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EFFECT OF A SCANDIUM ADDITION ON ANODIZING AlMg ALLOYS 添加钪对铝合金阳极氧化的影响
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-30 DOI: 10.17222/mit.2023.755
B. Karpe, Katarina Kern, J. Kovač, M. Klanjšek Gunde, A. Nagode, M. Bizjak, M. Zorc
Scandium (Sc) is known to be one of the most effective alloying elements of aluminum alloys. The only drawback is its high price, but that could change quickly due to the promising results of recent research on its extraction. However, the data on how it affects anodic oxidation are very scarce. In this research, we analyzed how a micro-addition of Sc to the AlMg alloy affects the growth mechanism and properties of the protective aluminium oxide layer depending on the anodization parameters. For comparison, alloy AA5083 with a similar magnesium content was also anodized with the same anodizing parameters. In all experiments, sulfuric acid (VI) with concentrations of 1.72 M or 2.2 M at temperatures of 21 °C or 35 °C was used as the electrolyte. Potentiostatic (18 V) and galvanostatic (20 mA/cm2) anodizing methods were applied. The results (SED-EDS) show that scandium is uniformly intercalated in the matrix of the oxide layer and decreases its resistivity, which increases the oxide growth rate during potentiostatic anodizing and decreases the pore density and pore diameters during galvanostatic anodizing. Moreover, it increases the mobility of cations through the oxide layer, thus accelerating the oxidation reaction in concentrated sulfuric acid electrolytes. On the other hand, the increased cation mobility considerably increases the sensitivity to the temperature of the electrolyte, which can change the growth mechanism of the oxide layer and thus its morphology.
钪(Sc)是已知的最有效的铝合金合金元素之一。唯一的缺点是它的价格高,但由于最近对其提取的研究取得了有希望的结果,这种情况可能很快就会改变。然而,关于它如何影响阳极氧化的数据非常少。在本研究中,我们分析了在AlMg合金中微量添加Sc对氧化铝保护层生长机理和性能的影响,以及阳极氧化参数的变化。为了比较,采用相同的阳极氧化参数对镁含量相近的合金AA5083进行了阳极氧化。在所有实验中,分别使用浓度为1.72 M和2.2 M,温度分别为21℃和35℃的硫酸(VI)作为电解液。采用恒电位(18 V)和恒流(20 mA/cm2)阳极氧化方法。结果(SED-EDS)表明,钪均匀嵌入到氧化层基体中,降低了氧化层的电阻率,提高了恒电位阳极氧化过程中氧化物的生长速率,降低了恒流阳极氧化过程中的孔隙密度和孔径。此外,它增加了阳离子通过氧化层的迁移率,从而加速了浓硫酸电解质中的氧化反应。另一方面,阳离子迁移率的增加大大增加了对电解质温度的敏感性,这可以改变氧化层的生长机制,从而改变其形态。
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引用次数: 0
MECHANICAL AND METALLURGICAL PROPERTIES OF FRICTION-STIR-WELDED AISI 304 STAINLESS STEEL aisi 304不锈钢摩擦搅拌焊接的力学和冶金性能
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-30 DOI: 10.17222/mit.2022.678
Sundar raju Govindaraj, Sivakumar Karuppa
Friction stir welding of AISI 304 stainless-steel sheets was successfully carried out with a tungsten-alloy (W+La2O3) tool and the effect of the tool rotational speed on the microstructure and mechanical properties of the joints were evaluated. 3-mm-thick plates were friction-stir welded at various rotational speeds of 600–1000 min–1 and a constant welding speed of 40 mm/min with a constant axial load of 15 kN. Defect-free joints were produced at 800 min–1 and 900 min–1, indicating a proper plastic flow of the material and ensuring adequate heat generation during welding. Tensile, Charpy impact, compression and microhardness tests were performed to evaluate the joint mechanical properties. The microstructural behavior of the welded and base-metal samples was examined with optical microscopy and scanning electron microscopy. According to the mechanical results, the welded material has a higher yield strength than the base metal due to the grain refinement and work hardening effect in the stir zone. FSW welds have a higher hardness than the base metal due to the high density of dislocations and continuous dynamic recrystallization. The joints also exhibit acceptable impact toughness. Finally, the EDS analysis confirms that there is no secondary-phase formation in the weld zone of the fabricated material.
采用钨合金(W+La2O3)刀具成功进行了AISI 304不锈钢板的搅拌摩擦焊接,并研究了刀具转速对接头组织和力学性能的影响。在恒定轴向载荷为15 kN的条件下,以600 ~ 1000 min - 1的不同转速和40 mm/min的恒定焊接速度对3 mm厚的钢板进行搅拌摩擦焊接。在800 min-1和900 min-1时产生无缺陷接头,表明材料塑性流动适当,并确保焊接时产生足够的热量。通过拉伸、夏比冲击、压缩和显微硬度测试来评估接头的力学性能。采用光学显微镜和扫描电镜对焊接试样和母材试样的显微组织行为进行了观察。力学结果表明,由于搅拌区的晶粒细化和加工硬化作用,焊接材料的屈服强度高于母材。由于位错密度高和连续动态再结晶,摩擦焊焊缝的硬度高于母材。接头也具有可接受的冲击韧性。最后,EDS分析证实,在焊接区没有二次相的形成。
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引用次数: 1
EFFECT OF THICKNESS REDUCTIONS ON MICROSTRUCTURE AND NANO-MECHANICAL PROPERTIES OF AZ31 MAGNESIUM ALLOY IN FLOW-FORMING 减薄对az31镁合金流动成形组织和纳米力学性能的影响
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.659
Han Zhang, Tingting Zhang, J. Zhang, Zhihang Yan, Wen-xian Wang
The effect of reducing the thinning rate when flow forming AZ31B magnesium alloy barrels on the microstructure, crystal orientation, micro-, nano- and macro-mechanical properties was investigated. The results demonstrate that when the magnesium alloy undergoes different degrees of plastic deformation after flow forming, the grain size and dislocation density inside the crystal change greatly, and the evolution pattern of the organization has a significant effect on the mechanical properties of the materials. The stress-strain curve of the cylindrical parts was obtained by nano-indentation and hardness. This is important to improve the mechanical properties of the magnesium alloy.
研究了流动成形AZ31B镁合金筒体时降低减薄速率对其显微组织、取向、微观、纳米和宏观力学性能的影响。结果表明:镁合金在流动成形后进行不同程度的塑性变形时,晶体内的晶粒尺寸和位错密度发生较大变化,组织演化模式对材料的力学性能有显著影响。采用纳米压痕法和硬度法得到了圆柱形零件的应力应变曲线。这对提高镁合金的力学性能具有重要意义。
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引用次数: 0
INVESTIGATION OF THE SURFACE QUALITY OF AA6082-ZrO2-Gr MMCs USING ABRASIVE WATERJET MACHINING 磨料水射流加工AA6082-ZrO2-Gr复合材料表面质量的研究
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.602
Kannapiran Karuppasamy, B. Ranganathan
Aluminium metal matrix composites have wide applications in the aerospace and automotive industries due to their excellent physical properties like hardness, tensile strength, etc. The reinforcement of ZrO2 hard ceramic particles and soft solid lubricant graphite on AA6082 produces a high-strength composite. This research aims to fabricate AA6082-ZrO2-Gr MMCs with different compositions and evaluate the abrasive-waterjet-machining (AWJM) parameters in the machining of the fabricated composites, which eliminates the thermal distortion and damage to the work material. The experiments were conducted by varying the dominant process parameters such as water pressure, traverse speed, abrasive flow rate and mesh size. The kerf taper angle was affected by the traverse speed and water pressure, while the surface roughness was affected by the abrasive flow rate, mesh size and water pressure. The abrasive mesh size of 120 provided the best surface finish.
金属铝基复合材料由于其优异的物理性能,如硬度、抗拉强度等,在航空航天和汽车工业中有着广泛的应用。ZrO2硬陶瓷颗粒和软固体润滑剂石墨在AA6082上的增强产生了高强度复合材料。本研究旨在制备不同成分的AA6082-ZrO2-Gr复合材料,并评估磨料水射流加工(AWJM)参数在复合材料加工中的应用,以消除热变形和对工作材料的损伤。实验通过改变主要工艺参数如水压、导线速度、磨粒流量和筛孔尺寸进行。刀口锥度角受横移速度和水压的影响,表面粗糙度受磨料流量、网目尺寸和水压的影响。磨料网目尺寸为120提供了最好的表面光洁度。
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引用次数: 0
A SINGLE-LAYER FSS FOR S-, C-, X-, KU- AND K-BAND APPLICATIONS 单层FSS,适用于s -, c -, x -, ku -和k -波段应用
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.710
Srigitha Surendranath, Varalakshmi Subramanian, Arthi Devarani Paulretnam, Elakkiya Azhagar
This research introduces an ultra-wideband frequency-selective surface (FSS) that offers a very good bandwidth for insulation and communication applications. It consists of two layers: a dielectric substrate layer and a metal layer. The basal layer, which is the substrate, is made of FR4; and the top patch, which is the metal, is made of copper. The FSS is constructed without using several layers or several resonators in a single unit cell. This single-sheet, planar-structure-based FSS has an ultra-level bandwidth of 20.3 GHz, ranging from 2.3 GHz to 22.6 GHz. It will be employed in microwave applications in the S, C, X, Ku, and K bands, with a centre frequency of 10.6 GHz. The polarisation and angle stability of the transverse electric (TE) and transverse magnetic (TM) modes are examined, and it was found that they are insensitive up to 90 degrees. Plots depicting the distribution of the magnetic field, surface current, and electric field are used to analyse the structure's physical mechanism. The performances from previous studies are compared and contrasted with that of the current work.  
本研究介绍了一种超宽带频率选择表面(FSS),为绝缘和通信应用提供了非常好的带宽。它由两层组成:介电衬底层和金属层。所述基底层为基材,由FR4制成;最上面的那块是金属,是铜做的。FSS的构造不需要在单个单元电池中使用几层或几个谐振器。这种基于单片平面结构的FSS具有20.3 GHz的超高带宽,范围从2.3 GHz到22.6 GHz。它将用于S、C、X、Ku和K波段的微波应用,中心频率为10.6 GHz。研究了横向电(TE)和横向磁(TM)模式的极化稳定性和角度稳定性,发现它们在90度以内不敏感。用磁场、表面电流和电场的分布图来分析结构的物理机理。将前人的研究成果与当前的研究成果进行了比较和对比。
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引用次数: 0
PREPARATION AND HARDNESS OF A FUNCTIONALLY GRADED Ni-Al COATING 一种功能梯度镍铝涂层的制备及其硬度
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.650
Ningning Li, Lei Xu, Liang Huang, Yuping Tong, Z. Jiang, Keliang Li
A functionally graded Ni-Al coating can improve the hardness of low-carbon steel, which can then adapt to various conditions due to a high hardness. The primary purpose of this research was the preparation of a Ni-Al coating by adopting a two-step method including nickel plating and pack aluminizing. The coating phase and morphology were characterized with XRD, SEM and EDS. Subsequently, the hardness of the Ni-Al coating was measured using a nanoindentation test. The results show that different aluminum contents in the coating surface lead to different coating phases, mainly Ni2Al3. The change in the coating phases conformed to the Ni-Al binary phase diagram. The Ni-Al coating showed a continuous gradient structure and composition. In addition, the coating also showed continuous gradient variation, relating to the hardness.  
功能梯度镍铝涂层可以提高低碳钢的硬度,使其硬度高,可以适应各种条件。本研究的主要目的是采用镀镍和填充渗铝两步法制备镍铝涂层。采用XRD、SEM和EDS对涂层的物相和形貌进行了表征。随后,使用纳米压痕测试测量Ni-Al涂层的硬度。结果表明:涂层表面铝含量不同导致涂层相不同,主要是Ni2Al3相;镀层相的变化符合Ni-Al二元相图。Ni-Al涂层呈现连续梯度结构和组成。此外,涂层也呈现出连续的梯度变化,这与硬度有关。
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引用次数: 0
EFFECTS OF PRE-OXIDATION ON HOT CORROSION RESISTANCE OF Al–Si COATINGS 预氧化对铝硅涂层耐热腐蚀性能的影响
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.689
R. Palanivel, Soundararaja Perumal Vigneshwaran, Y. Alqurashi, M. A. Rasheed
The joining of aluminium (Al) and copper (Cu) is an essential spot weld for renewable energy applications due to its excellent thermal and electrical conductivity. It is challenging to produce a high-quality Al-Cu spot weld using traditional techniques and the durability of a weldment is also uncertain. A new welding technique that is effective and suitable for spot welding Cu and Al is friction-melt-bonding (FMB) spot welding. The process parameters employed during welding have a strong impact on the quality of a weld. The strategy for integrating the FMB process characteristics, such as tool rotational speed and dwell time, into a mathematical model that may be used for predicting the process parameters of dissimilar spot joints, was the focus of this study. The findings showed that the tensile shear fracture load (TSFL) was significantly influenced by the tool's rotational speed and dwell time. Optimization was carried out using the response surface methodology (RSM) to find the best FMB process parameters for making a dissimilar spot weld of AA 6061-Cu.
铝(Al)和铜(Cu)的连接是可再生能源应用中必不可少的点焊,因为它具有优异的导热性和导电性。使用传统技术生产高质量的铝铜点焊具有挑战性,焊件的耐久性也不确定。摩擦熔接(FMB)点焊是一种有效且适用于铜铝点焊的新型焊接技术。焊接过程中采用的工艺参数对焊缝质量有很大的影响。将FMB工艺特征(如刀具转速和停留时间)集成到一个数学模型中,该模型可用于预测不同点状接头的工艺参数,这是本研究的重点。结果表明,刀具转速和停留时间对拉伸剪切断裂载荷(TSFL)有显著影响。采用响应面法(RSM)对AA 6061-Cu异种点焊FMB工艺参数进行了优化。
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引用次数: 0
AUSCULTATION OF A HEART AND VASCULAR ACTIVITY DURING AURICULAR NERVE STIMULATION 听诊在耳神经刺激时对心脏和血管活动的听诊
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.700
P. Pečlin, J. Rozman, Renata Janež, Nuša Bajželj, S. Ribaric, T. Mirkovic̆
The principal objective of the research was to develop and test a multichannel system intended to capture heart (PCG) and Korotkoff sound (KS) signals in a human model of transcutaneous auricular nerve stimulation (tANS). In particular, the purpose was to develop contact auscultation transducers (transducers) capable of capturing PCG and KS at standard auscultation positions without and during the selective tANS. The scope was to develop transducers capable of capturing body sounds lying in a portion of the frequency spectrum between 20 Hz and 200 Hz. They should be as insensitive as possible to external sound or ambient noise and should be capable of compensating for friction noise due to body movements. The system developed consisted of five transducers, where four of them were intended for the auscultation of PCG generated by heart valves, while one of them was intended to capture KS. The functionality of the transducers was tested in the female model by applying four of transducers to the standard positions on the chest and one over the Brachial artery. The results show that the system developed was highly sensitive to PCG and KS, and less sensitive to external ambient sounds and friction noise. Namely, the S1 and S2 heart-sound peaks are present clearly in the recorded PCG signal as well as during the tANS. It was also shown that during the tANS, heart cycles became slightly shorter and, thus, the heart rhythm slightly higher. Finally, during the tANS, both heart sounds S1 and S2 became louder. In conclusion, the findings provide some evidence that the sounds captured by the transducers emanate from the organs under study and are related to their activity and tANS.
该研究的主要目的是开发和测试一种多通道系统,用于在经皮耳神经刺激(tANS)人体模型中捕获心脏(PCG)和Korotkoff声(KS)信号。特别是,目的是开发接触式听诊传感器(换能器),能够在没有选择性tANS的情况下和在选择性tANS期间捕获标准听诊位置的PCG和KS。其范围是开发能够捕捉20赫兹至200赫兹之间部分频率范围内的身体声音的传感器。它们应该尽可能对外界声音或环境噪音不敏感,并且应该能够补偿由于身体运动而产生的摩擦噪音。该系统由五个传感器组成,其中四个用于听诊由心脏瓣膜产生的PCG,而一个用于捕获KS。在女性模型中,通过将四个换能器放置在胸部的标准位置和一个放置在肱动脉上来测试换能器的功能。结果表明,该系统对PCG和KS具有较高的灵敏度,对外部环境声和摩擦噪声的敏感性较低。也就是说,S1和S2心音峰值在记录的PCG信号中以及在tANS中都清晰地存在。研究还表明,在晒日光浴期间,心脏周期变得略短,因此,心率略高。最后,在tANS过程中,S1和S2的心音都变大了。总之,这些发现提供了一些证据,证明传感器捕获的声音来自所研究的器官,并与它们的活动和tANS有关。
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引用次数: 0
SHRINKAGE BEHAVIOR OF AN ECO-FRIENDLY ENGINEERED CEMENTITIOUS COMPOSITE 一种环保工程胶凝复合材料的收缩特性
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.669
R. R. Infanto, S. A. Kumar
The purpose of the present research is to assess the impact of foundry sand (FS) and cement kiln dust (CKD) on the autogenous shrinkage, drying and total shrinkage of engineered cementitious composites (ECCs) over 100 d. Additionally, the pore sizes and their distribution in the developed ECC system were assessed through the BJH adsorption technique. The findings showed that the pore structure was refined continuously over time. This indicates that the CKD-modified ECC mixes demonstrated decreased autogenous shrinkage at the early and later ages of the 100-d period, although the total shrinkage, developed during the later stages, was comparable to the CKD/FS mixes and conventional ECCs. Specimens with 30 % FS and 15 % CKD inclusions showed significantly fewer medium capillary holes and more gel pores. As the pores in a CKD-modified ECC system are smaller than in the traditional ECC, the modified ECC specimens are denser and show a lower loss of water.
本研究的目的是评估铸造砂(FS)和水泥窑粉尘(CKD)对工程胶凝复合材料(ECCs)在100 d内的自收缩、干燥和总收缩的影响。此外,通过BJH吸附技术评估了所开发的ECC系统的孔隙大小及其分布。结果表明,随着时间的推移,孔隙结构不断细化。这表明,CKD改性ECC混合料在100 d的早期和后期表现出减少的自收缩,尽管在后期发展的总收缩与CKD/FS混合料和常规ECC相当。30% FS和15% CKD包裹体的标本中,中毛细孔明显减少,凝胶孔明显增多。由于ckd改性ECC体系的孔隙比传统ECC更小,因此改性后的ECC试样密度更大,水分损失更小。
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引用次数: 0
ADVANCED MATERIALS AND RESEARCH FOR THE GREEN FUTURE 绿色未来的先进材料和研究
IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-01-25 DOI: 10.17222/mit.2022.717
B. Podgornik
Environmental concerns, such as pollution, greenhouse-gas emissions, sustainability, global warming and climate change, are the biggest challenges of our times. In this respect, the more efficient use of energy and materials combined with technology optimization and innovation are playing a key role in the quest to become a green society with green industry. Multiple environmental and economic benefits can mostly be achieved through novel, lightweight energy-efficient designs. In order to develop and properly use new materials and new designs, complete understanding and information on their properties must be obtained. It is also vital to know how these properties are affected by the conditions of a specific application. Furthermore, as the design of components is pushed towards the limits, unsuitable and outdated measuring methods, measuring uncertainty and deviations from the defined material properties can lead to unexpected premature failure of the component and environmental problems. For the green future, it is extremely important to develop new, advanced materials. However, it is often the changes of the production technology and to the surface of an already-existing material that can achieve great benefits to performance as well as the environment. It is all about modifying the material to perform better, last longer, be biocompatible and achieve different functionalities. Finally, besides high-tech equipment and research facilities, close cooperation between universities, research institutes and industry is needed to develop technologies, functional materials and solutions that can effectively support the journey of our society into a green future
环境问题,如污染、温室气体排放、可持续发展、全球变暖和气候变化,是我们这个时代面临的最大挑战。在这方面,更有效地利用能源和材料,结合技术优化和创新,在寻求成为绿色社会和绿色工业方面发挥着关键作用。多种环境和经济效益大多可以通过新颖的,轻量级的节能设计来实现。为了开发和正确使用新材料和新设计,必须获得对其特性的完整理解和信息。了解这些属性如何受到特定应用程序条件的影响也至关重要。此外,随着部件的设计被推向极限,不合适和过时的测量方法,测量不确定性和偏离定义的材料性能可能导致部件的意外过早失效和环境问题。为了绿色的未来,开发新的先进材料是极其重要的。然而,往往是生产技术的变化和对现有材料表面的改变,才能在性能和环境方面取得巨大的好处。这一切都是关于修改材料,使其性能更好,使用寿命更长,具有生物相容性并实现不同的功能。最后,除了高科技设备和研究设施外,还需要大学、研究机构和工业界密切合作,开发技术、功能材料和解决方案,有效地支持我们的社会走向绿色未来
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引用次数: 0
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