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Contents: Materials and Corrosion. 5/2024 内容:材料与腐蚀。5/2024
IF 1.8 4区 材料科学 Q2 Materials Science Pub Date : 2024-05-01 DOI: 10.1002/maco.202470053
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引用次数: 0
Mechanistic insights into chemical corrosion of AA1050 in ethanol-blended fuels with water contamination via phase field modeling 通过相场建模深入了解水污染乙醇混合燃料中 AA1050 的化学腐蚀机理
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-24 DOI: 10.1002/maco.202414388
Eugen Gazenbiller, Visheet Arya, Rüdiger Reitz, Matthias Oechsner, Mikhail L. Zheludkevich, Daniel Höche

Aluminum alloys are widely used in automotive construction, and since the introduction of biogenic ethanol into fuels, the issue of nonaqueous alcoholate corrosion has become an important topic. In this paper, the kinetics of AA1050 temperature-induced alcoholate pitting corrosion are examined experimentally with a specially constructed microreactor. The generated data are utilized to create a phase field model for the pit growth phase. The effects of ethanol-blend composition and water content are quantitatively assessed and simulated. Phase field simulations allow for the first time the mechanistic characterization of the chemical corrosion process with a water content of up to 0.3% and an estimation of relevant reaction parameters at temperatures of up to 150°C. The approach can further be utilized to develop strategies for minimizing corrosion risk in-service.

铝合金被广泛应用于汽车制造,自从燃料中引入生物乙醇以来,非水醇酸腐蚀问题已成为一个重要课题。本文利用专门建造的微反应器对 AA1050 温度诱发的醇酸点腐蚀动力学进行了实验研究。利用生成的数据建立了凹坑生长阶段的相场模型。对乙醇混合物成分和水含量的影响进行了定量评估和模拟。相场模拟首次对含水量高达 0.3% 的化学腐蚀过程进行了机理分析,并估算了温度高达 150°C 时的相关反应参数。该方法可进一步用于制定最大限度降低在役腐蚀风险的策略。
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引用次数: 0
Electrochemical characterization of surfaces of galvanized steels under different exposure conditions using gel electrolytes 使用凝胶电解质分析不同暴露条件下镀锌钢表面的电化学特性
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-17 DOI: 10.1002/maco.202414389
Andreas Heyn, Moritz Meist, Oliver Michael, Martin Babutzka, Svenja Valet, Gino Ebell

The corrosion behavior of galvanized steels and zinc components under atmospheric exposure depends mostly on the corrosion product-based cover layer formation under the prevailing conditions. The use of agar-based gel electrolytes makes it possible to use electrochemical methods to obtain a characteristic value from these cover layers that describe their current and future protective capacity. It is shown here that different states of galvanized steel can be distinguished very well under laboratory conditions and that this method is also suitable for use under practical conditions. Based on the characteristic values and assuming future time of wetness, it is very easy to draw up a forecast for the future corrosion rate, which provides plausible values.

镀锌钢和锌部件在大气暴露下的腐蚀行为主要取决于腐蚀产物在当时条件下形成的覆盖层。使用琼脂基凝胶电解质可以通过电化学方法获得这些覆盖层的特征值,从而描述其当前和未来的保护能力。实验表明,在实验室条件下可以很好地区分镀锌钢的不同状态,而且这种方法也适合在实际条件下使用。根据特征值并假设未来的潮湿时间,很容易得出未来腐蚀率的预测值,从而提供可信的数值。
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引用次数: 0
Corrosion behavior of two Cu-based shape memory alloys in NaCl solution: An electrochemical study 两种铜基形状记忆合金在氯化钠溶液中的腐蚀行为:电化学研究
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1002/maco.202314227
Roberto Spotorno, Elisa Fracchia, Christian Krancher, Romina Krieg, Ralf Theiß, Peter Dültgen, Francesco Marco Pezzana, Federico Simone Gobber, Marco Actis Grande, Paolo Piccardo

The corrosion behavior of two different Cu–Al–Mn–Ni alloys, pseudoelastic and pseudoplastic, was studied in a 0.6 M sodium chloride aqueous solution by monitoring the open circuit potential for 100 h and characterizing the resulting corrosion products. Electrochemical impedance spectroscopy analysis detected three processes related to the electrochemical double layer, a passive film and a diffusive contribution associated with the dissolution/precipitation of corrosion products. Potentiodynamic scans revealed a cathodically controlled corrosion mechanism and the presence of active–passive behavior at anodic potentials for both alloys studied. Polarization of the samples at selected potentials in the anodic branch allowed the investigation of the reactions involved, highlighting an improved corrosion resistance of the pseudoelastic alloy. The corrosion rates of the pseudoelastic and pseudoplastic alloys, after 100 h of immersion, were determined to be 0.007 and 0.011 mmpy, respectively. The post-experiment characterization was carried out by means of scanning electron microscopy, micro-Raman spectroscopy and X-ray diffraction, supporting the electrochemical results.

通过对开路电位进行 100 小时的监测,研究了两种不同的铜-铝-锰-镍合金(假弹性和假塑性)在 0.6 M 氯化钠水溶液中的腐蚀行为,并对由此产生的腐蚀产物进行了表征。电化学阻抗光谱分析检测到了与电化学双层、被动膜和与腐蚀产物溶解/沉淀相关的扩散作用有关的三个过程。电位动力扫描显示,所研究的两种合金都存在阴极控制的腐蚀机制和阳极电位下的主动-被动行为。在阳极分支的选定电位下对样品进行极化,可以研究其中涉及的反应,突出表明假弹性合金的耐腐蚀性更好。假弹性合金和假塑性合金在浸泡 100 小时后的腐蚀速率分别为 0.007 和 0.011 mmpy。实验后通过扫描电子显微镜、显微拉曼光谱和 X 射线衍射进行了表征,为电化学结果提供了支持。
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引用次数: 0
Corrosion and carburization of Ni3Al-based superalloys in high-temperature carbon dioxide 高温二氧化碳中 Ni3Al 基超合金的腐蚀和渗碳现象
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1002/maco.202414357
Hexin Zhang, Yanwen Sun, Yihan Zhao, Youshui Xie, Xiaopeng Li, Yuqi Wang, Chengzhi Zhao

To investigate the application of Ni3Al-based superalloys in gas turbine cycle systems, this experiment exposed Ni3Al-based superalloys to a 600°C/5 MPa environment with 99.995% pure CO2 gas. The corrosion and carburization behaviors and mechanisms were investigated in detail. The results reveal that with prolonged thermal exposure, the surface oxides of the samples tend to develop a continuous and homogeneous transition state alumina layer. This layer serves as a protective barrier, preventing the penetration and corrosion of external carbon-containing and oxygen-containing substances into the matrix. A small amount of carbon-containing hazardous substances still penetrates the oxide layer or grain boundaries through highly diffusive pathways such as nanochannels, pores, and cracks, because the transition state of alumina is not completely dense. This leads to carbon deposition at the interface between the oxide layer and the matrix, where a mixture of alumina and amorphous carbon is formed at the interface.

为了研究 Ni3Al 基超耐热合金在燃气轮机循环系统中的应用,本实验将 Ni3Al 基超耐热合金暴露在 600°C/5 MPa 的环境中,其中含有 99.995% 的纯 CO2 气体。实验详细研究了腐蚀和渗碳行为及机理。结果表明,随着长时间的热暴露,样品的表面氧化物往往会形成一层连续均匀的过渡态氧化铝层。这层氧化铝起到保护屏障的作用,防止外部含碳和含氧物质渗入基体并造成腐蚀。由于过渡态氧化铝并非完全致密,少量含碳有害物质仍会通过纳米通道、孔隙和裂缝等高扩散途径渗入氧化层或晶界。这导致碳沉积在氧化层和基体之间的界面上,在界面上形成氧化铝和无定形碳的混合物。
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引用次数: 0
Self-healing polyurethane anticorrosive coatings based on alkyd resin microcapsules 基于醇酸树脂微胶囊的自修复聚氨酯防腐涂料
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1002/maco.202314244
Bin Xie, Hongwei Shi, Yingwei Song, En-Hou Han

In this paper, self-healing microcapsules were prepared by in situ polymerization using poly(vinyl alcohol) as the emulsifier, urea-formaldehyde resin as the shell material, and alkyd resin as the core material. The average diameter of the obtained microcapsules was about 20 μm and the encapsulation rate of alkyd resin was 50.7 wt.%. The self-healing coating was prepared by adding 5 wt.% of microcapsules to the pure polyurethane coating and then coated on AA2024-T3 substrate. The self-healing effect was evaluated by scanning electron microscopy. Electrochemical impedance spectroscopy tests and neutral salt spray tests confirmed that the self-healing coating had good anticorrosion properties.

本文以聚乙烯醇为乳化剂,脲醛树脂为壳材料,醇酸树脂为芯材料,通过原位聚合制备了自修复微胶囊。得到的微胶囊平均直径约为 20 μm,醇酸树脂的封装率为 50.7 wt.%。在纯聚氨酯涂层中加入 5 重量百分比的微胶囊,制备出自愈合涂层,然后涂覆在 AA2024-T3 基材上。通过扫描电子显微镜评估了自愈合效果。电化学阻抗谱测试和中性盐雾测试证实自修复涂层具有良好的防腐性能。
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引用次数: 0
The effect of partial recrystallization on the corrosion resistance of EN AW6082 forged components evaluated with different tests 通过不同试验评估部分再结晶对 EN AW6082 锻造部件耐腐蚀性的影响
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1002/maco.202414354
Silvia Cecchel, Marcello Gelfi, Giovanna Cornacchia

Structural automotive components are extensively made of aluminum alloy forgings, due to the elevate strength and low weight required. These products are frequently subjected to recrystallization. Recrystallization, often limited to surface or forging portions, is expected to reduce its tensile strength and corrosion resistance, but the literature is scarce on this subject. For a more comprehensive understanding, the present research studied the corrosion behavior of samples collected from EN AW 6082-T6 forged components, designed to expose both recrystallized and not recrystallized surfaces to the corrosive environment. Several standardized corrosion tests (i.e., PV 1113, ISO 11846, and VW 96380) were applied to assess the most representative with respect to real field exposure. Tensile tests were performed in four different conditions, recrystallized and not recrystallized specimens in an as-forged state or after corrosion. The recrystallization led to a reduction in tensile properties, but this gap was compensated by a higher corrosion resistance than the not recrystallized samples. Consequently, the mechanical properties became comparable after the corrosion test.

由于铝合金锻件具有强度高、重量轻的特点,因此汽车结构件广泛采用铝合金锻件。这些产品经常会发生再结晶。再结晶通常仅限于表面或锻造部分,预计会降低其抗拉强度和耐腐蚀性,但这方面的文献很少。为了更全面地了解这一问题,本研究对从 EN AW 6082-T6 锻造部件中收集的样品的腐蚀行为进行了研究,旨在将再结晶和未再结晶的表面暴露在腐蚀环境中。采用了几种标准化腐蚀测试(即 PV 1113、ISO 11846 和 VW 96380),以评估与实际现场暴露有关的最具代表性的测试。拉伸试验在四种不同的条件下进行,即在锻造状态下或腐蚀后的再结晶和未再结晶试样。再结晶导致拉伸性能下降,但与未再结晶样品相比,较高的耐腐蚀性弥补了这一差距。因此,腐蚀试验后的机械性能变得相当。
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引用次数: 0
Stress corrosion tests for prestressing steels—Part 1: The influence of surface condition and test solution composition on hydrogen charging 预应力钢材的应力腐蚀试验--第 1 部分:表面条件和试验溶液成分对充氢的影响
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1002/maco.202313948
Lando Seifert, Andreas Grunewald, Thoralf Müller, Gino Ebell

Tests for assessing prestressing steels' susceptibility to hydrogen-induced stress corrosion cracking are essential for approvals, in-house monitoring, and third-party material testing. According to ISO 15630-3, the time to brittle fracture by constant load under corrosive conditions in thiocyanate test solutions (A or B) at 50°C is measured. In the literature, a high scattering in stress corrosion tests is reported, which questions the integrity of the test procedure. This paper shows the results of studies about the influence of solution composition on hydrogen charging in electrochemical and permeation measurements. Electrochemical experiments show that polished steel surfaces without common drawing layers have more consistent free corrosion currents, polarization resistances, and B-values in solution A with low scattering compared to the solution B experiments. The influence of temperature at 50°C and an ambient temperature of 22°C was also tested.

评估预应力钢材对氢诱导应力腐蚀开裂敏感性的测试对于审批、内部监控和第三方材料测试至关重要。根据 ISO 15630-3,在 50°C 的硫氰酸盐测试溶液(A 或 B)中,在腐蚀条件下通过恒定载荷测量脆性断裂的时间。据文献报道,应力腐蚀试验中的散射率很高,这对试验程序的完整性提出了质疑。本文展示了在电化学和渗透测量中溶液成分对氢充电影响的研究结果。电化学实验表明,与 B 溶液实验相比,没有普通拉丝层的抛光钢表面在散射较低的 A 溶液中具有更一致的自由腐蚀电流、极化电阻和 B 值。此外,还测试了温度在 50°C 和环境温度 22°C 时的影响。
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引用次数: 0
Effects of external corrosion defect growth on wall pipeline under internal pressure and various defect sizes with mechano-electrochemical interaction 内压和不同缺陷尺寸下机械-电化学相互作用对管壁外部腐蚀缺陷生长的影响
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-12 DOI: 10.1002/maco.202414391
Wei Zhang, Xiaoqian Fu, Minglei Hu, Ke Xu, Kunjie Dai, Jingkun Shi, Yucheng Ji, Chaofang Dong

The assessment of the impact of corrosion defects on the integrity and safe operation of through-wall pipelines is critical. In this work, a finite element-based model was developed to study the mechano-electrochemical (M-E) effects of external corrosion defects on 10CrMoAl steel pipelines. The effects of parameters such as defect sizes and internal pressures on pipeline conditions are also studied. The results show that increased corrosion depth leads to stress concentration at the center of the defect. The increase in internal pressure causes local plastic deformation and anodic current density concentration at the inner edge of the defect and in the adjacent areas of the defect. M-E interaction causes the growth of corrosion defects significantly at higher internal pressures. The corrosion defects increase with time. As the pressure increases, the failure pressure of the pipeline gradually decreases. The influence of defect depth on the corrosion rate at the defect is greater than that of defect width. With increasing in internal pressure and corrosion defect size, it will lead to more severe plastic deformation, resulting in accelerated corrosion.

评估腐蚀缺陷对穿墙管道完整性和安全运行的影响至关重要。在这项工作中,开发了一个基于有限元的模型,用于研究外部腐蚀缺陷对 10CrMoAl 钢管道的机械-电化学(M-E)影响。同时还研究了缺陷尺寸和内部压力等参数对管道状况的影响。结果表明,腐蚀深度增加会导致应力集中在缺陷中心。内部压力的增加导致局部塑性变形,阳极电流密度集中在缺陷内边缘和缺陷邻近区域。在较高的内部压力下,M-E 相互作用导致腐蚀缺陷显著增加。腐蚀缺陷随着时间的推移而增加。随着压力的增加,管道的失效压力逐渐降低。缺陷深度对缺陷处腐蚀速率的影响大于缺陷宽度。随着内压和腐蚀缺陷尺寸的增大,会导致更严重的塑性变形,从而加速腐蚀。
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引用次数: 0
Developing a self-healing anticorrosion coating for steel protection in marine tidal zone 开发用于海洋潮汐区钢材保护的自修复防腐涂层
IF 1.6 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-10 DOI: 10.1002/maco.202314174
Navid Atazadeh, Farhad Shahriari Nogorani

A self-healing anticorrosion protective was developed for steel st-37 exposed to the marine tidal zone, which is composed of a multi-layer polymer coating. The coating includes zinc-rich epoxy primer, self-healing microencapsulated embedded epoxy, and a top coat consisting of polyurethane incorporated with silica nanoparticles. The size of microcapsules decreased with increasing agitation during encapsulation, which varies from 4 to 43 µm. Good performance was observed for producing the encapsulated particles with a size of up to 5 µm and more than 90% loading of the embedded healing agent, in which a 1680 rpm agitation along with a pH of 3 for the synthesis environment and a 130 min for the synthesis duration is set. The optimal amount of microcapsules and silica nanoparticles was 10 and 1.5 wt%, respectively. Also, the promised self-healing anticorrosion coating leads the damaged areas to be fully healed in almost 12 h in the face of harsh conditions. In contrast to the non-self-healing one, the healing ability of the developed self-healing coating shows good barrier properties and leads to a lesser loss of interface adhesion.

为暴露在海洋潮汐区的钢 st-37 开发了一种由多层聚合物涂层组成的自修复防腐保护层。涂层包括富锌环氧底漆、自愈合微胶囊嵌入式环氧树脂和由聚氨酯与纳米二氧化硅颗粒组成的面漆。在封装过程中,微胶囊的尺寸随着搅拌次数的增加而减小,从 4 微米到 43 微米不等。在合成环境 pH 值为 3、合成持续时间为 130 分钟的条件下,1680 转/分钟的搅拌速度和 3 的 pH 值都能产生尺寸达 5 微米的封装颗粒,且嵌入的愈合剂的负载量超过 90%。微胶囊和二氧化硅纳米颗粒的最佳用量分别为 10 和 1.5 wt%。此外,承诺的自愈合防腐涂层可使受损区域在近 12 小时的恶劣条件下完全愈合。与非自愈合涂层相比,所开发的自愈合涂层的愈合能力显示出良好的阻隔特性,并导致较少的界面附着力损失。
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引用次数: 0
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