Pub Date : 2024-11-22DOI: 10.1016/j.mtchem.2024.102411
Yuanjun Liu, Xinyu Jiao
{"title":"Multi-functional flexible PANI-based material for the development of efficient heating sensing equipment: integrating intelligent heating, motion detection, moisture absorption and ultraviolet protection function","authors":"Yuanjun Liu, Xinyu Jiao","doi":"10.1016/j.mtchem.2024.102411","DOIUrl":"https://doi.org/10.1016/j.mtchem.2024.102411","url":null,"abstract":"","PeriodicalId":18353,"journal":{"name":"Materials Today Chemistry","volume":"42 1","pages":"102411-102411"},"PeriodicalIF":0.0,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147382104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.mtchem.2024.102281
Seyed Shahrooz Zargarian, Barbara Kupikowska-Stobba, Alicja Kosik-Kozioł, Magdalena Bartolewska, Anna Zakrzewska, Daniel Rybak, Kamil Bochenek, Magdalena Osial, Filippo Pierini
Functional antibacterial textiles fabricated from a hybrid of organic waste-derived and bio-inspired materials offer sustainable solutions for preventing microbial infections. In this work, we developed a novel antibacterial textile created through the valorization of spent coffee grounds (SCG). Electrospinning and electrospraying techniques were employed to integrate the biowaste within a polymeric nanofiber matrix, ensuring uniform particle distribution and providing structural support for enhanced applicability. Modification with polydopamine (PDA) significantly enhanced the textile's photothermal performance. Specific attention was paid to understanding the relation between temperature change and key variables, including the surrounding liquid volume, textile layer stacking, and applied laser power. Developed platforms demonstrated excellent photothermal stability. While the SCG-based textile demonstrated exceptional biocompatibility, the PDA-modified textile effectively eradicated () under near-infrared (NIR) irradiation. The developed textiles in our work demonstrate a dynamic balance between biocompatibility and on-demand antibacterial functionality, offering adaptable solutions in accordance with the desired application.
{"title":"Light-responsive biowaste-derived and bio-inspired textiles: Dancing between bio-friendliness and antibacterial functionality","authors":"Seyed Shahrooz Zargarian, Barbara Kupikowska-Stobba, Alicja Kosik-Kozioł, Magdalena Bartolewska, Anna Zakrzewska, Daniel Rybak, Kamil Bochenek, Magdalena Osial, Filippo Pierini","doi":"10.1016/j.mtchem.2024.102281","DOIUrl":"https://doi.org/10.1016/j.mtchem.2024.102281","url":null,"abstract":"Functional antibacterial textiles fabricated from a hybrid of organic waste-derived and bio-inspired materials offer sustainable solutions for preventing microbial infections. In this work, we developed a novel antibacterial textile created through the valorization of spent coffee grounds (SCG). Electrospinning and electrospraying techniques were employed to integrate the biowaste within a polymeric nanofiber matrix, ensuring uniform particle distribution and providing structural support for enhanced applicability. Modification with polydopamine (PDA) significantly enhanced the textile's photothermal performance. Specific attention was paid to understanding the relation between temperature change and key variables, including the surrounding liquid volume, textile layer stacking, and applied laser power. Developed platforms demonstrated excellent photothermal stability. While the SCG-based textile demonstrated exceptional biocompatibility, the PDA-modified textile effectively eradicated () under near-infrared (NIR) irradiation. The developed textiles in our work demonstrate a dynamic balance between biocompatibility and on-demand antibacterial functionality, offering adaptable solutions in accordance with the desired application.","PeriodicalId":18353,"journal":{"name":"Materials Today Chemistry","volume":"18 1","pages":""},"PeriodicalIF":7.3,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.mtchem.2024.102310
Jiaying Zou, Qiaolan Yu, Dan Cao, Qianer Wang, Na Ma, Wei Dai
Levofloxacin (LVX) capture with microcrystalline particles of monometallic metal-organic frameworks (MOFs) is definitely restricted and challenged by its difficulties in solid-liquid separation and enhanced of adsorption capacity issues. Meanwhile, the development of magnetic MOFs with excellent adsorption capabilities and outstanding recyclability is crucial. Herein, a novel magnetic Fe/Ni bimetal MOFs composite (MIL-101(Fe)@NiFeO, MNFO) for LVX capture has been effectively fabricated for LVX capture, utilizing MIL-101(Fe) as the primary adsorbent and NiFeO nanoparticles as the magnetic element. Attributed to the synergistic ability of bimetal ions (Fe and Ni), MNFO exhibits a significant adsorption capacity (335 mg/g) and rapid adsorption rate (10 min) towards LVX. The adsorption capacity indicates an increasing-then-decreasing trend with an increase of the pH values. Additionally, the adsorption data are well fitted by the Freundlich and pseudo-second-order kinetic models. Thermodynamic studies indicated that the adsorption process was spontaneous and endothermic. In addition, the adsorbent demonstrated excellent reusability, as it could be readily recovered from the liquid phase through the magnetic properties of NiFeO. Remarkably, it retained approximately 90 % of its adsorption capacity of the uptakes after 5 cycles. This study offers a innovative approach to the development of highly efficient adsorbents for capturing LVX from water.
{"title":"NiFe2O4 magnetic nanoparticles supported on MIL-101(Fe) as bimetallic adsorbent for boosted capture ability toward levofloxacin","authors":"Jiaying Zou, Qiaolan Yu, Dan Cao, Qianer Wang, Na Ma, Wei Dai","doi":"10.1016/j.mtchem.2024.102310","DOIUrl":"https://doi.org/10.1016/j.mtchem.2024.102310","url":null,"abstract":"Levofloxacin (LVX) capture with microcrystalline particles of monometallic metal-organic frameworks (MOFs) is definitely restricted and challenged by its difficulties in solid-liquid separation and enhanced of adsorption capacity issues. Meanwhile, the development of magnetic MOFs with excellent adsorption capabilities and outstanding recyclability is crucial. Herein, a novel magnetic Fe/Ni bimetal MOFs composite (MIL-101(Fe)@NiFeO, MNFO) for LVX capture has been effectively fabricated for LVX capture, utilizing MIL-101(Fe) as the primary adsorbent and NiFeO nanoparticles as the magnetic element. Attributed to the synergistic ability of bimetal ions (Fe and Ni), MNFO exhibits a significant adsorption capacity (335 mg/g) and rapid adsorption rate (10 min) towards LVX. The adsorption capacity indicates an increasing-then-decreasing trend with an increase of the pH values. Additionally, the adsorption data are well fitted by the Freundlich and pseudo-second-order kinetic models. Thermodynamic studies indicated that the adsorption process was spontaneous and endothermic. In addition, the adsorbent demonstrated excellent reusability, as it could be readily recovered from the liquid phase through the magnetic properties of NiFeO. Remarkably, it retained approximately 90 % of its adsorption capacity of the uptakes after 5 cycles. This study offers a innovative approach to the development of highly efficient adsorbents for capturing LVX from water.","PeriodicalId":18353,"journal":{"name":"Materials Today Chemistry","volume":"194 1","pages":""},"PeriodicalIF":7.3,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-13DOI: 10.1016/j.mtchem.2024.102303
Zeshan Sun, Peng Kong, He Gui, Zhiyuan Chen, Yu Song, Yao Wang, Yanxin Wang, Matt J. Kipper, Jianguo Tang, Linjun Huang
As a kind of artificial bionic membrane, smart response membrane can respond to the stimulus signals in the environment by the principle of bionic technology. Graphene oxide (GO) has a unique functional group and material structure, which makes it exhibit distinctive performance characteristics in smart response membranes, and smart response membranes prepared by using GO are characterized by highly sensitive response and intelligent tunability. This paper introduces the preparation method, response mechanism, performance characteristics, and application areas of GO-based smart response membranes. The GO-based smart response membranes are classified into physical response and chemical response according to the type of response, where physical response includes light response, temperature response, humidity response, and pressure response, and chemical response includes pH response, molecular/ionic response, and CO gas response. The article highlights the outstanding performance advantages and application examples of various smart response membranes, and discusses two new functional GO-based smart response membranes with self-cleaning and self-repair. Finally, the article comprehensively evaluates the performance of various smart response membranes, and looks forward to the future development of GO smart response membranes, expecting to explore a brighter development direction in this research field and contribute to human life, industrial development, and high-tech progress.
智能响应膜作为一种人工仿生膜，能够利用仿生技术原理对环境中的刺激信号做出响应。氧化石墨烯（GO）具有独特的官能团和材料结构，使其在智能响应膜中表现出与众不同的性能特征，利用GO制备的智能响应膜具有高灵敏响应和智能可调性的特点。本文介绍了基于 GO 的智能响应膜的制备方法、响应机理、性能特点和应用领域。GO基智能响应膜按响应类型分为物理响应和化学响应，其中物理响应包括光响应、温度响应、湿度响应和压力响应，化学响应包括pH响应、分子/离子响应和CO气体响应。文章重点介绍了各种智能响应膜的突出性能优势和应用实例，并讨论了两种基于 GO 的具有自清洁和自修复功能的新型智能响应膜。最后，文章全面评价了各种智能响应膜的性能，并对 GO 智能响应膜的未来发展进行了展望，期望能在该研究领域探索出更光明的发展方向，为人类生活、工业发展和高科技进步做出贡献。
{"title":"Recent advances in the preparation and application of graphene oxide smart response membranes","authors":"Zeshan Sun, Peng Kong, He Gui, Zhiyuan Chen, Yu Song, Yao Wang, Yanxin Wang, Matt J. Kipper, Jianguo Tang, Linjun Huang","doi":"10.1016/j.mtchem.2024.102303","DOIUrl":"https://doi.org/10.1016/j.mtchem.2024.102303","url":null,"abstract":"As a kind of artificial bionic membrane, smart response membrane can respond to the stimulus signals in the environment by the principle of bionic technology. Graphene oxide (GO) has a unique functional group and material structure, which makes it exhibit distinctive performance characteristics in smart response membranes, and smart response membranes prepared by using GO are characterized by highly sensitive response and intelligent tunability. This paper introduces the preparation method, response mechanism, performance characteristics, and application areas of GO-based smart response membranes. The GO-based smart response membranes are classified into physical response and chemical response according to the type of response, where physical response includes light response, temperature response, humidity response, and pressure response, and chemical response includes pH response, molecular/ionic response, and CO gas response. The article highlights the outstanding performance advantages and application examples of various smart response membranes, and discusses two new functional GO-based smart response membranes with self-cleaning and self-repair. Finally, the article comprehensively evaluates the performance of various smart response membranes, and looks forward to the future development of GO smart response membranes, expecting to explore a brighter development direction in this research field and contribute to human life, industrial development, and high-tech progress.","PeriodicalId":18353,"journal":{"name":"Materials Today Chemistry","volume":"41 1","pages":""},"PeriodicalIF":7.3,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This review provides an overview of research on wound dressings, highlighting the potential of collagen-based materials for future wound management. Collagen, known for its biodegradability and biocompatibility, holds promise for wound healing. However, challenges such as poor mechanical properties, stability, and the lack of antibacterial properties when using collagen alone have led to the development of various solutions. The review discusses different types of collagen-based dressings, their preparation methods, and how their internal structure influences their ability to accelerate the healing of different wound types. Additionally, the article emphasizes the significant potential for the application of collagen dressings in future skin tissue engineering and in vivo tissue engineering. Specifically, three-dimensional scaffolds prepared from nanofibers through electrospinning show promise for more efficient collagen-based wound dressings, as these nanofibers have a similar extracellular matrix structure and high specific surface area, which can stimulate tissue hemostasis and promote cell adhesion, proliferation, and differentiation. However, challenges such as high production costs and poor stability in the commercial production of nanofibers need to be addressed. Overall, collagen dressings hold great promise for future applications and can play a significant role in skin tissue engineering and even in vivo tissue engineering.
{"title":"The potential of collagen-based materials for wound management","authors":"Ruoying Zhu, Zhengyuan Huang, Jiayu Zhang, Guigang Shi, Xiaomeng Cai, Rui Dou, Jiaruo Tang, Cuiping Zhang, Yifan Zhao, Jun Chen","doi":"10.1016/j.mtchem.2024.102295","DOIUrl":"https://doi.org/10.1016/j.mtchem.2024.102295","url":null,"abstract":"This review provides an overview of research on wound dressings, highlighting the potential of collagen-based materials for future wound management. Collagen, known for its biodegradability and biocompatibility, holds promise for wound healing. However, challenges such as poor mechanical properties, stability, and the lack of antibacterial properties when using collagen alone have led to the development of various solutions. The review discusses different types of collagen-based dressings, their preparation methods, and how their internal structure influences their ability to accelerate the healing of different wound types. Additionally, the article emphasizes the significant potential for the application of collagen dressings in future skin tissue engineering and in vivo tissue engineering. Specifically, three-dimensional scaffolds prepared from nanofibers through electrospinning show promise for more efficient collagen-based wound dressings, as these nanofibers have a similar extracellular matrix structure and high specific surface area, which can stimulate tissue hemostasis and promote cell adhesion, proliferation, and differentiation. However, challenges such as high production costs and poor stability in the commercial production of nanofibers need to be addressed. Overall, collagen dressings hold great promise for future applications and can play a significant role in skin tissue engineering and even in vivo tissue engineering.","PeriodicalId":18353,"journal":{"name":"Materials Today Chemistry","volume":"207 1","pages":""},"PeriodicalIF":7.3,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The compelling global warming crisis as well as extraterrestrial artificial light synthesis craves photocatalytic reduction of CO into fuels and value-added chemicals, for which efficient and robust catalysts with high selectivity and conversion rate is a prerequisite but hitherto a rarity. Herein we create a lead-free double metal perovskite of CsAgBiBr, coupling with mesoporous/microporous UiO-66-NH MOF to form type-II heterojunctions for efficient photocatalytic reduction of CO with a high CO selectivity of 95 % at an electron consumption rate of 33 μmol g h (13.4 μmol g h for CO and 0.72 μmol g h for CH). Multilayered mesoporous MOF particles manifest higher catalytic activity than their microporous counterparts due to the highly open mesoporous channels and larger pore volume of the former. Femtosecond transient absorption in combination with in situ infrared spectroscopic measurements disentangle the underlying mechanism accounting for the high product selectivity: the ultrafast electron transfer of 12.3 ps from CsAgBiBr to UiO-66-NH-2 enables efficient charge separation; primary *COOH intermediates and rapid CO desorption from Bi-based photocatalyst lead to dominant CO product. Moreover, the MOF crystals maintain stability after γ-rays irradiation equivalent of over 45-year accumulation in a typical earth orbit, hinting their promising potential in extraterrestrial artificial light synthesis.
迫在眉睫的全球变暖危机和地外人工光合成需要光催化还原一氧化碳为燃料和高附加值化学品，而具有高选择性和高转化率的高效、坚固催化剂是前提条件，但迄今为止却非常罕见。在此，我们创造了一种无铅双金属包晶 CsAgBiBr，与介孔/微孔 UiO-66-NH MOF 相结合，形成 II 型异质结，用于高效光催化还原 CO，CO 选择性高达 95%，电子消耗率为 33 μmol g h（CO 为 13.4 μmol g h，CH 为 0.72 μmol g h）。多层介孔 MOF 颗粒的催化活性高于微孔颗粒，这是因为前者具有高度开放的介孔通道和较大的孔体积。飞秒瞬态吸收结合原位红外光谱测量揭示了高产物选择性的内在机理：CsAgBiBr 与 UiO-66-NH-2 之间 12.3 ps 的超快电子转移实现了高效的电荷分离；初级 *COOH 中间产物和 Bi 基光催化剂的快速 CO 解吸导致 CO 产物占主导地位。此外，MOF 晶体在γ 射线辐照后仍能保持稳定，相当于在典型地球轨道上积累了 45 年以上，这表明它们在地外人造光合成方面具有广阔的潜力。
{"title":"Disentangling the efficient photocatalytic reduction of CO2 by a stable UiO-66-NH2/Cs2AgBiBr6 catalyst","authors":"Na Li, Yan-Long Ma, Hui-Jie Zhang, Dan-Yang Zhou, Bei-Lin Yao, Jian-Feng Wu, Xin-Ping Zhai, Bo Ma, Ming-Jun Xiao, Qiang Wang, Hao-Li Zhang","doi":"10.1016/j.mtchem.2024.102306","DOIUrl":"https://doi.org/10.1016/j.mtchem.2024.102306","url":null,"abstract":"The compelling global warming crisis as well as extraterrestrial artificial light synthesis craves photocatalytic reduction of CO into fuels and value-added chemicals, for which efficient and robust catalysts with high selectivity and conversion rate is a prerequisite but hitherto a rarity. Herein we create a lead-free double metal perovskite of CsAgBiBr, coupling with mesoporous/microporous UiO-66-NH MOF to form type-II heterojunctions for efficient photocatalytic reduction of CO with a high CO selectivity of 95 % at an electron consumption rate of 33 μmol g h (13.4 μmol g h for CO and 0.72 μmol g h for CH). Multilayered mesoporous MOF particles manifest higher catalytic activity than their microporous counterparts due to the highly open mesoporous channels and larger pore volume of the former. Femtosecond transient absorption in combination with in situ infrared spectroscopic measurements disentangle the underlying mechanism accounting for the high product selectivity: the ultrafast electron transfer of 12.3 ps from CsAgBiBr to UiO-66-NH-2 enables efficient charge separation; primary *COOH intermediates and rapid CO desorption from Bi-based photocatalyst lead to dominant CO product. Moreover, the MOF crystals maintain stability after γ-rays irradiation equivalent of over 45-year accumulation in a typical earth orbit, hinting their promising potential in extraterrestrial artificial light synthesis.","PeriodicalId":18353,"journal":{"name":"Materials Today Chemistry","volume":"7 1","pages":""},"PeriodicalIF":7.3,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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