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ANALYSIS OF SPATIAL AND TEMPORAL VARIABILITY OF AEROSOL OPTICAL DEPTH OVER KARABUK USING MODIS 利用模型分析卡拉布克上空气溶胶光学深度的时空变异性
Pub Date : 2023-09-24 DOI: 10.36306/konjes.1333625
Duygu Arikan, Ferruh Yildiz
The concept of aerosol refers to the combination of microscopic solid or liquid particles present in the atmosphere along with a mixture of gases. These particles are suspended in the air at different sizes and are evaluated based on their ability to scatter or absorb light, which is quantified through a measurement known as aerosol optical depth. These particles' quantities are determined using specialized devices, commonly referred to as "aerosol optical depth meters" or "optical thickness meters." Additionally, through remote sensing technology, aerosol optical depth can also be measured via satellites. In this study, aerosol optical depth has been examined temporally and spatially in the Karabük province for 2022. For this aim, data from National Air Quality Monitoring Stations (NAQMS) situated nationwide was employed, along with MODIS satellite images. Data from five stations in Karabük province, namely Kardemir1, Kardemir2, Tören Alanı, 75.yıl, and Safranbolu, were used for temporal analysis, while satellite imagery was used for spatial analysis. The relationship between aerosol optical depths derived from MODIS satellite data using green and blue band information and station data was investigated. As a result, a 99% positive correlation was found between the two bands obtained from the MODIS satellite, and a significant correlation was observed between ground-based particulate matter 2.5(PM2.5) and particulate matter 10 (PM10) data. Data from the Tören Alanı station, which had a higher amount of data (357 days) compared to other stations, was used to determine this correlation. It was found that there was an 86.35% positive correlation among particulate matters. A moderate correlation was also identified between ground-based data and aerosol optical depth obtained from satellite imagery.
气溶胶的概念是指存在于大气中的微小固体或液体颗粒与气体混合物的组合。这些颗粒以不同的大小悬浮在空气中,并根据其散射或吸收光线的能力进行评估,这种能力通过一种称为气溶胶光学深度的测量方法进行量化。这些颗粒的数量是通过专门的设备(通常称为 "气溶胶光学深度计 "或 "光学厚度计")来确定的。此外,通过遥感技术,还可以通过卫星测量气溶胶光学深度。本研究对卡拉比克省 2022 年的气溶胶光学深度进行了时间和空间研究。为此,研究人员采用了来自全国各地国家空气质量监测站(NAQMS)的数据以及 MODIS 卫星图像。时间分析采用卡拉比克省五个监测站的数据,即卡德米尔1站、卡德米尔2站、托伦阿兰站、75.耶尔站和萨夫兰博卢站,空间分析采用卫星图像。研究了利用绿色和蓝色波段信息从 MODIS 卫星数据中得出的气溶胶光学深度与观测站数据之间的关系。结果发现,从 MODIS 卫星获得的两个波段之间存在 99% 的正相关性,地面颗粒物 2.5(PM2.5)和颗粒物 10(PM10)数据之间存在显著相关性。特伦阿兰站的数据量(357 天)高于其他站点,该站的数据被用于确定这种相关性。结果发现,颗粒物之间存在 86.35% 的正相关性。地面数据与卫星图像获得的气溶胶光学深度之间也存在一定的相关性。
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引用次数: 0
DETERMINING THE OPTIMUM PARKING ANGLES FOR VARIOUS RECTANGULAR-SHAPED PARKING AREAS: A PARTICLE SWARM OPTIMIZATION-BASED MODEL 确定各种矩形停车区域的最佳停车角度:基于粒子群优化的模型
Pub Date : 2023-09-21 DOI: 10.36306/konjes.1293799
Ziya Çakici, A. T. Şensoy
Reducing financial costs as much as possible through the effective and efficient use of parking areas is an important issue for sustainable urban planning. This can be achieved by optimizing the placement of angles of parking-lots. In this study, to determine the optimum parking angles for rectangular-shaped parking areas, a Particle Swarm Optimization-based model that aims to maximize the capacity of parking areas is developed. In the scope of the study, firstly, 324 parking area scenarios which have different dimensions from each other are created for testing the effectiveness of the model developed. Each scenario is separately analyzed by considering the optimization-based model and fixed-parking angles (0o, 30o, 45o, 60o and 90o) used in parking area planning. In the last step, parking area capacities obtained by applying different parking angles for each scenario and the total parking capacities for all scenarios are compared in detail. Results show that the capacities of parking areas can be increased up to approximately 50% with the model created. Besides, in contrast to existing literature, the findings of this study have proven that the optimum parking angle directly depends on the topology of the land. The model developed can be applied to all rectangular-shaped parking areas to achieve better urban planning.
通过有效和高效地利用停车场尽可能降低财务成本是可持续城市规划的一个重要问题。这可以通过优化停车场的角度来实现。在本研究中,为了确定矩形停车区域的最佳停车角度,开发了一个基于粒子群优化的模型,旨在最大限度地提高停车区域的容量。在研究范围内,首先创建了 324 个不同尺寸的停车区域场景,以测试所开发模型的有效性。通过考虑基于优化的模型和停车区域规划中使用的固定停车角度(0o、30o、45o、60o 和 90o),分别对每个场景进行分析。最后,详细比较了每种方案采用不同停车角度得出的停车区域容量和所有方案的总停车容量。结果表明,利用所创建的模型,停车区的容量最多可提高约 50%。此外,与现有文献相比,本研究的结果证明,最佳停车角度直接取决于土地的拓扑结构。所开发的模型可应用于所有矩形停车区,以实现更好的城市规划。
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引用次数: 0
A COMPARATIVE STUDY OF RELEASE KINETICS BEHAVIOR MODELS AND SHELF LIFE ASSESSMENT OF BACITRACIN ZINC-LOADED PLA COMPOSITES 杆菌肽锌负载 pla 复合材料释放动力学行为模型和保质期评估的比较研究
Pub Date : 2023-09-13 DOI: 10.36306/konjes.1328688
A. Özarslan, Fatih Ciftci
Mathematical modeling aims to simplify the complex process of drug release and to gain knowledge about the release mechanisms specific to a given material system. Consequently, a mathematical model focuses primarily on one or two important factors. Drug release aims to maximize the bioactivity of both naturally derived and synthetically derived macromolecules, thus increasing their clinical applicability and improving the overall quality of life. This study focused on fabricating PLA composites with different weight percentages of Bacitracin Zinc (0.5, 1.0, and 2.0) and evaluating their potential as a drug delivery system. To understand the release mechanism of Bacitracin Zinc from the PLA composites, we developed a Franz diffusion kinetic model and a mathematical model for cumulative release kinetics. The Franz diffusion model was utilized to analyze the release behavior of the PLA/Bacitracin Zinc composite structure. The results indicated a sustained release rate, following a Zero Order release kinetics pattern. Furthermore, the shelf life of the composite structure was determined to be 125 days. Python programming was employed to model the release behavior and estimate the shelf life of Bacitracin Zinc (0.5, 1.0, and 2.0) incorporated into the PLA matrix to compare different weight percentages' behavior and shelf life.
建立数学模型的目的是简化复杂的药物释放过程,了解特定材料系统的释放机制。因此,数学模型主要关注一到两个重要因素。药物释放的目的是最大限度地提高天然衍生和合成大分子的生物活性,从而提高其临床适用性并改善整体生活质量。本研究的重点是制备含有不同重量百分比(0.5、1.0 和 2.0)的杆菌肽锌聚乳酸复合材料,并评估其作为药物释放系统的潜力。为了解巴曲锌从聚乳酸复合材料中的释放机制,我们建立了弗兰兹扩散动力学模型和累积释放动力学数学模型。利用弗兰兹扩散模型分析了聚乳酸/杆菌肽锌复合结构的释放行为。结果表明,该结构具有持续的释放速率,遵循零阶释放动力学模式。此外,复合结构的保质期被确定为 125 天。为了比较不同重量百分比的释放行为和保质期,我们采用 Python 程序设计来模拟释放行为,并估算出加入聚乳酸基质中的杆菌肽锌(0.5、1.0 和 2.0)的保质期。
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引用次数: 0
EFFECT OF LOW-VELOCITY IMPACT DAMAGE ON THE ELECTROMAGNETIC INTERFERENCE SHIELDING EFFECTIVENESS OF CFRP COMPOSITES 低速冲击损伤对 CFRP 复合材料电磁干扰屏蔽效果的影响
Pub Date : 2023-08-13 DOI: 10.36306/konjes.1302313
Ferhat Yıldırım
Carbon fiber reinforced polymer (CFRP) composites are widely used engineering materials in aerospace technologies. These electrically conductive carbon-based materials, due to the lightness advantages, are preferred as shields against electromagnetic radiation, especially in aircraft and satellites. However, the performance losses caused by damage because of flying object collision such as bird, hail, or projectile contain significant uncertainty. Herein, the CFRP composite material was structurally damaged by low velocity impact test set-up at various energy levels between 2.5 to 10 joules, and then its electromagnetic interference (EMI) shielding performance was investigated. In addition, the electrical properties of the material were also examined, and the occurred damage status was evaluated by microscopy studies. Intrinsically, the increase in impact energy increases the grade of damage on body of the material. This results in a drastic decrease in electrical conductivity and EMI performance. In experiments, where 5 joule energy is detected as a threshold level, it has been observed that irreparable damage occurs at energy levels above this value.
碳纤维增强聚合物(CFRP)复合材料是航空航天技术中广泛使用的工程材料。这些导电碳基材料由于具有轻质优势,被优先用作电磁辐射防护罩,尤其是在飞机和卫星中。然而,由于鸟类、冰雹或弹丸等飞行物碰撞造成的损坏所带来的性能损失具有很大的不确定性。在此,CFRP 复合材料在 2.5 至 10 焦耳的不同能量水平的低速冲击试验装置下受到结构性破坏,然后研究了其电磁干扰(EMI)屏蔽性能。此外,还检测了材料的电学特性,并通过显微镜研究评估了发生的损坏状况。从本质上讲,冲击能量的增加会提高材料本体的损坏等级。这导致导电性和 EMI 性能急剧下降。在以 5 焦耳能量为阈值的实验中,我们发现当能量超过这个值时,就会发生不可修复的损坏。
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引用次数: 0
IMPROVEMENT OF HIGH PLASTICITY CLAY BY USING FILTER SLUDGE 利用过滤污泥改良高塑性粘土
Pub Date : 2023-08-13 DOI: 10.36306/konjes.1311189
İlyas Özkan, Y. Yenginar
Filter sludge (FS) is a waste material that occurs during sugar production in the sugar industry, and since it is not used anywhere, it creates a problem due to storage costs and environmental damage. In the present study, high plasticity clay was stabilized with a filter sludge which has never been used for soil stabilization in field cases. The changes in the geotechnical properties of a high plasticity clay (CH) with the additive of filter sludge (FS) were investigated. The amount of FS mixed into CH soil is 3-6-9-12-15% by dry weight of the soil. Changes in geotechnical properties such as consistency limits, compaction parameters, strength, swelling potential, CBR value of improved soils were determined. The plastic limit and optimum water content increase as the FS content added to the soil increases; liquid limit, plasticity index, and maximum dry density decrease. Improved soil strength increases as the curing time and FS amount increase, and the highest strength was obtained with 15% of FS. At the optimum additive ratio, the unconfined compressive strength increases by 33%. The swelling percentage of CH clay decreases from 42.5% to 20%. According to the wet CBR test results, the bearing capacity of the improved soil increased from %1.1 to %4.4. As a result of this study, it was seen that the FS waste material improved the geotechnical properties of the soil.
过滤污泥(FS)是制糖业在制糖过程中产生的一种废料,由于它没有被用于任何地方,因此造成了储存成本和环境破坏问题。在本研究中,使用过滤污泥对高塑性粘土进行了稳定化处理。研究了添加过滤污泥(FS)后高塑性粘土(CH)岩土特性的变化。在 CH 土中掺入的滤泥(FS)量为土干重的 3-6-9-12-15%。测定了改良土壤的岩土特性变化,如稠度极限、压实参数、强度、膨胀势、CBR 值。随着土壤中 FS 含量的增加,塑限和最佳含水量也随之增加;液限、塑性指数和最大干密度则有所降低。改良土的强度随固化时间和 FS 用量的增加而增加,FS 含量为 15%时强度最高。在最佳添加比例下,无压抗压强度提高了 33%。CH 粘土的膨胀率从 42.5% 降至 20%。根据湿CBR测试结果,改良土壤的承载力从%1.1提高到%4.4。研究结果表明,FS 废料改善了土壤的岩土特性。
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引用次数: 0
DEMOGRAFİK ÖZELLİKLERİN ÇEVRİMİÇİ MARKET ALIŞVERİŞİ KULLANIMINA ETKİSİNİN MAKİNE ÖĞRENMESİ YÖNTEMLERİ İLE TAHMİNİ 用机器学习方法预测人口特征对网上购物使用率的影响
Pub Date : 2023-08-07 DOI: 10.36306/konjes.1142886
Burak Bahçivan, Atınç Yilmaz
Çevrimiçi market alışverişi hizmeti sağlayan firmaların ürün satışlarını arttırmak ve yeni müşteriler elde etmek amacıyla hayata geçirdikleri birçok kampanyanın başarıya ulaşamadığı görülmektedir. Çevrimiçi alışverişte ürün satışlarının artmasını ve kampanyaların başarılı olmasını amaçlayarak, çevrimiçi market üzerinden alışveriş yapan 394 kullanıcıya ait çeşitli veriler anket aracılığı ile toplanmıştır. Çalışmada, sık kullanılan makine öğrenmesi algoritmaları ile modelleme yapılarak çevrimiçi market kullanıcılarının kişisel bakım kategorisinden alışveriş yapma eğilimlerinin öngörülmesini sağlayan bir model ortaya konulmuştur. Karar Ağaçları, K-En Yakın Komşu, Gradyan Arttırılmış Ağaçlar, Rastgele Orman ve Lojistik Regresyon yöntemleri modelleme için kullanılmıştır. Son olarak da ortaya çıkan eğri altında kalan alan (EAKA-AUC), geri çağırma (recall), f1-skor (f1-score) değerleri üzerinden yöntemlerin performans karşılaştırılması yapılmıştır. Çalışma sonucunda en yüksek performans 0.928 doğruluk oranı ve 0.92 AUC değerleri ile rastgele orman yöntemi ile elde edilirken; Gradyan Arttırılmış Ağaçlar yöntemi uygulanan model ise 0.704 doğruluk oranı ve 0.70 AUC değeri ile en düşük performansa ulaşmıştır. Çalışmada elde edilen bulgulara göre, özellikleri "43-47 yaş altı, günlük internet kullanımı fazla, kapıda kredi kartı ile ödeme tercihi yapmayan" kullanıcıların kişisel bakım kategorisinden alışveriş yapmayı tercih ettikleri analiz edilmiştir. Elde edilen sonuçlar incelendiğinde, şirketlerin çalışmada ortaya konan model ile hedef müşteri kitlelerini daha iyi belirlemelerine olanak sağlanacağı ve bu sayede yapılan gereksiz yatırımların önüne geçilebileceği öngörülmektedir.
我们发现,提供网上食品杂货购物服务的公司为增加产品销量和获得新客户而开展的许多活动都不成功。为了提高产品销量和成功开展网上购物活动,我们通过调查收集了通过网上杂货店购物的 394 名用户的各种数据。在这项研究中,通过使用常用的机器学习算法建模,提出了一个预测网上市场用户个人护理品类购物倾向的模型。建模时使用了决策树、K-近邻、梯度提升树、随机森林和逻辑回归等方法。最后,根据曲线下面积(AUC)、召回率和 f1 分数值对这些方法的性能进行了比较。研究结果表明,随机森林方法的准确率最高,为 0.928,AUC 值为 0.92,而梯度增强树方法的准确率最低,为 0.704,AUC 值为 0.70。根据研究结果分析,"年龄在 43-47 岁以下、每天上网次数多、不喜欢上门刷卡 "的用户更喜欢在个人护理品类中购物。在对所获得的结果进行分析后,预计企业将能够利用研究中提出的模型更好地确定其目标客户群,从而避免不必要的投资。
{"title":"DEMOGRAFİK ÖZELLİKLERİN ÇEVRİMİÇİ MARKET ALIŞVERİŞİ KULLANIMINA ETKİSİNİN MAKİNE ÖĞRENMESİ YÖNTEMLERİ İLE TAHMİNİ","authors":"Burak Bahçivan, Atınç Yilmaz","doi":"10.36306/konjes.1142886","DOIUrl":"https://doi.org/10.36306/konjes.1142886","url":null,"abstract":"Çevrimiçi market alışverişi hizmeti sağlayan firmaların ürün satışlarını arttırmak ve yeni müşteriler elde etmek amacıyla hayata geçirdikleri birçok kampanyanın başarıya ulaşamadığı görülmektedir. Çevrimiçi alışverişte ürün satışlarının artmasını ve kampanyaların başarılı olmasını amaçlayarak, çevrimiçi market üzerinden alışveriş yapan 394 kullanıcıya ait çeşitli veriler anket aracılığı ile toplanmıştır. Çalışmada, sık kullanılan makine öğrenmesi algoritmaları ile modelleme yapılarak çevrimiçi market kullanıcılarının kişisel bakım kategorisinden alışveriş yapma eğilimlerinin öngörülmesini sağlayan bir model ortaya konulmuştur. Karar Ağaçları, K-En Yakın Komşu, Gradyan Arttırılmış Ağaçlar, Rastgele Orman ve Lojistik Regresyon yöntemleri modelleme için kullanılmıştır. Son olarak da ortaya çıkan eğri altında kalan alan (EAKA-AUC), geri çağırma (recall), f1-skor (f1-score) değerleri üzerinden yöntemlerin performans karşılaştırılması yapılmıştır. Çalışma sonucunda en yüksek performans 0.928 doğruluk oranı ve 0.92 AUC değerleri ile rastgele orman yöntemi ile elde edilirken; Gradyan Arttırılmış Ağaçlar yöntemi uygulanan model ise 0.704 doğruluk oranı ve 0.70 AUC değeri ile en düşük performansa ulaşmıştır. Çalışmada elde edilen bulgulara göre, özellikleri \"43-47 yaş altı, günlük internet kullanımı fazla, kapıda kredi kartı ile ödeme tercihi yapmayan\" kullanıcıların kişisel bakım kategorisinden alışveriş yapmayı tercih ettikleri analiz edilmiştir. Elde edilen sonuçlar incelendiğinde, şirketlerin çalışmada ortaya konan model ile hedef müşteri kitlelerini daha iyi belirlemelerine olanak sağlanacağı ve bu sayede yapılan gereksiz yatırımların önüne geçilebileceği öngörülmektedir.","PeriodicalId":17899,"journal":{"name":"Konya Journal of Engineering Sciences","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139351525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
DÖNER DARBELİ DELİK DELME PERFORMANS ANALİZİ ve UYGUN UÇ SEÇİMİ: KAYSERİ HİMMETDEDE OCAĞI ÖRNEĞİ 旋挖钻性能分析和适当的钻头选择:开塞利赫梅特德采石场案例
Pub Date : 2023-08-06 DOI: 10.36306/konjes.1185508
Mehmet Osmanoğlu
Bu çalışmada Himmetdede ocaklarında kullanılan delici makineler ile delgi işlemi yapılmıştır. Delici uçlarının özelliklerine göre 3 farklı bit tipi kullanılmıştır. Button ve yari balistik olarak adlandırılan bu delici uç tiplerinin işletme sahasında verimliliği kıyaslanması yapılmıştır. Delik delme verimlerinde gerçekleşen değişimlerin incelenmesi amacıyla arazide delik delme süreleri ölçülmüş ve buna bağlı olarak her bir delici ucun delme hızları (PR) hesaplanmış ve delik delme işlemi sonucunda açığa çıkan kırıntılardan temsili örnekler alınarak laboratuarda elek serisi ile sınıflandırılarak her bir delik için pasa irilik katsayıları (PİK) hesaplanmıştır. Elde edilen bütün veriler birlikte değerlendirilerek farklı delici uç tipleri için delme verimlerinde gerçekleşen değişimlerin incelenmesi ile söz konusu granitoid ocaklarında gerçekleştirilen delme işlemi için uygun uç tipi belirlenmeye çalışılmıştır.
本研究使用 Himmetdede 采石场使用的钻孔机进行钻孔作业。根据钻头的特性,使用了三种不同类型的钻头。这些钻头被称为钮扣式和半弹道式,其效率在作业现场进行了比较。为了研究钻孔效率的变化,在现场测量了钻孔时间,并计算了每种钻头的钻孔速度 (PR)。 在实验室用一系列筛子对钻孔过程中释放的碎屑进行了代表性取样和分类,并计算了每个钻孔的锈蚀粒度系数 (PIK)。对获得的所有数据进行了综合评估,并通过分析不同钻头类型在钻孔效率方面的变化,试图确定适合相关花岗岩采石场钻孔工艺的钻头类型。
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引用次数: 0
STATISTICAL METHOD FOR ESTIMATING SELECTED GEOTECHNICAL PROPERTIES OF QUATERNARY SEDIMENT 估算第四纪沉积物选定岩土特性的统计方法
Pub Date : 2023-08-06 DOI: 10.36306/konjes.891806
Abbas J. Al-Taie
Quaternary sediments have characteristics that distinguish them from older soils. In engineering practice, these sediments are of particular interest to engineering geologists and geotechnical engineers because many engineering constructions have to be founded on, or in, them. This paper describes a method for rapidly estimating selected geotechnical properties of some Quaternary soil from the Mesopotamian Plain using statistical correlation equations. The paper explored an expedient statistical method to estimate some geotechnical properties (including total and dry unit weights, void ratio, porosity, Atterberg limits, and compression index) rapidly without running time-consuming and expensive laboratory tests. It was found that the selected properties showed a relatively moderate to high correlation with independent properties. Both the unit weight and void ratio depicted a high correlation with initial water content. while a moderate correlation existed between compression index and initial water content. Also, the plasticity index has a strong correlation with liquid limit values. The results of this study accord an additional usage as facultative engineering tools for geotechnical engineers to utilize for any preliminary engineering design.
第四纪沉积物具有不同于旧土的特征。在工程实践中,工程地质学家和岩土工程师对这些沉积物特别感兴趣,因为许多工程建设都必须建立在这些沉积物之上或之中。本文介绍了一种利用统计相关方程快速估算美索不达米亚平原一些第四纪土壤的选定岩土特性的方法。本文探讨了一种便捷的统计方法,可在不进行耗时且昂贵的实验室测试的情况下快速估算某些岩土特性(包括总重和干单位重、空隙率、孔隙度、阿特伯格极限和压缩指数)。研究发现,所选属性与独立属性之间的相关性相对较高。单位重量和空隙率与初始含水量的相关性较高,而压缩指数与初始含水量的相关性适中。此外,塑性指数与液限值也有很强的相关性。这项研究的结果为岩土工程师在任何初步工程设计中提供了额外的辅助工程工具。
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引用次数: 0
FABRICATION OF TERNARY SILICA-CALCIUM-MAGNESIUM AEROGELS: EFFECT OF FEEDING RATE AND MOLAR RATIO ON PROPERTIES 三元硅钙镁气凝胶的制备:进料速度和摩尔比对性能的影响
Pub Date : 2023-08-01 DOI: 10.36306/konjes.1260218
Burcu Karakuzu Ikizler, Pınar Terzioğlu, Tülay Merve TEMEL SOYLU, S. Yücel
The silica-calcium-magnesium ternary aerogels were prepared by a solvent exchange method and a subsequent ambient pressure drying process. The effect of process parameters such as feeding rate (9-70 mL.min-1) and molar ratio (Si/(Ca:Mg) = 1:1 - 3:1) on the material characteristics including density, elemental content, surface area, pore size, pore volume, and morphology of powders were investigated. Aerogels were characterized by Fourier transform infrared spectroscopy (FTIR), inductively coupled plasma optical emission spectroscopy (ICP-OES), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), Barrett–Joiner–Halenda (BJH) and tapping density analysis. It was found that the molar ratio of Si/(Ca:Mg) could remarkably affect the surface area and density of aerogels, while the feeding rate had slight effect. The resultant aerogels exhibited high specific surface areas. The results showed that the aerogel has a Si/(Ca:3Mg) molar composition obtained with 9 mL.min-1 had the highest surface area (524 m2.g−1). The increase of Ca to Mg molar ratio caused a decrease in the surface area and density of samples. The resultant aerogels are promising candidates as adsorbents to remove various contaminants.
通过溶剂交换法和随后的常压干燥工艺制备了硅钙镁三元气凝胶。研究了进料速率(9-70 mL.min-1)和摩尔比(Si/(Ca:Mg) = 1:1 - 3:1)等工艺参数对材料特性(包括密度、元素含量、表面积、孔径、孔体积和粉末形态)的影响。气凝胶的表征方法包括傅立叶变换红外光谱(FTIR)、电感耦合等离子体光发射光谱(ICP-OES)、扫描电子显微镜(SEM)、Brunauer-Emmett-Teller(BET)、Barrett-Joiner-Halenda(BJH)和攻丝密度分析。研究发现,Si/(Ca:Mg)的摩尔比对气凝胶的表面积和密度有显著影响,而进料速度的影响较小。所制备的气凝胶具有很高的比表面积。结果表明,摩尔组成为 Si/(Ca:3Mg)的气凝胶在 9 mL.min-1 的条件下比表面积最大(524 m2.g-1)。随着钙镁摩尔比的增加,样品的表面积和密度都有所下降。所得气凝胶有望成为去除各种污染物的吸附剂。
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引用次数: 0
DEVELOPMENT of Cu MATRIX COMPOSITE CONTACTORS REINFORCED by NICKEL COATED SiC 镍涂层碳化硅加固铜基复合接触器的开发
Pub Date : 2023-07-30 DOI: 10.36306/konjes.1255596
Cemalettin Arvas, İ. Altinsoy, T. Yener, G. Efe
In this study, Cu-Ni coated SiC composite samples were produced by electric current assisted sintering (ECAS) method by adding electroless nickel coated SiC powders to copper powders produced by cementation method at the ratios of 0.5, 1 and 1.5 wt%. The relative densities of the produced samples were measured by Archimedes’ principle, their microstructures were examined by SEM-EDS, dominant phases were determined by XRD technique; microhardness and electrical conductivity measurements were made. The relative density of undoped copper was determined as 99.42% and the relative density value of Cu-Ni SiC composite samples decreased to 98.35% at most with increasing SiC ratio. The hardness values of Cu-Ni SiC composite samples increased from 120HV to 145HV with the addition of SiC; electrical conductivity values decreased from 90.41 IACS (International annealed copper standard) to 58.56 IACS.
本研究采用电流辅助烧结(ECAS)方法,在固结法制备的铜粉末中加入无电解镍涂层碳化硅粉末,以 0.5、1 和 1.5 wt% 的比例制备了铜镍涂层碳化硅复合材料样品。利用阿基米德原理测量了制得样品的相对密度,利用扫描电子显微镜(SEM-EDS)检查了样品的微观结构,利用 XRD 技术确定了主要物相,并进行了显微硬度和电导率测量。未掺杂铜的相对密度被测定为 99.42%,随着碳化硅比例的增加,铜镍碳化硅复合材料样品的相对密度值最多下降到 98.35%。随着 SiC 的添加,Cu-Ni SiC 复合材料样品的硬度值从 120HV 增加到 145HV;电导率值从 90.41 IACS(国际退火铜标准)下降到 58.56 IACS。
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引用次数: 0
期刊
Konya Journal of Engineering Sciences
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