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Hand-held XRF sorting of spent refractory bricks to aid recycling 手持XRF分拣废旧耐火砖,帮助回收
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-23 DOI: 10.17159/2411-9717/1928/2023
N. Mabasa, N. Naudé, A. Garbers-Craig
An improved methodology is presented for assessing the economic feasibility and effectiveness of recycling MgO-C and Al2CO3-MgO-C refractory bricks, which are widely used in the steelmaking industry. Since approximately 28 Mt of refractory bricks are discarded each year, it is logical to recycle them. When furnaces and ladles are relined, the spent refractory bricks become mixed up, and need to be sorted before recycling. This study examined the use of a hand-held X-ray fluorescence analyser (HH-XRF) to distinguish between spent oxide-based and oxide-carbon-based refractory materials, with special emphasis on spent MgO-C (MC) and Al2O3-MgO-C (AMC) bricks. HH-XRF analysis was conducted on 18 oxide-carbon refractory bricks as well as on MgO-chromite and bauxite-based refractories. X-ray diffraction, reflected light optical microscopy, and scanning electron microscopy with energy dispersive spectroscopy were used to characterize the MgO-C and Al2O3-MgO-C bricks to confirm the accuracy of the HH-XRF analyses. This study also underlined the importance of calibrating the HH-XRF analyser for the refractory bricks to be sorted. The HH-XRF was successful in distinguishing between the different oxide-carbon-based refractory bricks both before and after cleaning. This result is important as it proves that HH-XRF provides a method whereby spent MC and AMC bricks can be sorted quickly and reliably.
提出了一种改进的方法,用于评估在炼钢工业中广泛使用的MgO-C和Al2CO3-MgO-C耐火砖的经济可行性和有效性。由于每年大约有28mt耐火砖被丢弃,因此回收它们是合乎逻辑的。当炉窑和钢包重新内衬时,用过的耐火砖会混合在一起,需要在回收前进行分类。本研究检查了手持式x射线荧光分析仪(HH-XRF)的使用,以区分废氧化基和氧化碳基耐火材料,特别强调废MgO-C (MC)和Al2O3-MgO-C (AMC)砖。对18种氧化碳耐火砖以及镁铬铁矿和铝土矿基耐火材料进行了HH-XRF分析。利用x射线衍射、反射光光学显微镜和扫描电子显微镜与能量色散光谱对MgO-C和Al2O3-MgO-C砖进行了表征,以证实HH-XRF分析的准确性。本研究还强调了HH-XRF分析仪对待分选耐火砖的校准的重要性。HH-XRF在清洗前后成功地区分了不同的氧化碳基耐火砖。这一结果很重要,因为它证明HH-XRF提供了一种方法,可以快速可靠地对废MC和AMC砖进行分类。
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引用次数: 1
Real-time underground route identification and route progress using simple on-board sensing and processing 利用简单的车载传感和处理实现实时地下路线识别和路线进展
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-23 DOI: 10.17159/2411-9717/1893/2023
R. F. Meeser, N. Theron
The global emphasis on conserving energy resources has led to the adoption of hybrid power systems in vehicles. Optimally applied, hybrid systems can save up to 40% on fuel costs. To optimally manage a hybrid vehicle's energy flow it is necessary to know, in real time, all the energy requirements to complete a given route. The energy consumption depends mainly on the vehicle mass, speed profile, and route topography. Of these, the topographic profile is the one factor that is only route-dependent and not influenced by the vehicle or driving styles. The heading vs. distance profile is also an example of a route characteristic not influenced by the vehicle or driving style. In this study the topographic and heading profiles are used to identify routes, and are easily measured by means of digital barometric pressure and compass sensors. Correlations between the current route and previously travelled/stored routes are performed based on their topographic and heading profiles in a point-by-point manner. Above-ground tests were first performed using a road vehicle and six routes to evaluate the system. The system consistently and correctly identified a 20 km route within the first 4 km. It also proved to function correctly in underground tests through the implementation of an instrumented hand-held surveyor's wheel. This system finds direct practical application in optimizing the energy management of an underground hybrid locomotive used by the mining industry in South Africa, but can also be of benefit in applications where route identification is required and using GPS is not feasible.
全球对节约能源的重视导致了混合动力系统在车辆中的采用。最佳应用,混合动力系统可以节省高达40%的燃料成本。为了优化管理混合动力汽车的能量流,有必要实时了解完成给定路线所需的所有能量。能量消耗主要取决于车辆质量、速度剖面和路线地形。在这些因素中,地形轮廓是唯一一个只依赖于路线而不受车辆或驾驶风格影响的因素。方向与距离的对比也是不受车辆或驾驶风格影响的路线特征的一个例子。在本研究中,地形和航向轮廓线被用来识别路线,并且很容易通过数字气压和罗经传感器测量。当前路线和以前旅行/存储的路线之间的相关性是基于它们的地形和标题剖面图以逐点的方式执行的。首先使用一辆公路车辆和六条路线进行了地面测试,以评估该系统。该系统在前4公里内始终准确地识别出一条20公里的路线。在地下测试中,它也被证明是正确的,通过一个仪器手持测量轮的实施。该系统在优化南非采矿业使用的地下混合动力机车的能源管理方面有直接的实际应用,但也可以在需要路线识别且无法使用GPS的应用中受益。
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引用次数: 0
Increasing the efficiency of secondary resources in the mining and metallurgical industry 提高矿冶工业二次资源利用效率
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-23 DOI: 10.17159/2411-9717/1092/2023
G. Jandieri
An improved methodology is presented for assessing the economic feasibility and effectiveness of recycling industrial waste. The methodology is based on the break-even control mechanism, but at the same time provides for the introduction of new evaluation criteria such as the threshold of conditionality and the degree of ore substitution. Based on an improved analysis, it becomes possible to more precisely predict recycling efficiency. A more refined determination of the lower limit of concentration of recoverable metals, at which technogenic waste can be assigned the status of secondary raw materials and processed profitably, leads to a significant expansion of the secondary raw material base suitable for recycling. The potential for recycling manganese-containing dust from the production of ferrosilicomanganese, dehydrated sludge from the hydro separation of slags, and cake from the production of electrolytic manganese dioxide at the Chiatura mining enterprise is used as an example. It is shown that with a threshold of -24% Mn content, the highest recycling efficiency can be achieved by the production of low-phosphorus manganese slag and conversion to ferrosilicomanganese using the above waste to replace 40-60% grade III and IV manganese concentrates in the feed.
提出了一种改进的方法来评估回收工业废物的经济可行性和有效性。该方法以盈亏平衡控制机制为基础,但同时规定引入新的评估标准,如条件门槛和矿石替代程度。基于改进的分析,可以更精确地预测回收效率。更精细地确定可回收金属的浓度下限,在该下限下,技术废物可以被指定为二次原料并进行有利可图的处理,这将大大扩大适合回收的二次原料基础。以Chiatura矿业企业回收硅锰生产过程中的含锰粉尘、炉渣水力分离过程中的脱水污泥和电解二氧化锰生产中的滤饼为例。研究表明,在锰含量为-24%的阈值下,通过生产低磷锰渣并利用上述废物转化为硅锰铁来代替饲料中40-60%的III级和IV级锰精矿,可以实现最高的回收效率。
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引用次数: 0
Elastic damage characterization of an ilmenite smelter freeze lining 钛铁矿冶炼厂冻结炉衬的弹性损伤特性
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-23 DOI: 10.17159/2411-9717/1248/2023
A. Mabentsela
A furnace freeze lining is necessary for safety and economic reasons in several smelting operations. The integrity of the freeze lining is put at risk by furnace power imbalances. Although numerous models have been derived to model the growth and depletion of the freeze lining due to power imbalances, no model exists for thermomechanical damage to the freeze lining. This study provides an initial pathway for modelling thermomechanical damage to the freeze lining in an ilmenite smelting furnace using information from the literature and experimental work. A methodology under the framework of continuum damage mechanics is proposed to model mechanical damage to the freeze lining due to phase changes, thermophysical changes, and constrained thermal expansion. Drill cores of solidified slag ingots were used to represent the freeze lining. The modified power law proved to be the best predictor of the softening response of the drill cores. Damage driving parameters were extracted from the raw data, and governing equations of the parameters with respect to temperature were derived for use in a finite element method (FEM) code.
在几种冶炼操作中,出于安全和经济原因,熔炉冻结衬里是必要的。熔炉功率失衡使冻结衬里的完整性面临风险。尽管已经推导出许多模型来模拟由于功率不平衡而导致的冻结衬里的生长和损耗,但还不存在对冻结衬里的热机械损伤的模型。这项研究为利用文献和实验工作中的信息模拟钛铁矿冶炼炉中冷冻衬里的热机械损伤提供了一条初步途径。在连续损伤力学的框架下,提出了一种方法来模拟由相变、热物理变化和约束热膨胀引起的冻结衬砌的机械损伤。凝固渣锭的钻芯被用来表示冻结衬里。改进的幂律被证明是岩心软化响应的最佳预测因子。从原始数据中提取损伤驱动参数,并推导出参数相对于温度的控制方程,用于有限元法(FEM)代码。
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引用次数: 0
Development status of coal mining in China 中国煤炭开采发展现状
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-23 DOI: 10.17159/2411-9717/1506/2023
X. Liu, L. Li, Y. Yang
Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.
中国的煤炭开采正面临着从产量到质量的转变。以总开采能力和平均产量为基础,分析了矿区、市、省三级煤炭开采现状,为矿业可持续发展布局和产量优化提供了数据支撑。结果表明,中国87%的煤炭是地下开采,平均每个矿井的生产能力为0.93 Mt/a。露天开采占13%,矿山平均产能为5.73 Mt/a。全国煤矿平均开采能力为105 Mt/a,平均产能低于0.3 Mt/a的煤矿有1181个,占全国煤矿总量的35%,但对产量的贡献率仅为4.51%。它们分布在6个省约48个城市,严重制约了煤炭向绿色开采的过渡。煤炭行业要加快重点省市小煤矿关停,淘汰中部地区落后产能,提高煤炭资源西移速度和比重,促进煤炭开采高质量发展。
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引用次数: 2
Studies on fluorination of Fe3O4 (magnetite) by NH4HF2 NH4HF2氟化Fe3O4(磁铁矿)的研究
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-10 DOI: 10.17159/2411-9717/1639/2022
L. Zhang, Y. Zhou, H. Wang, C. Mo
Fluorination of magnetite (Fe3O4) by NH4HF2 was investigated using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), and observing the morphology and phase changes using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffractometry (XRD). The results indicate that fluorination with the involvement of oxygen begins at room temperature, peaks at 1784ºC, and is completed at 200ºC with the formation of only (NH4)3FeF6. On heating, (NH4)3FeF6 gradually releases NH4F by the formation of NH4FeF4 at 259ºC, then (NH4)0.l8FeF3 at 327ºC, and finally FeF3 with minor FeF2 at 400ºC due to the partial reduction of Fe (III) to Fe (II). At 550ºC, FeF3 is oxidized to FeOF/Fe2O3.
采用热重法和差热分析(TG-DTA)研究了NH4HF2对磁铁矿(Fe3O4)的氟化反应,并利用扫描电子显微镜、x射线能谱仪(SEM-EDS)和x射线衍射仪(XRD)观察了氟化反应的形貌和相变化。结果表明,氧参与的氟化反应始于室温,在1784℃时达到峰值,在200℃时完成,只生成(NH4)3FeF6。加热时,(NH4)3FeF6在259℃形成NH4FeF4,逐渐释放出NH4F,然后(NH4)0。在327℃时,FeF3与FeF3在400℃时,由于Fe (III)部分还原为Fe (II),最终FeF3与少量FeF2。在550℃时,FeF3被氧化为FeOF/Fe2O3。
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引用次数: 0
Stochastic analysis of dig limit optimization using simulated annealing 基于模拟退火的挖掘极限优化随机分析
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-10 DOI: 10.17159/2411-9717/1036/2022
J. R. van Duijvenbode, M. S. Shishvan
The results of dig limit delineation in open pit mining are never truly optimized due to gaps in the underlying data, such as insufficient sampling. Aside from the data uncertainty, there is also an influence on the final dig limit by either humans or by the heuristic character of an optimization method like simulated annealing. Several dig limit optimizers have been published, which can replace the manual dig-limits designing process. However, these dig limit designs are generally not adapted to account for this heuristic character. In this paper we present a stochastic analysis tool that can be used with the results of heuristic dig-limit optimization to increase confidence in the obtained results. First, an enhanced simulated annealing algorithm for dig limit optimization is presented. Then, this algorithm is tested on ten different blasts at the Marigold mine, Nevada, USA, as a case study. Finally, the results are analysed with a destination-based ensemble probability map and an analysis conducted of the final solution data distribution. The generated dig-limit designs of the algorithm include high revenue areas that are excluded in comparable manual designs and show improved objective and revenue values. The analysis tool provides block destination probabilities and box plots with the distribution of opportunity value for the dig limit. Furthermore, with the analysis tool, it is possible to make well-informed design decisions in areas of uncertainty.
露天矿开采中,由于底层数据存在缺口,如采样不足等,无法真正优化开采极限圈定结果。除了数据的不确定性外,人类或模拟退火等优化方法的启发式特性也会影响最终挖掘极限。目前已经有几种优化器可以代替人工设计。然而,这些挖掘极限设计通常不适合解释这种启发式特征。在本文中,我们提出了一个随机分析工具,它可以与启发式极限优化的结果一起使用,以增加对所得结果的置信度。首先,提出了一种改进的模拟退火算法。然后,将该算法作为案例研究,在美国内华达州的万寿菊矿的十次不同的爆炸中进行测试。最后,利用基于目标的集成概率图对结果进行分析,并对最终解的数据分布进行分析。该算法生成的限位设计包括在可比手工设计中排除的高收入区域,并显示改进的目标和收入值。分析工具提供了区块目的地概率和具有挖掘极限机会值分布的箱形图。此外,使用分析工具,可以在不确定的领域做出明智的设计决策。
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引用次数: 0
Simulation of production processes and associated costs in mining using the Monte Carlo method 使用蒙特卡罗方法模拟采矿生产过程和相关成本
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-10 DOI: 10.17159/2411-9717/2079/2022
M. Mathey
The application of the Monte Carlo technique to production planning and everyday economic decisionmaking in mine production management is demonstrated. The logic is detailed using an example of underground production with continuous miners (CMs) and truck haulage. It is argued that availability of equipment and personnel are the predominant variables influencing mine output and productivity and that those availabilities may be well represented by binomial probability distributions. The probabilistic model is implemented in a standard Excel® spreadsheet with Palisade's @Risk add-on to facilitate simulations. Starting from model calibration against data obtained from a mine's annual reports, some general interdependencies of availability, utilization, productivity, and costs of production processes are outlined. Finally, several possible options and their consequences as regards production improvements are explored.
论证了蒙特卡洛技术在矿山生产管理中的生产计划和日常经济决策中的应用。以连续采矿机(CM)和卡车运输的地下生产为例详细说明了逻辑。有人认为,设备和人员的可用性是影响矿山产量和生产力的主要变量,这些可用性可以用二项式概率分布很好地表示。概率模型在标准Excel®电子表格中实现,带有Palisade的@Risk插件,以便于模拟。从根据矿山年度报告中获得的数据进行模型校准开始,概述了生产过程的可用性、利用率、生产力和成本的一些一般相互依存关系。最后,探讨了生产改进方面的几种可能选择及其后果。
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引用次数: 0
A simulation model to study truck-allocation options 研究卡车分配方案的仿真模型
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-10 DOI: 10.17159/2411-9717/2100/2022
W. Zeng, E. Baafi, H. Fan
We present a discrete event simulator, TSJSim (Truck-Shovel JaamSim Simulator), for evaluating the stochastic and dynamic operational variables in a truck-shovel system. TSJSim offers four truck allocation strategies: Fixed truck assignment (FTA), Minimizing shovel production requirement (MSPR), Minimizing truck waiting time (MTWT), and Minimizing truck semi-cycle time (MTSCT) including the genetic algorithm (GA) optimization and the frozen dispatching algorithm (FDA) optimization rules. Multiple decision points along the haul routes for all the trucks close to the decision points were included in the model. The simulation results indicate that the trends associated with production tons and queuing time utilizing the four truck allocation strategies (MSPR, MTWT, FDA, and GA) all demonstrated similar patterns as the fleet size varied. As the system fleet size increased, the system production tons under these strategies at first increased significantly and then remained relatively constant; the queuing time relating to these strategies showed a positive relationship with the system fleet size. The bunching time decreased when the truck allocation strategies were applied in the model. In the simulated truck-shovel network system with multiple traffic intersections, by assigning the trucks at the intersections, both productivity and fleet utilization increased.
我们提出了一个离散事件模拟器,TSJSim(卡车-铲JaamSim模拟器),用于评估卡车-铲系统中的随机和动态操作变量。TSJSim提供了四种卡车分配策略:固定卡车分配(FTA)、最小化铲产量要求(MSPR)、最小化卡车等待时间(MTWT)和最小化卡车半周期时间(MTSCT),其中包括遗传算法(GA)优化和冻结调度算法(FDA)优化规则。模型中包含了运输路线上所有靠近决策点的卡车的多个决策点。仿真结果表明,随着车队规模的变化,四种卡车分配策略(MSPR、MTWT、FDA和GA)与生产吨数和排队时间相关的趋势都表现出相似的模式。随着系统船队规模的增加,在这些策略下的系统生产吨数首先显著增加,然后保持相对稳定;与这些策略相关的排队时间与系统车队规模呈正相关。在模型中采用卡车分配策略后,聚类时间明显缩短。在具有多个交叉口的模拟车铲网络系统中,通过在交叉口分配车辆,提高了车辆的生产率和车队利用率。
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引用次数: 1
The spillover effect of industrial action on the profitability of platinum mining companies 工业行动对铂矿企业盈利能力的溢出效应
IF 0.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-02-10 DOI: 10.17159/2411-9717/1647/2022
B. Ceki, M. Pududu, K. Mohajane
This study was aimed at determining the effects of industrial action on profitability in the South African platinum mining sector. We compared companies where employees engaged in industrial action (affected companies) to strike-free companies (competing companies). Industrial action refers to strikes by rock-drillers, as these strikes typically result in the shutdown of production at the mines affected. A t-statistics analysis of significant differences in revenue and earnings of affected and non-affected platinum companies was conducted using data from platinum mining companies listed on the Johannesburg Stock Exchange from 2011 to 2015. Contrary to international studies, which suggest that the spillover effects of industrial action positively affect competing companies, our findings show that profits in the platinum sector decrease significantly during strike periods for both affected and competing companies. The results indicate industrial action is a threat to the profitability of all companies, and that employee demands should be prioritized and negotiated before they result in industrial action. Improved dialogue between management, labour unions, and employees in the platinum mining industry is recommended. The study contributes to the scanty literature on the effect of industrial action on the profitability of mining companies in a developing economy.
这项研究的目的是确定工业行动对南非铂矿部门盈利能力的影响。我们比较了员工参与工业行动的公司(受影响的公司)和没有罢工的公司(竞争公司)。工业行动指的是钻探工人的罢工,因为这些罢工通常会导致受影响矿山的停产。利用2011 - 2015年在约翰内斯堡证券交易所上市的铂金矿业公司的数据,对受影响的铂金公司和未受影响的铂金公司的收入和收益进行了显著差异的t统计分析。与国际研究相反,这些研究表明,工业行动的溢出效应对竞争公司产生积极影响,我们的研究结果表明,在罢工期间,铂金行业的利润对受影响的公司和竞争公司都显著下降。结果表明,工业行动对所有公司的盈利能力都是一种威胁,员工的要求应该在导致工业行动之前得到优先考虑和谈判。建议改善铂采矿业管理层、工会和雇员之间的对话。这项研究对发展中经济体中工业行动对矿业公司盈利能力影响的文献匮乏作出了贡献。
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引用次数: 0
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Journal of The South African Institute of Mining and Metallurgy
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