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Summary: Effects of minor elements on weld cracking in superalloys 摘要:微量元素对高温合金焊缝开裂的影响
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274972
M. Gittos, M. Scott
There are several distinct types of cracking which can occur during the fusion welding of superalloys, and they can all occur at high temperature. The cracking may occur in the weld metal or the heat-affected zone (HAZ), either during the making of the weld or during subsequent post-weld heat treatment. The latter applies only to precipitationhardened alloys, and has been described as strain-age cracking, but heat-treatment cracking is the preferred term. Solidification cracking occurs in the weld metal during the freezing of the weld pool and is usually referred to as being super-solidus. Liquation cracking occurs either in the HAZ or in previously deposited weld metal, reheated by an adjacent subsequent pass; it is associated with microsegregation. Ductility-dip cracking occurs in the HAZ, in weld metal, or in weld metal reheated by subsequent passes, and the same is true of heat-treatment cracking. Superalloys can be based on Fe, Ni, or Co, but most of the reported information relates to Ni-based alloys and very little to Co-based alloys. Nearly all of it deals with contents of minor elements above those that would normally be regarded as trace levels. The information available in the literature contains numerous apparent contradictions concerning the effects of elements on both individual crack mechanisms and different types of cracking. The influence of the various elements on weld cracking is discussed by grouping together the reported effects of each element on the various alloys and mechanisms which have been investigated. The behaviour of C provides an example of the confusing results that have been reported. Although one leading authority states that C has no effect on the weldability of Ni-Cr alloys, others have found that it promotes HAZ liquation, that it should be increased to stop HAZ liquation, and at low levels that it either aggravates or ameliorates post-weld heat-treatment cracking. There is general agreement on the detrimental effects of S, P, Pb, Sn, and Zr on high-temperature cracking resistance, and that high levels of Ti +Al promote postweld heat-treatment cracking. However, the effects of C, Si, Mg, and La are variable, and elements such as B have been shown to act in opposite senses for different crack mechanisms. Nb and Mn are generally accepted as having beneficial influences on weld cracking, although both have been demonstrated by microanalysis techniques to show an association with liquated (but not necessarily cracked) grain boundaries. In part, these contradictions can perhaps be explained by the existence of critical ranges within which a given element is harmful. This behaviour is perhaps best known and documented for AI alloys, where the effect of a given element on solidification cracking passes through a maximum at some given concentration. There is also the possibility of interaction between elements, minor and/or major, which may well influence the effect of any given element; this is particularly likely t
在高温合金的熔焊过程中可能发生几种不同类型的裂纹,它们都可能在高温下发生。开裂可能发生在焊缝金属或热影响区(HAZ),无论是在焊接过程中还是在随后的焊后热处理过程中。后者仅适用于沉淀硬化合金,并被描述为应变时效开裂,但热处理开裂是首选的术语。在焊接熔池冻结过程中,焊缝金属发生凝固裂纹,通常被称为超固相。液化开裂要么发生在热影响区,要么发生在先前沉积的焊接金属中,由相邻的后续道次再加热;它与微偏析有关。塑性倾斜裂纹发生在热影响区、焊缝金属或经过后续道次再加热的焊缝金属中,热处理裂纹也是如此。高温合金可以基于铁、镍或钴,但大多数报道的信息涉及镍基合金,很少涉及钴基合金。几乎所有的研究都涉及通常被视为痕量水平以上的微量元素的含量。文献中提供的信息包含了许多关于元素对单个裂纹机制和不同类型裂纹的影响的明显矛盾。通过将各元素对各种合金的影响和已研究的机制组合在一起,讨论了各元素对焊缝开裂的影响。C语言的行为提供了一个报告中令人困惑的结果的例子。尽管一位权威人士指出,C对Ni-Cr合金的可焊性没有影响,但其他人发现它促进热影响区液化,应该增加C以阻止热影响区液化,并且在低水平时,它要么加剧要么改善焊后热处理开裂。人们普遍认为,S、P、Pb、Sn和Zr对高温抗裂性有不利影响,而高含量的Ti +Al会促进焊后热处理开裂。然而,C、Si、Mg和La的作用是可变的,而B等元素已被证明在不同的裂纹机制中起相反的作用。Nb和Mn通常被认为对焊缝开裂有有益的影响,尽管两者都已被微量分析技术证明与液化(但不一定是开裂)晶界有关。在某种程度上,这些矛盾也许可以用某一特定元素有害的临界范围的存在来解释。这种行为可能在AI合金中最为人所知和记录,其中给定元素对凝固裂纹的影响在某些给定浓度下达到最大值。次要和/或主要元素之间也可能相互作用,这很可能影响任何给定元素的效果;对于合金添加量变化很大的高温合金来说尤其如此。研究微量元素对焊缝开裂影响的困难部分与焊接和焊接模拟技术固有的不一致性有关,但各种各样的商业合金的使用也无疑往往掩盖了故意添加元素和杂质元素的各种组合的重要相互作用。
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引用次数: 2
Mechanical properties and microstructure of lovv-carbon-4% manganese steels lovv-碳-4%锰钢的力学性能和显微组织
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274909
R. Reuben, T. N. Baker
AbstractThree vacuum-melted steels based on a composition 0·05–0·08C–4·0Mn, with and without a niobium addition, were controlled rolled to a finish-rolling temperature in the range 700−950°C and air cooled to room temperature. Measurements were made of the ferrite mean free distance, which was correlated with strength and toughness data. Additional qualitative information on precipitation was also gathered. Finished material showed a wide range of strength and toughness. Proof stresses were in the range 610–930 MNm−2 and ductile-brittle (55 J) transition temperatures varied between −90 and + 30°C. The properties of a given material seem to be governed by the carbon and niobium contents, as well as by the ferrite mean free distance. Up to 0·08%C, very high strength coupled with adequate toughness seemed to be obtained by retaining as much carbon in solution as possible, particularly by avoiding cementite precipitation. A fine NbC precipitation appeared to have a beneficial effect on toughness.
摘要对三种成分为0.005 - 0.08 C - 4.0 mn的真空熔炼钢,分别添加和不添加铌,控制轧制至700 ~ 950℃的精轧温度,然后风冷至室温。测量了铁氧体的平均自由距离,并将其与强度和韧性数据相关联。还收集了关于降水的其他定性资料。成品材料表现出广泛的强度和韧性。证明应力在610-930 MNm - 2范围内,韧脆(55 J)转变温度在- 90和+ 30℃之间变化。给定材料的性质似乎受碳和铌含量以及铁氧体平均自由距离的支配。在高达0.08%的温度下,通过在溶液中尽可能多地保留碳,特别是通过避免渗碳体的析出,似乎可以获得非常高的强度和足够的韧性。良好的NbC降水似乎对韧性有有益的影响。
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引用次数: 3
Trace elements in superalloys–an overview 高温合金中的微量元素综述
Pub Date : 1984-01-01 DOI: 10.1179/030716984803275188
G. W. Meetham
AbstractThis paper commences with a brief description of superalloys and their applications. Trace elements which may be present are classified, and their effects, adverse or beneficial, are briefly summarized. More detailed discussion of effects and mechanisms will be provided in the other papers in this issue. Some elements may be beneficial in small concentrations, but harmful in larger ones. In many cases, the effects of individual elements have been sufficiently quantified to allow specification limits to be set, but further work is required on the effects of different elemental combinations, on analysis at low concentrations, and on the mechanisms by which some trace element effects operate. With respect to the control of trace elements, it is necessary to specify not only the purity of the metallic raw materials, but also the purity of consumable manufacturing-process materials.
摘要本文首先简要介绍了高温合金及其应用。对可能存在的微量元素进行了分类,并简要总结了它们的作用,有害的或有益的。关于影响和机制的更详细讨论将在本期的其他论文中提供。有些元素浓度小可能有益,但浓度大则有害。在许多情况下,单个元素的影响已经得到了充分的量化,可以设定规格限制,但需要进一步研究不同元素组合的影响、低浓度分析的影响以及一些微量元素影响的机制。对于微量元素的控制,不仅要规定金属原料的纯度,而且要规定耗材的纯度。
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引用次数: 50
Strength and toughness of T42 high-speed steel T42高速钢的强度和韧性
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274387
C. S. Wright, A. Wronski, M. M. Rebbeek
AbstractHardness and compressive strength, Young's modulus, bend strength, and fracture toughness were measured in wrought and commercially sintered T42 high-speed steel. After identical heat treatments, no significant differences were found between wrought and sintered materials in hardness (800–1010 HV50), Young's modulus (∼220 GN m−2), or fracture toughness (9−18 MN m−3/2). The four-point bend strengths in the wrought material were slightly higher in specimens cut longitudinal to the working direction than in transverse specimens (1·3–2·4 GN m−2), and both were markedly superior in strength to the sintered material (1·0–1·2 GN m−2). For three-point bend tests with laboratory-sintered material, the stresses for brittle fracture were in the range 1·9–3·0 GN m−2, a level comparable to the wrought specimens. Wrought material contained carbide stringers with a scattering of large Me carbides, whereas in the sintered material pores and incomplete bonding could be detected, albeit infrequently. Fracture initi...
摘要:测定了T42高速钢的硬度、抗压强度、杨氏模量、弯曲强度和断裂韧性。经过相同的热处理,锻造材料和烧结材料在硬度(800-1010 HV50)、杨氏模量(~ 220 GN m−2)或断裂韧性(9 - 18 MN m−3/2)方面没有显著差异。变形后材料的四点弯曲强度在纵向(1·3 ~·4 GN m−2)略高于横向(1·3 ~·4 GN m−2),且均明显优于烧结材料(1·0 ~ 1·2 GN m−2)。在实验室烧结材料的三点弯曲试验中,脆性断裂的应力范围为1.9 - 3.0 GN m−2,与变形试样的水平相当。锻造材料中含有碳化物条纹,并有大量Me碳化物的散射,而在烧结材料中可以检测到孔隙和不完全结合,尽管不常见。骨折initi……
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引用次数: 20
Comparison of two methods of cold work to increase strength of hot-rolled reinforcing bar 两种冷加工提高热轧钢筋强度方法的比较
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274891
L. N. Pussegoda
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引用次数: 1
Stresscorrosion-rack grovvth behaviour of 7475 T6 retrogressed and reaged aluminium alloy 7475t6回温铝合金的应力腐蚀-齿条生长行为
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274594
M. Islam, W. Wallace
AbstractThe results of an investigation on the effects of long retrogression times of up to 4 h at 180 and 200°C, and short times of up 10 5 min at 240, 260, and 280°C, on the yield strength, electrical conductivity, and stress-corrosion-crack growth resistance of 7475 T6 aluminium alloy are presented. One optimum retrogression time to provide T6 strength and T73 electrical conductivity was selected for each temperature investigated and was applied to double-cantilever-beam (DCB) stress-corrosion-crack growth specimens. The results show that stress-corrosioncrack growth rates in retrogressed and reaged material are comparable to those in T73 material. Moreover, the 0·2% yield strengths, obtained from specimens machined from the broken DCB specimens, are also above the T6 design-strength level.
摘要研究了在180和200℃下长时间(最长可达4 h)和在240、260和280℃下短时间(最长可达10.5 min)对7475 T6铝合金屈服强度、电导率和抗应力腐蚀裂纹扩展性能的影响。在每个温度下,选择一个最佳的退化时间来提供T6强度和T73电导率,并将其应用于双悬臂梁(DCB)应力腐蚀裂纹扩展试样。结果表明,回火和回火材料的应力腐蚀裂纹扩展速率与T73材料相当。此外,破碎DCB试件加工得到的0.2%屈服强度也高于T6设计强度水平。
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引用次数: 22
Differential resistivity as a means of monitoring annealing in steels 差分电阻率作为监测钢退火的一种方法
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274576
R. Drew, W. B. Muir, W. M. Williams
AbstractAnnealing of cold-worked plain carbon and high-strength low-alloy steels may be monitored in situ by measurement of differential electrical resistivity using an alternating current method. The change in room-temperature resistivity is about 4% for steels given a prior cold reduction of 80%. Recovery and recrystallization are distinguishable as two separate stages in these materials; the onset and end point of recrystallization can be identified during the progress of annealing. It was also possible to observe changes in resistivity resulting from grain growth. However, the changes could not be quantified since grain-growth rates were extremely slow in the steels studied.
摘要:用交流电法测量差电阻率,可以现场监测冷加工普通碳钢和高强度低合金钢的退火过程。对于预先冷还原80%的钢,室温电阻率的变化约为4%。在这些材料中,恢复和再结晶可区分为两个独立的阶段;在退火过程中可以确定再结晶的起始点和结束点。还可以观察到由于晶粒生长而引起的电阻率变化。然而,由于所研究的钢的晶粒生长速度极其缓慢,因此这种变化无法量化。
{"title":"Differential resistivity as a means of monitoring annealing in steels","authors":"R. Drew, W. B. Muir, W. M. Williams","doi":"10.1179/030716984803274576","DOIUrl":"https://doi.org/10.1179/030716984803274576","url":null,"abstract":"AbstractAnnealing of cold-worked plain carbon and high-strength low-alloy steels may be monitored in situ by measurement of differential electrical resistivity using an alternating current method. The change in room-temperature resistivity is about 4% for steels given a prior cold reduction of 80%. Recovery and recrystallization are distinguishable as two separate stages in these materials; the onset and end point of recrystallization can be identified during the progress of annealing. It was also possible to observe changes in resistivity resulting from grain growth. However, the changes could not be quantified since grain-growth rates were extremely slow in the steels studied.","PeriodicalId":18409,"journal":{"name":"Metals technology","volume":"33 1","pages":"550-554"},"PeriodicalIF":0.0,"publicationDate":"1984-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80878644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Sources of trace elements in primary raw materials used in production of superalloys 高温合金生产中主要原料中微量元素的来源
Pub Date : 1984-01-01 DOI: 10.1179/030716984803275232
A. V. Bromley, R. H. Parker
AbstractThe stringent demands of producers of Ni-based superalloys set lower permissible levels of deleterious trace elements than those that are normally considered significant by the geologist or the extractive metallurgist. The classification of metallic elements as siderophile, chalcophile, and/or lithophile is found to be a good general guide, as the most harmful superalloy trace elements have strongly chalcophile characteristics, i.e. they are concentrated in sulphides. Ore associations of the major superalloy metals Ni, Co, Cr, Mo, Al, and Ti are reviewed, and it is suggested that only in the case of lateritic Ni and Co ores is any form of ore source selection likely to alleviate problems associated with deleterious trace elements. In all other cases, the problems are passed on to the extractive metallurgist, whose product purity is reviewed from the point of view of the trace elements Sb, As, Bi, Cd, Ga, In, Pb, Mg, Se, Ag, Te, Tl, Sn, and Zn. The purity of carbonyl and some electrolytic Ni seems ...
摘要镍基高温合金生产商的严格要求,使有害微量元素的允许含量低于地质学家或萃取冶金学家通常认为重要的水平。将金属元素分类为亲铁、亲铜和/或亲石是一个很好的一般指南,因为最有害的高温合金微量元素具有强烈的亲铜特征,即它们集中在硫化物中。对主要高温合金金属Ni、Co、Cr、Mo、Al和Ti的矿石组合进行了综述,并提出只有在红土型Ni和Co矿石的情况下,任何形式的矿石来源选择都可能减轻与有害微量元素相关的问题。在所有其他情况下,问题都交给萃取冶金学家,他们从微量元素Sb、As、Bi、Cd、Ga、In、Pb、Mg、Se、Ag、Te、Tl、Sn和Zn的角度来审查产品的纯度。羰基和一些电解镍的纯度似乎…
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引用次数: 8
31st Hatfield Memorial Lecture: Stainless steels – materials in competition 第31届哈特菲尔德纪念讲座:不锈钢——竞争中的材料
Pub Date : 1984-01-01 DOI: 10.1179/030716984803275034
R. Kießling
AbstractThe subject of stainless steels was chosen by the author for this lecture because of Dr Hatfield's pioneering work in this field. He feels, however, that today these steels are under intense competition; the interface between producer and consumer is given particular attention. The importance attached to this aspect of the producers' activities means that the problems under consideration fall as much in the field of market research as of physical metallurgy – it is necessary for suppliers to think as consumers rather than as producers. The competition from other materials with respect to physical properties is not very severe, but that in terms of economic considerations is strong, especially in view of the current overcapacity of the steel industry and the increasing prevalence of trade restrictions. A very brief review is given of contemporary stainless steels, together with a more detailed discussion of duplex austenitic–ferritic steels, which also furnish an example of the need for close coope...
由于哈特菲尔德博士在这一领域的开创性工作,作者选择了不锈钢作为这次讲座的主题。然而,他感到,如今这些钢材面临着激烈的竞争;生产者和消费者之间的界面受到特别关注。对生产者活动这一方面的重视意味着所考虑的问题既属于物理冶金领域,也属于市场研究领域- -供应商必须从消费者而不是生产者的角度考虑问题。在物理性能方面,来自其他材料的竞争不是很激烈,但在经济考虑方面,竞争很激烈,特别是考虑到目前钢铁行业的产能过剩和日益普遍的贸易限制。简要回顾了现代不锈钢,并对双相奥氏体-铁素体钢进行了更详细的讨论,这也提供了一个需要密切合作的例子。
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引用次数: 3
Conservation of energy and materials by recycling complex alloys 通过回收复杂合金来节约能源和材料
Pub Date : 1984-01-01 DOI: 10.1179/030716984803274413
G. Horn
AbstractTechniques for the recycling of complex alloys containing nickel, chromium, cobalt, molybdenum, tungsten, and titanium, in both solid and particulate form, are discussed. Material processed in this way has been accepted as sufficiently pure for direct charging into vacuum melting furnaces. Typical energy and cost savings that can be achieved by recycling complex alloys are presented.
摘要讨论了含镍、铬、钴、钼、钨和钛的复合合金的固体和颗粒回收技术。用这种方法加工的材料被认为是足够纯净的,可以直接装进真空熔炼炉。介绍了通过回收复杂合金可实现的典型能源和成本节约。
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引用次数: 0
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Metals technology
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