Methane hydrate (MH) is an abundant unconventional gas resource whose safe and efficient exploitation is essential for easing the energy crisis and facilitating carbon-neutral targets. Here we employ transparent microfluidic chips to capture the pore-scale dynamics of MH decomposition driven by (i) controlled thermal stimulation and (ii) pressure drawdown. In both modes, decomposition initiates in the porous hydrate and lags in the crystalline hydrate, confirming the higher thermodynamic stability of crystalline hydrate. Under depressurisation (outlet pressure 1.0 bar, inlet pressure 96.0 bar), three successive stages are identified. Stage I: continuous-phase porous hydrate decomposes first; liberated methane then impinges on intact crystals, triggering secondary nucleation, flow deceleration and partial channel blockage. Stage II: alternating episodes of rapid decomposition and re-formation produce a prolonged stagnation period in which porous and crystalline hydrate repeatedly form and dissolve. Stage III: hydrate re-formation and decomposition occur in quick succession, repeatedly obstructing and reopening pore throats, generating abundant micro-/nano-bubbles (ranging from 2.26 to 37.8 μm) and ultimately leading to complete hydrate dissociation. Each of the three stages lasts approximately 20, 1150 and 170 min, respectively. Simultaneous evolution of the outlet pressure reveals that the pore-pressure field evolves in concert with the process of hydrate decomposition. During Stages I–II, the decomposition front remains near the outlet, connectivity is poor, and newly formed hydrate sustains a high differential pressure. Once the front advances toward the inlet (Stage III), connectivity improves rapidly; vigorous gas–liquid flow and cyclic hydrate conversion induce a step-wise pressure decline until full decomposition is achieved. This work presents the first direct, time-resolved visualization of MH breakdown at the pore scale, elucidating the interplay of thermal, hydraulic and phase-change processes governing gas production. These insights provide a quantitative framework for optimising temperature–pressure protocols in field-scale MH exploitation.
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