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Cathionic corrosion inhibitors for protection of steel in chloride containing concrete pore solution 氯离子缓蚀剂在含氯混凝土孔隙溶液中保护钢筋
Q3 Materials Science Pub Date : 2019-03-01 DOI: 10.2478/kom-2019-0006
T. Lovaši, M. Kouřil, T. Jamborová, J. Stoulil, Š. Msallamová
Abstract Electrochemical chloride extraction from a reinforced concrete structure may be accompanied with an electrochemical injection of healing agents if such agents are positively charged and are able to migrate towards the activated reinforcement. Positive charge carried by nanoparticles or cathionic corrosion inhibitors might be the proper choice. Organic substances with a positive charge and their salts are mostly such inhibitors. The essential conditions for successful application of such corrosion inhibitors are their sufficient corrosion inhibition efficiency that was studied and evaluated and their stability of positive charge in chloride containing concrete pore solution.
摘要从钢筋混凝土结构中提取电化学氯化物时,如果愈合剂带正电并能够向活化的钢筋迁移,则可以同时进行愈合剂的电化学注射。纳米粒子或阴极离子缓蚀剂携带的正电荷可能是正确的选择。带正电荷的有机物质及其盐类大多是此类抑制剂。成功应用此类缓蚀剂的基本条件是其足够的缓蚀效率,以及其在含氯混凝土孔隙溶液中的正电荷稳定性。
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引用次数: 0
Corrosion survey of the palm greenhouse support structure in the castle garden in Lány Lány城堡花园棕榈温室支撑结构腐蚀调查
Q3 Materials Science Pub Date : 2019-03-01 DOI: 10.2478/kom-2019-0007
P. Pokorný, M. Hrabánek, D. Dvorsky, L. Turek
Abstract The corrosion survey of the supporting steel/cast iron structure of the palm greenhouse included not only the characteristics of the used metal materials (microstructure, chemical composition), but also the current state of the system of corrosion protection (thickness and stratigraphy of the applied coating system). From a static point of view, the palm greenhouse design meets the applicable standards if two damaged cast iron columns are repaired. A new top coat with extended corrosion resistance is required on the surface of individual metal profiles.
摘要对棕榈温室支撑钢/铸铁结构进行腐蚀调查,不仅包括所用金属材料的特征(微观结构、化学成分),还包括防腐体系的现状(涂覆体系的厚度和地层)。从静态角度来看,如果修复了两根损坏的铸铁柱,则棕榈温室设计符合适用标准。需要在单个金属型材的表面涂上一层具有更强耐腐蚀性的新面漆。
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引用次数: 0
Exposure tests of copper foils in a slurries of different bentonites 不同膨润土浆料中铜箔的暴露试验
Q3 Materials Science Pub Date : 2019-03-01 DOI: 10.2478/kom-2019-0003
J. Stoulil, M. Kouřil, D. Dobrev
Abstract The goal of the study was to compare corrosion performance of copper in different bentonite slurries. Copper coil samples were exposed in a slurries of bentonites BaM, Rokle, B75, G2M, Voltex, Sabenil. The test was carried out under anaerobic conditions in glovebox at laboratory temperature for duration of one to four months. Samples were evaluated by means of X-ray diffraction and mass loss. Liquid parts of slurries were analysed by ion chromatography and pH meter. The resistance of copper in all studied bentonites was very high. Corrosion rates were in order of tenths of micrometers per year. No trend between pore solution composition and corrosion rate or composition of corrosion products was observed.
摘要本研究的目的是比较铜在不同膨润土浆料中的腐蚀性能。铜线圈样品暴露在膨润土BaM, Rokle, B75, G2M, Voltex, Sabenil的浆液中。试验在实验室温度的手套箱中厌氧条件下进行,持续时间为1至4个月。通过x射线衍射和质量损失对样品进行了评价。用离子色谱法和pH计对浆料的液体部分进行了分析。在所有的膨润土中,铜的电阻都很高。腐蚀速度为每年十分之几微米。孔隙溶液组成与腐蚀速率和腐蚀产物组成之间没有明显的关系。
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引用次数: 0
Inhibition efficiency of sodium salts of carboxylic acids on corrosion of lead in archive environment 羧酸钠盐对铅在档案环境中腐蚀的抑制作用
Q3 Materials Science Pub Date : 2019-03-01 DOI: 10.2478/kom-2019-0005
K. C. Strachotová, M. Kouřil, K. Kuchťáková, Š. Msallamová
Abstract Lead in archive environment suffers from severe corrosion attack caused by the organic acids’ vapours usually presented in such an environment. One of possible ways of corrosion protection of lead is its surface treatment by solutions of sodium salts of monocarboxylic acids (general formula CH3(CH2)n-2COONa, noted NaCn, n = 10, 11, 12). The principle of this corrosion protection is a creation of conversion coating on the lead’s surface, which decreases corrosion rate of lead in the atmospheric environment polluted by organic acids’ vapour. Our research aims at the selection of a suitable protection system that would be applicable to conservation of historical lead in archives and museums. This paper evaluates the corrosion behaviour of treated lead based on the values of polarisation resistance and shape of potentiodynamic curves in simulated corrosive environment (0.01 mol l−1 solution of acetic acid). The lead samples with different state of surface (pure, corroded and electrochemically cleaned) were treated with sodium salts of monocarboxylic acids NaCn (n = 10, 11, 12) having concentration of 0.01 and 0.05 mol l−1. In simulated corrosive atmosphere (above 0.001 mol l−1 acetic acid solution vapours), corrosion rate was measured by means of electrical resistance technique. The inhibition efficiency of monocarboxylic acids is dependent on their carbon chain length and their concentration. The greatest inhibiting efficiency in corrosive atmospheres and for all lead samples was observed for the sodium salt of dodecanoic acid having concentration of 0.05 mol l−1. Artificially created corrosion products and salt coatings were analysed by X-ray diffraction analysis and their surface morphology was observed by scanning electron microscopy. A protective salt coatings are mainly composed of metallic soaps in dimer form.
摘要档案环境中的铅受到通常存在于这种环境中的有机酸蒸汽引起的严重腐蚀。铅防腐的一种可能方法是通过一元羧酸(通式CH3(CH2)n-2COONa,记为NaCn,n=10,11,12)的钠盐溶液对铅进行表面处理。这种防腐的原理是在铅表面形成转化涂层,从而降低铅在被有机酸蒸汽污染的大气环境中的腐蚀速率。我们的研究旨在选择一种适用于档案馆和博物馆历史铅保护的合适保护系统。本文根据模拟腐蚀环境(0.01mol l−1乙酸溶液)中的极化电阻值和动电位曲线形状,评估了处理过的铅的腐蚀行为。用浓度分别为0.01和0.05 mol l−1的一元羧酸NaCn(n=10,11,12)钠盐处理具有不同表面状态(纯净、腐蚀和电化学清洁)的铅样品。在模拟腐蚀性环境(高于0.001 mol l−1乙酸溶液蒸汽)中,通过电阻技术测量腐蚀速率。一元羧酸的抑制效率取决于它们的碳链长度和浓度。在腐蚀性环境和所有铅样品中,浓度为0.05 mol l−1的十二烷酸钠盐的抑制效率最高。通过X射线衍射分析对人工产生的腐蚀产物和盐层进行了分析,并通过扫描电子显微镜观察了它们的表面形态。保护性盐涂层主要由二聚体形式的金属皂组成。
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引用次数: 2
Restoration investigation of paint systems of steel structure of Main railway Prague 布拉格主干线钢结构涂料系统修复研究
Q3 Materials Science Pub Date : 2019-03-01 DOI: 10.2478/kom-2019-0002
H. Geiplová, L. Mindos, J. Mrazek, D. Majtás, P. Mácová, P. Pokorný
Abstract The paper follows the paper describing the condition of wrought iron structure of main railway station [1]. In this paper the investigation of condition of paint system corrosion surface treatment is given and the restoration procedure is described. The withdrawal samples of paint systems were analysed by stratigraphy, FTIR and XRF analysis. Due to identification of Pb pigment presence in primer the water jet technology was chosen which minimalised the danger waste formation.
摘要本文介绍了铁路主站锻铁结构的状况[1]。本文对涂料系统腐蚀表面处理情况进行了调查,并介绍了修复过程。通过地层学、FTIR和XRF分析对涂料体系的提取样品进行了分析。由于识别出底漆中存在Pb颜料,因此选择了水喷射技术,以最大限度地减少危险废物的形成。
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引用次数: 1
Influence of hydrate formation and wall shear stress on the corrosion rate of industrial pipeline materials 水合物形成和管壁剪切应力对工业管道材料腐蚀速率的影响
Q3 Materials Science Pub Date : 2018-12-01 DOI: 10.2478/kom-2018-0017
L. Poberezhny, A. Hrytsanchuk, G. Hrytsuliak, L. Poberezhna, M. Kosmii
Abstract In the modern systems of transportation of oil, gas and condensate, in the units of regasification of liquefied natural gas, two-phase flows play an increasingly important role in technological equipment used in the chemical and oil refining industry, power engineering and other industries. All available studies on the formation of gas hydrates were mainly focused on their ability to clog pipes along their entire length. While their ability to cause (initiate) corrosion remains virtually unexplored. Therefore, to increase the efficiency of industrial pipelines it is necessary to study the joint effect of hydration formation and stresses of friction on corrosion of the pipeline. The mathematical model of pipeline corrosion has been further developed by considering the influence of the gas hydrate. The influence of pressure, temperature on the speed of corrosion processes is estimated and it is shown that under the most unfavorable conditions the corrosion rate under the action of gas hydrates can increase several times.
摘要在现代石油、天然气和凝析油运输系统中,在液化天然气再气化装置中,两相流在化工、炼油、电力工程和其他行业的技术设备中发挥着越来越重要的作用。所有关于天然气水合物形成的现有研究主要集中在它们堵塞管道全长的能力上。尽管它们引起(引发)腐蚀的能力实际上尚未被探索。因此,为了提高工业管道的效率,有必要研究水化形成和摩擦应力对管道腐蚀的联合作用。考虑天然气水合物的影响,进一步建立了管道腐蚀的数学模型。估算了压力、温度对腐蚀过程速度的影响,结果表明,在最不利的条件下,天然气水合物作用下的腐蚀速率可以增加数倍。
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引用次数: 8
Evaluation of mechanical properties of gas pipeline DN 500 after more than 40 years of its operation DN500输气管道运行40多年后的力学性能评估
Q3 Materials Science Pub Date : 2018-12-01 DOI: 10.2478/kom-2018-0016
M. Hagarová, D. Jakubéczyová, G. Baranová, M. Fujda
Abstract The paper deals with the mechanical properties of steel gas pipeline DN 500 after more than 40 years of operation. Mechanical properties of the pipeline were established by a tensile test at an ambient temperature according to the standard EN ISO 6892-1. The resistance of the pipeline against brittle failure was evaluated by using Charpy impact test according to EN 10045-1. The character of fracture surface after the Charpy test was analysed by using scanning electron microscopy. A high proportion of transcrystalline cleavage was a characteristic feature of fracture surfaces. Mechanical characteristics obtained by static tensile testing were compared with the values obtained from steel manufacturer. Higher elongation was observed in a parallel direction compared to the perpendicular direction to the axis of the pipe. The observed anisotropy of properties was related to the distribution of inclusions in the direction of the deformation of the steel sheets used for the pipeline construction.
本文介绍了DN500钢制输气管道在运行40多年后的力学性能。管道的机械性能是根据标准EN ISO 6892-1在环境温度下通过拉伸试验确定的。根据EN 10045-1,采用夏比冲击试验对管道的脆性破坏阻力进行了评估。用扫描电子显微镜分析了夏比试验后的断口特征。高比例的穿晶解理是断口的一个特征。通过静态拉伸试验获得的机械特性与从钢铁制造商获得的值进行了比较。与垂直于管道轴线的方向相比,在平行方向上观察到更高的伸长率。观察到的性能各向异性与管道施工用钢板变形方向上夹杂物的分布有关。
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引用次数: 1
Corrosion resistance of stainless steel in drinking water treatment plants and water storage units 饮用水处理厂和储水装置中不锈钢的耐腐蚀性
Q3 Materials Science Pub Date : 2018-12-01 DOI: 10.2478/kom-2018-0020
T. Prošek, V. Šefl
Abstract Main factors affecting the corrosivity of water in water treatment plants and water towers and other storage facilities, observed types of corrosion degradation of stainless steel and the effect of manufacturing and surface treatment on their corrosion resistance are discussed. A list of stainless steel grades currently used in the field of treatment, transport and storage of drinking water is given together with some other suitable ones. Based on literature resources, optimal stainless steel grades are recommended as a function of water composition and treatment method.
文摘:讨论了影响水处理厂、水塔和其他储存设施中水腐蚀性的主要因素,观察到的不锈钢腐蚀降解类型,以及制造和表面处理对其耐腐蚀性的影响。列出了目前用于饮用水处理、运输和储存领域的不锈钢等级,以及其他一些合适的不锈钢等级。根据文献资源,根据水成分和处理方法,推荐了最佳不锈钢等级。
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引用次数: 0
Comparison of the thermal stability of magnesium phosphate (newberyite) coating with conventional zinc phosphate (hopeite) coating 磷酸镁(新铍石)涂层与常规磷酸锌(希望石)涂层热稳定性的比较
Q3 Materials Science Pub Date : 2018-12-01 DOI: 10.2478/kom-2018-0018
P. Pokorný
Abstract This article presents a detail comparison of the thermal stability of the new magnesium phosphate (newberyite – MgHPO4·3H2O) coating with a conventional coating of zinc phosphate (hopeite – Zn3(PO4)2·4H2O). It was confirmed that dehydration of zinc phosphate (hopeite) occurs gradually (dehydration start temperature: 115 °C). The start of magnesium phosphate (newberyite) dehydration is indeed shifted to somewhat higher temperatures (about 125 °C) but the dehydration has an intense jump character. When using magnesium phosphate (newberyite) coating for further surface treatment at higher temperatures, dehydration of the coating can result in reduction of the adhesion between the phosphate/primer coatings. Under these conditions, it is recommended to use a coating of conventional zinc phosphate (hopeite) or manganese phosphate (hurealite).
摘要本文详细比较了新型磷酸镁涂层(newberyite–MgHPO4·3H2O)与传统磷酸锌涂层(hopeite–Zn3(PO4)2·4H2O)的热稳定性。经证实,磷酸锌(hopeite)的脱水是逐渐发生的(脱水开始温度:115°C)。磷酸镁(新镁石)脱水的开始确实转移到了更高的温度(约125°C),但脱水具有强烈的跳跃性。当在更高的温度下使用磷酸镁(菜白石)涂层进行进一步的表面处理时,涂层的脱水会导致磷酸盐/底漆涂层之间的附着力降低。在这些条件下,建议使用传统的磷酸锌(hopelite)或磷酸锰(hurealite)涂层。
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引用次数: 1
Application of thermal analysis for the evaluation of mineral solution penetration into wood 热分析在评价矿物溶液渗透木材中的应用
Q3 Materials Science Pub Date : 2018-12-01 DOI: 10.2478/kom-2018-0019
T. Majstríková, J. Daňková, P. Mec
Abstract Interaction of mineral solutions with solid wood leads to saturation of the wood matrix, then to the deposition of mineral particles and eventually to reaction with wood components. In this way a partially or fully mineralized wood occurs in natural or artificial conditions, whose physical-mechanical properties are influenced by the retention and by the character of the solution. Targeted application of organosilanes is based on a similar principle that reduces the intake of liquid water and thus leads to an increase in durability, however, it also causes wood corrosion and consequent decrease in mechanical parameters. In this study, penetration of commercial organosilanes-based product Lukofob 39 into solid wood was described in order to determine the extent of the mineralized part into which the solution penetrated. In this case, characteristic mineral deposits are formed in the wood matrix and its quantification by thermal analysis can be advantageously used to describe the penetration of the solution. Based on the analyses of specific samples taken from primary specimens with different exposure times in the solution, it can be stated that with the increasing exposition time the penetration depth of the solution as well as the amount of mineral deposits increase. The shifts on the thermal analysis curves also show the corrosion effects of Lukofob 39 on the basic components of wood.
矿物溶液与实木的相互作用导致木材基体饱和,然后导致矿物颗粒沉积,最终与木材组分发生反应。通过这种方式,部分或完全矿化的木材在自然或人工条件下产生,其物理机械性能受到保留和溶液特性的影响。有机硅烷的定向应用基于类似的原理,即减少液态水的摄入量,从而提高耐久性,然而,它也会导致木材腐蚀,从而导致机械参数下降。在本研究中,描述了商业有机硅烷基产品Lukofob 39对实木的渗透,以确定溶液渗透的矿化部分的程度。在这种情况下,木材基质中形成了特征矿床,通过热分析对其进行量化可以有利地用于描述溶液的渗透。通过对不同暴露时间的原生试样的具体样品分析可知,随着暴露时间的增加,溶液的渗透深度和矿床的数量都在增加。热分析曲线的变化也表明Lukofob 39对木材基本组分的腐蚀作用。
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引用次数: 0
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Koroze a ochrana materialu
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