or ) = 5.08 ) yield a Rhodes–Wohlfarth ratio of ∼1, indicating the existence of the non-itinerant nature of 3d electrons, whereas the ferromagnetism and the linear or non-linear dependency of ) on T2 around indicates the presence of long-range Rudermann–Kittel–Kasuya–Yosida-type interaction. More importantly, the maximum magnetic entropy change ( ) obtained across the first-order magneto-structural transition and second-order magnetic transition are +18.2 J·kg−1K−1 at 6 T and −8.8 J·kg−1K−1 at 2 T, respectively, while a very high working temperature span (ΔTFWHM) of 28.561 K and 6.922 K are found for the same condition. The sample exhibits a significant relative cooling power of 402.98 J·kg−1 at a magnetic field of 6 T across the FOMT and 60.19 J·kg−1 at a 2 T field across the SOMT, respectively, along with excellent mechanical features such as a Vickers hardness (HV) of 411.80 HV (∼4.04 GPa). Meanwhile, Chen’s super hard model fails to predict the ribbon’s HV value, but Miao’s hard model does, indicating that the ribbon is hard but not super hard. It also paves the way for additional investigation into innovative FSMs like this.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"45 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142223063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-12DOI: 10.1088/1361-6463/ad75a0
Jiaxin Li, He Ding, Yongtian Wang and Jian Yang
The study of electrophysiological signals is crucial for understanding neural functions and physiological processes. Electrophysiological recordings offer direct insights into electrical activity across cellular membranes, aiding in diagnosing and treating neurological disorders. Different from the conventional recording method based on electrical signals and the genetically encoded with fluorescent proteins methods, this review explores label-free mechanisms for optically recording electrophysiological signals: electrochromic materials, surface plasmon resonance (SPR) responses, quantum dots (QDs), and semiconductor-based optoelectronic sensors. The sophistication and limitations of each technology have been discussed, providing insights into potential future directions in this field. Electrochromic materials change optical properties through redox reactions induced by voltages, offering high signal-to-noise ratios and rapid response capabilities. However, these materials have limited biocompatibility and stability. SPR technology modulates signals in response to local changes in electrical potential, achieving high sensitivity. However, challenges such as scattering noise and electro-optic effects still need to be addressed. QDs utilize their photoluminescent properties for high sensitivity and resolution, but concerns about connection efficiency and biocompatibility remain. Semiconductor optoelectronic technologies offer rapid response times, wireless functionality, and integration potential. However, improvements are needed in terms of toxicity, compatibility with biological tissues, and signal amplification and processing. These methods have advantages in neuroscience, medical diagnostics, and biological research, including rapid response, high sensitivity, and label-free monitoring. By combining different optical recording techniques, the performance of voltage imaging can be optimized. In conclusion, interdisciplinary collaboration and innovation are essential for advancing the optical recording of electrophysiological signals and developing diagnostic and therapeutic approaches.
{"title":"Advances in optical recording techniques for non-invasive monitoring of electrophysiological signals","authors":"Jiaxin Li, He Ding, Yongtian Wang and Jian Yang","doi":"10.1088/1361-6463/ad75a0","DOIUrl":"https://doi.org/10.1088/1361-6463/ad75a0","url":null,"abstract":"The study of electrophysiological signals is crucial for understanding neural functions and physiological processes. Electrophysiological recordings offer direct insights into electrical activity across cellular membranes, aiding in diagnosing and treating neurological disorders. Different from the conventional recording method based on electrical signals and the genetically encoded with fluorescent proteins methods, this review explores label-free mechanisms for optically recording electrophysiological signals: electrochromic materials, surface plasmon resonance (SPR) responses, quantum dots (QDs), and semiconductor-based optoelectronic sensors. The sophistication and limitations of each technology have been discussed, providing insights into potential future directions in this field. Electrochromic materials change optical properties through redox reactions induced by voltages, offering high signal-to-noise ratios and rapid response capabilities. However, these materials have limited biocompatibility and stability. SPR technology modulates signals in response to local changes in electrical potential, achieving high sensitivity. However, challenges such as scattering noise and electro-optic effects still need to be addressed. QDs utilize their photoluminescent properties for high sensitivity and resolution, but concerns about connection efficiency and biocompatibility remain. Semiconductor optoelectronic technologies offer rapid response times, wireless functionality, and integration potential. However, improvements are needed in terms of toxicity, compatibility with biological tissues, and signal amplification and processing. These methods have advantages in neuroscience, medical diagnostics, and biological research, including rapid response, high sensitivity, and label-free monitoring. By combining different optical recording techniques, the performance of voltage imaging can be optimized. In conclusion, interdisciplinary collaboration and innovation are essential for advancing the optical recording of electrophysiological signals and developing diagnostic and therapeutic approaches.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"5 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142223121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1088/1361-6463/ad76be
Yajing Wang, Chao Wang, Xinxin Wang, Shengqiang Cui, Min Hao, Chunhui Wang, Xudong Huang and Gui Yang
Polycrystalline SnSe, renowned for its environmental sustainability, holds promise as a significant thermoelectric material, attracting considerable research attention. This study focuses on the thermoelectric properties of p-type polycrystalline SnSe doped with silver copper telluride (AgCuTe). Our experimental results conclusively show that the decomposition products of AgCuTe not only fill Sn vacancies but also act as acceptors, thereby introducing additional hole carriers. This leads to a notable improvement in both carrier mobility and concentration. Importantly, the thermal conductivity of the doped samples remains largely unchanged, as the lattice flattening strategy significantly boosts electrical performance without affecting lattice thermal conductivity. Ultimately, the doped sample Sn0.97Se-0.5%AgCuTe resulted in a power factor of 6.2 mW mK−1 and a peak ZT value of 1.4 at 798 K, representing a 109% improvement in ZT value. All samples exhibits superior stability and reproducibility, emphasizing its reliability for practical applications.
多晶硒化锡以其环境可持续性而闻名，有望成为一种重要的热电材料，吸引了大量研究人员的关注。本研究的重点是掺杂了碲化银（AgCuTe）的 p 型多晶 SnSe 的热电特性。我们的实验结果确凿地表明，AgCuTe 的分解产物不仅填补了 Sn 的空位，而且还充当了受体，从而引入了额外的空穴载流子。这显著提高了载流子的迁移率和浓度。重要的是，掺杂样品的热导率基本保持不变，因为晶格扁平化策略在不影响晶格热导率的情况下显著提高了电性能。最终，掺杂样品 Sn0.97Se-0.5%AgCuTe 的功率因数达到 6.2 mW mK-1，798 K 时的 ZT 峰值为 1.4，ZT 值提高了 109%。所有样品都表现出卓越的稳定性和可重复性，突出了其在实际应用中的可靠性。
{"title":"Enhanced thermoelectric performance of AgCuTe-doped polycrystalline SnSe by lattice plainification","authors":"Yajing Wang, Chao Wang, Xinxin Wang, Shengqiang Cui, Min Hao, Chunhui Wang, Xudong Huang and Gui Yang","doi":"10.1088/1361-6463/ad76be","DOIUrl":"https://doi.org/10.1088/1361-6463/ad76be","url":null,"abstract":"Polycrystalline SnSe, renowned for its environmental sustainability, holds promise as a significant thermoelectric material, attracting considerable research attention. This study focuses on the thermoelectric properties of p-type polycrystalline SnSe doped with silver copper telluride (AgCuTe). Our experimental results conclusively show that the decomposition products of AgCuTe not only fill Sn vacancies but also act as acceptors, thereby introducing additional hole carriers. This leads to a notable improvement in both carrier mobility and concentration. Importantly, the thermal conductivity of the doped samples remains largely unchanged, as the lattice flattening strategy significantly boosts electrical performance without affecting lattice thermal conductivity. Ultimately, the doped sample Sn0.97Se-0.5%AgCuTe resulted in a power factor of 6.2 mW mK−1 and a peak ZT value of 1.4 at 798 K, representing a 109% improvement in ZT value. All samples exhibits superior stability and reproducibility, emphasizing its reliability for practical applications.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"27 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142223161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this article, we report the hydrogen storage capacity of zirconium (Zr) decorated C24 fullerene using state-of-the-art density functional theory simulations. Our study shows that zirconium, like most other transition metals, tends to bind strongly on the C–C bridge of C24 fullerene with a maximum binding energy of −3.64 eV. Each Zr atom decorated over C24 fullerene can adsorb a maximum of 7H2 molecules with an average adsorption energy of −0.51 eV/H2, leading to a gravimetric density of 7.9 wt%, which is higher than the prescribed target of 6.5 wt% set by United States-Department of Energy. There is a charge transfer from Zr to C atoms in C24 fullerene, which is the primary cause of the binding of Zr with C24 fullerene. H2 molecules are adsorbed over Zr sorption sites via Kubas-type interactions, which include charge donation from the filled s orbitals of hydrogen to the vacant 4d orbital of Zr and subsequent back charge donation to unfilled s* orbital of hydrogen from the filled 4d orbital of Zr. The structural stability of the Zr + C24 system at a high temperature of 500 K is verified using ab-initio molecular dynamics calculations. The high diffusion energy barrier of Zr (2.33 eV) inhibits clustering between the Zr atoms decorated on the C24 fullerene and ensures the system’s practical feasibility as a high-capacity H2 adsorbing system. Therefore, our computational studies confirm that Zr decorated C24 fullerene is stable and can be regarded as a potential candidate for H2 storage systems with optimum adsorption energy range.
{"title":"Zr doped C24 fullerene as efficient hydrogen storage material: insights from DFT simulations","authors":"Ajit Kundu, Ankita Jaiswal, Pranoy Ray, Sridhar Sahu and Brahmananda Chakraborty","doi":"10.1088/1361-6463/ad75a1","DOIUrl":"https://doi.org/10.1088/1361-6463/ad75a1","url":null,"abstract":"In this article, we report the hydrogen storage capacity of zirconium (Zr) decorated C24 fullerene using state-of-the-art density functional theory simulations. Our study shows that zirconium, like most other transition metals, tends to bind strongly on the C–C bridge of C24 fullerene with a maximum binding energy of −3.64 eV. Each Zr atom decorated over C24 fullerene can adsorb a maximum of 7H2 molecules with an average adsorption energy of −0.51 eV/H2, leading to a gravimetric density of 7.9 wt%, which is higher than the prescribed target of 6.5 wt% set by United States-Department of Energy. There is a charge transfer from Zr to C atoms in C24 fullerene, which is the primary cause of the binding of Zr with C24 fullerene. H2 molecules are adsorbed over Zr sorption sites via Kubas-type interactions, which include charge donation from the filled s orbitals of hydrogen to the vacant 4d orbital of Zr and subsequent back charge donation to unfilled s* orbital of hydrogen from the filled 4d orbital of Zr. The structural stability of the Zr + C24 system at a high temperature of 500 K is verified using ab-initio molecular dynamics calculations. The high diffusion energy barrier of Zr (2.33 eV) inhibits clustering between the Zr atoms decorated on the C24 fullerene and ensures the system’s practical feasibility as a high-capacity H2 adsorbing system. Therefore, our computational studies confirm that Zr decorated C24 fullerene is stable and can be regarded as a potential candidate for H2 storage systems with optimum adsorption energy range.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"4 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142223155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1088/1361-6463/ad76b8
Xiaojun Huang, Ke Li, Wei Hou, Yanpei Wang and Yutao Ma
This paper investigates a highly selective frequency selective rasorber (FSR) utilizing interdigitated resonators, characterized by a passband exhibiting low insertion loss (IL) and the introduction of a second-order passband response in the lossless layer enhances selectivity on both sides of the passband. The lossy unit is implemented by inserting interdigitated resonators on an octagonal ring loaded with lumped resistors, while the lossless layer is constructed with a five-layer structure. Simulation results demonstrate a low IL value of 0.78 dB at 3.5 GHz. At vertical incidence, the S21>−3 dB bandwidth ranges from 3.41 to 3.67 GHz, and the S11<−10 dB range spans from 2.2 to 8.2 GHz, obtaining two absorption bands on either side of the passband, with absorption rates exceeding 80%. The operating frequency bands are 1.95–3.27 GHz and 3.8–8.4 GHz. The designed FSR exhibits polarization insensitive. To validate simulation results, a prototype FSR was fabricated and tested, with experimental data aligning with simulation results.
{"title":"Interdigitated resonator based frequency selective rasorber with high selectivity","authors":"Xiaojun Huang, Ke Li, Wei Hou, Yanpei Wang and Yutao Ma","doi":"10.1088/1361-6463/ad76b8","DOIUrl":"https://doi.org/10.1088/1361-6463/ad76b8","url":null,"abstract":"This paper investigates a highly selective frequency selective rasorber (FSR) utilizing interdigitated resonators, characterized by a passband exhibiting low insertion loss (IL) and the introduction of a second-order passband response in the lossless layer enhances selectivity on both sides of the passband. The lossy unit is implemented by inserting interdigitated resonators on an octagonal ring loaded with lumped resistors, while the lossless layer is constructed with a five-layer structure. Simulation results demonstrate a low IL value of 0.78 dB at 3.5 GHz. At vertical incidence, the S21>−3 dB bandwidth ranges from 3.41 to 3.67 GHz, and the S11<−10 dB range spans from 2.2 to 8.2 GHz, obtaining two absorption bands on either side of the passband, with absorption rates exceeding 80%. The operating frequency bands are 1.95–3.27 GHz and 3.8–8.4 GHz. The designed FSR exhibits polarization insensitive. To validate simulation results, a prototype FSR was fabricated and tested, with experimental data aligning with simulation results.","PeriodicalId":16789,"journal":{"name":"Journal of Physics D: Applied Physics","volume":"59 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142223152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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