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Behavior of pile caps on one steel pile 钢桩承台性能分析
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00084
R. G. Delalibera, Marcell Godoi Sivelli, J. S. Giongo, V. F. Gonçalves, Márcio de Oliveira Filho
Piles are slender linear structural elements, whose purpose is to transfer the load from the superstructure to the soil. The connection between the piles and the superstructure is commonly done by pile caps that, according to the NBR 6118, are volumetric structures used to transfer the load coming from the superstructure to the piles. The first studies of great relevance, regarding the design of pile caps, are from Blévot & Frémy1 however, most of the researches on this area studied pile caps on reinforced concrete piles, leaving a vast field to be explored about pile caps on steel piles. According to Velloso & Lopes,2 the main disadvantage of using steel piles, in relation to other types of piles, is its high cost. Still, in some situations the use of steel piles is economically viable as they can be driven in almost any kind of soil and are highly effective against the vibration on the driving process. In agreement with NBR 6122,3 connection between the pile and the cap can be made with an embedment length of the pile in the cap of 20 centimeters and, in addition, a helical reinforcement may be used. After its review, the NBR 61224 suggests only that the connection must be made by using either steel plates on top of the piles, stirrups or steel rebar welded to the pile. Fundações Teoria e Prática5 recommends that a helical reinforcement is placed over the embedment length of the steel pile in the cap. Pfeil6 suggests that straight rebar must be welded over the embedment length of the steel pile, with the addition of helical reinforcement, and that the embedment length of the steel pile must be at least 30 centimeters.
桩是细长的线形结构构件,其作用是将上部结构的荷载传递给土体。桩与上部结构之间的连接通常由桩帽完成,根据NBR 6118,桩帽是用于将来自上部结构的荷载传递给桩的体积结构。对于承台的设计,最早有重要意义的研究来自blsamvot & frsammy1,但该领域的研究多是针对钢筋混凝土桩承台的设计,钢桩承台的设计还有广阔的领域有待探索。根据Velloso & Lopes的说法,与其他类型的桩相比,使用钢桩的主要缺点是成本高。尽管如此,在某些情况下,使用钢桩在经济上是可行的,因为它们几乎可以在任何类型的土壤中打入,并且在打入过程中对振动非常有效。根据NBR 6122的规定,桩与承台之间的连接可以采用桩在承台内埋设长度为20厘米的方式进行,此外还可以采用螺旋加固。经过审查,NBR 61224只建议连接必须通过在桩上使用钢板,箍筋或焊接到桩上的钢筋来实现。Fundações Teoria Prática5建议在承台钢桩预埋长度上方放置螺旋钢筋。Pfeil6建议在钢桩预埋长度上方焊接直钢筋,并添加螺旋钢筋,且钢桩预埋长度至少为30厘米。
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引用次数: 0
Vitrification and sinter-crystallization of fly ash with glass cullet 粉煤灰与玻璃渣的玻璃化和烧结结晶
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00112
Barrachina E, Stoyanova Lyubenova T, F. D., Calvet I, Carda Jb
Nowadays, in this second decade of this century, the industrial residues they continue generating environmental problems. Such of these wastes (glass cullet and bottom or fly ashes from the coal power stations) are still abundant and not definitive applications or solutions for its immobilizing have been given, though a considerable amount of research has been conducted in the last years. One of the promising applications proposed by laboratories research has been their potential for being used in the construction industry.1,2 With respect the glass cullet from the conventional glass there is abundant research carried out in the last decades of 20th and beginning of this 21st century.3–5 Vitrification process has been demonstrated is an adequate processing method for inertize toxic and abundant residues and even to facilitate their recycling as secondary raw materials in ceramics and glasses industries.6 Transforming of starting glasses after vitrification into glass-ceramics by controlled thermal treatment is possible to reach immobilizing of a wide range of industrial wastes (mineral residues, sludges from dumps, slags, ashes,). Besides, the low cost and great availability of waste make these glass-ceramics materials very attractive from an economical and technological point of view, so synthetic high-performance materials with broad applications in construction and civil engineering can be obtained from residues.7 Therefore, it has been the aim of this research to explore the synthesis of a new type of glass-ceramic by the sinter-crystallization process from soda-lime-silicate glass and several ashes from a coal power thermal station located in Andorra (Teruel, Spain). Materials and methods
在本世纪第二个十年的今天,工业残留物继续产生环境问题。这类废物(来自燃煤电厂的玻璃碎渣和底灰或飞灰)仍然很丰富,尽管在过去几年中进行了大量的研究,但尚未给出确定的应用或固定化方法。实验室研究提出的一个有前途的应用是它们在建筑工业中的应用潜力。关于传统玻璃的玻璃碎片,在20世纪最后几十年和21世纪初进行了大量的研究。玻璃化工艺已被证明是一种适当的处理方法,可以惰性化有毒和丰富的残留物,甚至可以促进它们作为陶瓷和玻璃工业的二次原料的回收利用通过控制热处理将玻璃化后的起始玻璃转化为玻璃陶瓷,可以实现各种工业废物(矿物残留物、垃圾场的污泥、炉渣、灰烬)的固定化。此外,从经济和技术的角度来看,低成本和高可利用性使得这些微晶玻璃材料非常有吸引力,因此,从渣滓中可以获得在建筑和土木工程中具有广泛应用的合成高性能材料因此,本研究的目的是探索以位于安道尔(Teruel,西班牙)的煤电热站的钠-石灰-硅酸盐玻璃和一些灰烬为原料,通过烧结结晶工艺合成一种新型玻璃陶瓷。材料与方法
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引用次数: 0
Shallow foundation analysis using the discrete element method 浅基础离散元法分析
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00104
Joaquim Araujo Costa Neto, Márcio Muniz de Farias, Bernardo Cascao Pires e Albuquerque, Jessica Soares da Rocha
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引用次数: 0
Mechanical and electrochemical behaviour of aluminum-based hybrid composites reinforced with silicon carbide and pride of barbardos seed ash produced by stir casting 搅拌铸造碳化硅增强铝基杂化复合材料的力学和电化学性能
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00110
O. Oladayo, Alege Kehinde Sikirat
Aluminum matrix composite (AMCs) represent a class of MMCs having characteristics of low density, high stiffness and strength, superior wear resistance, controlled co-efficient of thermal expansion, high fatigue resistance and better stability at elevated temperature. These properties made AMCs a good candidate for the design of various components for advanced engineering applications.1 It has been found that the use of AMCs in engine applications can reduce the overall weight, fuel consumption and pollution in the automobiles and aircrafts.2 MMCs reinforced with ceramic particles are very promising materials for structural applications due to excellent combination of properties.3 AMCs reinforced with either silicon carbide (3.18g/cm3) or alumina (3.9g/cm3) particles are attractive materials for aviation.4,5 Some of the reinforcements are denser than aluminum alloys (2.7g/cm3) and therefore increase the weight of the composites produced depending on the quantity of the reinforcement added.6 Moreover, ceramic particles addition to the Al-alloy increases the hardness and thereby making machining more difficult.6 Hybrid composites, in most cases possess superior strength than monolithic composite. The properties of the hybrid reinforcements (primary and secondary) can be combined to attain better material properties. More so, the use of stir casting method for production of AMCs reduces the cost of the composite.7 Current trends in AMCs show growing concern in the production of hybrid Aluminum Metal Composites (HAMCSs) with better physical and mechanical properties. Resent researches have shown that agro/industrial waste materials such as fly ash, graphite, rice husk ash, amongst others, can be successfully used as a complementary reinforcement in AMCs.7,8 Furthermore, the use of hybrid reinforcements increases the service performance of the composites by the formation of new features. These agro/industrial wastes can reduce the cost of aluminum composites. Secondly, the weight of the composite can be manipulated due to lower density of this agro/industrial waste materials.3 Thirdly, these composites can also offer competitive physical and mechanical properties.7 This research investigates the mechanical and corrosion behavior of Aluminum-hybrid composite produced by reinforcing Aluminum 6063 with pride of Barbados seed ash and silicon carbide via double stir casting method.
铝基复合材料(AMCs)具有密度低、刚度和强度高、耐磨性好、热膨胀系数可控、抗疲劳性能好、高温稳定性好等特点。这些特性使amc成为设计先进工程应用中各种部件的良好候选者研究发现,在发动机中使用AMCs可以减少汽车和飞机的总重量、燃料消耗和污染以陶瓷颗粒为增强材料的复合材料具有优异的综合性能,是一种非常有前景的结构材料碳化硅(3.18g/cm3)或氧化铝(3.9g/cm3)颗粒增强的碳纳米管是航空领域有吸引力的材料。有些增强剂比铝合金密度大(2.7g/cm3),因此根据增强剂的添加量增加了复合材料的重量此外,添加到铝合金中的陶瓷颗粒增加了硬度,从而使加工变得更加困难混合复合材料在大多数情况下比整体复合材料具有更好的强度。混合增强材料(初级和次级)的性能可以结合起来,以获得更好的材料性能。更重要的是,使用搅拌铸造法生产复合材料可以降低成本目前的趋势表明,生产具有更好的物理和机械性能的混合铝金属复合材料(hamcs)日益受到关注。最近的研究表明,农业/工业废料,如粉煤灰、石墨、稻壳灰等,可以成功地用作AMCs的补充增强剂。此外,混合增强材料的使用通过形成新的特征来提高复合材料的使用性能。这些农业/工业废料可以降低铝复合材料的成本。其次,由于这种农业/工业废料的密度较低,复合材料的重量可以控制第三,这些复合材料还可以提供有竞争力的物理和机械性能研究了以巴巴多斯种子灰和碳化硅为原料,采用双搅拌铸造法增强铝6063复合材料的力学性能和腐蚀性能。
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引用次数: 1
Effect of heat treatment on the microstructure and hardness of the SLMed TC4 alloy specimens 热处理对SLMed TC4合金显微组织和硬度的影响
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00096
Jinwu Kang
Titanium alloys have outstanding properties such as corrosion resistance, high strength-to-weight ratio even at high temperatures, which makes them a suitable candidate for high demanding applications such as in aerospace industry. Among the Ti-alloy families, Ti6Al-4V(TC4) has been widely used in additive manufacturing as well as traditional processing such as casting and forging. Additive manufacturing can be used to fabricate titanium alloys with complex geometrical features and reduce material waste, production time and costs. There are many researches about the effect of heat treatment on as-cast or as-forged microstructures.1,2 As additive manufacturing appears, the microstructure features and the effect heat treatment on the additive manufactured specimens come to be the research focus. Jiao et al.,3 found that α laths have a plate morphology, and they precipitated out from β phase following a tetrahedral relationship, a special morphology with mixture of plate-like and rod-like α phase in the fabricated Ti-10V-2Fe-3Al alloy specimen by laser melting deposition additive manufacturing. Aziz4 &Murr5 Thijs6 & Kobyrn7 & Zhu8 & Song9 investigated the microstructure of TC4 titanium alloy in selective laser manufacturing. SLMed samples own good mechanical properties except of ductility. Thus, researchers investigated the way how to improve the ductility by heat treatment. Erhard10 studied the effect of heat treatment on the microstructure and mechanical properties of samples made by SLM. Sabban11 proposed repeated thermal cycling close to but below the β transus temperature to form globular α phase, eliminating the need for plastic deformation prior to heat treatment, which led to the bimodal microstructure consisting of globular α in additively manufactured TC4 alloy. In order to provide the understanding how to improve the mechanical properties, the TC4 titanium alloy samples were made by SLM method and they were heat treated, the effect of heat treatment on microstructure was symmetrically investigated.
钛合金具有优异的性能,如耐腐蚀性,即使在高温下也具有高强度重量比,这使其成为航空航天工业等高要求应用的合适候选者。在钛合金家族中,Ti6Al-4V(TC4)已广泛应用于增材制造以及铸造和锻造等传统加工。增材制造可用于制造具有复杂几何特征的钛合金,减少材料浪费、生产时间和成本。热处理对铸态和锻态组织的影响研究很多。随着增材制造的出现,增材制造试样的显微组织特征及热处理对其的影响成为研究热点。Jiao等人发现,激光熔融沉积增材制造的Ti-10V-2Fe-3Al合金试样中,α条具有板状形态,它们从β相中析出,呈四面体关系,是一种片状和棒状α相混合的特殊形态。Aziz4 & murr5 Thijs6 & Kobyrn7 & Zhu8 & Song9研究了选择性激光加工中TC4钛合金的显微组织。SLMed试样除延展性差外,具有良好的力学性能。因此,研究人员研究了如何通过热处理来提高塑性的方法。Erhard10研究了热处理对SLM试样显微组织和力学性能的影响。Sabban11提出在接近但低于β温度的温度下反复热循环形成球状α相,消除了热处理前塑性变形的需要,从而导致增材制造TC4合金中由球状α组成的双峰组织。为了更好地提高TC4钛合金的力学性能,采用SLM法制备了TC4钛合金试样,并对其进行了热处理,对称地研究了热处理对显微组织的影响。
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引用次数: 1
Structural analysis of x-ray irradiated carbon nanostructures x射线辐照碳纳米结构的结构分析
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00105
A. Grozdanov, P. Paunović, Violeta Vasilevska-Nikodinovska, A. Dimitrov, V. Yukhymchuk, I. Stojkovski, Zorica Arsova
Emerging nanotechnologies in which nuclear applications and radiations play key roles are: nano-electronics in environmental monitoring and remediation, electrode materials in hydrogen economy, polymer based nanocomposites in biotechnology, diagnostics and therapy. Radiation based technology using x-rays, e-beams and ion-beams is the key to avariety of different approaches. Due to the various ionizing irradiations, physical, chemical and biological properties of the materials can be significantly modified. Compared with conventional chemical reduction, the irradiation techniques are environmentally friendly, easily controlled, highly pure and less destructive. The most common defects induced by irradiation are vacancies and interstitials. Carbon based nanostructures with sp2-like hybridization, are exclusive due to the fact that its valence permitted researchers to engineer a large collection of molecular architectures. What makes all these structures truly phenomenal is that they are indeed built from the same component and they still can differ in shape and dimensionality. The most prolific irradiation-induced defects in graphenic carbon nanostructures are vacancies (single or multi vacancies). These carbon sp2nanostrucutres develop an extended reconstruction of the atomic network near the vacancy by saturating two dangling bonds and forming a pentagon. In graphene, single vacancies reconstruct, but in CNT the reconstruction is much stronger owing to the curvature and inherent nanoscale size of the system. It was found that for a CNTs to contract locally to “heal” the hole and thus saturate energetically unfavorable danging bonds. Thus, curved graphitic structures such as CNTs can be referred to as self-healing materials under irradiation. Some of the last experimental studies on the irradiation of MWCNTs reported a broad range of interesting phenomena such as surface reconstructions, modified mechanical properties, ion-irradiation induced changes in electrical coupling between nanotubes.1-3 Kis et al., have shown a strong stiffening of bundles of CNTs after electron irradiation.4 Last years, irradiation with γ-rays was studied as one of the clean and easy method for modification of carbon nanostructures. Namely, the effects of γ-irradiation strongly depend on the irradiation conditions, the materials type and the irradiation medium. Guo et al. observed a dramatic increase in the ID/IG of the Raman spectrum of γ-ray irradiated multi-walled CNTs (MWCNTs), which was attributed to the large presence of sp3-hybridized carbon atoms.5 This is opposite to the trend reported by Xu et al.,6 who noted an 8% decrease in ID/ IG for MWCNTs irradiated to 20Mrad in air, signaling improved graphitic order.6 Also, it was found that γ-irradiation decreased the diameter of MWCNTs, increased their specific surface area and modified their oxygen functional groups.7 The graphitization of MWCNTs was improved with doses of 100kGy, while a higher dose of 150kGy induced
核应用和辐射发挥关键作用的新兴纳米技术包括:环境监测和修复中的纳米电子学、氢经济中的电极材料、生物技术、诊断和治疗中的聚合物基纳米复合材料。使用x射线、电子束和离子束的辐射技术是各种不同方法的关键。由于各种电离照射,材料的物理、化学和生物性能可以显著改变。与传统的化学还原技术相比,辐照技术具有环境友好、易于控制、纯度高、破坏性小等优点。辐照引起的最常见的缺陷是空位和间隙。具有sp2类杂化的碳基纳米结构是独一无二的,因为它的价态允许研究人员设计大量的分子结构。所有这些结构之所以如此惊人,是因为它们确实是由相同的组件建造而成,但它们在形状和维度上仍然存在差异。石墨碳纳米结构中最常见的辐照缺陷是空位(单空位或多空位)。这些碳sp2纳米结构通过饱和两个悬空键并形成五边形,在空位附近形成了一个扩展的原子网络重建。在石墨烯中,单个空位可以重建,但在碳纳米管中,由于系统的曲率和固有的纳米尺寸,重建要强得多。研究发现,为了使碳纳米管局部收缩以“修复”孔洞,从而使能量上不利的危险键饱和。因此,可以将CNTs等弯曲的石墨结构称为辐照下的自愈材料。最近一些关于MWCNTs辐照的实验研究报道了一系列有趣的现象,如表面重构、机械性能的改变、离子辐照诱导纳米管之间电耦合的变化。1-3 Kis等人的研究表明,电子辐照后碳纳米管束具有很强的硬化性近年来,人们研究了γ射线辐照作为一种清洁、简便的碳纳米结构改性方法。也就是说,γ辐照的效果与辐照条件、材料类型和辐照介质密切相关。Guo等人观察到γ射线辐照多壁碳纳米管(MWCNTs)的拉曼光谱的ID/IG显著增加,这是由于sp3杂化碳原子的大量存在这与Xu等人报道的趋势相反,他们指出,在空气中辐照至20Mrad时,MWCNTs的ID/ IG降低了8%,表明石墨有序性得到改善同时,γ辐照减小了MWCNTs的直径,增加了它们的比表面积,修饰了它们的氧官能团当剂量为100kGy时,MWCNTs的石墨化得到改善,而当剂量为150kGy时,则会引起结构损伤7 .对于石墨烯,采用γ辐照法在不同的液体介质中还原氧化石墨烯Bardi等人9研究了x射线辐照引起的单壁碳纳米管的结构变化基于拉曼和XPS测量,他们证实了纳米管表面结构的改变,并发现碳纳米管结构的无序程度与x射线照射剂量相关尽管人们做了大量的理论工作来了解各种辐照引起的碳纳米结构的结构变化和缺陷的起源,但在实验上却知之甚少。因此,本研究的重点是x射线辐照对碳基纳米结构(G、MWCNTs、G/MWCNTs混合)中变化和缺陷的结构识别的影响。
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引用次数: 2
Bacterial cellulose/phytotherapic hydrogels as dressings for wound healing 细菌纤维素/植物治疗水凝胶作为伤口愈合敷料
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00108
Paula Rf de S Moraes, Sidney J. L. Ribeiro, A. M. Gaspar
Skin, the largest organ of the human body, is formed mainly by epidermis and dermis and its main functions are assurance of mechanical protection and prevention against contamination.1,2 Wound healing begins from a skin-barrier disruption and is divided into inflammatory, proliferative, and maturation phases. The former consists in the recruitment of leukocytes to the site of the lesion. In the proliferative phase, the migration and proliferation of keratinocytes, fibroblasts, and endothelial cells results in reepithelization and formation of granulation tissue with a large quantity of type III collagen. Finally, in the maturation phase, most type III collagen fibers are substituted by type I fibers and the excess collagen is degraded by proteolytic enzymes that promote tissue remodeling. Despite some recent advances in the understanding of such basic processes, wound healing disorders continue to cause diseases and even death.3 Dressings play a substantial role in the conglutination of certain types of open wounds (e.g. traumatic, thermal or chronic wounds), since the moist, warm and nutritious environment of wound beds provides an ideal condition for microbial growth. The wound healing process can interfere with bacterial colonization and subsequent infection, which may cause an excessive and prolonged inflammatory response from the host tissues. The nature of lesions, patient’s physiologic state, wound degree of infection and contamination and other disease processes can interfere with the cutaneous wound healing.4 The basic requirement for a material to be used for tissue engineering purposes is biocompatibility. Over the past two decades, significant advances have been made regarding the development of biodegradable polymers and biodegradability is one of the most important properties, since the scaffold should degrade with time and be replaced with newly regenerated tissues.5
皮肤是人体最大的器官,主要由表皮和真皮层组成,其主要功能是保证机械防护和防止污染。伤口愈合从皮肤屏障破坏开始,分为炎症、增殖和成熟阶段。前者包括白细胞聚集到病变部位。在增生期,角质形成细胞、成纤维细胞和内皮细胞的迁移和增殖导致再上皮形成并形成含有大量III型胶原的肉芽组织。最后,在成熟阶段,大多数III型胶原纤维被I型纤维取代,多余的胶原被促进组织重塑的蛋白水解酶降解。尽管最近在了解这些基本过程方面取得了一些进展,但伤口愈合障碍继续导致疾病甚至死亡敷料在粘合某些类型的开放性伤口(例如创伤、热伤或慢性伤口)中起着重要作用,因为伤口床的潮湿、温暖和营养环境为微生物生长提供了理想的条件。伤口愈合过程可能干扰细菌定植和随后的感染,这可能导致宿主组织过度和长期的炎症反应。病变的性质、患者的生理状态、创面的感染和污染程度等疾病过程都会干扰皮肤创面的愈合用于组织工程目的的材料的基本要求是生物相容性。在过去的二十年里,生物可降解聚合物的发展取得了重大进展,生物可降解性是最重要的特性之一,因为支架应该随着时间的推移而降解,并被新的再生组织所取代
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引用次数: 5
An insight on the greenhouse gas emission from the metals process industries and its effects on climate change 金属加工工业的温室气体排放及其对气候变化的影响
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00115
I. Shahidul
The metals process the industry is a source of Greenhouse Gas (GHG), and the major components of these gases are CO2, CH4, N2O and Fluorinated gases (F-gases). The GHG is responsible for global warming potentials (GWP) and climate change.1,2 However, the common source of GHG emission is electricity production from fossil fuel to operate metals industries and as well from metals processing.3 The carbon dioxide in the atmosphere is about 65 percent.4 The methane is the second-largest carbon in GHG after CO2, which accounted for 16 percent of global emission. The effect of CH4 on GWP and climate change is about 25 percent higher than CO2. 5,6 Nitrous oxide is also a part of GHG in the atmosphere, and its contribution to GHG is about 6 percent. It has been reported that the metal process industries are a major emission source of N2O. 7,8The Fluorinated gas is a part of GHG and has a significant effect on climate change. The fact is the process of the metal industries are associated with Fluorinated gas emission. This gas includes hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride SF6.9,10 The Magnesium (Mg), Zinc, Lead, and other metals processing industries are the emitter of this gas.11 However, in a report, IEA stated that the burning of fossil fuel for electricity production to operate heavy industries like Iron, and Aluminum, Zinc. Magnesium and copper and significantly responsible for GWP.4,12
金属加工工业是温室气体(GHG)的一个来源,这些气体的主要成分是CO2、CH4、N2O和氟化气体(f -气体)。温室气体负责全球变暖潜值(GWP)和气候变化。然而,温室气体排放的共同来源是矿物燃料生产的电力,以运作金属工业,以及金属加工大气中的二氧化碳约占65%甲烷是仅次于二氧化碳的第二大温室气体,占全球排放量的16%。CH4对全球变暖潜能值和气候变化的影响比CO2高约25%。5,6一氧化二氮也是大气中温室气体的一部分,其对温室气体的贡献约为6%。据报道,金属加工工业是N2O的主要排放源。7,8氟化气体是温室气体的一部分,对气候变化有重大影响。事实是金属工业的过程与氟化气体排放有关。这种气体包括氢氟碳化物(HFCs)、全氟碳化物(pfc)和六氟化硫SF6.9,10镁(Mg)、锌、铅和其他金属加工工业是这种气体的排放源11然而,国际能源署在一份报告中指出,燃烧化石燃料用于发电,以运营铁、铝、锌等重工业。镁和铜对gwp有重要作用
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引用次数: 0
Numerical analysis of the crack behavior interface-fiber: interfacial crack 界面裂纹行为的数值分析-纤维界面裂纹
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00107
R. Sara, S. Boualem
The use of composite materials in industrial applications has been increasing for several years, and this in all industries: automotive, aeronautics, space, marine, railway or even sports, medical and nuclear. The performances in terms of mass gain, mechanical properties and manufacturing offer many possibilities of applications, sometimes very complex. Research activities specific to these materials are also very present in laboratories around the world to better understand the behavior of composite structures across many topics of study, with the aim of improving their uses and their adequacy with the industrial application. The joining of ceramics to metals is inherently difficult because of their distinctly different properties. But considerable efforts have devoted to the development of joining technologies during recent past years have led to significant successes.1 Dissimilar materials had to join together in many technical areas. One example of the ceramic to metal joint is to combine the wear resistance, high temperature strength and thermal or electrical resistance of the ceramic with the ductility of the metal. Due to the difference of the elastic properties and the thermal expansion coefficients of the ceramic and metal the high stresses occur at the intersection of edges and the interface of the joint under mechanical or thermal loading.2
复合材料在工业应用中的使用近年来一直在增加,这在所有行业:汽车,航空,航天,船舶,铁路甚至体育,医疗和核。在质量增益、机械性能和制造方面的性能提供了许多应用的可能性,有时非常复杂。在世界各地的实验室中,针对这些材料的研究活动也非常普遍,以更好地了解复合材料结构在许多研究主题中的行为,目的是改善它们的用途和它们在工业应用中的充分性。陶瓷和金属的结合本身就很困难,因为它们的性质截然不同。但是,近年来,人们在开发连接技术方面付出了巨大的努力,并取得了重大成功在许多技术领域,不同的材料必须结合在一起。陶瓷与金属连接的一个例子是将陶瓷的耐磨性、高温强度和耐热性或电阻性与金属的延展性结合起来。由于陶瓷和金属的弹性性能和热膨胀系数的差异,在机械或热载荷作用下,在接头的边缘交叉处和界面处产生高应力
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引用次数: 0
X-ray diffraction characterization of the untreated calcium phosphate from two Moroccan mining zones 摩洛哥两个矿区未处理磷酸钙的x射线衍射表征
Pub Date : 2019-01-01 DOI: 10.15406/mseij.2019.03.00093
K. El-hami, Ikram Labtaini
Calcium phosphate Ca3(PO4)2 has a wide range of applications in a number of fields, such as medical, chemistry and industrial. Calcium phosphates are used in many biomedical applications through good biocompatibility and bioactivity. In biochemistry, calcium phosphates participate in providing energy for metabolism and substances and contribute to important metabolic and enzymatic reactions in almost all organs and tissues.1 The main industrial application of calcium phosphate is in the production of agriculture fertilizers. Many studies have been carried out on the crystalline structure and the crystallographic parameters of natural phosphates; the most common way to determine such structures is X-ray diffraction. Therefore, a study at the crystallographic level can be useful to help us understand some properties related to different problem and applications. Indeed, many authors explored several analyses of untreated phosphates that show a variation of their characteristics and their field of application.2–4 The aim of this article is to compare the composition and the structure of calcium phosphate Ca3(PO4)2 from two different mining centers with X-ray diffraction. The particularity in this study is the characterization of the calcium phosphate samples as-received.
磷酸钙Ca3(PO4)2在医学、化学和工业等领域有着广泛的应用。磷酸钙具有良好的生物相容性和生物活性,被广泛应用于生物医学领域。在生物化学中,磷酸钙参与为新陈代谢和物质提供能量,并在几乎所有器官和组织中参与重要的代谢和酶促反应磷酸钙的主要工业应用是生产农业肥料。对天然磷酸盐的晶体结构和晶体学参数进行了大量的研究;确定这种结构最常用的方法是x射线衍射。因此,在晶体学水平上的研究可以帮助我们了解与不同问题和应用相关的一些性质。事实上,许多作者对未经处理的磷酸盐进行了一些分析,这些分析显示了它们的特性和应用领域的变化。2 - 4本文的目的是用x射线衍射比较两个不同采矿中心的磷酸钙Ca3(PO4)2的组成和结构。本研究的特殊性在于对收到的磷酸钙样品进行了表征。
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Material Science & Engineering International Journal
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