Marine and Petroleum Geology最新文献

{"title":"Experimental tests and modeling of CO2 and H2S co-sequestration in saline aquifers","authors":"Krzysztof Labus","doi":"10.1016/j.marpetgeo.2024.107196","DOIUrl":"10.1016/j.marpetgeo.2024.107196","url":null,"abstract":"<div><div>A simulation study and a series of autoclave experiments were performed, reproducing gas-rock-water systems under reservoir conditions, after injection of CO₂ and the mixture of CO₂ with H₂S into rocks representing the Upper Silesian Coal Basin and the adjacent Małopolska Block (Central Europe). The water-rock-gas interactions were modeled in two stages: the first–aimed at simulating the short-term changes in system impacted by the gas injection, and the second–long-term effects of sequestration.</div><div>On the basis of the simulations, the reactions behind mineral transformations were identified. These phenomena are different for the injection of CO₂ alone. and CO₂+H₂S mixtures, resulting in the formation of secondary minerals responsible for mineral sequestration. Depending on the original mineral composition of the rock, in the case of pure CO₂, these are mainly carbonate minerals siderite, dawsonite, magnesite, dolomite and calcite, while in the case of mixture injection: elemental sulfur, sulfur sulfides–pyrite and pyrrhotite.</div><div>In experiments with the H₂S+CO₂ mixture, dissolution of skeletal grains was observed, which was most visible in the case of carbonates, feldspars, and chlorites. The analysis of rocks containing hematite revealed the formation of elemental sulfur surrounded by FeS₂ crystals, which had not been previously reported.</div><div>The experiments generally confirmed the interactions in gas-rock-water systems identified by numerical simulation. This allowed to estimate the amount of mineral phases precipitated or dissolved in the analyzed reactions, and consequently the impact on changes in porosity and the amount of sequestered carbon dioxide and sulfur.</div><div>In samples abundant in carbonate minerals (the Dębowiec Formation psephites), the decomposition of ankerite, due to the injection of CO₂+H₂S, is not compensated for by the precipitation of sufficient amounts of other carbonates, which leads to the desequestration process–CO₂ release.</div><div>Based on the calculations, it was found that the potentially most favorable conditions for the sequestration occur in the Paralic Series mudstones, rich in chlorites–a maximum of 22.36 kg CO₂/m³ and 12.50 kg S/m³, trapping capacity after 10,000 years of storage.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107196"},"PeriodicalIF":3.7,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"On the generation of light hydrocarbons from the closed pores of Jurassic strata, Sichuan Basin","authors":"Fei Liu ,&nbsp;Yuanjia Han ,&nbsp;Hanyong Bao ,&nbsp;Ming Fan ,&nbsp;Zhiguo Shu ,&nbsp;Tian Dong ,&nbsp;Zhiliang He","doi":"10.1016/j.marpetgeo.2024.107208","DOIUrl":"10.1016/j.marpetgeo.2024.107208","url":null,"abstract":"<div><div>Light hydrocarbons (C₁-C₉) offer a specific opportunity to study petroleum generation mechanisms. However, a significant amount of light hydrocarbons evaporate during sample collection, preservation, and preparation. This study aims to identify the origin of light hydrocarbons preserved in the closed pores of Jurassic shale strata from the Sichuan Basin where evaporative losses have been minimized. Twenty-one samples of various maturity levels and lithofacies were investigated using a new approach based on online decrepitation-gas chromatography. Light hydrocarbons were released from the closed pores of finely stratified mudstone, limestone, and siltstone. Among these, gaseous hydrocarbons in the C₁-C₅ range were utilized to discriminate between petroleum generated by two opposing reactions, i.e., free radical and carbenium ion cracking. Accordingly, <em>in situ</em> petroleum can be divided into three types. (1) Free radical cracking type: a predominance of methane and straight-chain alkanes in the gaseous hydrocarbon range; (2) Carbenium ion cracking type: a deficiency of methane and straight-chain alkanes in gaseous hydrocarbons; (3) Mixed cracking type: their gaseous hydrocarbons exhibit intermediate compositions between those of free radical and carbenium ion cracking types. Differences in the chemical composition of the gaseous hydrocarbons, which can be used to discriminate between the two generation mechanisms, were further supported by variations in the mineral composition, e.g., calcite and mixed-layer clay minerals are characteristic of free radical reaction and carbenium ion reaction, respectively. The present classification diagrams for gaseous hydrocarbons are based on the Jurassic shale strata of the Sichuan Basin. This novel approach for determining the whole range of hydrocarbons from closed pores shows promising prospects for deciphering the origin of light hydrocarbons and thus may be extended to other regions of interest.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107208"},"PeriodicalIF":3.7,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effects of solvent extraction on pore structure properties and oil distribution in shales of alkaline lacustrine basins","authors":"Cunjian Zhang ,&nbsp;Qinhong Hu ,&nbsp;Qiming Wang ,&nbsp;Shengyu Yang ,&nbsp;Xiuhong Li ,&nbsp;Zhi Yang ,&nbsp;Shuang Yu ,&nbsp;Jianping Yan ,&nbsp;Changan Du","doi":"10.1016/j.marpetgeo.2024.107207","DOIUrl":"10.1016/j.marpetgeo.2024.107207","url":null,"abstract":"<div><div>Shale contains numerous nano-scale pores, whose pore structure property changes affect petroleum flow, complicating shale oil accumulation and exploration. Twelve shale samples from the Permian Fengcheng Formation in the Mahu Sag and the Permian Lucaogou Formation in the Jimusar Sag in northwestern China were analyzed to investigate the coupled oil distribution and pore structure in shales from alkaline lacustrine basins. Shale samples were comprehensively analyzed before and after solvent extraction using X-ray diffraction, total organic carbon measurement, Rock-Eval analyses, field emission-scanning electron microscopy, nitrogen physisorption (NP), and (ultra) small-angle X-ray scattering [(U)SAXS] to assess nanoscale pore structure (2–300 nm in diameter) and oil distribution. Solvent extraction increased total pore volume and specific surface area (SSA). However, the accessibility of nanoscale pores remains limited. Additionally, even after retained oil removal, (U)SAXS-derived total pore volumes are 1–10.4 times larger than NP-derived connected pore volumes. Complex variations in pore volume and SSA mainly result from the removal of extractable organic matter (EOM) and the refilling of small pores by organic matter. Despite the relatively small pore volume of mesopores (2–50 nm), the amount of EOM distribution in mesopores is comparable to that in macropores (50–300 nm); therefore, it is crucial not to overlook the retention capacity of mesopores for EOM. Macropores, particularly interparticle pores associated with quartz and feldspar, play a crucial role in oil mobility. The quantity and composition of EOM, along with other factors, can alter pore structure before and after solvent extraction and should be considered in evaluating the distribution and content of free oil.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107207"},"PeriodicalIF":3.7,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Extreme sulfur isotope heterogeneity in individual Ediacaran pyrite grains revealed by NanoSIMS analysis","authors":"Yongliang Hu ,&nbsp;Wei Wang ,&nbsp;Xianye Zhao ,&nbsp;Chengguo Guan ,&nbsp;Chuanming Zhou ,&nbsp;Chenran Song ,&nbsp;Hongyi Shi ,&nbsp;Yunpeng Sun ,&nbsp;Zhe Chen ,&nbsp;Xunlai Yuan","doi":"10.1016/j.marpetgeo.2024.107201","DOIUrl":"10.1016/j.marpetgeo.2024.107201","url":null,"abstract":"<div><div>Pyrite sulfur isotopic composition (δ³⁴S_py) is a crucial proxy for reconstructing ancient Ediacaran marine environments. However, recent <em>in situ</em> isotopic analyses of sedimentary pyrite have revealed distinct δ³⁴S_py signatures among different pyrite morphologies, indicating that secular changes in bulk δ³⁴S_py may reflect variations in proportions of different pyrite morphologies rather than environmental signals. Up to now, intragrain isotopic patterns within individual pyrite grains have not yet been extensively investigated for Ediacaran samples. The absence of this specific data set has hindered our ability to understand current complexities of bulk δ³⁴S_py in reconstruction paleoenvironment. This study aims to elucidate δ³⁴S_py patterns by conducting <em>in situ</em> isotopic analysis on pyrite grains from Ediacaran drill-core samples. We employed scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), Raman spectroscopy, and nanoscale secondary ion mass spectrometry (NanoSIMS) to examine the crystal texture, element atomic ratios (S/Fe), mineral composition, and <em>in situ</em> isotopic composition within single pyrite grains. SEM-EDS observations reveal that the euhedral/subhedral pyrite crystals generally exhibit uniform mineral texture, although some grains show varying degrees of dissolution edges and surface cavities. Raman spectroscopy demonstrates the possible presence of pyrrhotite mineral within pyrite grains at some specific sites and points. <em>In situ</em> isotopic analysis reveals significant intragrain δ³⁴S heterogeneity, with difference reaching up to 69.3‰ on a micrometer scale. Distinct deposition depths and burial rates may contribute to the varying value ranges and degrees of isotopic heterogeneity amongst pyrite grains. A model suggesting rapid precipitation from numerous nucleation sites simultaneously could account for the observed intragrain heterogeneity of <em>in situ</em> δ³⁴S values. Pyrite grains exhibit general atomic S/Fe ratios of &gt; 2, potentially due to the presence of trace elements incorporated into the pyrite structure. The occurrence of pyrrhotite leads to a slightly positive correlation between <em>in situ</em> δ³⁴S_py values and S/Fe ratios, yet the ³²S-enriched pyrrhotite plays less substantial in generating intragrain δ³⁴S heterogeneity of pyrite grains. Our findings reveal clear isotopic heterogeneities within individual pyrite grains, in addition to the notable δ³⁴S_py differences among pyrite of various morphologies. These results highlight significant microenvironmental heterogeneity and dynamic sulfur pool mixing on rapid short-term timescale during pyrite growth.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107201"},"PeriodicalIF":3.7,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Methane leakage from abandoned wells in the Dutch North Sea","authors":"G. de Bruin ,&nbsp;H. de Stigter ,&nbsp;M. Diaz ,&nbsp;A. Delre ,&nbsp;I. Velzeboer ,&nbsp;N. Versteijlen ,&nbsp;H. Niemann ,&nbsp;M. Wilpshaar ,&nbsp;G.J. Reichart","doi":"10.1016/j.marpetgeo.2024.107184","DOIUrl":"10.1016/j.marpetgeo.2024.107184","url":null,"abstract":"<div><div>Methane is a powerful greenhouse gas and the second most important when considering global warming due to anthropogenic added gasses. Global inventories of greenhouse gasses currently do not take into consideration methane emitted from the ocean and seas. The North Sea is an intensely exploited seas for oil and gas and it was recently suggested to be a major source for manmade methane emissions. All wells drilled through shallow gas (methane) were found to be leaking and one-third of all abandoned wells was found to be drilled through shallow gas. Here we present the results from a research expedition to investigate methane leakage at abandoned wells drilled through shallow gas in the Dutch North Sea. We surveyed 57 abandoned wells of which 33 were drilled through shallow gas. Nine locations showed bubble plumes (acoustic flares). We noted a distinct difference between gas leakage of abandoned wells and locations with natural gas seepage. Whereas well leakage consists of one or two bubble plumes at the wellhead itself and no bubble plumes in the surrounding area, natural plume fields are characterized by tens to hundreds of plumes and none at the wellhead. At six wells, we conclude that the plumes are caused by the well leaking shallow gas, whereas three observed plume fields classify as natural seepage. We found that 18% of wells drilled through shallow gas were leaking, with 11% of all abandoned wells being drilled through shallow gas. When we compensated for over-representation of shallow gas wells in our sample (58% of our sample is drilled through shallow gas), we find that less than 2% of all abandoned wells in the Dutch North Sea is likely leaking. Well leakage seems to occur when large quantities of shallow gas are present and the abandoned well apparently suffers from an integrity issue.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107184"},"PeriodicalIF":3.7,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evaluation and modeling of velocity dispersion and frequency-dependent attenuation in gas hydrate-bearing sediments","authors":"Linsen Zhan ,&nbsp;Jun Matsushima ,&nbsp;Haotian Liu ,&nbsp;Hailong Lu","doi":"10.1016/j.marpetgeo.2024.107204","DOIUrl":"10.1016/j.marpetgeo.2024.107204","url":null,"abstract":"<div><div>Wave velocity and attenuation of gas hydrate-bearing samples are often extrapolated from ultrasonic to lower seismic/sonic frequencies, but the impact of measurement frequency on these properties is rarely studied. This study evaluates velocity dispersion and frequency-dependent attenuation in gas hydrate-bearing sediments (GHBS) by comparing vertical seismic profile (VSP) and sonic logging data from the Nankai Trough and Mallik field. We also employ rock physics modeling to simulate the velocity dispersion and frequency-dependent attenuation at both sites. The results show strong velocity dispersion and frequency-dependent attenuation in the Nankai Trough, attributed to thin, low-saturation hydrate intervals. In contrast, the Mallik field exhibits weak dispersion and frequency dependence, likely due to thick, highly saturated hydrate layers. A compilation of global hydrate reservoir attenuations indicates frequency dependence, with a peak in the sonic logging range, likely due to pore-scale hydrate effects. These findings emphasize the necessity of considering the effect of measurement frequency when performing time-to-depth conversion for seismic data based on the sonic velocity at higher frequencies, particularly for thin and lowly saturated hydrate layers, thereby improving the accuracy of hydrate reservoir characterization.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107204"},"PeriodicalIF":3.7,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Seismic geomorphology and evolution of Mid-Late Miocene deepwater channels offshore Taranaki basin, New Zealand","authors":"Marco Shaban Lutome","doi":"10.1016/j.marpetgeo.2024.107202","DOIUrl":"10.1016/j.marpetgeo.2024.107202","url":null,"abstract":"<div><div>Deepwater channels play a significant role in deep marine environments by transporting sediments to deep marine environments, but they are also hydrocarbon reservoirs. In contrast, traditional seismic interpretation techniques have provided insights into these features; intricate channel-fill heterogeneities present challenges in revealing small features or associated elements. This study integrates high-resolution 3D seismic data, relative time geologic models (RGT), spectral decomposition, and geobody to identify the Middle-late Miocene submarine channels, their evolution, and their associated deposition elements. The geomorphologic and stratigraphic analysis results have revealed four depositional elements in the study area. These include (1) channel complexes, (2) distributary channels, (3) frontal splay channel complexes, and (4) crevasse splays. However, the channels lack constructional levee development outside the channel banks, which is linked to the limited sediment supply to deep areas. The identified channels are characterized by a narrow to wide width (0.37 km–1.92 km), a low to high degree of sinuosity, medium incision depths, and lateral migration. The channel fill geometries are highly variable, displaying horizontal to sub-horizontal, lateral accretion, divergent, and inclined reflection packages. Most channels originate as large and wide channels from the northeast and prograde southwest direction of the Taranaki coastline, and they have evolved differently at different development stages. The channel fills exhibit a variable basal amplitude reflection, ranging from medium to high, indicating the presence of sand-prone and mixed facies, such as sand and mudstone. The spectral decomposition maps show variable color intensity, which implies different facies associations within the channels. The channel evolution is likely to be controlled by the interplay of sediment discharge, faults, sea level changes, variable gravity flow strength, and the type of materials supplied from the shelf edge.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107202"},"PeriodicalIF":3.7,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Integrated fracture analysis for improved oil recovery in the reefal limestones of Soğucak formation, Northwest Thrace Basin, Türkiye","authors":"Ergin Karaca ,&nbsp;İsmail Ömer Yılmaz ,&nbsp;Günay Çifci ,&nbsp;Bulut Tortopoğlu ,&nbsp;Serhat Akın","doi":"10.1016/j.marpetgeo.2024.107198","DOIUrl":"10.1016/j.marpetgeo.2024.107198","url":null,"abstract":"<div><div>Natural fractures play a crucial role in both exploration and development phases in oil and gas industry, as their network and orientation significantly affect flow and recovery strategies. This study highlights the importance of identifying opening-mode fracture systems within a mature Deveçatağı oil field that has been actively producing for nearly half a century. In order to investigate the most effective rock physics parameter to locate oil saturated zones in the field, this study applies detailed rock physics analysis and 2D forward modeling to pinpoint the principal factors affecting production in the Deveçatağı oil field, addressing the challenge posed by the limited shear wave wireline data acquired from only one well within this highly heterogeneous area. Analysis show that acoustic impedance is a crucial elastic property for detecting oil-saturated zones especially in areas with natural fractures. This study successfully integrates drilling-induced fracture (DIF) data, ant tracking maps, and seismic inversion outputs to understand on the issues leading to dry wells and advances in developing more effective exploration and recovery methods in fractured reservoirs. After almost 50 years of operational activities, well stimulation processes, and natural fractures that are present in this field, understanding oil drainage mechanisms in such environments is complex, emphasizing the need for comprehensive analysis to optimize production strategies.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107198"},"PeriodicalIF":3.7,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Genesis of Botryococcus-rich laminae of the Eocene Upper Xiaganchaigou Formation in the western Qaidam Basin, NW China","authors":"Guolong Liu ,&nbsp;Mingzhen Zhang ,&nbsp;Rongchang Zhao ,&nbsp;Dunzhu Jiaoba ,&nbsp;Xiangtong Lei ,&nbsp;Baoxia Du ,&nbsp;Jing Zhang ,&nbsp;Shaohua Lin ,&nbsp;Peihong Jin ,&nbsp;Aijing Li ,&nbsp;Jing Peng ,&nbsp;Yiqiao Fu ,&nbsp;Jianguo Hui","doi":"10.1016/j.marpetgeo.2024.107203","DOIUrl":"10.1016/j.marpetgeo.2024.107203","url":null,"abstract":"<div><div>Laminated source rocks exhibit high hydrocarbon potential and good reservoir characteristics. <em>Botryococcus</em> fossils with high hydrocarbon potential have been discovered in the laminated source rocks of the Upper Xiaganchaigou Formation in the Qaidam saline basin in earlier research. However, planktonic algae typically thrive in freshwater or slightly brackish water environments. Subsequently, the seemingly contradictory phenomenon of <em>Botryococcus</em> blooms in saline lakes may be the key to revealing the formation mechanism of these high-quality algae-rich laminated source rocks. This study investigates the rich <em>Botryococcus</em> laminated source rocks in saline lacustrine basins using petrology and elemental geochemistry. First, this study indicates that the detrital laminae are rich in <em>Botryococcus</em> and pyrite framboids and form a couplet with clay or carbonate laminae. Comparatively, the clay laminae in the couplet lack <em>Botryococcus</em> but are rich in halite and amorphous microcrystalline pyrite particles, whereas the carbonate laminae lack <em>Botryococcus</em> and contain very little pyrite. Second, the nutrient element phosphorus exhibits minor changes among these laminae, suggesting that the key factor controlling the <em>Botryococcus</em> bloom may not be the nutrient element but water salinity and temperature conditions related to growth habits. Finally, the particle size and formation characteristics of pyrite framboids indicate water column redox stratification, suggesting that in warm and humid summer, surface runoff resulting from heavy rainfall brings abundant terrigenous minerals and elements into the lake water, the lake deepens and stratifies under the joint influence of temperature, salinity, and algae; the detrital laminae contain debris, <em>Botryococcus,</em> and pyrite framboids. Conversely, in cold and dry winters, the shrinking salinized lake water inhibits <em>Botryococcus</em> growth and pyrite framboid formation. Clay laminae rich in halite or carbonate laminae are deposited. The regional distributions of these sediment types also exhibit obvious differences that the Yingxiongling sag is rich in clay–detrital couplet laminae, whereas the Zhahaquan sag exhibits a high abundance of carbonate–detrital couplet laminae. Overall, the investigation of the genesis of laminated source rocks in saline lake basins may be of great significance to hydrocarbon understanding and exploration.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107203"},"PeriodicalIF":3.7,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"U-Pb ages of pre- to post-salt carbonates, Santos and Campos basins, SE Brazil: Implications for the evolution of the South Atlantic","authors":"Fernando F. Alkmim ,&nbsp;Cristiano C. Lana ,&nbsp;Marco A.L. Silva ,&nbsp;Dorval C. Dias-Filho ,&nbsp;Katia R.N. Mendonça ,&nbsp;Eveline E. Zambonato ,&nbsp;Bruno Raphael B.M. de Carvalho","doi":"10.1016/j.marpetgeo.2024.107192","DOIUrl":"10.1016/j.marpetgeo.2024.107192","url":null,"abstract":"<div><div>The exploration campaigns and independent studies conducted in the central South Atlantic basins after the discovery of giant oil accumulations in the Lower Cretaceous lacustrine carbonates sealed by the salt layer resulted in a new panorama of the tectonic framework, stratigraphic architecture, and petroleum systems of the investigated basins and passive margins in general. Despite these remarkable advances, the ages of the carbonate reservoirs and the sealing evaporites remain uncertain. Aiming to fill this gap, we present here the results of 30 U-Pb LA-ICP-MS calcite and dolomite age determinations representative of the depositional/eo-diagenetic processes and subsequent phases of carbonate cementation recorded by pre-to post-salt units of the Santos and Campos basins of southeastern Brazil. Microcrystalline calcite of a mudstone of the Itapema Formation (Santos Basin) yielded a minimum age of 126.8 ± 4.7 Ma. 19 depositional/eo-diagenetic ages obtained in mudstones, grainstones, shrubstones, spherulitestones, and travertines of the correlative Barra Velha and Macabu pre-salt lacustrine carbonates cluster around 124.1 ± 2.2 and 122.1 ± 2.3 Ma. Considering the errors, these results limit the deposition/eo-diagenesis of these units to the 126.2–120.0 Ma interval. Two determinations carried out in calcite laminae of a nodular anhydrite sample extracted from the lower portion of the Retiro Evaporite (Campos Basin) returned the ages of 119.2 ± 1.6 Ma and 119.18 ± 0.79 Ma, which we interpreted as the best approximation of the timing of the salt deposition. Analyses performed in 3 samples from the post-salt Quissamã carbonates (Campos Basin) provide a minimum age of 114.2 ± 2.8 Ma yielded by interparticle dolomite cement. Other phases of calcite and dolomite cements present in the investigated units were dated at ca. 119.4, 116.5, and 110.7 Ma. The stratigraphically coherent spectrum of ages obtained differs significantly from most available data, providing a new perspective for the ongoing discussions on the tectonic evolution of the South Atlantic and probably impacting the current views of the burial history and petroleum system of the Santos and Campos basins.</div></div>","PeriodicalId":18189,"journal":{"name":"Marine and Petroleum Geology","volume":"171 ","pages":"Article 107192"},"PeriodicalIF":3.7,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}