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Comparison of Methods for the Preparation of Fatty Acid Methyl Esters for the Analysis of Omega-3 Rich Oils by Gas Chromatography 气相色谱法分析富欧米茄-3油中脂肪酸甲酯制备方法的比较
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-28 DOI: 10.1002/aocs.12974
Tharani T. Dissanayake, Shona Crawford-Clark, Benjamin J. Bowen, Luke C. Henderson, Colin J. Barrow, Jacqui L. Adcock

Fatty acid analysis is required in a wide range of industries, and conversion to fatty acid methyl esters followed by gas chromatography is by far the most common method of analysis. However, despite widespread use, there is no consensus on which derivatization method should be used or how the methods compare. In this work, five methods for the preparation of fatty acid methyl esters were compared for the analysis of three omega-3 rich oils (marine, krill, and flaxseed oils). Overall, we found that all methods gave similar results for percentage composition of fatty acids, but some variation existed when comparing absolute quantitation of fatty acids. We also found that the derivatization efficacy of each method varied depending on lipid class, with catalyst type having a significant effect. Two methods employing: (i) methanolic hydrogen chloride and (ii) methanolic sodium hydroxide followed by a boron trihalide reagent (BCl3 or BF3) had derivatizing efficacies (by lipid class) that were significantly higher than for the other methods.

脂肪酸分析需要在广泛的行业,转化为脂肪酸甲酯随后气相色谱是迄今为止最常见的分析方法。然而,尽管广泛使用,但对于应该使用哪种衍生化方法或如何比较这些方法尚无共识。在这项工作中,比较了五种制备脂肪酸甲酯的方法,用于分析三种富含omega-3的油(海洋油、磷虾油和亚麻籽油)。总的来说,我们发现所有方法对脂肪酸组成百分比的结果相似,但在比较脂肪酸的绝对定量时存在一些差异。我们还发现,每种方法的衍生化效果因脂类而异,催化剂类型有显著影响。采用(i)甲醇氯化氢和(ii)甲醇氢氧化钠和三卤化硼试剂(BCl3或BF3)的两种方法的衍生化效率(按脂类划分)明显高于其他方法。
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引用次数: 0
Toward Rapid Analysis of Unsaturated Fatty Acid Oxidation in Edible Oils via Square-Wave Voltammetry 方波伏安法快速分析食用油中不饱和脂肪酸氧化的研究
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-24 DOI: 10.1002/aocs.12973
Matthew M. Thelen, Sebastian A. Flores, Jack A. Kelley, Brianna R. Swank, Jill K. Winkler-Moser, Matthew J. Fhaner

Square-wave voltammetry (SWV) was investigated as a potential analytical tool for quantitation of unsaturated fatty acid oxidation in edible oils exposed to high heat. A traditional linear regression calibration curve and a novel single-point calibration method were used to quantitate linoleic acid in oxidized oil samples. These methods were compared with a standard method for fatty acid analysis via gas chromatography flame ionization detection (GC-FID). Both GC-FID and SWV methods were able to detect a decrease in linoleic acid concentration for heated oil samples. SWV methods routinely calculated higher linoleic acid concentrations compared with GC-FID analysis. A novel finding is that SWV oxidation peak intensities, which are associated with electroactive compounds, decrease in intensity over time for peaks below 1.0 V and increase for peaks above this voltage. These findings represent a step forward in electrochemical characterization of heated oils in addition to further advancing opportunities for electrochemical oil quality screening.

研究了方波伏安法(SWV)作为测定食用油中不饱和脂肪酸氧化的潜在分析工具。采用传统的线性回归校准曲线和新颖的单点校准方法对氧化油样品中的亚油酸进行定量分析。将这些方法与气相色谱火焰离子化检测(GC-FID)脂肪酸分析的标准方法进行了比较。GC-FID和SWV方法均能检测到加热后的油样中亚油酸浓度的降低。与GC-FID分析相比,SWV方法通常计算出更高的亚油酸浓度。一项新的发现是,与电活性化合物相关的SWV氧化峰强度随着时间的推移,低于1.0 V的峰值强度会降低,高于1.0 V的峰值强度会增加。这些发现代表了加热油的电化学表征向前迈进了一步,并进一步推进了电化学油质量筛选的机会。
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引用次数: 0
Structured Lipids: Synthesis, Genetic Engineering, and Applications 结构脂质:合成、基因工程和应用
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-20 DOI: 10.1002/aocs.12970
Chandu S. Madankar, Avishkar S. Bhagat, Elham K. Nasser, Ammar B. Altemimi, Francesco Cacciola, Nasser Mahna

Lipids are essential to the human body, but some can be harmful. As a result, current research focuses on structured lipids (SLs), which are engineered to have specific fatty acid arrangements. These structural modifications can enhance both nutritional and physical properties. Fatty acids on the glycerol backbone can be rearranged through chemical, enzymatic, or genetic methods. Numerous studies have identified and characterized genes involved in SL biosynthesis. Among SLs, the medium-long-medium type is, particularly, valuable for its nutritional and therapeutic benefits. Considering the gap in comprehensive comparisons between chemical, enzymatic, and genetic-based synthesis methods, this review aims to highlight the methods used for SLs production. As health awareness grows, SLs are expected to play an increasingly important role in promoting human health, notably as nutraceuticals and functional foods, in clinical nutrition and therapeutics, in weight management, in infant formula, and as pharmaceutical carriers.

脂质对人体至关重要,但有些可能是有害的。因此,目前的研究集中在结构化脂质(SLs)上,它被设计成具有特定的脂肪酸排列。这些结构上的改变可以提高营养和物理特性。甘油主链上的脂肪酸可以通过化学、酶或遗传方法重新排列。许多研究已经鉴定和表征了参与SL生物合成的基因。在SLs中,中-长-中类型因其营养和治疗益处而特别有价值。考虑到化学、酶和遗传合成方法在综合比较方面的差距,本综述旨在重点介绍用于SLs生产的方法。随着健康意识的增强,预计特殊食品将在促进人类健康方面发挥越来越重要的作用,特别是作为营养品和功能性食品、临床营养和治疗、体重管理、婴儿配方奶粉和药物载体。
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引用次数: 0
Impact of Food Service Cooking on the Yield and Fat Content of Commercial Ground Meats and a Plant-Based Meat Substitute 食品服务烹饪对商业碎肉和植物性肉类替代品的产量和脂肪含量的影响
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-19 DOI: 10.1002/aocs.12969
Maria Victoria Acevedo-Estupinan, Ipek Bayram, Jean Alamed, Carolina Cantele, Vinatee Patil, Peyman Ebrahimi, Alexander Ong, Ken Toong, Kyle A. McKillop, Naomi K. Fukagawa, Eric A. Decker

Collecting data on cooking yields of different food products is critical for accurately calculating food composition and nutritional changes after food processing. Ground meat is a good example of a food product that will undergo significant yield changes during cooking. This manuscript investigates yield changes as well as changes in fat and moisture content of ground beef, pork, chicken, turkey, and a plant-based meat product cooked in a food service facility. The findings demonstrated a strong relationship between the initial fat content of the meat and yield, with higher fat content resulting in decreased yield. It was also observed that in meats with lower fat content, moisture loss had a bigger impact on yield than fat loss. The findings of this study will help in the calculation of nutritional content of cooked meat and may help in the use of future technologies such as artificial intelligence to estimate the nutritional content of meats.

收集不同食品的蒸煮产量数据对于准确计算食品成分和食品加工后的营养变化至关重要。绞碎的肉就是一个很好的例子,在烹饪过程中会发生显著的产量变化。这份手稿调查产量的变化,以及在脂肪和水分含量的变化碎牛肉,猪肉,鸡肉,火鸡,和植物性肉类产品在食品服务设施煮熟。研究结果表明,肉的初始脂肪含量与产量之间存在很强的关系,脂肪含量越高,产量越低。还观察到,在脂肪含量较低的肉类中,水分损失对产量的影响大于脂肪损失。这项研究的结果将有助于计算熟肉的营养成分,并可能有助于使用人工智能等未来技术来估计肉类的营养成分。
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引用次数: 0
Correction to “Evaluating the Oxidative Stability of Triacylglycerols in Rapeseed (Brassica napus) Oleosomes” 对“评价甘油三酯在油菜(芸苔)油质体中的氧化稳定性”的修正
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-19 DOI: 10.1002/aocs.12962

Plankensteiner L, Nikiforidis CV, Vincken J-P, Hennebelle M. Evaluating the oxidative stability of triacylglycerols in rapeseed (Brassica napus) oleosomes. J Am Oil Chem Soc. 2025; 102(2): 435–449. https://doi.org/10.1002/aocs.12902.

In the original publication, an additional author was inadvertently omitted. The following author should be added to the author list:

Khoa A. Nguyen - Laboratory of Food Chemistry, Wageningen University, Wageningen, The Netherlands

In the Authors’ Contributions section, the following sentence should be added before “Jean-Paul Vincken reviewed and edited the manuscript”:

Khoa A. Nguyen developed the empirical model and contributed to the interpretation of the results.

In the Acknowledgements section, the sentence “Dr. Khoa Nguyen for helping with the empirical modeling and” should be removed.

In the section titled “Empirical modeling of experimental data” on page 6, the phrase “as reported previously (Merkx et al., 2021):” should be deleted from the manuscript. Consequently, this reference should also be removed from the reference list.

The online version of this article has been corrected accordingly.

We apologize for this error.

李建军,李建军,李建军,等。甘油三酯在甘油三酯中氧化稳定性的研究。石油学报(自然科学版);102(2): 435 - 449。https://doi.org/10.1002/aocs.12902.In在原始出版物中,无意中遗漏了另一位作者。作者列表中应添加以下作者:Khoa A. Nguyen - Laboratory of Food Chemistry, Wageningen University, Wageningen, The Netherlands在作者贡献部分,在“Jean-Paul Vincken reviews and edited The manuscript”之前应添加以下句子:Khoa A. Nguyen开发了实证模型并对结果的解释做出了贡献。在致谢部分,应该删除“Dr. Khoa Nguyen帮助进行实证建模和”这句话。在第6页题为“实验数据的实证建模”部分,应删除“as reported previous (Merkx et al., 2021):”这一短语。因此,这个引用也应该从引用列表中删除。本文的在线版本已进行了相应的更正。我们为这个错误道歉。
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引用次数: 0
Oxidative and Physical Stability of Vegetable Oil Oleogels With a Binary Mixture of Beeswax and Candelilla Wax 蜂蜡和小蜡烛蜡二元混合物植物油油凝胶的氧化稳定性和物理稳定性
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-18 DOI: 10.1002/aocs.12965
Hong-Sik Hwang, Sanghoon Kim

Oxidative and physical stability of 3% and 7% beeswax-candelilla wax (BW-CDW, 1:1) oleogels prepared with flaxseed (FSO), soybean (SBO), and olive oils (OO) were evaluated during storage at 25°C and 4°C. Peroxide values (PV) and conjugated diene values (CDV) of BW-CDW oleogels were lower than bulk oils after storage at 4°C for 180 days, and those of 7% wax oleogels were lower than 3% wax oleogels, indicating the protection effect by oleogelation. In contrast, these oleogels had lower oxidative stability than bulk oils at 25°C, indicating the prooxidant activity of waxes. PV of 7% BW-CDW SBO oleogel increased slower than commercial margarine fat (CMF) at both storage temperatures, while its CDV increased faster at 25°C. Gel strength (firmness and cohesiveness) of oleogels decreased at both temperatures. Gel strength of CMF decreased faster than oleogels at 25°C, while it was steady at 4°C. Gel strength of OO oleogels dramatically decreased during storage at 4°C, which was likely due to large oil crystals formed that broke the wax crystal network at 4°C. Solid fat content and melting enthalpy of oleogels increased, indicating that new crystals formed during storage, which, however, did not provide higher gel strength. New spherulite crystals appeared during storage at 4°C, which might be the reason for decreased gel strength. Overall results indicated that BW-CDW oleogels had the oxidative and physical stability comparable to CMF, except for OO oleogels stored at 4°C.

用亚麻籽(FSO)、大豆油(SBO)和橄榄油(OO)制备3%和7%蜂蜡-小烛子蜡(BW-CDW, 1:1)油凝胶,在25°C和4°C条件下贮存,评价其氧化和物理稳定性。4℃保存180 d后,BW-CDW油凝胶的过氧化值(PV)和共轭二烯值(CDV)均低于散装油,7%蜡油凝胶的过氧化值(PV)和共轭二烯值(CDV)均低于3%蜡油凝胶,表明油凝胶的保护作用。相比之下,这些油凝胶在25°C时的氧化稳定性低于散装油,表明蜡的促氧化活性。在两种储存温度下,7% BW-CDW SBO油凝胶的PV增长都比商用人造黄油(CMF)慢,而其CDV在25°C时增长更快。在两种温度下,油凝胶的凝胶强度(牢固性和黏结性)都有所下降。在25°C时,CMF的凝胶强度比油凝胶下降得更快,而在4°C时则保持稳定。在4℃下,OO油凝胶的凝胶强度急剧下降,这可能是由于在4℃下形成了大的油晶体,破坏了蜡晶网络。油凝胶的固体脂肪含量和熔融焓增加,表明在储存过程中形成了新的晶体,但没有提供更高的凝胶强度。在4℃下贮藏时,出现了新的球晶,这可能是凝胶强度下降的原因。总体结果表明,BW-CDW油凝胶的氧化稳定性和物理稳定性与CMF相当,但在4°C下储存的OO油凝胶除外。
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引用次数: 0
Biodegradable Sodium Alginate Films Incorporated With Microcapsules of Amazonian Buriti Fruit Oil (Mauritia flexuosa L.) 含有亚马逊布里提果油微胶囊的可生物降解海藻酸钠薄膜
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-17 DOI: 10.1002/aocs.12967
Cecília Roratto Köhn, Polliana D’Angelo Rios, Simone Hickmann Flôres, Alessandro de Oliveira Rios

Pollution caused by plastic polymers is a growing concern as it compromises biodiversity and human health. As a sustainable solution, developing biodegradable films, such as sodium alginate, is promising due to its low vapor permeability, flexibility, gloss, and cost-effectiveness. Incorporating bioactive compounds, such as Buriti oil ( Mauritia flexuosa L.), enhances the antioxidant properties of the films, improving food safety and preservation. Encapsulation is an effective technique to protect these compounds. This study aimed to develop biodegradable sodium alginate films with the addition of microcapsules of Buriti oil (MBO) using the casting technique. The morphology of the films, as well as their physical, thermal, and barrier properties, were evaluated, along with the preservation of sunflower oil during 12 days of ṇcontrolled storage at 30°C, with analyses of peroxide, dienes, and conjugated trienes indices. The addition of microcapsules of Buriti oil did not significantly alter the structure of the films, but higher concentrations of microcapsules made the films weaker and more elastic. Lower concentrations of Buriti oil microcapsules effectively reduced water vapor permeability. The developed films were effective in preserving sunflower oil, showing lower and more stable levels of dienes and conjugated trienes peroxide indices compared to the commercial simulator and open control. Sodium alginate films with microcapsules of Buriti oil represent a potentially ecologically correct alternative for developing biodegradable packaging.

塑料聚合物造成的污染日益受到关注,因为它危及生物多样性和人类健康。作为一种可持续的解决方案,开发生物可降解薄膜,如海藻酸钠,由于其低透气性、柔韧性、光泽度和成本效益,是有前途的。加入生物活性化合物,如Buriti油(Mauritia flexuosa L.),增强了薄膜的抗氧化性能,提高了食品安全性和保存性。包封是一种有效的保护这些化合物的技术。本研究旨在采用浇铸技术制备海藻酸钠生物可降解膜,并添加布里提油微胶囊(MBO)。研究人员对膜的形态、物理、热学和屏障性能进行了评估,同时对葵花籽油在ṇcontrolled 30°C下保存12天,并对过氧化氢、二烯和共轭三烯指数进行了分析。Buriti油微胶囊的加入对膜的结构没有显著影响,但微胶囊浓度越高,膜的弹性越弱。较低浓度的Buriti油微胶囊可有效降低水蒸气渗透率。该显影膜对葵花籽油的保存效果较好,与商业模拟器和开放对照相比,其双烯和共轭三烯的过氧化指数更低且更稳定。海藻酸钠薄膜与Buriti油的微胶囊代表了开发可生物降解包装的潜在生态正确的替代方案。
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引用次数: 0
Fish Oil Recovery From Gilthead Sea Bream (Sparus aurata L.) Waste Using Ultrasound-Assisted Enzymatic Extraction: Process Optimization and Oil Characterization 从金头鲷(Sparus aurata L.)中提取鱼油利用超声波辅助酶法提取废物:工艺优化和油脂表征
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-17 DOI: 10.1002/aocs.12966
Hasene Keskin Çavdar, Hakkı Bilgin, Sibel Fadıloğlu

This study investigates the optimization of fish oil extraction from gilthead sea bream (Sparus aurata L.) waste using ultrasound-assisted enzymatic extraction (UAEE), which is a sustainable and effective technique for extraction. Addressing the problems of fish processing waste, which accounts for 20%–80% of the total fish mass, ultrasonic waves and enzymatic hydrolysis in UAEE improve extraction efficiency while minimizing environmental effects. The fish oil extraction process was optimized by following a response surface methodology. The optimum conditions for the highest yield (31.0%, g/g) included an ultrasound time of 10.3 min, an enzyme concentration of 0.60% (g/g), and a hydrolysis time of 5 h, obtaining 72.0% extraction efficiency compared to classic Soxhlet extraction. The oil quality and stability were assessed by analyzing its physicochemical properties, fatty acid analysis with GC-FID, and analyzing the oxidation induction temperature using DSC. The extracted oil was characterized by its favorable fatty acid profile, including its high levels of docosahexaenoic (22:6n-3, 4.40%, g/g) and eicosapentaenoic acid (20:5n-3, 2.20%, g/g). The saponification and iodine values of the extracted oils fall within an acceptable range reported for fish oils. Despite a slightly lower oxidation stability compared to Soxhlet extraction, UAEE demonstrates significant potential for producing high-quality fish oil while using less energy and no hazardous solvents. This study promotes sustainable practices by using underutilized fish waste and reduces dependence on dangerous chemicals, which is in line with the worldwide effort to adopt environmentally friendly technologies.

研究了超声辅助酶提法(UAEE)对鳙鱼鱼油的提取工艺优化,该工艺是一种可持续、高效的提取工艺。UAEE的鱼加工废弃物占鱼总质量的20%-80%,通过超声波和酶解技术提高了提取效率,同时减少了对环境的影响。采用响应面法对鱼油提取工艺进行优化。超声时间为10.3 min,酶浓度为0.60% (g/g),水解时间为5 h,提取率为72.0% (g/g)。通过理化性质分析、GC-FID脂肪酸分析和DSC氧化诱导温度分析,评价了油的品质和稳定性。提取的油具有良好的脂肪酸谱,包括高含量的二十二碳六烯酸(22:6n-3, 4.40%, g/g)和二十碳五烯酸(20:5n-3, 2.20%, g/g)。萃取油的皂化和碘值在鱼油可接受范围内。尽管与索氏萃取相比,UAEE的氧化稳定性略低,但在使用更少的能源和无有害溶剂的情况下,UAEE显示出生产高质量鱼油的巨大潜力。这项研究通过利用未充分利用的鱼类废物和减少对危险化学品的依赖来促进可持续做法,这符合世界范围内采用环境友好技术的努力。
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引用次数: 0
Formulation Optimization on Semi-Solid NLC Dispersions Containing Antioxidant Herbal Oils: A Novel Approach for Cosmeceuticals 含抗氧化草药油的半固态NLC分散体配方优化:药妆新途径
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-14 DOI: 10.1002/aocs.12964
Ulya Badilli, Kerem Cakir, Gizem Yegen, Ozge Inal, Buket Aksu

Skin aging prevention is increasingly important in cosmetics. Topical application of antioxidants protects the skin against reactive oxygen species (ROS) generated as a result of continuous exposure to UV radiation. Herbal oils offer significant anti-aging potential due to their antioxidant content. Lipid nanoparticles (i.e., SLN and NLC) have been comprehensively evaluated for dermal drug delivery and cosmetic applications since they offer enhanced skin hydration and improved percutaneous penetration. The latest approach for dermal application is the usage of semi-solid lipid nanoparticle dispersions, which offer unique advantages. Semi-solid SLN/NLC dispersions have a suitable consistency for dermal application and can be prepared by a one-step production method without additional excipients. Furthermore, they preserve the colloidal particle size in spite of their semi-solid consistency. Development of novel cosmeceutical semi-solid NLC dispersions containing valuable herbal oils such as pomegranate seed, argan, grape seed, and coconut oils was aimed at in this study. Formulation optimization was performed using a modeling program based on response surface methodology (RSM). Optimum semi-solid NLC formulation (Opt-NLC) was prepared using Compritol 888ATO and argan oil at amounts of 0.8403 and 0.5457 g, respectively. The particle size of the Opt-NLC formulation was found to be 188.6 ± 3.58 nm, which falls within the targeted size range. PDI was also reduced and a more uniform particle size was obtained by optimization. Rheological and mechanical characterization results revealed that Opt-NLC has suitable properties in terms of product performance and consumer compliance. As a result, formulation optimization of semi-solid NLC dispersions containing antioxidant herbal oils was successfully performed using RSM methodology.

预防皮肤老化在化妆品中越来越重要。局部应用抗氧化剂可以保护皮肤免受因持续暴露于紫外线辐射而产生的活性氧(ROS)的侵害。草药油具有显著的抗衰老潜力,因为它们含有抗氧化剂。脂质纳米颗粒(即,SLN和NLC)已被全面评估为真皮药物输送和美容应用,因为它们提供增强皮肤水合作用和改善经皮渗透。皮肤应用的最新方法是使用半固体脂质纳米颗粒分散体,它提供了独特的优势。半固体SLN/NLC分散体具有适合皮肤应用的一致性,并且可以通过一步生产方法制备,无需额外的辅料。此外,尽管它们具有半固体的一致性,但它们仍保持胶体粒度。本研究旨在开发含有石榴籽、摩洛哥坚果油、葡萄籽和椰子油等珍贵草药油的新型药妆半固体NLC分散体。采用基于响应面法(RSM)的建模程序进行配方优化。以Compritol 888ATO和摩洛哥坚果油为原料,用量分别为0.8403 g和0.5457 g,制备最佳半固体NLC (Opt-NLC)。Opt-NLC配方的粒径为188.6±3.58 nm,在目标粒径范围内。优化后的PDI也降低了,得到了更均匀的粒度。流变学和力学表征结果表明,Opt-NLC在产品性能和消费者依从性方面具有合适的性能。结果表明,采用RSM方法对含抗氧化草药油的半固态NLC分散体进行了配方优化。
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引用次数: 0
Fuel Properties of High Oleic Pennycress Oil Derived Biodiesel and Its Blends With Ultra-Low Sulfur Diesel 高含油pennygrass油衍生生物柴油及其与超低硫柴油的混合燃料特性
IF 2.4 4区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2025-06-13 DOI: 10.1002/aocs.12968
DeMichael D. Winfield, Robert O. Dunn, M. David Marks

Field Pennycress is an emerging crop for nonedible seed oil. In the Midwestern United States, it can be employed as a cover crop between corn and soybean seasons. This makes it an attractive feedstock for producing biodiesel without interfering with commodity food crops. Classical mutagenesis has been applied to develop different varieties of pennycress with desirable properties for biodiesel. In this study, we evaluated the fuel properties of biodiesel produced from the seed oil of a new pennycress variety, high oleic pennycress (HOP). The oil was converted to fatty acid methyl esters (FAMEs) and analyzed according to the ASTM standard for biodiesel. HOP biodiesel exhibited cold flow properties superior to those of biodiesel derived from other pennycress varieties and vegetable oils, with cloud point, pour point, and cold filter plug points of −19.7°C, −21°C, and −15.7°C respectively. The oxidative stability of the biodiesel was poor, with an induction period at 110°C of 0.46 h, indicating that additives would be needed for commercial use. Kinematic viscosity at 40°C was 4.113 mm2 s−1, meeting both the ASTM and EN biodiesel standard. The biodiesel had an average wear scar of 188 μm, demonstrating good lubrication properties. The efficacy of HOP biodiesel as an additive for ultra-low sulfur diesel was also evaluated. Loadings of 2% and 5% biodiesel were effective in terms of improving lubricity while maintaining sufficient oxidative stability. This work demonstrates the potential of HOP as a valuable wintertime oil seed crop for producing biodiesel in the Midwestern United States.

荠菜是一种新兴的非食用籽油作物。在美国中西部,它可以作为玉米和大豆季节之间的覆盖作物。这使得它成为生产生物柴油的有吸引力的原料,而不会干扰商品粮食作物。经典诱变技术已被应用于开发具有理想生物柴油性能的pennyress品种。在这项研究中,我们评估了由一种新的pennycres品种,高油pennycres (HOP)的种子油生产生物柴油的燃料性能。将油转化为脂肪酸甲酯(FAMEs),并按照ASTM生物柴油标准进行分析。HOP生物柴油的冷流动性能优于其他pennycrea品种和植物油衍生的生物柴油,浊点、倾点和冷过滤器堵塞点分别为- 19.7℃、- 21℃和- 15.7℃。该生物柴油的氧化稳定性较差,在110℃下的诱导期为0.46 h,需要添加添加剂才能实现商业化。40°C时的运动粘度为4.113 mm2 s−1,符合ASTM和EN生物柴油标准。生物柴油的平均磨损疤痕为188 μm,具有良好的润滑性能。并对HOP生物柴油作为超低硫柴油添加剂的效果进行了评价。添加2%和5%的生物柴油在改善润滑性的同时保持足够的氧化稳定性。这项工作证明了啤酒花作为一种有价值的冬季油籽作物在美国中西部生产生物柴油的潜力。
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Journal of the American Oil Chemists Society
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