Pub Date : 2024-09-12DOI: 10.1016/j.marpetgeo.2024.107093
Kachalla Aliyuda , Dimitrios Charlaftis , Charlotte Priddy , John A. Howell
The geometry, orientation and stacking patterns of sedimentary geobodies play a key control on fluid migration within subsurface reservoirs, aquifers, and repositories. Outcrops and more recently virtual outcrops are commonly used as analogues to characterise geobody architecture and stacking. Traditionally, both reservoirs and their analogues are described with respect to the bulk proportion of different facies and architectural elements within the system. These are combined with geometric measurements of the different geobodies to describe heterogeneity.
This study presents a new methodology for quantifying the range of facies proportions within architectural element panels taken from outcrop analogues. This method measures the facies proportions within a series of vertical profiles and considers the statistical distribution, rather than the simple mean across the entire panel. The basic premise being that within a layer cake system, the spread in facies proportions will be very narrow whereas in a more “jigsaw” type system the spread will be much wider.
To test this hypothesis, a series of nine virtual outcrops from a range of clastic depositional systems including fluvial, shallow marine and deep marine settings, have been analysed. Depositional facies (architectural elements) were interpreted in LIME and a series of depositional strike-orientated orthorectified panels were extracted. The panels were then analysed, and the extracted facies proportions were translated to “net sand” distribution. Results were then compared with conventional analysis of reservoir heterogeneity.
Different depositional systems show distinct patterns. When arranged in depositional dip order, there is a systematic decrease in sand distribution spread down dip with significant resets at the boundaries between the major gross depositional environments (continental, shallow marine/shelf, deep marine).
{"title":"Analysis of facies proportions as a tool to quantify reservoir heterogeneity","authors":"Kachalla Aliyuda , Dimitrios Charlaftis , Charlotte Priddy , John A. Howell","doi":"10.1016/j.marpetgeo.2024.107093","DOIUrl":"10.1016/j.marpetgeo.2024.107093","url":null,"abstract":"<div><p>The geometry, orientation and stacking patterns of sedimentary geobodies play a key control on fluid migration within subsurface reservoirs, aquifers, and repositories. Outcrops and more recently virtual outcrops are commonly used as analogues to characterise geobody architecture and stacking. Traditionally, both reservoirs and their analogues are described with respect to the bulk proportion of different facies and architectural elements within the system. These are combined with geometric measurements of the different geobodies to describe heterogeneity.</p><p>This study presents a new methodology for quantifying the range of facies proportions within architectural element panels taken from outcrop analogues. This method measures the facies proportions within a series of vertical profiles and considers the statistical distribution, rather than the simple mean across the entire panel. The basic premise being that within a layer cake system, the spread in facies proportions will be very narrow whereas in a more “jigsaw” type system the spread will be much wider.</p><p>To test this hypothesis, a series of nine virtual outcrops from a range of clastic depositional systems including fluvial, shallow marine and deep marine settings, have been analysed. Depositional facies (architectural elements) were interpreted in LIME and a series of depositional strike-orientated orthorectified panels were extracted. The panels were then analysed, and the extracted facies proportions were translated to “net sand” distribution. Results were then compared with conventional analysis of reservoir heterogeneity.</p><p>Different depositional systems show distinct patterns. When arranged in depositional dip order, there is a systematic decrease in sand distribution spread down dip with significant resets at the boundaries between the major gross depositional environments (continental, shallow marine/shelf, deep marine).</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107093"},"PeriodicalIF":3.7,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0264817224004057/pdfft?md5=dfb0280b705bcc32aba345fbae67f9ec&pid=1-s2.0-S0264817224004057-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The present study used well log and seismic data to determine the main lithology types, characterize and evaluate the reservoirs properties and discuss about the hydrocarbon quality and productivity in the onshore south of the Rio Del Rey Basin (RDRB). The main results show seven lithologies inside the Isongo, Diongo and Nguti including clays, sandstones and clayey sandstones, the most dominant, and limestones, dolomites, sandstone limestones and clayey limestones, the less dominant. Seventeen reservoir zones with fifteen gas-bearing and two oil-bearing were identified in the Miocene sands of the Isongo, Diongo and Nguti Formations and very few in the Upper Oligocene sands of Akata Formation. The average values of petrophysical parameters obtained are Vshale (13.26–31.3%), NTG (64.48–87.07%), ∅eff (18.54–26.60%), ∅avg (23.27–33.59%), Sw (4.84–11.10%), Shc (88.90–95.16%), and K (1258.96–2187.26 mD). It shows that the identified reservoirs are of the good quality and can be commercially viable for the gas. Knowing that the RDRB and the neighbouring ones (Niger Delta, Rio Muni and Gabon basins which are OPEC members) have good petrophysical parameters, findings from this investigation show that the key difference between RDRB and others lay on the low continuity and vertical extension of these reservoirs, as well as the lower sedimentary thickness (6–7 km), the tectono-stratigraphic architecture and the production essentially focused on the Miocene horizons.
{"title":"Petrophysical and seismo-stratigraphic analysis of the tertiary formations of the South onshore of the Rio Del Rey Basin (Cameroon margin, Gulf of Guinea) from well logs and seismic data","authors":"Armel Ambassa , François Mvondo Owono , Salomon Bertrant Bisse , Emile Ekomane","doi":"10.1016/j.marpetgeo.2024.107096","DOIUrl":"10.1016/j.marpetgeo.2024.107096","url":null,"abstract":"<div><p>The present study used well log and seismic data to determine the main lithology types, characterize and evaluate the reservoirs properties and discuss about the hydrocarbon quality and productivity in the onshore south of the Rio Del Rey Basin (RDRB). The main results show seven lithologies inside the Isongo, Diongo and Nguti including clays, sandstones and clayey sandstones, the most dominant, and limestones, dolomites, sandstone limestones and clayey limestones, the less dominant. Seventeen reservoir zones with fifteen gas-bearing and two oil-bearing were identified in the Miocene sands of the Isongo, Diongo and Nguti Formations and very few in the Upper Oligocene sands of Akata Formation. The average values of petrophysical parameters obtained are V<sub>shale</sub> (13.26–31.3%), NTG (64.48–87.07%), ∅<sub>eff</sub> (18.54–26.60%), ∅<sub>avg</sub> (23.27–33.59%), S<sub>w</sub> (4.84–11.10%), S<sub>hc</sub> (88.90–95.16%), and K (1258.96–2187.26 mD). It shows that the identified reservoirs are of the good quality and can be commercially viable for the gas. Knowing that the RDRB and the neighbouring ones (Niger Delta, Rio Muni and Gabon basins which are OPEC members) have good petrophysical parameters, findings from this investigation show that the key difference between RDRB and others lay on the low continuity and vertical extension of these reservoirs, as well as the lower sedimentary thickness (6–7 km), the tectono-stratigraphic architecture and the production essentially focused on the Miocene horizons.</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107096"},"PeriodicalIF":3.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142239609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1016/j.marpetgeo.2024.107095
David Cruset, Jaume Vergés
We present a geochronological and structural study of the sedimentary architecture of the Vaca Muerta-Quintuco System and Mulichinco Formation in Sierra de Reyes and La Yesera anticlines along the Andean front within the Neuquén Basin. Remote sensing mapping coupled with fieldwork has allowed us to analyse an Auquilco-related secondary detachment anticline in the Sierra de Reyes that exhibits growth strata within the Vaca Muerta-Quintuco and Mulichinco formations, with a decrease in growth rate at the top of the uppermost formation. Numerical ages based on 87Sr/86Sr ratios of calcite shells indicate that anticline growth occurred from Late Jurassic to Early Cretaceous between 148.65 and 132.5 Ma. These ages also allowed us to correlate the Vaca Muerta-Quintuco System in Sierra de Reyes with a published NW-SE seismic transect that traverses the entire Neuquén Basin and extends to the Andean front within the study area. The correlation reveals a coeval period of compression during the growth of the Sierra de Reyes, Loma la Lata and Río Neuquén highs (antiforms), constraining a regional period of intraplate contraction during the latest Jurassic and Early Cretaceous in the Neuquén Basin.
我们对内乌肯盆地安第斯前沿 Sierra de Reyes 和 La Yesera 反斜坡的 Vaca Muerta-Quintuco 系统和 Mulichinco 地层的沉积结构进行了地质年代和构造研究。通过遥感测绘和实地考察,我们分析了雷耶斯山脉中与奥基尔科有关的次级剥离反斜线,该反斜线显示了瓦卡穆埃尔塔-金图科地层和穆利琴科地层中的生长地层,最上层地层顶部的生长速度有所下降。根据方解石贝壳的 87Sr/86Sr 比值计算出的数字年龄表明,侏罗纪晚期至白垩纪早期的反斜增长发生在 148.65 Ma 到 132.5 Ma 之间。这些年龄还使我们能够将雷耶斯山脉的 Vaca Muerta-Quintuco 系统与已公布的西北-东南地震横断面相关联,该横断面横穿整个内乌肯盆地,并延伸至研究区域内的安第斯山脉前沿。这种相关性揭示了在 Sierra de Reyes、Loma la Lata 和 Río Neuquén 高地(蚁形地貌)的生长过程中存在一个共同的压缩期,从而确定了内乌肯盆地在最近的侏罗纪和白垩纪早期存在一个区域性的板块内收缩期。
{"title":"Dating of the syn-folding Vaca Muerta-Quintuco system based on Sr isotopic ratios of low-Mg shells. New time constraints on an intraplate contractional pulse in the Neuquén basin","authors":"David Cruset, Jaume Vergés","doi":"10.1016/j.marpetgeo.2024.107095","DOIUrl":"10.1016/j.marpetgeo.2024.107095","url":null,"abstract":"<div><p>We present a geochronological and structural study of the sedimentary architecture of the Vaca Muerta-Quintuco System and Mulichinco Formation in Sierra de Reyes and La Yesera anticlines along the Andean front within the Neuquén Basin. Remote sensing mapping coupled with fieldwork has allowed us to analyse an Auquilco-related secondary detachment anticline in the Sierra de Reyes that exhibits growth strata within the Vaca Muerta-Quintuco and Mulichinco formations, with a decrease in growth rate at the top of the uppermost formation. Numerical ages based on <sup>87</sup>Sr/<sup>86</sup>Sr ratios of calcite shells indicate that anticline growth occurred from Late Jurassic to Early Cretaceous between 148.65 and 132.5 Ma. These ages also allowed us to correlate the Vaca Muerta-Quintuco System in Sierra de Reyes with a published NW-SE seismic transect that traverses the entire Neuquén Basin and extends to the Andean front within the study area. The correlation reveals a coeval period of compression during the growth of the Sierra de Reyes, Loma la Lata and Río Neuquén highs (antiforms), constraining a regional period of intraplate contraction during the latest Jurassic and Early Cretaceous in the Neuquén Basin.</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107095"},"PeriodicalIF":3.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0264817224004070/pdfft?md5=5d44477edd442198927b9b236fd7d36d&pid=1-s2.0-S0264817224004070-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pyrobitumens, abundant in the Sichuan Basin, SW China, serve as indicators of past oil reservoirs. Currently, estimates of gas generation during oil cracking rely solely on pyrobitumen content with a uniform conversion rate. This study delves into reservoir fluid heterogeneity influenced by factors such as gravitational segregation, deasphaltene processes, biodegradation, and thermochemical sulfate reduction. It recommends a comprehensive geological analysis of pyrobitumens for precise estimation. The research underscores oil heterogeneity within the reservoir, with light oil prevalent in the upper column and heavy oil accumulating at the base. Oil cracking initiates in polar-enriched zones due to deep burial, high temperatures, and low activation energy requirement, leading to concentrated pyrobitumen zones at the column base and/or in highly permeable zones. Pyrobitumens are primarily found in dissolution pores and fractures, aiding in identifying their precursors through optical structure and elemental analysis. Methane production per unit weight of pyrobitumen is lower in pyrobitumen concentrated zones, typically at the column base, compared to dispersed pyrobitumen in the upper oil column. Relying solely on residual pyrobitumen content and a single conversion ratio for oil cracking formed methane estimation may result in misleading interpretations. The study proposes a mass balance calculation method, incorporating the atomic H/C ratio, to examine the gas yield-pyrobitumen relationship. Insights gained from the Sichuan Basin can offer valuable information for resource and environmental impact assessments in other basins with thermally cracked oils.
{"title":"Significance of pyrobitumen in the evaluation of gas generation from oil cracking in the Sichuan Basin, SW China: A review","authors":"Benjian Zhang , Haiping Huang , Xingwang Tian , Guangyou Zhu","doi":"10.1016/j.marpetgeo.2024.107109","DOIUrl":"10.1016/j.marpetgeo.2024.107109","url":null,"abstract":"<div><p>Pyrobitumens, abundant in the Sichuan Basin, SW China, serve as indicators of past oil reservoirs. Currently, estimates of gas generation during oil cracking rely solely on pyrobitumen content with a uniform conversion rate. This study delves into reservoir fluid heterogeneity influenced by factors such as gravitational segregation, deasphaltene processes, biodegradation, and thermochemical sulfate reduction. It recommends a comprehensive geological analysis of pyrobitumens for precise estimation. The research underscores oil heterogeneity within the reservoir, with light oil prevalent in the upper column and heavy oil accumulating at the base. Oil cracking initiates in polar-enriched zones due to deep burial, high temperatures, and low activation energy requirement, leading to concentrated pyrobitumen zones at the column base and/or in highly permeable zones. Pyrobitumens are primarily found in dissolution pores and fractures, aiding in identifying their precursors through optical structure and elemental analysis. Methane production per unit weight of pyrobitumen is lower in pyrobitumen concentrated zones, typically at the column base, compared to dispersed pyrobitumen in the upper oil column. Relying solely on residual pyrobitumen content and a single conversion ratio for oil cracking formed methane estimation may result in misleading interpretations. The study proposes a mass balance calculation method, incorporating the atomic H/C ratio, to examine the gas yield-pyrobitumen relationship. Insights gained from the Sichuan Basin can offer valuable information for resource and environmental impact assessments in other basins with thermally cracked oils.</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107109"},"PeriodicalIF":3.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142239610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1016/j.marpetgeo.2024.107099
Alice S. Hall , Simon Holford , Nick Schofield , Mark Bunch , Alan S. Collins , Morgan L. Blades , Darwinaji Subarkah
{"title":"Corrigendum to ‘The Derim Derim Dolerite, greater McArthur Basin, Australia: Using subsurface data to characterise a Mesoproterozoic magma plumbing system’ [Mar. Petrol. Geol., 169 (2024)]","authors":"Alice S. Hall , Simon Holford , Nick Schofield , Mark Bunch , Alan S. Collins , Morgan L. Blades , Darwinaji Subarkah","doi":"10.1016/j.marpetgeo.2024.107099","DOIUrl":"10.1016/j.marpetgeo.2024.107099","url":null,"abstract":"","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107099"},"PeriodicalIF":3.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1016/j.marpetgeo.2024.107108
Javad Iskandarov , Shehzad Ahmed , George S. Fanourgakis , Waleed Alameri , George E. Froudakis , Georgios N. Karanikolos
Carbon dioxide foam injection stands as a promising method for enhanced oil recovery (EOR) and carbon sequestration. However, accurately predicting its efficiency amidst varying operational conditions and reservoir parameters remains a significant challenge for conventional modeling techniques. This study explores the application of machine learning (ML) methodologies to develop a robust model for matching experimental values in CO2 foam flooding scenarios. Leveraging a comprehensive dataset encompassing diverse surfactants and rock types, with varied porosity and permeability, our model demonstrates accurate predictions across a wide spectrum of conditions. By focusing on key parameters such as foam apparent viscosity, interfacial tension (IFT), injected foam volume, initial oil saturation, porosity, and permeability, we unveil the pivotal role of these factors in determining CO2 foam EOR performance. Through rigorous analysis, we identify the relative importance of each input parameter, with injected foam volume, apparent viscosity, and IFT emerging as dominant factors. The most accurate model was deep neural network (DNN) (R2 value of 0.99). Higher foam viscosity and lower IFT were found to significantly enhance oil recovery rates, though their effects plateau beyond certain thresholds (apparent viscosities above 1200 cP and IFT values below 0.2 mN/m). The findings underscore the potential of ML-driven approaches in enhancing CO2 foam EOR predictions, offering insights crucial for optimizing foam flooding performance across diverse reservoir settings.
{"title":"Predicting and optimizing CO2 foam performance for enhanced oil recovery: A machine learning approach to foam formulation focusing on apparent viscosity and interfacial tension","authors":"Javad Iskandarov , Shehzad Ahmed , George S. Fanourgakis , Waleed Alameri , George E. Froudakis , Georgios N. Karanikolos","doi":"10.1016/j.marpetgeo.2024.107108","DOIUrl":"10.1016/j.marpetgeo.2024.107108","url":null,"abstract":"<div><p>Carbon dioxide foam injection stands as a promising method for enhanced oil recovery (EOR) and carbon sequestration. However, accurately predicting its efficiency amidst varying operational conditions and reservoir parameters remains a significant challenge for conventional modeling techniques. This study explores the application of machine learning (ML) methodologies to develop a robust model for matching experimental values in CO<sub>2</sub> foam flooding scenarios. Leveraging a comprehensive dataset encompassing diverse surfactants and rock types, with varied porosity and permeability, our model demonstrates accurate predictions across a wide spectrum of conditions. By focusing on key parameters such as foam apparent viscosity, interfacial tension (IFT), injected foam volume, initial oil saturation, porosity, and permeability, we unveil the pivotal role of these factors in determining CO<sub>2</sub> foam EOR performance. Through rigorous analysis, we identify the relative importance of each input parameter, with injected foam volume, apparent viscosity, and IFT emerging as dominant factors. The most accurate model was deep neural network (DNN) (R<sup>2</sup> value of 0.99). Higher foam viscosity and lower IFT were found to significantly enhance oil recovery rates, though their effects plateau beyond certain thresholds (apparent viscosities above 1200 cP and IFT values below 0.2 mN/m). The findings underscore the potential of ML-driven approaches in enhancing CO<sub>2</sub> foam EOR predictions, offering insights crucial for optimizing foam flooding performance across diverse reservoir settings.</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107108"},"PeriodicalIF":3.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-10DOI: 10.1016/j.marpetgeo.2024.107089
L.F. Sepeda , A.C.R. Nogueira , R.F. dos Santos , J. Okubo , P.A.S. Silva , J.C. Marques , J.M.N. Milhomem , G.L. Luvizotto , M.J.B. Macambira , A.N. Sial
<div><p>The establishment of extensive carbonate platforms characterized the Ediacaran period during CaCO3 oversaturation events and the exceptional creation of accommodation space associated with the aftermath of the Marinoan glaciation (∼635 Ma). Carbonate deposits in the Araras Group record the early Ediacaran period, stage 1, in the Amazon Craton. The Serra do Quilombo Formation is an intermediate unit characterized by heavily fractured and faulted dolomites, as well as the presence of dolomite-cemented breccias (CB) overlying thick limestone packages associated with diagenetic and hydrothermal modifications. These features are commonly attributed to structurally controlled hydrothermal dolomitization (HTD) and are of significant economic importance as hydrocarbon reservoirs and Mississippi Valley-type (MVT) lead-zinc mineralization hosts. This study aims to unravel the origin of cemented breccias and the diagenetic/burial processes within the unit, focusing on dolomitization processes. Dolomite samples were analyzed using petrographic, scanning electron microscopy, microprobe, micro-Raman, cathodoluminescence, and isotopic analyses (δ<sup>13</sup>C, δ<sup>18</sup>O, <sup>87</sup>Sr/<sup>86</sup>Sr) to unravel their burial history. CBs are sub-vertical to sub-horizontal bodies with complex geometries, generally cutting bedding at high angles, indicating hydrofracturing processes related to vertical flows of hydrothermal fluids (hydraulic breccia) and present the typical cockade texture of expansion breccias in dilatational faults. The substitutive matrix RD1 is the main constituent of the Serra Quilombo Formation, its low correlation between δ<sup>13</sup>C and δ<sup>18</sup>O (R<sup>2</sup> = 0.009), the well-preserved fabric, and the similarity with the isotopic values (C and Sr) documented for Ediacaran carbonates, suggest that the syndepositional dolomitization. The first generation of dolomite cement (DC1) and the last phase of dolomitic cementation (saddle dolomite - SD) occur, filling pores, CBs, and fractures. The cockade texture of the breccias evidences a low precipitation rate or a pause in precipitation between DC1 and SD. Concurrently, DC1 has isotopic signals of δ<sup>18</sup>O = −4.34 ± 1.32‰ (n = 18) and <sup>87</sup>Sr/<sup>86</sup>Sr = 0.708831 (n = 2), while SD has values of δ18O = −9.57 ± 2.51‰ (n = 15) and <sup>87</sup>Sr/<sup>86</sup>Sr = 0.711464 (n = 3). The large isotopic fractionation between DC1 and SD suggests different dolomitizing fluids. This relationship shows an increase in <sup>87</sup>Sr in the fluid as the temperature increases; moreover, the enrichment in <sup>87</sup>Sr of the fluid is explained by the interaction of this fluid with rocks from the crystalline basement. Thus, the main conduit for the ascent of this radiogenic fluid would be faults with deep roots spatially close to tectonically active zones. Lastly, the presence of tectonic stylolites cutting cemented breccias and rotated zebra-like strata
{"title":"Diagenetic and hydrothermal events revealed by an Ediacaran dolomite breccia from the Araras-Alto Paraguai basin, southern Amazon Craton","authors":"L.F. Sepeda , A.C.R. Nogueira , R.F. dos Santos , J. Okubo , P.A.S. Silva , J.C. Marques , J.M.N. Milhomem , G.L. Luvizotto , M.J.B. Macambira , A.N. Sial","doi":"10.1016/j.marpetgeo.2024.107089","DOIUrl":"10.1016/j.marpetgeo.2024.107089","url":null,"abstract":"<div><p>The establishment of extensive carbonate platforms characterized the Ediacaran period during CaCO3 oversaturation events and the exceptional creation of accommodation space associated with the aftermath of the Marinoan glaciation (∼635 Ma). Carbonate deposits in the Araras Group record the early Ediacaran period, stage 1, in the Amazon Craton. The Serra do Quilombo Formation is an intermediate unit characterized by heavily fractured and faulted dolomites, as well as the presence of dolomite-cemented breccias (CB) overlying thick limestone packages associated with diagenetic and hydrothermal modifications. These features are commonly attributed to structurally controlled hydrothermal dolomitization (HTD) and are of significant economic importance as hydrocarbon reservoirs and Mississippi Valley-type (MVT) lead-zinc mineralization hosts. This study aims to unravel the origin of cemented breccias and the diagenetic/burial processes within the unit, focusing on dolomitization processes. Dolomite samples were analyzed using petrographic, scanning electron microscopy, microprobe, micro-Raman, cathodoluminescence, and isotopic analyses (δ<sup>13</sup>C, δ<sup>18</sup>O, <sup>87</sup>Sr/<sup>86</sup>Sr) to unravel their burial history. CBs are sub-vertical to sub-horizontal bodies with complex geometries, generally cutting bedding at high angles, indicating hydrofracturing processes related to vertical flows of hydrothermal fluids (hydraulic breccia) and present the typical cockade texture of expansion breccias in dilatational faults. The substitutive matrix RD1 is the main constituent of the Serra Quilombo Formation, its low correlation between δ<sup>13</sup>C and δ<sup>18</sup>O (R<sup>2</sup> = 0.009), the well-preserved fabric, and the similarity with the isotopic values (C and Sr) documented for Ediacaran carbonates, suggest that the syndepositional dolomitization. The first generation of dolomite cement (DC1) and the last phase of dolomitic cementation (saddle dolomite - SD) occur, filling pores, CBs, and fractures. The cockade texture of the breccias evidences a low precipitation rate or a pause in precipitation between DC1 and SD. Concurrently, DC1 has isotopic signals of δ<sup>18</sup>O = −4.34 ± 1.32‰ (n = 18) and <sup>87</sup>Sr/<sup>86</sup>Sr = 0.708831 (n = 2), while SD has values of δ18O = −9.57 ± 2.51‰ (n = 15) and <sup>87</sup>Sr/<sup>86</sup>Sr = 0.711464 (n = 3). The large isotopic fractionation between DC1 and SD suggests different dolomitizing fluids. This relationship shows an increase in <sup>87</sup>Sr in the fluid as the temperature increases; moreover, the enrichment in <sup>87</sup>Sr of the fluid is explained by the interaction of this fluid with rocks from the crystalline basement. Thus, the main conduit for the ascent of this radiogenic fluid would be faults with deep roots spatially close to tectonically active zones. Lastly, the presence of tectonic stylolites cutting cemented breccias and rotated zebra-like strata","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107089"},"PeriodicalIF":3.7,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.marpetgeo.2024.107087
Xincheng Li , Yuguang Hou , Zhenhong Chen , Zhennan Duan , Yu Zeng , Sheng He , Daoliang Chu
Depositional events have a significant impact on the terrestrial redox conditions and provide evidence for studying the organic matter enrichment. The objective of this study was to evaluate the influence of volcanic and turbidity current events on benthic redox conditions during the Upper Triassic Chang 7 member (Ch7) of the Ordos Basin. To address these issues, the varying sedimentological settings, paleoredox conditions, and relationships between the redox environment and depositional events were investigated via sedimentary analysis of the profiles, microscopic analysis, organic geochemical analysis, and elemental geochemical data. The fine-grained sediments in the Chang 73 submember (Ch73) consist of abundant organic matter, collophanite, and framboidal pyrite. However, in the upper part of the Ch7 member, there was a decrease in organic matter, a decrease in the number of microorganisms, and an increase in pyrite size, indicating that the oxic environment is not favorable for organic matter enrichment. The element and geochemical proxies show similar vertical variations and redox changes. Volcanic activity can bring substantial amounts of material or elements to the basin. The enrichment of Hg and S exhibited considerable variation, ranging from 8.7 to 274.4 ppb and from 0.16 to 4.53 wt%, respectively, which influenced the organic matter accumulation through the flourishing and death of microorganisms and redox changes in the benthic environment of the terrestrial basin. As the lake basin shrinks, the Ti and Al contents increase with increasing frequency of turbidity current events, and the terrestrial debris transported to the lake basin gradually increases while carrying large amounts of oxygen and affecting sedimentation rates, contributing to the destruction of the reducing conditions of the benthic environment, subsequently, influencing organic matter accumulation. These results will be helpful in understanding the effect of multiple depositional events on organic matter enrichment in lacustrine basins.
沉积事件对陆地氧化还原条件有重大影响,并为研究有机质富集提供证据。本研究旨在评估鄂尔多斯盆地上三叠统长七组(Ch7)期间火山和浊流事件对底栖生物氧化还原条件的影响。针对这些问题,研究人员通过剖面沉积分析、显微分析、有机地球化学分析和元素地球化学数据,对不同的沉积环境、古氧化还原条件以及氧化还原环境与沉积事件之间的关系进行了研究。长 73 亚元(Ch73)中的细粒沉积物由丰富的有机质、辉绿岩和黄铁矿组成。然而,在 Ch7 成员的上部,有机质减少,微生物数量减少,黄铁矿粒度增大,表明缺氧环境不利于有机质的富集。元素和地球化学代用指标显示了类似的垂直变化和氧化还原变化。火山活动会给盆地带来大量物质或元素。Hg 和 S 的富集变化很大,分别从 8.7 到 274.4 ppb 和从 0.16 到 4.53 wt%,它们通过微生物的繁荣和死亡以及陆地盆地底栖环境的氧化还原变化影响着有机质的积累。随着湖盆的缩小,Ti 和 Al 含量随着浊流事件发生频率的增加而增加,运往湖盆的陆生碎屑逐渐增多,同时携带大量氧气,影响沉积速率,导致底栖环境还原条件的破坏,进而影响有机质的积累。这些结果将有助于理解多重沉积事件对湖盆有机质富集的影响。
{"title":"Volcanism and turbidity current events as drivers of the evolution of benthic redox conditions: Organic matter enrichment in the Chang 7 member, Upper Triassic Yanchang formation, Ordos Basin, North China","authors":"Xincheng Li , Yuguang Hou , Zhenhong Chen , Zhennan Duan , Yu Zeng , Sheng He , Daoliang Chu","doi":"10.1016/j.marpetgeo.2024.107087","DOIUrl":"10.1016/j.marpetgeo.2024.107087","url":null,"abstract":"<div><p>Depositional events have a significant impact on the terrestrial redox conditions and provide evidence for studying the organic matter enrichment. The objective of this study was to evaluate the influence of volcanic and turbidity current events on benthic redox conditions during the Upper Triassic Chang 7 member (Ch7) of the Ordos Basin. To address these issues, the varying sedimentological settings, paleoredox conditions, and relationships between the redox environment and depositional events were investigated via sedimentary analysis of the profiles, microscopic analysis, organic geochemical analysis, and elemental geochemical data. The fine-grained sediments in the Chang 7<sub>3</sub> submember (Ch7<sub>3</sub>) consist of abundant organic matter, collophanite, and framboidal pyrite. However, in the upper part of the Ch7 member, there was a decrease in organic matter, a decrease in the number of microorganisms, and an increase in pyrite size, indicating that the oxic environment is not favorable for organic matter enrichment. The element and geochemical proxies show similar vertical variations and redox changes. Volcanic activity can bring substantial amounts of material or elements to the basin. The enrichment of Hg and S exhibited considerable variation, ranging from 8.7 to 274.4 ppb and from 0.16 to 4.53 wt%, respectively, which influenced the organic matter accumulation through the flourishing and death of microorganisms and redox changes in the benthic environment of the terrestrial basin. As the lake basin shrinks, the Ti and Al contents increase with increasing frequency of turbidity current events, and the terrestrial debris transported to the lake basin gradually increases while carrying large amounts of oxygen and affecting sedimentation rates, contributing to the destruction of the reducing conditions of the benthic environment, subsequently, influencing organic matter accumulation. These results will be helpful in understanding the effect of multiple depositional events on organic matter enrichment in lacustrine basins.</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107087"},"PeriodicalIF":3.7,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142167991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.marpetgeo.2024.107084
Zili Zhang , Luzi Zhao , Daowei Zhang , Qi Li , Hehe Chen , Long Wen , Benjian Zhang , Gang Zhou , Yuan Zhong , Li Wenzheng
The Dengying Formation in the Penglai region of the Sichuan Basin is renowned for hosting high-quality dolomite reservoirs. However, the understanding of their formation mechanisms and spatial distribution patterns remains enigmatic. This study undertakes a comprehensive petrographic analysis of the second member of the Dengying Formation, primarily focusing on its burial history, reservoir characteristics, and an examination of the types, stages, and developmental patterns of cementation within the dolomite reservoir. This is achieved through the application of isotopic geochemistry, inclusion temperature analysis, and laser U-Pb dating. The findings reveal that cements within the second member of the Dengying Formation predominantly occur in pores and fractures, often exhibiting euhedral and subhedral morphologies. These cements also exhibit evidence of replacing original non-skeletal grains and micrites in semi-euhedral and other forms. Broadly, the cements can be classified into four types: calcium cement (the most abundant), dolomite cement, quartz, and pyrite. The formation of calcareous and siliceous cements closely aligns with the sedimentation and burial processes of the Dengying Formation as a whole. The early to late stages of early-middle diagenesis play a crucial role in the formation of dolomite within the second member. Notably, the degree of euhedral dolomite formation directly correlates with the specific diagenetic stage. Our research indicates that the development of high-quality reservoirs in deep-to-ultra-deep microbial dolomites is a result of complex multi-factor interactions and multi-stage discontinuous modifications, leading to strong heterogeneity within the reservoirs. Microbial dolomite carbonates inherently exhibit high initial porosity, with the favorable sedimentary facies serving as the fundamental basis for reservoir development. Dissolution processes during the syngenetic and quasi-syngenetic periods, in conjunction with epigenetic karstification, further augment porosity and expand the reservoir's capacity. During burial and deep burial stages, various acidic fluids play a pivotal role in preserving and modifying the early-formed pores. In the deep environment characterized by high temperature and pressure, microbial dolomite reservoirs undergo intricate diagenetic evolution and possess complex pore preservation mechanisms. Remarkably, even under exceptional ultra-deep conditions, high-quality microbial dolomite carbonate reservoirs can still develop and be preserved, presenting significant potential for oil and gas exploration.
{"title":"Diagenetic evolution and cementation mechanism in deep Carbonate reservoirs: A case study of Dengying Fm. 2 in Penglai, Sichuan Basin, China","authors":"Zili Zhang , Luzi Zhao , Daowei Zhang , Qi Li , Hehe Chen , Long Wen , Benjian Zhang , Gang Zhou , Yuan Zhong , Li Wenzheng","doi":"10.1016/j.marpetgeo.2024.107084","DOIUrl":"10.1016/j.marpetgeo.2024.107084","url":null,"abstract":"<div><div>The Dengying Formation in the Penglai region of the Sichuan Basin is renowned for hosting high-quality dolomite reservoirs. However, the understanding of their formation mechanisms and spatial distribution patterns remains enigmatic. This study undertakes a comprehensive petrographic analysis of the second member of the Dengying Formation, primarily focusing on its burial history, reservoir characteristics, and an examination of the types, stages, and developmental patterns of cementation within the dolomite reservoir. This is achieved through the application of isotopic geochemistry, inclusion temperature analysis, and laser U-Pb dating. The findings reveal that cements within the second member of the Dengying Formation predominantly occur in pores and fractures, often exhibiting euhedral and subhedral morphologies. These cements also exhibit evidence of replacing original non-skeletal grains and micrites in semi-euhedral and other forms. Broadly, the cements can be classified into four types: calcium cement (the most abundant), dolomite cement, quartz, and pyrite. The formation of calcareous and siliceous cements closely aligns with the sedimentation and burial processes of the Dengying Formation as a whole. The early to late stages of early-middle diagenesis play a crucial role in the formation of dolomite within the second member. Notably, the degree of euhedral dolomite formation directly correlates with the specific diagenetic stage. Our research indicates that the development of high-quality reservoirs in deep-to-ultra-deep microbial dolomites is a result of complex multi-factor interactions and multi-stage discontinuous modifications, leading to strong heterogeneity within the reservoirs. Microbial dolomite carbonates inherently exhibit high initial porosity, with the favorable sedimentary facies serving as the fundamental basis for reservoir development. Dissolution processes during the syngenetic and quasi-syngenetic periods, in conjunction with epigenetic karstification, further augment porosity and expand the reservoir's capacity. During burial and deep burial stages, various acidic fluids play a pivotal role in preserving and modifying the early-formed pores. In the deep environment characterized by high temperature and pressure, microbial dolomite reservoirs undergo intricate diagenetic evolution and possess complex pore preservation mechanisms. Remarkably, even under exceptional ultra-deep conditions, high-quality microbial dolomite carbonate reservoirs can still develop and be preserved, presenting significant potential for oil and gas exploration.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107084"},"PeriodicalIF":3.7,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142311306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-06DOI: 10.1016/j.marpetgeo.2024.107090
Yuchao Wang , Dongxia Chen , Lanxi Rong , Jialing Chen , Fuwei Wang , Shijie He , Yuqi Wang , Zijie Yang , Wenzhi Lei
The Paleogene lacustrine delta–turbidite facies sandstones of the Third Member of the Shahejie Formation (Es3) in the Linnan Depression have abundant tight oil resources. Movable fluids can independently characterize reservoir fluid mobility and recovery efficiency, which are essential for accurate reservoir assessment and efficient development and evaluation of oil reservoirs. Systematic research on the distribution patterns and controlling factors of movable fluids in the tight sandstone reservoirs of the Linnan Depression is lacking. To address this gap, this study employs multi-gradient centrifugation combined with Nuclear Magnetic Resonance (NMR) to characterize fluid mobility and determine the lower limit of the movable fluid pore radius (LLMPR) in various lithofacies of lacustrine delta-turbidite facies sandstones. In conjunction with core descriptions, thin section observations, X-ray diffraction (XRD) analysis, gas permeability tests, and High-pressure mercury injection (HPMI) data, this research explicates the macroscopic impacts of depositional and diagenetic processes and the microscopic effects of pore structure on fluid movability. The study identifies four lithofacies (delta front facies massive siltstone (DFMS)、delta front facies laminated siltstone (DFLS)、slump turbidite facies siltstone (STS), and slump turbidite facies calcareous siltstone (STCS)) with corresponding pore structures and space types (I-micropores, II-micropores, mesopores, macropores). DFLS and DFMS feature well-developed primary intergranular and intragranular dissolution pores, high HPMI mercury intrusion saturation, and large average pore radius, primarily contributing to fluid mobility through mesopores and macropores with movable fluid saturation of 56.1% and 52.9%, respectively. In contrast, STS and STCS mainly comprise mesopores and micropores with lower movable fluid saturation of 33.5% and 27.5%, influenced by clay filling and carbonate cementation, resulting in poor connectivity. Macroscopically, better-sorted delta-front sand bodies develop connected pores within rigid quartz and feldspar particle frameworks, increasing the proportion of mesopores and macropores. Microscopically, reservoir properties, RQI, maximum invasion saturation, displacement pressure, and average pore radius significantly influence fluid movability. As centrifugal force increases, fluid output from pores slows, and the LLMPR decreases exponentially. At an optimal centrifugal force of 2.75 MPa, the LLMPR in the Linnan Depression is calculated to be 0.033 μm. Based on these insights, a fluid mobility model for lacustrine delta front-turbidite facies tight sandstones is established, identifying DFMS and DFLS as the optimal lithofacies for movable fluids. This study provides theoretical references for understanding and effectively developing deep tight sandstone reservoirs.
{"title":"Evaluation of fluid mobility and factors influencing the deep tight sandstone of the third member of the Shahejie formation in the Jiyang depression, Bohai Bay Basin","authors":"Yuchao Wang , Dongxia Chen , Lanxi Rong , Jialing Chen , Fuwei Wang , Shijie He , Yuqi Wang , Zijie Yang , Wenzhi Lei","doi":"10.1016/j.marpetgeo.2024.107090","DOIUrl":"10.1016/j.marpetgeo.2024.107090","url":null,"abstract":"<div><p>The Paleogene lacustrine delta–turbidite facies sandstones of the Third Member of the Shahejie Formation (Es<sub>3</sub>) in the Linnan Depression have abundant tight oil resources. Movable fluids can independently characterize reservoir fluid mobility and recovery efficiency, which are essential for accurate reservoir assessment and efficient development and evaluation of oil reservoirs. Systematic research on the distribution patterns and controlling factors of movable fluids in the tight sandstone reservoirs of the Linnan Depression is lacking. To address this gap, this study employs multi-gradient centrifugation combined with Nuclear Magnetic Resonance (NMR) to characterize fluid mobility and determine the lower limit of the movable fluid pore radius (LLMPR) in various lithofacies of lacustrine delta-turbidite facies sandstones. In conjunction with core descriptions, thin section observations, X-ray diffraction (XRD) analysis, gas permeability tests, and High-pressure mercury injection (HPMI) data, this research explicates the macroscopic impacts of depositional and diagenetic processes and the microscopic effects of pore structure on fluid movability. The study identifies four lithofacies (delta front facies massive siltstone (DFMS)、delta front facies laminated siltstone (DFLS)、slump turbidite facies siltstone (STS), and slump turbidite facies calcareous siltstone (STCS)) with corresponding pore structures and space types (I-micropores, II-micropores, mesopores, macropores). DFLS and DFMS feature well-developed primary intergranular and intragranular dissolution pores, high HPMI mercury intrusion saturation, and large average pore radius, primarily contributing to fluid mobility through mesopores and macropores with movable fluid saturation of 56.1% and 52.9%, respectively. In contrast, STS and STCS mainly comprise mesopores and micropores with lower movable fluid saturation of 33.5% and 27.5%, influenced by clay filling and carbonate cementation, resulting in poor connectivity. Macroscopically, better-sorted delta-front sand bodies develop connected pores within rigid quartz and feldspar particle frameworks, increasing the proportion of mesopores and macropores. Microscopically, reservoir properties, RQI, maximum invasion saturation, displacement pressure, and average pore radius significantly influence fluid movability. As centrifugal force increases, fluid output from pores slows, and the LLMPR decreases exponentially. At an optimal centrifugal force of 2.75 MPa, the LLMPR in the Linnan Depression is calculated to be 0.033 μm. Based on these insights, a fluid mobility model for lacustrine delta front-turbidite facies tight sandstones is established, identifying DFMS and DFLS as the optimal lithofacies for movable fluids. This study provides theoretical references for understanding and effectively developing deep tight sandstone reservoirs.</p></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"170 ","pages":"Article 107090"},"PeriodicalIF":3.7,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}