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Time of protection equivalence principle to allow design barrier layers for promoting the use of recycled materials for food contact 保护时间等效原理允许设计屏障层,促进使用可回收材料进行食品接触
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337906001
Natacha Daoud, C. Breysse, S. Domenek, O. Vitrac
European and national environmental protection policies have programmed the forthcoming end of single-use plastics, including food packaging. Because plastic materials account for 50% of plastic waste, closed-loop recycling seems imperative. Still, plastics other than PET (Polyethylene terephthalate) are not widely recycled for food contact due to safety concerns. Among them, postconsumer polyolefins are heavily formulated, degraded, and contaminated by the previously contacting product. Using recycled materials behind a functional barrier (FB) could resolve the issue under specific provisions, but neither the European regulation nor the US FDA offer guidance concerning functional barriers evaluation and use. Mathematical modeling is the only viable method recognized by European and American agencies to evaluate recycled material under usage conditions. This study numerically explores the possibility of combining two effects: decontamination of the recycled material and a functional barrier to allow safe use of the recycled material.
欧洲和各国的环境保护政策已经规划了即将结束的一次性塑料,包括食品包装。由于塑料材料占塑料废物的50%,闭环回收似乎势在必行。尽管如此,出于安全考虑,PET(聚对苯二甲酸乙二醇酯)以外的塑料并没有被广泛回收用于食品接触。其中,消费后的聚烯烃被先前接触的产品大量配制、降解和污染。在功能屏障(FB)后使用回收材料可以根据具体规定解决问题,但欧洲法规和美国FDA都没有提供有关功能屏障评估和使用的指导。数学建模是欧美机构认可的唯一可行的评估回收材料使用条件的方法。本研究在数值上探讨了结合两种效果的可能性:回收材料的去污和功能屏障,以允许安全使用回收材料。
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引用次数: 0
Experimental Study of an upflow Fluidized Bed: Identification of Fluidization Regimes 上流流化床的实验研究:流化状态的识别
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337907005
Ronny Gueguen, Guillaume Sahuquet, S. Mer, A. Toutant, Françoise Bataille, G. Flamant
The concept of solar receiver using fluidized particles as heat transfer fluid is attractive from the point of view of its performance but also of the material used. In this concept, the receiver is composed of tubes subjected to concentrated solar radiation in which the fluidized particles circulate vertically. Circulation in the tubes, immersed in a “nurse” fluidized bed, is ensured thanks to a controlled pressure difference imposed on the latter and secondary aeration. This ventilation located at the bottom of the absorber tubes makes it possible to control the fluidization regimes. The latter strongly influence the parietal heat transfers and therefore the performance of the receiver. In order to better understand the conditions of appearance of these regimes and to better identify them, a study at room temperature was carried out with a tube 45 mm in internal diameter and 3.63 m in height. The tube is instrumented with several pressure sensors distributed over its height. More than 170 experiments have been performed exploring wide ranges of particle and aeration flow rates, with and without particle circulation. Signal processing methods, classically used in the scientific literature of fluidized beds, are applied. Combined together, these methods have enabled the identification of bubbling, pistoning (of the wall and axisymmetric), turbulent fluidization and rapid fluidization regimes. The pooling of all this information allows the establishment of a diagram of the fluidization regimes and their transition, showing that the local slip velocity is the key parameter governing the structure of the flow.
利用流化颗粒作为传热流体的太阳能接收器的概念从其性能和所用材料的角度来看是有吸引力的。在这个概念中,接收器由受集中太阳辐射的管组成,流化颗粒在其中垂直循环。由于对后曝气和二次曝气施加了可控的压差,因此在浸入“护士”流化床中的管道中的循环得到了保证。位于吸收管底部的通风装置使控制流化状态成为可能。后者强烈影响顶板传热,从而影响接收器的性能。为了更好地了解这些制度的外观条件并更好地识别它们,在室温下进行了一项研究,管内直径45 mm,高度3.63 m。管子上装有分布在其高度上的几个压力传感器。在有和没有颗粒循环的情况下,进行了170多个实验,探索了大范围的颗粒和曝气流速。应用了在流化床科学文献中经典使用的信号处理方法。结合在一起,这些方法能够识别鼓泡,活塞(壁面和轴对称),湍流流化和快速流化制度。所有这些信息的汇集可以建立流化机制及其转变的图表,表明局部滑移速度是控制流动结构的关键参数。
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引用次数: 0
Large-Scale Laboratory Trials of Self-Healing Technologies 自我修复技术的大规模实验室试验
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337807004
S. Rengaraju, C. Vlachakis, Vahid Afroughsabet, A. Al-Tabbaa
Prolonging the life of the reinforced concrete structure is the most promising solution to reduce the carbon emissions from concrete. To achieve that, the structure should be protected from crack formation, which acts as an easy pathway for deleterious agents. Self-healing technologies are intended to provide long-term resilience against cracking due to various deterioration processes. Technologies that performed well in small, laboratory-scale studies are taken to the next level to assess their performance on a larger scale and monitored using various NDT equipment. A 1m long beam with a cross-section (140×120 mm) was cast with two rebars – one with a cover depth of 50 mm from the top and another with a cover depth of 20 mm from the bottom. The mix design consists of CEM IIIA (50 OPC: 50 Slag) cement and 30% lightweight aggregate as a replacement for coarse aggregate. At 28 days of curing, the concrete beams are subjected to accelerated corrosion (by applying a voltage to the bottom rebar) to induce internal cracking. Once internal cracking is induced, the beams are subjected to another 28 days under water for healing. The performance of the beams is monitored via ultrasonic pulse velocity and half-cell potential before and after voltage application. This paper shows the preliminary results and the self-healing efficiency and corrosion resistance of these beams are continuously being monitored under severe chloride conditions to predict the long-term performance.
延长钢筋混凝土结构的使用寿命是减少混凝土碳排放最有希望的解决方案。为了实现这一目标,结构应该防止裂缝的形成,这是有害物质容易进入的途径。自修复技术的目的是提供长期的弹性,防止各种恶化过程造成的开裂。在小型实验室规模的研究中表现良好的技术被提升到下一个水平,以评估其在更大规模的性能,并使用各种无损检测设备进行监测。一根1米长的横截面梁(140×120 mm)用两根钢筋浇筑——一根覆盖深度为顶部50毫米,另一根覆盖深度为底部20毫米。混合设计由CEM IIIA (50 OPC: 50矿渣)水泥和30%轻骨料组成,以替代粗骨料。在28天的养护中,混凝土梁受到加速腐蚀(通过对底部钢筋施加电压),从而引起内部开裂。一旦内部开裂,梁将在水下再进行28天的修复。通过施加电压前后的超声脉冲速度和半电池电位来监测光束的性能。本文展示了初步结果,并对这些梁在严重氯化物条件下的自愈效率和耐腐蚀性进行了连续监测,以预测其长期性能。
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引用次数: 0
PVDF-based coatings with CNT additions for strain monitoring of mortar substrates subjected to bending 添加碳纳米管的pvdf基涂料用于砂浆基底弯曲应变监测
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337805001
Gabriele Milone, J. Tulliani, A. Al-Tabbaa
Sensing coatings are rapidly entering the field of non-destructive tests. While cement-based composites are proving an excellent interaction with new/recent structures, polymer-based coatings, already employed for structural retrofitting purposes, can provide a valuable alternative. This study investigated the production, application, and use of poly(vinylidene fluoride) (PVDF) coatings. A 10w/v% PVDF-to-solvent ratio became the best trade-off between electrical conductivity and bond strength with the substrate. Different concentrations of Carbon Nanotubes (CNT) were investigated: 0.05, 0.10, 0.25, 0.50, and 0.75% by weight of PVDF. The conductive PVDF-CNT composites were brushed on the casted mortar beams with screws embedded as electrodes. The mortar beams and attached polymer coatings were then subjected to bending stress. The Gauge Factor was obtained by comparing the substrate’s strain with the coating’s electric response. The sensing intervals in the Fractional Change of Resistance-strain curves varied in relation to the CNT concentration. For instance, adding 0.50w/v% of CNT gave the highest sensitivity up to 0.2‰ strain, followed by a lower – still sufficient – gauge factor. PVDF-based coatings with CNT additions of 0.25 and 0.75w/v% witnessed a comparable sensing performance in the same strain limits, abruptly increasing and finally stabilizing to a low gauge factor. In contrast, both 0.05 and 0.10w/v% resulted in a low monitoring potential overall. The varying sensing zones experienced by the coating were attributed to the microscopical behavior of CNT within the PVDF matrix. In conclusion, the results highlighted the potentiality of polymeric coatings for sensing, monitoring, and inspection of concrete structures.
传感涂层正在迅速进入无损检测领域。虽然水泥基复合材料被证明与新的/最近的结构具有良好的相互作用,但聚合物基涂层已经用于结构改造目的,可以提供一个有价值的替代方案。研究了聚偏氟乙烯(PVDF)涂料的生产、应用和使用情况。pvdf与溶剂的比例为10w/v%,是导电率和与基材结合强度之间的最佳折衷。研究了不同浓度的碳纳米管(CNT): 0.05, 0.10, 0.25, 0.50和0.75%的PVDF重量。将导电PVDF-CNT复合材料刷在浇铸砂浆梁上,并嵌入螺钉作为电极。然后砂浆梁和附着的聚合物涂层承受弯曲应力。通过对衬底应变与涂层电响应的比较,得到了测量因子。电阻-应变曲线分数阶变化的传感间隔随碳纳米管浓度的变化而变化。例如,加入0.50w/v%的碳纳米管,灵敏度最高可达0.2‰应变,其次是较低但仍然足够的测量因子。添加0.25和0.75w/v%碳纳米管的pvdf基涂层在相同应变极限下的传感性能相当,突然增加并最终稳定到一个低测量因子。相比之下,0.05和0.10w/v%导致整体监测电位较低。涂层所经历的不同传感区归因于碳纳米管在PVDF基体中的微观行为。总之,研究结果强调了聚合物涂层在混凝土结构传感、监测和检查方面的潜力。
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引用次数: 1
Experimental investigation on the ability of macro-encapsulated polyurethane to resist cyclic damaging actions in self-repaired cement-based elements 宏观包封聚氨酯抗自修复水泥基构件循环损伤能力的实验研究
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337802016
G. Anglani, J. Tulliani, P. Antonaci
The use of polymer precursors as repairing agents in capsule-based self-healing systems has been extensively studied in recent years. In particular, the effectiveness of macro-encapsulated polyurethane in restoring both watertightness and mechanical properties has been demonstrated at the laboratory level, and the experimental methods to test the effectiveness have been validated following pre-standard procedures. However, the use of macro-capsules containing polyurethane precursors for field applications has not been sufficiently implemented yet. For these systems to become appealing to the construction industry, it is essential to further characterize the self-healing effect in terms of stability in time, namely, to investigate the behavior of the self-healing system when subjected to recurring actions that can affect structures in time, after cracking and subsequent self-repairing. The goal of this study was to characterize the ability of commercial polyurethane foams to withstand cyclic flexural actions and repeated temperature variations after release from cementitious macro-capsules embedded in mortar specimens. The specimens were tested immediately after pre-cracking and self-repairing to characterize the initial sealing efficiency through a water-flow test. The same test was repeated at prescribed time intervals to analyze the evolution of the sealing efficiency with the applied mechanical and thermal stresses. The results showed that the proposed system has good stability against the selected damaging actions and confirmed the potential of encapsulated polyurethane for self-healing applications.
近年来,高分子前体作为修复剂在胶囊型自愈系统中的应用得到了广泛的研究。特别是,宏观封装聚氨酯在恢复水密性和机械性能方面的有效性已经在实验室水平上得到了证明,并且测试有效性的实验方法已经按照预标准程序进行了验证。然而,在现场应用中使用含有聚氨酯前体的大胶囊尚未得到充分实施。为了使这些系统对建筑行业具有吸引力,有必要进一步描述自愈效果在时间稳定性方面的特征,即研究自愈系统在遭受可能影响结构的反复动作时的行为,在破裂和随后的自我修复之后。本研究的目的是表征商用聚氨酯泡沫在从嵌入砂浆试样的胶凝宏观胶囊中释放后承受循环弯曲作用和重复温度变化的能力。试件在预裂后立即进行自修复试验,通过水流试验表征初始密封效率。在规定的时间间隔内重复进行相同的测试,以分析密封效率随施加的机械应力和热应力的演变。结果表明,该体系对所选择的损伤行为具有良好的稳定性,并证实了封装聚氨酯自修复应用的潜力。
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引用次数: 0
Development of bio-inspired multi-functional polymeric-based fibers (BioFiber) for advanced delivery of bacterial-based self-healing agent in concrete 用于在混凝土中先进输送细菌基自愈剂的仿生多功能聚合物基纤维(BioFiber)的开发
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337802001
M. H. Khaneghahi, Divya Kamireddi, Seyed Ali Rahmaninezhad, C. Schauer, Christopher M. Sales, A. Najafi, Aidan Cotton, Amir Sadighi, Y. Farnam
The goal of this research is to develop innovative damage-responsive bacterial-based self-healing fibers (hereafter called BioFiber) that can be incorporated into concrete to enable two functionalities simultaneously: (1) crack bridging functionality to control crack growth and (2) crack healing functionality when a crack occurs. The BioFiber is comprised of a load-bearing core fiber, a sheath of bacteria-laden hydrogel, and an outer impermeable strain-responsive shell coating. An instant soaking manufacturing process was used with multiple reservoirs containing bacteria-laden, hydrophilic prepolymer and crosslinking reagents to develop BioFiber. Sodium-alginate was used as a prepolymer to produce calcium-alginate hydrogel via ionic crosslinking on the core fiber. The dormant bacteria (spore) of Lysinibacillus sphaericus was incorporated in hydrogel as a self-healing agent. Then, an impermeable polymeric coating was applied to the hydrogel-coated core fibers. The impermeable strain-responsive shell coating material was manufactured using the polymer blend of polystyrene and polylactic acid. The high swelling capacity of calcium-alginate provides the water required for the microbially induced calcium carbonate precipitation (MICP) chemical pathway, i.e., ureolysis in this study. The strain-responsive impermeable coating provides adequate flexibility during concrete casting to protect the spores and alginate before cracking and sufficient stress-strain behavior to grant damage-responsiveness upon crack occurrence to activate MICP. To evaluate the behavior of developed BioFiber, the swelling capacity of the hydrogel, the impermeability of shell coating, the spore casting survivability, and MICP activities were investigated.
这项研究的目标是开发创新的基于细菌的损伤响应自愈纤维(以下称为生物纤维),这种纤维可以结合到混凝土中,同时具有两种功能:(1)裂缝桥接功能,以控制裂缝的生长;(2)裂缝发生时的裂缝愈合功能。生物纤维由承重核心纤维、充满细菌的水凝胶鞘和外部不渗透的应变响应外壳涂层组成。采用瞬间浸泡法制备多种含细菌、亲水性预聚物和交联试剂的储层,制备了生物纤维。以海藻酸钠为预聚物,在芯纤维上通过离子交联制备海藻酸钙水凝胶。将球形赖氨酸芽孢杆菌的休眠菌(孢子)作为自愈剂掺入水凝胶中。然后,在水凝胶包覆的芯纤维上涂上一层不渗透聚合物涂层。采用聚苯乙烯和聚乳酸共混聚合物制备了不透水应变响应壳涂层材料。海藻酸钙的高溶胀能力为本研究中微生物诱导碳酸钙沉淀(MICP)化学途径即尿解提供了所需的水。应变响应抗渗涂层在混凝土浇筑过程中提供了足够的柔韧性,在开裂之前保护孢子和海藻酸盐,并在裂缝发生时提供足够的应力-应变行为,以激活MICP。为了评价生物纤维的性能,研究了水凝胶的膨胀能力、外壳涂层的不渗透性、孢子的浇注存活能力和MICP活性。
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引用次数: 2
Simulation analysis of internal and external faults in transformer area 变压器区内外故障的仿真分析
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202338201041
Peixian Bai, Yixuan Jia
Under different types of internal and external faults of transformers, electrical quantities such as voltage, differential current and transformer oil flow rate change accordingly. In this paper, the variation law is studied, and the variation law of differential current and other electrical quantities under different types of faults and abnormal conditions inside and outside the transformer area is verified by simulation. The characteristics of faults inside and outside the area are different, and the faults inside and outside the transformer area are judged. At the same time, ANSYS Maxwell 3D, ANSYS Fluent and other software are used to model and simulate the transformer, and the oil flow rate changes under different operating conditions such as normal operation, external fault and internal fault of the transformer are analyzed.
在不同类型的变压器内外故障情况下,电压、差动电流、变压器油流量等电量会发生相应的变化。本文对其变化规律进行了研究,并通过仿真验证了变压器区域内外不同类型故障和异常情况下差动电流及其他电量的变化规律。区域内外故障特征不同,对变压器区域内外故障进行判断。同时利用ANSYS Maxwell 3D、ANSYS Fluent等软件对变压器进行建模仿真,分析了变压器正常运行、外部故障、内部故障等不同工况下的油流量变化情况。
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引用次数: 0
Initial proposal of a smart cement-based material to enhance the service-life of reinforcement concrete structures 一种智能水泥基材料的初步建议,以提高钢筋混凝土结构的使用寿命
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337805003
Ana Martínez-Ibernón, P. Antonaci, G. Anglani
The sustainable development of societies can be pursued by simultaneously avoiding the depletion of materials and resources and reducing the greenhouse gases emissions, with related climatic change effects. In order to get this, the extension of structures service-life plays a significant role in saving natural resources, decreasing the overall anthropogenic carbon-footprint, and reducing building and demolition wastes. In order to achieve such prolongation of structures service-life, one of the most promising approaches is the development of Smart Structures. These are defined as structures that are able to self-sense some external stimuli such as stress or temperature variations, and internal conditions such as chloride penetration, concrete carbonatation, etc. Consequently, ongoing damage phenomena can be detected promptly, thus allowing to implement suitable countermeasures in the most efficient way. Smart Structures can also process the information and respond autonomously in real time by using smart materials technologies such as self-healing technology. In this study we propose a preliminary version of a smart material system with self-healing and sensing properties, to demonstrate its effectiveness at a proof of concept level. The effectiveness of an active, capsule-based self-healing system in blocking chloride penetration through the crack and the effectiveness of voltametric Ag sensors in detecting the presence of chlorides were investigated experimentally. High-performance cement mortar was chosen as the material to be studied, in order to ensure that optimal behaviour could be observed in non-cracked conditions.
社会的可持续发展可以通过同时避免材料和资源的消耗和减少温室气体排放以及相关的气候变化影响来实现。为了实现这一目标,延长建筑物的使用寿命在节约自然资源、减少整体人为碳足迹以及减少建筑和拆除废物方面发挥着重要作用。为了延长结构的使用寿命,发展智能结构是最有前途的方法之一。这些被定义为能够自我感知一些外部刺激(如应力或温度变化)和内部条件(如氯化物渗透、混凝土碳化等)的结构。因此,可以及时发现正在发生的损害现象,从而允许以最有效的方式实施适当的对策。智能结构还可以利用自愈技术等智能材料技术,对信息进行实时处理和自主响应。在这项研究中,我们提出了一个具有自我修复和传感特性的智能材料系统的初步版本,以证明其在概念验证层面的有效性。实验研究了一种基于活性胶囊的自愈系统在阻止氯化物通过裂纹渗透方面的有效性,以及电压银传感器在检测氯化物存在方面的有效性。选择高性能水泥砂浆作为研究材料,以确保在无开裂条件下可以观察到最佳性能。
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引用次数: 0
Effect of microstructure heterogeneity shapes on constitutive behaviour of encapsulated self-healing cementitious materials 微结构非均质形态对包封自愈胶凝材料本构行为的影响
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337809004
S. Sayadi, E. Ricketts, E. Schlangen, P. Cleall, I. Mihai, A. Jefferson
Self-healing cementitious materials with microcapsules are complex multiscale and multiphase materials. The random microstructure of these materials governs their mechanical and transport behaviour. The actual microstructure can be represented accurately with a discrete lattice model, but computational restrictions mean that the size of domain that can be considered with this approach is limited. By contrast, a smeared approach, based on a micromechanical formulation, provides an approximate representation of the material microstructure with low computational costs. The aim of this paper is to compare simulations of a microcapsule-based self-healing cementitious system with discrete-lattice and smeared-micromechanical models, and to assess the relative strengths and weaknesses of these models for simulating distributed fracture and healing in this type of self-healing material. A novel random field generation technique is used to represent the microstructure of a cementitious mortar specimen. The meshes and elements are created by the triangulation method and used to determine the input required for the lattice model. The paper also describes the enhancement of the TUDelft lattice model to include self-healing behaviour. The extended micromechanical model considers both microcracking and healing. The findings from the study provide insight into the relative merits of these two modelling approaches.
微胶囊自愈胶凝材料是复杂的多尺度多相材料。这些材料的随机微观结构决定了它们的机械和传输行为。实际的微观结构可以用离散晶格模型精确地表示,但计算限制意味着可以用这种方法考虑的域的大小是有限的。相比之下,基于微力学公式的涂抹方法以较低的计算成本提供了材料微观结构的近似表示。本文的目的是比较基于微胶囊的自愈胶凝系统与离散晶格和涂抹微力学模型的模拟,并评估这些模型在模拟这种自愈材料的分布式断裂和愈合方面的相对优势和弱点。采用一种新的随机场生成技术来表示胶凝砂浆试件的微观结构。网格和元素是通过三角剖分方法创建的,用于确定晶格模型所需的输入。本文还描述了对TUDelft晶格模型的增强,以包括自愈行为。扩展的微力学模型同时考虑了微裂纹和微愈合。研究结果提供了对这两种建模方法的相对优点的见解。
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引用次数: 0
A coupled radial-torsional lumped parameter model of rubber bushing for multibody dynamic simulations 多体动力学仿真橡胶衬套径向-扭转耦合集总参数模型
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202338201023
Chang Cao, Xingxing Feng, Min Liu
Many constitutive models’ finite element (FE) models and lumped parameter models included have been presented for rubber bushings. In general, the FE models cannot be directly used in mechanical multibody systems with bushings, and the lumped parameter models can not consider the coupled modes of deformation of bushings. For this reason, a two-dimensional lumped parameter model for rubber bushings is presented, which considers the coupled radial-torsional deformation and can be easily implemented into mechanical multibody systems. FE method is used to simulate the rubber bushing subjected to a coupled radial-torsional deformation. A procedure to determine the model parameters is presented. The proposed coupled bushing model and a traditional one-dimensional bushing model are applied into a simple multibody system and compared. Simulation results show the coupled radial-torsional behavior of the bushing.
橡胶衬套的本构模型包括有限元模型和集总参数模型。一般情况下,有限元模型不能直接用于含衬套的机械多体系统,且集总参数模型不能考虑衬套变形的耦合模式。为此,提出了考虑径向-扭转耦合变形的橡胶衬套二维集总参数模型,该模型易于应用于机械多体系统。采用有限元法对橡胶衬套进行了径向-扭转耦合变形的数值模拟。给出了一种确定模型参数的方法。将所提出的耦合衬套模型与传统的一维衬套模型应用于一个简单的多体系统,并进行了比较。仿真结果显示了轴套的径向-扭转耦合特性。
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引用次数: 0
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