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Investigation and In Vitro Studies of a ZrO2/g-C3N4 Composite Coated on 316L Stainless Steel for Biomedical Applications
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-06 DOI: 10.1002/maco.202414525
Manoja Tharmaraj, Abinaya Radhakrishnan, Anuradha Ramani, Nagarajan Srinivasan

The advancement of smart coatings for bioimplants has yielded a combination of biocompatibility and corrosion resistance. 316L stainless steel (316LSS) is a commonly used commercial implant, but it has limitations in biocompatibility and durability, which hinders the widespread utilization of 316LSS alloys. In this study, the 316LSS alloy is coated with a mixture of zirconium dioxide (ZrO2), prepared using the sol–gel method, and graphitic carbon nitride (g-C3N4), synthesized by thermal polymerization. XRD and Raman analyses confirmed the crystal structure and purity of the synthesized samples. The corrosion resistance property was assessed using OCP, POL, and PEIS. The findings demonstrate that the ZrO2/g-C3N4-coated 316LSS shows significantly enhanced corrosion resistance and biocompatibility in a simulated body fluid. The in vitro bioactivity test reveals that the ZrO2/g-C3N4 coating leads to the formation of an apatite layer over the surface of 316LSS. The elemental composition of the HAP deposition was confirmed by Raman analysis. The results suggested that the ZrO2/g-C3N4–coated 316LSS substrate is a promising material for use in biomedical applications.

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引用次数: 0
Ant-Nest Corrosion in Copper Pipes Triggered by Ethylene Vinyl Acetate-Based Adhesive
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-06 DOI: 10.1002/maco.202414559
Luca Cozzarini, Lucia Marsich, Alessio Ferluga

Corrosion of condenser circuits in refrigeration systems significantly impacts appliance reliability and longevity. This study investigates an unreported cause linked to changing adhesive materials during copper pipe assembly. Transitioning from a polyethylene-based adhesive to one containing ethylene vinyl acetate caused unexpected perforation of copper coils within months. We hypothesized that even trace amounts of acetic acid, a byproduct of the latter adhesive, trigger a peculiar localized morphology known as “ant-nest corrosion.” We propose using ethylene vinyl acetate-free adhesives to prevent this issue in refrigeration systems.

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引用次数: 0
Synergistic Effect of Sn Doping in TiO2 Nanoparticles as an Additive in Anti-Corrosion Coatings
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-06 DOI: 10.1002/maco.202414492
Fariza Abdul Rahman, Wan Jefrey Basirun, Mohd Rafie Johan

Corrosion is a major problem and protective coatings offer an effective solution. However, organic coatings are often associated with microcracks caused by the evaporation of solvents during coating preparation. This study investigates the use of titanium dioxide (TiO2) nanoparticles as a coating additive to protect mild steel surfaces. Additionally, doping TiO2 with tin (Sn) is believed to enhance its properties due to the reduced size of the nanoparticles. These nanoparticles were synthesised using the sol–gel method and subjected to various analyses. The coated mild steel samples were prepared using the dip-coating method and immersed in 3.5 wt.% sodium chloride (NaCl) solution for 30 days. Electrochemical impedance spectroscopy (EIS) and Tafel polarisation showed that the Sn-doped TiO2 nanoparticles as an additive improved the corrosion resistance, as evidenced by a positive shift in corrosion potential (Ecorr) and reduced corrosion current density (Icorr).

{"title":"Synergistic Effect of Sn Doping in TiO2 Nanoparticles as an Additive in Anti-Corrosion Coatings","authors":"Fariza Abdul Rahman,&nbsp;Wan Jefrey Basirun,&nbsp;Mohd Rafie Johan","doi":"10.1002/maco.202414492","DOIUrl":"https://doi.org/10.1002/maco.202414492","url":null,"abstract":"<div>\u0000 \u0000 <p>Corrosion is a major problem and protective coatings offer an effective solution. However, organic coatings are often associated with microcracks caused by the evaporation of solvents during coating preparation. This study investigates the use of titanium dioxide (TiO<sub>2</sub>) nanoparticles as a coating additive to protect mild steel surfaces. Additionally, doping TiO<sub>2</sub> with tin (Sn) is believed to enhance its properties due to the reduced size of the nanoparticles. These nanoparticles were synthesised using the sol–gel method and subjected to various analyses. The coated mild steel samples were prepared using the dip-coating method and immersed in 3.5 wt.% sodium chloride (NaCl) solution for 30 days. Electrochemical impedance spectroscopy (EIS) and Tafel polarisation showed that the Sn-doped TiO<sub>2</sub> nanoparticles as an additive improved the corrosion resistance, as evidenced by a positive shift in corrosion potential (<i>E</i><sub>corr</sub>) and reduced corrosion current density (<i>I</i><sub>corr</sub>).</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 2","pages":"295-304"},"PeriodicalIF":1.6,"publicationDate":"2024-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Masthead: Materials and Corrosion. 10/2024 刊头:材料与腐蚀10/2024
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-03 DOI: 10.1002/maco.202470102
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引用次数: 0
Cover Picture: Materials and Corrosion. 10/2024 封面图片:材料与腐蚀10/2024
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-03 DOI: 10.1002/maco.202470101
Daniel Blücher, Torstein Lange, Judit Sandquist, Inge Saanum, Mikko Uusitalo

Cover:

Optical microscopy images of as tested C-276 C-rings. Pitting corrosion was evident on the stressed inner edge of the C-rings and on the surface. A more detailed analysis showed that also intercrystalline corrosion had taken place with the loss of occasional grains because of the applied stress in combination with corrosion.

More detailed information can be found in: Daniel Blücher, Torstein Lange, Judit Sandquist, Inge Saanum, Mikko Uusitalo, Corrosion performance of different alloys exposed to HTL conditions—a screening study, Materials and Corrosion 2024, 75, 1258.

封面:经测试的 C-276 C 形环的光学显微镜图像。在 C 形环的受力内缘和表面上,点状腐蚀非常明显。更详细的分析表明,由于外加应力和腐蚀的共同作用,晶间腐蚀也随晶粒的脱落而发生:Daniel Blücher, Torstein Lange, Judit Sandquist, Inge Saanum, Mikko Uusitalo, Corrosion performance of different alloy exposed to HTL conditions-a screening study, Materials and Corrosion 2024, 75, 1258.
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引用次数: 0
Contents: Materials and Corrosion. 10/2024 内容:材料与腐蚀。10/2024
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-03 DOI: 10.1002/maco.202470103
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引用次数: 0
Optical Surface Roughness Estimation Using Artificial Intelligence
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-29 DOI: 10.1002/maco.202414564
Jacob Maxa, Mathias Nowottnick

A system for analysing steel plates is presented for an application in the wind power industry. The objective of the system is to assess the surface roughness as a preliminary step for the application of an anti-corrosion coating. A number of noncontact sensor systems were considered, with the laser triangulation scanner proving to be the optimal solution. The samples are analysed in a test stand and the roughness is measured with this optical system. At the same time, the surface is recorded with a CMOS camera. An AI model is created from the sensor fusion of both systems, which can classify individual segments of the surface as well or poorly blasted. In the following step, the surface roughness is estimated as the Rz parameter by another AI model. An error of less than 6 μm is achieved.

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引用次数: 0
Numerical Simulation on Cathodic Protection Potential Distribution Along Horizontal Directional Drilling Pipe
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-20 DOI: 10.1002/maco.202414513
Dawei Zhuang, Yanxia Du, Dezhi Tang, Chen Du

Evaluating the cathodic protection (CP) effectiveness of horizontal directional drilling (HDD) pipe is a significant technical challenge, due to the feasibility of testing only in shallow buried areas at entry/exit extremities, and not in deeply buried areas or the crossing section of the pipe. Numerical simulation provides a method to evaluate the CP effectiveness of HDD pipes. To improve the accuracy of potential distribution along the HDD pipe, it is necessary to adopt appropriate boundary conditions of the HDD pipe and accurate holiday models of coating. A specialized deep well polarization test device was designed and employed in the field to obtain the actual polarization characteristics as the boundary condition of the HDD pipe at buried depths ranging from 2 to 25 m. The result revealed that the polarization characteristics of HDD pipe in various depths were different and the potential distribution of the actual situation was greatly different from the potential distribution of the shallow aerobic soil. The potential distribution along the HDD pipe was analyzed in two types of holiday models. The results could be used as a reference for the CP effectiveness evaluation of HDD pipes.

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引用次数: 0
On the Impact of Cathodic Polarization on the Chloride Threshold of Carbon Steel in Alkaline Solutions 论阴极极化对碱性溶液中碳钢氯化物阈值的影响
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-12 DOI: 10.1002/maco.202414601
Konstantin Fache, Sylvia Keßler, Jörg Harnisch

This study investigates the influence of cathodic polarization on the chloride threshold (CT) for carbon steel in alkaline solutions, analogous to reinforcing steel embedded in concrete, with a focus on the electrochemical steel potential as a critical factor for corrosion initiation. The research, incorporating a literature review and potentiostatic tests, reveals that CT shows potential independence at potentials more anodic than −200 mVSCE and increases for potentials more cathodic than −200 mVSCE. The observed increase in CT under cathodic polarization is attributed to alterations in the passive layer composition, supporting the existence of distinct potential regions that govern the onset of corrosion.

本研究调查了阴极极化对碱性溶液中碳钢氯化物阈值(CT)的影响,类似于埋入混凝土中的钢筋,重点是作为腐蚀起始关键因素的电化学钢势。这项研究结合了文献综述和恒电位测试,揭示了在阳极电位高于 -200 mVSCE 时,CT 与电位无关,而在阴极电位高于 -200 mVSCE 时,CT 会增加。在阴极极化条件下观察到的 CT 增加可归因于被动层成分的改变,从而证明存在不同的电位区域来控制腐蚀的发生。
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引用次数: 0
Research on Pulse Current Cathodic Protection Technology for Long-Distance Pipeline: A Review 长输管道脉冲电流阴极保护技术研究:综述
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-11 DOI: 10.1002/maco.202414557
Qiudie Zhao, Hongfu Li, Xiaowu Luo, Yanjie Shi, Jian Li, Chen Wang, Yanming Liu, Xianghong Lv

As an important infrastructure for oil and gas transportation, the safe and stable operation of long-distance pipelines is significant for guaranteeing national energy security and economic development. However, pipelines are susceptible to corrosion due to various factors. Therefore, it is crucial to take effective corrosion protection measures. Pulse current cathodic protection technology, as an advanced pipeline corrosion protection technology, is superior to traditional cathodic protection technology. This paper mainly summarizes the research progress of pulse current cathodic protection technology for long-distance pipelines in recent years. It briefly discusses the protection mechanism, characteristic parameters, challenges, and development trends of pulse current cathodic protection technology, which provides a useful reference for the further promotion and application of pulse current cathodic protection technology for long-distance transport pipelines.

作为油气运输的重要基础设施,长输管道的安全稳定运行对保障国家能源安全和经济发展意义重大。然而,由于各种因素的影响,管道很容易受到腐蚀。因此,采取有效的防腐措施至关重要。脉冲电流阴极保护技术作为一种先进的管道腐蚀防护技术,具有传统阴极保护技术的优越性。本文主要总结了近年来长输管道脉冲电流阴极保护技术的研究进展。简要论述了脉冲电流阴极保护技术的保护机理、特性参数、面临的挑战和发展趋势,为长输管道脉冲电流阴极保护技术的进一步推广和应用提供了有益的参考。
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引用次数: 0
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Materials and Corrosion-werkstoffe Und Korrosion
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