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An innovative method for anchoring glucose-sensing molecules on glassy micro-particles 一种将葡萄糖传感分子锚定在玻璃微粒上的创新方法
Pub Date : 2020-10-26 DOI: 10.15406/MSEIJ.2020.04.00140
M. Frechero, Marianela Zoratti, M. E. Centurión
In this work a modified glassy micro-particles glucose sensor was developed applying a new and effective procedure to anchor glucose oxidase on glassy micro particles using urea medium. The resulting sensor, in the presence of glucose, generates a color development in 60 seconds working at room temperature. The intensity of the resulting color shows a straightforward relationship with the glucose concentration in the samples tested. The resulting biosensor was tested to demonstrate its sensibility on dissolutions of glucose and honey.
本文采用一种新的、有效的方法,利用尿素将葡萄糖氧化酶锚定在玻璃微颗粒上,研制了一种改进的玻璃微颗粒葡萄糖传感器。这种传感器在葡萄糖的存在下,在室温下工作60秒就能显色。所得颜色的强度与测试样品中的葡萄糖浓度有直接的关系。所得到的生物传感器进行了测试,以证明其对葡萄糖和蜂蜜溶解物的敏感性。
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引用次数: 0
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne 氧化石墨作为钯和铑配合物的载体,作为1-庚烷部分氢化的催化剂
Pub Date : 2020-08-13 DOI: 10.15406/MSEIJ.2020.04.00136
Quiroga Me, L. da, Cagnola Ea, Á. Mastalir, T. Szabó, J. Paredes, L. MartínezBovier, C. Betti
Graphite oxide (GO) was used to anchor [PdCl 2 (TDA) 2 ] and [RhCl(TDA) 3 ] (TDA = NH 2 (CH 2 ) 12 CH 3 ) with 2wt % of metal load. Elemental analysis (EA), FTIR, XPS, XRD and atomic absorption spectroscopy (AA) were the techniques employed for characterization. FTIR and XRD revealed that both complexes were mainly immobilized on the GO surface. The partial hydrogenation of 1-heptyne was the test reaction to evaluate the catalytic behavior of these heterogenized complexes under mild conditions of temperature and pressure in a semi continuous process. The results were compared with those obtained with the Wilkinson catalyst under the same operational conditions. AA analysis revealed that there is no leaching of the complexes during the heterogeneous catalytic evaluations. [RhCl(TDA) 3 ]/GO was the best catalyst due to electronic and steric effects as well as the influence of the support.
用氧化石墨(GO)锚定[PdCl 2 (TDA) 2]和[RhCl(TDA) 3] (TDA = nh2 (ch2) 12 ch3),金属载荷为2wt %。采用元素分析(EA)、FTIR、XPS、XRD和原子吸收光谱(AA)等技术进行表征。FTIR和XRD分析表明,这两种配合物主要固定在氧化石墨烯表面。以1-庚烷的部分加氢反应为试验反应,在温和的温度和压力条件下,在半连续过程中评价了这些多相配合物的催化性能。并与相同操作条件下使用威尔金森催化剂的结果进行了比较。AA分析表明,在非均相催化评价过程中,配合物没有浸出。[RhCl(TDA) 3]/GO为最佳催化剂,受电子效应、位阻效应及载体的影响。
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引用次数: 0
A mean stress model of fatigue life of metal materials under multiaxial loading 多轴载荷下金属材料疲劳寿命的平均应力模型
Pub Date : 2020-03-04 DOI: 10.22541/au.158334209.96566671
Xiangqiao Yan
In this note, a linear mean stress model is presented on basis of the multiaxial model of fatigue life of metal materials proposed by Liu and Yan. By using the experimental data of fatigue life of metal materials reported in the literature, the model is systematically validated.
本文在Liu和Yan提出的金属材料疲劳寿命多轴模型的基础上,提出了线性平均应力模型。利用文献报道的金属材料疲劳寿命试验数据,对模型进行了系统验证。
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引用次数: 0
Efficacy of surface modification by layer-by-layer loading for drug delivery 一层一层装载药物的表面修饰效果
Pub Date : 2020-01-01 DOI: 10.15406/MSEIJ.2020.04.00128
O. Olaniran
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引用次数: 0
Improvement of fatigue and rutting performance with different base treatments 不同基底处理对疲劳和车辙性能的改善
Pub Date : 2020-01-01 DOI: 10.15406/MSEIJ.2020.04.00138
Mena I. Souliman, N. R. Bastola, W. Zeiada
Pavement performance is a key parameter that governs the serviceability of road networks. This performance is heavily influenced by the pavement construction materials such as asphalt binder and aggregates. The use of proper aggregates results in enhanced structural stability and greater long-term performance of pavements. However, due to the rapid construction of roads around the world, aggregates used in the base layer are often treated with various stabilizing agents such as lime and cement. In this study, various mechanistic analyses are performed using the 3-D Move Analysis software to study their effect on rutting and fatigue resistance performance. The analysis showed that the use of stabilizing agents increased the pavement performance up to 96% for fatigue cracking and 34.4% for rutting compared to untreated base layers. The cost-effectiveness analysis also showed that the use of stabilizing agents would reduce the long-term cost of pavement as compared to untreated bases.
路面性能是决定道路网络可用性的关键参数。这种性能很大程度上受沥青粘结剂和集料等路面施工材料的影响。使用适当的集料可提高路面的结构稳定性和更大的长期性能。然而,由于世界各地道路的快速建设,用于基层的骨料通常用各种稳定剂处理,如石灰和水泥。在本研究中,利用三维运动分析软件进行了各种力学分析,以研究它们对车辙和抗疲劳性能的影响。分析表明,与未经处理的基层相比,稳定剂的使用可使路面性能提高96%,使车辙性能提高34.4%。成本效益分析还表明,与未经处理的基层相比,使用稳定剂可以降低路面的长期成本。
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引用次数: 0
Chemical compound formation and diffusion – as parallel processes in grain boundary 晶界中化合物形成与扩散的平行过程
Pub Date : 2020-01-01 DOI: 10.15406/MSEIJ.2020.04.00125
Petelin Al, Bokstein Bs, A. Novikov, Novikov Ea
The Fischer’s model1 is the base of the standard description of the diffusion along grain boundary (GB) with leakage to grain bulk. Various versions of calculation diffusant concentration field were realized: for self diffusion and hetero diffusion, with a grain boundary segregation2,3 and formation of atomic complexes in GB,4‒6 for various temperature areas7 and various structural types of GBs.8 It may seem strange, but the model describing influence of chemical processes in GB, which bind a part of diffusing atoms, on the rate of their moving in GB wasn’t developed. Though the experimental fact of grain boundary diffusion (GBD) delay due to precipitation of nanoparticles in GB is well-known, it is usually connected with the idea that fine particles which are formed in GB reduce the section of boundary and diffusive flux. The direction of this investigation is the development the Fisher’s model of GBD taking into account simultaneous chemical interaction of diffusive and matrix atoms in GB. The events of this kind – parallel carrying out two processes with participation of the same atoms – are well-known in heterogeneous kinetics.9 As a typical example of those processes it can be considered the steel nitration process.
Fischer模型1是沿晶界扩散(GB)的标准描述的基础。实现了不同版本的扩散剂浓度场的计算:自扩散和异扩散,具有晶界偏析2、3和原子配合物的形成,4-6适用于不同温度区域7和不同结构类型的GB这可能看起来很奇怪,但描述GB中化学过程影响的模型,这些过程结合了一部分扩散原子,对它们在GB中的移动速度的影响并没有发展起来。虽然纳米颗粒在晶界中析出导致晶界扩散延迟的实验事实是众所周知的,但这通常与在晶界中形成的细颗粒减少了晶界的截面和扩散通量有关。本研究的方向是发展考虑扩散原子和基体原子同时化学相互作用的GBD的Fisher模型。这类事件——在相同原子的参与下并行进行两个过程——在异质动力学中是众所周知的作为这些过程的一个典型例子,可以认为是钢的氮化过程。
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引用次数: 0
Fracture analysis and geometrical parameter optimization of bolted composite joints 螺栓复合材料接头断裂分析及几何参数优化
Pub Date : 2020-01-01 DOI: 10.15406/MSEIJ.2020.04.00146
C. Moganapriya, Gobinath Vk, A. Manjusri, S. Santhosh, T. Mugilan
Composite materials are commonly used in structures that demand a high level of mechanical performance. Due to high strength and safety requirements, these applications require joining composites either to composites or to metals. Composite joints create highly localized stress concentration around the joints that cause failure in the substrates. The fracture toughness is the critical aspect that influence on the failure of the substrates. In this work, fracture toughness is determined for a center crack developed on the surface of the substrate of the composite joints. In FEM analysis, Stress intensity factor (K) and J integral are used to find out the fracture toughness value. The influence of various parameters such as fiber orientation angle, crack length, applied load and bolt hole diameter on fracture toughness is determined with the use of LEFM in finite element analysis. Stress intensity factor and J integral are validated with the theoretical data available. Geometrical parameters which affect fracture toughness are optimized by using Taguchi analysis and design of experiments. The result shows that the crack length is the most significant parameter which affects the fracture toughness substantially. Elasto plastic region (dog bone shape) near the crack tip is also analyzed in this work.
复合材料通常用于对机械性能要求较高的结构中。由于高强度和安全要求,这些应用需要将复合材料连接到复合材料或金属上。复合接头在接头周围产生高度局部的应力集中,从而导致基体的破坏。断裂韧性是影响基体失效的关键因素。在这项工作中,确定了在复合材料接头基体表面形成的中心裂纹的断裂韧性。在有限元分析中,采用应力强度因子(K)和J积分计算断裂韧性值。采用有限元分析方法,确定了纤维取向角、裂纹长度、外加载荷、螺栓孔直径等参数对断裂韧性的影响。用已有的理论数据对应力强度因子和J积分进行了验证。采用田口分析和实验设计对影响断裂韧性的几何参数进行了优化。结果表明,裂纹长度是影响断裂韧性的最重要参数。本文还对裂纹尖端附近的弹塑性区域(犬骨形)进行了分析。
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引用次数: 1
Petroleum engineering defaults about excessive productions of crude oil especially OPEC countries and its implications about lack of national financial sustainability 石油工程违约的原油生产过剩,特别是欧佩克国家和它的影响缺乏国家财政的可持续性
Pub Date : 2020-01-01 DOI: 10.15406/mseij.2020.04.00137
P. E. Atatah, Catherine W. Kisavi-Atatah
Historically speaking, crude oil was first discovered in Beaumont, Texas in the early 20th century by a farmer who was tilling his land only to see black nasty and dirty oily substance floating from his farm. He called on the public health and environmental engineering officials to take some samples of the oil for further examination. Thereafter, the milestone of oil as one of the most valuable items worldwide was born. Precisely speaking, that is why majority of the rich and possibly competitive millionaires in the USA were from the state of Texas. The millionaires’ monies were so massive that it developed a saying that “When it is big, it is only big enough for Texas; and not necessarily due to the size of the state of Texas.” Yes indeed, it was big enough for Texas. And, this was how oil was first discovered in the state of Texas and the rest of the world were forced to play the roles of runners’ ups trying to catch with this historic race.
从历史上讲,原油最早是在20世纪初在德克萨斯州的博蒙特被一位农民发现的,他正在耕种他的土地,却发现他的农场漂浮着黑色肮脏的油性物质。他呼吁公共卫生和环境工程官员采集一些石油样本进行进一步检查。从此,石油作为世界上最有价值的物品之一的里程碑诞生了。准确地说,这就是为什么美国大多数富有的、可能具有竞争力的百万富翁都来自德克萨斯州。百万富翁的钱是如此之多,以至于形成了这样一种说法:“当它大的时候,它只够德克萨斯州;而不一定是因为德克萨斯州的面积。”是的,的确,它对德州来说足够大了。这就是为什么石油第一次在德克萨斯州被发现,世界其他地方被迫扮演赛跑者的角色,试图赶上这场历史性的比赛。
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引用次数: 0
Vibration of protein microtubules via scale-dependent continuum models 基于尺度依赖连续体模型的蛋白质微管振动
Pub Date : 2020-01-01 DOI: 10.15406/MSEIJ.2020.04.00132
A. Farajpour, M. R. Farajpour, A. Shahidi
Increasing the level of knowledge on the mechanics of biological structures such as protein microtubules is important because of two main reasons. The first reason is that the biological properties of living organisms are highly affected by their mechanical properties such as their elasticity modulus and resonance natural frequencies. Secondly, the mechanical properties and characteristics can be used as a clue in order to analyze the performance and functionality of a living organism. In this paper, the pioneering research studies on the vibrational behavior of protein microtubules as an important part of the cytoplasm are reviewed. Two widely used theoretical approaches, namely the pure nonlocal and nonlocal strain gradient models, are proposed. The natural frequencies of microtubules are strongly influenced by the stress nonlocality and the half wave number along the axial direction.
由于两个主要原因,提高对蛋白质微管等生物结构力学的认识水平非常重要。第一个原因是生物体的生物特性受到其力学特性的高度影响,例如它们的弹性模量和共振固有频率。其次,力学性能和特征可以作为线索,以分析一个生物体的性能和功能。本文综述了作为细胞质重要组成部分的蛋白质微管的振动行为的研究进展。提出了两种广泛使用的理论方法,即纯非局部应变梯度模型和非局部应变梯度模型。应力非定域性和轴向半波数对微管的固有频率有很大影响。
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引用次数: 0
Plate impact method for shock physics testing 冲击物理试验用板冲击法
Pub Date : 2020-01-01 DOI: 10.15406/MSEIJ.2020.04.00123
M. Elamin, J. Varga
Dynamic loading experiments under extreme testing conditions yield much different mechanical and chemical responses in materials when compared to those found under static conditions. Engineering applications of shock physics including ballistic and explosive impact, as well as any other sort of high energy collision, are found in a range of industries such as armor and weapons. The extreme temperatures and pressures at which shock physics experiments are able to test can simulate the response of radioactive materials during the detonation of nuclear weapons. It is therefore critically important to these industries to have an understand of the plastic response of materials at high temperatures and strain rates. An understanding of material responses is especially important for applications whereby shear bands are generated under extreme high strain rate conditions, such as in automotive and aerospace structures.1‒4 The foregoing serves as the motivation to investigate the appropriate experimental techniques that test the material responses to these conditions. One of the most common methods of investigating the behavior of materials subjected to a continuous deformation at high strain rates on the order of 105107s-1 is to perform shear plate impact experiments.5‒7 In a general plate impact experiment, a gas gun launches a plate projectile towards a thin, circular specimen sandwiched between two additional plates.8 The flyer plate lies in between the projectile and the specimen, while the anvil plate lies behind the specimen. Often, the flyer plate itself is used as the projectile, making direct contact with the specimen. The projectile is guided by a key running through a keyway within the gas gun barrel, keeping it from rotating. A typical schematic of an experiment is depicted in Figure 1.
在极端测试条件下的动态加载实验与在静态条件下的实验相比,在材料中产生了非常不同的机械和化学反应。冲击物理的工程应用包括弹道和爆炸冲击,以及任何其他类型的高能碰撞,在装甲和武器等一系列行业中都有发现。冲击物理实验能够测试的极端温度和压力可以模拟核武器爆炸时放射性物质的反应。因此,对这些行业来说,了解材料在高温和应变率下的塑性响应是至关重要的。对于在极端高应变率条件下产生剪切带的应用,例如在汽车和航空航天结构中,对材料响应的理解尤为重要。1-4上述内容是研究测试材料对这些条件反应的适当实验技术的动机。研究材料在105107s-1量级的高应变率下连续变形的行为的最常用方法之一是进行剪切板冲击实验。在一般的板冲击实验中,气体枪向夹在两个附加板之间的薄圆形试样发射板射弹飞片位于弹丸和试样之间,砧片位于试样后面。通常,飞片本身被用作弹丸,与试样直接接触。弹丸由一个穿过气枪枪管内键槽的键引导,使其不旋转。一个典型的实验示意图如图1所示。
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引用次数: 8
期刊
Material Science & Engineering International Journal
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