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Microscopic Aggregation and Film-Forming Characteristics of Lubricant Additives on Oil–Water Interface: MD Simulation and Experiments on Water Separability 润滑油添加剂在油水界面上的微观聚集和成膜特性:水分离性的 MD 模拟和实验
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-16 DOI: 10.1002/ls.1718
Xinhuiyu Shen, Ya Lyu, Yingying Gong

The anti-emulsification property of lubricating oil is an important index to measure the quality of oil. In this paper, the behaviour of surfactants such as lubricating oil additives at the oil–water interface and the influence of the position of ethylene oxide (EO) and propylene oxide (PO) in the block polyether demulsifier on the demulsification effect were investigated by molecular simulation and experimental verification. The properties of seven lubricating oil additives with different functions and two pairs of isomers were investigated by molecular simulation, and their demulsification effects were verified by experiments. Some simulation results such as interface thickness and density distribution can accurately predict the experimental demulsification effect. Moreover, it was found that the position isomerism of surfactants affected the demulsification performance by changing the lipophilic balance and interface properties. The demulsification performance of sequenced copolymers is generally better than that of anti-sequenced copolymers. The accurate prediction of molecular dynamics simulation makes the selection of lubricating oil demulsifier more extensive and has practical application value.

润滑油的抗乳化性能是衡量油品质量的一项重要指标。本文通过分子模拟和实验验证,研究了润滑油添加剂等表面活性剂在油水界面上的行为,以及环氧乙烷(EO)和环氧丙烷(PO)在嵌段聚醚破乳剂中的位置对破乳化效果的影响。通过分子模拟研究了七种不同功能的润滑油添加剂和两对异构体的性能,并通过实验验证了它们的破乳化效果。一些模拟结果,如界面厚度和密度分布,可以准确预测实验中的破乳化效果。此外,研究还发现表面活性剂的位置异构会通过改变亲油平衡和界面特性来影响破乳性能。排序共聚物的破乳化性能普遍优于反排序共聚物。分子动力学模拟的精确预测使润滑油破乳化剂的选择更加广泛,具有实际应用价值。
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引用次数: 0
Additive Manufacturing of Composite Materials and Functionally Graded Structures Using Archerfish Hunting Technique 利用箭鱼狩猎技术增材制造复合材料和功能分级结构
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-07 DOI: 10.1002/ls.1716
B. Vijaya Prakash, Nitish Koushik, Sanjay Kumar Jha, Karuppasamy Ramasamy

This paper proposes an optimisation method for fabricating composite materials and functionally graded structures. Using the proposed method, 3D printing of copper (Cu)–polyethylene (PE) composite, Al2O3–ZrO2 ceramic composite and functionally graded CuO foams are utilised. This work aims to advance the capabilities of additive manufacturing by leveraging nature-inspired approaches to create complex, tailored structures with enhanced performance across various industries. The major objective of the proposed method is to reduce the feed rate and increase the airflow rate and airflow temperature for the heat transfer process. Using the proposed technique in the advanced preparation conditions, Cu–PE composites with unreliable Cu substances are fabricated. The PE binder particle is melting as well as forming thick composites by means of soft surfaces. Using the proposed AHO approach, functionally graded materials with common distributions can be efficiently optimised. By then, the proposed model is implemented on the MATLAB platform, and its execution is calculated using the current procedures. The proposed technique displays superior outcomes in all existing methods like wild horse optimiser, particle swarm optimisation and heap-based optimiser. The proposed method shows a throughput of 57 mm3. The existing method shows the throughput of 32, 27 and 45 mm3. The results show that the proposed method has higher throughput compared with existing methods.

本文提出了一种制造复合材料和功能分级结构的优化方法。利用所提出的方法,三维打印了铜(Cu)-聚乙烯(PE)复合材料、Al2O3-ZrO2 陶瓷复合材料和功能分级氧化铜泡沫。这项工作旨在利用自然启发的方法来创建复杂的定制结构,从而增强各行各业的性能,从而提高增材制造的能力。所提方法的主要目标是降低热传导过程中的进料速率,提高气流速率和气流温度。在先进的制备条件下使用所提出的技术,可以制造出含铜量不可靠的铜-聚乙烯复合材料。聚乙烯粘合剂颗粒正在熔化,并通过软表面形成厚复合材料。利用所提出的 AHO 方法,可以有效优化具有常见分布的功能分级材料。随后,在 MATLAB 平台上实现了所提出的模型,并使用当前程序对其执行情况进行了计算。与野马优化法、粒子群优化法和堆优化法等现有方法相比,所提出的技术显示出更优越的结果。拟议方法的吞吐量为 57 立方毫米。现有方法的吞吐量分别为 32、27 和 45 立方毫米。结果表明,与现有方法相比,建议的方法具有更高的吞吐量。
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引用次数: 0
Investigation on Surface Roughness and Power Consumption for Sustainability Assessment in Hard Turning of HSLA Steel With SPPP-AlTiSiN–Coated Carbide Tool Under Various Cooling-Lubrications 在不同冷却润滑条件下使用 SPPP-AlTiSiN 涂层硬质合金刀具硬车削 HSLA 钢时,为评估可持续性而对表面粗糙度和功耗进行的研究
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-30 DOI: 10.1002/ls.1717
Soumikh Roy, Arupam Pradhan, Smita Padhan, Anshuman Das, Sudhansu Ranjan Das, Debabrata Dhupal

The present research analyses the power consumption (P c) and surface roughness (R a) in hard turning of high-strength low-alloy (HSLA) grade AISI 4140 steel using a recently developed AlTiSiN-coated carbide tool under different cooling-lubrication conditions (dry, flooded, nanofluid-MQL). The nanofluid was prepared by mixing the MWCNT nanoparticles with an eco-friendly automotive radiator coolant (base fluid). The cooling-lubrication performance is investigated briefly by comparing the machining responses like machined surface morphology, tool wear, cutting force and temperature. The experiments associated with 46 trials were performed by considering various machining variables, namely cutting speed, nose radius, depth of cut, feed and cooling-lubrication methods. From the perspective of predictive modelling and multi-response optimisation, response surface methodology has been employed to minimise power consumption and surface roughness. Thereafter, the predictive modelling and optimisation results are implemented for economic analysis and energy-saving carbon footprint evaluation. This innovative research also addresses comparative environmental sustainability evaluation in hard turning under different cooling-lubrication conditions using a life cycle assessment methodology for cleaner and safer production. Results indicate that cutting speed was the most influential item in power consumption enhancement. Furthermore, compared with dry and flooded turning, lower cutting force, reduced cutting temperature, shorter width of flank wear and better surface morphology were obtained under nanofluid-MQL machining. It has been observed that nanofluid-MQL machining outperformed sustainability improvement concerning techno-economically viable societal acceptable and environmental friendliness.

本研究分析了在不同冷却润滑条件(干式、浸没式、纳米流体-MQL)下,使用最近开发的 AlTiSiN 涂层硬质合金刀具硬车削高强度低合金(HSLA)级 AISI 4140 钢时的功耗(Pc)和表面粗糙度(Ra)。纳米流体是通过将 MWCNT 纳米颗粒与环保型汽车散热器冷却液(基液)混合制备的。通过比较加工表面形态、刀具磨损、切削力和温度等加工响应,对冷却润滑性能进行了简要研究。通过考虑各种加工变量,即切削速度、刀头半径、切削深度、进给量和冷却润滑方法,进行了 46 次相关试验。从预测建模和多响应优化的角度出发,采用了响应面方法来最大限度地降低功耗和表面粗糙度。之后,将预测建模和优化结果用于经济分析和节能碳足迹评估。这项创新研究还采用生命周期评估方法,对不同冷却润滑条件下的硬车削进行了环境可持续性比较评估,以实现更清洁、更安全的生产。结果表明,切削速度是影响功耗增加的最大因素。此外,与干车削和浸水车削相比,纳米流体-MQL 加工可获得更低的切削力、更低的切削温度、更短的侧面磨损宽度和更好的表面形态。据观察,纳米流体-MQL 加工在技术经济可行性、社会可接受性和环境友好性方面的可持续发展方面表现出色。
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引用次数: 0
Extending Applicability of Amino-Functionalized Silica Nanoparticle as Poly-Alpha-Olefin Additive for Different Metal–Metal Sliding Pairs via Secondary Surface-Capping by Polyisobutylene Succinic Anhydride 通过聚异丁烯丁二酸酐的二次表面包覆,扩大氨基官能化二氧化硅纳米粒子作为聚α-烯烃添加剂在不同金属-金属滑动配对中的适用性
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-26 DOI: 10.1002/ls.1714
Jiajia Yao, Shuguang Fan, Ningning Song, Chuanping Gao, Yujuan Zhang, Shengmao Zhang

The tribological properties of lubricants containing the same additives often vary with varying hardness and composition of the frictional parts. This means that, in terms of the effectiveness of lubricant additives, most of current researches using GCr15 steel to assemble the frictional pair could not be directly cited by the moving parts made of other materials. Aiming at verifying if RNS-1A-PIBSA (referring to amino-functionalized silica nanoparticle [RNS-1A] after secondary surface-capping by polyisobutylene succinic anhydride [PIBSA]) is suitable for multiple frictional parts made of different materials with varying hardness and composition, herein we investigate its applicability an additive in poly-alpha-olefin 6 (PAO6) base oil to three types of sliding pairs constructed from GCr15 steel, #45 steel, and ductile iron with much different hardness and composition by SRV-5. A series of analyses of worn surface morphology and composition demonstrate that, independent of the composition and hardness of the frictional pairs, RNS-1A-PIBSA added in PAO6 base oil can form silica deposition film on the rubbed surfaces of the three kinds of sliding pairs, thereby effectively reducing friction and wear. Besides, we also examine the effect of RNS-1A-PIBSA on the thermal stability of the PAO6 base oil, and found the nano-additive RNS-1A-PIBSA can delay the thermal decomposition of PAO6 base oil to some extent, which is favourable for its application in lubrication engineering.

含有相同添加剂的润滑剂的摩擦学特性往往因摩擦部件的硬度和成分不同而不同。这意味着,就润滑油添加剂的效果而言,目前大多数使用 GCr15 钢组装摩擦副的研究无法直接引用其他材料制成的运动部件。为了验证 RNS-1A-PIBSA(指通过聚异丁烯丁二酸酐 [PIBSA]进行二次表面包覆后的氨基功能化二氧化硅纳米粒子 [RNS-1A])是否适用于不同硬度和成分的不同材料制成的多个摩擦零件、作为聚α-烯烃 6(PAO6)基础油的添加剂,我们在此研究了它对三种滑动副的适用性,这三种滑动副分别由硬度和成分大不相同的 GCr15 钢、45 号钢和球墨铸铁制成。对磨损表面形态和成分的一系列分析表明,与摩擦副的成分和硬度无关,添加在 PAO6 基础油中的 RNS-1A-PIBSA 可在三种滑动副的摩擦表面形成二氧化硅沉积膜,从而有效减少摩擦和磨损。此外,我们还研究了 RNS-1A-PIBSA 对 PAO6 基础油热稳定性的影响,发现纳米添加剂 RNS-1A-PIBSA 能在一定程度上延缓 PAO6 基础油的热分解,有利于其在润滑工程中的应用。
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引用次数: 0
Influence of Friction Properties Between Non-Smooth Surface GFER and 316L Stainless Steel Under Seawater Lubrication and Simulation Research 非光滑表面 GFER 与 316L 不锈钢在海水润滑下的摩擦特性影响及模拟研究
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-20 DOI: 10.1002/ls.1712
Shaofeng Wu, Hongrui Xu, Jian Guo, Zhiqiang Wang, Dianrong Gao

In this paper, the friction properties of the port pair with non-smooth surface in the pump were studied. The lubrication film was modelled and simulated to analyse dynamic pressure, velocity vector and friction coefficient. Tests were made for studying the effects of pit shape and revolution speed on friction properties of glass fibre epoxy resin (GFER) samples under seawater lubrication, with the wear of the surface and friction coefficient discussed. The results show that GFER is mainly manifested as adhesive and abrasive wear during the tests. The simulations and tests suggest that the hydrodynamic lubrication effect is improved by increasing revolution speed and using non-smooth surfaces, with the friction coefficient being decreased. Moreover, a roughness test was conducted, and it was found that the Ra value of the 316L sample decreased, whereas the Ra value of the GFER sample increased.

本文研究了泵中具有非光滑表面的端口对的摩擦特性。对润滑膜进行了建模和模拟,以分析动态压力、速度矢量和摩擦系数。试验研究了凹坑形状和旋转速度对海水润滑下玻璃纤维环氧树脂(GFER)样品摩擦性能的影响,并讨论了表面磨损和摩擦系数。结果表明,GFER 在试验过程中主要表现为粘着磨损和磨料磨损。模拟和试验表明,通过提高转速和使用非光滑表面,流体动力润滑效果会得到改善,摩擦系数会降低。此外,还进行了粗糙度测试,发现 316L 样品的 Ra 值下降,而 GFER 样品的 Ra 值上升。
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引用次数: 0
Selection of Various Indications of Tempering Lubricant Concentration Reuse in the Wet Rolling Process 选择湿法轧制过程中回火润滑剂浓度重复使用的各种指标
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-14 DOI: 10.1002/ls.1711
Zeng Junjian, Du Yijun, Fang Sheng, Shen Haitao, Zhao Jigang

Discarded tempering lubricants retained significant reuse potential, making their recycling a vital step in reducing resource wastage and wastewater treatment costs in the strip steel industry. Hence, developing an accurate, rapid evaluation indicator for recycled fluid concentration was essential for facilitating this process. Research showed that among common evaluation indicators for metal fluids, three—electrical conductivity, refractive index and total base number (TBN)—due to their high linear correlation with tempering lubricant concentration (R 2 > 0.995), could be utilised to monitor the dynamic changes in the concentration of tempering lubricants. Subsequent experiments on reused tempering lubricants revealed that electrical conductivity, significantly altered by iron powder (7%–24% variance), and refractive index, impacted by hydraulic oil (3% deviation), highlighted contaminant challenges; yet, filtration effectively mitigated iron powder's effect on TBN. Finally, A 17-day reused tempering lubricants simulation demonstrated consistent effectiveness of the three indicators in monitoring the need to update tempering lubricant concentration. However, in terms of sensitivity, precision, and particularly stability and relative mean deviation, the TBN concentration evaluation indicator outperformed, with TBN (3.38%) < Refractive Index (7.92%) < Electrical Conductivity (11.05%). This indicates the TBN method's superior stability over conductivity and refractive index methods, with its accuracy deviation below 2%, making it a stable, simple and reliable metric worthy of broader adoption.

废弃的回火润滑油具有巨大的再利用潜力,因此对其进行回收利用是减少带钢行业资源浪费和废水处理成本的重要一步。因此,开发一种准确、快速的回收液浓度评估指标对于促进这一过程至关重要。研究表明,在金属流体的常用评估指标中,电导率、折射率和总碱基数 (TBN) 这三种指标与回火润滑油浓度的线性相关性较高 (R2 > 0.995),可用于监测回火润滑油浓度的动态变化。随后对重复使用的回火润滑油进行的实验表明,电导率受铁粉(7%-24% 的偏差)和折射率(受液压油(3% 的偏差)的影响)的显著影响,凸显了污染物带来的挑战;然而,过滤可有效减轻铁粉对 TBN 的影响。最后,为期 17 天的回火润滑油重复使用模拟表明,这三个指标在监测是否需要更新回火润滑油浓度方面具有一致的有效性。不过,在灵敏度、精确度,特别是稳定性和相对平均偏差方面,TBN 浓度评估指标表现更佳,TBN (3.38%) < 折射率 (7.92%) < 电导率 (11.05%)。这表明 TBN 方法的稳定性优于电导率和折射率方法,其准确度偏差低于 2%,是一种稳定、简单、可靠的指标,值得广泛采用。
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引用次数: 0
A Comprehensive Study of Method Optimisation of Re-Refining Spent Lubricating Oil 废润滑油再提炼方法优化综合研究
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-05-27 DOI: 10.1002/ls.1710
Sayantan Sarkar, Deepshikha Datta, Gokulan Ravindiran, Bimal Das

Used lubricating oil is generated by various machinery after extended operation. It is also referred to as spent mobile oil. Extremely hazardous waste lubricating oil is detrimental to the environment because it produces oxidative products when additives break down. Used lubricating oil is classified as a hazardous waste substance and has a negative impact on the environment. Polychlorinated biphenyls (PCBs), carcinogenic substances and other impurities make lubricating oil poisonous and pose a serious threat to human health and the environment. Re-refining is considered the preferred technology for resource conservation, waste minimisation and reduced environmental hazards. The present study focuses on optimising the method of re-refining waste lubricating oil. The effects of various operating parameters such as refining time, refining temperature, solvent-to-used oil ratio and flocculant dosage have been extensively studied to maximise the percentage recovery of lubricating oil. Optimum process parameters are (i) a refining time of 80 min, (ii) a refining temperature of 48°C, (iii) solvent-to-waste oil ratio of 5:1 (w/w) and (iv) a flocculant dosage of 2 g/kg of solvent; the optimum yield was found to be 75% with the solvent extraction method and 78% with the extraction–flocculation method, respectively. The purity and physico-chemical properties of the recovered oil were thoroughly analysed using Fourier transform infrared spectroscopy and ASTM standard methods. It was concluded that refined oil can effectively reduce the ongoing oil crisis and create a clean, healthy environment.

废润滑油是各种机械在长时间运行后产生的。它也被称为废机油。极度危险的废润滑油对环境有害,因为添加剂分解后会产生氧化产物。废润滑油被归类为危险废物,对环境有负面影响。多氯联苯 (PCB)、致癌物质和其他杂质使润滑油有毒,对人类健康和环境构成严重威胁。再精炼被认为是节约资源、减少废物和降低环境危害的首选技术。本研究的重点是优化废弃润滑油的再精炼方法。我们广泛研究了各种操作参数的影响,如精炼时间、精炼温度、溶剂与废油比率和絮凝剂用量,以最大限度地提高润滑油的回收率。最佳工艺参数为:(i) 精炼时间为 80 分钟;(ii) 精炼温度为 48°C;(iii) 溶剂与废油比为 5:1(重量比);(iv) 絮凝剂用量为 2 克/千克溶剂;发现溶剂萃取法的最佳产量为 75%,萃取-絮凝法的最佳产量为 78%。采用傅里叶变换红外光谱法和美国材料试验协会标准方法对回收油的纯度和物理化学性质进行了全面分析。结论是,精炼油可以有效减少当前的石油危机,并创造一个清洁、健康的环境。
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引用次数: 0
Study on Oil–Water Separation Performance of PDA/ODA Composite–Modified Sponge PDA/ODA 复合改性海绵的油水分离性能研究
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-05-16 DOI: 10.1002/ls.1705
Jianfeng Chen, Yuanjing Hu, Zhiying Zhang, Xiaobing Li, Xiong Yu, Zhenping Wu, Zewen Chen

The study involved the modification of a melamine sponge (SP) through the introduction of polydopamine (PDA) and octadecylamine (ODA), resulting in the creation of three distinct sponge types: PDA/ODA@SP, PDA@SP and ODA@SP. The successful modification of PDA and ODA onto the surface of the sponge was confirmed through the utilisation of scanning electron microscopy and x-ray photoelectron spectroscopy. Consequently, the resulting sponges exhibited a unique micro–nano composite structure. Wettability testing was conducted to assess the properties of the sponges, revealing that the PDA/ODA@SP sponge demonstrated hydrophobic superlipophilic characteristics. Moreover, a series of 10 repeated oil–water separation experiments indicated that the PDA/ODA@SP sponge achieved an impressive separation efficiency of up to 97%, demonstrating its exceptional oil–water separation capabilities and reusability. Additionally, investigations utilising soybean oil and engine oil demonstrated the composite sponge's superior absorption capabilities for fatty acids and hydrocarbons.

该研究通过引入聚多巴胺(PDA)和十八胺(ODA)对三聚氰胺海绵(SP)进行改性,从而产生了三种不同的海绵类型:PDA/ODA@SP、PDA@SP 和 ODA@SP。利用扫描电子显微镜和 X 射线光电子能谱确认了 PDA 和 ODA 在海绵表面的成功改性。因此,所制备的海绵呈现出独特的微纳复合结构。为了评估海绵的特性,对其进行了润湿性测试,结果表明 PDA/ODA@SP 海绵具有疏水超亲油特性。此外,一系列重复 10 次的油水分离实验表明,PDA/ODA@SP 海绵的分离效率高达 97%,令人印象深刻,证明了其卓越的油水分离能力和可重复使用性。此外,利用大豆油和发动机油进行的研究表明,复合海绵对脂肪酸和碳氢化合物具有卓越的吸收能力。
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引用次数: 0
Effect of Dicarboxylic Acid Chain Length on the Tribological Properties of Aqueous Polyether Esters 二羧酸链长对水性聚醚酯摩擦学特性的影响
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-05-12 DOI: 10.1002/ls.1706
Wenqiang Shao, Chao Xu, Xiaobo Wang, Xiaoling Liu, Wenjing Lou

This article presents the preparation of environmentally friendly water-soluble lubricant additives. Adipic acid (AA), sebacic acid (SA) and dodecanedioic acid (DA) were individually subjected to esterification reactions with polyethylene glycol 1500 (PEG1500) to prepare a class of water-soluble polyether esters (AAPEE1500, SAPEE1500 and DAPEE1500) (referred to as XAPEE1500s) that exhibit excellent water solubility and do not contain environmentally harmful elements. First, the molecular structure characterisation and functional group analysis of these additives will be conducted using an infrared spectrometer and a nuclear magnetic resonance spectrometer. Subsequently, the frictional properties of the additives in the base liquid (deionised water) will be investigated using an SRV-V tribometer, Falex pin-on-disc tribometer and screw torque tester. The surface morphology of wear scars will be characterised and analysed using scanning electron microscopy (SEM) and a non-contact 3D profilometer. Finally, the lubrication mechanism of the DAPEE1500 additive will be analysed using X-ray photoelectron spectroscopy (XPS). The results indicate that the optimal lubrication performance is achieved when the added mass fraction of DAPEE1500 is at 3%. Compared with 0.5 wt% DAPEE1500, the average friction coefficient of 3 wt% DAPEE1500 decreased from 0.285 to 0.122, and the wear volume decreased from 25.52 × 10−5 μm3 to 10.96 × 10−5 μm3. The lubrication mechanism of polyether ester is the result of the combined action of its polar ester functional groups and long carboxylic acid chains in the structure. These polar functional groups can form a relatively firm adsorption film on the friction surface, while the long carboxylic acid chains act as a brush-like isolating layer, thus demonstrating superior anti-wear and anti-friction performance.

本文介绍了环保型水溶性润滑油添加剂的制备方法。将己二酸(AA)、癸二酸(SA)和十二烷二酸(DA)分别与聚乙二醇 1500(PEG1500)进行酯化反应,制备出一类水溶性聚醚酯(AAPEE1500、SAPEE1500 和 DAPEE1500)(简称 XAPEE1500s),它们具有优异的水溶性且不含对环境有害的元素。首先,将使用红外光谱仪和核磁共振光谱仪对这些添加剂进行分子结构表征和官能团分析。随后,将使用 SRV-V 摩擦仪、Falex 针盘摩擦仪和螺钉扭矩测试仪研究添加剂在基液(去离子水)中的摩擦特性。将使用扫描电子显微镜(SEM)和非接触式 3D 轮廓仪对磨损疤痕的表面形态进行表征和分析。最后,将使用 X 射线光电子能谱(XPS)分析 DAPEE1500 添加剂的润滑机理。结果表明,当 DAPEE1500 的添加质量分数为 3% 时,润滑性能最佳。与 0.5 wt% 的 DAPEE1500 相比,3 wt% 的 DAPEE1500 的平均摩擦系数从 0.285 降至 0.122,磨损体积从 25.52 × 10-5 μm3 降至 10.96 × 10-5 μm3。聚醚酯的润滑机理是其结构中极性酯官能团和长羧酸链共同作用的结果。这些极性官能团能在摩擦表面形成一层相对牢固的吸附膜,而长羧酸链则起到类似毛刷的隔离层的作用,从而表现出卓越的抗磨损和抗摩擦性能。
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引用次数: 0
Experimental Study of the Interfacial Slip on Hydrodynamic Lubrication Under Different Wettabilities 不同润湿性下流体动力润滑界面滑移的实验研究
IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-04-15 DOI: 10.1002/ls.1709
Suli Han, Feng Guo, Jing Shao, Qian Wang, Xinming Li, Wei Jin

This article presents an experimental study about boundary slippage on the film thickness of hydrodynamic lubrication (HL) using a custom-made slider-on-disc bearing testing apparatus. The interfaces with different affinity were obtained by surface energy modification of sliders with various oleophobic coatings, which are characterised by their contact angle (CA) and contact angle hysteresis (CAH). To study the mechanism of interfacial slip on HL under different wettability constraints, the film thickness and velocity profiles under shear were measured using interference and fluorescence photobleached method, respectively. The results showed that the CAH could better characterise the influence of interface effect on the film thickness of HL, which was explained by the correlation between CAH and the interface potential barrier. Furthermore, it was found that the slip velocity increased with lubricant viscosity and shear rate, which can be explained by the spatial heterogeneity of the flow in conformal contact and the critical shear stress slip model.

本文利用定制的滑块-圆盘轴承测试仪器,对流体动力润滑(HL)薄膜厚度的边界滑动进行了实验研究。通过对滑块进行表面能改性,在其表面涂上不同的疏油涂层,从而获得不同亲和力的界面,并通过接触角(CA)和接触角滞后(CAH)对其进行表征。为了研究不同润湿性约束条件下 HL 上界面滑移的机理,分别采用干涉法和荧光光漂白法测量了剪切作用下的薄膜厚度和速度曲线。结果表明,CAH 能更好地表征界面效应对 HL 薄膜厚度的影响,CAH 与界面势垒之间的相关性解释了这一点。此外,研究还发现滑移速度随润滑剂粘度和剪切速率的增加而增加,这可以用保形接触中流动的空间异质性和临界剪切应力滑移模型来解释。
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引用次数: 0
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Lubrication Science
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