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Effects of Alloying Elements on the Microstructure and Mechanical Properties of Novel α+β Dual-Phase Ti-Nb-Ta-Zr Alloys 合金元素对新型α+β双相Ti-Nb-Ta-Zr合金组织和力学性能的影响
Pub Date : 2020-12-11 DOI: 10.2139/ssrn.3746792
Tingan Zhang, Daixiu Wei, Liqiang Wang, Eryi Lu, Wen Wang, Kuai-She Wang, Xiaoqing Li, Lai‐Chang Zhang, H. Kato, Weijie Lu
A series of novel α+β dual-phase Ti-Nb-Ta-Zr (Ti-(3, 5) wt.% Nb-(2, 10, 13) wt.% Ta- 2 wt.% Zr) alloys with low elastic modulus were designed by reducing the stability of β-phase under the guidelines of ab initio calculations and d-electronic theory. The alloys exhibit typical characteristics of α+β dual-phase microstructure. Among the alloys, Ti-3Nb-13Ta-2Zr alloy shows the lowest Young’s modulus (61 GPa) with highest ultimate tensile strength (779 MPa), mainly attributed to the combination of α + β dual-phase structure with stress-induced α" martensite. Moreover, {0001} α α and {001} β β textures also contribute to the reduction of elastic modulus of the alloy. Atom probe tomography analysis reveals that the elemental partitioning between α and β leads to the enrichment of solutes (Nb, Ta, Zr) in the β phase, and the elements distribution in the β phase is uneven.
采用从头计算和d电子理论,通过降低β相的稳定性,设计了一系列具有低弹性模量的新型α+β双相Ti-Nb-Ta-Zr (Ti-(3,5) wt.% Nb-(2,10,13) wt.% Ta- 2wt .% Zr)合金。合金具有典型的α+β双相组织特征。其中,Ti-3Nb-13Ta-2Zr合金的杨氏模量最低(61 GPa),极限抗拉强度最高(779 MPa),这主要是由于α + β双相组织与应力诱导的α”马氏体结合所致。{0001} α α和{001}β β织构也导致合金弹性模量的降低。原子探针层析分析表明,α和β之间的元素分配导致溶质(Nb、Ta、Zr)在β相中富集,且元素在β相中分布不均匀。
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引用次数: 0
Thermodynamic, Thermal and Elastic Properties of Titanium Nitride TiN: Comparison of Various Data and Determination of the Most Reliable Values 氮化钛TiN的热力学、热学和弹性性能:各种数据的比较和最可靠值的确定
Pub Date : 2020-11-30 DOI: 10.21303/2585-6847.2020.001475
A. Kozma
The analysis of literary data on thermodynamic, thermal and elastic properties of titanium nitride TiN which included values Debye temperature θD, volume coefficient of thermal expansion αV and bulk modulus B under standard conditions is carried out. It has been shown that the known data have a significant spread of values from 20 to 43 %. The 8 most rational variants of optimizing calculations are proposed, which make it possible to reveal the most reliable values of some TiN parameters. At the same time, the minimum and maximum values of θD and αV were used from literary sources, as well as the least contradictory data on isobaric heat capacity Cp, melting temperature Tm.p and density d of TiN. To improve the calculated results, the values of θD(TiN) determined using the methods of Magnus ‒ Lindeman and Debye were also used. The Mayer’s relation was the basic test expression. The obtained values of the bulk modulus were compared with the literature data. This made it possible to distinguish the least and most reliable values of αV and θD, as well as make a refinement correction for the last value. As a result, it was found that under standard conditions, the value of θD(TiN) close to the optimal should be within 746‒769 K, and for its isochoric heat capacity CV ‒ in the range 36.55‒37.19 J/(mol×K). The range of values, after optimization, does not exceed 3 %, unlike the 20 % available in the literature. A more accurate definition of Debye temperature for TiN needs to radically refine the values of its αV and B
对标准条件下氮化钛TiN的热力学、热学和弹性性能(德拜温度θD、体积热膨胀系数αV和体积模量B)进行了文献数据分析。结果表明,已知数据的值在20%到43%之间有显著的分布。提出了8种最合理的优化计算变体,从而可以揭示某些TiN参数的最可靠值。同时,θD和αV的最小值和最大值采用文献资料,以及等压热容Cp、熔化温度Tm等矛盾最小的数据。p和TiN的密度d。为了改进计算结果,θD(TiN)也采用Magnus - Lindeman和Debye法测定的值。梅耶尔关系是基本的测试表达式。所得的体模量与文献数据进行了比较。这样就可以区分αV和θD的最小值和最可靠值,并对最后的值进行精化校正。结果发现,在标准条件下,θD(TiN)接近最优值应在746 ~ 769 K之间,其等时热容CV -在36.55 ~ 37.19 J/(mol×K)之间。优化后的取值范围不超过3%,而不像文献中提供的20%。更准确地定义TiN的德拜温度需要从根本上改进其αV和B的值
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引用次数: 4
Analysis of Free Oscillations of a Non-Homogeneous Pipe Along Thickness and Length, Taking Into Account the Resistance of the External Environment 考虑外部环境阻力的非均匀管道沿厚度和长度自由振荡分析
Pub Date : 2020-10-30 DOI: 10.15587/2706-5448.2020.213475
G. Mirzayeva, V. Rzayeva
Structural elements made of heterogeneous natural and artificial materials are widely used in the construction of modern building complexes and in many other areas. Among them is the use of boards and shells of different configurations. Currently, one of the most important requirements for designers and accountants is to properly assess the mechanical properties of the material of the structural element and the impact of the environment in contact during operation. Taking these into account, the mathematical solution of the problem becomes difficult, and if not, serious mistakes can be made. One of the most problematic places is considering the resistance of the external environment.

Objects of research are modern pipes exposed to the external environment.

In the paper is analysis Pasternak is one of the mathematical models that accurately reflects the elastic real properties of the environment, the model Winkler, which is characterized by two constants, the model of Karnet and the model of Rjanitsin. And is analysis their effected.

In the course of the research, the method of separation of variables and then Bubnov-Galerkin method is used, which explain relationship between the dimensionless value of frequency, the parameters that characterize the non-homogeneous of the base, and the pipe. The selection of special frequencies is carried out by selecting the corresponding special equation and boundary conditions. There are nonlinear algebraic equations and their solution using computer technology. It is shown that when the mechanical properties of the pipe vary in length, the above solution method does not work and the determination of the characteristic parameters must be performed using other approximate analytical methods. In engineering practice, it is usually sufficient to find the basic tone of the frequency. As a result of the research it is shown that the external environment effects are important for non-homogeneous pipe and should be considered in the design of the structure-ground interaction. In the future, the proposed approach and should be considered in the design of the structure non-homogenous pipe interaction.
异质天然和人造材料制成的结构构件广泛应用于现代建筑综合体和许多其他领域。其中之一就是使用不同配置的板和壳。目前,对设计人员和会计人员最重要的要求之一是正确评估结构元件材料的力学性能以及在运行过程中所接触的环境的影响。考虑到这些因素,问题的数学解就会变得困难,否则就会犯严重的错误。其中一个最成问题的地方是考虑外部环境的阻力。研究对象是暴露在外部环境中的现代管道。在本文的分析中,帕斯捷尔纳克模型是准确反映环境弹性真实特性的数学模型之一,即Winkler模型,其特征为两个常数,Karnet模型和Rjanitsin模型。这是分析他们的影响。在研究过程中,先采用分离变量的方法,再采用布布诺夫-伽辽金方法,解释了频率的无因次值、表征基底非均匀性的参数与管道之间的关系。通过选择相应的特殊方程和边界条件来进行特殊频率的选择。非线性代数方程及其计算机解法。结果表明,当管道的力学性能随长度变化时,上述求解方法不起作用,必须采用其他近似解析方法确定特征参数。在工程实践中,通常只要找到频率的基音就足够了。研究结果表明,外部环境对非均质管道的影响非常重要,在结构-地面相互作用的设计中应予以考虑。今后,本文提出的方法应在非均质管道相互作用的结构设计中加以考虑。
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引用次数: 0
Prediction of Elastic Stresses in Porous Materials Using Fully Convolutional Networks 利用全卷积网络预测多孔材料的弹性应力
Pub Date : 2020-10-19 DOI: 10.2139/ssrn.3714501
Ö. Keleş, Yinchuan He, B. Sirkeci-Mergen
Abstract Machine learning (ML) models enable exploration of vast structural space faster than the traditional methods, such as finite element method (FEM). This makes ML models suitable for stochastic fracture problems in brittle porous materials. In this work, fully convolutional networks (FCNs) were trained to predict stress and stress concentration factor distributions in two-dimensional isotropic elastic materials with uniform porosity. We show that even with downsampled data, FCN models predict the stress distributions for a given porous structure. FCN predicted stress concentration factors 10,000 times faster than the FEM simulations. The FCN-predicted stresses combined with fracture mechanics captured the effect of porosity on the strength of porous glass. Increasing variations in pore size increased the variations in fracture strength. Furthermore, the FCN model predicts the pore configurations with the lowest and highest stresses from a set of structures, enabling ML optimization of porous microstructures for increased reliability.
机器学习(ML)模型能够比传统的方法(如有限元法(FEM))更快地探索广阔的结构空间。这使得ML模型适用于脆性多孔材料的随机断裂问题。在这项工作中,训练全卷积网络(fcv)来预测具有均匀孔隙率的二维各向同性弹性材料的应力和应力集中系数分布。我们表明,即使使用下采样数据,FCN模型也可以预测给定多孔结构的应力分布。FCN预测应力集中系数的速度比FEM模拟快1万倍。结合断裂力学,fcn预测的应力捕获了孔隙率对多孔玻璃强度的影响。孔隙大小的变化增加了断裂强度的变化。此外,FCN模型预测了一组结构中具有最低和最高应力的孔隙结构,从而实现了多孔微结构的ML优化,从而提高了可靠性。
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引用次数: 1
Slip System Selection and Taylor Factor Evolution in FCC Metals FCC金属的滑移系统选择与泰勒因子演化
Pub Date : 2020-06-11 DOI: 10.2139/ssrn.3618715
J. Hirsch, Evgenij Aryshesnkij, S. Konovalov
The prediction of active slip systems during plastic deformation is analyzed for FCC metals under various deformation conditions (uniaxial, plane strain). The analysis reveals the orientation dependent stress contributions (Taylor factor and similar) and metallurgical effects of dislocation interaction, resulting in strain hardening and recrystallization mechanisms, i.e. nucleation and driving force for grain boundary motion. In technical terms the orientation effective strength as quantified by the Schmid- or Taylor-factor is of main interest for mechanical and anisotropic behavior of metal parts. The activated {111} slip systems and the relative amount of glide is evaluated for the case of stable orientations in uniaxial (tension, compression, bi-axial loading) and plane strain deformation (sheet rolling) in FCC metals. The classical Taylor analysis and related texture simulation models are applied under conditions of full and various relaxed constraints, considering the various boundary conditions, as described in the classical Sachs and Taylor models and derived "Relaxed Constraints" (RC) or "Grain Inter-Action" (GIA) models. These models which describe the principle effects slip system selection during plastic deformation and related texture formation and orientation stability have been analyzed for active slip systems and resulting stress contributions of stable orientations and textures of FCC metals.
分析了FCC金属在不同变形条件(单轴、平面应变)下塑性变形过程中主动滑移系统的预测。分析揭示了取向依赖的应力贡献(泰勒因子和类似因素)和位错相互作用的冶金效应,导致应变硬化和再结晶机制,即晶界运动的形核和驱动力。在技术术语中,施密德或泰勒因子量化的取向有效强度对金属零件的力学和各向异性行为具有重要意义。在FCC金属的单轴(拉伸、压缩、双轴加载)和平面应变变形(板轧制)稳定取向的情况下,评估了激活的{111}滑动系统和滑动的相对量。经典的Taylor分析和相关的纹理模拟模型是在充分约束和各种松弛约束的条件下应用的,考虑到各种边界条件,如经典的Sachs和Taylor模型以及派生的“松弛约束”(RC)或“颗粒相互作用”(GIA)模型。这些模型描述了塑性变形过程中滑移体系选择的主要影响以及相关织构形成和取向稳定性,分析了FCC金属的主动滑移体系以及由此产生的稳定取向和织构的应力贡献。
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引用次数: 1
Rate-Dependent Mechanical Behaviour of Semilunar Valves Under Biaxial Deformation: From Quasi-Static to Physiological Loading Rates 双轴变形下半月瓣的速率相关力学行为:从准静态到生理加载速率
Pub Date : 2020-01-23 DOI: 10.2139/ssrn.3455094
A. Anssari-Benam, Y. Tseng, Gerhard A. Holzapfel, A. Bucchi
In this study we investigate the rate-dependency of the mechanical behaviour of semilunar heart valves under biaxial deformation, from quasi-static to physiological loading rates. This work extends and complements our previous undertaking, where the rate-dependency in the mechanical behaviour of semilunar valve specimens was documented in sub-physiological rate domains (Acta Biomater. 2019; https://doi.org/10.1016/j.actbio.2019.02.008). For the first time we demonstrate herein that the stress-stretch curves obtained from specimens under physiological rates too are markedly different to those at sufficiently lower rates and at quasi-static conditions. The results importantly underline that the mechanical behaviour of semilunar heart valves is rate dependent, and the physiological mechanical behaviour of the valves may not be correctly obtained via material characterisation tests at arbitrary low deformation rates. Presented results in this work provide an inclusive dataset for material characterisation and modelling of semilunar heart valves across a 10,000 fold deformation rate, both under equi-biaxial and 1:3 ratio deformation rates. The important application of these results is to inform the development of appropriate mechanical testing protocols, as well as devising new models, for suitable determination of the rate-dependent constitutive mechanical behaviour of the semilunar valves.
在这项研究中,我们研究了双轴变形下半月心瓣膜的机械行为的速率依赖性,从准静态到生理加载速率。这项工作扩展并补充了我们之前的工作,其中在亚生理速率域中记录了半月瓣标本机械行为的速率依赖性(Acta Biomater. 2019;https://doi.org/10.1016/j.actbio.2019.02.008)。本文首次证明了在生理速率下得到的应力-拉伸曲线与在足够低的速率和准静态条件下得到的应力-拉伸曲线也有显著不同。结果重要地强调,半月心瓣膜的力学行为是速率依赖的,在任意低变形率下,瓣膜的生理力学行为可能无法通过材料表征试验正确获得。在这项工作中提出的结果提供了一个包容性的数据集,用于在10,000倍变形率下的半月形心脏瓣膜的材料表征和建模,包括在等双轴和1:3比变形率下。这些结果的重要应用是告知适当的机械测试方案的发展,以及设计新的模型,以适当地确定半月形阀的速率相关的本构力学行为。
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引用次数: 3
Direct Correlation of the Crack Distribution in APS Thermal Barrier Coatings with the Measured Synchrotron XRD Residual Stress Distribution APS热障涂层裂纹分布与同步加速器x射线衍射残余应力分布的直接关系
Pub Date : 2020-01-10 DOI: 10.2139/ssrn.3513103
C. Lia, R. Cernik
Residual stress distributions as a function of depth in APS TBCs after different heat treatment times have been measured by synchrotron XRD. Three types of residual stress distribution were observed. The first type was a low stress state from the as-received sample; the second type was a compressive stress state increasing from the surface to the interface with a discontinuous "jump feature" in the trend near the interface; the third type of residual stress distribution has two "jump" features in the trend, one was observed near the sample surface and the other near the interface. To understand the double "jump" features in the third kind of trend, the 3D microstructures of the measured samples were systematically measured X-ray μ-CT. Vertical cracks and edge cracks were observed. We have shown by image based modelling that the vertical cracks do not have a large effect on the residual stress distribution and that edge cracks are related to the "jump features" near the sample surface. The edge crack can be observed in all the measured samples with the third kind of the residual stress trend; and the measured samples with the second kind of the residual stress trend are crack free. The relationship between the middle and the through edge cracks and the residual stress distribution was also investigated by image based modelling. It was found that the middle crack can also cause a "jump feature" near the sample surface while the through edge crack seems to not have a large effect on the residual stress distribution. A semi-destructive method was developed to determine the existence and the position of horizontal cracks in the APS TBC samples based on the above findings.
采用同步加速器x射线衍射仪(XRD)测量了不同热处理次数后APS tbc中残余应力随深度的分布。观察到三种类型的残余应力分布。第一种是接收样品的低应力状态;第二种是压应力从表面向界面递增,在界面附近呈不连续的“跳变”趋势;第三类残余应力分布在趋势上有两个“跳跃”特征,一个在试样表面附近,另一个在界面附近。为了解第三种趋势的双“跳变”特征,采用x射线μ-CT系统测量了被测样品的三维显微结构。观察到垂直裂纹和边缘裂纹。我们已经通过基于图像的建模表明,垂直裂缝对残余应力分布没有很大的影响,边缘裂缝与样品表面附近的“跳跃特征”有关。所有试样均存在边缘裂纹,残余应力趋势均为第三种;第二种残余应力趋势下的试样无裂纹。采用基于图像的建模方法研究了中间裂纹和贯通裂纹与残余应力分布的关系。发现中间裂纹也会引起试样表面附近的“跳跃特征”,而贯通边缘裂纹对残余应力分布的影响似乎不大。在此基础上,提出了一种半破坏性的方法来确定APS TBC试样中水平裂纹的存在和位置。
{"title":"Direct Correlation of the Crack Distribution in APS Thermal Barrier Coatings with the Measured Synchrotron XRD Residual Stress Distribution","authors":"C. Lia, R. Cernik","doi":"10.2139/ssrn.3513103","DOIUrl":"https://doi.org/10.2139/ssrn.3513103","url":null,"abstract":"Residual stress distributions as a function of depth in APS TBCs after different heat treatment times have been measured by synchrotron XRD. Three types of residual stress distribution were observed. The first type was a low stress state from the as-received sample; the second type was a compressive stress state increasing from the surface to the interface with a discontinuous \"jump feature\" in the trend near the interface; the third type of residual stress distribution has two \"jump\" features in the trend, one was observed near the sample surface and the other near the interface. To understand the double \"jump\" features in the third kind of trend, the 3D microstructures of the measured samples were systematically measured X-ray μ-CT. Vertical cracks and edge cracks were observed. We have shown by image based modelling that the vertical cracks do not have a large effect on the residual stress distribution and that edge cracks are related to the \"jump features\" near the sample surface. The edge crack can be observed in all the measured samples with the third kind of the residual stress trend; and the measured samples with the second kind of the residual stress trend are crack free. The relationship between the middle and the through edge cracks and the residual stress distribution was also investigated by image based modelling. It was found that the middle crack can also cause a \"jump feature\" near the sample surface while the through edge crack seems to not have a large effect on the residual stress distribution. A semi-destructive method was developed to determine the existence and the position of horizontal cracks in the APS TBC samples based on the above findings.","PeriodicalId":180833,"journal":{"name":"Mechanical Properties & Deformation of Materials eJournal","volume":"13 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2020-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133602715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study Towards Green Concrete for Better Sustainable Construction 绿色混凝土研究促进可持续建筑
Pub Date : 2019-12-30 DOI: 10.2139/ssrn.3511629
K. Das, Trina Dutta, S. Chattaraj, Aditya Dasgupta, T. Mondal, A. Chakraborty, Akash Roy, Moutoshi Das
Concrete which has been made from waste of concrete that are eco friendly is termed as green concrete. 8 to 10% of world total CO2 emission comes from production of cement, when lime stone and crushed clay are heated at high temperature during the production. Green concrete uses waste material at least one of its component and environment destruction did not occur during the time of production. Researchers have conducted various experiments to find perfect solution for sustainable construction and from them green concrete is one. Here an effort has been made to inculcate the ideas about the mechanical and rheological properties of Green Concrete grade M25 by replacing cement with micro silica, fine and coarse aggregates with crushed recycled aggregates and crushed glass from 10 to 30% replacement by weight of the materials. And they have been compared with conventional mixed concrete. It has been observed that when cement, sand and coarse aggregate is replaced by 30% 0f micro silica, 20% crushed recycled aggregates and 30% crushed glass it has shown a better result in mechanical and fresh property with respect to conventional concrete.
用废弃的环保混凝土制成的混凝土被称为绿色混凝土。世界总二氧化碳排放量的8 - 10%来自水泥生产,在生产过程中石灰石和碎粘土在高温下加热。绿色混凝土使用的是废料,它的至少一种成分和环境在生产时没有发生破坏。研究人员进行了各种各样的实验来寻找可持续建筑的完美解决方案,绿色混凝土就是其中之一。在这里,通过用微二氧化硅代替水泥,用破碎的再生骨料和破碎的玻璃代替细骨料和粗骨料,努力灌输关于M25级绿色混凝土的机械和流变特性的想法,这些材料的重量替代率为10%到30%。并与常规混合混凝土进行了比较。研究发现,用30%的微硅粉、20%的破碎再生骨料和30%的破碎玻璃代替水泥、砂石和粗骨料,其力学性能和新鲜性能均优于常规混凝土。
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引用次数: 0
Bio-Mimic Ti-Ta Composite with Hierarchical 'Brick-and-Mortar' Microstructure 具有分层“砖瓦”微观结构的仿生Ti-Ta复合材料
Pub Date : 2019-07-24 DOI: 10.2139/ssrn.3425440
Shenghang Xu, M. Du, Jia Li, K. Yan, B. Cai, Quanfeng He, Q. Fang, O. Magdysyuk, Bin Liu, Yong Yang, Yong Liu
Nature materials, such as bones and nacre, achieve excellent balance of toughness and strength via a hierarchical "brick-and-mortar" microstructure, which is an attractive model for engineering materials design. Here, we produced nacre-like Ti-Ta metallic composites via a powder metallurgy process, during which milled powders were sintered by spark plasma sintering, followed by hot rolling and then annealing. The structure consists of soft Ta-enriched regions and hard Ti-enriched regions in a hierarchical and laminated fashion. The microstructural heterogeneity spans several scales due to the diffusion between Ti and Ta. This yields a novel metal-metal composite with a balanced combination of strength and ductility (1226 MPa ultimate tensile strength and 20.8% elongation), outperforming most of conventional Ti based alloys and composites. Via complementary in situ synchrotron X-ray diffraction and electron microscopies, it is found out that multiple micromechanisms are active, including nano-particle and dislocation localized strengthening as well as a "phase transformation induced plasticity. The manufacturing route developed here is versatile, capable of making high performance bio-mimic metallic composites.
自然材料,如骨骼和珍珠,通过分层的“砖和砂浆”微观结构实现了韧性和强度的良好平衡,这是工程材料设计的一个有吸引力的模型。在这里,我们通过粉末冶金工艺制备了类珠状Ti-Ta金属复合材料,在此过程中,研磨好的粉末通过火花等离子烧结,然后进行热轧,然后退火。该结构由软富ta区和硬富ti区组成,呈分层层状。由于Ti和Ta之间的扩散,微观组织的非均质性跨越了多个尺度。这就产生了一种新型的金属-金属复合材料,它具有平衡的强度和延展性(1226 MPa的极限抗拉强度和20.8%的伸长率),优于大多数传统的钛基合金和复合材料。通过原位同步加速器x射线衍射和电子显微镜观察,发现了多种微观机制,包括纳米颗粒和位错局部强化以及相变诱导塑性。本研究开发的制造路线具有通用性,能够制造高性能仿生金属复合材料。
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引用次数: 3
Development of Strong and Ductile Metastable Face-Centered Cubic Single-Phase High-Entropy Alloys 强延展性亚稳面心立方单相高熵合金的研制
Pub Date : 2019-07-08 DOI: 10.2139/ssrn.3416324
Daixiu Wei, Xiaoqing Li, S. Schönecker, Jing Jiang, W. Choi, Byeong-Joo Lee, Hyoung-Seop Kim, A. Chiba, H. Kato
Abstract Face-centered cubic (fcc)-phase high-entropy alloys (HEAs) have attracted much academic interest, with the stacking fault energy (SFE) playing an important role in regulating their mechanical behaviors. Here, we revealed the principles for regulating both the elastic and plastic behaviors by composition modification and Mo addition in an fcc-phase quaternary CoCrFeNi system with the assistance of ab initio and thermodynamics calculations. An increase in Co content and a decrease in Fe and Ni contents reduced the fcc phase stability and SFE, but enhanced the elastic modulus, anisotropy, and lattice friction stress. A minor substitution of Co by Mo increased the lattice constant, but decreased the SFE and elastic modulus. Based on these findings, we developed a series of strong and ductile metastable fcc-phase CoxCr25(FeNi)70-xMo5 (x = 30, 40, 50) HEAs with mechanical properties superior to those of the CoCrFeNi HEAs. The careful investigation revealed that the enhanced mechanical properties are due to the Mo-addition-induced strengthening accompanied with a low-SFE-induced restriction of planar behavior of dislocations, mechanical twinning, and strain-induced martensitic transformation. The findings shed light on the development of high-performance HEAs.
摘要面心立方(fcc)相高熵合金(HEAs)的力学行为受层错能(SFE)的调控,引起了学术界的广泛关注。本文通过从头算和热力学计算,揭示了组分改性和Mo加入对fcc相四元CoCrFeNi体系弹性和塑性行为的调节原理。Co含量的增加和Fe、Ni含量的降低降低了fcc的相稳定性和SFE,但提高了fcc的弹性模量、各向异性和晶格摩擦应力。少量的Mo取代Co增加了晶格常数,但降低了SFE和弹性模量。基于这些发现,我们开发了一系列强韧性的亚稳fcc相CoxCr25(FeNi)70-xMo5 (x = 30,40,50)HEAs,其力学性能优于CoCrFeNi HEAs。仔细的研究表明,力学性能的增强是由于mo添加诱导的强化伴随着低sfe诱导的位错、机械孪晶和应变诱导马氏体转变的平面行为的限制。这些发现为高性能HEAs的发展提供了线索。
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引用次数: 121
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