Materials最新文献

Currently, postulated trends and law regulations tend to direct polymer technology toward sustainability and environmentally friendly solutions. These approaches are expressed by keeping materials in a loop aimed at the circular economy and by reducing the environmental burdens related to the production and use of polymers and polymer-based materials. The application of recycled or waste-based materials often deals efficiently with the first issue but at the expense of the final products' performance, which requires various additives, often synthetic and petroleum-based, with limited sustainability. Therefore, a significant portion of research is often required to address the drawbacks induced by the application of secondary raw materials. Herein, the presented study aimed to investigate the fire performance of polymer composites containing highly flammable matrix polyurethane (PU) foam and filler ground tire rubber (GTR) originating from car tire recycling. Due to the nature of both phases and potential applications in the construction and building or automotive sectors, the flammability of these composites should be reduced. Nevertheless, this issue has hardly been analyzed in literature and dominantly in our previous works. Herein, the presented work provided the next step and investigated the input of nanoclays to the synergistic flammability reduction in flexible, foamed PU/GTR composites. Hybrid compositions of organophosphorus FRs with expandable graphite (EG) in varying proportions and with the addition of surface-modified nanoclays were examined. Changes in the parameters obtained during cone calorimeter tests were determined, discussed, and evaluated with the fire performance index and flame retardancy index, two parameters whose goal is to quantify the overall fire performance of polymer-based materials.

In this paper, a morphologically stable composite phase change material (CPCM) suitable for use in the field of building energy conservation was developed using Na₂HPO₄∙12H₂O (DHPD) as the phase change material, Na₂SiO₃∙9H₂O (SSNH) as the nucleating agent, and silica aerogel (SA) as the carrier. The results showed that the incorporation of 25 wt% SA resulted in the as-prepared DHPD-SSNH/SA CPCM with a phase change temperature of 30.4 °C, an enthalpy of 163.4 J/g, and a low supercooling degree of 1.3 °C, which also solved the corrosion problem of reinforcing bars caused by the hydrated salt PCM. Meanwhile, DHPD-SSNH/SA CPCM had good shape stability and low thermal conductivity (0.1507 W/(m·K)). The phase change temperature was basically unchanged, and the enthalpy only decreased by 4.8% after 200 cold-heat cycles. In addition, the thermal performance evaluation of CPCM showed that the indoor thermal comfort time of the testing system loaded with PCM board accounted for 50.75%, which was 43.38% higher than that of the one without PCM board (7.37%). The results suggest that the obtained CPCM had a good energy saving effect and great potential in the field of building energy conservation.

Due to the complexity of the marine corrosive environment, the rebar corrosion in reinforced concrete (RC) bridge piers is usually longitudinal non-uniform. However, the study on the mechanical behavior of longitudinal non-uniformly corroded RC structural members is very limited. To systematically study the deformation performance of the longitudinal non-uniformly corroded RC columns, the finite element models of 106 RC columns with different parameters were established using the commercial software ABAQUS 2016. The effects of the height of the bottom section (represented in the text by the variable "position"), the length, and the rebar corrosion ratio of the corroded segment on the deformation performance of the longitudinal non-uniformly corroded RC columns were analyzed. It is found that the change in the position of the corroded segment on the column may change the most unfavorable section of the column and the failure mode. The length of the corroded segment significantly affects the yield deformation. The ultimate plastic deformation increases with the increase of position or length of the corroded segment. With the increase of rebar corrosion ratio of the corroded segment, the ultimate plastic deformation decreases.

Aerogels have gained increasing attention due to their unique properties since their introduction in 1932. Silica aerogel, one of the earliest and most advanced types, is known for its high transparency and excellent thermal insulation. However, its internal pearl-like structure makes it extremely brittle, which limits its practical applications. To address this, through multiple refinements in formulation and production techniques, we developed a novel Polyvinyl Alcohol (PVA) aerogel using an innovative one-step standing method. This method significantly reduces the gelling time compared to the freeze-thaw method and eliminates the need for refrigeration, making it a more environmentally friendly and sustainable process. The resulting one-step standing PVA aerogel features a hierarchical porous structure, remarkable transparency, improved strength, and enhanced thermal insulation. Mechanical tests demonstrated that the PVA aerogel produced by the one-step standing method exhibited a significantly higher Young's modulus of 4.2596 MPa, surpassing that of silica, copper nanowire (Cu NM), and graphene aerogels. Additional tests, including transmittance and thermal analysis, further confirmed that the one-step standing PVA aerogel excels in both transparency and thermal insulation. This combination of improved mechanical performance and light transmission opens novel potential applications, such as drug delivery systems, where the aerogel's pore structure can store drugs while maintaining strength and transparency.

A dense monolithic SiC/(Hf_0.25Ta_0.25Zr_0.25Nb_0.25)C/C high-entropy ceramic nanocomposite was prepared using a polymer-derived ceramic (PDC) method combined with spark plasma sintering (SPS). The microstructural evolution and mechanical properties of the obtained nanocomposites were characterized by X-ray diffractometer (XRD), transmission electron microscope (TEM), scanning-electron microscope (SEM), and nanoindentation. The results indicate that the phase composition of SiC/(Hf_0.25Ta_0.25Zr_0.25Nb_0.25)C/C can be adjusted by modifying the metal content of the single-source precursor (SSP) through molecular design. The resulting precursor exhibits an exceptionally high ceramic yield, with mass retention of over 90% at 1100 °C, which guarantees the densification of the final SiC/(Hf_0.25Ta_0.25Zr_0.25Nb_0.25)C/C composites. The PDC route facilitates the in situ formation of a high-entropy phase within the ceramic matrix under low temperature pyrolysis conditions. Combined with SPS, a dense monolithic SiC/(Hf_0.25Ta_0.25Zr_0.25Nb_0.25)C/C nanocomposite was obtained, exhibiting an open porosity of 0.41 vol%, nano-hardness of 27.47 ± 0.46 GPa, elastic modulus of 324.00 ± 13.60 GPa, and fracture toughness of 3.59 ± 0.24 MPa·m^0.5, demonstrating excellent mechanical properties.

Quantum dots (QDs) are becoming essential materials for future scientific and real-world applications, owing to their interesting and distinct optical and electrical properties compared to their bulk-state counterparts. The ability to tune the bandgap of QDs based on size and composition-a key characteristic-opens up new possibilities for enhancing the performance of various optoelectronic devices. These advances could extend to cutting-edge applications such as ultrawide-band or dual-band photodetectors (PDs), optoelectronic logic gates, neuromorphic devices, and security functions. This paper revisits the recent progress in QD-embedded optoelectronic applications, focusing on bandgap tunability. The current limitations and challenges in advancing and realizing QD-based optoelectronic devices are also discussed.

Graphene oxide (GO) has recently gained significant attention in electrocatalysis as a promising electrode material owing to its unique physiochemical properties such as enhanced electron transfers due to a conjugated π-electron system, high surface area, and stable support for loading electroactive species, including metal nanoparticles. However, only a few studies have been directed toward the structural characteristics of GO, elaborating on the roles of oxygen-containing functional groups, the presence of defects, interlayer spacing between the layered structure, and nonuniformity in the carbon skeleton along with their influence on electrochemical performance. In this work, we aim to understand these properties in various GO materials derived from different graphitic sources. Both physiochemical and electrochemical characterization were employed to correlate the above-mentioned features and explore the effect of the location of the palladium nanoparticles (Pd NPs) on various GO supports for the hydrogen evolution reaction (HER). The interaction of the functional groups has a crucial role in the Pd dispersion and its electrochemical performance. Among the different GO samples, Pd supported on GO derived from graphene nanoplate (GNP), Pd/GO-GNP, exhibits superior HER performance; this could be attributed to the optimal balance among particle size, defect density, less in-plane functionalities, and higher electrochemical surface area. This study, thus, helps to identify the optimal conditions that lead to the best performance of Pd-loaded GO, contributing to the design of more effective HER electrocatalysts.

The current intensive development of steelmaking is being impeded by a scarcity of pure scrap. The potential to replace pure scrap with metallized raw materials that are naturally alloyed with vanadium and titanium, such as annealed unfluxed titanomagnetite pellets, could facilitate the achievement of key objectives in metallurgical development, particularly in the smelting of electric steel. The objective of this research was to produce annealed and metallized pellets from titanomagnetite concentrate under laboratory conditions, with the intention of further processing them as a commercial product in a blast furnace or as an intermediate product for the production of hot briquetted iron (HBI). The results demonstrate that pellets derived from titanomagnetite concentrate exhibit sufficient compressive strength (up to 300 kg/pellet) and a degree of metallization exceeding 90%, which aligns with the requirements for electric steelmaking. The suitability of pellets derived from titanomagnetite concentrate for use in both blast furnaces and metallization processes has been corroborated.

The multi-parameter characteristics of the physical model pose a challenge to the fatigue life prediction of 2024-T3 aluminum (Al) alloy. In response to this issue, a parameter-solving method that integrates particle swarm optimization (PSO) with extreme gradient boosting (XGBoost) is proposed in this study. The fatigue performance and failure mechanism of the 2024-T3 Al alloy are analyzed. Furthermore, the fatigue life prediction physical model of the 2024-T3 Al alloy is established by using the energy method of fracture mechanics. The physical model incorporates critical physical parameters. Meanwhile, the PSO algorithm optimizes the hyperparameters of the XGBoost model based on fatigue data of the 2024-T3 Al alloy. Eventually, the optimized XGBoost model is used to solve the parameters of the physical model. Furthermore, the analytical equation of the fatigue life prediction model is obtained. This paper provides a new method for solving the parameters of the fatigue life prediction model, which reduces the error and cost of obtaining the model parameters in the experiment and shortens the time required.

This article presents the first use of shape forming elements (SFEs) to produce architected composites from multiple materials in an extrusion process. Each SFE contains a matrix of flow channels connecting input and output ports, where materials are routed between corresponding ports. The mathematical operations of rotation and shifting are described, and design automation is explored using Bayesian optimization and genetic algorithms to select fifty or more parameters for minimizing two objective functions. The first objective aims to match a target cross-section by minimizing the pixel-by-pixel error, which is weighted with the structural similarity index (SSIM). The second objective seeks to maximize information content by minimizing the SSIM relative to a white image. Satisfactory designs are achieved with better objective function values observed in rectangular rather than square flow channels. Validation extrusion of modeling clay demonstrates that while SFEs impose complex material transformations, they do not achieve the material distributions predicted by the digital model. Using the SSIM for results comparison, initial stages yielded SSIM values near 0.8 between design and simulation, indicating a good initial match. However, the control of material processing tended to decline with successive SFE processing with the SSIM of the extruded output dropping to 0.023 relative to the design intent. Flow simulations more closely replicated the observed structures with SSIM values around 0.4 but also failed to predict the intended cross-sections. The evaluation highlights the need for advanced modeling techniques to enhance the predictive accuracy and functionality of SFEs for biomedical, energy storage, and structural applications.