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Characteristics and mechanism of persulfate activated by natural siderite for water disinfection 天然菱铁矿活化过硫酸盐用于水消毒的特性及机理
IF 2.3 Q2 Environmental Science Pub Date : 2022-08-19 DOI: 10.2166/wrd.2022.030
G. Li, Chaoyi Wang, Yingying Zhang, Hongyou Wan, Ming Dou, Hongbin Xu
In this study, low-cost siderite was used to activate peroxydisulfate (PDS, S2O82-)-inactivated Enterococcus faecalis to study the inactivation characteristics and mechanism of siderite/PDS. The results showed that the siderite/PDS had a better inactivation effect on Enterococcus faecalis at pH 3. The sterilization effect increases with the increase of siderite dosage, PDS concentration and temperature. The inactivation rate is decreased with the increase of initial bacterial concentration. Inorganic ions and natural organic matter (NOM) can inhibit the inactivation effect of this technology, and the inhibition intensity is NOM > HCO3− > NO3−. The free radical quenching test shows that HO• is the main oxidizing substance in the sterilization process of siderite/PDS technology. In addition, the main disinfection mechanism is highly reactive oxygen species destroying the cell wall of bacteria and releasing organic compounds in cells. After siderite was reused for four times, simply washing siderite would recover almost 80% of the removal of Enterococcus faecalis in siderite/PDS, indicating that siderite has the potential of recycling.
本研究采用低成本的菱铁矿活化过硫酸氢盐(PDS, S2O82-)灭活粪肠球菌,研究菱铁矿/PDS的灭活特性及机制。结果表明,在pH为3时,菱铁矿/PDS对粪肠球菌具有较好的灭活效果。灭菌效果随菱铁矿用量、PDS浓度和温度的增加而增加。随着初始细菌浓度的增加,失活率降低。无机离子和天然有机物(NOM)均能抑制该技术的失活效果,抑制强度为:NOM > HCO3−> NO3−。自由基淬火试验表明,在菱铁矿/PDS工艺灭菌过程中,HO•是主要的氧化物质。此外,主要的消毒机制是高活性氧破坏细菌的细胞壁,释放细胞中的有机化合物。菱铁矿重复利用4次后,对其进行简单洗涤,可回收菱铁矿/PDS中粪肠球菌去除率的近80%,说明菱铁矿具有回收利用的潜力。
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引用次数: 9
Microbial and chemical risk from reclaimed water use for residential irrigation 住宅灌溉中水的微生物和化学风险
IF 2.3 Q2 Environmental Science Pub Date : 2022-07-30 DOI: 10.2166/wrd.2022.014
J. Weidhaas, M. Olsen, J. McLean, N. Allen, L. Ahmadi, K. Duodu, R. Dupont
Arid and semi-arid locations are increasingly utilizing nontraditional irrigation water including reclaimed wastewater. Human health risk associated with reclaimed wastewater use was determined by testing reservoir, distribution line and home spigot water (n=190) and 14 types of vegetables and fruits (n=90) harvested from 5 home gardens for 7 waterborne pathogens, 47 antibiotic resistance genes and 12 pharmaceuticals and personal care products (PPCPs). Based on surveys of the residents’ use of the reclaimed wastewater, two exposure routes were modeled: irrigation of fruits and vegetables and drinking from irrigation hoses. Probabilistic quantitative microbial risk assessment indicated that consumption of raw vegetables and fruits exceeded a 0.015 benchmark illness rate due to adenovirus and enterococci. Chemical risk assessments indicated that consumption of tons of vegetables per day and hundreds to millions of gallons of water per day would be needed to reach an unacceptable risk among the 10 PPCPs detected in home spigot water, indicating de minimis risk from PPCPs. Eight different drug resistance gene families were detected in the water samples and crops indicating that antibiotic-resistant organisms are present on foods irrigated with reclaimed water containing pharmaceuticals. These results elucidate the combined risk from pathogens and PPCPs from reclaimed wastewater irrigation.
干旱和半干旱地区越来越多地利用非传统灌溉水,包括再生废水。通过测试蓄水池、配水管线和家用龙头水(n=190)以及从5个家庭花园收获的14种蔬菜和水果(n=90)中的7种水传播病原体、47种抗生素抗性基因和12种药品和个人护理产品,确定了与回收废水使用相关的人类健康风险。根据居民对再生废水使用情况的调查,建立了两种暴露途径的模型:水果和蔬菜灌溉和灌溉软管饮用。概率定量微生物风险评估表明,由于腺病毒和肠球菌,生蔬菜和水果的食用量超过了0.015的基准患病率。化学风险评估表明,在家庭自来水中检测到的10种PPCP中,每天需要消耗数吨蔬菜和数亿加仑水才能达到不可接受的风险,这表明PPCP的风险很小。在水样和作物中检测到八个不同的耐药性基因家族,这表明用含有药物的再生水灌溉的食物中存在抗生素耐药性生物。这些结果阐明了来自再生废水灌溉的病原体和PPCP的综合风险。
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引用次数: 8
Safe water reuse through a quasi-natural water cycle 通过准自然水循环安全用水回用
IF 2.3 Q2 Environmental Science Pub Date : 2022-07-27 DOI: 10.2166/wrd.2022.039
Xiaochang C. Wang
Safe water reuse usually means the provision of reclaimed water with its quality meeting the criteria for safeguarding human health and aquatic ecology. Regarding this, people often overstress the technological magic in terms of hazardous substances removal by engineered processes while ignoring the utilization of nature's power to provide an additional barrier for safety control. Based on an understanding of the function of the hydrological cycle to secure water quality and the fact that water reuse is through a water loop, the author presented his viewpoint on creating a quasi-natural water cycle for water reuse. Existing data showed the remarkable effects of emerging pollutants removal and associated reduction of biotoxicities from the reclaimed water during open-storage under a quasi-natural condition. Adsorption by soil particles, sunlight-induced photolysis and purification by aquatic life were thought to be the major actions contributing to effective water quality improvement in a quasi-natural manner. Safe water reuse through a quasi-natural water cycle can thus be a recommendable strategy for system design in accordance with the purposes of water use.
安全回用水通常是指提供质量符合保障人体健康和水生生态标准的再生水。关于这一点,人们常常过分强调通过工程过程去除有害物质的技术魔力,而忽略了利用大自然的力量为安全控制提供额外的障碍。基于对水循环保障水质功能的认识,以及水回用是通过水循环进行的这一事实,作者提出了创建准自然水循环进行水回用的观点。现有数据表明,在准自然条件下露天储存再生水对新出现的污染物去除和相关生物毒性的降低效果显著。土壤颗粒的吸附、阳光诱导的光解作用和水生生物的净化作用被认为是准自然方式有效改善水质的主要作用。因此,通过准自然水循环的安全水回用可以成为根据用水目的进行系统设计的可取策略。
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引用次数: 7
Social knowledge, attitudes, and perceptions on wastewater treatment, technologies, and reuse in Tanzania 坦桑尼亚关于废水处理、技术和再利用的社会知识、态度和看法
IF 2.3 Q2 Environmental Science Pub Date : 2022-06-14 DOI: 10.2166/wrd.2022.096
Gerubin Liberath Msaki, K. Njau, A. Treydte, T. Lyimo
This study assessed the social knowledge, attitude, and perceptions (KAPs) on wastewater treatment, the technologies involved, and its reuse across different wastewater treatment areas in four regions of Tanzania. We used both quantitative and qualitative data collection methods in a household-level questionnaire (n=327) with structured and semi-structured questions, which involved face-to-face interviews and observation. Our results show that social KAPs surrounding wastewater treatment and reuse were sufficient based on KAP scores achieved from asked questions. However, the general knowledge on treatment technologies, processes, and reuse risks was still low. Of the respondents, over 50% approved using treated wastewater in various applications, while the majority (93%) were reluctant if the application involved direct contact with the water. Furthermore, over 90% of interviewees did not know the technologies used to treat wastewater and the potential health risks associated with its use (59%). Multivariate analysis of variance revealed significant differences (P<0.05) in the KAPs on treated wastewater across different studied demographic variables, i.e., age, sex, and education level. Therefore, we recommend that more effort be spent on providing public education about the potential of wastewater treatment and existing technologies in order to facilitate their adoption for the community's and environment's benefit.
本研究评估了坦桑尼亚四个地区不同废水处理区对废水处理、相关技术及其再利用的社会知识、态度和看法(KAP)。我们在一份家庭层面的问卷(n=327)中使用了定量和定性数据收集方法,其中包括结构化和半结构化问题,包括面对面访谈和观察。我们的研究结果表明,基于提问的KAP得分,围绕废水处理和再利用的社会KAP是足够的。然而,关于处理技术、工艺和再利用风险的一般知识仍然很低。在受访者中,超过50%的人赞成在各种应用中使用处理过的废水,而如果应用涉及直接接触水,大多数人(93%)则不愿意。此外,超过90%的受访者不知道用于处理废水的技术以及与使用废水相关的潜在健康风险(59%)。多元方差分析显示,在不同的研究人口统计学变量(即年龄、性别和教育水平)中,处理过的废水的KAP存在显著差异(P<0.05)。因此,我们建议加大力度,向公众提供有关废水处理潜力和现有技术的教育,以促进采用这些技术,造福社区和环境。
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引用次数: 3
Continuous and efficient oil/water separation by special wettability granular filter media 采用特殊的润湿性颗粒过滤介质,实现连续高效的油水分离
IF 2.3 Q2 Environmental Science Pub Date : 2022-06-01 DOI: 10.2166/wrd.2022.102
Zhang Hongwei, Qi Junye, Che Yinglong, Man Shide, Liu Jianlin, Wei Bigui

To improve the separation efficiency of the oil/water mixture and simplify the separation process, a superhydrophilic/underwater superoleophobic quartz sand filter media (PR@QS) was prepared by coating potato residue onto the quartz sand surface, and an oil/water mixture separator containing two horizontally placed filter columns and one inlet chamber was proposed. One filter column was filled with the PR@QS, and the other column was filled with the superhydrophobic/superoleophilic quartz sand filter media. The experimental results showed that the separation efficiencies of five kinds of oil/water mixtures (petroleum ether, engine oil, diesel oil, cyclohexane, and methylene chloride) were up to 99.4%. Except for engine oil, the hydraulic conductivities of the other four oils and water are all greater than 3.5 m/h. When the filter layer is invaded by the lyophobic liquid, its filtration performance can be restored by backwashing. In summary, the separator can separate oil/water mixtures continuously and efficiently without filter contamination. Therefore, it has a broad prospect for practical application.

为提高油水混合物的分离效率,简化分离过程,在石英砂表面涂覆马铃薯渣制备了超亲水/水下超疏油石英砂滤料(PR@QS),并设计了一种包含两个水平放置的过滤柱和一个进口室的油水混合物分离器。一个过滤柱内填充PR@QS,另一个过滤柱内填充超疏水/超亲油石英砂过滤介质。实验结果表明,5种油水混合物(石油醚、机油、柴油、环己烷、二氯甲烷)的分离效率可达99.4%。除机油外,其余四种油和水的水力导率均大于3.5 m/h。当滤层被疏水液体侵入时,可通过反冲洗恢复滤层的过滤性能。总之,分离器可以连续有效地分离油/水混合物,而不会污染过滤器。因此,具有广阔的实际应用前景。
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引用次数: 0
Quantification and health risk assessment of nitrate in southern districts of Tehran, Iran 伊朗德黑兰南部地区硝酸盐的定量和健康风险评估
IF 2.3 Q2 Environmental Science Pub Date : 2022-05-23 DOI: 10.2166/wrd.2022.007
S. Kalteh, Farshad Hamidi, Mahdi Ahmadi Nasab, Narges Mohseni Gharibdoosti, Mohammad Rezvani Ghalhari, Mina Parvizishad, A. Mahvi
Nitrate is a common contaminant of drinking water. Due to its adverse health effects, this study aimed to determine nitrate levels in six southern districts of Tehran. A total of 148 samples were taken from tap waters. In 84.46% (n = 125) of the samples, the nitrate concentration was below national and WHO limits (50 mg/L); however, 15.54% (n = 23) were in violation of the criteria. The total mean concentration of nitrate was 36.15 mg/L (±14.74) ranging from 4.52 to 80.83 mg/L. The overall hazard quotient (HQ) for age groups were ordered as Children (1.71) > Infants (1.24) > Teenagers (1.2) > Adults (0.96). In all districts, the HQ values for infants and children groups were greater than 1, indicating potential adverse health risks. In teenagers age group, only the HQ estimations of districts 10 (HQ = 0.93) and 11 (HQ = 0.74) were lower than 1 and in adults age group, the estimated HQ values for districts were lower than 1 with the exception for district 19 (HQ = 1.19). The sensitivity analysis (SA) showed that nitrate content plays a major role in the value of the assessed risk.
硝酸盐是饮用水中常见的污染物。由于其对健康的不利影响,本研究旨在确定德黑兰南部六个地区的硝酸盐水平。在自来水中抽取了148个样本。84.46% (n = 125)的样品硝酸盐浓度低于国家和WHO标准(50 mg/L);但有15.54% (n = 23)的患者不符合标准。硝酸盐总平均浓度为36.15 mg/L(±14.74),范围为4.52 ~ 80.83 mg/L。各年龄组的总危险系数(HQ)为:儿童(1.71)、婴儿(1.24)、青少年(1.2)、成人(0.96)。各区婴儿和儿童组的HQ值均大于1,表明存在潜在的不良健康风险。在青少年年龄组中,只有10区(HQ = 0.93)和11区(HQ = 0.74)的HQ估计值低于1;在成人年龄组中,除19区(HQ = 1.19)外,其余各区的HQ估计值均低于1。敏感性分析(SA)表明,硝酸盐含量对风险评估值起主要作用。
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引用次数: 1
Downscaling reverse osmosis for single-household wastewater reuse: towards low-cost decentralised sanitation through a batch open-loop configuration 减少单户废水回用的反渗透:通过批量开环配置实现低成本分散式卫生设施
IF 2.3 Q2 Environmental Science Pub Date : 2022-04-15 DOI: 10.2166/wrd.2022.084
C. Davey, N. Thomas, E. McAdam
There is a significant demand for water recycling in low-income countries. However, wastewater infrastructure is primarily decentralised, necessitating the development of affordable household-scale reclamation technology. In this study, a batch open-loop reverse osmosis (RO) system is therefore investigated as a low-cost clean water reclamation route from highly saline concentrated blackwater. In a single-stage configuration, increasing feed pressure from 10 to 30 bars improved selective separation at water recovery exceeding 85%, whereas lower cross-flow velocity improved product recovery, reducing specific permeate energy demand from 21 to 4.8 kWh m−3. Rejection achieved for total phosphorous (99%), chemical oxygen demand (COD, 96%), and final pH (8.7) of the RO permeate was compliant with the ISO30500 reuse standard for discharge. However, the rejection of total nitrogen in the RO permeate was non-compliant with the reuse standard due to the transmission of low-molecular weight (MW) uncharged organic compounds. It is suggested that rejection may be improved by increasing feed pressure to rebalance selectivity but may also be controlled by reducing fluid residence time (storage) to constrain the hydrolysis of urea. The economic analysis identified that a high-pressure 1812 element cost of ∼US$30 meets the sanitation affordability index of US$0.05 capita−1 day−1. However, the unit cost of a high-pressure feed pump must be reduced to ∼US$500 to obtain an affordable system cost. These unit costs can be achieved by manufacturing 1812 elements at economies of scale, and by adopting pumping solutions that have been developed for other applications requiring high pressures and low flows. Overall, our findings suggest that RO in the batch open-loop configuration has the potential to deliver affordable and safe water production from blackwater in a decentralised (single-household) context.
低收入国家对水循环利用的需求很大。然而,废水基础设施主要是分散的,因此需要开发负担得起的家庭规模的回收技术。因此,本研究研究了间歇式开环反渗透(RO)系统作为高盐浓缩黑水的低成本清洁水回收途径。在单级配置中,将进料压力从10 bar提高到30 bar,提高了选择性分离,水采收率超过85%,而降低交叉流速提高了产品采收率,将比渗透能量需求从21 kWh m−3降低到4.8 kWh m−3。反渗透膜的总磷(99%)、化学需氧量(COD, 96%)和最终pH值(8.7)均符合ISO30500排放再利用标准。然而,由于低分子量(MW)不带电有机化合物的传输,反渗透膜中总氮的截留不符合再利用标准。建议通过增加进料压力来重新平衡选择性来改善排异,但也可以通过减少流体停留时间(储存)来限制尿素的水解来控制。经济分析表明,高压1812元素成本约30美元符合卫生负担能力指数0.05美元人均- 1天- 1。然而,高压给水泵的单位成本必须降低到约500美元,才能获得负担得起的系统成本。这些单位成本可以通过规模经济制造1812个元件,以及采用为其他需要高压低流量的应用开发的泵送解决方案来实现。总体而言,我们的研究结果表明,批量开环配置中的RO有可能在分散(单户)环境中从黑水中提供负担得起的安全用水。
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引用次数: 5
A pilot-scale anaerobic moving-bed biofilm reactor with PVA gel beads as media for the treatment of fish canning industry wastewater PVA凝胶珠厌氧移动床生物膜反应器处理鱼罐头工业废水的中试研究
IF 2.3 Q2 Environmental Science Pub Date : 2022-04-12 DOI: 10.2166/wrd.2022.090
Akarawin Jirasaranporn, Krittayapong Jantharadej, K. Wongwailikhit, C. Chawengkijwanich, Jenyuk Lohwatcharin, B. Suwannasilp
This research aims to investigate the performance of a pilot-scale anaerobic moving-bed biofilm reactor (AnMBBR) using PVA gels as media for the treatment of real wastewater from a fish canning factory. The chemical oxygen demand (COD) removal efficiencies at different organic loading rates (OLRs) were investigated at 3.0, 4.3, 6.5, and 8.7 kg COD/m3day by adjusting the flow rates to 350, 500, 750 and 1,000 L/d, respectively. The soluble COD removal efficiencies of the system at flow rates of 350, 500, 750, and 1,000 L/d were 81.0 ± 12.4%, 76.8 ± 8.2%, 74.7 ± 6.2%, and 70.6 ± 12.4%, respectively. According to the residence time distribution (RTD) tests at the highest and lowest flow rates, the mean residence times of both flow rates were significantly higher than the theoretical residence time, indicating very strong external recirculation inside the AnMBBR. The results suggest a 3-pass flow pattern through the AnMBBR. From 16S rRNA gene amplicon sequencing (MiSeq, Illumina) and scanning electron microscopy (SEM) analysis, Methanosaeta, acetoclastic methanogens, were the predominant microorganisms in the system. Most of the microorganisms were located within a 1.994 ± 0.266 mm depth from the PVA gel surface, with two distinct layers.
本研究旨在研究以PVA凝胶为介质的中试厌氧移动床生物膜反应器(AnMBBR)处理鱼罐头厂实际废水的性能。通过将流速分别调整为350、500、750和1000L/d,研究了在3.0、4.3、6.5和8.7kgCOD/m3的不同有机负荷率下化学需氧量(COD)的去除效率。在流量为350、500、750和1000L/d时,该系统的可溶性COD去除率分别为81.0±12.4%、76.8±8.2%、74.7±6.2%和70.6±12.4%。根据最高和最低流速下的停留时间分布(RTD)测试,两种流速的平均停留时间都显著高于理论停留时间,表明AnMBBR内部有非常强的外部再循环。结果表明,通过AnMBBR的流动模式为三级。从16S rRNA基因扩增子测序(MiSeq,Illumina)和扫描电子显微镜(SEM)分析来看,甲烷菌是该系统中的主要微生物。大多数微生物位于距离PVA凝胶表面1.994±0.266 mm的深度内,具有两个不同的层。
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引用次数: 3
Effect of organic load regulation on anaerobic digestion performance and microbial community of solar-assisted system of food waste 有机负荷调节对食物垃圾太阳能辅助系统厌氧消化性能和微生物群落的影响
IF 2.3 Q2 Environmental Science Pub Date : 2022-03-29 DOI: 10.2166/wrd.2022.107
X. Zhen, Miao Luo, Haiying Dong, L. Fang, Weiwei Wang, Lei Feng, Qin Yu
The semi-continuous digestion experiment of food waste was carried out based on a solar-assisted heat anaerobic digestion reactor. The effects of organic load regulation (OLR of 2.0, 4.0, 6.0 and 7.0 kg m−3 d−1 VS (volatile solid)) on methane production, physical and chemical parameters, and microbial community structure were studied. The results showed that 6.0 kg m−3 d−1 VS could achieve the optimal methane production as the anaerobic digestion limit OLR of kitchen waste. At this stage, the accumulation of organic acids in the reactor led to a great fluctuation of pH. Artificial alkali regulation could restore the stable operation of the reactor, but the reactor could not withstand the OLR shock of 7.0 kg m−3 d−1 VS. In addition, Qualcomm sequencing results showed that microorganisms showed high functional concentration and poor community richness under low OLR, and increasing OLR could promote microbial richness. At the same time, the Methanosaeta of acetic acid methanogens was relatively abundant in the low OLR stage, while the hydrogen trophic methanogenic bacteria Methanoregula and Methanospirillum showed high activity in the high OLR stage, but the excessive reproduction of acidogenic bacteria in the digestive system would affect the stability of the archaea community when the OLR was too high.
在太阳能辅助加热厌氧消化反应器上进行了餐厨废弃物的半连续消化实验。研究了有机负荷调节(OLR为2.0、4.0、6.0和7.0 kg m−3 d−1 VS(挥发性固体))对甲烷产量、物理化学参数和微生物群落结构的影响。结果表明,6.0 kg m−3 d−1 VS可达到餐厨垃圾厌氧消化极限OLR的最佳甲烷产量。在此阶段,有机酸在反应器中的积累导致pH值的大幅波动。人工碱调节可以恢复反应器的稳定运行,但反应器无法承受7.0 kg m−3 d−1 VS的OLR冲击。此外,高通测序结果表明,在低OLR条件下,微生物表现出较高的功能浓度和较差的群落丰富度,增加OLR可以促进微生物丰富度。同时,乙酸产甲烷菌的甲烷菌在低OLR阶段相对丰富,而氢营养产甲烷菌Methanogula和Methanospirillum在高OLR阶段表现出较高的活性,但当OLR过高时,产酸菌在消化系统中的过度繁殖会影响古菌群落的稳定。
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引用次数: 4
Acid-activated bentonite blended with sugarcane bagasse ash as low-cost adsorbents for removal of reactive red 198 dyes 酸活化膨润土与蔗渣灰混合作为低成本吸附剂去除活性红198染料
IF 2.3 Q2 Environmental Science Pub Date : 2022-03-18 DOI: 10.2166/wrd.2022.056
T. Adane, Sintayehu Mekuria Hailegiorgis, E. Alemayehu
The present research work investigated the removal efficiency of acid-activated bentonite blended with a sugarcane bagasse ash (SCBA) adsorbent for the removal of reactive red 198 (RR198) from a synthetic dye solution. The effect of the adsorption parameters of bentonite on SCBA blending ratio, dye solution pH, adsorption contact, adsorbent dosage, and initial dye concentration was investigated, and the parameters were optimized for maximum RR198 removal from the synthetic dye solution. At an optimum condition of 1:1 bentonite to the SCBA blending ratio, a solution pH of 2, 3.7 g/L of adsorbent dosage, and 15 mg/L of initial dye concentration 150 min of adsorption time, the properties of adsorbents such as adsorbent specific surface area, crystalline phase structure, functional groups, and surface morphologies of the adsorbents were investigated. At optimum conditions, 97% RR198 removal efficiency of the adsorbent was achieved. In order to determine adsorption kinetics and isotherm models, different adsorption models were employed. It was observed that the adsorption of the RR198 dye into the acid-activated bentonite blended with the SCBA adsorbent was represented well by the Langmuir isotherm model and the adsorption kinetics order was found to be the pseudo-second order.
研究了酸活化膨润土与甘蔗渣(SCBA)吸附剂混合对合成染料溶液中活性红198 (RR198)的去除效果。考察了膨润土的吸附参数对SCBA掺比、染料溶液pH、吸附接触、吸附剂用量和初始染料浓度的影响,并优化了吸附参数,以最大限度地去除合成染料溶液中的RR198。在膨润土与SCBA配比为1:1、溶液pH为2、吸附剂用量为3.7 g/L、初始染料浓度为15 mg/L、吸附时间为150 min的最佳条件下,考察了吸附剂的比表面积、晶相结构、官能团和表面形貌等性能。在最佳条件下,吸附剂的RR198去除率达到97%。为了确定吸附动力学和等温线模型,采用了不同的吸附模型。结果表明,含SCBA吸附剂的酸活化膨润土对RR198染料的吸附符合Langmuir等温线模型,吸附动力学为准二级。
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引用次数: 6
期刊
Journal of Water Reuse and Desalination
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