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Geological characteristics and in-situ retention mechanisms of clay-rich lacustrine shale oil in the Songliao Basin 松辽盆地富泥湖相页岩油地质特征及原位储集机制
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-30 DOI: 10.1016/j.marpetgeo.2025.107593
Min Wang , Yan Wu , Xuefeng Bai , Ming Li , Junhui Li , Xin Wang , Jinyou Zhang , Jinbu Li , Changqi Yu , Roufeida Bennani
The Cretaceous Qingshankou Formation in the Gulong Sag of the Songliao Basin, located in the eastern of the Eurasian Plate, exhibits unique shale oil properties, including high clay mineral content (>40 %), high organic matter maturity (>1.0 %), and low shale oil density (∼0.78 cm3/g). This represents the first globally documented shale oil produced from clay-rich shales. This study systematically investigates the characteristics and controlling factors of reservoir space, oil-bearing properties and the formation and enrichment processes of shale oil. Findings reveal that the Qing-1 Member predominantly comprises laminated argillaceous shale, bedded mixed shale, and massive calcareous shale. The kerogen is mainly Type I, characterized by well-developed lamalginite and high organic matter (OM) abundance, with an average Total Organic Carbon (TOC) of 2.27 %. Thermal maturity (Ro) in oil-producing intervals typically exceeds 1.0 %. The main pore types are intergranular pores, intragranular pores, OM-hosted pores, exposed pores after OM degradation, and microfractures, with pore development influenced by TOC, clay mineral content, and Ro. The Gulong shale is notably oil-rich, with oil films present observed in different types and sizes of pores, and oil content significantly affected by TOC and Ro. The coupling of hydrocarbon evolution, fault activity periods, and regional stress changes governs the in-situ retention of light oil within the sag and dictates the reservoir formation sequence and spatial distribution of tight and conventional oil outside the source rock. This study offers critical insights for the exploration and development of continental clay-rich shale oil reservoirs.
松辽盆地古龙凹陷白垩系青山口组位于欧亚板块东部,具有粘土矿物含量高(约40%)、有机质成熟度高(约1.0%)、页岩油密度低(约0.78 cm3/g)的独特页岩油性质。这是全球首次有记录的从富含粘土的页岩中开采出的页岩油。系统研究了页岩油的储集空间、含油性质、形成富集过程等特征及控制因素。结果表明,青一段主要由层状泥质页岩、层状混合页岩和块状钙质页岩组成。干酪根以I型为主,以板藻褐铁矿发育、有机质丰度高为特征,平均总有机碳(TOC)为2.27%。产油层段的热成熟度(Ro)一般超过1.0%。孔隙类型主要为粒间孔、粒内孔、OM寄存孔、OM降解后暴露孔和微裂缝,孔隙发育受TOC、粘土矿物含量和Ro的影响。古龙页岩富油明显,不同类型和大小的孔隙均存在油膜,含油量受TOC和Ro的影响显著。油气演化、断裂活动期和区域应力变化的耦合作用决定了凹陷内轻质油的原位储集,并决定了烃源岩外致密油和常规油的成藏顺序和空间分布。该研究对陆相富泥页岩油藏的勘探开发具有重要意义。
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引用次数: 0
Mechanisms for initiation and termination of extraordinarily high total organic carbon in the Longmaxi Formation, Yangtze Platform, South China 扬子地台龙马溪组高总有机碳起终止机制
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-30 DOI: 10.1016/j.marpetgeo.2025.107588
Zongyuan Sun , Hao Chen , Xianguo Lang , Bolin Zhang , Qing Chen , Kun Zhao , Shengxian Zhu , Fangqi Zhao , Feng Liang , Chuyuan Liu , Junxuan Fan
The Early Silurian Longmaxi Formation in the Yangtze Platform of South China hosts exceptional shale gas reservoirs, particularly in intervals where total organic carbon (TOC) exceeds 3 wt%. However, the initial TOC values and termination timing of these “extraordinarily high TOC” intervals differ markedly among localities, especially between inner- and outer-shelf settings. In this study, we integrate graptolite biostratigraphy, carbon isotope chemostratigraphy, and multiple geochemical proxies (e.g., major–trace elements and sulfur isotopes) from drill cores in Yichang, Hubei Province, South China (outer shelf). We establish a refined chronostratigraphic framework, identifying an extraordinarily high TOC interval (>3 wt%) and a subsequent high TOC interval (2–3 wt%), and then compare these intervals with representative inner-shelf sections. Our results show that at the base of the Longmaxi Formation in Yichang, TOC values are notably lower than those in the inner-shelf Changning area, Sichuan Province, South China, whereas the extraordinarily high TOC interval extends to a higher stratigraphic level in Yichang. Paleoenvironmental proxies indicate that extraordinarily high TOC intervals formed in a euxinic setting with higher primary productivity, and moderate restriction, whereas the high TOC interval reflects an anoxic setting, lower productivity, and stronger restriction. By determining sedimentation rates, sulfur isotope values, paleogeographic setting, and the influence of the Kwangsian Orogeny, we propose two sedimentary models to explain TOC variability in the Longmaxi Formation. The Sedimentation Rate–H2S Concentration Model highlights how rapid sedimentation and abundant availability of 34S-enriched H2S promote extraordinarily TOC enrichment in inner-shelf settings, while slower burial and limited H2S availability inhibit TOC accumulation in outer-shelf locations. The Kwangsian Orogeny–Hydrographic Restriction Model associates tectonic uplift with enhanced hydrographic restriction, reducing sulfate supply and driving the diachronous termination of high TOC intervals across the platform. These insights refine our understanding of early Silurian black-shale deposition and offer practical guidance for future shale-gas exploration in South China.
华南扬子地台早志留统龙马溪组具有特殊的页岩气储层,特别是在总有机碳(TOC)超过3 wt%的层段。然而,这些“异常高TOC”区间的初始TOC值和终止时间在不同地点之间存在显著差异,特别是在内部和外部大陆架环境之间。本研究综合了湖北宜昌(外陆架)钻孔岩心的笔石生物地层学、碳同位素化学地层学和多种地球化学指标(如主要微量元素和硫同位素)。我们建立了一个精细的年代地层格架,确定了一个非常高的TOC层段(>3 wt%)和随后的高TOC层段(2-3 wt%),然后将这些层段与代表性的陆架内剖面进行比较。结果表明,宜昌龙马溪组基底TOC值明显低于四川长宁内陆架地区,而异常高TOC区间在宜昌延伸至更高的地层水平。古环境指标表明,高TOC层段形成于富氧环境,初级生产力高,限制适度;而高TOC层段形成于缺氧环境,初级生产力低,限制较强。通过测定沉积速率、硫同位素值、古地理环境和光西安造山运动的影响,提出了两种沉积模式来解释龙马溪组TOC的变化。沉积速率- H2S浓度模型强调了快速沉积和丰富的富含34s的H2S如何促进大陆架内部环境中TOC的富集,而较慢的埋藏和有限的H2S可用性抑制了大陆架外部位置TOC的积累。光县造山—水文约束模型将构造隆升与增强的水文约束联系在一起,减少了硫酸盐供应,推动了整个平台高TOC层段的历时性终止。这些发现完善了我们对早志留世黑页岩沉积的认识,为今后华南地区页岩气勘探提供了实践指导。
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引用次数: 0
Geochemical insights into authigenic pyrite formation in central Yellow Sea sediments: influence of sedimentary environment and microbial sulfate reduction 黄海中部沉积物自生黄铁矿形成的地球化学研究:沉积环境和微生物硫酸盐还原的影响
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-29 DOI: 10.1016/j.marpetgeo.2025.107587
Yu Gu , Xin Chang , Xiting Liu , Mingyu Zhang , Yanfei An , Guangchao Zhuang , Houjie Wang
Authigenic pyrite is a key archive of paleo-redox conditions and sulfur cycling in marine sediments, yet its formation mechanisms under variable marginal sea environments remain incompletely understood. This study investigates the formation of authigenic pyrite in Holocene sediments from the central Yellow Sea, focusing on its morphology, sulfur isotopes, and environmental controls. Pyrite formation is primarily constrained by the availability of reactive organic carbon, as revealed by total organic carbon–total sulfur relationships (C/S ratios) and reactive iron content. High C/S ratios suggest that the supply of organic matter, rather than the availability of sulfate or iron, plays the dominant role. Framboidal pyrite is the most common morphology. These framboids consist of tightly packed microcrystals, primarily octahedral and truncated octahedral in shape, indicating rapid precipitation under early diagenetic, low-oxygen, and low-energy conditions. The sulfur isotopes of pyrite (δ34Spyr, Vienna Canyon Diablo Troilite; V-CDT) range from −47.4 ‰ to −7.8 ‰, reflecting large fractionations associated with microbial sulfate reduction (MSR). The vertical δ34Spyr profile shows transitions from open- to closed-system MSR regimes, modulated by changes in sedimentation rate, freshwater input, and stratification linked to the Yellow Sea Cold Water Mass. These findings reveal the interplay between sedimentary environment, pyrite morphology, and sulfur isotope composition, offering insights into sulfur cycling in modern marginal marine settings and ancient analogues.
自生黄铁矿是海洋沉积物中古氧化还原条件和硫循环的重要资料,但其在多变边缘海环境下的形成机制尚不完全清楚。本文研究了黄海中部全新世沉积物中自生黄铁矿的形成,重点研究了其形态、硫同位素和环境控制。总有机碳-总硫关系(C/S比)和活性铁含量表明,黄铁矿的形成主要受活性有机碳可用性的制约。高碳硫比表明有机质的供应,而不是硫酸盐或铁的可用性,起主导作用。草莓状黄铁矿是最常见的形态。这些树状体由紧密排列的微晶体组成,形状主要为八面体和截尾八面体,表明在早期成岩、低氧和低能条件下快速沉淀。黄铁矿(δ34Spyr, Vienna Canyon Diablo Troilite; V-CDT)的硫同位素变化范围为- 47.4‰~ - 7.8‰,反映了与微生物硫酸盐还原(MSR)有关的大分馏。垂直δ34Spyr剖面显示了从开放系统到封闭系统的MSR状态的转变,受沉积速率、淡水输入和与黄海冷水团相关的分层变化的调节。这些发现揭示了沉积环境、黄铁矿形态和硫同位素组成之间的相互作用,为现代边缘海洋环境和古代类似环境中的硫循环提供了见解。
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引用次数: 0
Diagenesis and burial history controls on Oligocene Huagang sandstones, southern Xihu Sag (East China Sea Basin): Implications for the formation of effective reservoirs 东海盆地西湖凹陷南部渐新统花岗砂岩成岩作用及埋藏史控制:对有效储层形成的启示
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-29 DOI: 10.1016/j.marpetgeo.2025.107592
Hong-Liang Huo , Cheng-Lin Liu , Dao-Wu Huang , An-Qi Tian , Rizwan Sarwar Awan , Hong-Yan Gao , Chuang-Xin Liu , Xue-Yong Chen , Zi-Ye Tian , Tao-Zheng Yang , Bin-Bin Liu , Chao-Jun Liang
This study aims to reveal the diagenetic evolution sequence and controlling factors of Oligocene Huagang Formation (E3h) sandstone reservoirs in the HY area, and predict high-quality reservoir distribution to guide hydrocarbon exploration. A comprehensive approach integrating core observation, thin-section petrography, geochemical analysis, and seismic-log interpretation was employed. By combining burial history simulation and diagenetic analysis, we systematically analyzed reservoir quality and diagenetic evolution and established evolution models for effective reservoir pore spaces. Results indicate that E3h sandstones underwent intense diagenetic processes including compaction, cementation, and dissolution. Diagenesis plays a critical role in controlling reservoir quality: compaction is the primary factor that governs vertical variations in petrophysical properties, where shallower intervals typically exhibit better quality than deeper ones. In contrast, cementation and dissolution serve as secondary controls, explaining property differences between Blocks A and B, with Block A reservoirs being superior. A three-stage relationship has been identified between burial history and diagenesis: (1) early gradual subsidence stage (GSS) with weak feldspar dissolution, early carbonate cementation, chlorite coating, and mechanical compaction; (2) intermediate tectonic activity stage (TAS) with massive feldspar dissolution, quartz overgrowth precipitation, and ferruginous cement formation; (3) late stable burial stage (SBS) featuring intensified compaction and clay mineral transformations. The spatial configuration of fault systems and sandstones, combined with compositional attributes, strongly controls diagenetic evolution. Favorable zones for dissolution development occur at intersections of fault zones and acidic fluid migration pathways, while quartz-feldspar-rich zones mitigate porosity loss via compaction resistance. Three effective reservoir development models were proposed: high dissolution-low cementation-low compaction, moderate dissolution-low cementation-low compaction, and low compaction-low cementation-low dissolution. This research provides a critical basis for predicting E3h high-quality reservoirs in the study area. Furthermore, the comprehensive burial history-diagenesis analysis method presented here offers a valuable reference for studies on sandstone diagenetic evolution and hydrocarbon exploration in similar geological settings.
旨在揭示HY地区渐新统华岗组砂岩储层成岩演化序列及控制因素,预测优质储层分布,指导油气勘探。采用岩心观测、薄片岩石学、地球化学分析和地震测井解释相结合的综合方法。通过埋藏史模拟与成岩分析相结合,系统分析储层物性和成岩演化,建立有效储层孔隙空间演化模型。结果表明,E3h砂岩经历了压实、胶结和溶蚀等强烈成岩作用。成岩作用在控制储层质量方面起着至关重要的作用:压实作用是决定岩石物性垂直变化的主要因素,其中较浅的层段通常比较深的层段表现出更好的质量。相比之下,胶结作用和溶蚀作用是次要控制因素,这解释了A区块和B区块的物性差异,A区块的储层更优越。埋藏史与成岩作用有三个阶段的关系:(1)早期逐渐沉降阶段(GSS):弱长石溶蚀、早期碳酸盐胶结、绿泥石包覆、机械压实;(2)以大量长石溶蚀、石英过度生长沉淀、含铁胶结物形成为特征的构造活动中期;(3)以压实和粘土矿物转化强化为特征的晚期稳定埋藏阶段(SBS)。断裂系统和砂岩的空间构型及其组成属性对成岩演化具有重要的控制作用。在断裂带和酸性流体运移路径的交叉处出现有利于溶蚀发育的带,而石英-长石富集带通过抗压实作用减轻孔隙度损失。提出了高溶蚀-低胶结-低压实、中等溶蚀-低胶结-低压实、低压实-低胶结-低溶蚀3种有效的油藏开发模式。该研究为研究区E3h优质储层预测提供了重要依据。此外,本文提出的埋藏史-成岩作用综合分析方法,为类似地质环境下砂岩成岩演化研究和油气勘探提供了有价值的参考。
{"title":"Diagenesis and burial history controls on Oligocene Huagang sandstones, southern Xihu Sag (East China Sea Basin): Implications for the formation of effective reservoirs","authors":"Hong-Liang Huo ,&nbsp;Cheng-Lin Liu ,&nbsp;Dao-Wu Huang ,&nbsp;An-Qi Tian ,&nbsp;Rizwan Sarwar Awan ,&nbsp;Hong-Yan Gao ,&nbsp;Chuang-Xin Liu ,&nbsp;Xue-Yong Chen ,&nbsp;Zi-Ye Tian ,&nbsp;Tao-Zheng Yang ,&nbsp;Bin-Bin Liu ,&nbsp;Chao-Jun Liang","doi":"10.1016/j.marpetgeo.2025.107592","DOIUrl":"10.1016/j.marpetgeo.2025.107592","url":null,"abstract":"<div><div>This study aims to reveal the diagenetic evolution sequence and controlling factors of Oligocene Huagang Formation (E<sub>3</sub>h) sandstone reservoirs in the HY area, and predict high-quality reservoir distribution to guide hydrocarbon exploration. A comprehensive approach integrating core observation, thin-section petrography, geochemical analysis, and seismic-log interpretation was employed. By combining burial history simulation and diagenetic analysis, we systematically analyzed reservoir quality and diagenetic evolution and established evolution models for effective reservoir pore spaces. Results indicate that E<sub>3</sub>h sandstones underwent intense diagenetic processes including compaction, cementation, and dissolution. Diagenesis plays a critical role in controlling reservoir quality: compaction is the primary factor that governs vertical variations in petrophysical properties, where shallower intervals typically exhibit better quality than deeper ones. In contrast, cementation and dissolution serve as secondary controls, explaining property differences between Blocks A and B, with Block A reservoirs being superior. A three-stage relationship has been identified between burial history and diagenesis: (1) early gradual subsidence stage (GSS) with weak feldspar dissolution, early carbonate cementation, chlorite coating, and mechanical compaction; (2) intermediate tectonic activity stage (TAS) with massive feldspar dissolution, quartz overgrowth precipitation, and ferruginous cement formation; (3) late stable burial stage (SBS) featuring intensified compaction and clay mineral transformations. The spatial configuration of fault systems and sandstones, combined with compositional attributes, strongly controls diagenetic evolution. Favorable zones for dissolution development occur at intersections of fault zones and acidic fluid migration pathways, while quartz-feldspar-rich zones mitigate porosity loss via compaction resistance. Three effective reservoir development models were proposed: high dissolution-low cementation-low compaction, moderate dissolution-low cementation-low compaction, and low compaction-low cementation-low dissolution. This research provides a critical basis for predicting E<sub>3</sub>h high-quality reservoirs in the study area. Furthermore, the comprehensive burial history-diagenesis analysis method presented here offers a valuable reference for studies on sandstone diagenetic evolution and hydrocarbon exploration in similar geological settings.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"182 ","pages":"Article 107592"},"PeriodicalIF":3.6,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145044394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Depositional conditions affecting proximal to distal variation in the crystallo-chemical properties of Paleogene glauconites: Example from the Mesopotamian basin, Iraq 沉积条件影响古近系海绿石晶体化学性质近端到远端变化:以伊拉克美索不达米亚盆地为例
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-29 DOI: 10.1016/j.marpetgeo.2025.107591
Tarang Sarin , Santanu Banerjee , Ibrahim Q. Mohammed , Nibras Zaki , Sherif Farouk , Howri Mansurbeg , Pragya Singh
The proximal to distal variation in glauconite composition across a basin, although rarely attempted, may provide crucial insights into the depositional conditions. The Paleogene glauconites from the transgressive and condensed deposits are tracked from the proximal to the distal parts of the Mesopotamian basin in Iraq, to delineate their compositional variation. They prevail within the Paleocene Upper Aaliji Formation and the Eocene basal Jaddala Formation. The Fe2O3(total) (av. 16.78 wt%) and K2O (av. 7.04 wt%) contents, and the ordering of the crystal structure and maturity (decreasing d-spacing and FWHM of 001 basal reflection) of glauconites increase, while the Al2O3 (av. 9.82 wt%) and MgO (av. 5.24 wt%) contents decrease from the proximal to distal settings. Therefore, the Al-rich and less mature glauconite is attributed to the proximal setting, whereas Fe-rich and more mature glauconites are attributed to the central and distal settings. The proximal setting is enriched with detrital Al-rich clay minerals forming less mature, Al-rich glauconites in kaolinite and illite-smectite precursors within the prevailing gently suboxic conditions. Whereas the central and distal settings sustain a lower sedimentation rate and enhanced mobility of ferrous ions, forming more mature, Fe-rich glauconites within the prevailing oxygen-depleted conditions. Glauconites form within two warming intervals from Late Danian to Late Ypresian and Late Lutetian to Late Bartonian. Warm climatic conditions amplify elemental supply, promote transgressive conditions, intensify reaction kinetics, and produce redox conditions encouraging abundant growth of glauconite. The composition and abundance of glauconites corroborate their formation within warm climatic conditions.
海绿石组成的近端到远端变化虽然很少尝试,但可能为沉积条件提供重要的见解。从伊拉克美索不达米亚盆地近端到远端对海侵和缩合沉积中的古近系海绿石进行了追踪,描绘了其组成变化。它们主要分布在古新世上阿利吉组和始新世基底贾达拉组。海绿石的Fe2O3(总含量)(16.78 wt%)和K2O (7.04 wt%)含量、晶体结构的有序性和成熟度(d -间距减小和001基反射的FWHM)增加,Al2O3 (9.82 wt%)和MgO (5.24 wt%)含量从近端到远端递减。因此,富al和不成熟的海绿石属于近端环境,而富fe和更成熟的海绿石属于中心和远端环境。近端环境富含碎屑富铝粘土矿物,形成不太成熟的高岭石和伊利石-蒙脱石前体中的富铝海绿石,处于普遍的轻度缺氧条件下。而中部和远端环境则维持较低的沉积速率和亚铁离子的增强流动性,在普遍的缺氧条件下形成更成熟、富铁的海绿石。海绿石形成于晚丹尼世至晚伊波斯世和晚鲁特世至晚巴尔顿世两个变暖间隔。温暖的气候条件增加了元素供应,促进了海侵条件,强化了反应动力学,并产生了促进海绿石丰富生长的氧化还原条件。海绿石的组成和丰度证实了它们是在温暖的气候条件下形成的。
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引用次数: 0
Origin and controls on shale oil enrichment of bedding-parallel fractures in the Chang 73 lacustrine shales, Yanchang Formation, Ordos Basin 鄂尔多斯盆地延长组长73湖相页岩层状平行裂缝成因及页岩油富集控制
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-27 DOI: 10.1016/j.marpetgeo.2025.107590
Zilong Li , Kelai Xi , Yingchang Cao , Yifan Zhang , Xiaobing Niu , Xiujuan Wang , Wenzhong Ma , Yuan You , Yuxuan Wang , Guanghui Yuan
As the main fracture type of lacustrine shales, bedding-parallel fractures (BPFs) play a key controlling role in diagenetic mass transfer as well as hydrocarbon migration and accumulation. To reveal the origin of BPFs and their controls on shale oil enrichment, this study integrates core, thin section, scanning electron microscopy (SEM) observations, and fluid inclusion analysis, focusing on the BPFs of the lacustrine shales of the Chang 73 sub-member, Yanchang Formation, Ordos Basin. The results show that the variations in mineral composition, arrangement, and size on both sides of the laminae interface induce significant mechanical anisotropy, which become the essential geological prerequisite for the generation and extension of BPFs along the laminae interface. Furthermore, influenced by the mineral planar fabrics, BPFs can also develop within the laminae. Compared with laminated shale, massive mudstone does not show significant BPFs development characteristics due to the lack of lamina fabric. As a consequence of disequilibrium compaction, the vertical seepage force gradient caused by hydrocarbon generation overpressure periodically breaks through the pressure threshold of the closed shale system, resulting in the episodic opening of weak interfaces, thereby constituting the major formation mechanism of BPFs. In addition, the tectonic compression effect near the basin margin can also promote the development of BPFs to a certain extent. In different lithofacies of shales, the differences in the development characteristics and degree of BPFs are mainly caused by the variations in laminae attributes including laminae combination, linear density, and average thickness. High total organic carbon (TOC) content is conducive to increasing hydrocarbon generation overpressure. However, excessive TOC content reduces the compressive strength of rocks and has an adverse effect on the development of BPFs. The analysis of shale oil production indicates that, compared with non-bedding-parallel fractures (NBPFs), BPFs play a dominant role in the enrichment of shale oil and can significantly increase the daily oil production of individual wells. These findings provide a theoretical basis for revealing the origin, development pattern of BPFs and their influence on fluid activity in lacustrine shales.
层理平行裂缝作为湖相页岩的主要裂缝类型,在成岩传质和油气运聚过程中起着关键的控制作用。为揭示bp成因及其对页岩油富集的控制作用,结合岩心、薄片、扫描电镜(SEM)观察和流体包裹体分析,以鄂尔多斯盆地延长组长73亚段湖相页岩bp为研究对象。结果表明:层状界面两侧矿物组成、排列和大小的变化引起了显著的力学各向异性,这成为沿层状界面形成和扩展的重要地质前提;此外,受矿物平面组构的影响,纹层内也可发育bp。与层状页岩相比,块状泥岩由于缺乏层状组构,没有表现出明显的bp发育特征。由于不平衡压实作用,生烃超压引起的垂向渗流力梯度周期性突破封闭页岩系统压力阈值,导致弱界面幕式打开,构成了bp的主要形成机制。此外,靠近盆地边缘的构造挤压作用也在一定程度上促进了bp的发育。在不同的页岩岩相中,纹层发育特征和程度的差异主要是由纹层组合、线密度和平均厚度等纹层属性的差异造成的。总有机碳(TOC)含量高有利于提高生烃超压。然而,过量的TOC含量降低了岩石的抗压强度,对bpf的发育有不利影响。页岩油产量分析表明,与非层理平行裂缝相比,层理平行裂缝对页岩油的富集起主导作用,可显著提高单井日产量。这些发现为揭示湖相页岩bp的成因、发育模式及其对流体活动的影响提供了理论依据。
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引用次数: 0
New data on the identification of magnesium-rich carbonate phases using Fourier Transform Infrared Spectroscopy 傅里叶变换红外光谱法鉴别富镁碳酸盐相的新资料
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-22 DOI: 10.1016/j.marpetgeo.2025.107585
Katarzyna Stanienda-Pilecki , Dariusz Łukowiec
This paper presents the theory behind the importance and applicability of Fourier infrared spectroscopy in identifying carbonate phases with varying magnesium content. It presents the results of studies of Triassic limestone and dolomite samples taken from the Polish part of the Germanic Basin, which were analysed using this method. The scientific significance of the FTIR method lies in its ability to identify carbonate phases with varying magnesium content, even at low levels. FTIR is one of the few methods that offer such possibilities.
The following phases were analysed: low-Mg calcite, high-Mg calcite, dolomite and huntite. These carbonate phases were identified based on wave numbers occurring in the infrared absorption spectra. Low-Mg calcite is the dominant phase in the limestones. Some samples also contain a small amount of high-Mg calcite. Dolomite and huntite were also identified. High-Mg calcite and dolomite are prevalent in dolomites and dolomitic limestones. The research results indicate that the rocks of the Gogolin Unit (Lower Muschelkalk) and Diplopor Unit (Middle Muschelkalk) exhibit the least differentiation in carbonate phase content with varying magnesium contents, whereas the rocks of the Tarnowice and Boruszowice Units (Upper Muschelkalk) exhibit the most. The results suggest that the rocks of the Lower Muschelkalk (Gogolin Unit) and Middle Muschelkalk (Diplopor Unit) are quartz- and kaolinite-rich limestones. In contrast, the rocks of the Upper Muschelkalk (Tarnowice and Boruszowice units) are dolomites and dolomitic limestones. The results of the study demonstrate that Fourier infrared spectroscopy is one of the most effective methods for identifying carbonate phases with varying magnesium content, including those with magnesium substitution, due to its ease of use and high level of accuracy.
本文介绍了傅里叶红外光谱在鉴别不同镁含量碳酸盐相中的重要性和适用性。本文介绍了对日耳曼盆地波兰部分三叠纪石灰岩和白云岩样品的研究结果,这些样品是用这种方法分析的。FTIR方法的科学意义在于它能够识别不同镁含量的碳酸盐相,即使镁含量很低。FTIR是为数不多的提供这种可能性的方法之一。分析了低镁方解石、高镁方解石、白云石和猎石等物相。这些碳酸盐相是根据红外吸收光谱中的波数来确定的。灰岩中以低镁方解石为主。一些样品还含有少量的高镁方解石。白云石和狩猎石也被发现。白云岩和白云质灰岩中普遍存在高镁方解石和白云石。研究结果表明,Gogolin单元(下Muschelkalk)和Diplopor单元(中Muschelkalk)的岩石碳酸盐相含量差异最小,镁含量变化较大,而Tarnowice和Boruszowice单元(上Muschelkalk)的岩石碳酸盐相含量差异最大。结果表明,下Muschelkalk (Gogolin单元)和中Muschelkalk (Diplopor单元)的岩石为富含石英和高岭石的灰岩。相比之下,上Muschelkalk (Tarnowice和Boruszowice单元)的岩石为白云岩和白云质灰岩。研究结果表明,傅里叶红外光谱由于其易于使用和精度高,是识别含镁含量变化的碳酸盐相(包括含镁取代的碳酸盐相)最有效的方法之一。
{"title":"New data on the identification of magnesium-rich carbonate phases using Fourier Transform Infrared Spectroscopy","authors":"Katarzyna Stanienda-Pilecki ,&nbsp;Dariusz Łukowiec","doi":"10.1016/j.marpetgeo.2025.107585","DOIUrl":"10.1016/j.marpetgeo.2025.107585","url":null,"abstract":"<div><div>This paper presents the theory behind the importance and applicability of Fourier infrared spectroscopy in identifying carbonate phases with varying magnesium content. It presents the results of studies of Triassic limestone and dolomite samples taken from the Polish part of the Germanic Basin, which were analysed using this method. The scientific significance of the FTIR method lies in its ability to identify carbonate phases with varying magnesium content, even at low levels. FTIR is one of the few methods that offer such possibilities.</div><div>The following phases were analysed: low-Mg calcite, high-Mg calcite, dolomite and huntite. These carbonate phases were identified based on wave numbers occurring in the infrared absorption spectra. Low-Mg calcite is the dominant phase in the limestones. Some samples also contain a small amount of high-Mg calcite. Dolomite and huntite were also identified. High-Mg calcite and dolomite are prevalent in dolomites and dolomitic limestones. The research results indicate that the rocks of the Gogolin Unit (Lower Muschelkalk) and Diplopor Unit (Middle Muschelkalk) exhibit the least differentiation in carbonate phase content with varying magnesium contents, whereas the rocks of the Tarnowice and Boruszowice Units (Upper Muschelkalk) exhibit the most. The results suggest that the rocks of the Lower Muschelkalk (Gogolin Unit) and Middle Muschelkalk (Diplopor Unit) are quartz- and kaolinite-rich limestones. In contrast, the rocks of the Upper Muschelkalk (Tarnowice and Boruszowice units) are dolomites and dolomitic limestones. The results of the study demonstrate that Fourier infrared spectroscopy is one of the most effective methods for identifying carbonate phases with varying magnesium content, including those with magnesium substitution, due to its ease of use and high level of accuracy.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"182 ","pages":"Article 107585"},"PeriodicalIF":3.6,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144893284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D reconstruction of pore throat connectivity in Shale: An SAXS-MICP integrated framework 页岩孔喉连通性三维重建:SAXS-MICP集成框架
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-21 DOI: 10.1016/j.marpetgeo.2025.107584
Linhao Zhang , Shu Jiang , Jiale Fu , Fei Xie , Zhile Han , Zihao Li , Mengdi Sun
Digital rock technology enables simulation of reservoir dynamic response under coupled multi-physical fields, providing scientific basis for optimization of development schemes through virtual experiments. However, traditional CT technology shows significant limitations in processing low-porosity samples (<5 %), with insufficient ability to accurately identify nano-scale throats, resulting in unrealistic isolated pore networks in reconstruction. Meanwhile, challenges remain in balancing resolution and field of view, as well as experimental cost and efficiency. To address these issues, this study innovatively introduces Small-Angle X-ray Scattering technology, leveraging its advantages of wide testing range, excellent sample representativeness, and ability to characterize closed pores. The research employs fast Gaussian random field method for 3D reconstruction, combines Delaunay triangulation and minimum spanning tree algorithms for network structure optimization, and integrates throat parameters obtained from mercury intrusion capillary pressure data. Finally, a low-porosity porous media model with realistic connectivity characteristics was successfully constructed, laying a solid foundation for detailed reservoir characterization and fluid transport mechanism research.
数字岩石技术能够模拟多物理场耦合作用下油藏的动态响应,通过虚拟实验为优化开发方案提供科学依据。然而,传统CT技术在处理低孔隙度样品(< 5%)时存在明显的局限性,无法准确识别纳米级喉道,导致重建时孤立的孔隙网络不切实际。同时,在分辨率和视场平衡、实验成本和效率等方面仍存在挑战。为了解决这些问题,本研究创新性地引入了小角度x射线散射技术,利用其测试范围广、样品代表性好、能够表征封闭孔隙等优势。研究采用快速高斯随机场法进行三维重建,结合Delaunay三角剖分和最小生成树算法进行网络结构优化,并整合汞侵入毛细管压力数据获取的喉道参数。最终,成功构建了具有真实连通性特征的低孔隙度多孔介质模型,为油藏详细表征和流体输运机理研究奠定了坚实基础。
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引用次数: 0
Reservoir space types, controlling factors, and evolution models of interbedded shale in the Jurassic Lianggaoshan Formation, Sichuan Basin 四川盆地侏罗系梁高山组层间页岩储层空间类型、控制因素及演化模式
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-14 DOI: 10.1016/j.marpetgeo.2025.107583
Yan Wu , Min Wang , Xuefeng Bai , Xin Wang , Yu Sun , Youzhi Wang , Xinyi Yang , Liang Xu , Tianyi Li
The type, structure, and origin of shale pores, which serve as both storage spaces for hydrocarbon accumulation and percolation pathways, fundamentally determine reservoir quality and further influence sweet spot identification and production performance in shale oil reservoirs. The heterogeneous interlayers such as siltstone and silty mudstone developed in continental shale have greatly altered the pore structure, fluid storage state and percolation capacity of the reservoir, resulting in significant differences in its reservoir properties compared with shale. This study investigates lacustrine interbedded shale reservoirs through a comprehensive approach incorporating X-ray diffraction (XRD), thin-section petrography, field emission scanning electron microscopy (FE-SEM), low temperature nitrogen adsorption, and nuclear magnetic resonance (NMR) techniques. The results demonstrate that the reservoir properties of different shale lithofacies are generally better than those of fine siltstone lithofacies, especially the organic-rich laminated argillaceous shale (O-rLAS) lithofacies, which has the best reservoir properties. Organic matter (OM) - related pores (particularly organo-clay composite pores) and the interlayer fractures/intercrystalline pores of clay mineral constitute the primary contributors to the reservoir space. Thermal cracking of organic matter and clay mineral transformation enhance the storage capacity of shale lithofacies, whereas cementation is identified as the main factor responsible for the poor reservoir quality of fine siltstone lithofacies. The development of OM-related pores is jointly controlled by thermal maturity, total organic carbon (TOC), and OM type, as well as clay mineral content. The occurrence state of clay minerals with OM and clay mineral type predominantly influence the development of clay mineral interlayer pores. Dissolution pores are mainly affected by TOC and felsic mineral content, while felsic mineral content significantly impacts the development of intergranular pores and microfractures. This study enriches the theoretical understanding of diagenetic and reservoir-forming mechanisms in continental shale reservoirs. It provides critical geological basis and theoretical support for accurately identifying and evaluating the high-quality "sweet spots" of continental interbedded shale oil. These findings offer practical guidance for efficient exploration and development of such complex reservoirs.
页岩孔隙既是油气聚集的储集空间,又是渗流的通道,其类型、结构和成因从根本上决定了储层质量,进而影响页岩油藏甜点识别和生产动态。陆相页岩中发育的粉砂岩、粉砂质泥岩等非均质夹层,极大地改变了储层的孔隙结构、储液状态和渗流能力,使其储层物性与页岩储层存在显著差异。本研究通过综合x射线衍射(XRD)、薄片岩石学、场发射扫描电镜(FE-SEM)、低温氮吸附和核磁共振(NMR)技术对湖相互层页岩储层进行了研究。结果表明,不同页岩岩相储层物性总体优于细粉砂岩岩相,尤其是富有机质层状泥质页岩(O-rLAS)岩相储层物性最好。有机质相关孔隙(特别是有机-粘土复合孔隙)和粘土矿物层间裂缝/晶间孔隙构成储集空间的主要贡献者。有机质热裂解和粘土矿物转化增强了页岩岩相储层能力,而胶结作用是细粉砂岩岩相储层质量差的主要原因。有机质相关孔隙的发育受热成熟度、总有机碳(TOC)、有机质类型及粘土矿物含量的共同控制。含有机质粘土矿物的赋存状态和粘土矿物类型对粘土矿物层间孔隙的发育影响较大。溶蚀孔隙主要受TOC和长英质矿物含量的影响,而长英质矿物含量对粒间孔隙和微裂缝的发育有显著影响。该研究丰富了陆相页岩储层成岩成藏机理的理论认识。为准确识别和评价陆相互层页岩油优质“甜点”提供了重要的地质依据和理论支持。这些发现对此类复杂储层的高效勘探开发具有实际指导意义。
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引用次数: 0
Cenozoic sedimentary records from the eastern offshore of China reveal the Eocene birth of the Yangtze River 中国东部近海新生代沉积记录揭示了始新世长江的诞生
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-08-12 DOI: 10.1016/j.marpetgeo.2025.107558
Qian Zhao , Hongtao Zhu , Tandis S. Bidgoli , Yiming Jiang , Yinshan Chang , Qianghu Liu , Wei Wang
The Yangtze River, which links the Tibetan Plateau to the eastern offshore of China, is one of the most important sediment routing systems in East Asia. However, the timing of its establishment has remained controversial. This study examines new and published zircon U-Pb geochronology data from eastern offshore basins (the East China Sea Shelf Basin and South Yellow Sea Basin) and major rivers in East Asia, establishing new constraints on the timing of full integration of the Yangtze River. We report detrital zircon U-Pb ages (n = 664) from Paleogene strata in the East China Sea Shelf Basin, the primary sink for the river during the Cenozoic. Detrital zircons from the Eocene to early Oligocene Pinghu Formation range from 34.9 ± 0.7 to 2800 ± 42 Ma, with 100–250 Ma and 1700–2100 Ma age clusters, and small Paleozoic, Neoproterozoic, and Paleoproterozoic-Archean peaks. A similar age range (33 ± 0.4 to 2842 ± 43 Ma) and nearly identical peaks are documented for the Oligocene Huagang Formation. The maximum depositional age, based on the youngest single grains in our samples, is 34.9 ± 0.7 Ma for Pinghu Formation and 33 ± 0.4 Ma for Huagang Formation. Statistical comparison of the new U-Pb ages with published data from sands collected in major segments of the modern Yangtze River and its estuary demonstrate similar provenance, but with larger contributions of 700–1000 Ma and 1700–2100 Ma zircons, sourced from the Songpan-Garze terrane. Additionally, the new data suggest that both the East China Sea Shelf Basin and the South Yellow Sea Basin retain young (<80 Ma) zircons, likely sourced from the Jinshajiang segment of the Yangtze River. The youngest of these zircons are ∼37-33 Ma and only occur in sands from the upper reaches of the modern river. The high degree of similarity between the eastern offshore samples and the modern Yangtze system suggests the river and source-to-sink system were established by the late Eocene, and may point to topographic adjustments in the Qiangtang portion of the Tibetan Plateau as a driver of drainage expansion and integration.
长江连接着青藏高原和中国东部近海,是东亚最重要的泥沙输送系统之一。然而,其成立的时间仍然存在争议。本文分析了东部近海盆地(东海陆架盆地和南黄海盆地)和东亚主要河流的锆石U-Pb年代学新资料和已发表资料,建立了长江完全一体化时间的新约束条件。本文报道了东海陆架盆地古近系地层的碎屑锆石U-Pb年龄(n = 664)。始新世—早渐新世平湖组碎屑锆石年龄范围为34.9±0.7 ~ 2800±42 Ma,有100 ~ 250 Ma和1700 ~ 2100 Ma的年龄群,古生代、新元古代、古元古代—太古宙小峰。渐新统花岗组的年龄范围(33±0.4 ~ 2842±43 Ma)相似,峰也几乎相同。根据样品中最年轻的单粒沉积年龄,平湖组最大沉积年龄为34.9±0.7 Ma,华岗组最大沉积年龄为33±0.4 Ma。与已发表的现代长江及其河口主要河段砂体的U-Pb年龄进行统计比较,发现物源相似,但来自松潘-甘孜地体的700 ~ 1000 Ma和1700 ~ 2100 Ma锆石贡献较大。此外,新资料表明东海陆架盆地和南黄海盆地均保留年轻锆石(<80 Ma),可能来自长江金沙江段。这些锆石中最年轻的为~ 37 ~ 33 Ma,仅出现在现代河流上游的砂中。东部近海样品与现代长江水系的高度相似表明,河流和源-汇系统是在始新世晚期建立的,这可能表明青藏高原羌塘地区的地形调整是流域扩张和整合的驱动因素。
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引用次数: 0
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Marine and Petroleum Geology
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