Materialwissenschaft und Werkstofftechnik最新文献

The illustrations above demonstrate that as the percentage of niobium increases, the grain size decreases, leading to an increase in the stability of transformation induced plasticity steel. This, in turn, results in improved mechanical strength. The optimal volume fraction of retained austenite for a significant transformation induced plasticity effect to occur is reported to be in the range of 10 vol. %–20 vol. %. The volume fraction of retained austenite directly determines the carbon content and grain size of the retained austenite, its two main stabilization factors. The stability of the retained austenite dictates when the strain-induced martensite transformation (SIMT) occurs during straining of transformation induced plasticity high strength steel. Unstable retained austenite transforms almost immediately upon deformation, increasing work hardening rate and formability during the stamping process. At the appropriate stability of the retained austenite, the Strain-Induced Martensite Transformation begins only at strain levels beyond those produced during stamping and forming, and the retained austenite is still present in the final part; it can transform into martensite in the event of a crash, providing greater crash energy absorption. The tensile strength level of micro-alloyed transformation induced plasticity steels may exceed 1 GPa. Grain refinement mechanism is considered as the most applied mechanism used in increasing of steel strength without deterioration of ductility and toughness. Recently, it was proposed that the grain refinement could act positively on promoting the transformation induced plasticity effect of advanced high strength steel through improving the stability of retained austenite. In this research, quenching and partitioning heat treatment technique was applied to four grades of low carbon steel with different percentage of niobium. Then, the effect of niobium on grain refinement has been detected by microstructure observations. Mechanical properties and strain hardening properties of investigated steel have been determined. In addition, by using x-ray diffraction, as well as a new electric resistance-based sensor, it was possible to characterize the stability of the retained austenite through the plastic deformation of steel. Grain refinement by using of niobium has a great impact on promoting the stability of retained austenite against the plastic stress at the plastic deformation zone.

Using the fluorescence method, the study quantifies the cleaning efficiency of flat surfaces of selected materials (steel, polymethyl methacrylate, glass) compared to the usual cleaning methods: cleaning using ultrasound and cleaning using solutions (ethanol/isopropyl alcohol – isopropanol). Cleaning using ethanol/isopropanol solutions was carried out in such a way as to simulate common procedures: rubbing, rinsing and a combination of application of the solution and ultrasound. Based on the prepared and evaluated (following the average at several places on the surface) values of fluorescence maps of material surfaces, the resulting values of fluorescence before/after cleaning or at the selected moment of degreasing/cleaning of surfaces (applies to steel) were determined. The application of diffuse coplanar surface barrier discharge plasma discharge to the surfaces of flat materials can provide: a reduction in the environmental burden (no chemicals are needed to clean the surfaces) and an improvement in the efficiency of surface cleaning in industrial/manufacturing conditions (plasma cleaning usually takes a few seconds). diffuse coplanar surface barrier discharge plasma can clean and simultaneously activate the surfaces of flat materials.

The diffusion absorption refrigeration (DAR) systems are driven by heat and utilize a binary solution along with an inert gas as the working fluid. In commercial applications, the choice of binary solutions operating with an auxiliary gas is typically limited to ammonia-water or water-lithium bromide combinations. The focus of this study is to explore the viability of using tetrafluoropropene (R-1234yf, an HFO refrigerant) as the refrigerant, dimethylacetamide (DMAC) as the absorbent, and helium as the auxiliary gas. As the thermodynamic properties of this specific binary solution are yet to be studied, experimental investigations are conducted to obtain these properties. The results allow the establishment of the pressure-temperature and concentration relationships and determine the mixture‘s enthalpy for various temperatures. Subsequently, both numerical and experimental analyses of the diffusion absorption system are performed. The experimental findings show that, under certain concentrations of the components and with appropriate heat input, temperatures in the evaporator reached below 0 °C. However, the system exhibits low coefficient of performance values, high generation temperatures, and overall inefficiency, suggesting that this particular binary solution may not be well-suited for diffusion absorption cooling systems.

The manuscript presents the synthesis and dry sliding wear performance of Al7075 alloy-based composites. Five compositions namely Al7075 alloy, Al7075+3 vol % molybdenum disulfide, Al7075+3 vol % molybdenum disulfide+3 vol % zirconium diboride, Al7075+3 vol % molybdenum disulfide+6 vol % zirconium diboride and Al7075+3 vol % molybdenum disulfide+9 vol % zirconium diboride were stir cast and characterized for hardness, x-ray diffraction, microstructure, and tribological properties. In-situ formed zirconium diboride particles increase the hardness of Al7075 alloy whereas molybdenum disulfide shows the opposite trend due to its self-lubricating nature. X-ray diffraction analysis identifies subsequent phase particles in the matrix while microstructural images exhibit the dispersion and morphology of reinforcement particles. The wear tests and friction coefficient were analyzed with variations of sliding velocity, normal load, sliding distance, and compositions. Further, the obtained wear results were also correlated with microstructure and wear surface topography. Al7075+3 vol % molybdenum disulfide composite shows the lowest coefficient of friction because of its self-lubricating nature. Al7075+3 vol % molybdenum disulfide+9 vol % zirconium diboride hybrid composite exhibits the lowest wear rate at high velocity as well as at high load and can be potentially used in manufacturing and tribological applications. Moreover, the use of this material may lead to the minimum requirement of external toxic lubricants that make it cost-effective and environmentally sustainable.

Commercial titanium dioxide is successfully plasma-treated under ambient conditions for different periods, leading to reduced crystallite size and the creation of oxygen vacancies. Density functional theory-based calculations reveal the emergence of additional localized states close to the conduction band, primarily associated with under-coordinated titanium atoms in non-stoichiometric titanium-oxide systems. The plasma-treated samples exhibit improved photocatalytic performance in the degradation of methylene blue compared to untreated samples. Moreover, the 4-hour plasma-treated photocatalyst demonstrates commendable stability and reusability. This work highlights the potential of cost-effective plasma treatment as a simple modification technique to significantly enhance the photocatalytic capabilities of titanium-oxide materials.

Microstructural characteristics and mechanical properties of the ductile iron in three heat treatment processes (normalizing, quenching + high-temperature tempering and isothermal quenching) were investigated in this paper. The pearlite and ferrite with large-sized spherical graphites can be obtained in the normalized sample, and the spherical graphites with relatively large size can still be observed in the mechanical mixture of tempered martensite and acicular ferrite for the quenched-tempered sample. Meanwhile, the lower bainite accompanied with the relatively fine spherical graphites are existed in the isothermal-quenched sample. The difference of tensile strength is mainly caused by the phase composition, distribution and size of the spherical graphites and the effect of the solid solution strengthening. The weaker degree of the debonding damage, higher proportion of high-angle grain boundaries will improve the impact toughness of the ductile iron. In a word, the optimum combination of strength and toughness is acquired by using isothermal quenching, and the tensile strength and impact toughness are ~1350 MPa and ~10.62 J, respectively.

An advanced material known as structurally graded material has composition and structure that gradually alters or changes the quality of material in tandem. Various materials could be used with this idea for structural and practical purpose. By offering practical and affordable solutions for design validation, product prototype, and production of high-performance functional components, fused deposition modelling, a highly regarded three-dimensional printing technique, has sparked the industrial advancements. Fiber reinforced polymer (polylactic acid-based composites) are replacing traditional thermosetting polymers and steel as alternative materials. The aircraft industry and energy industry (gas turbines, structural re-entry thermal production) both frequently utilize ceramic reinforced polymer. In these applications, ceramic reinforced polymer components must be permanently or temporarily adhered to the surrounding materials. Here, in this research work structurally graded wall is fabricated using carbon fiber reinforced polymer and ceramic reinforced polymer through fused deposition modelling process. This research work for creation of structurally graded material architecture was inspired by idea of merging seemingly incompatible functionalities such as the toughness of carbon fiber reinforced polymer and refractoriness of ceramic reinforced polymer with the relaxing of defects.