Materials Letters: X最新文献

Lumefantrine, exhibits poor bioavailability due to its very low solubility. A liquisolid compact of lumefantrine was prepared with mesoporous silica as a novel coating material. Lactose anhydrous and syloid 244FP were selected as carrier and coating materials respectively. Varying the carrier to coating ratio from 10 to 35, six formulations were prepared and evaluated for tests for tablets. thermal, surface characteristics, surface morphology, and surface area analysis. The tabletability of the formulation lactose to syloid 244FP ratio at 20:1 was found to be the best among all in terms of compression characteristics, faster disintegration, and enhanced dissolution. Hence it can be concluded that the use of a suitable amount of mesoporous silica in the formulation of liquisolid compact could significantly enhance the dissolution of the drug.

An effect of variation of slit widths of excitation and emission monochromators on emission intensity, peak position and asymmetric ratio of Eu³⁺ has been observed in YPO₄:Eu³⁺. Stark splitting is observed. Eu³⁺ ion occupies D_2d site symmetry in crystal lattice. However, asymmetric ratio is observed to be lesser in value ∼≤1.5. The possible explanation for low value of asymmetric ratio is explained.

Additive manufactured flexible electrodes show prospect applications in flexible electronics. However, morphological defects may affect a flexible electronic device's sensitivity, response value, reliability, etc. Therefore, accurate and efficient defect detection is still challenging, especially for mass-manufactured flexible electrodes. This paper proposed and tested a rapid morphological defects detection approach with infrared thermography technology. This approach shows advantages of high detect resolution (minimum test defect: 183.38um), good linearity (R² = 0.9887), efficiency, and nondestructive and large-scale applications, thereby achieving quality control and process evaluation in the mass additive manufacturing of flexible electrodes. Furthermore, resulting in improves the reliability and consistency of flexible electronic devices.

In general, metastable β-Ti-alloys exhibit low ductility at room temperature, which restricts its workability and critical applications. Here, we report a hierarchical microstructure tailoring strategy to achieve an excellent strength-ductility combination in Ti-4Al-5Mo-5V-5Cr-1Nb (Ti-45551) alloy. It was revealed that high density deformation twinning can be successfully introduced in primary α particles of Ti-45551 alloy through warm dynamic plastic deformation (DPD). After warm DPD process, the hierarchical microstructure was constructed in Ti-45551 alloy, including equiaxed primary α particles with high density deformation twins, β-phase matrix and finely dispersed nanoscale secondary α lamellas. Uniaxial tensile experiments have revealed that Ti-45551 alloy exhibited enhanced strength-ductility synergy with hierarchical microstructure at room temperature. This excellent combination of strength and ductility is derived from high twin density in in primary α particles and unique hierarchical microstructure. Also, this study demonstrates a feasible and low-cost route to design high performance Ti alloy.

Despite extensive studies on electrorefining to remove impurities from copper production units, bleeding electrolytes is the most popular method for controlling impurities due to low operating costs. A controlled cooled-reheat cycle was used to remove impurities in industrial electrolytes of Khatoon Abad copper company. Phase identification and physical study were done by the XRD, SEM, TEM, and FTIR techniques. The results confirmed the possibility of the removal of 23 wt% Ni, 26 wt% Sb, 2.4 wt% As and convention of 6 wt% of As⁵⁺ to As³⁺ at cooled-reheat cycle.

Hot pressing of pure Ti and cast iron under vacuum formed a ∼15 µm wide TiC-layer through the thermo-reactive diffusion process. Nanoindentation testing of the TiC-layer revealed average hardness and elastic modulus values of ∼35 GPa and ∼400 GPa, respectively. High-resolution indentation mapping indicated hardness change across the boundary with peak values observed within the TiC-layer. Solid state high temperature diffusion holds significant potential for developing uniform hard coatings on pure Ti/Ti-alloys.

Alumina deposit was produced by metalorganic chemical vapour deposition process on a NiCoCrAlY superalloy substrate. Low frequency injection in the range 5–10 Hz was used to feed the Aluminium Tri-isopropoxide precursor into a deposit chamber holding at 400 °C of temperature. Both scanning electron microscopy and X-ray diffraction analysis were accomplished to characterize the deposited alumina. Topographic images show an alumina deposit roughness of Ra 35 nm measured by atomic force microscopy. An X-photon spectroscopy analysis of the alumina deposit was performed to identify both Al species and chemical analysis. Thermo-gravimetric analysis was conducted to assess the effect of deposited alumina on the superalloy.

A model to depict that it is possible to separate solid cobalt and copper from liquid Mg-Co-Cu mixtures is presented. The model aims to demonstrate how the application of solution thermodynamics concepts can help in depicting real processes.

In the present research work, an aluminomagnesium hydrogel was synthesized via co-precipitation, organic solvent-based aging, and microwave irradiation drying. The synthesized hydrogel was used to remove methylene blue dye from aqueous solutions. The adsorption experiments at room temperature indicated a removal efficiency of 99.7% under an adsorbent dosage of 4 g/L and a duration of 30 min. The adsorbent regeneration tests also confirmed the reusability of the adsorbent for the removal of dye, so that after five regeneration cycles, the hydrogel exhibited a removal efficiency of more than 90% under the same conditions. Overall, the results confirmed that the synthesized aluminomagnesium hydrogel could be used as a promising dye scavenger for methylene blue.

Octacalcium phosphate (OCP) has attracted attention as a bone-repairing material with excellent bone regeneration ability, and F⁻ incorporation is expected to further promote bone formation. However, because OCP is easily converted to fluorapatite in an aqueous fluoride solution, it is difficult to incorporate a large amount of F⁻ while maintaining the crystalline structure of OCP. Therefore, in this study, we attempted to introduce F⁻ into OCP using an ionic liquid with high F⁻ concentration in a non-aqueous environment. OCP was incorporated with F⁻ in the form of ion pairs after treatment with an acetone solution of 1-ethyl-3-methylimidazolium tetrafluoroborate. The F⁻ content was approximately 9%, which was approximately 28 times greater than achieved in previous studies. The amount of OCP with F⁻ dissolved in acetate buffer was less than that of untreated OCP.