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Evaluation of the self-healing effect in cement-based materials with embedded cementitious capsules by means of Acoustic Emission techniques 用声发射技术评价嵌入胶凝胶囊的水泥基材料的自愈效果
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337804004
G. Anglani, P. M. Montanari, Jean Marc Tulliani, G. Lacidogna, P. Antonaci
Due to its low tensile strength and the presence of defects brought on by improper construction methods or other factors, cracks in concrete are practically inevitable. For reinforced-concrete structures, even if cracks do not necessarily increase the risk of collapse, they unquestionably hinder aspects such as service life. Self-healing cementitious materials have been developed because of growing concern for the security and sustainability of structures. For these new materials to be used in actual structures, it is essential to conduct research into the self-repair effect that they may offer, and possibly quantify it directly on-site, by means of non-destructive methods. In this sense, the objective of this work is to use Acoustic Emission (AE) analyses to non-destructively characterise the response of an autonomic capsule-based system, as a function of the specific polymeric healing agents contained in the capsules. Comparisons will be made between the reference and selfhealing specimens, and between the different self-healing specimens themselves, through the analysis of such parameters as the ultimate load, absorbed fracture energy, and emitted Acoustic Emission (AE) energy. Such type of analysis can give valuable insights not only on quantitative but also on qualitative aspects (such as the level of brittleness or ductility introduced by the specific self-healing system adopted) in view of possible applications in real structures.
由于混凝土本身抗拉强度低,加上施工方法不当或其他因素造成的缺陷,混凝土裂缝几乎是不可避免的。对于钢筋混凝土结构,即使裂缝不一定会增加倒塌的风险,但它们无疑会影响使用寿命等方面。自愈胶结材料的发展是由于人们对结构的安全性和可持续性的日益关注。为了将这些新材料应用于实际结构中,有必要对它们可能提供的自我修复效果进行研究,并可能通过非破坏性方法直接在现场进行量化。从这个意义上说,这项工作的目的是使用声发射(AE)分析来非破坏性地表征基于自主胶囊的系统的响应,作为胶囊中包含的特定聚合物愈合剂的功能。通过对极限载荷、吸收断裂能、发射声发射能等参数的分析,对参考试件与自愈试件、不同自愈试件本身进行比较。这种类型的分析不仅可以在定量方面,而且可以在定性方面(例如所采用的特定自愈系统引入的脆性或延性水平)提供有价值的见解,考虑到实际结构的可能应用。
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引用次数: 0
Feasibility of Visible Near-Infrared Hyperspectral Imaging in Detection of Calcium Hypochlorite in Sago Flour 可见近红外高光谱成像检测西米粉中次氯酸钙的可行性
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337701005
Ming Hao Lee, A. Saptoro, K. Lim, H. Chua, T. Vu, Nurleyna Yunus, Hasnain Hussain
The general public perspective on sago flour quality is based on the perceived colour appearances. This contributed to the potential of food fraud by excessive usage of bleaching agents such as calcium hypochlorite (CHC) to alter the product’s colour. Conventional methods to detect and quantify CHC such as titration and chromatography are time-consuming, expensive and limited to laboratory setups only. In this research, visible near-infrared hyperspectral imaging (Vis-NIR HSI) was combined with partial least squares regression (PLSR) model to quantify CHC in pure sago flour accurately and rapidly. Hyperspectral images with the spectral region of 400 nm to 1000 nm were captured for CHC-pure sago mixture samples with CHC concentration ranging from 0.005 w/w% to 2 w/w%. Mean reflectance spectral data was extracted from the hyperspectral images, and was used as inputs to develop the PLSR model to predict the CHC concentration. The PLSR model achieved the commendable predictive results in this study, with Rp = 0.9509, RMSEP = 0.1655 and MAPEP of 3.801%, proving that Vis-NIR HSI can effectively predict the concentration of CHC in sago flour.
一般公众对西米面粉质量的看法是基于感知到的颜色外观。由于次氯酸钙(CHC)等漂白剂的过量使用改变了产品的颜色,这增加了食品欺诈的可能性。传统的检测和定量CHC的方法,如滴定法和色谱法,耗时、昂贵且仅限于实验室设置。本研究采用可见光近红外高光谱成像(Vis-NIR HSI)与偏最小二乘回归(PLSR)模型相结合的方法,对纯西米粉中的CHC进行了准确、快速的定量分析。CHC-纯西米混合物样品的CHC浓度为0.005 w/w% ~ 2 w/w%,可获得光谱区域为400 ~ 1000 nm的高光谱图像。从高光谱图像中提取平均反射率光谱数据,并将其作为PLSR模型的输入,用于预测CHC浓度。PLSR模型在本研究中取得了令人满意的预测结果,Rp = 0.9509, RMSEP = 0.1655, MAPEP为3.801%,证明Vis-NIR HSI可以有效预测西米粉中CHC的浓度。
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引用次数: 0
Research on a tubeless tire for a mobile robot 移动机器人无内胎轮胎的研究
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337501002
R. Zinko, O. Polishchuk, I. Demchuk, Olexsand Shpak, J. Wilczarska
Airless tires are used not only in cars, but also in vehicles used in the construction, road, forestry, and robotics industries. In order to develop the construction of an airless tire, its optimization at the stage of their design, a comprehensive method of researching the operational properties of an airless tire is proposed. The methodology includes stress-strain analysis, modal and thermal analysis of an airless tire using three-dimensional modeling using the finite element method. The airless tire was studied in the following modes of uniform movement of the wheel on a solid base: driven wheel; driving wheel; free wheel; neutral wheel; brake wheel. An example of the study of an airless tire of a mobile robot is given.
无气轮胎不仅用于汽车,还用于建筑、道路、林业和机器人工业的车辆。为了发展无气轮胎的结构,在无气轮胎设计阶段对其进行优化,提出了一种研究无气轮胎使用性能的综合方法。方法包括应力应变分析、模态分析和热分析,采用三维有限元法对无气轮胎进行建模。研究了无气轮胎在实心基础上的均匀运动模式:从动轮;驱动轮;自由轮;中性轮;制动轮。给出了移动机器人无气轮胎的研究实例。
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引用次数: 0
Self-healing abilities of cement mortars containing microorganisms produced in the process of sewage sludge treatment 污水污泥处理过程中产生微生物的水泥砂浆的自愈能力
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337802003
Muath Abu Askar, T. Zdeb, J. Chwastowski, L. Ferrara
The enormous quantity of sewage water produced each day continues to present a serious challenge for its treatment and management. Sewage water is one of the most abundant sources of biomass, such as bacteria. Concrete, on the other hand, is the second most widely employed substance on the planet, after freshwater. Cracking of concrete is a major factor affecting the strength and durability of the material. The development of a crack pattern can contribute to increasing the permeability of concrete, which is typically associated with a significant decrease in its durability. Under specific circumstances, bio concrete is a self-healing biomaterial. Bacteria have the ability to precipitate calcite in concrete or form a layer of calcite precipitation, which plays a crucial role in the remediation of plastic shrinkage microcracks, thereby enhancing the structural integrity and durability of concrete over the long term. This paper summarises the study of investigating the possibility of using sewage water as a self-healing agent, using bacteria from different stages of treatment to heal cracks in concrete samples, and evaluating the effect of sewage water from different stages of treatment on fresh and hardened concrete properties. Based on the data collected from the experiments. Complete replacement of ordinary tap mixing water with sewage water from the Biological Reactor oxygen Zone achieved cracks healing of a crack width of 200 μm in less than 14 days without compromising the binder and mortar properties such setting time, slump value, compressive and flexural strength when compared to a reference sample made with tap mixing water.
每天产生的大量污水继续对其处理和管理构成严重挑战。污水是细菌等生物质最丰富的来源之一。另一方面,混凝土是地球上第二广泛使用的物质,仅次于淡水。混凝土开裂是影响混凝土强度和耐久性的主要因素。裂缝模式的发展有助于增加混凝土的渗透性,这通常与耐久性的显著降低有关。在特定情况下,生物混凝土是一种自我修复的生物材料。细菌具有在混凝土中沉淀方解石或形成一层方解石沉淀的能力,对塑性收缩微裂缝的修复起着至关重要的作用,从而提高混凝土的结构完整性和长期耐久性。本文综述了研究污水作为自愈剂的可能性,利用不同处理阶段的细菌来修复混凝土样品中的裂缝,以及评价不同处理阶段的污水对新拌混凝土和硬化混凝土性能的影响。根据从实验中收集的数据。用生物反应器氧区的污水完全替代普通自来水,在不到14天的时间内,裂缝宽度达到200 μm,与用自来水配制的参考样品相比,在不影响粘结剂和砂浆的凝结时间、坍落度值、抗压和抗折强度等性能的情况下,实现了裂缝愈合。
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引用次数: 0
Tensile behavior of strain-hardening cementitious composites after self-healing based on a novel fiber-bridging model considering preloading and reloading 基于考虑预加载和再加载的新型纤维桥接模型的应变硬化胶凝复合材料自愈后拉伸行为
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337809005
Yangqing Liu, Bo Wu, J. Qiu
The self-healing of strain-hardening cementitious composites (SHCCs) causes the recovery of the debonded fiber-to-matrix interface by the products of autogenous healing (mainly calcium carbonates). The recovery of chemical bond Gd has been detected in the reactive magnesia cement (RMC)-based SHCC (SHMC), and the recovery of frictional bond τ0 has been detected in both SHMCs and normal SHCCs. While these phenomena can significantly alter the fiber-bridging σ-w relationship in SHCCs, they have not been quantified in any existing analytical models. In this work, we present a new fiber-bridging model that captures the effect of self-healing of RMC-based SHCC. On the single-fiber level, the debonding and slip-hardening of the fiber-to-matrix interface induced by a tensile preloading as well as the recovery of the interface properties by self-healing are coherently quantified in a clear kinetic process. On the fiber-bridging level, the tensile stress vs. crack width curve is formed by summing individual fibers’ tensile load vs. displacement relationship. The modeling results can well capture the fiber-bridging behavior of the self-healed SHCC specimens. Further, a parametric study is conducted to investigate the tensile behavior of SHCC after self-healing. The effects of preloading levels, recovered τ0, and fiber strength are discussed.
应变硬化胶凝复合材料(SHCCs)的自愈作用是通过自愈产物(主要是碳酸钙)使脱落的纤维-基体界面恢复。在活性镁水泥(RMC)基SHCC (SHMC)中检测到化学键Gd的恢复,在SHMC和正常SHCC中检测到摩擦键τ0的恢复。虽然这些现象可以显著改变shcc中光纤桥接的σ-w关系,但在现有的分析模型中尚未对其进行量化。在这项工作中,我们提出了一种新的纤维桥接模型,该模型捕捉了基于rmc的SHCC的自愈效果。在单纤维水平上,拉伸预加载引起的纤维-基体界面的脱粘和滑移硬化以及自修复引起的界面性能的恢复在一个明确的动力学过程中得到了一致的量化。在纤维桥接水平上,拉应力与裂缝宽度曲线由单个纤维的拉伸载荷与位移关系求和而成。模拟结果较好地反映了自愈SHCC试件的纤维桥接行为。此外,进行了参数研究,以探讨自愈后SHCC的拉伸行为。讨论了预压水平、恢复τ0和纤维强度的影响。
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引用次数: 0
Experimental investigation on the ability of macro-encapsulated polyurethane to resist cyclic damaging actions in self-repaired cement-based elements 宏观包封聚氨酯抗自修复水泥基构件循环损伤能力的实验研究
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337802016
G. Anglani, J. Tulliani, P. Antonaci
The use of polymer precursors as repairing agents in capsule-based self-healing systems has been extensively studied in recent years. In particular, the effectiveness of macro-encapsulated polyurethane in restoring both watertightness and mechanical properties has been demonstrated at the laboratory level, and the experimental methods to test the effectiveness have been validated following pre-standard procedures. However, the use of macro-capsules containing polyurethane precursors for field applications has not been sufficiently implemented yet. For these systems to become appealing to the construction industry, it is essential to further characterize the self-healing effect in terms of stability in time, namely, to investigate the behavior of the self-healing system when subjected to recurring actions that can affect structures in time, after cracking and subsequent self-repairing. The goal of this study was to characterize the ability of commercial polyurethane foams to withstand cyclic flexural actions and repeated temperature variations after release from cementitious macro-capsules embedded in mortar specimens. The specimens were tested immediately after pre-cracking and self-repairing to characterize the initial sealing efficiency through a water-flow test. The same test was repeated at prescribed time intervals to analyze the evolution of the sealing efficiency with the applied mechanical and thermal stresses. The results showed that the proposed system has good stability against the selected damaging actions and confirmed the potential of encapsulated polyurethane for self-healing applications.
近年来,高分子前体作为修复剂在胶囊型自愈系统中的应用得到了广泛的研究。特别是,宏观封装聚氨酯在恢复水密性和机械性能方面的有效性已经在实验室水平上得到了证明,并且测试有效性的实验方法已经按照预标准程序进行了验证。然而,在现场应用中使用含有聚氨酯前体的大胶囊尚未得到充分实施。为了使这些系统对建筑行业具有吸引力,有必要进一步描述自愈效果在时间稳定性方面的特征,即研究自愈系统在遭受可能影响结构的反复动作时的行为,在破裂和随后的自我修复之后。本研究的目的是表征商用聚氨酯泡沫在从嵌入砂浆试样的胶凝宏观胶囊中释放后承受循环弯曲作用和重复温度变化的能力。试件在预裂后立即进行自修复试验,通过水流试验表征初始密封效率。在规定的时间间隔内重复进行相同的测试,以分析密封效率随施加的机械应力和热应力的演变。结果表明,该体系对所选择的损伤行为具有良好的稳定性,并证实了封装聚氨酯自修复应用的潜力。
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引用次数: 0
PVDF-based coatings with CNT additions for strain monitoring of mortar substrates subjected to bending 添加碳纳米管的pvdf基涂料用于砂浆基底弯曲应变监测
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337805001
Gabriele Milone, J. Tulliani, A. Al-Tabbaa
Sensing coatings are rapidly entering the field of non-destructive tests. While cement-based composites are proving an excellent interaction with new/recent structures, polymer-based coatings, already employed for structural retrofitting purposes, can provide a valuable alternative. This study investigated the production, application, and use of poly(vinylidene fluoride) (PVDF) coatings. A 10w/v% PVDF-to-solvent ratio became the best trade-off between electrical conductivity and bond strength with the substrate. Different concentrations of Carbon Nanotubes (CNT) were investigated: 0.05, 0.10, 0.25, 0.50, and 0.75% by weight of PVDF. The conductive PVDF-CNT composites were brushed on the casted mortar beams with screws embedded as electrodes. The mortar beams and attached polymer coatings were then subjected to bending stress. The Gauge Factor was obtained by comparing the substrate’s strain with the coating’s electric response. The sensing intervals in the Fractional Change of Resistance-strain curves varied in relation to the CNT concentration. For instance, adding 0.50w/v% of CNT gave the highest sensitivity up to 0.2‰ strain, followed by a lower – still sufficient – gauge factor. PVDF-based coatings with CNT additions of 0.25 and 0.75w/v% witnessed a comparable sensing performance in the same strain limits, abruptly increasing and finally stabilizing to a low gauge factor. In contrast, both 0.05 and 0.10w/v% resulted in a low monitoring potential overall. The varying sensing zones experienced by the coating were attributed to the microscopical behavior of CNT within the PVDF matrix. In conclusion, the results highlighted the potentiality of polymeric coatings for sensing, monitoring, and inspection of concrete structures.
传感涂层正在迅速进入无损检测领域。虽然水泥基复合材料被证明与新的/最近的结构具有良好的相互作用,但聚合物基涂层已经用于结构改造目的,可以提供一个有价值的替代方案。研究了聚偏氟乙烯(PVDF)涂料的生产、应用和使用情况。pvdf与溶剂的比例为10w/v%,是导电率和与基材结合强度之间的最佳折衷。研究了不同浓度的碳纳米管(CNT): 0.05, 0.10, 0.25, 0.50和0.75%的PVDF重量。将导电PVDF-CNT复合材料刷在浇铸砂浆梁上,并嵌入螺钉作为电极。然后砂浆梁和附着的聚合物涂层承受弯曲应力。通过对衬底应变与涂层电响应的比较,得到了测量因子。电阻-应变曲线分数阶变化的传感间隔随碳纳米管浓度的变化而变化。例如,加入0.50w/v%的碳纳米管,灵敏度最高可达0.2‰应变,其次是较低但仍然足够的测量因子。添加0.25和0.75w/v%碳纳米管的pvdf基涂层在相同应变极限下的传感性能相当,突然增加并最终稳定到一个低测量因子。相比之下,0.05和0.10w/v%导致整体监测电位较低。涂层所经历的不同传感区归因于碳纳米管在PVDF基体中的微观行为。总之,研究结果强调了聚合物涂层在混凝土结构传感、监测和检查方面的潜力。
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引用次数: 1
Large-Scale Laboratory Trials of Self-Healing Technologies 自我修复技术的大规模实验室试验
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337807004
S. Rengaraju, C. Vlachakis, Vahid Afroughsabet, A. Al-Tabbaa
Prolonging the life of the reinforced concrete structure is the most promising solution to reduce the carbon emissions from concrete. To achieve that, the structure should be protected from crack formation, which acts as an easy pathway for deleterious agents. Self-healing technologies are intended to provide long-term resilience against cracking due to various deterioration processes. Technologies that performed well in small, laboratory-scale studies are taken to the next level to assess their performance on a larger scale and monitored using various NDT equipment. A 1m long beam with a cross-section (140×120 mm) was cast with two rebars – one with a cover depth of 50 mm from the top and another with a cover depth of 20 mm from the bottom. The mix design consists of CEM IIIA (50 OPC: 50 Slag) cement and 30% lightweight aggregate as a replacement for coarse aggregate. At 28 days of curing, the concrete beams are subjected to accelerated corrosion (by applying a voltage to the bottom rebar) to induce internal cracking. Once internal cracking is induced, the beams are subjected to another 28 days under water for healing. The performance of the beams is monitored via ultrasonic pulse velocity and half-cell potential before and after voltage application. This paper shows the preliminary results and the self-healing efficiency and corrosion resistance of these beams are continuously being monitored under severe chloride conditions to predict the long-term performance.
延长钢筋混凝土结构的使用寿命是减少混凝土碳排放最有希望的解决方案。为了实现这一目标,结构应该防止裂缝的形成,这是有害物质容易进入的途径。自修复技术的目的是提供长期的弹性,防止各种恶化过程造成的开裂。在小型实验室规模的研究中表现良好的技术被提升到下一个水平,以评估其在更大规模的性能,并使用各种无损检测设备进行监测。一根1米长的横截面梁(140×120 mm)用两根钢筋浇筑——一根覆盖深度为顶部50毫米,另一根覆盖深度为底部20毫米。混合设计由CEM IIIA (50 OPC: 50矿渣)水泥和30%轻骨料组成,以替代粗骨料。在28天的养护中,混凝土梁受到加速腐蚀(通过对底部钢筋施加电压),从而引起内部开裂。一旦内部开裂,梁将在水下再进行28天的修复。通过施加电压前后的超声脉冲速度和半电池电位来监测光束的性能。本文展示了初步结果,并对这些梁在严重氯化物条件下的自愈效率和耐腐蚀性进行了连续监测,以预测其长期性能。
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引用次数: 0
Experimental Study of an upflow Fluidized Bed: Identification of Fluidization Regimes 上流流化床的实验研究:流化状态的识别
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337907005
Ronny Gueguen, Guillaume Sahuquet, S. Mer, A. Toutant, Françoise Bataille, G. Flamant
The concept of solar receiver using fluidized particles as heat transfer fluid is attractive from the point of view of its performance but also of the material used. In this concept, the receiver is composed of tubes subjected to concentrated solar radiation in which the fluidized particles circulate vertically. Circulation in the tubes, immersed in a “nurse” fluidized bed, is ensured thanks to a controlled pressure difference imposed on the latter and secondary aeration. This ventilation located at the bottom of the absorber tubes makes it possible to control the fluidization regimes. The latter strongly influence the parietal heat transfers and therefore the performance of the receiver. In order to better understand the conditions of appearance of these regimes and to better identify them, a study at room temperature was carried out with a tube 45 mm in internal diameter and 3.63 m in height. The tube is instrumented with several pressure sensors distributed over its height. More than 170 experiments have been performed exploring wide ranges of particle and aeration flow rates, with and without particle circulation. Signal processing methods, classically used in the scientific literature of fluidized beds, are applied. Combined together, these methods have enabled the identification of bubbling, pistoning (of the wall and axisymmetric), turbulent fluidization and rapid fluidization regimes. The pooling of all this information allows the establishment of a diagram of the fluidization regimes and their transition, showing that the local slip velocity is the key parameter governing the structure of the flow.
利用流化颗粒作为传热流体的太阳能接收器的概念从其性能和所用材料的角度来看是有吸引力的。在这个概念中,接收器由受集中太阳辐射的管组成,流化颗粒在其中垂直循环。由于对后曝气和二次曝气施加了可控的压差,因此在浸入“护士”流化床中的管道中的循环得到了保证。位于吸收管底部的通风装置使控制流化状态成为可能。后者强烈影响顶板传热,从而影响接收器的性能。为了更好地了解这些制度的外观条件并更好地识别它们,在室温下进行了一项研究,管内直径45 mm,高度3.63 m。管子上装有分布在其高度上的几个压力传感器。在有和没有颗粒循环的情况下,进行了170多个实验,探索了大范围的颗粒和曝气流速。应用了在流化床科学文献中经典使用的信号处理方法。结合在一起,这些方法能够识别鼓泡,活塞(壁面和轴对称),湍流流化和快速流化制度。所有这些信息的汇集可以建立流化机制及其转变的图表,表明局部滑移速度是控制流动结构的关键参数。
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引用次数: 0
Effect of microstructure heterogeneity shapes on constitutive behaviour of encapsulated self-healing cementitious materials 微结构非均质形态对包封自愈胶凝材料本构行为的影响
Pub Date : 2023-01-01 DOI: 10.1051/matecconf/202337809004
S. Sayadi, E. Ricketts, E. Schlangen, P. Cleall, I. Mihai, A. Jefferson
Self-healing cementitious materials with microcapsules are complex multiscale and multiphase materials. The random microstructure of these materials governs their mechanical and transport behaviour. The actual microstructure can be represented accurately with a discrete lattice model, but computational restrictions mean that the size of domain that can be considered with this approach is limited. By contrast, a smeared approach, based on a micromechanical formulation, provides an approximate representation of the material microstructure with low computational costs. The aim of this paper is to compare simulations of a microcapsule-based self-healing cementitious system with discrete-lattice and smeared-micromechanical models, and to assess the relative strengths and weaknesses of these models for simulating distributed fracture and healing in this type of self-healing material. A novel random field generation technique is used to represent the microstructure of a cementitious mortar specimen. The meshes and elements are created by the triangulation method and used to determine the input required for the lattice model. The paper also describes the enhancement of the TUDelft lattice model to include self-healing behaviour. The extended micromechanical model considers both microcracking and healing. The findings from the study provide insight into the relative merits of these two modelling approaches.
微胶囊自愈胶凝材料是复杂的多尺度多相材料。这些材料的随机微观结构决定了它们的机械和传输行为。实际的微观结构可以用离散晶格模型精确地表示,但计算限制意味着可以用这种方法考虑的域的大小是有限的。相比之下,基于微力学公式的涂抹方法以较低的计算成本提供了材料微观结构的近似表示。本文的目的是比较基于微胶囊的自愈胶凝系统与离散晶格和涂抹微力学模型的模拟,并评估这些模型在模拟这种自愈材料的分布式断裂和愈合方面的相对优势和弱点。采用一种新的随机场生成技术来表示胶凝砂浆试件的微观结构。网格和元素是通过三角剖分方法创建的,用于确定晶格模型所需的输入。本文还描述了对TUDelft晶格模型的增强,以包括自愈行为。扩展的微力学模型同时考虑了微裂纹和微愈合。研究结果提供了对这两种建模方法的相对优点的见解。
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引用次数: 0
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