Joanna Janiszewska-Olszowska, Agnieszka Droździk, Katarzyna Tandecka, Katarzyna Grocholewicz
Composite restorations are inevitably exposed to prophylactic procedures associated with a risk of surface damage (loss of substance and roughening). The aim of the present study was to compare the effect of air-polishing with three different powders of reduced abrasiveness on composite fillings. Forty-eight specimens of microhybrid light-cure composite were randomly divided into three groups (n = 16 each), scanned in 3D and air-polished with the following: sodium bicarbonate (40 µm), glycine (25 µm) and erythritol (14 µm), respectively. Then, the specimens were rescanned and the data were processed in specialized 3D analysis software. Loss of composite material was visible in all specimens. The estimated mean composite volume loss was higher for sodium bicarbonate and erythritol (0.09 mm3 and 0.08 mm3, respectively) than for glycine (0.05 mm3). No statistically significant differences were found between sodium bicarbonate and erythritol. Powder particles were additionally characterized from SEM images (N = 1600 per powder), using equivalent circular diameter (ECD) and shape descriptors (aspect ratio and circularity). Therefore, glycine powder should be preferred when the primary goal is minimizing composite abrasion. When higher composite material removal is acceptable, erythritol and sodium bicarbonate may be considered to be interchangeable under the present conditions due to their comparable abrasive effect.
{"title":"Effect of Air-Polishing on 3D Surface Integrity of Composite Dental Restorations-Comparison of Three Different Powders with Reduced Abrasiveness.","authors":"Joanna Janiszewska-Olszowska, Agnieszka Droździk, Katarzyna Tandecka, Katarzyna Grocholewicz","doi":"10.3390/ma19010140","DOIUrl":"10.3390/ma19010140","url":null,"abstract":"<p><p>Composite restorations are inevitably exposed to prophylactic procedures associated with a risk of surface damage (loss of substance and roughening). The aim of the present study was to compare the effect of air-polishing with three different powders of reduced abrasiveness on composite fillings. Forty-eight specimens of microhybrid light-cure composite were randomly divided into three groups (n = 16 each), scanned in 3D and air-polished with the following: sodium bicarbonate (40 µm), glycine (25 µm) and erythritol (14 µm), respectively. Then, the specimens were rescanned and the data were processed in specialized 3D analysis software. Loss of composite material was visible in all specimens. The estimated mean composite volume loss was higher for sodium bicarbonate and erythritol (0.09 mm<sup>3</sup> and 0.08 mm<sup>3</sup>, respectively) than for glycine (0.05 mm<sup>3</sup>). No statistically significant differences were found between sodium bicarbonate and erythritol. Powder particles were additionally characterized from SEM images (N = 1600 per powder), using equivalent circular diameter (ECD) and shape descriptors (aspect ratio and circularity). Therefore, glycine powder should be preferred when the primary goal is minimizing composite abrasion. When higher composite material removal is acceptable, erythritol and sodium bicarbonate may be considered to be interchangeable under the present conditions due to their comparable abrasive effect.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12787085/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tomasz Kozior, Jerzy Bochnia, Jiri Hajnys, Jakub Mesicek
The aim of the presented research is to assess the possibility of manufacturing thin-walled models using innovative 3D printing technology and to determine limitations. This article presents the results of tensile tests of the Continuous Filament Fabrication (CFF) technology for thin-walled sample models. Two types of materials were tested. The first material is pure ONYX based on polyamide, and the second is ONYX with an additional core made of carbon fiber. The paper presents the limitations of using the core in thin-walled structures, and for pure ONYX material, samples were made with different orientations on the 3D printer platform, which allowed determining the effect of the printing direction on the mechanical properties of the samples. In addition, microscopic photographs of the fracture of the broken samples were taken in the paper, based on which the defects of the technological process were identified. It was shown that the strength of thin-walled samples (1 mm, 1.4 mm, and 1.8 mm thick) printed in the Y direction is significantly greater than that of samples printed in the X and Z directions. For example, for 1 mm thick samples printed in the Y direction, the strength is 49.02 MPa, while for samples printed in the X and Z directions, it is 27.71 MPa and 21.28 MPa, respectively. The strength of samples (4 mm thick) reinforced with ONYX + OCF carbon fiber printed in the X direction is 191.36% greater than that of samples made of pure ONYX.
{"title":"Continuous Filament Fabrication Technology and Its Mechanical Properties for Thin-Walled Component.","authors":"Tomasz Kozior, Jerzy Bochnia, Jiri Hajnys, Jakub Mesicek","doi":"10.3390/ma19010144","DOIUrl":"10.3390/ma19010144","url":null,"abstract":"<p><p>The aim of the presented research is to assess the possibility of manufacturing thin-walled models using innovative 3D printing technology and to determine limitations. This article presents the results of tensile tests of the Continuous Filament Fabrication (CFF) technology for thin-walled sample models. Two types of materials were tested. The first material is pure ONYX based on polyamide, and the second is ONYX with an additional core made of carbon fiber. The paper presents the limitations of using the core in thin-walled structures, and for pure ONYX material, samples were made with different orientations on the 3D printer platform, which allowed determining the effect of the printing direction on the mechanical properties of the samples. In addition, microscopic photographs of the fracture of the broken samples were taken in the paper, based on which the defects of the technological process were identified. It was shown that the strength of thin-walled samples (1 mm, 1.4 mm, and 1.8 mm thick) printed in the Y direction is significantly greater than that of samples printed in the X and Z directions. For example, for 1 mm thick samples printed in the Y direction, the strength is 49.02 MPa, while for samples printed in the X and Z directions, it is 27.71 MPa and 21.28 MPa, respectively. The strength of samples (4 mm thick) reinforced with ONYX + OCF carbon fiber printed in the X direction is 191.36% greater than that of samples made of pure ONYX.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12787027/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dawei Wang, Peidong Du, Jiping Wang, Zhenqiang Han, Xiong Lan
The increasing number of waste rubber tires has attracted the attention of more and more researchers. Rubber asphalt has better performance compared with original asphalt. However, the compatibility between rubber powder and asphalt is poor because of the difference in physical and chemical properties and the improvement of high-temperature performance of asphalt by rubber powder is very limited. The compatibility between rubber powder and original asphalt plays a key role in the storage stability and rheological performance of rubber asphalt. This paper provides a comprehensive overview of rubber asphalt, factors influencing compatibility, compatibility evaluation methods, and improvement approaches. Desired compatibility results from the fact that rubber powder is cross-linked with molecules of original asphalt and evenly distributed in the original asphalt, forming a homogeneous system. Starting from the preparation process of rubber asphalt, the best preparation process was summarized. Then the activity of rubber powder is improved by physical and chemical methods, or other additives are added to finally promote the formation of a cross-linking network structure between rubber powder and original asphalt. Rheological method is the most widely used method in compatibility evaluation, but it is gradually accepted by researchers to evaluate the compatibility by observing the molecular morphology of rubber asphalt.
{"title":"A Review of Compatibility Evaluation Methods and Improvement Measures Between Rubber Powder and Base Asphalt.","authors":"Dawei Wang, Peidong Du, Jiping Wang, Zhenqiang Han, Xiong Lan","doi":"10.3390/ma19010139","DOIUrl":"10.3390/ma19010139","url":null,"abstract":"<p><p>The increasing number of waste rubber tires has attracted the attention of more and more researchers. Rubber asphalt has better performance compared with original asphalt. However, the compatibility between rubber powder and asphalt is poor because of the difference in physical and chemical properties and the improvement of high-temperature performance of asphalt by rubber powder is very limited. The compatibility between rubber powder and original asphalt plays a key role in the storage stability and rheological performance of rubber asphalt. This paper provides a comprehensive overview of rubber asphalt, factors influencing compatibility, compatibility evaluation methods, and improvement approaches. Desired compatibility results from the fact that rubber powder is cross-linked with molecules of original asphalt and evenly distributed in the original asphalt, forming a homogeneous system. Starting from the preparation process of rubber asphalt, the best preparation process was summarized. Then the activity of rubber powder is improved by physical and chemical methods, or other additives are added to finally promote the formation of a cross-linking network structure between rubber powder and original asphalt. Rheological method is the most widely used method in compatibility evaluation, but it is gradually accepted by researchers to evaluate the compatibility by observing the molecular morphology of rubber asphalt.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12786771/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aluminum-based brazing alloys have been developed for joining 7072 high-strength aluminum alloys. However, challenges related to their high melting points and joint softening still require further exploration. This study employs a combination of first-principles calculations and experimental techniques to examine the microstructure and mechanical properties of 7072 aluminum alloy joints brazed with (Ni, Y)-modified Al-Si-Cu-Zn filler alloys. Through the virtual crystal approximation (VCA) method, it was observed that the Al-10Si-10Cu-5Zn-xNi-yY (x = 0, 1.0, 2.0, 3.0, y = 0.2, 0.4, 0.6) filler alloy exhibits excellent mechanical stability, combining both high strength and reasonable ductility. Seven brazed joint samples with varying Ni and Y contents were fabricated using melting brazing and analyzed. The findings showed that Ni reduces the liquidus temperature of the filler, narrowing the melting range. This facilitates the conversion of the brittle Al2Cu phase into a more ductile Al2(Cu,Ni) phase, thus enhancing joint strength. Y acts as a heterogeneous nucleation site, promoting local undercooling, increasing the nucleation rate, and refining the microstructure. When the Ni content was 2.0 wt.% and the Y content was 0.4 wt.%, the tensile strength of the brazed joint reached a peak value of 295.1 MPa. Computational predictions align with the experimental results, confirming that first-principles calculations are a reliable method for predicting the properties of aluminum alloy brazing materials.
{"title":"Microstructure and Mechanical Properties of 7072 Aluminum Alloy Joints Brazed Using (Ni, Y)-Modified Al-Si-Cu-Zn Filler Alloys.","authors":"Wei Guo, Ruihua Zhang, Zhen Xue, Hui Wang, Xinyu Zhang","doi":"10.3390/ma19010138","DOIUrl":"10.3390/ma19010138","url":null,"abstract":"<p><p>Aluminum-based brazing alloys have been developed for joining 7072 high-strength aluminum alloys. However, challenges related to their high melting points and joint softening still require further exploration. This study employs a combination of first-principles calculations and experimental techniques to examine the microstructure and mechanical properties of 7072 aluminum alloy joints brazed with (Ni, Y)-modified Al-Si-Cu-Zn filler alloys. Through the virtual crystal approximation (VCA) method, it was observed that the Al-10Si-10Cu-5Zn-<i>x</i>Ni-<i>y</i>Y (x = 0, 1.0, 2.0, 3.0, y = 0.2, 0.4, 0.6) filler alloy exhibits excellent mechanical stability, combining both high strength and reasonable ductility. Seven brazed joint samples with varying Ni and Y contents were fabricated using melting brazing and analyzed. The findings showed that Ni reduces the liquidus temperature of the filler, narrowing the melting range. This facilitates the conversion of the brittle Al<sub>2</sub>Cu phase into a more ductile Al<sub>2</sub>(Cu,Ni) phase, thus enhancing joint strength. Y acts as a heterogeneous nucleation site, promoting local undercooling, increasing the nucleation rate, and refining the microstructure. When the Ni content was 2.0 wt.% and the Y content was 0.4 wt.%, the tensile strength of the brazed joint reached a peak value of 295.1 MPa. Computational predictions align with the experimental results, confirming that first-principles calculations are a reliable method for predicting the properties of aluminum alloy brazing materials.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12787186/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu Liu, Xiaoyuan Guo, Min Wang, Kaixing Yao, Huiqing Dong, Yafan Li, Zhidong Wang, Feng Wang, Rui Luo
Incoloy 800H is important structural alloy for heat exchange tubes of Generation IV nuclear power systems. Revealing the key heat treatment effects on the microstructure and corrosion behavior of 800H is a key issue for its performance optimization and safe application in IV nuclear power industries. This work investigated the solid solution heat treatment-microstructure-corrosion resistance relationship using various electrochemical corrosion techniques and morphology characterizations. The results showed that 1120 °C was an insufficient solid solution heat treatment temperature for 800H, at which 800H demonstrated uneven enlargement of grains and undissolved Cr-carbides, which resulted in fast corrosion. 800H demonstrated even growth of grains with best grain uniformity and dissolution of Cr-carbides at 1150 °C, thus showing the best corrosion resistance. However, the further increase in solid solution temperature to 1180 °C resulted in excessive grain growth and severe intergranular corrosion (IGC) attack. This work deepened the understanding of the corrosion mechanism of 800H and provided data for its performance optimization.
{"title":"Effects of Solid Solution Heat Treatment on the Corrosion Behavior of 800H Used in Fourth-Generation Nuclear Power Generators.","authors":"Yu Liu, Xiaoyuan Guo, Min Wang, Kaixing Yao, Huiqing Dong, Yafan Li, Zhidong Wang, Feng Wang, Rui Luo","doi":"10.3390/ma19010143","DOIUrl":"10.3390/ma19010143","url":null,"abstract":"<p><p>Incoloy 800H is important structural alloy for heat exchange tubes of Generation IV nuclear power systems. Revealing the key heat treatment effects on the microstructure and corrosion behavior of 800H is a key issue for its performance optimization and safe application in IV nuclear power industries. This work investigated the solid solution heat treatment-microstructure-corrosion resistance relationship using various electrochemical corrosion techniques and morphology characterizations. The results showed that 1120 °C was an insufficient solid solution heat treatment temperature for 800H, at which 800H demonstrated uneven enlargement of grains and undissolved Cr-carbides, which resulted in fast corrosion. 800H demonstrated even growth of grains with best grain uniformity and dissolution of Cr-carbides at 1150 °C, thus showing the best corrosion resistance. However, the further increase in solid solution temperature to 1180 °C resulted in excessive grain growth and severe intergranular corrosion (IGC) attack. This work deepened the understanding of the corrosion mechanism of 800H and provided data for its performance optimization.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12786482/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this article, the thermal and mechanical properties of mortars reinforced with polypropylene (PP) fibres have been studied. Particularly, the effect of polypropylene fibres' addition on the thermal behaviour of fine-grained building mortars at high temperatures was studied using simultaneous thermal analysis. Two types of polypropylene fibres, differing in shape and size, were used as fillers. The thermal behaviour of cement mortar samples with and without fibres was described. Special attention was given to the thermal behaviour of fibre-reinforced cement mortars subjected to the high temperatures of 100 °C, 200 °C, 300 °C, 400 °C, 500 °C, and 600 °C. Comparative studies using simultaneous thermal analysis (STA) were also performed for non-heated samples (20 °C). The TG, DTG, and DTA curves were analysed to investigate the effects related to the dehydration and the decomposition of hydration and carbonation products. Compared to mortar samples without fibres, the results showed that the presence of polypropylene fibres contributes to an increase in the thermal stability of the samples. It has been proven that the impact of the type and amount of PP fibres in the tested range (1.8 kg/m3 vs. 3.6 kg/m3) on the thermal stability of specimens of tested cement composites was found not to be significantly visible. Next, extensive research was performed on the impact of fire environmental exposure on the variability in the strength parameters of the mortars. Tensile strength tests were conducted based on the standards specified by the Polish Committee for Standardization. The research material consisted of high-strength, fine-grained building mortars, modified by an original method with polypropylene fibres at concentration of 1.8 kg/m3, 3.0 kg/m3, and 3.6 kg/m3. For reference, ordinary mortars without fibres were used, as well. Tensile strength was evaluated for mortar samples, which were exposed to temperatures of 100 °C, 200 °C, 300 °C, 400 °C, 500 °C, and 600 °C, respectively. Special attention was paid to the thermal behaviour of cement mortars reinforced with polypropylene (PP) fibres, subjected to high temperatures. Based on the obtained test results, a detailed statistical analysis was developed, along with comprehensive temperature-parameter relationships, which could enable an approximate post-failure assessment of the mortar's condition. The main outcomes of this paper include optimal fibre dosage, which is 3.6 kg/m3, identified optimal fibre type, namely F fibre, as well as plateau in tensile strength for temperatures between 200 °C and 400 °C for fibre-reinforced samples.
本文研究了聚丙烯纤维增强砂浆的热性能和力学性能。采用同步热分析的方法,研究了聚丙烯纤维的加入对细粒建筑砂浆高温下热性能的影响。两种形状和尺寸不同的聚丙烯纤维被用作填料。描述了含纤维和不含纤维水泥砂浆试样的热性能。特别关注纤维增强水泥砂浆在100°C、200°C、300°C、400°C、500°C和600°C高温下的热行为。使用同步热分析(STA)的比较研究也对未加热的样品(20°C)进行了比较。分析TG、DTG和DTA曲线,探讨脱水和水化碳酸产物分解的影响。与不含纤维的砂浆样品相比,结果表明聚丙烯纤维的存在有助于提高样品的热稳定性。已经证明,在测试范围内(1.8 kg/m3 vs. 3.6 kg/m3) PP纤维的类型和数量对测试水泥复合材料样品的热稳定性的影响并不明显。其次,对火灾环境暴露对砂浆强度参数变化的影响进行了广泛的研究。拉伸强度测试是根据波兰标准化委员会规定的标准进行的。研究材料由高强度、细粒建筑砂浆组成,采用原方法改性聚丙烯纤维,浓度分别为1.8 kg/m3、3.0 kg/m3和3.6 kg/m3。作为参考,也使用了没有纤维的普通迫击炮。砂浆样品分别暴露在100°C、200°C、300°C、400°C、500°C和600°C的温度下,对其拉伸强度进行了评估。特别注意用聚丙烯(PP)纤维增强水泥砂浆在高温下的热行为。基于获得的测试结果,开发了详细的统计分析,以及全面的温度-参数关系,可以对砂浆的状态进行近似的破坏后评估。本文的主要成果包括最佳纤维用量为3.6 kg/m3,确定了最佳纤维类型,即F纤维,以及纤维增强样品在200°C至400°C之间的拉伸强度平台。
{"title":"Thermoanalytical and Tensile Strength Studies of Polypropylene Fibre-Reinforced Cement Composites Designed for Tunnel Applications.","authors":"Tomasz Drzymała, Ewa Rudnik, Sylwia Lewicka","doi":"10.3390/ma19010142","DOIUrl":"10.3390/ma19010142","url":null,"abstract":"<p><p>In this article, the thermal and mechanical properties of mortars reinforced with polypropylene (PP) fibres have been studied. Particularly, the effect of polypropylene fibres' addition on the thermal behaviour of fine-grained building mortars at high temperatures was studied using simultaneous thermal analysis. Two types of polypropylene fibres, differing in shape and size, were used as fillers. The thermal behaviour of cement mortar samples with and without fibres was described. Special attention was given to the thermal behaviour of fibre-reinforced cement mortars subjected to the high temperatures of 100 °C, 200 °C, 300 °C, 400 °C, 500 °C, and 600 °C. Comparative studies using simultaneous thermal analysis (STA) were also performed for non-heated samples (20 °C). The TG, DTG, and DTA curves were analysed to investigate the effects related to the dehydration and the decomposition of hydration and carbonation products. Compared to mortar samples without fibres, the results showed that the presence of polypropylene fibres contributes to an increase in the thermal stability of the samples. It has been proven that the impact of the type and amount of PP fibres in the tested range (1.8 kg/m<sup>3</sup> vs. 3.6 kg/m<sup>3</sup>) on the thermal stability of specimens of tested cement composites was found not to be significantly visible. Next, extensive research was performed on the impact of fire environmental exposure on the variability in the strength parameters of the mortars. Tensile strength tests were conducted based on the standards specified by the Polish Committee for Standardization. The research material consisted of high-strength, fine-grained building mortars, modified by an original method with polypropylene fibres at concentration of 1.8 kg/m<sup>3</sup>, 3.0 kg/m<sup>3</sup>, and 3.6 kg/m<sup>3</sup>. For reference, ordinary mortars without fibres were used, as well. Tensile strength was evaluated for mortar samples, which were exposed to temperatures of 100 °C, 200 °C, 300 °C, 400 °C, 500 °C, and 600 °C, respectively. Special attention was paid to the thermal behaviour of cement mortars reinforced with polypropylene (PP) fibres, subjected to high temperatures. Based on the obtained test results, a detailed statistical analysis was developed, along with comprehensive temperature-parameter relationships, which could enable an approximate post-failure assessment of the mortar's condition. The main outcomes of this paper include optimal fibre dosage, which is 3.6 kg/m<sup>3</sup>, identified optimal fibre type, namely F fibre, as well as plateau in tensile strength for temperatures between 200 °C and 400 °C for fibre-reinforced samples.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12786535/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145945023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Roxana-Elena Cristian, Cornel Balta, Hildegard Herman, Alina Ciceu, Bogdan Trica, Beatrice G Sbarcea, Eftimie Miutescu, Anca Hermenean, Anca Dinischiotu, Miruna S Stan
In the original publication [...].
在原出版物中[…]。
{"title":"Correction: Cristian et al. Exploring In Vivo Pulmonary and Splenic Toxicity Profiles of Silicon Quantum Dots in Mice. <i>Materials</i> 2024, <i>17</i>, 2778.","authors":"Roxana-Elena Cristian, Cornel Balta, Hildegard Herman, Alina Ciceu, Bogdan Trica, Beatrice G Sbarcea, Eftimie Miutescu, Anca Hermenean, Anca Dinischiotu, Miruna S Stan","doi":"10.3390/ma19010141","DOIUrl":"10.3390/ma19010141","url":null,"abstract":"<p><p>In the original publication [...].</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12786399/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study systematically investigates the effects of Fe and Si impurities on the microstructure and mechanical properties of Al-Cu-Li alloys. Five alloy compositions with controlled Fe (0.03-0.12 wt.%) and Si (0.03-0.12 wt.%) contents were fabricated and processed through homogenization, hot extrusion, solution treatment, and aging. Microstructural characterization demonstrates that Fe promotes the formation of coarse skeletal Al7Cu2Fe intermetallics, while Si facilitates the precipitation of blocky α-AlFeSi phases and eutectic Si particles. An elevated Fe content substantially deteriorates strength, ductility, and fracture toughness, primarily due to two mechanisms: the persistence of thermally stable impurity phases that serve as stress concentrators and preferential crack initiation sites throughout thermomechanical processing, and the consumption of Cu that reduces the volume fraction of primary T1 (Al2CuLi) strengthening precipitates. In contrast, Si exhibits comparatively moderate detrimental effects. The findings establish that stringent Fe control is essential for maintaining mechanical performance, whereas strategic Si adjustment offers a viable approach for cost management in recycled alloy production.
{"title":"Effect of Fe and Si Content on Microstructure and Properties of Al-Cu-Li Alloys.","authors":"Tianyi Feng, Wei Zhao, Changlin Li, Ying Li, Xiwu Li, Zhicheng Liu, Lizhen Yan, Pengfei Xu, Hongwei Yan, Yongan Zhang, Zhihui Li, Baiqing Xiong","doi":"10.3390/ma19010147","DOIUrl":"10.3390/ma19010147","url":null,"abstract":"<p><p>This study systematically investigates the effects of Fe and Si impurities on the microstructure and mechanical properties of Al-Cu-Li alloys. Five alloy compositions with controlled Fe (0.03-0.12 wt.%) and Si (0.03-0.12 wt.%) contents were fabricated and processed through homogenization, hot extrusion, solution treatment, and aging. Microstructural characterization demonstrates that Fe promotes the formation of coarse skeletal Al<sub>7</sub>Cu<sub>2</sub>Fe intermetallics, while Si facilitates the precipitation of blocky α-AlFeSi phases and eutectic Si particles. An elevated Fe content substantially deteriorates strength, ductility, and fracture toughness, primarily due to two mechanisms: the persistence of thermally stable impurity phases that serve as stress concentrators and preferential crack initiation sites throughout thermomechanical processing, and the consumption of Cu that reduces the volume fraction of primary T<sub>1</sub> (Al<sub>2</sub>CuLi) strengthening precipitates. In contrast, Si exhibits comparatively moderate detrimental effects. The findings establish that stringent Fe control is essential for maintaining mechanical performance, whereas strategic Si adjustment offers a viable approach for cost management in recycled alloy production.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12786567/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiandong Guan, Yi Li, Guoming Zhu, Yonglin Kang, Feng Wang, Jun Xu, Meng Xun
With the rapid development of the automotive industry, particularly the year-on-year growth in sales of new energy vehicles, automobile outer panel materials have shown a trend toward high-strength lightweight solutions. Regarding steel for outer panels, existing research has paid less attention to the UF steel that has entered the market in recent years. Moreover, studies on the similarities and differences in deformation behavior among various outer panel steels are lacking. In this study, room-temperature tensile tests at 5% and 8% strain were conducted in accordance with the stamping deformation range on commonly used ultra-low carbon automotive outer panel steels of comparable strength grades, namely, UF340, HC180BD, and DX53D+Z. Prior to deformation, the three materials exhibited similar texture components, predominantly characterized by the γ-fiber texture beneficial for deep drawing, and their room-temperature tensile deformation behaviors were fundamentally identical. After transverse tensile deformation, the textures concentrated towards {111}<112> texture. After 8% deformation, UF340 demonstrated a more rapid stress increase and a higher degree of work hardening. This phenomenon is attributed to the presence of the precipitate free zone (PFZ) near grain boundaries in the UF340, which facilitates the continuous generation of dislocations at grain boundaries during deformation, leading to a rapid increase in dislocation density within the grains. Consequently, this induces accelerated work hardening under small-strain conditions. This mechanism enables UF steels to achieve a strength level comparable to that of bake-hardened (BH) steels, exhibiting a significant performance advantage.
{"title":"Research on Microstructure Evolution and Rapid Hardening Mechanism of Ultra-Low Carbon Automotive Outer Panel Steel Under Minor Deformation.","authors":"Jiandong Guan, Yi Li, Guoming Zhu, Yonglin Kang, Feng Wang, Jun Xu, Meng Xun","doi":"10.3390/ma19010128","DOIUrl":"10.3390/ma19010128","url":null,"abstract":"<p><p>With the rapid development of the automotive industry, particularly the year-on-year growth in sales of new energy vehicles, automobile outer panel materials have shown a trend toward high-strength lightweight solutions. Regarding steel for outer panels, existing research has paid less attention to the UF steel that has entered the market in recent years. Moreover, studies on the similarities and differences in deformation behavior among various outer panel steels are lacking. In this study, room-temperature tensile tests at 5% and 8% strain were conducted in accordance with the stamping deformation range on commonly used ultra-low carbon automotive outer panel steels of comparable strength grades, namely, UF340, HC180BD, and DX53D+Z. Prior to deformation, the three materials exhibited similar texture components, predominantly characterized by the γ-fiber texture beneficial for deep drawing, and their room-temperature tensile deformation behaviors were fundamentally identical. After transverse tensile deformation, the textures concentrated towards {111}<112> texture. After 8% deformation, UF340 demonstrated a more rapid stress increase and a higher degree of work hardening. This phenomenon is attributed to the presence of the precipitate free zone (PFZ) near grain boundaries in the UF340, which facilitates the continuous generation of dislocations at grain boundaries during deformation, leading to a rapid increase in dislocation density within the grains. Consequently, this induces accelerated work hardening under small-strain conditions. This mechanism enables UF steels to achieve a strength level comparable to that of bake-hardened (BH) steels, exhibiting a significant performance advantage.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12787252/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This article presents the results of research on a composite filament made of a thermoplastic polymer with the addition of steel powder, used to produce samples using Fused Deposition Modeling (FDM) 3D printing technology. Samples were printed with different print orientations (0° and 90°) to assess the effect of print direction on mechanical and tribological properties. Sample hardness was tested using the Shore D method. Wettability was determined by measuring the contact angle using an optical tensiometer. Tribological wear tests were conducted using the ball-on-disk method. During the tests, the friction coefficient was recorded, and the wear traces were analyzed using an optical microscope. Friction-wear tests were conducted under dry friction conditions and with a physiological saline solution. The obtained results allowed for determining the relationship between print orientation and the mechanical properties and wear resistance of the analyzed composite material.
{"title":"Effect of Print Orientation on the Tribological Behavior of a Steel Powder-Modified Thermoplastic.","authors":"Krystyna Radoń-Kobus, Paweł Szczygieł","doi":"10.3390/ma19010132","DOIUrl":"10.3390/ma19010132","url":null,"abstract":"<p><p>This article presents the results of research on a composite filament made of a thermoplastic polymer with the addition of steel powder, used to produce samples using Fused Deposition Modeling (FDM) 3D printing technology. Samples were printed with different print orientations (0° and 90°) to assess the effect of print direction on mechanical and tribological properties. Sample hardness was tested using the Shore D method. Wettability was determined by measuring the contact angle using an optical tensiometer. Tribological wear tests were conducted using the ball-on-disk method. During the tests, the friction coefficient was recorded, and the wear traces were analyzed using an optical microscope. Friction-wear tests were conducted under dry friction conditions and with a physiological saline solution. The obtained results allowed for determining the relationship between print orientation and the mechanical properties and wear resistance of the analyzed composite material.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"19 1","pages":""},"PeriodicalIF":3.2,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12787268/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145944907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}