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Pioneering data on detection, identification and quantification of key carbonate minerals using spectral tomography 利用光谱层析成像技术对关键碳酸盐矿物进行探测、鉴定和定量的开创性数据
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-05 DOI: 10.1016/j.marpetgeo.2025.107536
Kanchana Kularatne , Nicolas E. Beaudoin , Pascale Sénéchal , Peter Moonen , Souhail Youssef , Fadi H. Nader
In this study, we present, for the first time, the spectral computed tomography (sp-CT) signatures of key carbonate rock-forming minerals namely, calcite, magnesian calcite, dolomite, and magnesite. Although the raw spectra of these phases may not be readily distinguishable, we demonstrate that they appear in clusters on a multi-energy histogram derived from laboratory sp-CT. These clusters show a strong correlation with the MgCO3 mol.% of the carbonate phases. In addition to discriminating among these carbonate phases, we demonstrate the capability of time-resolved sp-CT to monitor mineral replacement reactions in carbonates. As an example, we analyze a series of time-lapse sp-CT images of a carbonate sample undergoing hydrothermal dolomitization in the laboratory. The results reveal a progressive transformation of pure calcite into an Mg-rich carbonate, with the sp-CT data indicating a final composition of approximately 32 mol.% MgCO3. This estimate, while lower than the 46–50 mol.% MgCO3 determined through complementary chemical analysis, provides a valuable first-order approximation. This contribution introduces a novel methodology for visualizing, monitoring, and quantifying such chemical reactions in multi-phase carbonate systems, in 2D, 3D and even 4D, offering advantages over destructive techniques such as 3D FIB-tomography. Our findings pave the way to further exploration of carbonate diagenesis and open up new perspectives for the application of spectral tomography in Earth sciences.
在这项研究中,我们首次提出了关键碳酸盐岩形成矿物方解石、镁质方解石、白云石和菱镁矿的光谱计算机断层扫描(sp-CT)特征。虽然这些相的原始光谱可能不容易区分,但我们证明它们出现在实验室sp-CT衍生的多能直方图上。这些团簇与碳酸盐相的MgCO3摩尔%有很强的相关性。除了区分这些碳酸盐相外,我们还展示了时间分辨sp-CT监测碳酸盐中矿物替代反应的能力。作为一个例子,我们分析了一系列在实验室中经历热液白云化的碳酸盐样品的延时sp-CT图像。结果显示,纯方解石逐渐转变为富镁碳酸盐,sp-CT数据表明,最终成分约为32mol .% MgCO3。这一估计虽然低于通过补充化学分析确定的46-50 mol.% MgCO3,但提供了有价值的一阶近似。这一贡献介绍了一种新的方法,用于在2D、3D甚至4D多相碳酸盐系统中可视化、监测和定量此类化学反应,具有优于3D fib断层扫描等破坏性技术的优势。这些发现为进一步探索碳酸盐岩成岩作用铺平了道路,为光谱层析成像在地球科学中的应用开辟了新的前景。
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引用次数: 0
Pyrite morphologies in Bazhenov Formation source rocks: diversity, systematic classification, sulfur isotopic composition and insights into sedimentation and diagenesis processes 巴治诺夫组烃源岩黄铁矿形态:多样性、系统分类、硫同位素组成及沉积成岩作用
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-05 DOI: 10.1016/j.marpetgeo.2025.107535
Alina Karamova, Tagir Karamov, Mikhail Spasennykh
Pyrite is a common authigenic mineral in organic-rich source rocks, which is diverse in morphology and carries valuable genetic information about geological processes. This study proposes comprehensive genetic morphological classification of pyrite aggregates in organic-rich shales of the Bazhenov Formation – one of the world largest source rock located in the Western Siberia. Scanning electron microscopy was used to analyze over 530 samples from 17 wells, identifying various types of pyrite such as framboids (with corresponding subtypes based on orderliness of the internal structure, crystallographic shape of microcrystals, infilling of internal structure, and integrity), euhedral crystals, and pyrite pseudomorphosis. The obtained sulfur isotopic composition for framboidal pyrite, which turned out to be the lightest (δ34S vary in the range from −55.38 ‰ to −26.02 ‰), is indicative of anoxic conditions on seafloor. Euhedral pyrite develops in diagenesis under limited sulfate supply, reflecting slow growth in pore-water depleted in 32S (δ34S values range from +15.05 ‰ to +26.49 ‰). Described morphological types cover the diversity of pyrite forms in other similar geological objects around the world, which allows pyrite to be used as a geochemical proxy for paleoenvironmental reconstructions and hydrocarbon exploration, enhancing understanding of sulfur cycle and basin evolution.
黄铁矿是富有机质烃源岩中常见的自生矿物,其形态多样,具有重要的地质成因信息。本文提出了世界上最大的烃源岩之一、位于西伯利亚西部的巴济诺夫组富有机质页岩中黄铁矿聚集体的综合成因形态分类。利用扫描电镜对17口井的530余份样品进行了分析,鉴定出了草莓状(根据内部结构的有序性、微晶的晶体形态、内部结构的充填性、完整性等特征对应的亚型)、自形晶体和黄铁矿假形态等多种黄铁矿类型。树状黄铁矿的硫同位素组成最轻(δ34S变化范围为−55.38‰~−26.02‰),反映了海底缺氧条件。自形黄铁矿在硫酸盐供应有限的条件下发育,反映了32S枯竭孔隙水生长缓慢(δ34S值范围为+15.05‰~ +26.49‰)。所描述的形态类型涵盖了世界上其他类似地质对象中黄铁矿形态的多样性,这使得黄铁矿可以作为古环境重建和油气勘探的地球化学指标,增强了对硫循环和盆地演化的认识。
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引用次数: 0
Trace and rare earth element signatures in microcrystalline aragonite as indicators of oil vs. methane seepage 微晶文石中微量元素和稀土元素特征作为油与甲烷渗漏的指示物
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-04 DOI: 10.1016/j.marpetgeo.2025.107534
Yuedong Sun , Shanggui Gong , Jörn Peckmann , Fang Chen , Yao Guan , Dong Feng
Oil seeps are important hydrocarbon sources to the ocean and sustain diverse chemosynthesis-based ecosystems. Distinguishing oil- from methane-dominated seeps in the geological record is crucial for reconstructing the evolution of chemosynthetic communities, yet remains challenging. Authigenic carbonates precipitating at seeps offer a valuable archive of the composition of seep fluid. While previous work has focused on fibrous aragonite cement, the geochemical potential of volumetrically dominant microcrystalline analog remains underexplored. Here, we present a comprehensive study of the petrography and stable isotope as well as element composition of oil-derived seep carbonates from the northern Gulf of Mexico (sites GC232, GC185), compared to methane-derived seep carbonates from the northern Gulf of Mexico (site AT340) and the South China Sea (site GMGS2-08). All studied samples are dominated by microcrystalline aragonite. Carbon isotope data (average δ13C = −20.9 ± 4.5 ‰; VPDB) and the presence of oil residues agree with crude oil degradation as the main carbon source of the oil-seep carbonate. Compared to methane-seep carbonates, oil-seep carbonates exhibit higher rare earth elements (REE) contents, slight light-REE enrichment, and elevated contents of uranium (U), molybdenum (Mo), zinc (Zn), and cobalt (Co), signatures linked to microbial oil oxidation. These element patterns preserved in microcrystalline aragonite offer a novel proxy for identifying oil seepage in the rock record, particularly in cases where fibrous cement is absent.
石油渗漏是海洋重要的碳氢化合物来源,并维持着以化学合成为基础的多种生态系统。在地质记录中区分石油和甲烷为主的渗漏对于重建化学合成群落的演化至关重要,但仍然具有挑战性。在渗漏处沉淀的自生碳酸盐为渗漏流体的组成提供了宝贵的资料。虽然以前的工作主要集中在纤维文石水泥上,但体积优势微晶模拟物的地球化学潜力仍未得到充分探索。本文对墨西哥湾北部(GC232、GC185)的油源渗碳酸盐岩与墨西哥湾北部(AT340)和南海(GMGS2-08)的甲烷源渗碳酸盐岩进行了岩石学、稳定同位素和元素组成的对比研究。所有研究样品均以微晶文石为主。碳同位素数据(平均δ13C =−20.9±4.5‰;VPDB)和油渣的存在与原油降解为渗油碳酸盐岩的主要碳源一致。与甲烷渗碳酸盐相比,油渗碳酸盐表现出较高的稀土元素(REE)含量,轻度轻稀土元素富集,铀(U)、钼(Mo)、锌(Zn)和钴(Co)含量升高,这些特征与微生物油氧化有关。这些保存在微晶文石中的元素模式为识别岩石记录中的石油渗漏提供了一种新的替代方法,特别是在纤维性水泥缺失的情况下。
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引用次数: 0
Inter-strata oil migration and its implications of hydrocarbon accumulation in the lacustrine shale system of the Lucaogou Formation, Jimusaer Sag, Junggar Basin 准噶尔盆地吉木萨尔凹陷芦草沟组湖相页岩体系油层间运移及其油气成藏意义
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-03 DOI: 10.1016/j.marpetgeo.2025.107533
Enze Wang , Maowen Li , Xiaoxiao Ma , Menhui Qian , Tingting Cao , Zhiming Li , Zhijun Jin
Traditionally, shale petroleum systems are considered to possess self-generating and self-storing characteristics. However, with the advancement in understanding of these systems, researchers have discovered that hydrocarbon migration is a common phenomenon within them. Given that the scale of hydrocarbon migration in shale petroleum systems is significantly smaller compared to conventional systems, identifying such migration within shales remains a challenging endeavor. Moreover, few studies have systematically discussed the impact of hydrocarbon migration on petroleum accumulation in shale systems. This study focuses on the Lucaogou Formation in the Jimusar Sag of the Junggar Basin. Building upon geochemical data reported by previous research, we have reinterpreted and further explored geochemical data, presenting a novel approach for quantitatively identifying various types of hydrocarbon migration within shale using pyrolysis and molecular geochemical parameters, which are commonly generated in the petroleum industry. Additionally, it explores the influence of hydrocarbon migration on oil enrichment. The findings reveal that various forms of hydrocarbon migration have contributed to the paradoxes in the pyrolysis (the mismatch between TOC and S1 contents) and molecular geochemical features (anomalies of the C29 αββ/(αββ+ααα) and C29 ααα 20S/(20S + 20R) ratios) of the Lucaogou Formation. Based on the hydrocarbon migration status, four distinct types of reservoirs are identified within the Lucaogou Formation shale: lateral migration, carrier bed, inter-layer migration, and in situ retention. According to exploration practices, the Lucaogou shale can be divided into different sections (upper section sweet spot, middle section mudstone, and lower section sweet spot), each exhibiting distinct differences in hydrocarbon migration types. Lateral migration is commonly observed in the upper section sweet spot, whereas in the middle-section mudstone and the lower section sweet spot, the occurrence of lateral migration is limited, with inter-layer migration and in situ retention being more prevalent. In shale systems, extensive lateral hydrocarbon migration facilitates the formation of localized, high-quality exploration sweet spots, although these sweet spots bear more resemblance to conventional structural-lithologic reservoirs. Future exploration and development strategies for shale petroleum systems should consider the patterns of hydrocarbon migration when formulating plans. This study offers a framework for the detailed characterization of hydrocarbon migration types within shale petroleum systems and highlights the impact of hydrocarbon migration on shale oil enrichment.
传统上认为页岩油系统具有自生自储的特点。然而,随着对这些系统认识的不断深入,研究人员发现,油气运移是这些系统中常见的现象。与常规系统相比,页岩油气系统中的油气运移规模要小得多,因此在页岩中识别此类运移仍然是一项具有挑战性的工作。此外,很少有研究系统地讨论油气运移对页岩油气成藏的影响。本文以准噶尔盆地吉木萨尔凹陷芦草沟组为研究对象。在以往研究报告的地球化学数据基础上,我们对地球化学数据进行了重新解释和进一步探索,提出了一种利用石油工业中常见的热解和分子地球化学参数定量识别页岩中各种类型烃运移的新方法。探讨了油气运移对油气富集的影响。结果表明,烃类运移的多种形式导致芦草沟组热解(TOC与S1含量不匹配)和分子地球化学特征(C29 ααα αα /(αββ+ααα)和C29 ααα 20S/(20S + 20R)比值异常)的矛盾。根据油气运移状况,将芦草沟组页岩划分为侧向运移型、载体层型、层间运移型和原地滞留型4种类型。根据勘探实践,芦草沟页岩可划分为不同剖面(上部甜点、中部泥岩、下部甜点),各剖面油气运移类型差异明显。横向运移主要发生在上部甜点区,而中部泥岩和下部甜点区横向运移较少,以层间运移和原地滞留为主。在页岩系统中,广泛的横向油气运移有助于形成局部的、高质量的勘探甜点,尽管这些甜点与常规的构造岩性油藏更相似。未来页岩油气勘探开发规划应考虑油气运移规律。该研究为页岩油气系统内油气运移类型的详细表征提供了框架,并突出了油气运移对页岩油富集的影响。
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引用次数: 0
Onset of the Messinian Salinity Crisis: Insights from molecular organic geochemistry 墨西尼亚盐度危机的开始:来自分子有机地球化学的见解
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-02 DOI: 10.1016/j.marpetgeo.2025.107532
A. Permanyer , M.A. Kruge , L. Gibert
The Messinian Salinity Crisis (MSC) generated extensive anoxic sediments under the evaporitic deposits in marginal Mediterranean basins. In an interdisciplinary approach combining field work with multiple laboratory techniques, the oil source rock potential and biomarkers of pre-evaporitic Messinian sediments from the Caltanissetta Basin (Sicily) were evaluated using Rock-Eval pyrolysis, gas chromatography-mass spectrometry, isotopic analysis and optical and electron microscopy. Organic-rich samples from the 45 m Serra Pirciata section consist of cycles of diatomaceous and carbonate layers alternating with organic shales of variable TOC. The organic matter is mostly optically amorphous, increasing in content upwards in the section. Of the 43 samples analyzed within the section, an especially organic- and sulfur-rich interval shows TOC values up to 10 %, and oil generation potential (Rock-Eval S2) up to 75 mg HC/g rock. Samples show Rock-Eval Hydrogen Indices (HI) up to ca. 800 mg HC/g TOC, but most fall in the range of 300–600 mg HC/g TOC, indicating type II kerogen. Within this section, a specific interval is especially remarkable for its unusual biomarker assemblage, having abundant sulfur compounds including isoprenoid, steroid, and hopanoid thiophenes and thiolanes, as well as microscopic sponge fossils. We propose that this organic-rich interval with its distinctive biomarkers represents an initial episode of basin restriction and, based on cyclostratigraphic interpretations, constitutes a non-evaporitic record of the onset of the MSC in the deeper part of the Caltanissetta Basin, where gypsum deposits were initially absent. If the depocenter of the Caltanissetta Basin is an analog for the deep Mediterranean basin, these results suggest that a large volume of organic matter of bacterial origin accumulated in the deep Mediterranean prior to evaporitic deposition.
迈西尼亚盐危机(MSC)在地中海边缘盆地的蒸发沉积下产生了广泛的缺氧沉积。采用跨学科的方法,结合现场工作和多种实验室技术,利用岩石热解、气相色谱-质谱、同位素分析、光学和电子显微镜对西西里岛Caltanissetta盆地前蒸发期迈西旦期沉积物的油源岩潜力和生物标志物进行了评估。45 m Serra Pirciata剖面的富有机质样品由硅藻质和碳酸盐层的旋回与可变TOC的有机页岩交替组成。有机质大部分为光学无定形,在剖面上含量向上增加。在该剖面分析的43个样品中,一个特别富有机和富硫的层段显示TOC值高达10%,生油潜力(rock - eval S2)高达75 mg HC/g岩石。岩石评价氢指数(HI)可达800 mg HC/g TOC左右,但大部分在300 ~ 600 mg HC/g TOC之间,为ⅱ型干酪根。在这一剖面中,一个特定的层段因其不寻常的生物标志物组合而特别引人注目,其中含有丰富的含硫化合物,包括类异戊二烯、类固醇、类藿烷噻吩和噻烷,以及微观海绵化石。根据旋回地层的解释,我们认为这个富含有机物的层段代表了盆地限制的初始阶段,构成了Caltanissetta盆地深层MSC开始的非蒸发记录,那里最初没有石膏矿床。如果Caltanissetta盆地的沉积中心与地中海盆地相似,那么这些结果表明,在蒸发沉积之前,大量细菌来源的有机质在地中海深处积累。
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引用次数: 0
Genesis of differential cementation by authigenic kaolinite in deep-buried tight sandstone reservoirs for the upper Triassic Xujiahe Formation, western Sichuan foreland basin, China 川西前陆盆地上三叠统须家河组深埋致密砂岩储层自生高岭石差异胶结成因
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-28 DOI: 10.1016/j.marpetgeo.2025.107526
Mengfei Zhang , Mingjie Liu , Bo Cao , Peng Huang , Zilong Wang
<div><div>The tight sandstone reservoirs of the Xu3 Member in the Depression Zone of the Western Sichuan Foreland Basin (WSFB-DZ) are characterized by the widespread development of kaolinite cement, with notable cementation variations observed between the northern and southern regions of the depression zone. Utilizing an integrated methodology that encompasses cast thin section petrography, SEM, XRD, CL, fluid inclusion homogenization temperatures, in-situ micro-area carbon and oxygen isotopes, and trace element analysis, this study compared the differential cementation traits and genetic mechanisms of authigenic kaolinite within the Xu3 Member tight sandstone reservoirs, distinguishing between the northern and southern regions of WSFB-DZ. The study indicates that the northern Xu3 Member tight sandstone reservoirs are predominantly litharenite. The authigenic kaolinite crystals exhibit well-defined structures, predominantly, manifesting as pseudo-hexagonal platy single crystals and vermicular-to-booklet-like aggregates. These crystals fill predominantly intragranular dissolution pores and intergranular pores, and coexist mainly with quartz cement and carbonate cement. In contrast, the southern region is primarily litharenite and sublitharenite. The crystal morphology of authigenic kaolinite in this area is less well-developed compared to that in the northern region, with rare vermicular aggregates. Additionally, kaolinite cement in this region underwent substantial transformation into illite and chlorite through late diagenetic alteration. The Xu3 Member tight sandstone reservoirs in the WSFB-DZ exhibit two stages of kaolinite cementation, early and late. These cements originated from the dissolution of easily soluble grains such as feldspar and rock fragments by humic acids derived from early coal-bearing strata and organic acids generated during organic matter maturation and decarboxylation in the late stage. The southern Xu3 Member sandstone reservoirs exhibit a relatively high content of K-feldspar grains, and the dissolution of K-feldspar by organic acids released a significant amount of K<sup>+</sup> ions. Additionally, the late-stage carbonate cementation consumed only a small amount of Fe<sup>2+</sup> and Mg<sup>2+</sup> ions, resulting in late diagenetic fluids that were rich in K<sup>+</sup>, Fe<sup>2+</sup>, and Mg<sup>2+</sup> ions. These geochemical conditions favor the widespread transformation of authigenic kaolinite into illite and chlorite in the southern Xu3 Member sandstone reservoirs. Consequently, the southern sandstones are characterized by a low content of kaolinite cement and a relatively high content of illite and chlorite cement. In contrast, the northern Xu3 Member sandstone reservoirs have a lower content of K-feldspar grains, resulting in reduced K<sup>+</sup> ions release from organic acid dissolution. Simultaneously, the late-stage carbonate cementation sequestered substantial Fe<sup>2+</sup> and Mg<sup>2+</sup> ion
川西前陆盆地坳陷带徐三段致密砂岩储层普遍发育高岭石胶结,坳陷带南北胶结差异明显。利用铸体薄片岩相学、SEM、XRD、CL、流体包裹体均一温度、原位微区碳氧同位素、微量元素分析等综合方法,对比了wsbf - dz许3段致密砂岩储层中自生高岭石的差异胶结特征和成因机制,并对其北部和南部地区进行了区分。研究表明,北徐三段致密砂岩储层以岩屑岩为主。自生高岭石晶体具有明确的结构,主要表现为伪六方片状单晶和蠕蠕状至小册子状聚集体。这些晶体主要充填于粒内溶蚀孔隙和粒间孔隙,主要与石英胶结物和碳酸盐胶结物共存。南部以岩屑岩和次岩屑岩为主。本区自生高岭石的晶体形态较北部地区欠发达,极少见蛭状聚集体。此外,该地区高岭石胶结物在后期成岩蚀变中发生了大量的伊利石和绿泥石转变。WSFB-DZ徐三段致密砂岩储层表现出早、晚两个阶段的高岭石胶结作用。这些胶结物是早期含煤地层中产生的腐植酸和晚期有机质成熟脱羧过程中产生的有机酸对长石、岩屑等易溶颗粒的溶解作用形成的。南旭3段砂岩储层钾长石颗粒含量较高,有机酸对钾长石的溶蚀释放出大量的钾离子。晚期碳酸盐胶结作用仅消耗少量的Fe2+和Mg2+离子,形成了富含K+、Fe2+和Mg2+离子的晚期成岩流体。这些地球化学条件有利于徐三段南部砂岩储层中自生高岭石向伊利石和绿泥石的广泛转化。因此,南部砂岩的特点是高岭石胶结物含量低,伊利石和绿泥石胶结物含量相对较高。北徐三段砂岩储层钾长石颗粒含量较低,导致有机酸溶蚀释放的K+离子减少。同时,晚期碳酸盐胶结封存了大量的Fe2+和Mg2+离子,导致晚期成岩流体中K+、Fe2+和Mg2+离子的富集。这些条件只导致高岭石水泥的部分伊利石化和绿泥石化,主要表现为高岭石水泥含量相对较高,伊利石和绿泥石含量较低。徐三段砂岩中钾长石颗粒含量和碳酸盐胶结作用的差异,导致晚期成岩流体中微量元素离子浓度的变化,是造成南北地区徐三段砂岩中自生高岭石胶结差异的关键因素。
{"title":"Genesis of differential cementation by authigenic kaolinite in deep-buried tight sandstone reservoirs for the upper Triassic Xujiahe Formation, western Sichuan foreland basin, China","authors":"Mengfei Zhang ,&nbsp;Mingjie Liu ,&nbsp;Bo Cao ,&nbsp;Peng Huang ,&nbsp;Zilong Wang","doi":"10.1016/j.marpetgeo.2025.107526","DOIUrl":"10.1016/j.marpetgeo.2025.107526","url":null,"abstract":"&lt;div&gt;&lt;div&gt;The tight sandstone reservoirs of the Xu3 Member in the Depression Zone of the Western Sichuan Foreland Basin (WSFB-DZ) are characterized by the widespread development of kaolinite cement, with notable cementation variations observed between the northern and southern regions of the depression zone. Utilizing an integrated methodology that encompasses cast thin section petrography, SEM, XRD, CL, fluid inclusion homogenization temperatures, in-situ micro-area carbon and oxygen isotopes, and trace element analysis, this study compared the differential cementation traits and genetic mechanisms of authigenic kaolinite within the Xu3 Member tight sandstone reservoirs, distinguishing between the northern and southern regions of WSFB-DZ. The study indicates that the northern Xu3 Member tight sandstone reservoirs are predominantly litharenite. The authigenic kaolinite crystals exhibit well-defined structures, predominantly, manifesting as pseudo-hexagonal platy single crystals and vermicular-to-booklet-like aggregates. These crystals fill predominantly intragranular dissolution pores and intergranular pores, and coexist mainly with quartz cement and carbonate cement. In contrast, the southern region is primarily litharenite and sublitharenite. The crystal morphology of authigenic kaolinite in this area is less well-developed compared to that in the northern region, with rare vermicular aggregates. Additionally, kaolinite cement in this region underwent substantial transformation into illite and chlorite through late diagenetic alteration. The Xu3 Member tight sandstone reservoirs in the WSFB-DZ exhibit two stages of kaolinite cementation, early and late. These cements originated from the dissolution of easily soluble grains such as feldspar and rock fragments by humic acids derived from early coal-bearing strata and organic acids generated during organic matter maturation and decarboxylation in the late stage. The southern Xu3 Member sandstone reservoirs exhibit a relatively high content of K-feldspar grains, and the dissolution of K-feldspar by organic acids released a significant amount of K&lt;sup&gt;+&lt;/sup&gt; ions. Additionally, the late-stage carbonate cementation consumed only a small amount of Fe&lt;sup&gt;2+&lt;/sup&gt; and Mg&lt;sup&gt;2+&lt;/sup&gt; ions, resulting in late diagenetic fluids that were rich in K&lt;sup&gt;+&lt;/sup&gt;, Fe&lt;sup&gt;2+&lt;/sup&gt;, and Mg&lt;sup&gt;2+&lt;/sup&gt; ions. These geochemical conditions favor the widespread transformation of authigenic kaolinite into illite and chlorite in the southern Xu3 Member sandstone reservoirs. Consequently, the southern sandstones are characterized by a low content of kaolinite cement and a relatively high content of illite and chlorite cement. In contrast, the northern Xu3 Member sandstone reservoirs have a lower content of K-feldspar grains, resulting in reduced K&lt;sup&gt;+&lt;/sup&gt; ions release from organic acid dissolution. Simultaneously, the late-stage carbonate cementation sequestered substantial Fe&lt;sup&gt;2+&lt;/sup&gt; and Mg&lt;sup&gt;2+&lt;/sup&gt; ion","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"181 ","pages":"Article 107526"},"PeriodicalIF":3.7,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144523363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiple observations to delineate the characteristics of cold seep system in the Qiongdongnan Basin 多观测圈定琼东南盆地冷渗系统特征
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-27 DOI: 10.1016/j.marpetgeo.2025.107522
Xiujuan Wang , Wenlu Wang , Jiapeng Jin , Guangxu Zhang , Zhendong Luan , Chaolun Li , Minxiao Wang , Zhengyi Zhang , Bo Liu , Wei Li , Sanzhong Li
Cold seeps in the Qiongdongnan Basin have been identified from three-dimensional (3D) seismic data, geophysical attributes, and in situ observations. Amplitude, dip, coherence and acoustic impedance attributes are employed to delineate the spatial variations of cold seeps across different layers by identifying faults, fractures and reservoir properties. These variations arise from the differences inside and outside of cold seeps due to the occurrence of gas hydrate, where mass transport deposits (MTDs) are widely distributed. The primary objective is to characterize the diverse features of cold seep systems, including seafloor features, plumbing systems, and their potential relationships with gas hydrates and shallow gas. Moreover, new remotely operated vehicle (ROV) dives have been utilized to distinguish two distinct chemosynthetic biological communities associated with methane bubble plumes. One community represents an active cold seep, characterized by abundant mussels and clams on or around carbonates, while the other is a paleo-cold seep that has been reactivated by gas hydrate drilling due to the leakage of trapped gas near the base of gas hydrate stability zone. All identified cold seeps exhibit weak amplitude anomalies, pull-up reflections, and chimney-like structures, which are located within high amplitude zones above local uplift in different sags of the Qiongdongnan Basin. Logging-while-drilling and coring data within these chimney-like structures have confirmed moderate to high gas hydrate saturations with diverse morphologies, as well as methane-related carbonates, indicating the presence of buried or active cold seeps. These findings suggest that cold seep activity is influenced by MTDs and that the upward fluid migration is closely linked to deep gas or shallow gas below the BGHSZ, which penetrate through MTDs along fault and fracture systems, suggesting pressure-controlled gas seepage.
利用三维地震资料、地球物理属性和现场观测资料对琼东南盆地冷渗进行了识别。通过识别断层、裂缝和储层物性,利用振幅、倾角、相干性和声阻抗属性来描绘不同层间冷渗的空间变化。这些变化是由于天然气水合物的发生导致冷渗漏内部和外部的差异造成的,而冷渗漏内部和外部的质量输运沉积物(MTDs)分布广泛。主要目标是表征冷渗系统的各种特征,包括海底特征、管道系统,以及它们与天然气水合物和浅层天然气的潜在关系。此外,新的遥控潜水器(ROV)潜水已被用于区分与甲烷气泡羽流相关的两种不同的化学合成生物群落。一个群落代表活跃的冷渗层,其特征是在碳酸盐岩上或周围有大量的贻贝和蛤蜊;另一个群落代表古冷渗层,由于天然气水合物稳定带底部附近的圈闭气体泄漏而被天然气水合物钻探重新激活。已识别的冷渗漏均表现为弱振幅异常、拉升反射和烟囱状构造,位于琼东南盆地不同凹陷局部隆起以上的高振幅带内。随钻测井和取心数据在这些烟囱状结构中证实了具有不同形态的中高天然气水合物饱和度,以及与甲烷相关的碳酸盐,表明存在埋藏或活跃的冷渗漏。这些结果表明,冷渗活动受MTDs的影响,流体向上运移与BGHSZ以下深层或浅层气体运移密切相关,流体沿断裂和裂缝系统穿过MTDs,具有压力控制的气体渗流特征。
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引用次数: 0
Paleolandscapes recorded by the Top Basement surface in the Norwegian North Sea 挪威北海顶部基底面记录的古地貌
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-27 DOI: 10.1016/j.marpetgeo.2025.107527
M.S. Bauck , J.I. Faleide , H. Fossen , R.L. Gawthorpe
Mapping the diachronous Top Basement in the North Sea reveals a complex amalgamation of paleolandscapes and provides valuable insights into the Late Paleozoic and Mesozoic geologic history. To illuminate the temporal geologic and geomorphic evolution, we document and analyze geomorphic characteristics and relate these to the regional tectonostratigraphic events. The paleolandscapes represented by the Top Basement surface generally fall into the following categories: rough, irregular terrains; rough, confined drainage networks; and smooth, planar landscapes. Notably, the irregular landscape found at the base of the deep basins is covered by Upper Paleozoic sediments and represents a potential late stage of the Devonian denudation of the Caledonian mountain chain. A distinct drainage network on the Top Basement of the Patch Bank Ridge represents two exposure phases: one related to extension during Devonian exhumation and the other associated with Carboniferous exhumation. Two regional tectonic events are candidates for such Carboniferous exhumation, one is Variscan contraction, the other is the Pennsylvanian event dated onshore Greenland and Fenoscandia. Preserved drainage networks observed on various basement highs correspond to local Late Permian to Early Triassic fault block uplift. In tilted fault blocks, these features are significant, while in horst block structures, smooth, planar landscape expression occurs. This is linked to repeated uplift of horst block structures, while tilted fault blocks get buried sooner. A distinct terrain observed in a confined area on the western Måløy Slope exhibits geomorphic characteristics comparable to those found on the tilted Vette and Tusse fault blocks overlain by sediment of Triassic or older origin. Thus, we suggest that this is a strong indication that Late Permian to Early Triassic rifting impacted the Måløy Slope. Tectonic and climatic processes controlled the relief and spatial extent of these landscapes. Our findings correlate with onshore exhumation and landscape development documented from other studies onshore East Greenland and Fennoscandia. These insights highlight the potential for identifying further paleolandscape features across the wider North Sea region and beyond.
绘制北海顶基底的历时图揭示了古地貌的复杂融合,为了解晚古生代和中生代的地质历史提供了有价值的见解。为了阐明时间地质和地貌演化,我们记录和分析了地貌特征,并将其与区域构造地层事件联系起来。以上基底面为代表的古地貌一般分为以下几类:粗糙、不规则的地形;粗糙的、密闭的排水网络;以及平滑、平面的景观。值得注意的是,在深盆底部发现的不规则景观被上古生界沉积物覆盖,代表了加里东山脉的泥盆世晚期剥蚀。Patch Bank Ridge顶部基底上有一个独特的排水网络,代表了两个暴露阶段:一个与泥盆纪挖掘时的伸展有关,另一个与石炭纪挖掘有关。两个区域构造事件是石炭纪发掘的候选事件,一个是Variscan收缩,另一个是宾夕法尼亚事件,可追溯到格陵兰岛和Fenoscandia岸上。在不同基底高地观测到的保留的水系网络对应于局部晚二叠世至早三叠世断块隆起。在倾斜断块中,这些特征非常明显,而在主体断块结构中,则表现为光滑的平面景观。这与主块体构造的反复隆升有关,而倾斜的断块被埋得更快。在马洛伊斜坡西部的一个封闭区域观察到的独特地形,其地貌特征与三叠纪或更早起源的沉积物覆盖的倾斜的Vette和Tusse断块相似。因此,我们认为这是一个强烈的迹象,表明晚二叠世至早三叠世的裂陷作用影响了马 løy斜坡。构造和气候过程控制着这些景观的地形和空间范围。我们的发现与东格陵兰岛和芬诺斯坎迪亚的其他陆上研究记录的陆上挖掘和景观发展有关。这些见解强调了在更广泛的北海地区及其他地区进一步识别古地貌特征的潜力。
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引用次数: 0
Tectono-stratigraphic evolution of the Late Cretaceous-Eocene of Jordan and implications for the Arabian Plate convergent margin phase 约旦晚白垩世-始新世构造地层演化及其对阿拉伯板块辐合边缘期的启示
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-27 DOI: 10.1016/j.marpetgeo.2025.107525
Amir Kalifi , Jihede Haj Messaoud , Guillaume Baby , Khalil Ibrahim , John H. Powell , Frans van Buchem
The Late Cretaceous-Eocene geodynamic evolution of Jordan is presented, combining, for the first-time, outcrop and subsurface data in this poorly known, yet important part of the Arabian Plate. A new age model developed for outcrop sections, integrating biostratigraphy, C/O and Sr isotopes, together with seismic and well log data significantly improves the timing of the structural events in Jordan and shows their potential relationship to Arabian Plate scale deformation events.
The late Albian-early Turonian displays a gradual north-northwestward thickening trend across Jordan during a phase of tectonic quiescence, whereas in the overlying late Turonian-early Campanian there is ample evidence for extensional/transtensional tectonic activity, with an acme during the early Campanian, expressed in the development of the northwest-trending Azraq-Hamza Graben in central-east Jordan. This graben, with an offset of c. 1800 m, extends southeastwards to the Wadi Sirhan Graben in Saudi Arabia and northwestwards to the Levant Basin. The subsequent late Campanian-Eocene succession records reduced tectonic subsidence within the graben during a sag phase and marks a return to regional stability.
The Azraq-Hamza Graben is proven to be time-equivalent to the similarly oriented extensional events in Syria (Euphrates Graben) and Iraq (Sinjar Graben) and is coeval with the compressional structures of the foreland basins in Oman and Iran. This study contributes, to the large-scale tectonic evaluation of the African-Arabian plate deformation and evolution during the Late Cretaceous obduction and subduction phases, which played a critical role in the shaping of the petroleum systems and phosphorite sedimentation of the region.
本文介绍了约旦晚白垩世-始新世的地球动力学演化,首次结合了这个鲜为人知但重要的阿拉伯板块的露头和地下数据。结合生物地层学、C/O和Sr同位素以及地震和测井资料,建立了一个新的露头剖面时代模型,显著改善了约旦构造事件的时间,并显示了它们与阿拉伯板块尺度变形事件的潜在关系。在构造静止期,晚阿尔—早Turonian期在约旦表现出逐渐的北-西北向的增厚趋势,而在上覆的晚Turonian—早坎帕尼亚期则有充分的伸展/张拉构造活动证据,在坎帕尼亚期早期达到高峰,表现为约旦中东部西北走向的Azraq-Hamza地堑的发育。这个地堑,偏移约1800米,东南延伸到沙特阿拉伯的Wadi Sirhan地堑,西北延伸到黎凡特盆地。随后的晚坎帕世-始新世序列记录了断陷期地堑内的构造沉降减少,标志着区域稳定的回归。Azraq-Hamza地堑与叙利亚(幼发拉底河地堑)和伊拉克(辛贾尔地堑)的伸展活动在时间上相当,与阿曼和伊朗前陆盆地的挤压构造在时间上相同。该研究有助于对晚白垩世逆冲和俯冲期非洲-阿拉伯板块的变形演化进行大规模的构造评价,该时期的构造演化对该地区油气系统的形成和磷矿沉积起着至关重要的作用。
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引用次数: 0
Submarine morphology offshore Crotone (Calabrian accretionary prism, Central Mediterranean): Pockmark fields and mud extrusion in a mobile shale domain 克罗托内近海海底形态(地中海中部卡拉布里亚增生棱镜):活动页岩域的麻坑田和泥挤压
IF 3.7 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-06-27 DOI: 10.1016/j.marpetgeo.2025.107530
Andrea Argnani, Marzia Rovere
The narrow Calabrian Arc accretionary prism, in the Mediterranean Sea, is known to be populated by mud volcanoes, although only a few of them have been extensively documented. The Ionian Sea offshore the Crotone Promontory offers examples where the expressions of fluid expulsion and sediment mobilization are visible both in the subsurface and at the seafloor. The analysis of a proprietary 3D seismic data cube allows characterization of pockmark patterns and identification of a mud diapir, which appears at the seafloor as a large mud pool, ca. 1200 m in diameter. The high resolution 3D seismic profiles allow differences to be inferred about the mechanisms of fluid focusing at very shallow sub-seafloor depths. Fluid focusing and pockmark formation are aided by normal faults arising from both outer arc extension and dilation in shallow unconsolidated sediments influenced by sharp increases in slope gradient. In some instances, it can be shown that fluid venting also contributed to destabilizing the uppermost sedimentary strata, triggering small landslides along the slope. The mud diapir has apparently been mobilized along an extensional fault, which tapped into a mobile shale domain. A fossil mud pool has also been recognized in the study area. This fossil mud pool is sealed by undeformed sedimentary strata which constrains a minimum age for fluid and sediment mobilization in the accretionary prism. Seismic reflection amplitudes suggest that the fossil conduit still acts as a preferential fluid seepage pathway, contributing to destabilization of the overlying slope sediments.
位于地中海的狭窄的卡拉布里亚弧(Calabrian Arc)是众所周知的泥火山聚集地,尽管只有少数泥火山被广泛记录在案。克罗托内海附近的爱奥尼亚海就是一个例子,在那里流体排出和沉积物动员的表现在地下和海底都是可见的。通过对专有的三维地震数据立方体的分析,可以表征凹坑模式并识别泥底辟,泥底辟在海底表现为一个直径约1200米的大型泥池。高分辨率三维地震剖面可以推断出海底极浅深度流体聚焦机制的差异。浅层松散沉积层受斜坡坡度急剧增大的影响,由外弧伸展和扩张引起的正断层有助于流体聚焦和麻坑的形成。在某些情况下,可以证明流体喷发也有助于破坏最上层沉积地层的稳定,引发沿坡的小型滑坡。泥底辟显然是沿着一条伸展断裂被动员起来的,这条断裂进入了一个活动的页岩域。研究区还发现了古泥塘。这个化石泥池被未变形的沉积地层所封闭,这限制了在增生棱镜中流体和沉积物动员的最小年龄。地震反射振幅表明,化石管道仍然是一个优先的流体渗流通道,有助于上覆斜坡沉积物的失稳。
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引用次数: 0
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Marine and Petroleum Geology
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