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TWO-STEP SYNTHESIS AND FORMATION MECHANISM FOR LACUOS NANO-SIZED AGGLOMERATES 多孔纳米团聚体的两步合成及其形成机理
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-29 DOI: 10.17222/mit.2023.879
Xin Li, Qiang Li, Zhenning Ma, Yan Sun
We have developed a two-step synthesis method to obtain pure LaCuOS nano-sized agglomerates using La(NO3)3·6H2O, CuSO4·5H2O and NH3·H2O as the starting materials. The result shows that the precursor can be converted into La2O2SO4, La2(SO4)3 and CuO phases at 800 °C for 2 h in air, which was then converted into a pure LaCuOS phase by a reduction at 800 °C for 5 h in a flowing argon and hydrogen atmosphere. The as prepared LaCuOS nano-aggregates have poor dispersion and a wide size distribution range (50–100 nm).
以La(NO3)3·6H2O、CuSO4·5H2O和NH3·H2O为原料,研究了两步法合成纯LaCuOS纳米团聚体的方法。结果表明,前驱体在空气中800℃作用2 h可转化为La2O2SO4、La2(SO4)3和CuO相,在氩气和氢气中800℃还原5 h可转化为纯LaCuOS相。所制备的LaCuOS纳米聚集体分散性差,粒径分布范围宽(50 ~ 100 nm)。
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引用次数: 0
INFLUENCE OF THE THERMAL CONDITION OF STEEL ON THE TRANSFORMATION TEMPERATURES OF TWO CHROMIUM HOT-WORK TOOL STEELS 钢的热条件对二铬热加工工具钢相变温度的影响
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-29 DOI: 10.17222/mit.2023.822
T. Balaško, J. Medved
The influence of the thermal condition of the steel on the transformation temperatures of two chromium hot-work tool steels was investigated. The steels studied were in two different thermal states: the soft -annealed state and the hardened-and-tempered state. The soft-annealed condition, i.e., the fully annealed condition, is a thermal state of steels in which the matrix is ferritic, and the carbon is chemically bonded in spherical carbides. The hardened-and-tempered condition, on the other hand, means a fully hardened-and-tempered martensitic matrix with uniformly distributed (primary and secondary) carbides. The samples were analysed in a simultaneous thermal analyser (STA) using the differential scanning calorimetry (DSC) method to determine the transformation temperatures. We also performed calculations based on the CALPHAD method to obtain the equilibrium temperatures of the transformations. The aim of the study was to determine the influence of different thermal conditions of chromium hot-work tool steels on the transformation temperatures such as solidus/liquidus temperatures, eutectoid transformation temperatures (A1 and A3), austenite solidification temperature and martensite transformation start temperatures. Since DSC analysis also measures thermal influence, we were able to determine the energies absorbed during eutectoid transformation and melting (endothermic processes) and the energies released during the solidification of δ-ferrite and γ-austenite (exothermic processes), as well as the energies released during martensite transformation. It was found that hardening and tempering reduce both eutectoid transformation temperatures and that the solidification intervals are closer to those calculated. From an energetic point of view, hardening and tempering reduce the energies absorbed during melting.
研究了钢的热条件对两种铬热加工工具钢相变温度的影响。所研究的钢处于两种不同的热状态:软退火状态和淬火回火状态。软退火状态,即完全退火状态,是钢的一种热状态,在这种状态下,基体是铁素体,碳在化学上结合成球形碳化物。另一方面,淬火回火状态是指具有均匀分布的(初生和次生)碳化物的完全淬火回火马氏体基体。样品在同步热分析仪(STA)中使用差示扫描量热法(DSC)分析以确定转变温度。我们还基于CALPHAD方法进行了计算,得到了相变的平衡温度。研究了不同热处理条件对铬热工工具钢固液相温度、共析相变温度(A1和A3)、奥氏体凝固温度和马氏体相变起始温度等相变温度的影响。由于DSC分析还测量了热影响,我们能够确定共析转变和熔化过程中吸收的能量(吸热过程),δ-铁素体和γ-奥氏体凝固过程中释放的能量(放热过程),以及马氏体转变过程中释放的能量。结果表明,淬火和回火均降低了共晶转变温度,凝固间隔更接近于计算值。从能量的角度来看,淬火和回火减少了熔化过程中吸收的能量。
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引用次数: 0
PICKLING – PASSIVATION MECHANISM AND PROCESS OPTIMIZATION OF Q235 STEEL PIPELINE q235钢管道酸洗钝化机理及工艺优化
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-29 DOI: 10.17222/mit.2023.807
H. Ji, S. Cai, Fengyun Zhu, Weichi Pei, W. Xiao, Xue-feng Tang
Pipe cleaning is currently the most effective method to improve the cleanliness and corrosion resistance of pipes. In this paper, a new method of pipe cleaning is proposed, combining mechanical and chemical cleaning, offline tank cleaning and online cycle cleaning. Through experiments and characterization of the morphology changes, the mechanism of pickling and passivation of Q235 steel was explored, and the entire process of microstructure and morphology changes on the pipe wall’s surface was analyzed to verify the feasibility of this technology. The cleaning process was optimised using response surface analysis to determine the optimum cleaning conditions. This study is of great relevance to the effective operation of continuous-casting equipment over a long period of time.
管道清洗是目前提高管道清洁度和耐腐蚀性的最有效方法。本文提出了一种机械清洗与化学清洗、罐体离线清洗与在线循环清洗相结合的管道清洗新方法。通过对形貌变化的实验和表征,探讨了Q235钢酸洗钝化的机理,分析了管壁表面组织和形貌变化的全过程,验证了该工艺的可行性。利用响应面分析法对清洗工艺进行了优化,确定了最佳清洗条件。本研究对连铸设备长期有效运行具有重要意义。
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引用次数: 0
MICROSTRUCTURE AND HIGH-TEMPERATURE WEAR BEHAVIOR OF FE-BASED AMORPHOUS COATINGS BY LASER CLADDING 激光熔覆铁基非晶涂层的显微组织和高温磨损性能
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-29 DOI: 10.17222/mit.2023.803
Lu Xie, Yueming Wang, Jianlin Yang, Chenlong Li, Xuhang Han, Jie Huang
FeCrMoCB amorphous coatings were prepared on 316 stainless steel via an amorphous powder. Scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) were used to analyze the microstructure, composition, and phase structure of the coatings. Hardness and friction wear testers were applied to investigate the microhardness and wear behavior of the coatings. Results show that the Cr23C6, Cr15Fe7C6 and Fe3Mo crystal phases appeared after laser cladding relative to the complete amorphous powder, and the amorphous phase fraction of the coating was calculated up to 68.4 % using the Verdon method. The coating exhibited a dominating adhesive wear mechanism under room temperature (RT) and transformed to a fatigue wear mechanism as wear test temperature increased to 600 °C. As the temperature was elevated from RT to 600 °C, the wear rate increased from 26 × 10–6 mm3/N·m to 79 × 10–6 mm3/N·m. The laser-cladded Fe-based amorphous coating exhibited much stronger wear performance than the 316 stainless steel, even the wear rate reached one third of that of steel.
采用非晶粉末在316不锈钢表面制备了FeCrMoCB非晶涂层。利用扫描电子显微镜(SEM)、能谱仪(EDS)和x射线衍射仪(XRD)分析了涂层的微观结构、成分和相结构。采用硬度仪和摩擦磨损仪对涂层的显微硬度和磨损性能进行了研究。结果表明,相对于完整的非晶粉末,激光熔覆后出现了Cr23C6、Cr15Fe7C6和Fe3Mo的晶相,采用Verdon法计算得到熔覆层的非晶相分数高达68.4%。涂层在室温下以粘着磨损为主,当磨损温度升高至600℃时,涂层转变为疲劳磨损。随着温度从RT升高到600℃,磨损率从26 × 10-6 mm3/N·m增加到79 × 10-6 mm3/N·m。激光熔覆铁基非晶态涂层的磨损性能明显优于316不锈钢,其磨损率达到钢的三分之一。
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引用次数: 0
THERMAL-POWER-PLANT CONDENSER-TUBE CORROSION ANALYSIS 热电厂冷凝器管腐蚀分析
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-28 DOI: 10.17222/mit.2023.747
J. Batelić, V. Špada, M. Kršulja, S. Martinez
The thermal-power-plant condenser tubes, conducting cooling seawater, experienced frequent leakages, prompting the hereby presented failure analysis. Visual inspection of the corroded/ruptured tube segments revealed that localized corrosion may be linked to seawater sediments and thick layers of corrosion products at the tube water side. Sediments were found along the tube bottom and thick corrosion products were found adjacent to the point of contact between the baffle plates and the exterior tube walls. Underdeposit corrosion, accelerated due to sulphate-reducing bacteria, was diagnosed based on the excess sulphur found at the pit bottom using EDX, the FT-IR spectrum indicating the presence of biofilm and SEM determining the featuring corrosion products based on the biofilm. It was proposed that the corrosion initiating deposits were linked to the condenser shutdown and startup periods. Results showed that pitting corrosion occurred under the influence of biofilm microorganisms tolerant to copper. The main goal of this research was achieved by defining a systematic procedure for avoiding a shutdown of the thermal power plant.
火电厂的凝汽器管由于输送冷却海水,经常发生泄漏,故提出故障分析。对腐蚀/破裂管段的目视检查显示,局部腐蚀可能与海水沉积物和管道水侧厚层腐蚀产物有关。沿管底发现有沉积物,在折流板与外管壁的接触点附近发现有较厚的腐蚀产物。沉积物底部腐蚀由硫酸盐还原菌加速,根据坑底发现的过量硫,使用EDX进行诊断,FT-IR光谱表明生物膜的存在,SEM根据生物膜确定特征腐蚀产物。提出了凝汽器启停周期与腐蚀引发沉积有关。结果表明,点蚀是在耐铜生物膜微生物的作用下发生的。本研究的主要目标是通过定义一个避免火力发电厂关闭的系统程序来实现。
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引用次数: 0
DESIGN OF A TRIPLE-BANDPASS FILTER USING A MODIFIED T-SHAPED RECTANGULAR COUPLED WITH A STEPPED IMPEDANCE RESONATOR FOR SMART PORTABLE COMMUNICATION DEVICE APPLICATIONS 采用改进的t形矩形耦合阶跃阻抗谐振器设计用于智能便携式通信设备的三带通滤波器
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-28 DOI: 10.17222/mit.2023.846
M. Arulaalan, Viswanathan Ramasamy, R. Saravanakumar, S. Maheswari
This paper presents a ground-breaking triple-bandpass filter design utilizing a modified T-shape rectangular coupled with a stepped impedance resonator (MTSR-CSIR) for smart portable communication device applications. The MTSR-CSIR filter operates at (2.2, 3.62 and 4.6) GHz, providing wide passbands in three operating modes. To achieve the optimal performance, the filter design is executed on a multi-layered liquid-crystal polymer (LCP) substrate with a thickness of 50 µm, dielectric constant of 2.9 and loss tangent of 0.002. Simulation results for the MTSR-CSIR filter demonstrate a high level of accuracy and consistency with the measurement results for the fabricated filter. The filter exhibits an excellent stopband rejection, low loss and compact size while maintaining high-performance levels. Its performance parameters, such as insertion loss, return loss and group delay, are considered to evaluate the filter’s performance. The results highlight the applicability of the MTSR-CSIR filter for smart portable communication devices.
本文提出了一种突破性的三带通滤波器设计,利用改进的t形矩形与阶跃阻抗谐振器(MTSR-CSIR)耦合,用于智能便携式通信设备应用。MTSR-CSIR滤波器工作在(2.2,3.62和4.6)GHz,在三种工作模式下提供宽频带。为了获得最佳性能,滤波器设计在多层液晶聚合物(LCP)衬底上进行,衬底厚度为50µm,介电常数为2.9,损耗正切为0.002。对MTSR-CSIR滤波器的仿真结果表明,该滤波器具有较高的精度,且与预制滤波器的测量结果一致。该滤波器具有优异的阻带抑制,低损耗和紧凑的尺寸,同时保持高性能水平。考虑了插入损耗、回波损耗和群延迟等性能参数来评价滤波器的性能。结果表明MTSR-CSIR滤波器适用于智能便携式通信设备。
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引用次数: 0
A CONTEMPORARY REVIEW OF THE ADVANCEMENTS IN JOINING TECHNOLOGIES FOR BATTERY APPLICATIONS 电池应用中连接技术的当代进展综述
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-31 DOI: 10.17222/mit.2023.797
R. Palanivel
The joining of multilayered foils to a conductive tab necessitates a joining process in the battery, which is an important storage device in renewable-energy sectors. Cell, module, and pack are the three levels of pouch cell joining in a battery pack. The joining of multi-layered dissimilar conductive materials is necessary for battery-pack fabrication. Mostly copper (Cu) and aluminium (Al) are used in battery-pack applications. The Cu and Al are characterized as high thermally and electrically conductive materials. However, obtaining a quality Cu-Al weld using conventional methods is hard and the durability of the weldments is uncertain. In general, the development of intermetallic compounds (IMCs) during welding is a major challenge for the joining of dissimilar materials due to the differences in the chemical and physical properties. This review addresses the battery packs and challenges involved in joining the conductive tabs. In addition, this review provides an insight into the suitability of various joining processes and explores their suitability for the joining of battery packs.  
多层箔与导电片的连接需要在电池中进行连接过程,而电池是可再生能源领域的重要存储设备。电池、模块和电池组是连接在电池组中的三个级别的小袋电池。多层不同导电材料的连接是制造电池组的必要条件。铜(Cu)和铝(Al)主要用于电池组应用。铜和铝具有高导热和高导电性的特点。然而,使用传统方法获得高质量的铜铝焊缝是困难的,并且焊缝的耐久性是不确定的。一般来说,由于化学和物理性质的差异,金属间化合物(IMCs)在焊接过程中的发展是不同材料连接的主要挑战。这篇综述讨论了电池组和连接导电片所涉及的挑战。此外,本综述还提供了对各种连接工艺的适用性的见解,并探讨了它们在电池组连接中的适用性。
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引用次数: 0
INJECTION MOLDING OF POLYCARBONATE THICK-WALLED PARTS USING A TOOL WITH VARIOUSLY DESIGNED GATE INSERTS 注塑成型的聚碳酸酯厚壁零件使用的工具与各种设计的浇口插入
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-31 DOI: 10.17222/mit.2022.692
Jiri Vanek, Michal Stanek, M. Ovsik, Vlastimil Chalupa
Injection molding is an advantageous technology for the mass production of plastic parts without the necessity for additional procedures. The applicability of this method is still partially limited by the required properties of the manufactured parts. Especially in the field of optics, there is a need to produce thick-walled parts while maintaining their transparency. This paper reports on how various shapes of gating systems affected the process parameters and cavity filling during the injection molding of polycarbonate thick-walled specimens. These outcomes demonstrated that film gates and their alternatives are more suitable for the standard injection molding of thick-walled optical products than the triple-edge gating systems. Favorable results were observed particularly in the uniformity of cavity filling, size of shrinkage, and in the occurrence of defects such as voids or sink marks.
注射成型是一种有利的技术,可以大批量生产塑料零件,而不需要额外的工序。这种方法的适用性仍然部分地受到所制造零件所要求的性能的限制。特别是在光学领域,需要在生产厚壁零件的同时保持其透明度。本文报道了不同形状的浇注系统对聚碳酸酯厚壁试样注射成型过程中工艺参数和型腔填充的影响。这些结果表明,薄膜门及其替代品比三边门系统更适合厚壁光学产品的标准注射成型。特别是在空腔填充的均匀性、收缩的大小以及空洞或凹痕等缺陷的发生方面,观察到良好的结果。
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引用次数: 0
EFFECTS OF ALLOYING ELEMENTS AND SURFACE PROPERTIES ON THE CORROSION BEHAVIOR OF HVOF-DEPOSITED WC COATINGS 合金元素和表面性能对高温沉积wc涂层腐蚀行为的影响
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-31 DOI: 10.17222/mit.2023.833
Erhan Ozkan
The main purpose of this study is to investigate the corrosion behavior of nickel-aluminum buffer and tungsten-carbide-based ceramic-metal composite coated materials on EN 1.4404 quality stainless steels in a sulfuric acid (H2SO4) environment for petrochemical industry applications. For this purpose, tungsten-carbide-based coatings were produced on nickel-aluminum-deposited 1.4404 stainless-steel substrates using the HVOF (High Velocity Oxy-Fuel) technique. In the characterization of coatings, X-ray diffraction (XRD) for phase analysis, optical microscope and scanning electron microscope (SEM) for surface morphology, image analyzer for coating thickness measurements, energy distribution spectroscopy (EDS) for elemental analysis, and roughness device for surface structures, were used. WC-, Co-, Ni-, and NiAl-based phases were observed in the coatings. According to metallographic studies, all the coatings had a similar coating microstructure and made good contact with the substrate. Potentiodynamic polarization measurements and corrosion tests were carried out to determine the corrosion behavior of HVOF plasma-sprayed coatings using a potentiostat/galvanostat. The results showed that the WCCo-NiAl-coated stainless-steel substrate had a higher corrosion resistance to the H2SO4 environment than the NiAl and WCNi-NiAl samples.
本研究的主要目的是研究镍铝缓冲液和碳化钨基陶瓷-金属复合涂层材料在石化工业应用的EN 1.4404质量不锈钢上在硫酸(H2SO4)环境中的腐蚀行为。为此,使用HVOF(高速氧燃料)技术在镍铝沉积的1.4404不锈钢衬底上制备了碳化钨基涂层。在涂层的表征中,采用x射线衍射(XRD)进行物相分析,光学显微镜和扫描电镜(SEM)进行表面形貌分析,图像分析仪进行涂层厚度测量,能谱分析仪进行元素分析,粗糙度仪进行表面结构分析。在涂层中观察到WC、Co、Ni和nial基相。金相研究表明,各涂层具有相似的涂层组织,且与基体接触良好。利用恒电位器/恒流器进行了动电位极化测量和腐蚀试验,以确定HVOF等离子喷涂涂层的腐蚀行为。结果表明,与NiAl和WCNi-NiAl样品相比,wccco -NiAl涂层的不锈钢基体具有更高的耐H2SO4腐蚀性能。
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引用次数: 0
DEVELOPMENT OF A PNEUMATIC, ARTIFICIAL-MUSCLE- BASED PRESS FOR PUNCHING THIN METAL SHEETS 一种用于冲压金属薄板的气动、人造肌肉式压力机的研制
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-05-31 DOI: 10.17222/mit.2023.783
A. Kapti, Ilker Atakul
The present study examines the nonlinear behavior of pneumatic, artificial muscles and investigates their availability for producing pressing forces over the experimentally determined tensile forces. It covers the design and manufacturing studies of a test setup and a pneumatic, artificial-muscle-based press to achieve this goal. The press design consists of a single pneumatic artificial muscle to provide the main pressing force and another two to bring the press back to the neutral position. The proposed approach is considered sufficient for thin sheet-metal punching molds and fills a gap in the spectrum of pressing technologies. A sufficient level of pressing force for thin sheet-metal punching is found to be achievable using a single 40-mm-diameter, pneumatic, artificial muscle. The results show that the press can produce (9.1, 23.1 and 36.9) kN pressing forces at (200, 400 and 600) kPa air pressures, respectively.
本研究考察了气动、人造肌肉的非线性行为,并研究了它们在实验确定的拉力上产生压力的可用性。它涵盖了设计和制造研究的测试装置和气动,人造肌肉为基础的压力机,以实现这一目标。压力机设计由单个气动人工肌肉组成,用于提供主压力力,另外两个用于将压力机恢复到中性位置。所提出的方法被认为足以用于薄板金属冲压模具,填补了冲压技术领域的空白。利用单个直径为40毫米的气动人造肌肉,可以获得足够的冲压薄板的压力。结果表明,在200、400和600 kPa的空气压力下,该压机可分别产生(9.1、23.1和36.9)kN的压力。
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引用次数: 0
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