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Energy efficiency in the South African mining sector: A case study at a coal mine in Mpumalanga 南非矿业部门的能源效率:以普马兰加省一个煤矿为例研究
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-23 DOI: 10.17159/2411-9717/1788/2023
C.M.D. Majola, K.E. Langerman
Energy efficiency is a cost-effective way of both bolstering energy security and limiting the harmful effects of energy use on the environment. Mining is an inherently energy-intensive activity, and the 2008 revision of South Africa's National Energy Efficiency Strategy (NEES) set a target of a 10% reduction in energy consumption by 2015 for the mining sector. In this study, we investigate the effectiveness of the NEES in improving energy efficiency in the South African coal mining sector by surveying energy intensity at a number of operations, and analysing energy efficiency trends and energy use by process and energy carrier at an underground coal mine in Mpumalanga. Most mines surveyed exhibit an increase in energy intensity over time. At the case study mine, the increase was primarily due to increased energy use in the beneficiation and discard reclaiming processes. Trends in energy consumption are a poor reflection of trends in energy intensity, as a decline in energy consumption is most easily achieved by reducing production. A more appropriate metric for energy efficiency at coal mines is energy intensity, defined as energy use per unit of saleable product, relative to a multi-year baseline. The evidence suggests that the NEES has been ineffective in promoting energy efficiency in South African coal mines. We propose that greater success could be achieved by monitoring and reporting on energy intensity at the process level, and by incentivizing energy efficiency gains.
提高能源效率是一种既能加强能源安全又能限制能源使用对环境的有害影响的经济有效的方法。采矿业本质上是一项能源密集型活动,2008年修订的南非国家能源效率战略(NEES)设定了到2015年采矿业能耗减少10%的目标。在这项研究中,我们调查了NEES在提高南非煤炭开采部门能源效率方面的有效性,通过调查一些业务的能源强度,并分析了普马兰加省一个地下煤矿的能源效率趋势和能源使用过程和能源载体。大多数被调查的矿山随着时间的推移表现出能源强度的增加。在案例研究矿山中,增加主要是由于选矿和废料回收过程中的能源使用增加。能源消耗的趋势不能很好地反映能源强度的趋势,因为能源消耗的下降最容易通过减少生产来实现。衡量煤矿能源效率的一个更合适的指标是能源强度,定义为相对于多年基线的每单位可销售产品的能源使用量。有证据表明,NEES在促进南非煤矿的能源效率方面是无效的。我们建议,通过在流程层面监测和报告能源强度,以及通过激励能源效率的提高,可以取得更大的成功。
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引用次数: 0
Optimization of shape factor by the response surface method, and the effect on sphalerite flotation recovery 利用响应面法优化形状因子,研究对闪锌矿浮选回收率的影响
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-23 DOI: 10.17159/2411-9717/2645/2023
T. Uysal
Various morphological parameters that affect the flotation recovery of sphalerite were modelled and optimized using the response surface method (RSM). The effects of roughness value, shape factor, and collector concentration were investigated using the central composite full design method. The results were evaluated by analysis of variance. The optimum roughening time was found to be 25 minutes, the optimum roughness value was 2.9071 um, and the optimum collector concentration was 0.001 M. Using these values, a flotation recovery of 98.01% was obtained. Similarly, in shape factor studies, the optimum grinding time was 15 seconds, the optimum roundness value 0.7421, and the optimum collector concentration 0.0009 M, which resulted in a flotation recovery of 94.30%. The average error between the optimization results and the experimental results was estimated to be less than 6%, and the R2 values were greater than 90%. The study shows that RSM can be effectively applied in finding the economic optimum condition for obtaining maximum flotation recovery with minimum reagent consumption.
采用响应面法(RSM)对影响闪锌矿浮选回收率的各种形态参数进行了建模和优化。采用中心复合完全设计方法,研究了粗糙度值、形状因子和捕集剂浓度的影响。通过方差分析对结果进行评价。结果表明,最佳粗化时间为25 min,最佳粗化值为2.9071 um,最佳捕收剂浓度为0.001 m,可获得98.01%的浮选回收率。同样,在形状因子研究中,最佳磨矿时间为15 s,最佳圆度为0.7421,最佳捕收剂浓度为0.0009 M,浮选回收率为94.30%。估计优化结果与实验结果的平均误差小于6%,R2值大于90%。研究表明,RSM可以有效地用于寻找以最小药剂用量获得最大浮选回收率的经济最佳条件。
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引用次数: 0
The needle penetration index for estimating the physico-mechanical properties of pyroclastic rocks 评价火山碎屑岩物理力学性质的针状穿透指数
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-23 DOI: 10.17159/2411-9717/1433/2023
S. Kahraman, I. Ince
Preparation of suitable core specimens for physico-mechanical testing s not always possible, particularly for soft and clay-bearing rocks. Although several indirect test methods have been proposed to predict the properties of rocks, specimen preparation from soft rocks for some indirect tests is still difficult. For such cases, the needle penetration test has been developed. In this paper we present a study on the predictability of the physico-mechanical properties of pyroclastic rocks from the needle penetration index (NPI). The NPI, uniaxial compressive strength (UCS), Brazilian tensile strength (BTS), density, and porosity tests were performed in the laboratory on specimens from ten different locations in Turkey. Correlations were established between the NPI values and the physico-mechanical properties. Strong correlations were observed between NPI and both UCS and BTS. General correlations were found between NPI and both density and porosity.
制备合适的岩心试样进行物理力学试验并不总是可能的,特别是对于软质和含粘土的岩石。虽然已经提出了几种间接测试方法来预测岩石的性质,但从软岩中制备样品进行一些间接测试仍然很困难。针对这种情况,已经开发了针穿试验。本文研究了用针穿指数(NPI)预测火山碎屑岩物理力学性质的方法。NPI、单轴抗压强度(UCS)、巴西抗拉强度(BTS)、密度和孔隙率测试在实验室对来自土耳其十个不同地点的样品进行。建立了NPI值与材料物理力学性能之间的相关性。NPI与UCS和BTS之间存在很强的相关性。NPI与密度和孔隙度之间存在一般的相关性。
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引用次数: 0
A study of different grinding aids for low-energy cement clinker production 低能水泥熟料生产中不同助磨剂的研究
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-23 DOI: 10.17159/2411-9717/2702/2023
S.R.M. Zan, K.E.H.K. Ishak
Cement production requires significant energy, and entails high costs and CO2 emissions. This is because the clinker requires very fine grinding. Grinding aids can improve production and fineness and decrease energy consumption by reducing the agglomeration of particles and protecting the balls and liners in the mill. In this study we compare the effects of three different grinding aids on clinker grinding using a ball mill. A commercial grinding additive, triethanolamine (TEA), and two industrial grinding aids (GAA079 and GAA088) were compared by ball milling tests, with additions of 0.05, 0.25, 0.50 and 1.00 wt%. The industrial grinding aids were characterized using gas chromatography-mass spectrometry (GC-MS). Particle size and morphological analyses were performed using SEM and XRD. The best results were obtained with 0.25% GAA088, which has a higher active component of diethanolamine isopropanolamine (DEIPA) than TEA. The unique combination of TEA and DEIPA in GAA088 enhances grinding efficiency and significantly improves the particle size distribution compared to TEA alone.. The grinding aids produced smooth rounded particles, which have a smaller specific surface area, enhancing the quality of the cement. XRD showed no significant structural distortion with or without grinding aids, and it was also found that the grinding aids helped decrease ball coating during grinding. The use of grinding aids can significantly improve clinker production and fineness while decreasing energy consumption, which can help reduce the costs and CO2 emissions associated with cement production.
水泥生产需要大量能源,成本高,二氧化碳排放量大。这是因为熟料需要非常精细的研磨。助磨剂通过减少颗粒团聚,保护磨球和衬板,可以提高产量和细度,降低能耗。在本研究中,我们比较了三种不同助磨剂对球磨机熟料粉碎的影响。通过球磨试验比较了三乙醇胺(TEA)和GAA079、GAA088两种工业助磨剂(添加量分别为0.05、0.25、0.50和1.00 wt%)的性能。采用气相色谱-质谱联用技术对工业助磨剂进行了表征。采用扫描电镜(SEM)和x射线衍射(XRD)对其粒度和形貌进行了分析。当GAA088含量为0.25%时效果最佳,其二乙醇胺异丙醇胺(DEIPA)活性成分高于TEA。与单独使用TEA相比,GAA088中TEA和DEIPA的独特组合提高了磨削效率,显著改善了粒度分布。助磨剂产生的颗粒光滑圆润,比表面积小,提高了水泥质量。XRD分析表明,添加助磨剂和不添加助磨剂均没有明显的结构畸变,助磨剂有助于减少磨球过程中的球包层。使用助磨剂可以显著提高熟料产量和细度,同时降低能耗,有助于降低水泥生产相关的成本和二氧化碳排放。
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引用次数: 0
The thermal decomposition kinetics of carbonaceous and ferruginous manganese ores in atmospheric conditions 大气条件下含碳和含铁锰矿石的热分解动力学
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-18 DOI: 10.17159/2411-9717/2527/2023
S.A.C. Hockaday, F. Dinter, Q.G. Reynolds
The thermal decomposition of carbonate minerals as pre-treatment before smelting reduces the energy requirement for smelting. It can also make the combustion of fossil fuels for heating unnecassary. Thermal decomposition may become important in reducing greenhouse gas emissions when producing ferromanganese alloys while simultaneously reducing electrical energy demand during smelting. A kinetic reaction rate model for the thermal decomposition of manganese ores is presented, based on published reaction rate kinetics for the decomposition of manganese oxides and calcium carbonate. The model was validated against thermogravimetric data for two carbonaceous manganese ore samples and one ferruginous manganese ore sample. The reaction rate model shows that carbonate minerals in the manganese ores are decomposed at temperatures above 900 °C while pyrolusite is decomposed at temperatures from 450 °C to 500 °C. Mn2O3 decomposes rapidly at 550 °C. Braunite decomposition at temperatures below 1000 °C was negligible. The presence of organic carbon in the samples led to further reduction of the samples during thermal treatment.
碳酸盐矿物的热分解作为冶炼前的预处理,降低了冶炼所需的能量。它还可以使燃烧化石燃料取暖变得不必要。在生产锰铁合金时,热分解在减少温室气体排放,同时减少冶炼过程中的电能需求方面可能变得重要。基于已发表的氧化锰和碳酸钙分解反应速率动力学,提出了锰矿石热分解反应速率动力学模型。用两个碳质锰矿样和一个铁质锰矿样的热重数据对模型进行了验证。反应速率模型表明,锰矿中的碳酸盐矿物在900℃以上分解,软锰矿在450℃~ 500℃分解。Mn2O3在550℃时迅速分解。在低于1000℃的温度下,布劳内分解可以忽略不计。样品中有机碳的存在导致样品在热处理过程中进一步还原。
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引用次数: 0
Removal of arsenic and metal ions from acidic effluents via the Fenton reaction method Fenton反应法去除酸性废水中的砷和金属离子
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-18 DOI: 10.17159/2411-9717/1863/2023
Y. Wang
Arsenic-bearing acidic effluent from hydrometallurgical processes contains many harmful metal ions and must be appropriately treated before discharge. In the present study, arsenic, copper, zinc, aluminum, and magnesium were co-precipitated by means of the Fenton reaction. The precipitates obtained under different conditions were investigated to determine their stability. The results indicate that pH value and hydrogen peroxide (H2O2) dosage have significant effects on the removal of various elements. Arsenic, copper, zinc, and aluminum (but not magnesium) can be removed at pH 5-6 and anH2O2/As mole ratio of 2 at ambient temperature. The precipitates were mainly amorphous and granular with particle size in the micrometre range. The arsenic concentration in leachate from the toxicity characteristic leaching test was 3.6 mg/L, which proves that the precipitates are effective in fixing arsenic.
湿法冶金含砷酸性废水中含有大量有害金属离子,排放前必须进行适当处理。在本研究中,砷、铜、锌、铝和镁通过芬顿反应共沉淀。考察了在不同条件下得到的析出物的稳定性。结果表明,pH值和过氧化氢(H2O2)用量对各元素的去除率有显著影响。砷、铜、锌和铝(但不包括镁)可以在pH 5-6和h2o2 /As的摩尔比为2的环境温度下去除。析出物主要为非晶态和粒状,粒度在微米量级。毒性特征浸出试验中,渗滤液中砷的浓度为3.6 mg/L,证明沉淀对砷有固定作用。
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引用次数: 0
Mechanism and control of deformation in gob-side entry with thick and hard roof strata 厚硬顶板采空区巷道变形机理及控制
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-18 DOI: 10.17159/2411-9717/1707/2023
J.S. Guo, L.Q. MaII, I. Ngo
Deformation of gob-side entries has always been a critical concern for ensuring stability in longwall coal mines. This paper addresses the significant deformation and support challenges that arise in thick and hard roof longwall faces (THRLF) due to dynamic pressure. The study aims to elucidate the characteristics and mechanisms of deformation during the retreat of the longwall face. The research findings indicated that the primary cause of deformation was the combination of advanced abutment stress resulting from longwall face mining and the movement of the lateral roof over the chain pillar. To mitigate this issue, we propose a deformation control method known as cutting off the lateral roof (COLR) over the chain pillar. Simulation results demonstrate a significant reduction in roof stress and deformation of the gob-side entry after implementing the lateral roof-cutting technique. These findings provide valuable guidance for effectively managing deformation in gob-side entries, particularly when dealing with thick and hard roof strata.
采空区巷道变形一直是影响长壁煤矿稳定的关键问题。本文论述了在动压作用下,厚硬顶板长壁工作面产生的显著变形和支护挑战。本研究旨在阐明长壁工作面回撤过程中的变形特征及机理。研究结果表明,变形的主要原因是长壁工作面开采产生的超前支承应力和侧顶板对锚链矿柱的移动共同作用。为了缓解这个问题,我们提出了一种变形控制方法,即切断链柱上方的侧顶(COLR)。模拟结果表明,采用侧切顶板技术后,采空区巷道顶板应力和变形明显减小。这些发现为有效管理采空区巷道的变形提供了有价值的指导,特别是在处理厚而硬的顶板岩层时。
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引用次数: 0
Mechanical activation and physicochemical factors controlling pyrometallurgical, hydrometallurgical, and electrometallurgical processing of titanium ore: A review 钛矿热法、湿法和电法加工的机械活化和理化因素综述
4区 材料科学 Q3 Materials Science Pub Date : 2023-10-18 DOI: 10.17159/2411-9717/2082/2023
H.C.S. Subasinghe, A.S. Ratnayake
In this study, we review the role of mechanical activation in the pyrometallurgical, hydrometallurgical, and electrometallurgical processing of titanium feedstock. Mechanical activation has been shown to decrease the activation energy of chemical reactions, thus enhancing process efficiency and product quality by reducing processing time and energy consumption. Pyrometallurgical processing is energy-intensive and time-consuming. Hydrometallurgy is costly, requires high-grade feed material, and generates toxic waste. Waste generation and process complexity are the major drawbacks of electrometallurgy and solvent extraction. Bioleaching via a mechanically activated pyrometallurgical process can be identified as an alternative method, but the lengthy processing time is the major disadvantage. Mechanically activated titanium concentrate can be used in a finely tuned combined metallurgical process to overcome the challenges and drawbacks in these technologies.
本文综述了机械活化在钛原料火法、湿法和电法加工中的作用。机械活化已被证明可以降低化学反应的活化能,从而通过减少加工时间和能耗来提高工艺效率和产品质量。火法冶金工艺耗能大,耗时长。湿法冶金成本高,需要高级原料,并产生有毒废物。废弃物的产生和工艺的复杂性是电冶金和溶剂萃取的主要缺点。通过机械活化的火法冶金工艺进行生物浸出可以确定为一种替代方法,但处理时间长是主要缺点。机械活化钛精矿可用于精细调整的组合冶金工艺,以克服这些技术的挑战和缺点。
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引用次数: 0
Bord-and-pillar design for the UG2 Reef containing weak alteration layers UG2暗礁含弱蚀变层的Bord和矿柱设计
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-07-13 DOI: 10.17159/2411-9717/2482/2023
P. M. Couto, D. Malan
We propose a layout design for the UG2 Reef where weak geological alteration layers are present. The collapse of the Everest platinum mine in South Africa indicated that these layers substantially weaken the pillars. The popular Hedley and Grant pillar strength formula cannot be used where these alteration layers are present. Underground investigations at Everest mine and numerical modelling of the layout were conducted using the TEXAN code and a limit equilibrium model. Simulations of a collapsed area and an intact area allowed for a preliminary calibration of the model. This was subsequently used to explore modified layouts for these ground conditions. An alternative is to compartmentalize the blocks of ore using barrier pillars. The numerical modelling predicted that the barrier pillars appear to remain stable even in the case of large-scale collapses, provided their width exceeds 25 m. Main access routes into the mine can be protected by a double row of pillars at least 15 m wide to provide a safe travelling way. As a cautionary note, these conclusions are based on the model calibration and this needs to be refined in future. Calibration of the limit equilibrium model remains a challenge owing to the large number of parameters involved.
我们提出了UG2暗礁的布局设计,该暗礁存在薄弱的地质蚀变层。南非珠穆朗玛峰铂矿的坍塌表明,这些地层大大削弱了矿柱。在存在这些蚀变层的情况下,不能使用流行的Hedley和Grant矿柱强度公式。使用德克萨斯州代码和极限平衡模型对Everest矿山进行了地下调查,并对布局进行了数值建模。对坍塌区域和完整区域的模拟允许对模型进行初步校准。这随后被用于探索针对这些地面条件的修改布局。另一种选择是使用障壁柱来划分矿石块。数值模型预测,即使在大规模坍塌的情况下,只要其宽度超过25米,屏障矿柱似乎也会保持稳定。进入矿井的主要通道可以由至少15米宽的双排矿柱保护,以提供安全的行进方式。值得注意的是,这些结论是基于模型校准的,这需要在未来进行改进。由于涉及大量参数,校准极限平衡模型仍然是一个挑战。
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引用次数: 0
Calibration of the limit equilibrium pillar failure model using physical models 用物理模型标定极限平衡矿柱破坏模型
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-07-13 DOI: 10.17159/2411-9717/2655/2023
R.P. Els, D. Malan
The limit equilibrium model, used in displacement discontinuity codes, is a popular method to simulate pillar failure. This paper investigates the use of physical modelling to calibrate this model. For the experiments, an artificial pillar material was prepared and cubes were poured using the standard 100 mm χ 100 mm civil engineering concrete moulds. The friction angle between the cubes and the platens of the testing machine was varied by using soap and sandpaper. Different modes of failure were observed depending on the friction angle. Of interest is that significant loadshedding was recorded for some specimens which visually remained mostly intact. This highlights the difficulty of classifying pillars as failed or intact in underground stopes where spalling is observed. The laboratory models enabled a more precise calibration of the limit equilibrium model compared to previous attempts. Guidelines to assist with calibration of the model are given in the paper. The limit equilibrium model appears to be a useful approximation of the pillar failure as it could simulate the stress-strain behaviour of the laboratory models.
在位移不连续规范中,极限平衡模型是模拟矿柱破坏的常用方法。本文研究了使用物理建模来校准该模型。在试验中,制备了一种人工支柱材料,并使用标准的100 mm χ 100 mm土木工程混凝土模具浇注立方体。用肥皂和砂纸分别改变了试件与试验台板的摩擦角。根据摩擦角的不同,观察到不同的破坏模式。有趣的是,一些标本在视觉上基本保持完整,但却记录了显著的负载减少。这突出了在观察到剥落的地下采场中将矿柱分类为破坏或完整的困难。与以前的尝试相比,实验室模型能够更精确地校准极限平衡模型。本文给出了协助模型校准的指导方针。极限平衡模型似乎是一个有用的近似柱破坏,因为它可以模拟实验室模型的应力-应变行为。
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引用次数: 0
期刊
Journal of The South African Institute of Mining and Metallurgy
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