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Production of sodium-based zeolites and a potassium-containing leach liquor by alkaline leaching of South African coal fines ash 南非煤粉灰碱浸法制备钠基沸石及含钾浸出液
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-05-03 DOI: 10.17159/2411-9717/1167/2023
A. Collins, C. Strydom, R. Matjie, J. Bunt, J. van Dyk
South African coal discards derived from feed coal for thermoprocesses pose human health and environmental problems and incur high disposal costs. These issues need to be resolved. Coal fines and a coal fines/ K2CO3 blend were combusted at 700°C in a laboratory rotary kiln to produce ashes containing metakaolinite (Al2O3.2SiO2) and illite/muscovite/orthoclase amorphous materials. The blend ash and coal fines ash, containing 18% K2O and <1% K2O respectively, were leached with water and with 1 M and 8 M NaOH at 80°C for 4 hours using a solid to liquid ratio of 1:5. The 8 M NaOH leach yielded 17% sodalite (Na8Si6Al6O24(OH)2) formation through SiO32-, Al(OH)4_, and Na+ precipitation in the leached ashes. The 1 M NaOH leach yielded no sodalite. X-ray fluorescence analysis of the original ashes and leached ashes showed low Al and Si dissolution efficiencies due to the sodalite formation. Sequential NaOH leaching resulted in the highest potassium dissolution efficiency of 89% for the ashes of fines/K2CO3 blend and 59% for the fines. It may be possible to increase the ash-derived zeolite concentration by using even higher NaOH concentrations (12-20 M NaOH) during leaching. Sodalite derived from coal ash could possibly be utilized for water purification in industrial applications, or as molecule separators. The potassium-containing liquid could be used in fertilizer manufacture.
南非用于热处理的饲料煤产生的废煤给人类健康和环境带来了问题,并产生了高昂的处置费用。这些问题需要解决。在实验室回转窑中,将煤粉和煤粉/ K2CO3共混物在700℃下燃烧,得到含有偏高岭石(Al2O3.2SiO2)和伊利石/白云母/正长石非晶态材料的灰烬。将K2O含量为18%的混合灰和K2O含量<1%的煤粉灰,在80℃条件下,以1 M和8 M NaOH为溶剂,料液比为1:5,加水浸出4小时。通过sio2 -、Al(OH)4_和Na+的析出,8 M NaOH浸出灰中形成了17%的钠石(Na8Si6Al6O24(OH)2)。1m NaOH浸出不产钠石。原始灰和浸出灰的x射线荧光分析显示,由于钠石质的形成,铝和硅的溶解效率较低。顺序NaOH浸出的钾溶出率最高,细粒/K2CO3混合灰溶出率为89%,细粒溶出率为59%。在浸出过程中使用更高的NaOH浓度(12-20 M NaOH)可能会增加灰源沸石的浓度。从煤灰中提取的钠石可能用于工业用水净化,或作为分子分离器。该含钾液体可用于化肥生产。
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引用次数: 0
Numerical investigation into slag solidification inside an ilmenite DC arc furnace using a finite element method approach 用有限元方法对钛铁矿直流电弧炉内渣的凝固过程进行了数值研究
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-04-14 DOI: 10.17159/2411-9717/1247/2023
A. Mabentsela, A. Mainza
A finite element model of a 5 m radius DC arc ilmenite furnace in idling mode was used to test the notion that the slag solidifies when it comes in to contact with colder pig iron, thus constituting the initial step in the formation of solid slag at the slag-pig iron interface. It was found that a slag that is 150°C hotter than the pig iron does not solidify at the interface. The 150°C temperature difference between the slag and pig iron is a result of solid slag at the slag-pig iron interface, not the other way around as suggested in the literature. Calculations show that the thickness of the frozen slag at the slag-pig iron interface is 1.7 cm for the furnace used. It is proposed that slag solidification begins with the slow co-current flow of molten slag and pig iron in the outer parts of the furnace. This provides enough time for molten slag to interact with molten pig iron without solidifying. As the reduction products form due to reduction of the slag by carbon in the pig iron, the slag solidifies. This approach negates the need for the slag to solidify by merely coming into contact with an inherently colder pig iron. Making use of a low thermal contact conductance between the slag and pig iron was found to be sufficient to numerically capture the presence of solid slag at the slag-pig iron interface and to preserve the 150°C difference between the slag and pig iron phase.
采用半径为5m的直流电弧钛铁矿炉空转模式的有限元模型,验证了炉渣在与较冷的生铁接触时凝固的概念,这是在炉渣-生铁界面形成固体炉渣的第一步。结果表明,当炉渣比生铁温度高150℃时,在界面处不会凝固。炉渣和生铁之间150℃的温差是由于固体渣在炉渣-生铁界面处造成的,而不是文献中提出的相反的结果。计算表明,该炉在炉渣-生铁界面处的冻渣厚度为1.7 cm。提出炉渣凝固始于炉渣与生铁在炉外缓慢共流。这为熔渣与熔体生铁相互作用而不凝固提供了足够的时间。由于炉渣被生铁中的碳还原而形成还原产物,炉渣凝固。这种方法只需要与本质上较冷的生铁接触,就不需要炉渣固化。利用炉渣和生铁之间的低热接触电导,可以在数值上捕捉炉渣-生铁界面上固体渣的存在,并保持炉渣和生铁之间150°C的相差。
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引用次数: 0
Prediction of ground vibrations induced by bench blasting using the random forest algorithm 用随机森林算法预测台阶爆破引起的地面振动
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-04-14 DOI: 10.17159/2411-9717/936/2023
N. Dzimunya, B. Besa, R. Nyirenda
The accurate estimation of peak particle velocity (PPV) is crucial during the design of bench blasting operations in open pit mines, since the vibrations caused by blasting can significantly affect the integrity of nearby buildings and other structures. Conventional models used to predict blast-induced vibrations are not capable of capturing nonlinear relationships between the different blasting-related parameters. Soft computing techniques, i.e., techniques that are founded on the principles of artificial intelligence, effectively model these complexities. In this paper, we use the random forest (RF) algorithm to develop a model to predict blast-induced ground vibrations from bench blasting using 48 data records. The model was trained and tested using WEKA data-mining software. To build this model, a feature selection process using several combinations of Attribute Evaluators and Search Methods under the WEKA Select Attributes tab was performed. The correlation coefficient of the actual data and RF model-predicted data was 0.95, and the weighted average of the relative absolute error (RAE) was 10.9%. The RF model performance was also compared to the equivalent-path-based (EPB) equation on the testing data-set, and it was seen that the RF model can effectively be used to predict PPV. The study also demonstrates that the EPB equation is a suitable empirical method for predicting PPV.
在露天矿台阶爆破作业的设计过程中,准确估计峰值颗粒速度(PPV)至关重要,因为爆破引起的振动会严重影响附近建筑物和其他结构的完整性。用于预测爆破引起的振动的传统模型不能捕捉不同爆破相关参数之间的非线性关系。软计算技术,即建立在人工智能原理基础上的技术,有效地模拟了这些复杂性。在本文中,我们使用随机森林(RF)算法,利用48个数据记录,建立了一个预测台阶爆破引起的地面振动的模型。使用WEKA数据挖掘软件对模型进行了训练和测试。为了构建该模型,在WEKA“选择属性”选项卡下使用属性计算器和搜索方法的几种组合进行了特征选择过程。实际数据与RF模型预测数据的相关系数为0.95,相对绝对误差的加权平均值(RAE)为10.9%。在测试数据集上,将RF模型的性能与基于等效路径的方程进行了比较,表明RF模型可以有效地用于预测PPV。研究还表明,EPB方程是预测PPV的一种合适的经验方法。
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引用次数: 0
Effect of mineralogy on grindability -A case study of copper ores 矿物学对可磨性的影响——以铜矿石为例
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-04-14 DOI: 10.17159/2411-9717/1714/2023
T. Nghipulile, T. Moongo, G. Dzinomwa, K. Maweja, B. Mapani, J. Kurasha, M. Amwaama
The effect of mineralogy on the grindability was investigated using three copper ores - two sulphides and one oxide. The dominant copper minerals were identified by optical microscopy and mineral chemistry derived from SEM-EDS analysis. The sample designated sulphide 1 was bornite-rich, sulphide 2 ore was mainly chalcopyrite, and the oxide ore was predominantly malachite and minor azurite. The gangue minerals were identified using semi-qualitative XRD analysis. Sulphide 1 contained more than 80% (w/w) of quartz compared to about 70% in the other two ores. The Bond work indices were 13.8, 21.6, and 17.3 kWh/t for sulphide 1, sulphide 2, and oxide ore respectively. This suggested that the chalcopyrite-rich ore is the hardest, while the malachite-rich ore has intermediate hardness, and the bornite-rich ore is the softest. The brittleness indices of the ores were calculated using the chemical composition of the gangue, and a good correlation between brittleness indices and Bond work indices was observed, which highlights the importance of the gangue composition in determining the fracture behaviour of the ores. There is scope for further investigation into the relationship between ore mineralogy and comminution behaviour using other breakage characterization techniques.
使用三种铜矿——两种硫化物和一种氧化物——研究了矿物学对可磨性的影响。通过光学显微镜和SEM-EDS分析得出的矿物化学鉴定了主要的铜矿物。指定为硫化物1的样品富含斑铜矿,硫化物2的矿石主要为黄铜矿,氧化物矿石主要为孔雀石和少量天青石。采用半定性XRD分析对脉石矿物进行了鉴定。硫化物1含有超过80%(w/w)的石英,而其他两种矿石中的石英含量约为70%。硫化物1、硫化物2和氧化物矿石的粘结功指数分别为13.8、21.6和17.3 kWh/t。这表明富含黄铜矿的矿石是最坚硬的,而富含孔雀石的矿石具有中等硬度,富含斑铜矿的矿石最柔软。利用脉石的化学成分计算了矿石的脆性指数,并观察到脆性指数与粘结功指数之间的良好相关性,这突出了脉石成分在决定矿石断裂行为中的重要性。使用其他破碎表征技术对矿石矿物学和粉碎行为之间的关系进行进一步研究还有余地。
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引用次数: 0
Material characteristics of Ti-6AL-4V samples additively manufactured using laser-based direct energy deposition 利用激光直接能量沉积添加制造的Ti-6AL-4V样品的材料特性
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-03-24 DOI: 10.17159/2411-9717/1508/2023
M. G. Willemse, C. Siyasiya, D. Marais, A. Venter, N. Arthur
Although additive manufacturing is fast gaining traction in the industrial world as a reputable manufacturing technique to complement traditional mechanical machining, it still has problems such as porosity and residual stresses in components that give rise to cracking, distortion, and delamination, which are important issues to resolve in structural load-bearing applications. This research project focused on the characterization of the evolution of residual stresses in Ti-6Al-4V extra-low interstitial (ELI) additive-manufactured test samples. Four square thin-walled tubular samples were deposited on the same baseplate, using the direct energy deposition laser printing process, to different build heights. The residual stresses were analysed in the as-printed condition by the neutron diffraction technique and correlated to qualitative predictions obtained using the ANSYS software suite. Good qualitative agreement between the stress measurements and predictions were observed. Both approaches revealed the existence of large tensile stresses along the laser track direction at the sections that were built last, i.e., centre of the top layers of the samples. This in addition leads to large tensile stresses at the outer edges (corners) which would have the effect of separating the samples from the baseplate should the stresses exceed the yield strength of the material. Such extreme conditions did not occur in this study, but the stresses did lead to significant distortion of the baseplate. In general, the microstructures and spatial elemental mapping revealed a strong correlation between the macro-segregation of elemental V and the distribution of the β-phase in the printed parts.
尽管增材制造作为一种完善传统机械加工的著名制造技术,在工业界迅速受到重视,但它仍然存在诸如部件中的孔隙率和残余应力等问题,这些问题会导致开裂、变形和分层,这是结构承载应用中需要解决的重要问题。本研究项目的重点是表征Ti-6Al-4V超低间隙(ELI)添加剂制造的试样中残余应力的演变。采用直接能量沉积激光打印工艺,将四个方形薄壁管样品沉积在同一基板上,达到不同的构建高度。通过中子衍射技术分析了打印状态下的残余应力,并将其与使用ANSYS软件套件获得的定性预测相关联。在应力测量和预测之间观察到良好的定性一致性。这两种方法都揭示了在最后构建的部分,即样品顶层的中心,沿着激光轨迹方向存在大的拉伸应力。此外,这会在外边缘(角)处产生较大的拉伸应力,如果应力超过材料的屈服强度,则会产生将样品与基板分离的效果。这项研究中没有出现这种极端情况,但应力确实导致了底板的显著变形。一般来说,微观结构和空间元素映射揭示了元素V的宏观偏析与印刷件中β相的分布之间的强相关性。
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引用次数: 1
Hyperspectral core scanner: An effective mineral mapping tool for apatite in the Upper Zone, northern limb, Bushveld Complex 高光谱岩心扫描仪:Bushveld杂岩北翼上部磷灰石的有效矿物填图工具
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-03-24 DOI: 10.17159/2411-9717/1890/2023
H. Mandende, C. Ndou, T. Mothupi
The technological advances in efficient, rapid, and non-destructive hyperspectral core logging systems for systematic mineral mapping have led to the discovery and exploitation of new mineral deposits Hyperspectral imaging in the long-wave infrared range has been recently used successfully to identify various phosphate-bearing minerals (monazite, xenotime, and britholite), with limited work on apatite associated with mafic-ultramafic layered intrusions. In this study we investigate the effectiveness of a hyperspectral imaging (HSI) system with long-wave infrared (LWIR) bandwidthsto identify apatite in the Upper Zone of the Bushveld Complex. The accuracy of the HSI results was validated by mineralogical and geochemical data. The two apatite-enriched zones detected by HSI suggesting widespread development of apatite throughout the uppermost 600 m of the Upper Zone. The lower apatite-enriched zone is approximately 40 m thick, while the upper apatite-enriched zone is about 23 m thick, consistent with previous thickness determinations by traditional logging and analytical methods. Spectral mixing observed in the response of apatite is ascribed either to the common association of apatite and olivine in these rocks, or to differences between the spatial resolution of the hyperspectral image and the size of apatite grains. The VNIR-SWIR wavelength region did not show prominent spectral features of apatite. Nonetheless, HSI in the LWIR range is effective in mapping apatite and should therefore be considered as an exploration tool. This research advances our knowledge of the reflectance spectroscopy of REE-bearing minerals, which makes it easier to detect, identify, and quantify REE-bearing silicate minerals by HSI.
用于系统矿物测绘的高效、快速和无损的高光谱岩心测井系统的技术进步导致了新矿床的发现和开发。长波红外范围内的高光谱成像最近已成功用于识别各种含磷酸盐矿物(独居石、异长岩和辉长岩),与镁铁质-超镁铁质层状侵入体相关的磷灰石研究有限。在这项研究中,我们研究了具有长波红外(LWIR)带宽的高光谱成像(HSI)系统识别布什维尔德杂岩上部磷灰石的有效性。通过矿物学和地球化学数据验证了HSI结果的准确性。HSI检测到的两个磷灰石富集带表明,磷灰石在上部带最上部600 m范围内广泛发育。下部磷灰石富集区的厚度约为40 m,而上部磷灰石富集区厚度约为23 m,这与之前通过传统测井和分析方法确定的厚度一致。在磷灰石的响应中观察到的光谱混合要么归因于这些岩石中磷灰石和橄榄石的共同结合,要么归因于高光谱图像的空间分辨率和磷灰石颗粒大小之间的差异。VNIR-SWIR波长区域没有显示出磷灰石的显著光谱特征。尽管如此,LWIR范围内的HSI在绘制磷灰石方面是有效的,因此应被视为一种勘探工具。这项研究提高了我们对含REE矿物反射光谱的认识,使HSI更容易检测、识别和量化含REE硅酸盐矿物。
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引用次数: 1
A critical comparison of interpolation techniques for digital terrain modelling in mining 采矿数字地形建模中插值技术的关键比较
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-03-24 DOI: 10.17159/2411-9717/2271/2023
M. A. Razas, A. Hassan, M. Khan, M. Z. Emad, S. A. Saki
Digital modelling of a surface is crucial for Earth science and mining applications for many reasons. These days, high-tech digital representations are used to produce a high-fidelity topographic surface in the form of a digital terrain model (DTM). DTMs are created from 2D data-points collected by a variety of techniques such as traditional ground surveying, image processing, LiDAR, radar, and global positioning systems. At the points for which data is not available, the heights need to be interpolated or extrapolated from the points with measured elevations. There are several interpolation/extrapolation techniques available, which may be categorized based on criteria such as area size, accuracy or exactness of the surface, smoothness, continuity, and preciseness. In this paper we examine these DTM production methods and highlight their distinctive characteristics. Real data from a mine site is used, as a case study, to create DTMs using various interpolation techniques in Surfer® software. The significant variation in the resulting DTMs demonstrates that developing a DTM is not straightforward and it is important to choose the method carefully because the outcomes depend on the interpolation techniques used. In mining instances, where volume estimations are based on the produced DTM, this can have a significant impact. For our data-set, the natural neighbour interpolation method made the best predictions (R2 = 0.969, β = 0.98, P < 0.0001).
由于许多原因,地表的数字建模对于地球科学和采矿应用至关重要。如今,高科技数字表示被用于以数字地形模型(DTM)的形式产生高保真的地形表面。dtm是由各种技术(如传统地面测量、图像处理、激光雷达、雷达和全球定位系统)收集的2D数据点创建的。在没有数据的点,高度需要从测量到的高度点内插或外推。有几种可用的插值/外推技术,可以根据诸如面积大小、表面的准确性或精确性、平滑性、连续性和精确性等标准进行分类。本文对这些DTM制作方法进行了分析,并突出了它们各自的特点。使用来自矿山现场的真实数据作为案例研究,在Surfer®软件中使用各种插值技术创建dtm。所得到的DTM的显著变化表明,开发DTM不是直截了当的,仔细选择方法很重要,因为结果取决于所使用的插值技术。在采矿实例中,体积估计是基于生成的DTM,这可能会产生重大影响。对于我们的数据集,自然邻居插值法的预测效果最好(R2 = 0.969, β = 0.98, P < 0.0001)。
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引用次数: 2
The necessity of 3D analysis for open-pit rock slope stability studies: Theory and practice 露天矿岩石边坡稳定性研究三维分析的必要性:理论与实践
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-03-24 DOI: 10.17159/2411-9717/2425/2023
A. McQuillan, N. Bar
Geotechnical models developed during the planning stages of open pit mines are three-dimensional so as to capture the spatial variation in lithological, structural, hydrogeological, and geomechanical conditions. Geological models that describe the lithological and structural (faulting and folding) characteristics of a deposit are always 3D. Likewise, boreholes and piezometers used to develop geomechanical properties and groundwater models are drilled at spatial offsets across the deposit to understand the lateral and vertical characteristics. Yet when geotechnical analysis is completed, often the three-dimensional geological, hydrogeological, and structural models as well as geometrically complex 3D mine designs for optimizing economic mineral recovery and overburden removal are simplified to two-dimensional sections. In this paper we demonstrate that this simplification can lead to the wrong failure mechanism being identified, analysed, and/or a conservative factor of safety being calculated and hence an over-estimation of slope stability. Through case studies we show how three-dimensional analysis methods are more suited to rock slopes, particularly those with anisotropic material strength, when singularities such as geological faults are present, and nonlinear slope geometry. When the same slopes are analysed in two dimensions, the failure mechanism calculated is often fundamentally incorrect. The case studies further reveal that the factor of safety calculated in three dimensions is not always higher than the two-dimensional factor of safety.
露天矿规划阶段建立的岩土模型是三维的,可以捕捉露天矿在岩性、构造、水文地质和地质力学条件等方面的空间变化。描述矿床的岩性和构造(断裂和褶皱)特征的地质模型总是三维的。同样,用于开发地质力学特性和地下水模型的钻孔和压力计在整个矿床的空间偏移上钻孔,以了解横向和垂直特征。然而,当岩土工程分析完成后,通常将三维地质、水文地质和结构模型以及几何复杂的三维矿山设计简化为二维剖面,以优化经济的矿物回收和覆盖层去除。在本文中,我们证明了这种简化可能导致错误的破坏机制的识别、分析和/或保守的安全系数的计算,从而高估了边坡的稳定性。通过案例研究,我们展示了三维分析方法如何更适合于岩石边坡,特别是那些具有各向异性材料强度的边坡,当存在奇异性(如地质断层)和非线性边坡几何形状时。当对同一边坡进行二维分析时,计算出的破坏机制往往是根本不正确的。实例分析进一步表明,三维计算的安全系数并不总是高于二维计算的安全系数。
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引用次数: 1
Determination of the erosion level of a porphyry copper deposit using soil geochemistry 用土壤地球化学方法确定斑岩铜矿床侵蚀程度
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-03-24 DOI: 10.17159/2411-9717/2029/2023
F. Moradpouri, S. Ahmadi, R. Ghaedrahmati, K. Barani
As exploration is time-consuming, costly, and risky, determination of the erosion surface of a metalliferous deposit before geophysical surveying and exploration drilling might be very helpful. Geochemical haloes can be used to determine whether the erosion surface is supra-ore or sub-ore and thus reduce the risk of exploration operations. The aim of this investigation is to determine the erosion surface of the North ROK porphyry deposit (NRPD) in northwestern British Columbia in Canada using linear productivity (LP), which is the content of an element defining the halo multiplied by the width of the halo. A total of 2045 soil samples from the B horizon were analysed using ICP-MS for 36 elements, including Cu, Mo, Pb, Zn, Au, As, Ag, Ni, Co, Fe, and Mn. The data-set was snalysed to obtain the statistical parameters and the elements Cu, Mo, Pb, and Zn were chosen to calculate the linear productivity and the total linear productivity. These four elements were modelled using probability plots to identify and separate subpopulations in terms of anomalous haloes and background, including the threshold values of each subpopulation. The results of the probability plot modelling and thresholds values were then used to map the distribution of each element in a GIS to calculate the linear productivity. The total linear productivity indicated that the erosion surface is supra-ore. Finally, a 3D orebody model of the Cu, Mo, Pb, and Zn distributions was constructed using borehole data and used to validate the results.
由于勘探费时、昂贵且有风险,在地球物理测量和勘探钻探之前确定含金属矿床的侵蚀面可能是非常有用的。地球化学晕可以用来确定侵蚀面是上矿面还是下矿面,从而降低勘探作业的风险。本次调查的目的是利用线性生产力(LP)来确定加拿大不列颠哥伦比亚省西北部北韩斑岩矿床(NRPD)的侵蚀面,线性生产力是定义晕的元素含量乘以晕的宽度。采用ICP-MS对2045份B层土壤样品进行了36种元素的分析,包括Cu、Mo、Pb、Zn、Au、As、Ag、Ni、Co、Fe和Mn。对数据集进行分析,得到统计参数,并选择Cu、Mo、Pb和Zn元素计算线性生产率和总线性生产率。利用概率图对这四个元素进行建模,根据异常光晕和背景识别和分离亚种群,包括每个亚种群的阈值。然后使用概率图建模和阈值的结果来绘制GIS中每个元素的分布,以计算线性生产率。总线性生产力表明侵蚀面为超矿石。最后,利用钻孔数据建立了Cu、Mo、Pb和Zn的三维矿体模型,并对结果进行了验证。
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引用次数: 1
The effect of petrographically determined parameters on reductant reactivity in the production of high-carbon ferromanganese 高碳锰铁生产中岩石学参数对还原剂反应性的影响
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-03-24 DOI: 10.17159/2411-9717/2321/2023
S. Soqinase, J. Steenkamp, P. den Hoed, N. Wagner
In pyrometallurgical processes, metal oxides are reduced from molten slag through carbothermic reduction. It is of interest to evaluate the reactivity of the carbonaceous materials towards substances such as slag. Characterization techniques such as coal petrography can provide insight into the influence of feed coal properties and how they potentially dictate reductant performance. This study aimed to compare the petrographically determined organic composition of coal to reductant reactivity. Two South African medium-rank C bituminous coals and one anthracite sample were investigated together with high-carbon ferromanganese industrial slag. The reductant reactivity tests were conducted at 1500°C in a muffle furnace to assess the potential of carbonaceous reductant in reacting with the main slag components. SEM-EDS was applied to understand the extent of MnO (and to a lesser extent, SiO2) reduction from the slag. Coal 2, consisting of a greater proportion of vitrinite (59.5 vol% on a mineral matter-free basis and 54.7 vol% including mineral matter) was the most reactive reductant. The anthracite sample, with the highest inert maceral proportions (71.8 vol% including mineral matter and 76.8 vol% on a mineral matter-free basis), was the least reactive reductant.
在火法冶金过程中,金属氧化物通过碳热还原从熔渣中还原。评估碳质材料对诸如炉渣之类的物质的反应性是令人感兴趣的。煤岩相学等表征技术可以深入了解原料煤性质的影响,以及它们如何潜在地决定还原剂的性能。本研究旨在比较岩相测定的煤的有机成分与还原剂的反应性。研究了两种南非中阶C烟煤和一种无烟煤样品以及高碳锰铁工业矿渣。还原剂反应性试验在1500°C的马弗炉中进行,以评估碳质还原剂与主要炉渣成分反应的潜力。应用SEM-EDS来了解炉渣中MnO(以及在较小程度上SiO2)还原的程度。由更大比例的镜质组组成的煤2(59.5体积%,基于无矿物物质,54.7体积%,包括矿物物质)是最具反应性的还原剂。无烟煤样品具有最高的惰性显微组分比例(包括矿物质的71.8体积%和无矿物质的76.8体积%),是反应性最低的还原剂。
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引用次数: 0
期刊
Journal of The South African Institute of Mining and Metallurgy
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