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Reconstruction of ancient sulfate‒methane transition depths using the concentrations and sulfur isotopic compositions of authigenic sulfide minerals in marine sediments 利用海洋沉积物中自生硫化物矿物的浓度和硫同位素组成重建古代硫酸盐-甲烷过渡深度
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1016/j.marpetgeo.2024.107199
Chenhui Liu , Shao-Yong Jiang , Xin Su , Tao Yang
On the basis of a one-dimensional transport-reaction model, we propose a novel approach to identify the relationship between the depth of the sulfate‒methane transition (SMT) and the stratigraphic distribution of authigenic sulfide minerals in terms of both concentration and sulfur isotopic composition. We apply this approach to Ocean Drilling Program Sites 994 and 995 at the Blake Ridge, offshore southeastern North America. Within the present-day sulfate reduction zone, our numerical simulation suggests that sulfide mineralization is basically at a steady state, the concentrations of which depend largely on the reactivity of sedimentary organic carbon. The observed extreme 34S-depletion of sulfide minerals (e.g., δ34S values as low as −45‰ VCDT) can occur without the process of sulfur disproportionation. We then derive a series of theoretical profiles by changing the SMT depth from 4 m to 30 m below the seafloor and construct a contour plot of the theoretical SMT depth as a function of the concentration and sulfur isotopic composition of solid-phase sulfides after complete mineralization under steady-state conditions. Below the present-day SMT, six stratigraphic locations of the ancient SMT are identified and their depths below each contemporaneous seafloor are interpolated. Theoretical estimates suggest that the SMT gradually subsided from 8.4 to ca. 24 m below the contemporaneous seafloor (mbcsf) over the past 643 to 6.6 ka. At present, the SMT has been occurring steadily at depths of ca. 21 to 22 mbcsf for at least 2.9 kyr. This is the first time that the evolution of the ancient SMT depth has been quantitatively reconstructed, by which the attainment of knowledge can be used to research the early diagenetic evolution history of the pore water sulfur species and will arouse much interest and concern from other researchers.
在一维迁移-反应模型的基础上,我们提出了一种新方法来确定硫酸盐-甲烷转变(SMT)深度与自生硫化物矿物在浓度和硫同位素组成方面的地层分布之间的关系。我们将这种方法应用于北美东南部近海布莱克海脊的大洋钻探计划 994 号和 995 号站点。在现今的硫酸盐还原区内,我们的数值模拟表明硫化物矿化基本上处于稳定状态,其浓度主要取决于沉积有机碳的反应活性。观察到的硫化物矿物 34S 极度消耗(例如,δ34S 值低至 -45‰ VCDT)可以在没有硫磺歧化过程的情况下发生。然后,我们通过将 SMT 深度从海底下 4 米改变到 30 米,得出了一系列理论剖面图,并构建了理论 SMT 深度与稳态条件下完全矿化后固相硫化物的浓度和硫同位素组成的等值线图。在现今 SMT 的下方,确定了古 SMT 的六个地层位置,并对其在各同时代海底下方的深度进行了内插。理论估算表明,在过去的 643 至 6.6 ka 年间,SMT 从低于同期海底 8.4 米逐渐下沉至约 24 米(mbcsf)。目前,SMT 在约 21 至 22 mbcsf 的深度稳定地出现了至少 2.9 千年。这是首次定量重建古SMT深度的演化过程,可用于研究孔隙水硫物种的早期成岩演化历史,将引起其他研究者的极大兴趣和关注。
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引用次数: 0
Occurrence characteristics and factors that influence shale oil in the Jurassic Lianggaoshan Formation, northeastern Sichuan Basin 四川盆地东北部侏罗系梁高山地层页岩油的赋存特征及影响因素
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1016/j.marpetgeo.2024.107197
Xuefeng Bai , Xin Wang , Min Wang , Junhui Li , Shuangfang Lu , Xinyi Yang , Yidong Jia , Rong Wu , Tianyi Li , Youzhi Wang
Well Ping'an 1, located in the northeastern Sichuan Basin, tested 112.8 m3/d of oil from the Lianggaoshan Formation, marking an important breakthrough in shale oil production. However, due to the influence of complex lithofacies, high thermal maturity, and limited exploration, the occurrence and factors that influence shale oil across the different lithofacies of the Lianggaoshan Formation remain unclear, thereby severely impeding exploration and development. This study systematically examines the occurrence and factors that influence shale oil (adsorbed oil and free oil) in the Lianggaoshan Formation through an integrated approach involving petrology, geochemistry, scanning electron microscopy, nuclear magnetic resonance spectroscopy, multi-temperature pyrolysis, and gas chromatography. Results demonstrate the following: (1) Residual shale oil (adsorbed oil) in the study area predominantly exists as oil films, precipitated oil, and residues (asphalt). Oil films appear on the edges of organic matter (OM), clay minerals, pyrite, and felsic minerals. Crude oil adheres as thin layers to mineral edges, with part of the oil resulting from the lipophilic properties of OM. Precipitated oil tends to accumulate around organic pores, and at higher maturity stages, heavy oil components adhere to mineral surfaces as residues. The hydrocarbon loss of the sample is serious, and free oil is difficult to observe due to experimental processing. (2) Based on the experimental results of preserved cored samples, the shale oil in the study area is mainly free oil (0.86–4.46 mg/g, average 1.99 mg/g), followed by adsorbed oil (0.0007–1.36 mg/g, average 0.43 mg/g). The presence of higher concentrations of clay minerals and total organic carbon (TOC) correlates with increased quantities of free and adsorbed oil in the Lianggaoshan Formation. (3) The two-dimensional nuclear magnetic resonance method combined with the “e” index method was employed to quantify the free oil volumes in shale reservoirs of varying maturity within the study area. The recovery coefficient initially increases rapidly and then gradually with increasing Ro (vitrinite reflectance) values. Compared with other lithofacies types, OM-rich laminated argillaceous shale and OM-poor laminated siliceous shale have higher free oil content, which makes them easier to produce, in other words, these two lithofacies should be preferred as favorable exploration and development targets.
位于四川盆地东北部的平安1号井在梁戈山地层测试出112.8立方米/天的石油,标志着页岩油生产取得重要突破。然而,由于岩性复杂、热成熟度高、勘探有限等因素的影响,梁戈山地层不同岩性页岩油的发生及影响因素尚不清楚,严重阻碍了勘探开发。本研究通过岩石学、地球化学、扫描电子显微镜、核磁共振波谱、多温热解和气相色谱等综合方法,系统研究了梁戈山地层页岩油(吸附油和游离油)的发生及其影响因素。研究结果表明(1) 研究区域的残余页岩油(吸附油)主要以油膜、沉淀油和残渣(沥青)的形式存在。油膜出现在有机物 (OM)、粘土矿物、黄铁矿和长石矿物的边缘。原油以薄层形式附着在矿物边缘,其中部分油是由 OM 的亲油特性产生的。沉淀油往往积聚在有机孔隙周围,在成熟度较高的阶段,重油成分作为残留物附着在矿物表面。由于实验处理的原因,样品的碳氢化合物损失严重,很难观察到游离油。(2)根据保存的取芯样品的实验结果,研究区的页岩油主要是游离油(0.86-4.46 毫克/克,平均 1.99 毫克/克),其次是吸附油(0.0007-1.36 毫克/克,平均 0.43 毫克/克)。粘土矿物和总有机碳(TOC)浓度较高与梁戈山地层游离油和吸附油的数量增加相关。(3) 采用二维核磁共振法结合 "e "指数法对研究区内不同成熟度页岩油藏中的游离油量进行了定量分析。随着 Ro(玻璃光泽反射率)值的增加,采收率系数最初迅速增加,然后逐渐增加。与其他岩性相比,富含 OM 的层状箭状页岩和贫含 OM 的层状硅质页岩的游离油含量较高,因此更容易开采,换言之,这两种岩性应作为有利的勘探和开发目标。
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引用次数: 0
Analytical model for CO2-water displacement with rate-dependent phase permeability for geological storage 用于地质封存的二氧化碳-水位移分析模型,其相渗透率取决于速率
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-03 DOI: 10.1016/j.marpetgeo.2024.107195
Amin Shokrollahi, Kofi Ohemeng Kyei Prempeh, Syeda Sara Mobasher, Pavel Bedrikovetsky
Analytical modelling is an effective tool for predicting reservoir behaviour under high uncertainties, like CO2 storage in aquifers, where multiple simulation runs are necessary for stochastic modelling and risk assessment. This paper formulates the Buckley-Leverett problem with x-dependent fractional flow. We derive a new analytical model for displacement of brine by CO2 accounting for (i) rate-dependent phase permeability during radial flows and (ii) radial flows of Forchheimer's high-rate gas injection; this analytical model is also valid for (iii) linear flows during flooding in micro heterogeneous or composite cores and (iv) CO2-water flow upscaling in reservoirs where layering is perpendicular to flux direction. An exact solution of the flow equation is based on the observation that the flux of each phase conserves along the characteristic trajectories. We discuss S-shape fractional flow function, which is typical for reservoir rocks. The solution includes formulae for phase saturations and fluxes and trajectories of the displacement CO2-water front and of the forward and rear mixture zone boundaries. The fast analytical model can be used for multivariate sensitivity study and sweep efficiency prediction.
分析建模是预测高不确定性条件下储层行为的有效工具,如含水层中的二氧化碳封存,需要多次模拟运行以进行随机建模和风险评估。本文提出了 Buckley-Leverett 问题,该问题与 x 有关。我们推导出了一个新的分析模型,用于分析二氧化碳对盐水的置换,该模型考虑到了(i) 径向流动过程中与速率相关的相渗透率和 (ii) Forchheimer 高速注气的径向流动;该分析模型还适用于(iii) 微异质或复合岩心充水过程中的线性流动和(iv) 储层中分层垂直于通量方向的二氧化碳-水流动放大。流动方程的精确解基于各相流量沿特征轨迹保持不变的观测结果。我们讨论了储层岩石中典型的 S 型分数流动函数。解法包括相饱和度和通量公式,以及二氧化碳-水位移前沿和前后混合区边界的轨迹。快速分析模型可用于多变量敏感性研究和扫气效率预测。
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引用次数: 0
The Baroch Nala section (NE Pakistan): A new PETM standard for the eastern Tethys 巴罗克纳拉断面(巴基斯坦东北部):特提斯东部新的 PETM 标准
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1016/j.marpetgeo.2024.107183
Mubashir Ali , Giovanni Coletti , Eduardo Garzanti , Thierry Adatte , Sébastien Castelltort , Pietro Sternai , Andrea Benedetti , Elisa Malinverno , Luca Mariani , Jorge E. Spangenberg , Suleman Khan , Daniela Basso , Elias Samankassou , László Kocsis , Muhammad Usman
We present an integrated, high-resolution, biostratigraphical, mineralogical, and geochemical characterization of the well-exposed Upper Paleocene - Lower Eocene stratigraphic succession of the Surghar Range (Baroch Nala section, NE Pakistan). The faunal assemblages from the Baroch Nala section, dominated by hyaline benthic foraminifera and green calcareous algae, along with the significant terrigenous fraction and the presence of terrestrially derived organic matter, testify to the deposition in a low-energy shallow-marine environment. Such environmental conditions, coupled with weak diagenetic effects, allow us to integrate a continuous record of carbon stable isotopes with a detailed account of the biotic response by carbonate-producing assemblages, paleoclimatic information based on clay-minerals, and information on volcanic activity based on mercury concentrations. The environmental evolution from the Late Paleocene up to the Paleocene Eocene Thermal Maximum (PETM) is clearly documented, including the weaker warm excursion that precedes the PETM (i.e. the Pre-Onset Excursion “POE”), and the evolution of large benthic foraminiferal assemblages. The overall record perfectly shows how the turnover in benthic carbonate producers started with the onset of the PETM and was completed by the time the excursion ended, highlighting how (geologically) brief environmental oscillations can have long lasting effects on the biosphere.
我们对巴基斯坦东北部苏尔加尔山脉(Baroch Nala 段)暴露较好的上古新世-下新世地层演替进行了综合、高分辨率的生物地层学、矿物学和地球化学鉴定。Baroch Nala 段的动物群落以透明底栖有孔虫和绿色钙质藻类为主,并含有大量陆生部分和陆源有机质,证明该段沉积于低能量的浅海环境中。这样的环境条件加上微弱的成岩作用,使我们能够将碳稳定同位素的连续记录与碳酸盐生成集合体生物反应的详细说明、基于粘土矿物的古气候信息以及基于汞浓度的火山活动信息结合起来。研究清楚地记录了从晚古新世到古新世始新世热极盛期(PETM)的环境演变,包括 PETM 之前较弱的温暖偏移(即 "POE"),以及大型底栖有孔虫群的演变。总体记录完美地展示了底栖碳酸盐生产者的更替是如何从 PETM 开始,到偏移结束时完成的,突出了(地质学上的)短暂环境振荡如何对生物圈产生长期持久的影响。
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引用次数: 0
Kinematic and rheological controls on ultra-wide asymmetric rifted margins evolution 超宽非对称裂谷边缘演化的运动学和流变学控制因素
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1016/j.marpetgeo.2024.107171
Sara dos Santos Souza , Claudio Alejandro Salazar-Mora , Victor Sacek , Mario Neto Cavalcanti de Araujo
Only a limited number of geodynamic numerical models have been successful in simulating both asymmetric and ultra-wide (>500 km) rifted margins. In this paper, we present a comprehensive suite of 72 thermo-mechanical geodynamic numerical simulations of rifting. These simulations revealed the impact of initial crustal thickness, variations in the ratios between the upper and lower crusts, rift velocity, structural inheritance, and shear heating on the asymmetry and width of conjugate rifted margins. Our findings highlight that initial crustal thickness is a primary controlling factor of conjugate rifted margin geometries. Specifically, initial crustal thicknesses ranging from 35 to 40 km generally do not result in margins exceeding 300 km in width, where wider margins are 1.5 times longer than the narrow corresponding conjugate. An initial crustal thickness of 45 km facilitates the formation of ultra-wide margins, especially when the upper crust is thicker than the lower crust. This is attributed to the greater concentration of heat-producing elements in the thicker upper crust, which accumulates heat, weakens the crust, and promotes ductile thinning. Additionally, high rifting velocities enhance advective heating from the upwelling asthenosphere. This further influences the development of the distal margin domains and results in highly asymmetric conjugate margin pairs with one ultra-wide margin. Structural inheritance also emerges as a critical factor, as it distributes strain within the pre-rift lithosphere, thereby enhancing the development of ultra-wide (>500 km) and highly asymmetric margins. Our results are compatible with conjugate rifted margins between Brazil and Africa, such as Espirito Santo - North Kwanza, Campos - South Kwanza and Santos - Benguela.
只有数量有限的地球动力数值模型成功地模拟了非对称和超宽(500 公里)裂谷边缘。在本文中,我们介绍了 72 套全面的裂谷热机械地球动力数值模拟。这些模拟揭示了初始地壳厚度、上地壳和下地壳比例变化、裂谷速度、结构继承和剪切加热对共轭裂谷边缘不对称和宽度的影响。我们的研究结果突出表明,初始地壳厚度是共轭断裂边缘几何形状的主要控制因素。具体而言,初始地壳厚度在 35 至 40 千米之间的边缘宽度一般不会超过 300 千米,其中较宽的边缘长度是较窄的共轭边缘长度的 1.5 倍。初始地壳厚度为 45 千米时,有利于形成超宽边缘,特别是当上部地壳比下部地壳厚时。这归因于较厚的上地壳富集了更多的产热元素,从而积聚了热量,削弱了地壳,促进了韧性变薄。此外,高的断裂速度增强了上涌岩浆层的平流加热。这进一步影响了远端边缘域的发展,导致了高度不对称的共轭边缘对和一个超宽边缘。结构继承也是一个关键因素,因为它分布了前裂谷岩石圈内的应变,从而促进了超宽(>500 km)和高度不对称边缘的发展。我们的研究结果与巴西和非洲之间的共轭裂谷边缘相吻合,例如圣埃斯皮里图-北宽扎、坎波斯-南宽扎和桑托斯-本格拉。
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引用次数: 0
Characteristics and main controlling factors of the Sangonghe tight sandstone reservoirs in the Shengbei Sub-sag of the Turpan-Hami basin, China 中国吐鲁番-哈密盆地圣北亚海沟桑公河致密砂岩储层特征及主要控制因素
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1016/j.marpetgeo.2024.107181
Xinda Zhu , Xiyu Qu , Hua Zhang , Weiming Wang , Changsheng Miao , Yangchen Zhang , Wenbo Wu
The Sangonghe tight sandstone hydrocarbon reservoirs in the Shengbei Sub-sag of the Turpan-Hami Basin are key areas for hydrocarbon exploration. However, previous research has mostly focused on petrological characteristics, physical properties, and pore types. There is a lack of understanding regarding diagenesis, microscopic pore-throat features, and the impact of overpressure on the reservoir. This gap in knowledge poses a disadvantage for future studies and hydrocarbon exploration. This study examines the Sangonghe tight sandstone hydrocarbon reservoirs in the Shengbei Sub-sag of the Turpan-Hami Basin. It combines cast thin sections, physical property tests, high-pressure mercury injection experiments, low-temperature nitrogen adsorption experiments, and well logging overpressure identification to investigate the basic characteristics, diagenesis, and microscopic pore-throat features of these reservoirs. Based on this analysis, the study identifies the main controlling factors of the reservoir properties and presents three key findings. First, the reservoir rocks are primarily composed of lithic sandstone and feldspathic lithic sandstone with porosity ranging from 4% to 10% and permeability ranging between 0.1 and 10 mD, classifying it as a low-porosity, low-permeability tight sandstone reservoir. Second, the reservoir has undergone several diagenetic processes, with significant compaction and common occurrences of cementation and metasomatism. Acidic dissolution is the main dissolution process, but it is relatively weak. The pore-throat system exhibits poor and concentrated sorting, with nanometer-sized pores being predominant. These include 'ink-bottle' pores with narrow necks and wide bodies, and parallel plate-structured fissure pores. Finally, the development of the reservoirs is mainly influenced by sedimentation, dissolution, and overpressure. The parent rock provenance features a high content of stable heavy minerals, larger grain sizes, and thicker sand body layers. These factors enhanced the reservoir's resistance to compaction and promoted the development of primary intergranular pores. Additionally, organic acid fluids caused extensive dissolution of feldspar and lithic fragments, resulting in the formation of numerous secondary dissolution pores. Additionally, under-compaction overpressure helped preserve primary pores, while hydrocarbon generation overpressure extended the hydrocarbon generation period. This extended period provided the driving force for fluid migration, enhanced the transformation of reservoir space, and aided in hydrocarbon accumulation.
吐鲁番-哈密盆地圣北亚沙格的桑公河致密砂岩油气藏是油气勘探的重点区域。然而,以往的研究主要集中在岩石学特征、物理性质和孔隙类型方面。对成岩作用、微观孔喉特征以及超压对储层的影响缺乏了解。这一知识空白对今后的研究和油气勘探造成了不利影响。本研究考察了吐鲁番-哈密盆地圣北亚沙格的桑公河致密砂岩油气藏。该研究结合薄片铸造、物性测试、高压注汞实验、低温氮气吸附实验和测井超压鉴定,对这些储层的基本特征、成因和微观孔喉特征进行了研究。在此分析基础上,研究确定了储层性质的主要控制因素,并提出了三项重要发现。首先,储层岩石主要由岩性砂岩和长石岩性砂岩组成,孔隙度在 4% 至 10% 之间,渗透率在 0.1 至 10 mD 之间,属于低孔隙度、低渗透率致密砂岩储层。其次,该储层经历了多个成岩过程,具有明显的压实性,并常见胶结和变质现象。酸性溶解是主要的溶解过程,但相对较弱。孔隙-咽喉系统的分选效果差且集中,主要是纳米级孔隙。这些孔隙包括窄颈宽体的 "墨水瓶 "孔隙和平行板状结构的裂隙孔隙。最后,储层的发育主要受沉积、溶解和超压的影响。母岩产状的特点是稳定的重矿物含量高、粒度较大、砂体层较厚。这些因素增强了储层的抗压性,促进了原生晶间孔隙的发育。此外,有机酸流体导致长石和碎石大量溶解,形成了大量二次溶解孔隙。此外,欠压实超压有助于保留原生孔隙,而碳氢化合物生成超压则延长了碳氢化合物生成期。这一时期的延长为流体迁移提供了动力,加强了储层空间的转换,并有助于碳氢化合物的积累。
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引用次数: 0
Insights into the wetting mechanisms in low-permeability sandstone reservoirs and its evolution processes: The shahejie formation in the Dongying Depression, Bohai Bay basin 对低渗透砂岩储层润湿机制及其演化过程的认识渤海湾盆地东营凹陷沙河街地层
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-26 DOI: 10.1016/j.marpetgeo.2024.107179
Xin Wang , Jianhui Zeng , Benjieming Liu , Wen Zhao , Kuanyuan Shi , Kunkun Jia
During the accumulation and development processes of low-permeability oil, wettability plays a crucial role in the percolation capacity of fluids. In particular, the evolution of low-permeability sandstones involves complex changes in formation fluid properties and mineral types, leading to a deficient understanding of wetting mechanisms in low-permeability sandstones. This gap significantly impedes research on the accumulation mechanisms of low-permeability oil. Focusing on the low-permeability sandstones in Shahejie formation of Dongying Depression, Bohai Bay Basin, tests like Casting thin section, scanning electron microscope, contact angle measurement, molecular dynamics simulation and the Amott method based on nuclear magnetic resonance technology were performed to comprehensively investigate sandstone wettability and its evolutionary process. The results indicate that the adsorption capacity of hydroxyl groups or monovalent cations (K+and Na+) for water molecules causes residual intergranular pores, feldspar dissolution pores, quartz dissolution pores, clay mineral intercrystalline pores and micro-cracks to exhibit hydrophilicity; while the adsorption capacity of divalent cations (Ca2+and Mg2+) for oil molecules causes the surface of dissolution pores of carbonate minerals to exhibit neutrality or lipophilicity. Additionally, changes in formation conditions (temperature, pressure, ion types, and ion concentration) significantly control the wettability of pore surfaces, further determining the overall wettability of low-permeability sandstone reservoirs. Throughout the evolutionary process of low-permeability sandstones, the Amott-Harvey index of low permeability sandstone is greater than zero, and the wettability exhibited hydrophilic or neutral. From A-stage eodiagenesis to B-stage mesodiagenesis, the Amott-Harvey index is 0.82, 0.12, 0.37, 0.03, and 0.49, and the wettability of reservoirs transitions through phases of strong hydrophilicity, weak hydrophilicity, hydrophilicity, neutrality, and hydrophilicity, respectively. Finally, an evolutionary model of the wettability of low-permeability sandstone reservoirs was established, which is of great significance for predicting the quality of low-permeability sandstone reservoirs.
在低渗透石油的积累和开发过程中,润湿性对流体的渗透能力起着至关重要的作用。特别是,低渗透砂岩的演化涉及地层流体性质和矿物类型的复杂变化,导致人们对低渗透砂岩的润湿机制认识不足。这一空白极大地阻碍了对低渗透石油累积机制的研究。以渤海湾盆地东营凹陷沙河街地层低渗透砂岩为研究对象,通过铸造薄片、扫描电子显微镜、接触角测量、分子动力学模拟和基于核磁共振技术的阿莫特法等试验,对砂岩润湿性及其演化过程进行了全面研究。结果表明,羟基或一价阳离子(K+和Na+)对水分子的吸附能力使残留晶间孔、长石溶孔、石英溶孔、粘土矿物晶间孔和微裂缝表现出亲水性;而二价阳离子(Ca2+和Mg2+)对油分子的吸附能力使碳酸盐矿物溶孔表面表现出中性或亲脂性。此外,地层条件(温度、压力、离子类型和离子浓度)的变化在很大程度上控制着孔隙表面的润湿性,进一步决定了低渗透砂岩储层的整体润湿性。在低渗透砂岩的整个演化过程中,低渗透砂岩的阿莫特-哈维指数大于零,润湿性呈现亲水性或中性。从A阶段eodiagenesis到B阶段mesodiagenesis,Amott-Harvey指数分别为0.82、0.12、0.37、0.03和0.49,储层的润湿性分别经历了强亲水、弱亲水、亲水、中性和亲水等阶段。最后,建立了低渗透砂岩储层润湿性的演化模型,这对预测低渗透砂岩储层的质量具有重要意义。
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引用次数: 0
High-resolution oceanic anoxic event 2 (OAE2) records from the north of eastern Tethys and evidence for short-term sea regression and wildfire at its early phase 东特提斯北部的高分辨率大洋缺氧事件 2(OAE2)记录及其早期阶段的短期海退和野火证据
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-26 DOI: 10.1016/j.marpetgeo.2024.107180
Mingzhen Zhang , Shuang Dai , Baoxia Du , Yongli Wang , Guolong Liu , Yifeng Hong , Jing Zhang , Yan Liu , Jingjing Cai
Oceanic Anoxic Event 2 (OAE2), occurring at the Cenomanian-Turonian boundary (CTB; 93.9 Ma), is a representative global event of carbon cycling fluctuations and transient climate anomalies. OAE2 was initially discovered and intensively studied in the trans-Atlantic and western Tethys Oceans; however, research on the eastern Tethys Ocean, especially the vast northern regions, is inadequate. Further, there is still considerable controversy regarding the triggering mechanisms and early environmental changes of OAE2. In this study, we present high-resolution carbonate carbon isotopes (δ13Ccarb), total organic carbon, and mercury (Hg) concentration records from the northern part of the eastern Tethys Ocean during the OAE2 interval, sampled at the ZK20-1 drillcore section of the Kukebai Formation in the western Tarim Basin, China. Following the global classification scheme for carbon isotope excursion (CIE) at the CTB, the carbon isotope change curve of this study is classified into six stages (C1-C6), and three substages (C3a, C3b, C3c) in the C3 stage. Sedimentary features reveal a short-term sea-level regression in the Tarim Basin during the onset stage (C2) of OAE2, which likely involved vast regions of the eastern Tethys Ocean and even the Pacific region. The mercury (Hg) concentration data reveal increasing Hg levels in the lower part of the Kukebai Formation, mainly corresponding to the onset stage (C3) of the OAE2, but it is significantly lower than that in other typical volcanogenic Hg anomalies. We preliminarily speculated that the intensified wildfire activity at the onset stage of OAE2 potentially accelerate the Hg extracted from the terrestrial soil or organic matter into the offshore area. This is also supported by the evidence of wildfire and Hg anomalies from the Western Interior Seaway (WIS) of North America.
大洋缺氧事件 2(Oceanic Anoxic Event 2,OAE2)发生在震旦纪-震旦纪边界(Cenomanian-Turonian boundary,CTB;93.9 Ma),是碳循环波动和瞬时气候异常的代表性全球事件。OAE2 最初是在跨大西洋和特提斯洋西部被发现和深入研究的;然而,对特提斯洋东部,特别是北部广大地区的研究还很不够。此外,关于 OAE2 的触发机制和早期环境变化仍存在很大争议。在本研究中,我们在中国塔里木盆地西部库克拜地层 ZK20-1 钻芯剖面取样,展示了 OAE2 期间东特提斯洋北部的高分辨率碳酸盐碳同位素(δ13Ccarb)、总有机碳和汞浓度记录。按照CTB碳同位素偏移(CIE)的全球划分方案,本研究将碳同位素变化曲线划分为六个阶段(C1-C6),以及C3阶段的三个子阶段(C3a、C3b、C3c)。沉积特征显示,在 OAE2 开始阶段(C2),塔里木盆地出现了短期海平面倒退,可能涉及特提斯洋东部甚至太平洋地区的广大区域。汞(Hg)浓度数据显示,库克拜地层下部的汞含量不断增加,主要与 OAE2 开始阶段(C3)相对应,但明显低于其他典型的火山成因汞异常。我们初步推测,在 OAE2 开始阶段,野火活动的加剧可能会加速从陆地土壤或有机物中提取的汞进入近海区域。北美西部内陆海道(WIS)的野火和汞异常证据也支持这一观点。
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引用次数: 0
Tectonic evolution of the early permian Junggar basin: Insights into a foreland basin shaped by lithospheric folding 早侏罗世准噶尔盆地的构造演化:洞察岩石圈褶皱塑造的前陆盆地
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.1016/j.marpetgeo.2024.107178
Linjun Huang , Jinbao Su , Shuxin Pan , Chuang Li , Zecheng Wang
Foreland basins are shaped by the sedimentary architecture and lithospheric flexure due to the sediment load, slab pull, orogenic growth, and asthenospheric mantle flow. However, it is challenging to differentiate foreland basins from rift basins due to the destructive effects of multiphase orogenesis. Situated at the core of the western Central Asian Orogen Belt, the Junggar Basin holds vital clues regarding the closure of the Paleo-Asian Ocean. There is debate regarding whether it was a compressional foreland basin or an extended rift after the closure of the surrounding oceans. Furthermore, uncertainties persist regarding the fate of the residual oceanic crust and the precise tectonic processes during the collision of the ocean-arc-continent system. Understanding the basin's style during the early Permian period is crucial for deciphering its dynamic tectonic history. This study leverages regional seismic data to reevaluate the overall structure of the Junggar Basin, providing insights into its tectonic context and the mechanisms of intraplate deformation during the early Permian period. The findings reveal significant early Permian deformation features characterized by varying strata thicknesses and unconformities, signifying continuous tectonic activity during deposition. The western and southern depressions that developed from the late Carboniferous to early Permian are in keeping with compressional dynamics and reflect a foredeep basin, while the central uplift corresponds to a forebulge. This study posits that the observed foreland basin system was shaped by lithospheric flexure at the end of the late Carboniferous and lithospheric buckling in the early Permian, which contributed to the creation of uplifted Mosuowan-Baijiahai forebulge in the interior. The Junggar Basin featured a convergent dynamic environment, although the surrounding orogen transitioned into a postcollisional orogen in the Central Asian Orogenic Belt during the early Permian.
前陆盆地是由沉积结构和沉积负荷、板块拉动、造山运动和星体层地幔流动造成的岩石圈挠曲形成的。然而,由于多相造山运动的破坏作用,区分前陆盆地和裂谷盆地具有挑战性。准噶尔盆地位于中亚造山带西部的核心,是古亚洲洋关闭的重要线索。关于准噶尔盆地是一个压缩性前陆盆地,还是周边海洋闭合后的延伸裂谷,目前还存在争议。此外,关于残余大洋地壳的命运以及大洋-弧-大陆系统碰撞期间的精确构造过程,仍然存在不确定性。了解盆地在二叠纪早期的风格对于解读其动态构造历史至关重要。本研究利用区域地震数据重新评估了准噶尔盆地的整体结构,深入了解了其构造背景以及二叠纪早期板内变形的机制。研究结果揭示了二叠纪早期的重要变形特征,其特点是地层厚度不同和不整合,表明沉积过程中存在持续的构造活动。从石炭纪晚期到二叠纪早期形成的西部和南部凹陷符合压缩动力学,反映了前深盆地,而中部隆起则与前凸起相对应。本研究认为,所观察到的前陆盆地系统是由石炭纪晚期的岩石圈挠曲和二叠纪早期的岩石圈屈曲形成的,这促成了内部隆起的莫索湾-白家海前凸的形成。准噶尔盆地具有汇聚的动力环境,尽管在二叠纪早期,周围的造山带已过渡为中亚造山带的后碰撞造山带。
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引用次数: 0
Multistage selective diagenesis increasing poro-perm properties of Anisian sponge-microbial-coral patch reefs and adjacent facies in the Muschelkalk of Upper Silesia, Southern Poland 多级选择性成岩作用增加了波兰南部上西里西亚穆谢尔卡尔克地区安尼西亚海绵-微生物-珊瑚斑块礁及邻近岩层的孔隙特性
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-24 DOI: 10.1016/j.marpetgeo.2024.107174
Iga Ryczkowska, Michał Matysik
Carbonate rocks, particularly reefs and circum-reef facies, are significant reservoir rocks whose reservoir properties depend on their primary composition and diagenetic history. This paper reconstructs the influence of multistage selective diagenesis on the pore system evolution and porosity-permeability properties of the Anisian tropical reef system (Karchowice and Diplopora Beds) in the Muschelkalk of Upper Silesia, southern Poland, using field and slab observations, standard and cathodoluminescence petrography, bulk and SIMS carbon and oxygen stable isotope analyses, porosity-permeability plug study, and computer image analysis of macroporosity (>5 mm across). The reef system comprises two distinct levels of sponge-microbial(-coral) reef mounds surrounded by diverse bioclastic, peloidal, coated-grain, and micritic facies rich in Balanoglossites burrows. The strata experienced complex diagenetic alterations related to various fluids (marine, evaporitic, meteoric) and diagenetic environments (shallow substratal, burial, telogenetic), including (in chronological order): 1) early-marine precipitation of isopachous fibrous rims; 2) early dissolution during emersion; 3) brine-reflux dolomitization; 4) patchy silicification; 5) recrystallization; 6) burial calcite cementation by heated marine fluid; 7) deposition of vadose silt; 8) meteoric calcite cementation; 9) chemical compaction; 10) fracturing; and 11) final karstification, dedolomitization, FeO precipitation, and Liesegang ring formation by meteoric water during Cenozoic telogenesis. Many processes were selective and affected the same (more permeable) parts of the rocks. The strata exhibit porosities reaching 50% (combined plug porosity of 6–35% and macroporosity of up to 20%) and plug permeabilities of 0.07–70 mD, with the highest values occurring in the reefs and burrowed facies. The dominant late-stage telogenic dissolution pores originated from selective removal of dolomitized micrite within burrows and between sponge-microbial automicrite as well as dolomite crystals. The study illustrates the transition of the reef system from tight to porous due to multistage selective diagenesis and fluid flow, which enhanced subtle permeability differences between various types of micrite. This is the first case where four different fluids (dolomitizing, early dissolving, calcite-forming, and late dissolving) selectively migrated through the same rock parts at different times and modified them one after another.
碳酸盐岩,尤其是礁岩和环礁层,是重要的储层岩石,其储层性质取决于其原始成分和成岩历史。本文利用野外和板岩观测、标准和阴极发光岩石学、大量和 SIMS 碳和氧稳定同位素分析、孔隙度-渗透塞研究以及对大孔隙度(直径达 5 毫米)的计算机图像分析,重建了多级选择性成岩作用对波兰南部上西里西亚 Muschelkalk 地区 Anisian 热带礁岩系统(Karchowice 和 Diplopora 床)孔隙系统演化和孔隙度-渗透特性的影响;5 毫米宽)。礁石系统由两层不同的海绵-微生物(-珊瑚)礁丘组成,周围环绕着多种多样的生物碎屑岩、球状岩、涂布粒状岩和微粒岩层,富含巴拉诺格洛石洞穴。地层经历了与各种流体(海洋流体、蒸发流体、陨石流体)和成岩环境(浅底层、埋藏、远成岩)有关的复杂成岩变化,包括(按时间顺序排列):1)早期海洋沉淀:1)早期海相沉淀的等长纤维状边缘;2)浸润过程中的早期溶解;3)盐水回流白云石化;4)斑点状硅化;5)重结晶;6)埋藏中的方解石被加热的海相流体胶结;7) 沉积淤泥;8) 陨石方解石胶结;9) 化学压实;10) 断裂;以及 11) 新生代末期陨石水的最终岩溶化、反钙化、氧化铁沉淀和利斯冈环的形成。许多过程都是选择性的,并影响到岩石的相同(渗透性较强)部分。地层的孔隙率达到 50%(塞孔率为 6-35%,大孔隙率高达 20%),塞孔渗透率为 0.07-70 mD,最高值出现在礁岩和洞穴面。主要的晚期端生溶蚀孔隙源于洞穴内和海绵-微生物自动岩之间白云石化微晶以及白云石晶体的选择性去除。这项研究说明,由于多级选择性成岩作用和流体流动,珊瑚礁系统从致密过渡到多孔,从而加强了各类微晶岩之间微妙的渗透性差异。这是首次出现四种不同流体(白云石化流体、早期溶解流体、方解石形成流体和晚期溶解流体)在不同时期有选择性地流经同一岩石部分,并相继对其进行改造的情况。
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引用次数: 0
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Marine and Petroleum Geology
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