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HYBRID COMPOSITES REINFORCED WITH GRAPHENE AND TITANIUM CARBIDE IN AA7068 MATRIX: EVALUATION OF MECHANICAL AND TRIBOLOGICAL PROPERTY 石墨烯与碳化钛复合材料在aa7068基体中的力学与摩擦学性能评价
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.915
Naganambi Nambirajan, None Selvakumar N.
The present work deals with the fabrication of AA7068 as a matrix reinforced with different weight percentages of titanium carbide (0, 0.5, 1, 1.5, 2, and 2.5) % and with a constant weight percentage of graphene of 1 % using the stir casting method. The objective of this work is to study the mechanical and tribological properties of the hybrid composite. The uniform distribution of graphene and titanium carbide particles in the AA7068 matrix was validated with SEM investigations of the manufactured composite. A tensile test was performed, and a maximum ultimate tensile strength (UTS) of 199 MPa and a low percentage of elongation of 4.42 were obtained for the AA7068-1.0 w/% graphene-2.5 w/% TiC composite. The hardness of the composite was measured using a Rockwell hardness tester, and a maximum value of 63 HRB was obtained for the AA7068-1.0 w/% graphene-2.5 w/% TiC composite. The hardness increased as the percentage of TiC increased. The impact strength was determined with a Charpy test, and a maximum value of 4.5 J was obtained for the AA7068-1.0 w/% graphene-2.5 w/% TiC composite. A dry sliding wear test was performed in a pin-on-disc wear testing machine with different loads (5, 10 and 15) N, a constant sliding speed of 1000 min–1, and a sliding distance of 1000 m. The sample having 2.5 w/% TiC had a lower coefficient of friction and lower wear loss under different load conditions. Due to the presence of graphene and TiC reinforcements, the composites’ tensile, hardness and tribological properties improved significantly when compared to the aluminium alloy 7068 matrix.
本研究采用搅拌铸造方法制备了不同重量百分比碳化钛(0、0.5、1、1.5、2和2.5)%和恒定重量百分比石墨烯(1%)的AA7068基体。本工作的目的是研究混杂复合材料的力学和摩擦学性能。通过对复合材料的SEM研究,证实了石墨烯和碳化钛颗粒在AA7068基体中的均匀分布。拉伸试验表明,AA7068-1.0 w/%石墨烯-2.5 w/% TiC复合材料的最大极限拉伸强度为199 MPa,伸长率为4.42。采用洛氏硬度计测定复合材料的硬度,结果表明:AA7068-1.0 w/%石墨烯-2.5 w/% TiC复合材料的硬度最大值为63 HRB。硬度随TiC含量的增加而增加。用Charpy试验测定了复合材料的冲击强度,结果表明,AA7068-1.0 w/%石墨烯-2.5 w/% TiC复合材料的冲击强度最大值为4.5 J。在针盘式磨损试验机上进行干滑动磨损试验,试验载荷分别为5、10、15 N,滑动速度为1000 min-1,滑动距离为1000 m。在不同的载荷条件下,TiC含量为2.5 w/%的试样具有较低的摩擦系数和较低的磨损损失。由于石墨烯和TiC增强剂的存在,与铝合金7068基体相比,复合材料的拉伸、硬度和摩擦学性能得到了显著提高。
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引用次数: 0
HEMOCOMPATIBILITY STUDIES OF LAYER-BY-LAYER POLYELECTROLYTE COMPLEXES FOR BIO-BASED POLYMERS 生物基聚合物的层层聚电解质复合物的血液相容性研究
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.922
Mthabisi Talent George Moyo, Terin Adali, Oğuz Han Edebal, Ece Bayir, Aylin Şendemir
Thrombogenesis is an important issue that causes blood-contacting biomedical device failure. This study focuses on hemocompatibility studies of novel blood-contacting polyelectrolyte complexes (PECs) for biomedical application designs. PEC films were fabricated from biobased polymers of silk fibroin (SF), chitosan (CH), and sodium alginate (AL) through the solvent casting method as well as Layer-by-Layer (LbL) technique. Characterization was carried out by Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Atomic force microscopy (AFM), and Differential scanning calorimetry (DSC) analyses. FTIR spectra displayed all layers’ characteristic peaks of SF, CH, and AL. AFM images indicated that the addition of AL as an outer layer increased surface roughness. DSC analysis suggested that the best thermal stability has been observed with the CH outer layer of PECs. SEM micrograph analysis indicated that the morphologies of PECs were affected by the inclusion of the clopidogrel bisulfate (CLB). Hemocompatibility properties were investigated by complete blood count (CBC), prothrombin time (PT), international normalized ratio (INR), activated partial thromboplastin time (APTT), platelet adhesion, erythrocyte morphology analysis, in vitro cholesterol, and albumin level tests. These hemocompatibility analyses demonstrated that the PEC surfaces provide favourable principles to design and develop non-thrombogenic PECs for blood-contacting biomedical applications
血栓形成是导致血液接触生物医学设备失效的一个重要问题。本研究的重点是研究用于生物医学应用设计的新型血液接触多电解质复合物(PECs)的血液相容性。以丝素蛋白(SF)、壳聚糖(CH)和海藻酸钠(AL)为原料,采用溶剂浇铸法和逐层技术制备了生物基聚合物膜。通过傅里叶变换红外光谱(FTIR)、扫描电镜(SEM)、原子力显微镜(AFM)和差示扫描量热(DSC)分析对其进行了表征。FTIR光谱显示了所有层的特征峰SF、CH和AL。AFM图像表明,AL作为外层的加入增加了表面粗糙度。DSC分析表明,聚羧酸聚乙烯外层的CH具有最佳的热稳定性。扫描电镜分析表明,氯吡格雷(CLB)的加入影响了PECs的形态。血液相容性通过全血细胞计数(CBC)、凝血酶原时间(PT)、国际标准化比率(INR)、活化部分凝血活素时间(APTT)、血小板粘附、红细胞形态分析、体外胆固醇和白蛋白水平测试进行研究。这些血液相容性分析表明,PEC表面为设计和开发用于血液接触生物医学应用的非血栓性PEC提供了有利的原则
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引用次数: 0
WETTABILITY STUDIES ON FEMTOSECOND-¬LASER-TEXTURED N-TYPE SILICON SURFACES 飞秒激光织构n型硅表面的润湿性研究
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.838
Srikanth Vipparla, Samuel G.L., Dongbin Wei
This present study examines the wetting behavior of N-type silicon surfaces that have been textured using a femtosecond laser. By employing three different patterns, i.e., square pillars, micro dimples, and circumferential grooves, and manipulating key femtosecond laser parameters such as laser power (ranging from 8 W to 12 W) and repetitions (ranging from 40 to 60), the wettability properties of the silicon surfaces are modified. The wettability properties of the surface were evaluated by measuring the contact angle by the sessile-drop method using distilled deionized water as a testing liquid. The textured surfaces displayed various wettability characteristics, varying from hydrophilic to hydrophobic. The hydrophobic behavior was observed on surfaces with a peak laser power of 12 W, 60 repetitions, and the lowest pitch of 160 µm. For the square pillar and micro-dimple textures, contact angles of 146° and 120°, respectively, were measured. Conversely, the circumferential grooves exhibited hydrophilic behavior with a contact angle of 20°. These results were achieved at laser powers of 10 W and 8 W, higher pitch values, and increased repetitions. The contact angle decreased with an increase in pitch and a decrease in repetitions and laser power. Based on the experimental findings, it can be concluded that the wettability of silicon surfaces can be controlled for specific applications using a single-step laser ablation technique. The desired wettability characteristics can be achieved by carefully adjusting the key femtosecond-laser parameters and geometrical features.
本研究考察了用飞秒激光织构的n型硅表面的润湿行为。通过采用三种不同的模式,即方柱、微凹窝和周向凹槽,并操纵关键的飞秒激光参数,如激光功率(范围从8 W到12 W)和重复次数(范围从40到60),硅表面的润湿性得到了改善。以蒸馏去离子水为测试液,采用无基滴法测量接触角,评价了表面的润湿性。织构表面表现出从亲水性到疏水性的不同润湿性特征。在峰值激光功率为12 W,重复60次,最低间距为160µm的条件下,观察到表面的疏水行为。对于方柱和微窝纹理,分别测量了146°和120°的接触角。相反,当接触角为20°时,周向凹槽表现出亲水性。这些结果是在激光功率为10 W和8 W,更高的音高值和增加重复的情况下实现的。接触角随着螺距的增加、重复次数的减少和激光功率的减小而减小。基于实验结果,可以得出结论,硅表面的润湿性可以通过单步激光烧蚀技术来控制。通过仔细调整关键的飞秒激光参数和几何特征,可以实现所需的润湿性特性。
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引用次数: 0
OPTIMIZATION OF PROCESS PARAMETERS FOR A SOLID-STATE-WELDED AISI 430 STEEL JOINT WITH THE GRG REINFORCED RESPONSE SURFACE METHODOLOGY 基于GRG增强响应面法的aisi 430钢固态焊接接头工艺参数优化
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.873
Senthilkumar G., V. Vinodkumar, T. Mayavan, G. Rathinasabapathi
High-temperature applications such as heat exchangers and burner tubes employ AISI 430 steel. A larger heat-affected zone, undesired metallurgical changes and higher hardness in the weld area occur when fusion welding this type of steel. The study investigates the feasibility of welding ferritic stainless steel AISI 430, utilizing a solid-state method (continuous drive friction welding). The experiment uses an L27 orthogonal array and three levels of variation in the welding parameters such as frictional pressure, forging pressure, friction time, forging time and rotational speed. Tensile strength, axial shortening and impact toughness are the observed quality characteristics. In an integrated approach of the grey incidence reinforced response surface methodology, the benefits of the grey relational theory are merged with the statistical analysis of the response surface methodology to determine the ideal friction welding inputs (frictional pressure – 59.95 MPa, friction time – 4 s, upset pressure – 68.5 MPa, forging time – 3 s and rotational speed – 1399 min–1). The AISI 430 steel joint’s qualities are improved by 2.25, 12.74 and 7.89 % in terms of the maximum ultimate tensile strength, axial shortening and impact toughness, respectively.
高温应用如热交换器和燃烧器管采用AISI 430钢。当熔焊这类钢时,会出现较大的热影响区、不期望的冶金变化和焊缝区域较高的硬度。研究了采用固态法(连续驱动摩擦焊)焊接铁素体不锈钢AISI 430的可行性。实验采用L27正交阵列,对摩擦压力、锻造压力、摩擦时间、锻造时间、转速等焊接参数进行3个水平的变化。拉伸强度、轴向缩短和冲击韧性是观察到的质量特征。在灰色关联增强响应面方法的综合应用中,将灰色关联理论的优点与响应面方法的统计分析相结合,确定了理想的摩擦焊接输入(摩擦压力- 59.95 MPa,摩擦时间- 4 s,镦粗压力- 68.5 MPa,锻造时间- 3 s,转速- 1399 min-1)。AISI 430钢接头的最大极限抗拉强度、轴向缩短和冲击韧性分别提高了2.25%、12.74%和7.89%。
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引用次数: 0
PREDICTION OF MICROSTRUCTURE EVOLUTION OF 316LN AUSTENITIC STAINLESS STEEL USING CELLULAR AUTOMATA AND A NOVEL EVALUATION METHOD FOR GRAIN SIZE INHOMOGENEITY 用元胞自动机预测316ln奥氏体不锈钢组织演变及一种新的晶粒尺寸不均匀性评价方法
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.796
Min Qin, Jiansheng Liu
Inhomogeneous grain size is a significant structural defect in large forgings. This study employed cellular automata to simulate the dynamic recrystallization (DRX) of 316LN steel and analyzed the grain distribution during DRX. The accuracy of the CA method was verified by comparing its results with the results of a thermal simulation test on Gleeble 1500D. Subsequently, a novel method for evaluating grain size inhomogeneity was proposed. The grain size inhomogeneity coefficient Gu was introduced to determine the evolution of grain size inhomogeneity during DRX. This coefficient accurately and objectively reflects grain inhomogeneity. The impact of the initial and recrystallized grain size on the inhomogeneity during DRX was also analyzed.
晶粒尺寸不均匀是大型锻件中一个重要的组织缺陷。采用元胞自动机模拟了316LN钢的动态再结晶过程,分析了动态再结晶过程中的晶粒分布。通过与Gleeble 1500D热模拟试验结果的比较,验证了CA方法的准确性。随后,提出了一种评价晶粒尺寸不均匀性的新方法。引入晶粒尺寸不均匀性系数Gu来确定DRX过程中晶粒尺寸不均匀性的演变。该系数准确、客观地反映了颗粒的不均匀性。分析了初始晶粒尺寸和再结晶晶粒尺寸对DRX非均匀性的影响。
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引用次数: 0
SYNTHESIS, CHARACTERIZATION OF CeO2@Ag HOLLOW SPHERES AND EVALUATION OF THEIR CATALYST ACTIVITY FOR THE REDUCTION OF 4-NP CeO2@Ag空心球的合成、表征及其还原4-NP催化剂活性评价
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.813
Shu Cui, Haixin Zhao, Chengyou Liu, Hai Yu, Nan Li, Xiaotian Li
A CeO2@Ag hollow spherical composite catalyst was synthesized with the template method. Firstly, a SiO2@CeO2 core-shell structure was synthesized using SiO2 spheres as the template, and then the SiO2 core was removed by etching to obtain hollow CeO2 spheres. The CeO2 hollow microspheres have a large specific surface area, which can effectively suppress the aggregation of Ag nanoparticles, leading to CeO2@Ag with a regular morphology and well dispersed Ag nanoparticles. There is a strong synergistic effect between CeO2 and Ag, which is beneficial to improving the catalytic performance. As a result, the CeO2@Ag hollow spherical composite catalyst can reduce 4-nitrophenol efficiently.
采用模板法合成了CeO2@Ag空心球形复合催化剂。首先,以SiO2球为模板合成了SiO2@CeO2核壳结构,然后通过蚀刻去除SiO2核得到空心CeO2球。CeO2空心微球具有较大的比表面积,可以有效抑制银纳米粒子的聚集,使CeO2@Ag具有规则的形态和分散良好的银纳米粒子。CeO2与Ag之间存在较强的协同效应,有利于提高催化性能。结果表明,CeO2@Ag空心球形复合催化剂能有效还原4-硝基苯酚。
{"title":"SYNTHESIS, CHARACTERIZATION OF CeO2@Ag HOLLOW SPHERES AND EVALUATION OF THEIR CATALYST ACTIVITY FOR THE REDUCTION OF 4-NP","authors":"Shu Cui, Haixin Zhao, Chengyou Liu, Hai Yu, Nan Li, Xiaotian Li","doi":"10.17222/mit.2023.813","DOIUrl":"https://doi.org/10.17222/mit.2023.813","url":null,"abstract":"A CeO2@Ag hollow spherical composite catalyst was synthesized with the template method. Firstly, a SiO2@CeO2 core-shell structure was synthesized using SiO2 spheres as the template, and then the SiO2 core was removed by etching to obtain hollow CeO2 spheres. The CeO2 hollow microspheres have a large specific surface area, which can effectively suppress the aggregation of Ag nanoparticles, leading to CeO2@Ag with a regular morphology and well dispersed Ag nanoparticles. There is a strong synergistic effect between CeO2 and Ag, which is beneficial to improving the catalytic performance. As a result, the CeO2@Ag hollow spherical composite catalyst can reduce 4-nitrophenol efficiently.","PeriodicalId":18258,"journal":{"name":"Materiali in tehnologije","volume":"90 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135739791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A STUDY ON SOUND-ABSORPTION ABILITY OF CLOSED-CELL ALUMINIUM FOAMS 闭孔泡沫铝吸声性能的研究
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.741
Vaddi Thulasikanth, Padmanabhan Raghupathy
Metallic foams have gained popularity in industrial applications and research due to their unique mechanical properties combined with light weight, vibroacoustic damping and high-temperature resistance. Generally, closed-cell foams have poor sound absorption properties due to their closed cellular structure when compared to open-cell foams. This paper investigates a new composite closed-cell foam for its acoustic properties. The new closed-cell aluminium fly-ash foam was made with liquid processing, using calcium carbonate (CaCO3) as the blowing agent. The effects of the fly-ash content on the cell morphology and mechanical properties were analyzed. Acoustic studies were conducted on the prepared closed-cell foam using the impedance tube method. Samples were prepared in different ways to determine the effects of the changing parameters. The results of quasi-static compression and microstructural analyses of two different combinations of the foam revealed small pore sizes with varying relative densities and compressive strengths. It is evident from the acoustic studies that the foams are capable of improved sound absorption of medium and high frequencies.
金属泡沫由于其独特的机械性能,结合了重量轻、振动声阻尼和耐高温等特点,在工业应用和研究中得到了广泛的应用。与开孔泡沫相比,闭孔泡沫的闭孔结构使其吸声性能较差。研究了一种新型复合闭孔泡沫材料的声学性能。以碳酸钙(CaCO3)为发泡剂,采用液体法制备了新型闭孔铝粉煤灰泡沫。分析了粉煤灰掺量对细胞形态和力学性能的影响。采用阻抗管法对所制备的闭孔泡沫进行了声学研究。以不同的方式制备样品,以确定参数变化的影响。两种不同组合泡沫的准静态压缩和微观结构分析结果表明,相对密度和抗压强度不同,孔隙尺寸较小。从声学研究中可以明显看出,泡沫材料能够改善中高频的吸声效果。
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引用次数: 0
BIOMECHANICAL ANALYSIS OF AN OPTIMIZED PATIENT-SPECIFIC DENTAL-IMPLANT SCREW IN THE POSTERIOR MANDIBLE 改良后下颌骨患者特异性牙种植螺钉的生物力学分析
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.907
N. Selvakumar, Balamurugan P.
Implant design developed considerably with the advancement of restorative dentistry. Examining the stress distribution in the cancellous and cortical bones around custom-made implants with different thread-profile models is the study’s objective. The newly designed implants were made with a diameter and length of 4.5 mm and 11.5 mm. The implants were designed the same, but had different thread profiles. Model A is designed with a standard V-shape thread design, and it was compared with the remaining three dental implants (models B, C, and D) having different customized thread-profile designs. The biomechanical characteristics of the four implant models were compared with the use of biomechanical profiling to predict the mechanical performance of various dental-screw models, including the influence of physiological factors. The stress distribution in the D4 bone area of implants with different thread-profile designs under a vertical load of 100 N at 0° and an oblique load of 223.6 N at 25° was examined using ANSYS Workbench. The trabecular and cortical bones comprise the structure of the D4 bone area. Deformation and stress (von Mises) findings were found for the dental implants and bone. While implant models C and D showed less stress distribution in the cortical and cancellous bone, they nonetheless produced outcomes superior to those of the conventional model A underloading. According to the findings, the unique dental implant design lessens the stress concentration in the cortical bone’s neck area. The suggested model C increases the implant’s stability in that region by distributing a low stress over the D4 bone.
随着牙科修复技术的发展,种植体的设计也有了很大的发展。本研究的目的是研究不同螺纹轮廓模型定制植入物周围松质骨和皮质骨的应力分布。新设计的种植体直径和长度分别为4.5 mm和11.5 mm。植入物设计相同,但螺纹轮廓不同。模型A采用标准的v型螺纹设计,并与其余三种不同定制螺纹轮廓设计的种植体(模型B、C、D)进行比较。比较四种种植体模型的生物力学特性,利用生物力学剖面预测各种牙钉模型的力学性能,包括生理因素的影响。采用ANSYS Workbench分析了不同螺纹型设计的种植体在垂直载荷为100 N、倾斜载荷为223.6 N、垂直载荷为25°时D4骨区的应力分布。小梁骨和皮质骨构成D4骨区的结构。牙种植体和骨均出现变形和应力(von Mises)。虽然种植体模型C和D在皮质骨和松质骨中的应力分布较小,但它们的结果优于常规模型A的负荷不足。根据研究结果,独特的种植体设计减少了皮质骨颈部区域的应力集中。建议的C型通过在D4骨上分配低应力来增加植入物在该区域的稳定性。
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引用次数: 0
PREDICTING THE OPTIMAL PARAMETERS BY MULTI-OBJECTIVE DECISION MAKING WHILE MACHINING AN Al6061 ALLOY USING CBN INSERTS WITH DIFFERENT CUTTING-EDGE GEOMETRIES 用不同尖端几何形状的CBN刀片加工Al6061合金时,用多目标决策方法预测最优参数
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.830
I Sri Phani Sushma, Samuel G.L., Gyula Varga
The present work aims to investigate the effect of cutting-tool edge geometry on cutting force and surface finish while machining an Al6061 alloy under different conditions. A series of experiments was performed with a custom-fabricated cutting insert of a chamfered edge to observe the effect of feed rate and depth of cut on the cutting forces and surface finish. The results showed that varying the cutting-edge geometry has a significant effect on controlling the cutting forces. Also, as the feed and depth of cut were reduced (at high cutting speeds), the surface roughness was observed to reduce with the geometry effect. Furthermore, in the present work validation of the experimental results were also performed based on a multi-criteria decision-making method called Grey Relational Analysis (GRA). The weighted GRA predicted the optimal combination of machining parameters for two different cutting-tool inserts. Finally, the obtained optimal results were compared with the predicted and experimental values in terms of weighted GRG. The result shows that there was no significant improvement while using the standard cutting tool, whereas a net improvement of 16.9 % was observed while using the chamfered cutting tool for machining the Al 6061 alloy.
研究了不同条件下加工Al6061合金时,刀具刃口几何形状对切削力和表面光洁度的影响。利用定制的倒角切削刀片进行了一系列实验,观察了进给量和切削深度对切削力和表面光洁度的影响。结果表明,改变尖端几何形状对切削力的控制有显著影响。此外,随着进给量和切削深度的减小(在高切削速度下),观察到表面粗糙度随着几何效应而减小。此外,在本工作中,还基于灰色关联分析(GRA)的多准则决策方法对实验结果进行了验证。加权GRA预测了两种不同刀具刀片加工参数的最优组合。最后,将得到的最优结果与加权GRG的预测值和实验值进行了比较。结果表明,使用标准刀具加工Al 6061合金时,无明显改善,而使用倒角刀具加工Al 6061合金时,净改善率为16.9%。
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引用次数: 0
MICROSTRUCTURE EVOLUTION AND PHASE TRANSFORMATIONS IN MICROALLOYED ARMOX 500T STEEL DURING A DILATATION PROCESS 微合金化armox 500t钢在膨胀过程中的组织演变和相变
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-10-03 DOI: 10.17222/mit.2023.804
Mervat Youssef, Eman El-Shenawy, Wael Khair-Eldeen, Tadaharu Adachi, Adel Nofal, Mohsen A. Hassan
With this work we successfully developed two modified Armox 500T alloys using microalloying with different amounts of niobium (Nb) and boron (B) to obtain a finer grain size, which in return enhances the remnant properties. Furthermore, different heat-treatment cycles were designed and performed using a quenching dilatometer to study the combined effect of thermal cycling and microalloying with Nb and B on the microstructure and transformation temperatures including the start and finish temperature of the austenite transformation (Ac1, Ac3) and the martensite start and finish temperature (Ms, Mf) of the investigated alloys. Dilatometry results show that increasing the content of Nb from 0.07 w/% to 0.13 w/% and B from 0.0035 to 0.0046 w/% increases the temperature range between Ac1 and Ac3 by 55 °C, indicating a broader range for changing heat-treatment temperatures. In addition, the Ms temperature is reduced by 13 °C due to austenite refinement caused by the microalloying of Nb and B. The effect of the annealing temperature at a constant heating rate showed a significant impact on the austenite grain size and hardness. Furthermore, the kinetics of phase transformations were theoretically studied using Thermo-Calc, and the numerical predictions were confirmed experimentally with dilatometry results. Metallography investigations using a scanning electron microscope (SEM) and an optical microscope (OM) were conducted to evaluate the microstructure evolution of the developed alloys. Hardness tests were performed to evaluate the effect of the grain refinement of martensite lathes caused by microalloying with Nb, B, and heat-treatment thermal cycling. It is found that the hardness of the modified Armox alloys in this research was improved by 14 % in comparison with the conventional Armox 500T.
通过这项工作,我们成功地开发了两种改性的Armox 500T合金,使用不同数量的铌(Nb)和硼(B)进行微合金化,获得了更细的晶粒尺寸,从而提高了残余性能。采用淬火膨胀仪设计不同热处理循环,研究热循环和微量合金化对合金组织和转变温度的影响,包括奥氏体转变的开始和结束温度(Ac1, Ac3)和马氏体转变的开始和结束温度(Ms, Mf)。膨胀测量结果表明,将Nb的含量从0.07 w/%增加到0.13 w/%, B的含量从0.0035 w/%增加到0.0046 w/%, Ac1和Ac3之间的温度范围增加了55℃,表明热处理温度的变化范围更大。此外,由于Nb和b的微合金化导致奥氏体细化,Ms温度降低了13℃。恒定升温速率下的退火温度对奥氏体晶粒尺寸和硬度有显著影响。此外,用热钙法对相变动力学进行了理论研究,并用膨胀测量法的实验结果证实了数值预测。利用扫描电子显微镜(SEM)和光学显微镜(OM)进行金相观察,评价合金的微观组织演变。通过硬度试验评价Nb、B微合金化和热处理热循环对马氏体车床晶粒细化的影响。结果表明,与常规Armox 500T合金相比,改性Armox合金的硬度提高了14%。
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引用次数: 1
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