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Influence of Hydrogen on the Failure Mechanism of Standard Duplex Stainless Steel X2CrNiMoN22-5-3 Exposed to Corrosion Fatigue 氢对暴露于腐蚀疲劳的标准双相不锈钢 X2CrNiMoN22-5-3 失效机理的影响
Pub Date : 2024-07-03 DOI: 10.4028/p-QJf7Bl
M. Wolf, A. Pfennig
IIn a geothermal environment, cathodic protection is employed to improve resistance against corrosion fatigue. However, during the cathodic reactions under applied potential, hydrogen is generated and assimilated, leading to a reduced lifetime expectancy of high-alloyed steels. The corrosion fatigue mechanism of a standard duplex stainless steel X2CrNiMoN22-5-3 (1.4462) specimen loaded with hydrogen was studied in a corrosion chamber specifically designed for the purpose, surrounded by the electrolyte of the Northern German Basin at 369 K. The microstructural reactions resulting in hydrogen incorporation significantly decrease the number of cycles to failure of the specimen. This reduction is attributed to hydrogen enhancing crack propagation and causing early failure, primarily due to the deterioration of the mechanical properties of the ferritic phase rather than corrosion reactions or corrosive degradation.
在地热环境中,采用阴极保护可提高抗腐蚀疲劳的能力。然而,在外加电位下的阴极反应过程中,会产生并同化氢,从而导致高合金钢的预期寿命缩短。在专门为此设计的腐蚀室中,在 369 K 的德国北部盆地电解液的包围下,研究了加载氢的标准双相不锈钢 X2CrNiMoN22-5-3 (1.4462) 试样的腐蚀疲劳机理。这种减少归因于氢促进了裂纹扩展并导致早期失效,这主要是由于铁素体相机械性能的恶化,而不是腐蚀反应或腐蚀降解。
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引用次数: 0
Crystallinity Study of Electrodeposited SnO2 on FTO Substrate FTO 基底上电沉积二氧化硒的结晶度研究
Pub Date : 2024-04-18 DOI: 10.4028/p-5z5lce
Uddipan Agasti, S. Karmakar, S. Kundu, Mili Sarkar, Sayan Chatterjee
Tin oxide (SnO2) holds significance as an n-type semiconductor metal oxide, finding diverse applications across various fields. It has optimal properties as a gas sensing material, fuel cells, batteries, and so on. The main objective of this research is to synthesize SnO2 thin films at a low-cost, easily replicable method and study its crystallographic properties. Here, the thin film was prepared by electrodeposition using tin sulfate, tartaric acid, and potassium nitrate at 2.1 pH followed by annealing the obtained thin film at 773 K. The whole process was conducted at 300 K without any external DC. The synthesized substrate was crystallographic properties were studied using X-ray diffraction. The average crystallite grain size was evaluated to be around 19 nm with degree of crystallinity close to 48.3%. These outcomes show that the method used to create thin films was in an appropriate direction.
氧化锡(SnO2)作为一种 n 型半导体金属氧化物,在各个领域都有广泛的应用。它具有作为气体传感材料、燃料电池、电池等的最佳特性。本研究的主要目的是以低成本、易复制的方法合成二氧化锰薄膜,并研究其晶体学特性。在这里,薄膜是通过使用硫酸亚锡、酒石酸和硝酸钾在 pH 值为 2.1 的条件下进行电沉积制备的,然后将获得的薄膜在 773 K 下退火。用 X 射线衍射法研究了合成基底的晶体学特性。平均晶粒大小约为 19 纳米,结晶度接近 48.3%。这些结果表明,制造薄膜的方法是正确的。
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引用次数: 0
Processing and Application of Engineering Materials 工程材料的加工与应用
Pub Date : 2024-04-18 DOI: 10.4028/b-7dfrjt
Bruno Castanie, Ramesh K. Agarwal, Sandip A. Kale, Shanmugam Thillikkani
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引用次数: 0
Evaluation of Recycled Polypropylene (PP) Made from Plastic Cups as Filaments for Additive Manufacturing 评估将塑料杯制成的回收聚丙烯 (PP) 用作增材制造丝材的情况
Pub Date : 2024-04-18 DOI: 10.4028/p-p4o9jk
Ria Grace P. Abdon, Shanlaine F. Barbastro, Kian James C. Francisco, Cedric John D. Quicay
Plastic waste is one of the most problematic wastes produced daily. A potential solution to this problem is to recycle and convert them into filaments for 3D printing. This study aims to prepare recycled polypropylene (rPP) from plastic cups and convert them into filaments for 3D printing using an extrusion process. It also aims to produce a quality printout and compare its mechanical properties with a commercial filament, polylactic acid (PLA). In this study, rPP cups were collected and treated to undergo an extrusion process. A temperature calibration tower was then fabricated to determine the ideal temperature settings for printing. Lastly a total of 24 tensile and flexural specimens were printed utilizing both rPP and PLA, facilitating a comparative evaluation of their mechanical properties. Results showed that the best extruder heater settings were 240°C, 235°C, 210°C, and 180°C from heat zone 1 to 4. The ideal printing temperature for rPP material was established at 230°C. The application of polypropylene packaging tapes, hairspray, and incorporation of a brim around the model proved effective in mitigating warpage during the printing process. Mechanical testing indicated an average tensile strength and flexural strength of 24.5 MPa and 45 MPa, respectively. In contrast the average tensile strength and flexural strength for PLA was measured at 43 MPa and 80 MPa respectively. It is clear that PLA demonstrated higher outcomes, but it lacks durability and flexibility exhibited by rPP.
塑料垃圾是每天产生的最棘手的废物之一。解决这一问题的一个潜在办法是回收塑料杯并将其转化为 3D 打印用长丝。本研究旨在从塑料杯中制备再生聚丙烯(rPP),并通过挤出工艺将其转化为 3D 打印用长丝。它还旨在生产高质量的打印件,并将其机械性能与商用长丝聚乳酸(PLA)进行比较。在这项研究中,收集了 rPP 杯,并对其进行了挤压处理。然后制作了一个温度校准塔,以确定理想的打印温度设置。最后,利用 rPP 和 PLA 印刷了总共 24 个拉伸和弯曲试样,以便对它们的机械性能进行比较评估。结果表明,挤出机加热器的最佳设置为热区 1 至热区 4 的 240°C、235°C、210°C 和 180°C。在印刷过程中,使用聚丙烯包装带、发胶和在模型周围加装帽檐可有效减少翘曲。机械测试表明,平均拉伸强度和弯曲强度分别为 24.5 兆帕和 45 兆帕。而聚乳酸的平均拉伸强度和弯曲强度分别为 43 兆帕和 80 兆帕。显然,聚乳酸具有更高的性能,但它缺乏 rPP 所表现出的耐久性和柔韧性。
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引用次数: 0
Development and Characterization of a Micro-Concrete Based on Wood Waste from Sawmills 基于锯木厂木材废料的微混凝土的开发与表征
Pub Date : 2024-04-18 DOI: 10.4028/p-syj2nc
Rachel Raïssa Ngono Mvondo, René Oum Lissouck, Sophie Grigoletto
An experimental study was carried out to evaluate the feasibility of using concrete compositions containing waste wood for structural and non-structural building applications. First, the inert and wood aggregates used in the composite design were characterized. Five compositions containing a reference, 50% and 100% of wood particles were then produced and characterized in terms of physical and mechanical performance (e.g., apparent density, abrasion, compressive strength, and flexural strength). The selected specimens were used for additional experimental tests. These included water absorption and thermal tests. Increasing wood waste content considerably lower compressive and flexural strengths while improving the thermal insulation quality of wood waste-cement composite. The durability assessment of selected compositions further showed that the abrasion resistance of manufactured specimen decreased by adding wood waste in the cement matrix while there was an increase of the capillarity absorption coefficients. It appears that the incorporation of waste wood particles into mortars decrease their thermal conductivities to 0.3 W/mK. The use of wood waste treated by a lime solution improves the studied properties.
我们开展了一项实验研究,以评估在结构性和非结构性建筑应用中使用含废旧木材的混凝土成分的可行性。首先,对复合设计中使用的惰性和木质骨料进行了鉴定。然后生产了五种含有参考、50% 和 100%木质颗粒的组合物,并对其物理和机械性能(如表观密度、耐磨性、抗压强度和抗折强度)进行了表征。选定的试样用于其他实验测试。这些试验包括吸水性和热试验。增加木质废料的含量大大降低了抗压强度和抗折强度,同时提高了木质废料-水泥复合材料的隔热性能。对所选成分进行的耐久性评估进一步表明,在水泥基质中添加木质废料后,制造试样的耐磨性下降,而毛细管吸收系数却增加了。看来,在灰泥中加入废木屑会将其导热系数降低到 0.3 W/mK。使用经石灰溶液处理的废木料可改善所研究的特性。
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引用次数: 0
Experimental and Numerical Study of the Physico-Hygrothermal Behavior of Two Tropical Wood Species 两种热带木材的物理热学行为的实验和数值研究
Pub Date : 2024-04-18 DOI: 10.4028/p-xsva64
Carlos A. Houngbeme, A. Houngan, Armand A. Djossou
In the first stage. an integral saturation test of lignocellulosic materials was carried out on samples of wood under the control of a previously established theoretical basis. At the end of this test. parameters such as the porosity at saturation with water. the basal density. the total volume shrinkage. the linear shrinkages. the density at the saturation of the samples are deduced. The second stage of this work is based on the exploitation of the hot tape method to achieve the thermophysical properties of wood samples over a range of humidity levels from 0% to 60%. The last stage of this research consisted in developing in the laboratory a device for controlling the saturation rate of steam in order to determine the adsorption/desorption isotherms. the mass diffusivity and the water capacity of these same wood species at various temperature. The counting of the results resulting from these tests has pointed out. among other things. that gmelia arborea is a more hygroscopic. lighter and more thermally insulating wood than afzelia wood. It is also noted that the two species of wood have average shrinkage. anisotropy and nervousness suggesting good stability in service. It is also noticed that equilibrium moisture sorption by these species increases with increasing relative humidity at constant temperature. but decreases slightly as temperature increases at constant humidity. In short . this work reinforces the database on tropical woods by providing in particular more local measurements. allowing the reliable dimensioning of wooden structures.
在第一阶段,根据之前建立的理论基础,对木质纤维素材料样本进行了整体饱和度测试。测试结束后,将推导出各种参数,如水饱和时的孔隙率、基本密度、总体积收缩率、线性收缩率、样品饱和时的密度。这项工作的第二阶段是利用热胶带方法,在 0% 至 60% 的湿度范围内测定木材样本的热物理性质。研究的最后一个阶段是在实验室中开发一种控制蒸汽饱和率的装置,以确定这些木材在不同温度下的吸附/解吸等温线、质量扩散率和水容量。对这些测试结果的统计表明,除其他外,菠萝格比阿夫榉木更吸湿、更轻、更隔热。还注意到,这两种木材的收缩率、各向异性和紧张性都很平均,这表明它们在使用中具有良好的稳定性。还注意到,在恒温条件下,这些树种的平衡吸湿性随相对湿度的增加而增加,但在恒湿条件下,随着温度的增加,平衡吸湿性略有下降。总之,这项工作通过提供更多的本地测量数据,加强了热带木材数据库,从而能够可靠地确定木结构的尺寸。
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引用次数: 0
Modeling and Simulation of Friction Stir Welding of Aluminum and Magnesium Alloys Using Finite Element Analysis 利用有限元分析对铝合金和镁合金的搅拌摩擦焊接进行建模和模拟
Pub Date : 2024-04-18 DOI: 10.4028/p-47wkms
Dame Alemayehu Efa, E. M. Gutema, H. Lemu, Mahesh Gopal
The aviation and automobile sectors have witnessed significant expansion and demand for lightweight metals. The friction stir welding (FSW) procedure is used for joining lightweight and low melting temperature materials. A Finite Element Analysis (FEA) utilising COMSOL® Multiphysics 6.0 software is utilised in this article to combine dissimilar metals AA6061-T6 and Mg AZ31-B, and their thermo-mechanical characteristics are explored. The peak temperature was observed to increase to 448K and 928K when the coefficient of friction (COF) increased from 0.01 to 0.4, while other parameters remained constant. When the tool rotational speed is increased to 500, 600, or 700 rpm, the peak temperature climbs to 658 K, 706 K, and 759 K, while all other parameters stay constant. When the welding speed is increased, the peak temperature reduces from 665K, 649K, and 638K to 45mm/min, 60mm/min, and 75mm/min, with all other parameters remained constant in this study. The peak temperature climbed to 632K, 684K, and 759K when the axial force increased to 10 kN, 15 kN, and 20 kN, respectively, which is a tolerable temperature less than the point of melting of materials. Peak temperatures increase to 628K, 630K, and 635K when the shoulder-to-pin diameter ratio increases to 2.5, 3.0 and 3.5 with all other parameters remaining constant. As a result, the peak temperature is directly related to tool rotational speed, coefficient of friction, axial force, and shoulder-to-pin diameter ratio, whereas welding speed is inversely proportional.
航空和汽车行业对轻质金属的需求大幅增长。搅拌摩擦焊 (FSW) 程序用于连接轻质和低熔点材料。本文利用 COMSOL® Multiphysics 6.0 软件进行有限元分析 (FEA),将异种金属 AA6061-T6 和 Mg AZ31-B 结合在一起,并探讨了它们的热机械特性。在其他参数保持不变的情况下,当摩擦系数(COF)从 0.01 增加到 0.4 时,峰值温度分别上升到 448K 和 928K。当工具转速增加到 500、600 或 700 rpm 时,峰值温度上升到 658 K、706 K 和 759 K,而其他参数保持不变。当焊接速度提高到 45mm/min、60mm/min 和 75mm/min 时,峰值温度分别从 665K、649K 和 638K 降至 665K、649K 和 638K,其他参数保持不变。当轴向力增加到 10 kN、15 kN 和 20 kN 时,峰值温度分别升至 632K、684K 和 759K,这是低于材料熔点的可承受温度。当肩针直径比增加到 2.5、3.0 和 3.5,而其他参数保持不变时,峰值温度分别升至 628K、630K 和 635K。因此,峰值温度与工具转速、摩擦系数、轴向力和肩针直径比直接相关,而与焊接速度成反比。
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引用次数: 0
Thermoelectric Properties of Spray Coated n-Type PEDOT:PSS Film 喷涂 n 型 PEDOT:PSS 薄膜的热电性能
Pub Date : 2024-04-18 DOI: 10.4028/p-so3x5d
Cyril O. Ugwuoke, Ahmed Abd El-Moneim, Mohsen Ghali
Inorganic thermoelectric (TE) materials have gained significant attention because of their salient properties. However, they possess some significant drawbacks, including high production costs, high heat loss, and fragility. Recently, Organic conducting polymers presented a promising platform as an alternative TE material because of their great mechanical flexibility, high stretchability, and environmental friendliness. In this work, we report for the first time on the TE properties of n-PEDOT:PSS film prepared using spray coating technique. The structural, optical and TE properties of the obtained n-PEDOT:PSS thin film was investigated using X-ray diffraction spectroscopy, UV-vis spectroscopy and Seebeck coefficient measurement systems, respectively. The n-PEDOT:PSS layer showed excellent optical properties with a band gap ranges from 3.91 to 3.78. In addition, the Seebeck coefficient and power factor (PF) were obtained to be 1096.77 µVK-1 and 298.59 µWm-1K-2 respectively, making n-PEDOT:P PSS to be regarded as efficient TE material.
无机热电(TE)材料因其突出的特性而备受关注。然而,它们也有一些明显的缺点,包括生产成本高、热损耗大和易碎。最近,有机导电聚合物因其良好的机械柔韧性、高伸展性和环境友好性,成为一种很有前途的热电半导体材料替代平台。在这项研究中,我们首次报道了利用喷涂技术制备的 n-PEDOT:PSS 薄膜的 TE 特性。利用 X 射线衍射光谱、紫外可见光谱和塞贝克系数测量系统分别研究了所制备 n-PEDOT:PSS 薄膜的结构、光学和 TE 性能。n-PEDOT:PSS 层显示出优异的光学特性,其带隙范围为 3.91 至 3.78。此外,塞贝克系数和功率因数(PF)分别为 1096.77 µVK-1 和 298.59 µWm-1K-2,使 n-PEDOT:PSS 成为高效 TE 材料。
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引用次数: 0
Comparative Analysis of Local Materials Effects on Two Buildings Thermal Behaviours in Sahelian Climate 萨赫勒气候下当地材料对两栋建筑热性能影响的对比分析
Pub Date : 2024-04-18 DOI: 10.4028/p-l3tgxq
Felicité Ronelngar Modjinguem, Malloum Soultan, Jacques Jay, Michel Querry
The present work focuses on the effect of local materials on the energy performance and thermal comfort of residential and tertiary buildings in the Sahelian climate. Within the framework of the CABET project (Construction Alternative à Basse Energie au Tchad), two buildings were built, one in compacted and additivated raw earth bricks, the other in concrete blocks. These two buildings of same dimensions without floor and single-room were instrumented with temperature and relative humidity sensors since 2019. A weather station is used to monitor outdoor condition. By comparing the experimental data, differences in thermal comfort can be estimated. A heat balance was calculated in the two air volumes inside each building: the room and the space between the ceiling and the roof. An improvement in thermal comfort was experienced by the users after the installation of plant mats on the roof of the concrete block building.
本研究的重点是当地材料对萨赫勒气候条件下住宅和第三产业建筑的能效和热舒适性的影响。在 CABET 项目(Construction Alternative à Basse Energie au Tchad)的框架内,我们建造了两栋建筑,一栋是用压实和添加剂的生土砖建造的,另一栋是用混凝土砌块建造的。自 2019 年起,这两栋尺寸相同、不带地板和单间的建筑都安装了温度和相对湿度传感器。一个气象站用于监测室外情况。通过比较实验数据,可以估算出热舒适度的差异。计算了每栋建筑内部两个空气体积的热平衡:房间以及天花板和屋顶之间的空间。在混凝土砌块建筑的屋顶安装植物垫后,用户的热舒适度得到了改善。
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引用次数: 0
Optimization of Titanium Alloy-Ti-6Al-4V to Minimize Mass, Maximize Stiffness and Frequency in Additive Manufacturing 优化钛合金-Ti-6Al-4V,使增材制造中的质量最小、刚度最大、频率最高
Pub Date : 2024-04-18 DOI: 10.4028/p-so6m4z
Dame Alemayehu Efa, E. M. Gutema, H. Lemu, Mahesh Gopal
Manufacture of intricate components, products without the need for tooling, shorter lead times and material grading are the most beneficial applications of Additive Manufacturing (AM). The goal of this study is to develop a design optimization framework for developing an aircraft component using additive manufacturing utilizing topology and lattice optimization techniques. Solid works were used to create a 3D model of an aircraft bracket made of Titanium alloy. To minimize mass and maximize frequency and stiffness, the optimization was performed using Altair Inspire 2022.1 software. Component optimization was performed using the finite element method, which entails reducing material while maintaining the proper function of the modelled component. The optimal performance of the designed aerospace component using topology with lattice infill is achieved with minimization of mass from 2.24810 kg to 0.16235 kg and the volume from 5.07579x105 mm3 to 4.70922x102 mm3, frequency is increased from 0.02 kHz to 13.9537 kHz, stiffness is maximized from 1,485,884.1 N/m to 4,558,924.0939 N/m with a factor of safety of 1.73. Therefore, the mechanical properties of the optimized model can full fill its overall performance.
制造复杂的部件、无需模具的产品、更短的交付周期和材料分级是增材制造(AM)最有益的应用。本研究的目标是开发一个设计优化框架,利用拓扑和网格优化技术,使用增材制造技术开发飞机部件。研究人员使用 Solid works 创建了一个由钛合金制成的飞机支架三维模型。为了使质量最小化,频率和刚度最大化,使用 Altair Inspire 2022.1 软件进行了优化。组件优化采用有限元法,即在减少材料的同时保持建模组件的正常功能。使用带晶格填充的拓扑结构设计的航空航天组件实现了最佳性能,质量从 2.24810 千克降至 0.16235 千克,体积从 5.07579x105 毫米3降至 4.70922x102 毫米3,频率从 0.02 千赫增至 13.9537 千赫,刚度从 1,485,884.1 牛/米增至 4,558,924.0939 牛/米,安全系数为 1.73。因此,优化模型的机械性能可以充分发挥其整体性能。
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引用次数: 0
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Key Engineering Materials
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