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The role of reservoir compartmentalization in the failure of reservoirs of structurally complex accommodation zones: an example from The Morgan Accommodation Zone, Gulf of Suez, Egypt 储层分区在构造复杂可容纳带储层破坏中的作用:以埃及苏伊斯湾摩根可容纳带为例
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-29 DOI: 10.1016/j.marpetgeo.2025.107610
Zakaria Hassan , Mohamed S. Hammed , Ahmed E. Radwan , Selim S. Selim , Shaimaa Abdelhaleem
Compartmentalization of hydrocarbon reservoirs represents a global challenge in assessing and developing proven fields due to the necessity for a detailed survey of the field structures, burial history, and pressure system. The geological complexity arising from overlapping fault segments, kinematically linked fracture networks, and heterogeneous stratigraphic juxtapositions within accommodation zones between Gulf of Suez rift segments results in highly variable reservoir performance—yielding prolific hydrocarbon production in some fields, while others remain non-productive—and contribute to the occurrence of multiple oil-water contacts within individual producing reservoirs. We use structural restoration, basin modelling, pore pressure and fracture gradient modelling to assess the pre-rift reservoir failure and the variation of the oil-water contact in the syn-rift reservoirs of the Morgan accommodation Zone, Gulf of Suez. Our results show that: (1) pre-Miocene source rocks are too shallow for maturation due to complex fault linkages and interaction; (2) immature pre-Miocene source rocks prevent effective hydrocarbon generation and charge; (3) no overpressure above the Eocene Thebes Formation; lack of charge attributed to either immature source rocks at juxtaposition points or sealing faults; (4) a fill-to-spill mechanism governs Miocene syn-rift oil-water contact variations; deeper oil-water contact in western blocks results from better connectivity to mature source kitchens west of GS327. These results offer crucial new insights into the interplay of pressure regimes, migration routes, and reservoir compartmentalization governing hydrocarbon plays in complex accommodation zones.
由于需要对油田结构、埋藏历史和压力系统进行详细调查,油气藏划分是评估和开发已探明油田的一个全球性挑战。由于苏伊士湾裂谷段之间可调节带内的重叠断裂段、运动学连接的裂缝网络和非均匀地层并置所引起的地质复杂性,导致储层性能变化很大,在一些油田产生了丰富的油气产量,而在另一些油田则保持非生产性,并导致在单个生产油藏中出现多个油水接触。利用构造恢复、盆地模拟、孔隙压力和裂缝梯度模拟等方法,对苏伊士湾摩根容纳带同裂谷储层的裂谷前储层破坏和油水接触变化进行了评价。结果表明:(1)前中新世烃源岩由于断裂联系和相互作用复杂,烃源岩太浅,无法成熟;(2)前中新世烃源岩不成熟,不利于有效生烃和充注;(3)始新世底比斯组以上无超压;并置点的未成熟烃源岩或封闭性断层导致充注不足;(4)中新世同裂谷油水接触变化受充溢机制支配;由于与GS327以西的成熟油源厨房的连通性更好,西部区块的油水接触更深。这些结果为复杂调节带中控制油气作用的压力机制、运移路线和储层划分的相互作用提供了重要的新见解。
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引用次数: 0
New constraints on the nature and composition of the São Paulo Plateau, Santos Basin: Magmatic, continental or hybrid crust? 对<s:1>圣保罗高原、桑托斯盆地性质和组成的新限制:岩浆、大陆还是混合地壳?
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-28 DOI: 10.1016/j.marpetgeo.2025.107612
Michelle Cunha Graça , Nick Kusznir , Natasha Stanton , Gianreto Manatschal , Andres Mora
The São Paulo Plateau (SPP), located in the Santos segment of the southeastern (SE) Brazilian margin underlying thick Cretaceous to Recent sediments, is an enigmatic feature with disputed crustal composition. Proposed crustal types include thinned continental crust, thick magmatic crust, and hybrid crust consisting of continental crust and magmatic addition. We use combined analysis of mainly geophysical datasets to investigate the crustal basement thickness and crustal type of the SPP, and the variation in timing of its rifting and magmatic addition. 2D and 3D combined analysis of deep seismic reflection and gravity anomaly data has been used to determine Moho depth, crustal thickness and basement density variation. Flexural back-stripping has been used to map sediment-corrected residual depth anomaly (RDA). A combination of observations of crustal thickness from gravity inversion, magnetic anomalies reduced to the pole, basement density from gravity-seismic joint-inversion, and RDA have been used together to distinguish and identify crustal basement types. Using these approaches, we show the distribution and coexistence of continental, hybrid and magmatic crust, as well as possible exhumed mantle in the Santos Basin.
In addition, 2D and 3D post-breakup subsidence modelling consisting of flexural back-stripping, decompaction and reverse thermal subsidence modelling has been used to determine the palaeo-datum of base and top salt at the time of salt formation. This salt palaeo-datum modelling is used to distinguish syn-tectonic from post-tectonic salt and to investigate the contrasting consequences of magmatic versus thinned continental crust on the palaeo-bathymetry of Aptian salt deposition. We show that the distribution of post-tectonic salt primarily corresponds to that of continental crust thinned by widespread early Aptian rifting while syn-tectonic salt locations correspond to that of magmatic crust extended by late Aptian rifting.
圣保罗高原(SPP)位于巴西东南部(SE)边缘的桑托斯段,下伏白垩纪至近代厚沉积物,是一个具有争议的地壳组成的神秘特征。提出的地壳类型包括薄大陆地壳、厚岩浆地壳和由大陆地壳和岩浆添加物组成的混合地壳。通过对主要地球物理资料集的综合分析,研究了SPP的地壳基底厚度、地壳类型以及裂谷和岩浆作用时间的变化。利用深地震反射和重力异常资料进行二维和三维联合分析,确定了莫霍深度、地壳厚度和基底密度变化。利用弯曲反剥法绘制沉积校正后的残余深度异常(RDA)。结合重力反演的地壳厚度观测、磁异常降至极点、重震联合反演的基底密度观测和RDA等方法,对地壳基底类型进行了区分和识别。利用这些方法,我们揭示了桑托斯盆地大陆地壳、混合地壳和岩浆地壳的分布和共存,以及可能的地幔发掘。此外,采用折弯反剥脱、分解和逆热沉降的二维和三维破碎后沉降模型,确定了成盐时基底和上盐的古基准面。这种盐古基准面模拟用于区分同构造盐和后构造盐,并研究岩浆和变薄大陆地壳对阿普田盐沉积古测深的对比影响。构造后盐的分布主要与阿普田早期裂陷作用下的大陆地壳减薄相对应,而同构造盐的分布与阿普田晚期裂陷作用下的岩浆地壳伸展相对应。
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引用次数: 0
Constraining self-sourcing stratigraphic plays in North Sumatra: Integration of basin-petroleum system and stratigraphic forward modeling 北苏门答腊约束自源地层油气藏:盆地-含油气系统与地层正演模拟的结合
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-25 DOI: 10.1016/j.marpetgeo.2025.107611
Qi Adlan , Barry M. Hartono , Harya D. Nugraha , Adhipa Herlambang , Waleed AlGharbi , Eriko Sabra
Stratigraphic traps are typically identified and delineated using 3D seismic analysis or by integrating well data. These plays involve greater exploration uncertainty than conventional traps, especially in regions where multiple petroleum systems coexist. A notable example is the self-sourcing stratigraphic trap, where hydrocarbons migrate laterally within coeval rock formations. This challenge is particularly significant in frontier areas lacking 3D seismic data and with limited well data. Therefore, developing a reliable methodology is essential to accurately identify potential stratigraphic trap zones while effectively accounting for the complex interactions within petroleum systems.
This study integrates stratigraphic forward modeling (SFM) and basin and petroleum system modeling (BPSM) to better constrain self-sourcing stratigraphic traps. The North Sumatra Basin was selected as the study area because it features a complex petroleum system involving three source rocks and various trapping mechanisms, including stratigraphic traps from the Middle Miocene. The systematic approach demonstrated in this study involves four key stages: (1) assessing geochemical evidence, (2) using SFM to delineate trap zones, (3) simulating organic matter distribution, and (4) applying BPSM to evaluate source rock maturation and hydrocarbon expulsion. This systematic approach provides a cost-effective framework for early-stage hydrocarbon exploration, helping geoscientists de-risk prospects before committing to high-cost data acquisition like 3D seismic surveys. It is particularly suited for evaluating stratigraphic traps associated with self-sourcing plays and has potential applications in unconventional resource exploration, including shale gas. Regionally, this research provides the first geochemical evidence of oil mixing in the area and presents conclusive insights into the four active petroleum system plays, potentially redefining exploration strategies in the region.
地层圈闭通常是通过三维地震分析或整合井数据来识别和圈定的。与常规圈闭相比,这些油气藏具有更大的勘探不确定性,特别是在多个含油气系统共存的地区。一个值得注意的例子是自源地层圈闭,其中碳氢化合物在同古岩层中横向运移。在缺乏三维地震数据和井数据有限的前沿地区,这一挑战尤为显著。因此,开发一种可靠的方法对于准确识别潜在的地层圈闭带,同时有效地考虑石油系统内部复杂的相互作用至关重要。该研究将地层正演模拟(SFM)与盆地与油气系统模拟(BPSM)相结合,以更好地约束地层自源圈闭。选择北苏门答腊盆地作为研究区,是因为该盆地具有复杂的含油气系统,包括三种烃源岩和多种圈闭机制,包括中中新世地层圈闭。该系统方法包括四个关键阶段:(1)地球化学证据评估;(2)利用SFM圈闭区圈定;(3)模拟有机质分布;(4)利用BPSM评价烃源岩成熟和排烃。这种系统的方法为早期油气勘探提供了一个经济有效的框架,帮助地球科学家在进行高成本的数据采集(如3D地震调查)之前降低前景风险。它特别适合于评价与自源油藏相关的地层圈闭,并在非常规资源勘探(包括页岩气)中具有潜在的应用前景。从区域上看,该研究提供了该地区石油混合的第一个地球化学证据,并对四个活跃的含油气系统区提供了决定性的见解,有可能重新定义该地区的勘探策略。
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引用次数: 0
Maceral-specific evolution of molecular structure and porosity from the early oil to dry gas window in black shales 黑色页岩早期油-干气窗分子结构与孔隙度的微观特征演化
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-22 DOI: 10.1016/j.marpetgeo.2025.107609
Yingzhu Wang , Jianfa Wu , Qing Luo , Jinyou Zhang , Zhuoheng Chen , Jijin Yang
The chemical composition and structural evolution of organic matter (OM) controls pore development in shale reservoirs, but their intrinsic relationship during thermal maturation remains insufficiently understood. This study integrates light microscopy, scanning electron microscopy (SEM), and Raman spectroscopy to investigate microscale variations in petrological features, molecular structures, and pore characteristics across diverse maceral types in the Upper Devonian Duvernay shales, spanning a thermal maturity range of 0.5 %–3.0 % reflectance (Ro) in the West Canada Sedimentary Basin. Results show that alginite and solid bitumen undergo more pronounced compositional transformation with thermal maturation than inertinite and vitrinite, as reflected in broad ranges of Raman spectral parameters. While inertinite consistently displays the highest aromaticity, vitrinite shows a similar aromaticity with pore-filling solid bitumen after Ro >1.0 %. The divergent evolutionary pathways among diverse OM macerals are attributed to the differences in biological origin and hydrocarbon generation kinetics. OM-hosted pores mainly develop in solid bitumen after the late oil window, coincident with a sharp increase in both OM aromaticity and oil expulsion. Moreover, pore-filling solid bitumen shows a higher apparent transformation ratio (15 %–25 %) and larger mean pore size (40–45 nm) than alginite-derived solid bitumen, likely due to chromatographic fractionation. Throughout the gas window, pore-filling solid bitumen accounts for >90 % of the total OM-hosted porosity. Those findings advance our understanding of pore generation and evolution mechanisms across maceral types, and provide a chemical framework for predicting shale reservoir quality over a range of thermal maturities.
页岩储层有机质的化学组成和结构演化控制着孔隙发育,但它们在热成熟过程中的内在关系尚不清楚。本研究结合光学显微镜、扫描电镜(SEM)和拉曼光谱(Raman spectroscopy),研究了加拿大西部沉积盆地上泥盆统Duvernay页岩不同显微组分类型的岩石学特征、分子结构和孔隙特征的微观变化,该页岩的热成熟度范围为0.5% - 3.0%反射率(Ro)。结果表明,随着热成熟,褐藻煤和固体沥青的组成转变比惰质岩和镜质岩更明显,这反映在拉曼光谱参数的宽范围上。在Ro >; 1.0%之后,镜质组与孔隙填充固体沥青表现出相似的芳香性,而惰质组始终表现出最高的芳香性。不同有机质的演化路径不同,主要是由于生物来源和生烃动力学的差异。有机质孔隙主要发育于晚含油窗后的固体沥青中,有机质芳香度和排油量均急剧增加。此外,孔隙填充型固体沥青的表观转化率(15% ~ 25%)和平均孔径(40 ~ 45 nm)均高于褐藻石衍生型固体沥青,这可能与色谱分馏有关。在整个气窗中,孔隙填充的固体沥青占总om储集孔隙度的90%。这些发现促进了我们对孔隙生成和演化机制的理解,并为预测不同热成熟度范围内页岩储层的质量提供了化学框架。
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引用次数: 0
Unraveling the parameters controlling diagenetic evolution in relatively shallow-buried, syn-tectonic ramp limestones (Upper Cretaceous), United Arab Emirates 阿拉伯联合酋长国上白垩统相对浅埋同构造斜坡灰岩成岩演化控制参数揭示
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-19 DOI: 10.1016/j.marpetgeo.2025.107607
Mohammad Alsuwaidi , Howri Mansurbeg , Abdullah H. Awdal , Salahadin Shahrokhi , Ali M. Al-Tameemi , Filippo Casali , Mohammed Y. Ali , Luiz Fernando De Ros , Ibrahim Q. Mohammed , Hamed Gamaleldien , Sadoon Morad
This study utilizes petrographic, geochemical, and fluid-inclusion microthermometric analyses to unravel the controls on the distribution of diagenetic alterations of shallow-buried Upper Cretaceous syn-tectonic, foreland, ramp limestones of the United Arab Emirates. The diagenetic alterations are linked to porewater evolution during the tectonic evolution of the basin, as well as to the depositional facies and sequence stratigraphy. Limited improvement of reservoir quality was promoted by dissolution of allochems and formation of moldic pores. Porosity reductionensued mostly from: (i) cementation by meteoric waters and by hot basinal/hydrothermal brines with wide ranges of δ18OV-PDB (−6.3 ‰ to −3.2 ‰) and precipitation temperatures (Th ≈ 65–125 °C; salinity ≈ 16–22 wt% NaCl eq), and (ii) mechanical compaction of ductile peloids formed by micritization of allochems. Micritization, notably prevalent in the transgressive lagoon and upper ramp slope packstones, as well as in the regressive shoal grainstones below marine-flooding surfaces, led to the development of abundant microporosity. Porosity was preserved in some of the grainstones by partial calcite cementation (rims, as well as scattered equant crystals and syntaxial overgrowths), which supported the framework against mechanical compaction. Dissolution of aragonitic allochems and concomitant cementation by equant calcite was prevalent in regressive shoal grainstones during repeated episodes of subaerial exposure and meteoric-water incursion as a consequence of the syn-tectonic deposition. The δ13CV-PDB (−11.6 ‰ to +13.2 ‰; mostly −2‰ to +2 ‰) suggests derivation from marine porewaters and/or dissolution of the host limestones and, in some cases, from methanogenesis of organic matter and methane oxidation. The lack of systematic differences in porosity and permeability between the limestones from the crest and the flanks of the field is attributed to the accomplishment of most diagenetic alterations before oil emplacement.
本研究利用岩石学、地球化学和流体包裹体显微温度分析,揭示了阿拉伯联合酋长国上白垩统浅埋同构造、前陆、斜坡灰岩成岩蚀变分布的控制因素。成岩蚀变与盆地构造演化过程中的孔隙水演化有关,也与沉积相、层序地层学有关。异质物的溶蚀作用和霉菌孔隙的形成促进了储层质量的有限改善。孔隙度的减少主要来自:(1)大气水和热盆地/热液的胶结作用(δ 18v - pdb范围为- 6.3‰~ - 3.2‰)和降水温度(Th≈65 ~ 125℃,盐度≈16 ~ 22 wt% NaCl eq),以及(2)异化物微晶化形成的韧性样质体的机械压实作用。泥晶化作用主要存在于海侵泻湖和上斜坡砾岩中,以及海淹面以下的退退浅滩砾岩中,导致了丰富的微孔隙发育。部分方解石胶结(边缘,以及分散的等晶和合成过度生长)保留了一些颗粒石的孔隙度,这支持了框架免受机械压实。在同构造沉积的多次地面暴露和大气水侵入过程中,文石异变物的溶解和等量方解石的胶结作用在退退的浅滩颗粒岩中普遍存在。δ13CV-PDB(- 11.6‰~ +13.2‰,多数为- 2‰~ +2‰)表明其成因为海相孔隙水和/或寄主灰岩溶蚀作用,部分为有机质产甲烷作用和甲烷氧化作用。油田顶部和侧翼的灰岩在孔隙度和渗透率方面缺乏系统性差异,这是由于大多数成岩蚀变在石油侵位之前完成的。
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引用次数: 0
Gas-in-place (GIP) model and resource potential of the ultra-deep Lower Cambrian gas-rich shales in the southern Sichuan Basin, China 四川盆地南部下寒武统超深层富气页岩就地气(GIP)模式及资源潜力
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-18 DOI: 10.1016/j.marpetgeo.2025.107606
Haitao Gao , Peng Cheng , Wei Wu , Chao Luo , Haifeng Gai , Liang Xu , Tengfei Li , Shangli Liu , Hui Tian
The deep and ultra-deep Lower Cambrian Qiongzhusi (DUDQ) shales have abundant gas resources. However, the strong heterogeneity of the DUDQ shale makes it complex to accurately predict the gas-in-place (GIP) content and resource potential. The first high-yield DUDQ shale well Z201 in the southern Sichuan Basin, offering a crucial opportunity to investigate their gas-bearing characteristics. This study focuses on the Qiongzhusi Formation Q12 submember (Q12) of well Z201, analyzes their geological characteristics, and measures its adsorption parameters through high-temperatures (60−150 °C) and high-pressures (0.01−35 MPa) methane adsorption experiments, and a geological GIP model is established to predict the shale gas resources of the DUDQ shales. The maximum absolute adsorption gas content (n0) and adsorbed phase methane density (ρads) of the DUDQ shales range from 1.90 to 4.91 cm3/g and 0.28−0.47 g/cm3, respectively. Both n0 and ρads are positively correlated with total organic carbon (TOC) content and geopressures, but negatively correlated with temperature. The average adsorption capacity of inorganic matter (IM) in the DUDQ shales is 1.99 cm3/g, which, together with high TOC content, are the main important factors contributing to the high GIP contents. With increasing burial depth, the formation temperature and pressure gradually increase. Meanwhile, the adsorbed gas content (nads) and total gas content (ntot) initially tend to increase followed by a subsequent decrease, whereas the free gas content (nfree) tends to increase. Moreover, ntot is also affected by the TOC content and effective porosity. The most promising areas for the DUDQ shale gas exploration and development are the central area of the intracratonic sag and the surrounding regions of the Weiyuan anticline, with estimated shale gas resources exceeding 2.52 × 1012 m3.
下寒武统筇竹寺(DUDQ)深层和超深层页岩具有丰富的天然气资源。然而,由于DUDQ页岩具有很强的非均质性,使得准确预测GIP含量和资源潜力变得非常复杂。川南地区首口高产DUDQ页岩井Z201,为研究其含气特征提供了重要契机。以Z201井筇竹斯组Q12亚段(Q12)为研究对象,分析其地质特征,并通过高温(60 ~ 150℃)和高压(0.01 ~ 35 MPa)甲烷吸附实验测量其吸附参数,建立地质GIP模型对DUDQ页岩气资源进行预测。DUDQ页岩最大绝对吸附气含量(n0)和吸附相甲烷密度(ρads)分别为1.90 ~ 4.91 cm3/g和0.28 ~ 0.47 g/cm3。nh0和ρ值与总有机碳(TOC)含量和压力呈正相关,与温度呈负相关。DUDQ页岩中无机物(IM)的平均吸附量为1.99 cm3/g,这与高TOC含量是导致页岩中GIP含量高的主要因素。随着埋深的增加,地层温度和压力逐渐升高。同时,吸附气含量(nads)和总气含量(not)呈先增加后降低的趋势,而自由气含量(nfree)呈增加的趋势。此外,TOC含量和有效孔隙度也会影响孔隙度。DUDQ页岩气勘探开发最具前景的区域为克拉通内凹陷中部和威远背斜周缘,页岩气资源量估计超过2.52 × 1012 m3。
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引用次数: 0
The static and dynamic behaviour of large faults as seals and conduits to aqueous and petroleum fluid flow at geological time-scales: Observations from the Beryl Embayment, UK North Sea 在地质时间尺度上,作为水和石油流体流动的密封和管道的大断层的静态和动态行为:来自英国北海绿柱石勘探的观测
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-14 DOI: 10.1016/j.marpetgeo.2025.107604
Philip T.S. Rose , Rene Jonk , Rachael Crowe , John Gibson , Andrew Dickson , Andrew Lind , Daniel Helgeson
Faults play an important role in controlling flow and retention of aqueous and petroleum fluids from overpressured basin centres (“kitchens”) to basin flanks. The Beryl Kitchen is a deep overpressured basin in the Beryl Embayment on the flanks of the Viking Graben in the UK northern North Sea and provides a data rich laboratory allowing these processes to be studied in detail. In this study we combine the results of detailed structural mapping, constrained by broadband seismic and abundant well control, with reservoir pressure data and hydrocarbon geochemistry. We use the data to demonstrate how the bounding faults of the Beryl Kitchen have acted as significant capillary seals, even with abundant porous and permeable reservoir juxtaposition across the key faults. The fault plane seals allowed the baffled escape of aqueous fluids, creating fault-bounded pressure compartments, while trapping significant hydrocarbon columns at the boundary between overpressured and normally pressured reservoirs. We demonstrate how the behaviour of some of these faults has evolved with progressive burial and increasing source rock maturity in the deepest parts of the basin. On the flanks of the Beryl Kitchen these processes have resulted in the preservation of hydrocarbon accumulations with unexpectedly tall columns and an unintuitive distribution of hydrocarbon water contacts in adjacent fault blocks. These accumulations provide valuable exploration analogues for the evaluation of the hydrocarbon potential of fault bound structures at the margins of overpressured basins.
断层在控制含水和含油流体从超压盆地中心(“厨房”)向盆地侧翼的流动和滞留方面起着重要作用。绿柱石厨房是位于英国北海北部维京地堑侧翼的绿柱石Embayment中的一个深超压盆地,它提供了一个数据丰富的实验室,可以详细研究这些过程。在这项研究中,我们将详细的构造填图结果与储层压力数据和油气地球化学数据结合起来,这些结果受到宽带地震和丰富的井控的约束。我们利用这些数据证明了绿柱石厨房的边界断层是如何发挥重要的毛细管密封作用的,即使在关键断层上有丰富的多孔性和渗透性储层并立。断裂面封闭性使得含水流体可以不受阻碍地逸出,形成了断层边界的压力区,同时在超压油藏和常压油藏之间的边界处圈闭了重要的油气柱。我们展示了这些断层的行为是如何随着盆地最深处的逐渐埋藏和烃源岩成熟度的增加而演变的。在绿柱基灶的侧翼,这些作用导致了油气聚集的保存,这些聚集具有出乎意料的高柱,并且在邻近断块中烃类水接触面分布不直观。这些聚集为评价超压盆地边缘断裂束缚构造的油气潜力提供了有价值的勘探模拟。
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引用次数: 0
Kinetics of thermochemical sulfate reduction based on pyrolysis gold-tube experiments on lacustrine oil: Implications for H2S prediction in Brazilian pre-salt reservoirs 基于热裂解金管实验的湖相油热化学硫酸盐还原动力学:对巴西盐下储层硫化氢预测的启示
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-13 DOI: 10.1016/j.marpetgeo.2025.107600
Igor V.A.F. Souza , Yongchun Tang , Le Lu , Alexandre A. Ferreira , Geoffrey S. Ellis , Rut A. Díaz , Luiz Felipe Carvalho Coutinho , Ana Luiza S. Albuquerque
The Pre-salt section in the Santos Basin area is one of the largest oil discoveries in the world during the last 20 years. The reservoir fluid in this area contains non-hydrocarbon gases (CO2 and H2S) that can negatively impact the economic prospects of the field. Previous studies have indicated that the main H2S generation process in Pre-salt reservoirs is thermochemical sulfate reduction (TSR). However, a more comprehensive understanding of these occurrences is required, particularly considering the reservoir temperatures (less than 120 °C) and the variations in δ34S H2S values. Moreover, there is currently no published research addressing the kinetic behavior of TSR in lacustrine oils. To better understand the origin of these non-hydrocarbon gases, TSR experiments with gold tubes were carried out to obtain information about the fluid changes, kinetic behavior, identification of fluid proxies, and to create a fluid composition model to predict H2S in exploratory areas. With increasing extent of TSR reaction, the experimentally generated gases show the following patterns: i) Large generation of non-hydrocarbon gases with CO2 being predominant; ii) The progressive increase in gas dryness (C1/ΣC1-5) ultimately reaching 99.9 % by the end of the experiments; iii) The carbon isotopic composition (δ13C) trending toward heavier values for C1-C3 and CO2; and iv) The sulfur isotopic composition of H2S approaches the δ34S of sulfate. Additionally, the TSR process reduced the liquid mass by as much as 50 %, mainly focused on the gasoline range fraction (C6-C14), indicating the suitability for hydrocarbon oxidation. A large amount of residual hydrocarbons was observed at the end of each experiment, reaching 33 % of the original mass under the most extensive TSR conditions. The parameters for the TSR kinetics were: i) pre-exponential factor (Af) of 4.8x1013 s−1, ii) unimodal activation energy (Ea) in 53 kcal/mol, iii) total potential of 767 mg H2S/g oil. These kinetic parameters were tested in one geological scenario derived from the regional petroleum system model and compared with previous kinetic models from the literature. Two types of TSR reactions (with and without initiators/catalysts) were identified by the model predictions. The model generated with the kinetic parameters proposed by this work predicted a gas composition the closest to that observed in the modeled well. The developed kinetic model can be an important tool for better H2S prediction in exploratory areas of the Pre-salt Santos Basin.
桑托斯盆地的盐下部分是近20年来世界上最大的石油发现之一。该地区的储层流体中含有非碳氢化合物气体(CO2和H2S),会对油田的经济前景产生负面影响。已有研究表明,盐下储层中主要的H2S生成过程是热化学硫酸盐还原(TSR)。然而,需要更全面地了解这些产层,特别是考虑到储层温度(低于120°C)和δ34S H2S值的变化。此外,目前还没有关于湖相油中TSR的动力学行为的研究。为了更好地了解这些非碳氢气体的来源,研究人员利用金管进行了TSR实验,以获得有关流体变化、动力学行为、流体代理识别的信息,并建立了流体成分模型来预测勘探区域的H2S。随着TSR反应程度的增加,实验生成的气体表现出以下模式:1)大量生成以CO2为主的非烃气体;ii)实验结束时,气体干燥度(C1/ΣC1-5)逐渐增加,最终达到99.9%;ⅲ)C1-C3和CO2的碳同位素组成(δ13C)值趋于偏大;H2S的硫同位素组成接近于硫酸盐的δ34S。此外,TSR工艺减少了高达50%的液体质量,主要集中在汽油范围分数(C6-C14),表明适合烃类氧化。在每次实验结束时都观察到大量残余烃,在最广泛的TSR条件下,残余烃达到原始质量的33%。TSR动力学参数为:指数前因子(Af)为4.8x1013 s−1,单峰活化能(Ea)为53 kcal/mol,总势能为767 mg H2S/g油。这些动力学参数在一个由区域油气系统模型导出的地质情景中进行了测试,并与文献中已有的动力学模型进行了比较。通过模型预测确定了两种类型的TSR反应(有和没有引发剂/催化剂)。根据这项工作提出的动力学参数生成的模型预测的气体成分与模拟井中观察到的最接近。建立的动力学模型可为Santos盆地盐下勘探区进行更好的H2S预测提供重要工具。
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引用次数: 0
Where the salt sheet ends - submarine allochthonous salt advance and hindrance, The Elda Salt Sheet, Eastern Prebetics (Southern Iberia) 盐片的终点-海底异域盐的推进和阻碍,埃尔达盐片,东部先锋队(南部伊比利亚)
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-13 DOI: 10.1016/j.marpetgeo.2025.107598
David Paul Canova , Gabriel Cofrade , Eduard Roca , Marco De Matteis , Oriol Ferrer
The Eastern Prebetics are part of the External Zone of the Betic Fold-and-Thrust Belt in SE Iberia where a significant amount of salt structures crops out including: diapirs, allochthonous sheets, welds, primary and secondary minibasins, and rafts. Our study focuses on the subsalt, syn-contractional, early to middle Miocene (Aquitanian-Langhian) stratigraphy of the Elda Salt Sheet, aiming to document the sub seismic scale deformation and salt-sediment interactions during allochthonous salt advance. Stratigraphic sections, halokinetic fold analysis, geologic field mapping and foraminiferal dating are used to characterize the subsalt sediments exposed in contact with the northwestern edge of the outcropping Elda Salt Sheet.
Based on the subsalt sedimentary and structural relationships we show that the Elda Salt Sheet advanced at least 8 km towards the north during the syn-orogenic Aquitanian – Langhian times before being buried during the latest Langhian - Serravallian times. This overall northward advance can be defined by six main phases. All the phases occur in submarine conditions in a carbonate ramp with water depths ranging from 10's to 100's of meters and are: (1) the extrusion of a salt sheet in an inner – outer carbonate ramp environment coeval to the onset of regional Oligocene-Miocene shortening corroborated by an Aquitanian aged flat and stranded intrasalt stringers along the subsalt flat; (2) Burdigalian-early Langhian burial of the salt sheet toe in an outer shelf – basinal environment where pinned inflation, and subsequent breakout of a confined salt sheet is evidenced by a hectometric halokinetic fold ramp and rafts of Burdigalian stratigraphy above the salt sheet. (3) early-middle Langhian rapid lateral advance of the salt sheet along a base salt flat which occurred in a deepwater basinal environment; (4) middle-late Langhian hindrance of the salt advance, development of subsalt decametric thick and decametric spaced halokinetic fold ramps in a basinal – outer shelf environment; (5) late Langhian salt sheet burial by shallow water carbonates and deepwater basinal marlstones; and (6) subsidence of secondary minibasins. These stages reflect a detailed history of a salt sheet lineage. This field-based study documents for the first time the structural and stratigraphic architecture of a subaqueous salt sheet lineage in a contractional setting.
东部前bebetics是伊比利亚东南部bebetic褶皱冲断带的外部带的一部分,在那里出现了大量的盐构造,包括:底辟、异质片、焊缝、初级和次级迷你盆地和筏体。本研究以鄂尔达盐片早至中新世中期盐下同收缩地层为研究对象,旨在记录异位盐推进过程中的亚地震尺度形变和盐-沉积相互作用。利用地层剖面、盐动力褶皱分析、地质野外填图和有孔虫测年等方法,对露头埃尔达盐片西北缘接触的盐下沉积物进行了表征。根据盐下沉积和构造关系,我们认为埃尔达盐片在同造山期阿基坦期-朗吉安期向北移动了至少8公里,然后在朗吉安期-塞拉瓦利期晚期被掩埋。整个向北推进可以分为六个主要阶段。所有阶段都发生在海底条件下的碳酸盐岩斜坡中,水深10 ~ 100米,它们是:(1)内-外碳酸盐岩斜坡环境中盐片的挤压,与区域渐新世-中新世缩短的开始同时发生,由阿基坦期老化的平原和沿盐下平原搁浅的盐内细带证实;(2)布尔底亚—朗喜期早期盐片趾埋于外陆架—盆地环境中,在此环境中抑制了暴胀,随后形成了封闭盐片的破裂,盐片上方的布尔底亚地层形成了等温盐动褶皱斜坡和木筏。(3)陇县早中期盐片沿基底盐滩快速横向推进,形成于深水盆地环境;(4)陇西中晚期盐进阻碍,盐下十尺度厚度和十尺度间隔盐动褶皱斜坡发育;(5)陇县晚期盐层受浅水碳酸盐岩和深水盆地泥灰岩埋藏;(6)次生小型盆地沉降。这些阶段反映了盐层谱系的详细历史。这项基于野外的研究首次记录了收缩环境下水下盐片谱系的构造和地层结构。
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引用次数: 0
Corrigendum to “Trace and rare earth element signatures in microcrystalline aragonite as indicators of oil vs. methane seepage” [Mar. Pet. Geol. 182 (2025), 107534] “微晶文石中痕量和稀土元素特征作为石油与甲烷渗漏指标”的勘误表[3 . Pet]。地球物理学报,2002,23(5):534 - 534。
IF 3.6 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-13 DOI: 10.1016/j.marpetgeo.2025.107603
Yuedong Sun , Shanggui Gong , Jörn Peckmann , Fang Chen , Yao Guan , Dong Feng
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引用次数: 0
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Marine and Petroleum Geology
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