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Estimating Wood Specific Gravity of Ravenala madagascariensis Sonn. Using Near-Infrared Spectroscopy 利用近红外光谱估算 Ravenala madagascariensis Sonn. 的木材比重使用近红外光谱法估算木材比重
Pub Date : 2024-04-18 DOI: 10.4028/p-rorn3t
Lalaina Patricia Rasoamanana, Andriambelo Radonirina Razafimahatratra, T. Ramananantoandro
Near InfraRed Spectroscopy (NIRS) has emerged as a promising non-destructive method for wood analysis. In this study, the efficacy of NIRS in predicting the wood specific gravity (WSG) of Ravenala madagascariensis, an endemic non-woody species of Madagascar was assessed. The optimal model, employing "SNV (standard normal variate) + DT (detrending)" pre-treatment and utilizing 11 latent variables, exhibited interesting performance metrics, including an RMSEcv of 0.013 g.cm-3, R²cv of 0.73, and RPDcv of 2.76. Additionally, in independent validation, the model achieved an R² of 0.70 and an RPD of 2.17, with 11 numbers of latent variables. The predictive model's application unveiled significant radial variability in WSG within Ravenala madagascariensis. Specifically, the central zone exhibited lower density (average of 0.082 g.cm-³) than the peripheral zone (0.12 g.cm-³), with a highly significant difference (>0.1% threshold). Furthermore, there was a significant interaction effect between radial portion and compartment on WSG, exceeding a threshold of 1%. However, no such significant effects were observed for radial portion×sites interaction at the 5% significance level. This study contributes valuable insights into the wood properties of this endemic species, enhancing the understanding of its ecological and physical significance.
近红外光谱(NIRS)已成为一种很有前途的非破坏性木材分析方法。本研究评估了近红外光谱在预测马达加斯加特有的非木质树种 Ravenala madagascariensis 的木材比重 (WSG) 方面的功效。采用 "SNV(标准正态变异)+ DT(去趋势)"预处理并利用 11 个潜变量的最佳模型显示出有趣的性能指标,包括 RMSEcv 为 0.013 g.cm-3、R²cv 为 0.73 和 RPDcv 为 2.76。此外,在独立验证中,该模型的 R² 为 0.70,RPD 为 2.17,潜变量数量为 11 个。预测模型的应用揭示了 Ravenala madagascariensis 中 WSG 的显著径向变化。具体来说,中心区的密度(平均 0.082 克/厘米-立方厘米)低于外围区(0.12 克/厘米-立方厘米),差异非常显著(阈值大于 0.1%)。此外,径向部分和隔室对 WSG 有明显的交互影响,超过了 1%的临界值。然而,在 5%的显著性水平上,径向部分与分区的交互作用没有观察到这种显著影响。这项研究为了解这种特有树种的木材特性提供了宝贵的资料,有助于加深对其生态和物理意义的理解。
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引用次数: 0
Synthesis of Acid-Based Fly Ash Geopolymer with Pure Phosphoric Acid Compare with P-Leachate Activator 用纯磷酸合成酸基粉煤灰土工聚合物与 P 浸出液活化剂的比较
Pub Date : 2024-04-18 DOI: 10.4028/p-zxkyg9
Euricia Mkhonto, T. Mashifana, N. Sithole
Acid-based geopolymers (ABG) have gained attention as eco-friendly alternatives to Ordinary Portland cement. This study synthesized ABG by activating fly ash with commercial H3PO4 and an alternative P leachate from sewage sludge. The ABG was synthesized at different molar concentrations of 4M, 6M, 8M, 10M, and 12M, while P-leachate geopolymer (PFA) was synthesized with liquid/solid ratios of 0.2-0.5. The unconfined compressive strength (UCS) was used to measure the geopolymer performance, which was also studied using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The P concentration was higher than the alternative P source; however, the Al concentration was low, resulting in a lower UCS compared to ABG FA. ABG FA activated with 8M reported a UCS of 11.53 MPa. The strength of ABG FA was attributed to the Si-O-P-O-Si, (PO4)5-, (AlO4)5, and Al-O-Si networks and the participation of H2PO4-in geopolymerization. The PFA exhibited the formation of a Si-O-Al-O-P unit and a P-O vibration band, and the microstructure was composed of cenospheres covered with some minor gelatinous particles.
酸性土工聚合物(ABG)作为普通硅酸盐水泥的生态友好型替代品已受到关注。本研究利用商品 H3PO4 和污水污泥中的替代性 P 浸出液活化粉煤灰,合成了 ABG。合成 ABG 的摩尔浓度分别为 4M、6M、8M、10M 和 12M,而 P 浸出液土工聚合物(PFA)的液固比为 0.2-0.5。无压抗压强度(UCS)用于测量土工聚合物的性能,扫描电子显微镜(SEM)和傅立叶变换红外光谱(FTIR)也对其进行了研究。P 浓度高于替代 P 源,但 Al 浓度较低,导致 UCS 低于 ABG FA。用 8M 活化的 ABG FA 的 UCS 为 11.53 兆帕。ABG FA 的强度归因于 Si-O-P-O-Si、(PO4)5-、(AlO4)5 和 Al-O-Si 网络以及 H2PO4 参与了土工聚合。PFA 显示出 Si-O-Al-O-P 单元和 P-O 振带的形成,其微观结构由覆盖着一些微小胶状颗粒的仙人球组成。
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引用次数: 0
DFT + U +V Investigation on Adsorption of Gas Molecules (CO, SO2, NO, and NO2) on Ni Doped Bismuth Ferrite Oxide (010) 掺杂镍的氧化铋铁氧体(010)对气体分子(一氧化碳、二氧化硫、一氧化氮和二氧化氮)吸附的 DFT + U + V 研究
Pub Date : 2024-04-18 DOI: 10.4028/p-90hgo8
Amogh A. Sambare, Ramkisan S. Pawar, Mahendra D. Shirsat
The structural and electrical adsorption performance of carbon monoxide (CO), nitrous oxide (NO), nitrous dioxide (NO2), and sulphur dioxide (SO2) are explored using density functional theory calculations on Ni-doped atoms in the crystal structure of bismuth ferrite oxide (BFO). DFT+U+V offers a more complete description than either DFT or DFT+U alone. Good agreement with the experiments is obtained for both the band gap and the crystal field splitting. Ni-doped BFO (010) has adsorption energies of -0.35443 Ry for CO, -0.056076 Ry for NO, -5.64867 Ry for NO2, and -55.5483 Ry for SO2. Also, it was found that the energy of the band gap in pure BFO (010) can be lowered by adding Ni atoms. Further evidence from the DOS plot that Ni-doped BFO (010) may be considered as an emerging doped perovskite in high temperature gas sensing system for SO2 detection.
利用密度泛函理论计算氧化铋铁氧体(BFO)晶体结构中的掺镍原子,探讨了一氧化碳(CO)、一氧化二氮(NO)、二氧化亚氮(NO2)和二氧化硫(SO2)的结构和电吸附性能。DFT+U+V 提供了比单独使用 DFT 或 DFT+U 更完整的描述。带隙和晶场分裂均与实验结果吻合。掺镍的 BFO (010) 对 CO 的吸附能为 -0.35443 Ry,对 NO 的吸附能为 -0.056076 Ry,对 NO2 的吸附能为 -5.64867 Ry,对 SO2 的吸附能为 -55.5483 Ry。此外,研究还发现,加入 Ni 原子可以降低纯 BFO (010) 的带隙能量。DOS 图进一步证明,掺杂镍的 BFO (010) 可被视为一种新兴的掺杂包晶,可用于高温气体传感系统的二氧化硫检测。
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引用次数: 0
Synthesis, Characterization, and Utilization of Water Hyacinth (Eichhornia crassipes) Magnetic Biochar for Nitrate Removal from Simulated Wastewater 水葫芦(Eichhornia crassipes)磁性生物炭的合成、表征和利用,用于去除模拟废水中的硝酸盐
Pub Date : 2024-04-18 DOI: 10.4028/p-mqqs5n
Tristan Roy L. Panaligan, Andrea Kate S. Lee, Chelsea J. Petareal, Jhon Rex Tadena
The research centered on creating magnetic water hyacinth biochar (MWHB) by chemically co-precipitating Fe2+ and Fe3+ ions onto the initial biomass, which was pyrolyzed at 450°C for an hour. This MWHB was then utilized in a series of batch adsorption experiments to evaluate its effectiveness in removing nitrates from simulated wastewater. The investigation focused on understanding the impact of pH, amount of adsorbent used, and duration of contact on nitrate removal efficiency. These parameters were selected using a 2k+1 Full Factorial Design of Experiments (DOE). The data collected from the experiments underwent analysis in JMP® (SAS institute) using Pearson’s Correlation test, providing a comprehensive statistical analysis beyond utilizing the software's Prediction Profiler. The findings revealed that the quantity of adsorbent used significantly affected the nitrate removal efficiency of the magnetic biochar, demonstrating a correlation coefficient (r) of 0.8459. On the other hand, pH and contact time exhibited relatively weaker effects, obtaining correlation coefficients of-0.1943 and 0.2915, respectively. The DOE suggested the optimal conditions for nitrate removal to be at pH 3, utilizing 0.40 grams of adsorbent, and maintaining a contact time of 90 minutes, with a predicted nitrate removal efficiency of approximately 99.10%, while the actual removal efficiency stood at 97.31%. Additionally, Scanning Electron Microscopy (SEM) analysis was employed to examine the surface morphology of the MWHB before and after nitrate removal, aiding in understanding the factors contributing to the observed nitrate removal efficiency.
研究的核心是通过化学方法将 Fe2+ 和 Fe3+ 离子共沉淀到初始生物质上,然后在 450°C 下热解一小时,从而制造出磁性水葫芦生物炭(MWHB)。然后利用这种 MWHB 进行一系列批量吸附实验,以评估其从模拟废水中去除硝酸盐的效果。调查的重点是了解 pH 值、吸附剂用量和接触时间对硝酸盐去除效率的影响。这些参数是通过 2k+1 全因子实验设计 (DOE) 选定的。从实验中收集的数据在 JMP® (SAS 研究所)中进行了分析,使用了皮尔逊相关性检验,提供了超越软件预测剖析器的综合统计分析。研究结果表明,使用的吸附剂数量对磁性生物炭的硝酸盐去除效率有显著影响,相关系数 (r) 为 0.8459。另一方面,pH 值和接触时间的影响相对较弱,相关系数分别为-0.1943 和 0.2915。DOE 认为,去除硝酸盐的最佳条件是 pH 值为 3,使用 0.40 克吸附剂,接触时间为 90 分钟,预测的硝酸盐去除率约为 99.10%,而实际去除率为 97.31%。此外,还采用扫描电子显微镜(SEM)分析法检查了 MWHB 在去除硝酸盐之前和之后的表面形态,以帮助了解导致观察到的硝酸盐去除效率的因素。
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引用次数: 0
Signal Processing Technique to Study the Propagation Modes of Ultrasonic Waves in Wood Protected by Layers of Liquid Paint (Cement) 研究超声波在受液体油漆(水泥)层保护的木材中传播模式的信号处理技术
Pub Date : 2024-04-18 DOI: 10.4028/p-d4xwj4
M. Tafkirte, A. Hamine
Several techniques based on ultrasound have been proposed for non-destructive evaluation (NDE). It has been widely applied in many fields such as medicine, mechanical, and construction, especially for the detection of cracks and flaws in structures and for the identification of material properties, which is capable of performing tasks to provide quick measurements while guaranteeing great accuracy. In this paper, we have developed the technique of ultrasonic transmission by water immersion as an alternative technique to study the propagation of ultrasonic waves in two structural materials: wood and wood protected by liquid paint (cement). Overall, the application of the transmission technique by change of the angle of incidence enables the demonstration of the experimental dispersion curves for the ultrasonic modes within the plates and allows the investigation and characterization of the function of the paint system (cement) in the wood plate.
在无损评价(NDE)方面,已经提出了几种基于超声波的技术。它已被广泛应用于医学、机械和建筑等许多领域,特别是用于检测结构中的裂缝和缺陷以及鉴定材料特性,能够在保证高精度的同时完成快速测量任务。在本文中,我们开发了浸水超声波透射技术,作为研究超声波在两种结构材料(木材和受液体涂料(水泥)保护的木材)中传播的替代技术。总之,通过改变入射角度来应用透射技术,可以展示板材内超声波模式的实验频散曲线,并可以研究和描述木板中油漆系统(水泥)的功能。
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引用次数: 0
Mitigation of Efflorescence and Alkali Leaching in Activated Slag Using Foundry Sand 使用铸造砂缓解活性矿渣中的沉积和碱浸出问题
Pub Date : 2024-04-18 DOI: 10.4028/p-k5cjzo
N. Sithole
This research aimed to examine the impact of foundry sand on alkali leaching and the formation of efflorescence in alkali-activated slag. The activation process involved the utilization of sodium hydroxide and sodium silicate solutions in activating ground-granulated blast furnace slag (GBFS) and sand samples. The leaching of alkali and the formation of efflorescence were observed to occur at a reduced rate in samples derived solely from 100% ground granulated blast furnace slag (GBFS). In contrast, higher rates were identified in samples containing chemically bonded foundry sand. The incorporation of chemically bonded foundry sand elevated the mobility of alkali, leading to an increased formation of efflorescence in alkali-activated slag. Following a three-day immersion of the specimens in deionized water, nearly all of the sodium was leached from the samples, highlighting the limited affinity of sodium within the gel structure.
本研究旨在探讨铸造用砂对碱浸出和碱活化炉渣中形成藻华的影响。活化过程包括利用氢氧化钠和硅酸钠溶液活化磨碎的高炉矿渣(GBFS)和砂样品。据观察,在完全由 100% 研磨粒化高炉矿渣(GBFS)制成的样品中,碱的浸出率和藻华的形成率都有所降低。相比之下,含有化学粘合铸造砂的样品的碱浸出率更高。化学粘合铸造砂的加入提高了碱的流动性,导致碱激活炉渣中形成更多的藻华。将试样在去离子水中浸泡三天后,几乎所有的钠都从试样中浸出,这说明钠在凝胶结构中的亲和力有限。
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引用次数: 0
Morphological and Physico-Chemical Characterization of Soils from Gold Panning in Komabangou, Niger 尼日尔科马班古淘金土壤的形态和物理化学特征
Pub Date : 2024-04-18 DOI: 10.4028/p-uyv2np
Soumaila Alassane Boukari, Ibrahim Elhadji Daou, Abdoulaye Garba Neino, Yaya Soro, Abdourahamane Tankari Dan Badjo, Kouassi Benjamin Yao, Kouakou Aphonse Yao
L'objectif de ce travail est la caractérisation morphologique et physico-chimique d'échantillons de sols issus d'activités d'orpaillage dans la région de Komabangou (Niger). Les analyses ont été réalisées à l'aide d'un microscope électronique à balayage couplé à la spectroscopie dispersive en énergie (SEM-EDS), d'un pH-mètre, d'un COT-mètre et par infrarouge. Les résultats obtenus ont montré que les sols des sites étudiés sont généralement acides. En effet, l'analyse infrarouge donne les constituants majoritaires : silice, calcite, aluminium, fer et magnésium. L'analyse MEB a montré la présence de feuilles d'argile dispersées sous forme de filaments ou d'amas d'agrégats qui peuvent être dus à la présence de carbonates ainsi qu'à la présence d'éléments traces métalliques. L'analyse par spectroscopie d'énergie dispersive (DES) du sol pollué du site (S1) a révélé la présence de 60,25 % d'oxygène (O) ; 18,70 % de carbone (C); 8,34 % de silice (SiO2 ); 4,72 % d'aluminium (Al); 0,86 % de fer (Fe); 0,79 % magnésium (Mg); 0,12 % de titane (Ti); 0,11 % de zinc (Zn); 0,06 % de cadmium (Cd) et 0,0 % de plomb (Pb). En revanche, pour le site périphérique (S3), on note 77,09 % d'oxygène (O) ; 14,49 % de silice (SiO 2 ); 8,89 % d'aluminium (Al); 1,11 % de fer (Fe); 0,34 % de potassium (K) et quelques traces de manganèse (0,03 %) ; cobalt (0,01 %) ; cuivre (0,01 %) ; nickel (0,01 %) ; chrome; cadmium; mener. Enfin, le site témoin (ET), qui est vierge, contient 67,56 % d'oxygène ; 17,86 % carbone; 9,18 % silice; 4,28 % aluminium ; 0,91 % de fer et 0,13 % de potassium.
本研究的目的是分析尼日尔科马班古地区淘金活动采集的土壤样本的形态和物理化学特征。使用扫描电子显微镜和能量色散光谱仪(SEM-EDS)、pH 计、TOC 计和红外线进行了分析。结果表明,研究地点的土壤一般呈酸性。红外线分析显示了主要成分:二氧化硅、方解石、铝、铁和镁。扫描电子显微镜(SEM)分析表明,土壤中存在分散成丝状或团块状的片状粘土,这可能是由于土壤中存在碳酸盐和痕量金属。对现场(S1)受污染土壤的能量色散光谱(EDS)分析表明,其中氧气(O)占 60.25%;碳(C)占 18.70%;硅(Si)占 8.34%;8.34% 硅 (SiO2);4.72% 铝 (Al);0.86% 铁 (Fe);0.79% 镁 (Mg);0.12% 钛 (Ti);0.11% 锌 (Zn);0.06% 镉 (Cd) 和 0.0% 铅 (Pb)。相比之下,外围地点(S3)含有 77.09% 的氧(O);14.49% 的二氧化硅(SiO 2 );8.89% 的铝(Al);1.11% 的铁(Fe);0.34% 的钾(K)以及少量的锰(0.03%)、钴(0.01%)、铜(0.01%)、镍(0.01%)、铬、镉和铅。最后,对照点(ET)未受影响,含氧 67.56%;碳 17.86%;硅 9.18%;铝 4.28%;铁 0.91%;钾 0.13%。
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引用次数: 0
Synthesis and Fabrication of Luminescence of CsPbBr3/PAN Nanocomposite Fiber 铯硼砂/PAN 纳米复合纤维的合成与发光制备
Pub Date : 2024-04-18 DOI: 10.4028/p-z88m9u
Taras Genovievo De Yonarosa, A. D. Pramata, Farhan Aryo Hutomo, Diah Susanti
Perovskite semiconductor have gained increasing attention in the recent years. However, pristine halide perovskites often faces bottle-neck related to low their stability. Herein, for the first time synthesis and fabrication of CsPbBr3/PAN fiber composite with electrospinning method is reported. CsPbBr3 quantum dots (QDs) embedded PAN fiber were successfully fabricated based on the XRD and FTIR test result. The result demonstrates electrospun fiber stable for over than one week in the condition of being immersed in water. The CsPbBr3 QDs was synthesized by Ligand Assisted Reprecipitation Process (LARP) method. The average particle size of our CsPbBr3 particle sizes ranging from 80 to 240 nm. Our findings reveal that the effect of variations between toluene and acetone had an effect on the size of the fiber and the intensity of photoluminescence reduction of the CsPbBr3/PAN fiber composite. Which is the smallest fiber and the lowest reduction intensity belongs to the 4:1 variation, namely with a fiber size of a 727.56 nm and a percentage decrease in intensity of 66,67%.
近年来,过氧化物半导体越来越受到人们的关注。然而,原始的卤化物包晶往往面临着稳定性低的瓶颈。本文首次报道了电纺丝法合成和制备 CsPbBr3/PAN 纤维复合材料。根据 XRD 和 FTIR 测试结果,成功制备了嵌入 CsPbBr3 量子点(QDs)的 PAN 纤维。结果表明,电纺纤维在水中浸泡一周以上仍保持稳定。CsPbBr3 QDs 是通过配体辅助沉淀法(LARP)合成的。CsPbBr3 的平均粒径为 80 至 240 nm。我们的研究结果表明,甲苯和丙酮之间的变化对 CsPbBr3/PAN 纤维复合材料的纤维尺寸和光致发光还原强度有影响。其中,4:1 变化的纤维最小,还原强度最低,即纤维尺寸为 727.56 nm,强度下降了 66.67%。
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引用次数: 0
Poly(O-Phenylene Diamine) Reformed Pencil Graphite as the Disposable Electrochemical Sensor for Voltammetric Analysis of Tryptamine 聚(邻苯基二胺)改性铅笔石墨作为一次性电化学传感器用于色胺的伏安分析
Pub Date : 2024-04-18 DOI: 10.4028/p-jfp00y
Aswathy S. Murali, Chippy Harish, Sherin Susan Cherian, Gayathri S. Nair, S. Lekshmi, Surya Gopidas, Beena Saraswathyamma
By means of electropolymerization process, a simple as well as proficient electrochemical sensor was developed for electrochemical resolution of tryptamine. The morphology and electrochemistry of thus fabricated poly (O-Phenylene diamine) reformed pencil graphite is evaluated thoroughly by FESEM along with DPV and CV respectively. Under experimental settings, finely resolved irreversible electro-oxidation peak at potential +0.594 V obtained for tryptamine on the altered electrode surface with phosphate buffer of pH 9 as supporting electrolyte. The oxidation peak current and tryptamine concentration are observed to possess linearity in the range of 0.4 μM to 117 μM with R2 = 0.99. Additionally the limit of detection (LOD) for tryptamine quantification is found as 0.2 μM. The sensor exhibited superior analytical properties such as high reproducibility, repeatability and anti-interference capability. The practical efficiency of fabricated sensor tested successfully in cheese obtained from milk.
通过电聚合工艺,我们开发出了一种既简单又高效的电化学传感器,用于对色胺进行电化学分析。利用 FESEM 以及 DPV 和 CV 分别对所制备的聚(邻苯基二胺)重整铅笔石墨的形态和电化学性能进行了全面评估。在实验设置下,以 pH 值为 9 的磷酸盐缓冲液为支撑电解质,在改变电极表面上的色胺在电位 +0.594 V 处获得了精细分辨的不可逆电氧化峰。氧化峰电流和色胺浓度在 0.4 μM 至 117 μM 范围内呈线性关系,R2 = 0.99。此外,色胺定量的检测限(LOD)为 0.2 μM。该传感器具有出色的分析性能,如重现性高、重复性好和抗干扰能力强。在牛奶制成的奶酪中成功测试了所制造传感器的实用效率。
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引用次数: 0
Chip Formation and Shaping in Milling Machining of Light Metal Casting Materials 轻金属铸造材料铣削加工中的切屑形成与成型
Pub Date : 2024-04-05 DOI: 10.4028/p-tftpu0
Pascal Fritzsche, Ilgar Abbasov
The main purpose of the research is to study the floating chips produced during mechanical processing. Chips derived from aluminium material cause several difficulties in mechanical processing. Research shows that floating chips clog filters in chip conveyors, resulting in significant downtime in production processes. In this article, cause-effect research has been carried out to find approaches to solving this problem.
研究的主要目的是研究机械加工过程中产生的浮屑。铝材料产生的切屑会给机械加工带来一些困难。研究表明,浮屑会堵塞铝屑输送机中的过滤器,导致生产过程严重停机。本文开展了因果关系研究,以找到解决这一问题的方法。
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引用次数: 0
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Key Engineering Materials
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